natgillin/translations-raw huggingface dataset:
Koncentrationen bestemmes ved analyse under hensyntagen til resultaterne af blindprøverne
This concentration is analytically determined taking into account the values given by the blanks;
masse af stof adsorberet på jorden ved adsorptionsligevægt (µg)
mass of the substance adsorbed on the soil at adsorption equilibrium (μg);
masse af stof i opløsningen ved adsorptionsligevægt (µg)
mass of the substance in the solution at adsorption equilibrium (μg);
mængde jordfase, angive; som tor masse af jord (g)
quantity of the soil phase, expressed in dry mass of soil (g);
begyndelsesrumfang af vandig fase i kontakt med jorden (cm3).
initial volume of the aqueous phase in contact with the soil (cm3).
Forholdet mellem Aeq og Kd er givet ved;
The relation between Aeq and Kd is given by:
adsorptionsprocent ved adsorptionsligevægt, %.
percentage of adsorption at adsorption equilibrium, %.
Den normaliserede adsorptionskoefficient for organisk kulstof Koc angiver sammenhængen mellem fordelingskoefficienten Kd og jordprøvens organiske kulstofindhold:
The organic carbon normalised adsorption coefficient Koc relates the distribution coefficient Kd to the content of organic carbon of the soil sample:
% oc procentdel organisk kulstof i jordprøven (g g-1).
%OC percentage of organic carbon in the soil sample (g g-1).
Koc-koefficienten angiver ved én enkelt værdi fordelingen af hovedsagelig ikke-polære organiske stoffer mellem organisk kulstof i jord eller slam og vand.
Koc coefficient represents a single value which characterises the partitioning mainly of non-polar organic chemicals between organic carbon in the soil or sediment and water.
Adsorptionen af sådanne kemiske stoffer er korreleret med det organiske indhold af det sorberende faste stof (7); således afhænger Koc-værdierae af de særlige karakteristika af humusfraktionerne, hvis sorptionsevne afviger betydeligt som følge af forskelle i oprindelse, tilblivelse osv.
The adsorption of these chemicals is correlated with the organic content of the sorbing solid (7); thus, Koc values depend on the specific characteristics of the humic fractions which differ considerably in sorption capacity, due to differences in origin, genesis, etc.
Freundlich-adsorptionsisotermligningen giver sammenhængen mellem den adsorberede mængde prøvestof og koncentrationen af opløst prøvestof ved ligevægt (ligning 8).
The Freundlich adsorption isotherms equation relates the amount of the test substance adsorbed to the concentration of the test substance in solution at equilibrium (equation 8).
Data behandles som angivet under »Adsorption«, og for hvert prøveglas beregnes indholdet af prøvestof adsorberet på jorden efter adsorptionstestenCs
The data are treated as under ‘Adsorption’ and, for each test tube, the content of the test substance adsorbed on the soil after the adsorption test (Cs
(andetsteds betegnet x/m).
, elsewhere denoted as x/m) is calculated.
Det antages, at der er indtrådt ligevægt, og at Cs
It is assumed that equilibrium has been attained and that Cs
udtrykker ligevægtsværdien:
represents the equilibrium value:
Freundlich-adsorptionsligningen er vist i (8):
The Freundlich adsorption equation is shown in (8):
eller, på lineær form:
or in the linear form:
Freundlich-adsorptionskoefficient; den har kun dimensionen cm3 g-1, såfremt l/n = 1: i alle andre tilfælde indføres hældningen l/n i dimensionen af KF
Freundlich adsorption coefficient; its dimension is cm3 g-1 only if 1/n = 1; in all other cases, the slope 1/n is introduced in the dimension of KF
(μg1-1/n (cm31/n g-1)
(μg1-1/n (cm3)1/n g-1);
n regressionskonstant; l/n ligger sædvanligvis i intervallet 0,7-1,0, hvilket viser, at sorptionsdata ofte er let ulineære.
n regression constant; 1/n generally ranges between 0,7-1,0 indicating that sorption data is frequently slightly non-linear.
Ligning 8 og 9 afsættes, og værdierne afKF
Equations (8) and (9) are plotted and the values of KF
og l/n beregnes ved regressionsanalyse ved anvendelse af ligning 9.
and 1/n are calculated by regression analysis using the equation 9.
Korrelationskoefficienten r2 for den logaritmiske ligning beregnes ligeledes.
The correlation coefficient r2 of the log equation is also calculated.
Et eksempel på sådanne afbildninger er givet i figur 2.
An example of such plots is given in Fig. 2.
Fig. 2. Freundlich adsoprtionskurve, normal og lineariseret.
Fig. 2 Freundlich Adsorption Plot, normal and linearised
Massebalance
Mass balance
Massebalancen (MB) defineres som den procentdel af den nominelle mængde stof ved testens begyndelse, som kan genfindes analytisk efter en adsorptionstest.
