natgillin/translations-raw huggingface dataset:
Følgende formel anvendes til beregning af den samlede påvirkning fra MBT og DBT. 
The following form is used to calculate the total effect of MBT and DBT.
En brøksum < 1 svarer til, at der ikke er grund til sundhedsmæssig bekymring for det samlede indhold af MBT og DBT i bogen: 
A fraction sum < 1 means that the total content of MBT and DBT in the book do not cause any health concern.
Daglig eksponering, tin, nyfødt: 
Daily exposure, tin, newborn:
Daglig eksponering, tin, 1,5 år: 
Daily exposure, tin, 1.5 years:
Det ses af ovenstående beregning, at der ikke er grund til sundhedsmæssig bekymring for indholdet af MBT og DBT i bogen. 
The above calculation shows that the content of MBT and DBT in the book does not cause reason for health concern.
MoS, MBT + DBT, nyfødt: 
MoS, MBT + DBT, newborn:
En høj MoS yder en stor sikkerhed for forbrugeren. 
A high MoS means a good protection of the consumer.
Det vil således være muligt at estimere hvor stor en andel af TDI, der kan allokeres til eksponering fra forbrugerprodukter. 
An estimation of how large an amount of TDI that could be allocated to consumer products is then possible.
Miljøstyrelsen udvalgte på baggrund af kortlægningsfasen følgende produkter til testning: 
Based on the survey phase the Danish Environmental Protection Agency selected the following products for testing:
Analysedelen var en iterativ proces, der blev indledt med kvalitative og kvantitative analyser af 8 produkter for bromerede flammehæmmere, TCEP, phthalater og tungmetaller. 
The analysis part, which was an iterative process, was initiated with qualitative and quantitative analyses of 8 products for bromated flame-retardants, TCEP, phthalates and metals.
Der blev endvidere testet for indhold af organotinforbindelser og indhold af farvestoffer samt screenet for flygtige organiske stoffer i udvalgte produkter. 
Performed were also tests for content of organic tin compounds, content of colorants and screening for volatile organic compounds in selected products.
Der blev kun målt koncentrationer af phthalater og organotinforbindelser over detektionsgrænsen. 
Only concentrations of phthalates and organic tin compounds above the detection limit were measured.
Det blev påbudt at tilbagekalde to produkter (4 og 7) fra det danske marked, da de indeholdte phthalater i mængder, der var højere end den tilladte grænseværdi for legetøj beregnet til børn mellem 0-3 år på 0,05 % (3). . 
Based on the phthalate analyses, two products were withdrawn (4 and 7) from the Danish market because the contained amount was higher than the permitted limit value for phthalates in toys intended for children between 0-3 years (0.05%) (3).
5 kemiske stoffer blev udvalgt til den sundhedsmæssige vurdering i fase 3; diisobutylphthalat (DIBP), di-n-butylphthalat (DBP), diisononylphthalate (DINP), monobutyltin (MBT) og dibutyltin (DBT). 
5 chemical substances were selected for the health assessment to be performed in phase 3; diisobutylphthalate (DIBP), di-n-butylphthalate (DBP), diisononylphthalate (DINP), monobutyltin (MBT) og dibutyltin (DBT).
Forhandleren af produkt 1 er orienteret om indholdet af DINP i produktet og arbejder på at få stoffet helt ud af produktet. 
The distributor of product 1 has been informed about the content of DINP in the product and is working on eliminating the substance completely from the product.
En brøksum < 1 svarer til, at der ikke er grund til sundhedsmæssig bekymring for det samlede indhold af MBT og DBT i bogen. 
A fraction sum < 1 means that the total MBT and DBT in the book do not cause reason for health concern.
Den additive effekt af stofferne blev udregnet til 0,08 og 0,03 for hhv. et nyfødt barn og et barn på 1,5 år. 
The additive effect of the substances was calculated to be 0.08 and 0.03 for a newborn child and a child of 1.5 years, respectively.
Det vurderes derfor, at der ikke er grund til sundhedsmæssig bekymring for indholdet af MBT og DBT i bogen. 
Based on this calculation the content of MBT and DBT in the book should not cause any health concern.
