natgillin/translations-raw huggingface dataset:
Acrylater består af acrylsyre og methaacrylsyre samt deres methyl-, ethyl- og butylestre /4/.
Acrylates consist of acrylic acid and meta acrylic acid and their methyl, ethyl and butyl esters /4/.
I Tabel 4.2 er vist hvilke bindemidler og restmomomerer som ifølge kortlægningen kan findes i vinduesfarver.
Table 4.2 shows which paint binders and residual monomers may be found in window colours according to the survey.
Desuden er de fareklasser stofferne er indplaceret i samt stoffernes klassificering fra Listen over farlige stoffer vist.
In addition, the table shows the hazard classes in which the products are placed and their classification on the List of Dangerous Substances.
Tabel 4.2 Bindemidler og restmonomerer i vinduesfarver og tilhørende fysisk-kemiske egenskaber (data fra 11, 14 og 23) og klassificering.
Table 4.2 Paint Binders and residual monomers in window colours and their physicochemical properties (data from 11, 14 and 23) and classification.
- angiver at værdien er ukendt.
Name of substance (formula)
Ethylacrylat-methacrylsyre polymer
Ethylacrylate-methacrylic acid polymer
Methylmethacrylat (C5H8O2)
Methylmethacrylate (C5H8O2)
MW= molekylvægt; S = opløselighed i vand;
MW= Molecular Weight; S = Solubility in water;
Alle de fundne vinduesfarver er vandbaserede, hvilket med andre ord vil sige at bæremidlet er vand.
All the window colours encountered were water-based, i.e. their medium is water.
Derudover kan produkterne indeholde mindre mængder opløsningsmiddel.
In addition, the products may contain small amounts of solvent.
Ifølge den indhentede information findes en række tilsætningsstoffer i vinduesfarverne.
According to the information gathered, window colours contain a number of additives.
I Tabel 4.3 ses en oversigt over tilsætningsstoffer, som anvendes i vinduesfarver, udvalgte fysisk-kemiske egenskaber samt de fareklasser stofferne er indplaceret i og stoffernes klassificering fra Listen over farlige stoffer.
Table 4.3 shows a list of the additives used in window colours, selected physico-chemical properties and the hazard classes in which the substances are placed and the classification of substances from the List of Dangerous Substances.
Tabel 4.3 Tilsætningsstoffer i vinduesfarver og tilhørende fysisk-kemiske egenskaber (data fra 11, 14 og 23), samt deres klassificering (28, 33).
Table 4.3 Additives in window colours and their physico-chemical properties (data from 11, 14 and 23), and their classification (28, 33).
- angiver at værdien er ukendt.
- indicates that value is unknown.
Ammoniak (H5NO)
Ammonia (H5NO)
Dipropylenglycolmethylether (C7H16O3)
Dipropyleneglycolmethylethe r (C7H16O3)
> 100 -1,36 Sundhedsskadelig Xn;R22
> 100 -1.36 Harmful to health Xn;R22
Formaldehyd (CH2O)
Formaldehyde (CH2O)
Kræftfremkaldende, giftig, ætsende, sensibiliserende
Carcinogenic, toxic, corrosive, sensitizing
2-Methyl-4-isothiazol-3-on (C4H5NOS)
2-Methyl-4-isothiazol-3-one (C4H5NOS)
Sundhedsskadelig, lokalirriterende, miljøfarlig
Harmful to health, Local irritant, Dangerous to the environment
Polypropylenglycol Propylen glycol (C3H8O2)
Polypropylener glycol Propylene glycol (C3H8O2)
Triethanolamin (C6H15NO3)
Triethanolamine (C6H15NO3)
1) Klassificering fra Listen over farlige stoffer eller fra den vejledende liste til selvklassificering (italic).
1) Classification from the List of Dangerous Substances or from the guideline list for selfclassification (in italics).
I forbindelse med kortlægningen fremkom oplysninger om naphthol med Cas nr. 1321-67-1.
During the survey information was found on naphthol with Cas no. 1321-671.
De to isothiazolinonderivater indgår begge i lav koncentration i vinduesfarverne og findes under bagatelgrænsen i følge sikkerhedsdatabladene for de undersøgte produkter.
The two isothiazolinone derivatives are both contained by window colours in low concentrations which lie below the de minimis limit according to the safety data sheets for the investigated products.
Stofferne forekommer også i f.eks. kosmetikprodukter, hvor den tilladte grænse er 0,0015%.
The substances also occur e.g. in cosmetics products, where the permitted limit is 0.0015%.
Ti vinduesfarver blev analyseret for deres indhold af kemiske stoffer.
The window colours were analysed for their content of chemical substances.
Tabel 5.1 angiver produkternes farver.
Table 5.1 lists the products' colours.
Tabel 5.1 testprodukter udvalgt til kvalitativ analyse.
Table 5.1 test products selected for qualitative analysis.
En delprøve af ekstraktet udtages og analyseres direkte samt opkoncentreret ved kombineret gaskromatografi og massespektrometri (GC/MS), ved at scanne over et større masseområde.
A part sample of the extract was removed and analysed directly and concentrated by combined gas chromatography and mass spectrometry (GC/MS) by scanning over a larger mass area.