The mass balance (MB) is defined as the percentage of substance which can be analytically recovered after an adsorption test versus the nominal amount of substance at the beginning of the test.
Behandlingen af data vil afvige, hvis det opløste stof er fuldstændig blandbart med vand.
The treatment of data will differ if the solvent is completely miscible with water.
For opløsningsmidler blandbare med vand kan man ved at behandle data som beskrevet under »Desorption« bestemme den mængde stof, som genfindes ved ekstraktion med opløsningsmiddel.
In the case of water-miscible solvent, the treatment of data described under ‘Desorption’ may be applied to determine the amount of substance recovered by solvent extraction.
Er opløsningsmidlet mindre blandbart med vand, må den genfundne mængde bestemmes.
If the solvent is less miscible with water, the determination of the amount recovered has to be made.
Beregning af massebalancen MB for adsorption: leddet (mE) antages at svare til den samlede masse prøvestof ekstraheret af jorden og fra prøveglassets overflade med organisk opløsningsmiddel:
The mass balance MB for the adsorption is calculated as follows; it is assumed that the term (mE) corresponds to the sum of the test chemical masses extracted from the soil and surface of the test vessel with an organic solvent:
MB massebalance ( %)
MB mass balance (%);
samlet masse prøvestof ekstraheret fra jord og prøveglassets vægge i to trin (μg)
total mass of test substance extracted from the soil and walls of the test vessel in two steps (μg);
initial massekoncentration af prøveopløsning i berøring med jorden (ug cm-3)
initial mass concentration of the test solution in contact with the soil (μg cm-3);
rumfang supernatant, som er opsamlet efter indtræden af adsorptionsligevægt (cm-3).
volume of the supernatant recovered after the adsorption equilibrium (cm-3).
Desorptionen (D) defineres som den procentdel af den tidligere adsorberede stofmængde, som desorberes under forsøgsbetingelserne:
The desorption (D) is defined as the percentage of the test substance which is desorbed, related to the quantity of substance previously adsorbed, under the test conditions:
desorptionsprocent til tidspunktet ti ( %)
desorption percentage at a time point ti(%);
masse af prøvestof desorberet fra jorden til tiden ti (μg)
mass of the test substance desorbed from soil at a time point ti (μg);
masse af prøvestof adsorberet til jorden ved adsorptionsligevægt (μg).
mass of the test substance adsorbed on soil at adsorption equilibrium (μg).
Udførlige oplysninger om, hvordan desorptionsprocenten Dti
Detailed information on how to calculate the percentage of desorption Dti
Den tilsyneladende desorptionskoefficient (Kdes) er forholdet mellem indholdet af resterende stof i jordfasen og massekoncentrationen af desorberet stof i den vandige opløsning under testbetingelserne efter indtræden af desorptionsligevægt:
The apparent desorption coefficient (Kdes) is, under the test conditions, the ratio between the content of the substance remaining in the soil phase and the mass concentration of the desorbed substance in the aqueous solution, when desorption equilibrium is reached:
desorptionskoefficient (cm3 g-1)
desorption coefficient (cm3 g-1);
samlet masse af prøvestof desorberet fra jorden ved desorptionsligevægt (μg)
total mass of the test substance desorbed from soil at desorption equilibrium (μg);
samlet masse af vandig fase i kontakt med jorden under desorptionskinetikforsøget (cm3).
total volume of the aqueous phase in contact with the soil during the desorption kinetics test (cm3).
Vejledning tor beregning afmaq
Guidance for calculating the maq
(eq) findes i tillæg 5 under overskriften »Desorption«.
is given in Appendix 5 under the heading ‘Desorption’.
Bemærkning:
Remark
Hvis den efterfølgende adsorptionstest blev udført med den parallelle metode, sættes rumfanget VT i ligning 12 lig V0.
If the adsorption test which was preceded, was performed with the parallel method the volume VT in the equation (12) is considered to be equal to V0.
Freundlich-ligningen for adsorptionsisotermer udtrykker sammenhængen mellem den mængde prøvestof, som stadig er absorberet på jorden, og koncentrationen af prøvestof ved desorptionsligevægt (ligning 16).
The Freundlich desorption isotherms equation relates the content of the test substance remaining adsorbed on the soil to the concentration of the test substance in solution at desorption equilibrium (equation 16).