Margin of Safety (MoS) for eksponering for de to organotinforbindelser fra bogen blev udregnet ved at dividere NOAEL med eksponeringen (under antagelse af at hele den målte mængde MBT (1,95 µg/kg bog) og DBT (1,15 µg/kg bog) frigives på én dag). 
The Margin of Safety (MoS) for the exposure of the two organic tin compounds from the book was calculated by dividing NOAEL with the exposure (under the assumption that the entire amount of MBT (1.95 µg/kg book) and DBT (1.15 µg/kg book) is released in one day.
En MoS på 86000 og 250000 blev udregnet hhv. for et nyfødt barn og et barn på 1,5 år, hvilket antages at give tilstrækkelig beskyttelse. 
A MoS of 86000 and 250000 was calculated for a newborn child and a child of 1.5 years old, respectively.
DTC vurderer at eksponering for organotinforbindelser fra bogen ikke giver anledning til sundhedsmæssig bekymring. 
DTC estimates that exposure to organic tin compounds from the book does not cause any health concerns.
DTC anbefaler at bidragene fra andre kilder udregnes. 
DTC recommends however that the contribution from other sources is calculated.
Det vil således være muligt at estimere hvor stor en andel af TDI, der kan allokeres til eksponering fra forbrugerprodukter. 
An estimation of how large an amount of TDI that could be allocated to consumer products would then be possible.
Kortlægning af kemiske stoffer i forbrugerprodukter 
Survey of Chemical Substances in Consumer Products
Undersøgelse af kemiske stoffer i varer indeholdende dekorative væsker 
Investigation of chemical substances in products containing decorative liquids
Birgit Lundskov, Anne Dilani Pedersen, Erik Andersen Teknologisk Institut, Kemiteknik 
Birgit Lundskov, Anne Dilani Pedersen, Erik Andersen Danish Technological Institute, Chemical Department
1 BAGGRUND OG FORMÅL 2 BESKRIVELSE AF VARER 3 ANALYSEMETODER 
SAMMENFATNING 1 BACKGROUND AND OBJECTIVE 2 DECRIPTION OF PRODUCTS 3 METHODS OF ANALYSIS
3.5 BESTEMMELSE AF KINEMATISK VISKOSITET 
3.5 DETERMINATION OF CINEMATIC VISCOSITY
I produkter med 2 faser er de farvede faser identificeret som vand og de farveløse faser som forskellige mineralske olier. 
In the samples with 2-phase liquids, the coloured liquids have been identified as water and the colourless liquids have been identified as different mineral oils.
Olierne består af kulbrinter i intervallet C8H18-C26H54. 
The oils consist of hydrocarbons in the interval C8H18-C26H54.
Disse blødgørere kan stamme fra plastmaterialet. 
These plasticizers might originate from the plastic container.
Farvestofferne er identificeret som triarylmethan farvestof (patentblå VF) og monoazo farvestoffer (sunset yellow, tartrazin, ponceau 4R, red 2G og acid red 33). 
The dyes were identified as triarylmethane dye (patent blue VF) and monoazo dyes (Sunset Yellow, Tartrazin, Ponceau 4R, Red 2G and Acid red 33).
Der kan desuden nævnes indhold af decahydronaphtalin i 2 prøver. 
The analysis also showed a content of decahydronaphtalin in 2 of the samples.
Der er foretaget kinematisk viskositetsmålinger på udvalgte oliefaser. 
Cinematic viscosity measurements were carried out on selected oils.
Alle karakteriseres som værende af lav viskositet. 
All oils are characterised as being low viscosity oils.
1 Baggrund og formål 
1 Background and objective
Formålet med dette projekt er at undersøge hvilke kemiske stoffer, der findes i varer, indeholdende dekorative væsker, på det danske marked. 
The objective of this project is to investigate which chemical substances exist in products in the Danish market that contain decorative liquids.
Miljøstyrelsen har iværksat denne undersøgelse, som sammen med en række andre projekter skal kortlægge indholdet af kemiske stoffer i forbrugerprodukter. 
The Danish Environmental Protection Agency has implemented this investigation which together with a number of other projects will assess the content of chemical substances in consumer products.
Da der er en risiko for, at disse væsker kan sive ud, og komme i berøring med børn og voksne er det relevant for forbrugerne at få information om, hvilke kemikalier de risikerer at blive eksponeret for. 
