natgillin/translations-raw huggingface dataset:
συνολικός όνκος της υδατικής φάσης σε επαφή με το έδαφος κατά τη διάρκεια της δοκιμής κινητικής εκρόφησης (cm3).
total volume of the aqueous phase in contact with the soil during the desorption kinetics test (cm3).
Οδηγίες για τον υπολογισμό της maq
Guidance for calculating the maq
δίδονται στο προσάρτημα 5 υπό τον τιτλο «Εκρόφηση».
is given in Appendix 5 under the heading ‘Desorption’.
Παρατήρηση:
Remark
Εάν η προηγηθείσα δοκιμή προσρόφησης εκτελέστηκε με την παράλληλη μέθοδο, ο όγκος VT στην εξίσωση (12) θεωρείται ότι είναι ίσος με V0.
If the adsorption test which was preceded, was performed with the parallel method the volume VT in the equation (12) is considered to be equal to V0.
Η εξίσωση των ισοθέρμων εκρόφησης Freundlich δίδει την υπάρχουσα σχέση της συγκέντρωσης της υπό δοκιμή ουσίας που παραμένει προσροφημένη στο έδαφος με τη συγκέντρωση της υπό δοκιμή ουσίας στο διάλυμα σε κατάσταση ισορροπίας εκρόφησης (εξίσωση 16).
The Freundlich desorption isotherms equation relates the content of the test substance remaining adsorbed on the soil to the concentration of the test substance in solution at desorption equilibrium (equation 16).
Για κάθε δοκιμαστικό σωλήνα, η συγκέντρωση της ουσίας που παραμένει προσροφημένη στο έδαφος σε κατάσταση ισορροπίας εκρόφησης υπολογίζεται ως εξής:
For each test tube, the content of the substance remaining adsorbed on soil at desorption equilibrium is calculated as follows:
συγκέντρωση της υπό δοκιμής ουσίας που παραμένει προσροφημένη στο έδαφος σε κατάσταση ισορροπίας εκρόφησης (μg g-1);
content of the test substance remaining adsorbed on the soil at desorption equilibrium (μg g-1);
μάζα ουσίας που προσδιορίζεται αναλυτικώς στην υδατική φάση σε κατάσταση ισορροπίας εκρόφησης
mass of substance determined analytically in the aqueous phase at desorption equilibrium (μg);
μάζα της υπό δοκιμή ουσίας που περισσεύει από την ισορροπία προσρόφησης λόγω ατελούς κατ' όγκο αντικατάστασης (μg),
mass of the test substance left over from the adsorption equilibrium due to incomplete volume replacement (μg);
όγκος του διαλύματος που παραλαμβάνεται από το σωλήνα για τη μέτρηση της υπό δοκιμή ουσίας σε κατάσταση ισορροπίας εκρόφησης (cm3);
volume of the solution taken from the tube for the measurement of the test substance, at desorption equilibrium (cm3);
όγκος του υπερκείμενου υγρού που απομακρύνεται από το σωλήνα μετά την επίτευξη ισορροπίας προσρόφησης και αντικαθίσταται από το ίδιο όγκο διαλύματος 0,01 Μ CaCl2(cm3).
volume of the supernatant removed from the tube after the attainment of adsorption equilibrium and replaced by the same volume of a 0,01 M CaCl2 solution (cm3);
Η εξίσωση εκρόφησης Freundlich δίνεται από τον τύπο (16):
The Freundlich desorption equation is shown in (16):
συντελεστής εκρόφησης Freundlich,
Freundlich desorption coefficient;
n σταθερά αναγωγής,
n regression constant;
κ.ό. συγκέντρωση της ουσίας στην υδατική φάση σε κατάσταση ισορροπίας εκρόφησης μg cm-3).
mass concentration of the substance in the aqueous phase at desorption equilibrium (μg cm-3).
Οι εξισώσεις 16 και 17 μπορούν να παρασταθούν γραφικώς και οι τιμές των και KF
The equations (16) and (17) can be plotted and the value of KF
1/n υπολογίζονται με ανάλυση αναγωγής χρησιμοποιώντας την εξίσωση 17.
and 1/n are calculated by regression analysis using the equation 17.