For hvert prøveglas beregnes indholdet af prøvestof, som stadig er adsorberet til jorden ved desorptionsligevægt, på følgende måde:
For each test tube, the content of the substance remaining adsorbed on soil at desorption equilibrium is calculated as follows:
indhold af prøvestof, som ved desorptionsligevægt stadig er adsorberet til jorden (μg g-1)
content of the test substance remaining adsorbed on the soil at desorption equilibrium (μg g-1);
masse af stof, som er bestemt analytisk i den vandige fase ved desorptionsligevægt (μg)
mass of substance determined analytically in the aqueous phase at desorption equilibrium (μg);
masse af prøvestof, som på grund af ufuldstændig volumenudskiftning er tilbage efter indtræden af adsorptionsligevægtt (μg)
mass of the test substance left over from the adsorption equilibrium due to incomplete volume replacement (μg);
rumfang opløsning, som ved desorptionsligevægt er udtaget af prøveglasset med henblik på bestemmelse af prøvestof (cm3)
volume of the solution taken from the tube for the measurement of the test substance, at desorption equilibrium (cm3);
rumfang supernatant, som efter opnåelse af adsorptionsligevægt er fjernet fra prøveglasset og erstattet af samme rumfang 0,01 M CaCl2-opløsning (cm3).
volume of the supernatant removed from the tube after the attainment of adsorption equilibrium and replaced by the same volume of a 0,01 M CaCl2 solution (cm3);
Freundlich-desorptionsligningen er vist i (16):
The Freundlich desorption equation is shown in (16):
Freundlich-desorptionskoefficient
Freundlich desorption coefficient;
n regressionskonstant
n regression constant;
= massekoncentration af stof i vandig fase ved desorptionsligevægt (μg cm-3).
mass concentration of the substance in the aqueous phase at desorption equilibrium (μg cm-3).
Ligningerne 16 og 17 kan afsættes grafisk, og værdien af KF
The equations (16) and (17) can be plotted and the value of KF
og l/n beregnes ved regressionsanalyse ved anvendelse af ligning 17.
and 1/n are calculated by regression analysis using the equation 17.
Hvis Freundlich-adsorptions- eller desorptionseksponenten l/n er lig 1, vil Freundlich-bindingskonstanten for adsorption eller desorption (KF
if the Freundlich adsorption or desorption exponent 1/n is equal to 1, the Freundlich adsorption or desorption binding constant (KF
ogKF
and KF
være lig ligevægtskonstanterne (Kd og Kdes) for henholdsvis adsorption og desorption, og ved afbildning af Cs mod Caq fås en ret linje.
will be equal to the adsorption or desorption equilibrium constants (Kd and Kdes) respectively, and plots of Cs vs Caq will be linear.
Er eksponenterne forskellige fra 1, bliver en afbildning af Cs som funktion af Caq ulineær, og adsorptions- og desorptionskonstanterne vil ændre sig langs isotermerne.
If the exponents are not equal to 1, plots of Cs vs Caq will be non-linear and the adsorption and desorption constants will vary along the isotherms.
fuldstændig identifikation af de anvendte jordprøver, med angivelse af:
complete identification of the soil samples used including,
stedsbestemmelse for lokaliteten (bredde og længde)
geographical reference of the site (latitude, longitude),
prøveindsamlingsdato
date of sampling,
anvendelsesmønster (f.eks. landbrugsjord, skov osv.)
use pattern (e.g. agricultural soil, forest, etc.),
dybde af prøvetagning
depth of sampling,
sand-/silt-/lerindhold
sand/silt/clay content;
pH-værdi (i 0,01 M CaCl2)
pH values (in 0,01 M CaCl2),
organisk kulstofindhold
organic carbon content,
indhold af organisk stof
organic matter content,
kvælstofindhold
nitrogen content,
C/N-forhold
C/N ratio,
kationbytningskapacitet (mmol/kg)
cation Exchange Capacity (mmol/kg),
udtømmende oplysninger om indsamling og opbevaring af jordprøver
all information relating to the collection and storage of soil samples,
når det er hensigtsmæssigt, alle relevante oplysninger til fortolkning af prøvestoffets adsorption/desorption
where appropriate, all relevant information for the interpretation of the adsorption — desorption of the test substance,
henvisninger, som angiver de metoder, der er anvendt til bestemmelse af hver parameter
reference of the methods used for the determination of each parameter,
oplysninger om prøvestoffet, hvis det er hensigtsmæssigt
information on the test substance as appropriate,
forsøgstemperaturen
temperature of the experiments,
centrifugeringsbetingelser
centrifugation conditions,
analysemetode anvendt til analyse af prøvestoffet
analytical procedure used to analyse the test substance,
begrundelse af enhver brug af opløsningsmiddel til fremstilling af stamopløsningen af prøvestoffet
justification for any use of solubilising agent for the preparation of the stock solution of the test substance,
forklaring af eventuelle korrektioner foretaget i beregningerne
explanations of corrections made in the calculations, if relevant,
data i henhold til formularbladet (tillæg 6) og grafiske fremstillinger
data according to the form sheet (Appendix 6) and graphical presentations,
alle oplysninger og bemærkninger, som kan være til hjælp ved fortolkning af testresultaterne.
all information and observations helpful for the interpretation of the test results.
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