There is a risk that these liquids somehow might leak and that children might get into touch with them and therefore it is relevant for consumers to receive information about which chemicals they risk being exposed to.
Til projektet er der undersøgt 16 forskellige produkter indeholdende dekorative væsker. 
16 different products containing decorative liquids have been examined.
• Elleve varer indeholder en klar og en farvet væske. 
♦ Eleven products contain a colourless and a coloured liquid.
• Fire varer indeholder én farvet væske. 
♦ Four products contain one coloured liquid.
• Én lavalampe adskiller sig fra de andre varer ved - udover en vandfase - at 
♦ One product differs from the others as it - beyond an aqueous phase
indeholde en tyktflydende fase. 
also contains a viscous phase.
Alle varer er indkapslet i plastmateriale. 
All products are embedded in plastic material.
Undersøgelsen er alene baseret på kemiske analyser, da forhandlerne ikke var i besiddelse af produktinformationer fra producenter. 
The investigation is solely based on chemical analyses, as the distributors were not in possession of any product information from the manufacturers.
2 Beskrivelse af varer 
2 Description of products
Miljøstyrelsen har indkøbt 16 forskellige varer indeholdende dekorative væsker. 
The Danish Environmental Protection Agency has purchased 16 different products containing decorative liquids.
Tandbørsteholder medto væskefaser, klar-blå. 
Holder for tooth brushes with two liquid phases, clearblue.
Sæbeskål med to væskefaser, klar-blå. 
Soap dish with two liquid phases, clear-blue.
Badeforhæng med én blå væske med lidt glimmer. 
Shower curtain with a blue liquid with a little stardust.
Pairvægt med én klar væske med glimmer. 
Paper weight with one clear liquid with stardust.
Øloplukker med to væskefaser, klar-lyserød. 
Bottle opener with two liquid phases, clear-pink.
Øloplukker med to væskefaser, klar-lyseblå. 
Bottle opener with two liquid phases, clear-light blue.
Øloplukker med to væskefaser, klar-lilla. 
Bottle opener with two liquid phases, clear-lilac.
Øloplukker med to væskefaser, klar-orange. 
Bottle opener with two liquid phases, clear-orange.
Timeglas med to væskefaser, klar-gul/orange. 
Hourglass with two liquid phases, clear-yellow/orange.
Timeglas med to væskefaser, klar-lyserød. 
Hourglass with two liquid phases, clear-pink.
Glas med én farvet væske. 
Glass with a coloured liquid.
Nøglering med to væskefaser; klar-blå. 
Keyring with two liquid phases; clear-blue.
Inden analyse af prøverne udtages væskerne af de forskellige varer. 
Before the products are analysed the liquids are removed from the different products.
Dette gøres ved at bore hul i plastmaterialet. 
That takes place by boring a hole in the plastic material.
Der laves opløselighedsforsøg med dichlormethan for at undersøge hvorvidt værskerne er polære(vandblandbare) eller upolære, før analyserne påbegyndes. 
Solubility tests are carried out with dichloromethane to investigate to which extent the liquids are polar (mixable with water) or non-polar before the analyses are started.
Til kvantitativ og kvalitativ analyse af prøverne er anvendt nedenstående teknikker: 1. 
In order to carry out quantitative and qualitative analyses of the samples, the below techniques have been used: 1.
Identifikation af væskefaserne ved gaschromatografi med flammeionisationsdetektor (1. 
Identification of the liquid phases through gas chromatography with flame ionisation detector (1.
GC-FID) og infrarød spektrometri (2. 
GC-FID) and infrared spectrometry (2.
2. Identifikation og kvantisering af organiske tilsætningsstoffer ved gaschromatografi med massespektrometrisk detektion (3. 
2. Identification and quantification of organic additives through gas chromatography with mass spectrometric detection (3.
3. Identifikation af farvestoffer ved tyndtlagschromatografi (4. 
3. Identification of dyes through thin layer chromatography (4.
TLC) og væskechromatografi (5. 
TLC) and liquid chromatography (5.
EDXRF) og ionchromatografi (7. 
EDXRF) and ion chromatography (7.
IC - DS/EN ISO 10304-2). 
ICDS/EN ISO 10304-2).