Εάν ο εκθέτης προσρόφησης η εκρόφησης Freundlich 1/n είναι ίσος με 1. οι σταθερές συνδέσεως προσρόφησης ή εκρόφησης Freundlich (και ) θα είναι ίσες με τις σταθερές ισορροπίας προσρόφησης ή εκρόφησης (KF
if the Freundlich adsorption or desorption exponent 1/n is equal to 1, the Freundlich adsorption or desorption binding constant (KF
και KF
and KF
αντιστοίχως, και οι καμπύλες των CS εναντι Caq θα είναι γραμμικές.
will be equal to the adsorption or desorption equilibrium constants (Kd and Kdes) respectively, and plots of Cs vs Caq will be linear.
Εάν οι εκθέτες δεν είναι ίσοι με 1. οι καμπύλες των Cb έναντι Caq δεν θα είναι γραμμικές και ο; σταθερές προσρόφησης και εκρόφησης θα διαφέρουν κατά μήκος των ισοθέρμων.
If the exponents are not equal to 1, plots of Cs vs Caq will be non-linear and the adsorption and desorption constants will vary along the isotherms.
η πλήρης ταυτότητα των χρησιμοποιηθέντων εδαφικών δειγμάτων συμπεριλαμβανομένων:
complete identification of the soil samples used including,
του γεωγραφικού εντοπισμού της τοποθεσίας (γεωγραφικό πλάτος και μήκος),
geographical reference of the site (latitude, longitude),
της ημερομηνίας δειγματοληψίας,
date of sampling,
του προτύπου χρήσεως (π.χ. γεωργικό έδαφος, δάσος, κ.λπ.),
use pattern (e.g. agricultural soil, forest, etc.),
του βάθους δειγματοληψίας,
depth of sampling,
της περιεκτικότητας σε άμμο/προσχωσιγενή/άργιλο,
sand/silt/clay content;
των τιμών pH (σε 0,01 Μ CaCl2),
pH values (in 0,01 M CaCl2),
της περιεκτικότητας σε οργανικό άνθρακα,
organic carbon content,
της περιεκτικότητας σε οργανική ύλη,,
organic matter content,
της περιεκτικότητας σε άζωτο,
nitrogen content,
της σχέσης C/N,
C/N ratio,
της κατιοανταλλακτικής ικανότητας (mmol/kg),
cation Exchange Capacity (mmol/kg),
κάθε στοιχείου σχετικού με τη συλλογή και αποθήκευση εδαφικών δειγμάτων,
all information relating to the collection and storage of soil samples,
όπου χρειάζεται, κάθε σχετικού στοιχείου για την ερμηνεία της προσρόφησης-εκρόφησης της υπό δοκιμή ουσίας,
where appropriate, all relevant information for the interpretation of the adsorption — desorption of the test substance,
αναφοράς των μεθόδων που χρησιμοποιήθηκαν για τον προσδιορισμό κάθε παραμέτρου,
reference of the methods used for the determination of each parameter,
πληροφορίες για την υπό δοκιμή ουσία, όπου απαιτείται,
information on the test substance as appropriate,
η θερμοκρασία των πειραμάτων,
temperature of the experiments,
οι συνθήκες φυγοκέντρησης,
centrifugation conditions,
η αναλυτική διαδικασία που χρησιμοποιήθηκε για την ανάλυση της υπό δοκιμή ουσίας,
analytical procedure used to analyse the test substance,
αιτιολόγηση της τυχόν χρήσεως διαλυτοποιητικού μέσου για την παρασκευή του αρχικού διαλύματος της υπό δοκιμή ουσίας,
justification for any use of solubilising agent for the preparation of the stock solution of the test substance,
επεξηγήσεις για τις τυχόν διορθώσεις που έγιναν στους υπολογισμούς,
explanations of corrections made in the calculations, if relevant,
δεδομένα σύμφωνα με το έντυπο (προσάρτημα 6) και γραφικές παραστάσεις,
data according to the form sheet (Appendix 6) and graphical presentations,
κάθε πληροφορία και παρατήρηση που είναι χρήσιμη για την ερμηνεία των αποτελεσμάτων των δοκιμών.
all information and observations helpful for the interpretation of the test results.
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