5. Bestemmelse af kinematisk viskositet efter ASTM D445. 
5. Determination of cinematic viscosity according to ASTM D445.
3.1 Identifikation af væskefaser ved gaschromatografi med flammeionisationsdetektor (GC-FID) og infrarød spektrometri (IR) 
3.1 Identification of liquid phases through gas chromatography with flame ionisation detector (GC-FID) and infrared spectrometry (IR)
Oliefaserne fortyndes med methylenchlorid tilsat brombenzen og o-terphenyl som interne standarder. 
The oil phases are diluted with methylene chloride to which bromobenzene and o-terphenyl have been added as internal standards.
Den faste fase i prøve 14 opløses i svovlkulstof. 
The fixed phase in sample 14 is dissolved in carbon disulphide.
Fortyndingerne og voksopløsningen analyseres gas-chromatografisk med flammeionisationsdetektor (GC-FID). 
The dilutions and the wax solution are analysed gas chromatographically with flame ionisation detector (GC-FID).
Til analyse af oliefaser anvendes kolonne, temperaturprogram, injektionstype og temperatur mærket med 1 herunder. 
The methods used to analyse the oil phases have in the following been marked with 1.
Til analyse af voksopløsningen anvendes det der er mærket med 2 herunder. 
The methods used to analyse the wax solution have in the following been marked with 2.
Liner med glødet glasuld 
Liner with glowing glass wool
For fastlæggelse af kulbrintesammensætning og kogepunktsinterval medanalyseres kendte mineralolieprodukter samt kulbrintestandardrækker fra C8H18 til C35H72 og C20H42 til C44H90. 
In order to determine the hydrocarbon composition and the boiling point interval, known mineral oil products and hydrocarbon standard series from C8H18 to C35H72 and C20H42 to C44H90 are analysed.
Vandfaserne identificeres ved fourier transform infrarød spektrometri under anvendelse af kaliumbromidteknik. 
The water phases are identified through fourier transform infrared spectrometry by using potassium bromide technology.
Et tyndt lag af væsken afsættes på en kaliumbromidtablet, og der optages IR-spektrum på et Perkin Elmer 1720x FT-IR spectrometer. 
A thin layer of the liquid is placed on a potassium bromide tablet and IR spectrum is taken on a Perkin Elmer 1720x FT-IR spectrometer.
I bilag B ses eksempler på IR-spektre af en vandfase og en mineralsk oliefase. 
Examples of the IR spectra of a water phase and a mineral oil phase appear from enclosure B.
3.2 Identifikation og kvantisering af organiske tilsætningstoffer ved Gaschromatografi med massespektrometrisk detektion, GC-MS 
3.2 Identification and quantification of organic additives through gas chromatography with mass spectrometric detection, GC-MS
Oliefaserne fortyndes med methylenchlorid tilsat brombenzen og o-terphenyl som interne standarder. 
The oil phases are diluted with methylene chloride to which bromobenzene and o-terphynyl have been added as internal standards.
Vandfaserne ekstraheres med methylenchlorid tilsat samme interne standarder. 
The water phases are extracted with methylene chloride to which the same internal standards have been added.
Fortyndingerne og ekstrakter analyseres gaschromatografisk med massespektrometrisk detektion. 
The dilutions and extracts are analysed gas chromatographically with mass spectrometric detection.
Til identifikation af enkeltkomponter anvendes MS NIST98 biblioteksøgning. 
In order to identify individual components MS NIST98 library search is applied.
Indholdet af bakteriedræbende stoffer bestemmes semikvantitativt overfor intern standard, brombenzen, da det ikke var muligt at fremskaffe referencestofferne. 
The content of bactericidal substances is determined semi-quantitatively against the internal standard, bromobenzene, as it was not possible to obtain the reference standards.
Brombenzen anvendes rutinemæssigt som intern standard i det kogepunktsområde hvori de bakteriedræbende stoffer ligger. 
Bromobenzene is used routinely as internal standard in the boiling point area in which the bactericidal substances are situated.
Indholdet af phthalater bestemmes kvantitativt overfor eksterne standarder. 
The content of phthalates is determined quantitatively against external standards.
I Tabel 2 er detektionsgrænser angivet. 
In table 2, the detection limits are stated.
Tabel 2 Detektionsgrænser Parametre 
Table 2: Detection limits Parameters
Til endelig identifikation anvendes HPLC med UV diodearray detektor, hvor der medtages en række reference levnedsmiddelfarver. 
For final identification HPLC is used with UV diode array detector and a number of reference colours used within the food industry are included.
Chromatogrammer optages både ved scan og ved udvalgte bølgelængder: 254 nm, 430 nm, 520 nm og 640 nm, se Tabel 3. 
Chromatograms are taken by means of screening and at selected wave lengths: 254 nm, 430 nm, 520 nm and 640 nm, see table 3.
Prøverne 'vaskes' med hexan for at fjerne eventuelle olierester, inddampes til tørhed og reopløses i mobilfase. 
The samples are "washed" with hexane to remove possible oil residues, they are evaporated to dryness and decomposed once again in mobile phase.
Prøver, der ikke kan inddampes, køres direkte på HPLC. 
Samples that cannot be evaporated are analysed directly on HPLC.
Til identifikation af farvestoffer sammenlignes med referencefarvestoffer og tabel i /1/. 
In order to identify dyes they are compared with reference dyes and the table in ref (1).
I bilag C ses eksempler på UV-kurver. 
Enclosure C gives examples of UV curves.
/2/ er anvendt som opslagsværk over farvestoffer. 
Ref (2) is used as reference of colours.
Tabel 3 Bølgelængder og farver Bølgelængder i nm 
Table 3: Wave lengths and colours
3.4 Identifikation og kvantificering af uorganiske tilsætnings stoffer ved røntgenfluorescens spektrometri (edxrf) og ion 
3.4 Identification and quantification of inorganic additives through X-ray fluorescence spectrometry (edxrf) and ion chromatography (IC)
Væsker er overført til Somar Cups med mylarfolie og analyseret på PV9100 spectrometer, med helium i prøvekammer. 
Liquids are transferred to Somar Cups with mylar foil and analysed on a PV9100 spectrometer with helium in the test chamber.
Med denne teknik kan prøverne screenes for grundstoffer fra med atomnummer Z=14 Silicium. 
Through this technique the samples can be screened for elements on and after atomic number 14 (silicium).
Lettere grundstoffer ses ikke ved denne teknik. 
Lighter elements do not appear with this technology.
Bundfald, glimmer m.m. er filtreret fra, udvasket for olie og analyseret under vakuum. 
Precipitates, stardust etc. have been filtered off, washed out for oil and analysed under vacuum.
Resultater angives i m 
The results are stated in m
I dette afsnit gennemgås resultater af: Identifikation af væsker og farvestoffer v. IR, GC-FID, HPLC og TLC, bestemmelse af tilsætningsstoffer v. GC-MS, EDXRF og IC, kinematisk viskositetsmålinger. 
In this chapter the following results are studied: Identification of liquids and dyes by means of IR, GC-FID, HPLC and TLC, determination of additives by means of GC-MS, EDXRF and IC and cinematic viscosity measurements
4.1 Identifikation af væsker og farvestoffer 
4.1 Identification of liquids and dyes
Væskerne er identificeret som vand og mineralske olier bestående af kulbrinter i intervallet C8H18-C26H54, svarende til kogepunktsinterval 126ºC-412ºC. 
The liquids have been identified as water and mineral oils consisting of hydrocarbons in the interval of C8H18-C26H54, corresponding to the boiling point interval of 126ºC-412ºC.
Det faste stof i prøve 14, er identificeret som voks, bestående af kulbrinter C20H42-C44H90,, svarende til kogepunktsinterval 343ºC-548ºC. 
The solid substance in sample 14, has been identified as wax consisting of hydrocarbons C20H42-C44H90,, corresponding to the boiling point interval of 343ºC-548ºC.
Analyseresultater fremgår af Tabel 4. 
The analysis results appear from table 4.
I bilag D ses en liste med CAS-numre på identificerede kulbrinter. 
In enclosure D there is a list with CAS numbers on identified hydrocarbons.
I bilag A, ses udvalgte chromatogrammer til illustration af oliernes forskellige sammensætning af kulbrinter. 
In enclosure A, selected chromatograms are shown to illustrate the different composition of hydrocarbons in oil.
Farvestofferne er identificeret som triarylmethan farvestof (patentblå VF) og monoazo farvestoffer (sunset yellow, tartrazin, ponceau 4R, red 2G og acid red 33) 
The dyes have been identified as triarylmethane dye (patent blue VF) and monoazo dyes (sunset yellow, tartrazin, ponceau 4R, red 2G and acid red 33).
Tabel 4 Kulbrinteinterval og farvestoffer 
Table 4: Hydrocarbon interval and dyes
Vandfase CI nr. 
Water phase CI no.
Patentblå VF 42045 (blå) Blå 
Patent blue VF 42045 (blue) Blue
Farvestof ikke identificeret 
Dye not identified
Patentblå VF Tartrazin 
Patent blue VF Tartrazin
Patentblå VF 42045 (blå) Lyseblå 
Patent blue VF 42045 (blue) Light blue
Patentblå VF + formentlig Red 2G 
Patent blue VF + presumably Red 2G
Patentblå VF 42045 (blå) Orange 
Patent blue VF 42045 (blue) Orange
Denne prøve indeholder en fast rød voksfase og en blå vandfase 
This sample contains a solid red wax phase and a blue water phase.
Identifikationen er foretaget ved sammenligning af UV-spetret med absorptionsmaxima i tabel i ref 1, s.19, og ikke ved sammenligning med referencefarvestof. 
Identification was carried out by comparing the UV spectrum with absorption maxima in the table in ref. 1, page 19, and not by comparison with reference dye.
Identifikationen alene er foretaget ved sammenligning af retentionstid for referencestof og blåt farvestof i prøve. 
Identification is solely carried out by comparing the retention time of the reference dye and blue dye in sample.
UV-spektret for det blå farvestof i prøven kunne ikke optages pga. for lille signal. 
The UV spectrum of the blue dye in the sample could not be absorbed as the signal was too small.
I enkelte prøver er der i vandfaserne konstateret tilsætningsstoffer som salte, bakteriedræbende stoffer og phthalater, bis(2-ethylhexyl)phthalat (DEHP) og dibutyl phthalat (DBP). 
In some tests additives such as salts, bactericidal substances and phthalates, bis(2-ethylhexyl)phthalate (DEHP) and dibutyl phthalate (DBP) were demonstrated in the water phase.
Det kan ikke udelukkes, at phthalaterne stammer fra plastmaterialet. 
It cannot be ruled out that the phthalates originate from the plastic material.
Salte er sandsynligvis tilsat for at få massefylden ændret, så genstandene kan flyde. 
Salts have probably been added in order to change the density so the items can float.
I Tabel 5 er resultaterne samlet. 
In table 5, all the results have been collected.
Detektionsgrænser er angivet i Tabel 2. 
The detection limits are stated in table 2.
Tabel 5 Tilsætningsstoffer Produktnummer 
Table 5: Additives Sample number DEHP
DEHP stammer sandsynligvis fra plastmaterialet, der er blød plast, sandsynligvis blød PVC, som omgiver væsken. 
The content of DEHP is probably from the plastic material, which is soft plastic and probably soft PVC.
Det kan ikke umiddelbart forklares, hvorfor der er tilsat salte til prøve 9 og 10. 
However, it cannot immediately be explained why salt has been added to sample 9 and 10.
I Tabel 6 ses en liste over stoffer, der er fundet kvalitativt ved GC-MS screeningen. 
In table 6, there is a list of the substances that have been found qualitatively through the GC-MS screening.
Identifikationen er alene foretaget ved sammenligning med MS Nist-reference bibliotek og der kan derfor være tale om isomere forbindelser. 
Identification has solely been carried out by comparing with the MS Nist reference library and therefore isomeric combinations might be in question.
Tabel 6 Liste over indholdsstoffer der er bestemt kvalitativt ved GC/MS screening. 
Table 6: List of contents determined qualitatively through GC-MS screening.
Cyclohexanon Cyclohexanol 2-Butoxyethanol 
Cyclohexanone Cyclohexanol 2-Butoxyethanol
Butanol Methyl benzen sulfonamid 
Butanol Methyl benzen sulphonamides
Trans+cis, decahydronaphthalen * 
Trans+cis, decahydronaphthalene *