Indholdet beregnes overfor relevante eksterne standarder (angivet med * i tabellen under ”Analyseresultater”) eller interne standarder (øvrige ekstraherbare stoffer).
The contents were analysed compared to relevant external standards (indicated with an * in the Analysis Results) or internal standards (other extractable substances).
For de komponenter, der er beregnet overfor intern standard, er kvantificeringen semikvantitativ svarende til en større usikkerhed (anslået 50-200%).
Quantification of the components calculated compared to internal standards is semi-quantitative, thus implying greater uncertainty (estimated 50-200%).
For kvantificering overfor eksterne standarder er usikkerheden anslået til 10-20%.
In the case of quantification compared to external standards uncertainty was estimated at 10-20%
Analyserne udføres som ægte dobbeltbestemmelser.
The analysis were carried out as true double determinations.
Detektionsgrænsen er 1-5 mg/kg for de komponenter, der er semikvantificeret og 1 mg/kg for de komponenter, hvor der er medtaget ekstern standard.
The detection limit was 1-5 mg/kg for the components that are semi-quantified and 1 mg/kg for the components where external standards were included.
En delprøve undersøges ved røntgen-teknik for indhold af 40 grundstoffer.
A part sample was subject to X-ray analysis for the content of 40 elements.
Analyserne er udført som ægte dobbeltbestemmelser.
The analysis were carried out as true double determinations.
Detektionsgrænsen er 10 mg/kg. Analyseusikkerheden er 5-10% RSD.
The detection limit was 10 mg/kg. Analysis uncertainty was 5-10% RSD.
Usikkerheden på analysen er 10% RSD.
Analysis uncertainty was 10% RSD.
Af prøven udtages en delprøve, hvoraf der presses en kaliumbromid tablet, der analyseres ved FT-IR analyse, hvorved prøvens indhold af organiske hovedbestanddele bestemmes ved sammenligning med databiblioteksspektre.
A part sample was removed from the sample which was pressed into a potassium bromide tablet and subject to FT-IR analysis to determine the main organic contents of the sample by comparison with data library spectra.
Analysen vil ikke blive afrapporteret særskilt.
This analysis will not be reported on separately.
Resultatet af screeningerne er brugt som understøttelse af resultatet af GC/MS screeningen.
The results of the screening were used to underpin the results of the GC/MS screening.
I Tabel 5.2 og Tabel 5.3 følger resultaterne for GC/MS screeningen.
Table 5.2 and Table 5.3 shows the results of the GC/MS screening.
De to resultater angiver dobbeltbestemmelserne.
The two results refer to double determinations.
Alle identifikationer af stoffer er foretaget ud fra massespektret ved sammenligning med massespektre i et databibliotek.
All identification of substances was made based on the mass spectrum through comparison with mass spectra in the data library.
Spektre, der repræsenterer det bedste match, er i hvert enkelt tilfælde vurderet ved ”scientific judgement”.
The spectra giving the closest match were assessed using scientific judgement in each case.
I de tilfælde hvor identifikation ikke er mulig, indgår komponenterne i en gruppebetegnelse med en samlet sum eller er angivet med et stofnavn i parentes, hvor stofnavnet er det mest sikre estimat.
Where identification is not possible the components are designated by group as a total amount or specified with a substance name in parentheses, this name being the most viable estimate of what the substance might be.
Detektionsgrænsen er 1-5 mg/kg.
The detection limit was 1-5 mg/kg.
Efter ønske fra Miljøstyrelsen er der medtaget standarder udvalgt ud fra resultaterne af kortlægningen for enkelte komponenter.
In conformity with the wishes of the Danish EPA, standards have been selected based on the results of the survey of individual components.
Disse komponenter er derfor beregnet overfor standarderne.
These components have therefore been calculated against the standards.
For alle øvrige organiske komponenter er der foretaget en semikvantitativ beregning overfor intern standard.
Semiquantitative calculations against internal standards were made for all other organic components.
De komponenter der er beregnet overfor ekstern standard er angivet med * i tabellen.
The components calculated against external standards are indicated with * in the table.
Detektionsgrænsen for komponenter beregnet overfor ekstern standard er 1 mg/kg.
The detection limit for components calculated against external standards is 1 mg/kg.
For enkelte komponenter var indholdet så stort, at det var nødvendigt at fortynde prøven for at beregne indholdet korrekt.
For certain components the content was so great that it was necessary to dilute the sample in order to calculate the content correctly.
Disse komponenter er angivet med ^ i tabellen.
These components are marked with an ^ in the table.
Tabel 5.2 Resultater for analyser for ekstraherbare stoffer i V1-V5.
Table 5.2 Results of analysis for extractable substances in V1-V5.
De to resultater angiver dobbeltbestemmelserne.
The two results refer to the double determinations.
Resultaterne er angivet i mg/kg. Detektionsgrænsen er angivet i ovenstående tekst.
Results are given in mg/kg. The detection limit is stated above.
Uid. phthalater (sum af to toppe)
Unidentified phthalates (sum of two peaks)
Benzophenon Dodecanthiol* Dodecylmethyl sulfid Thiabendazol
Benzophenone Dodecanthiol* Dodecylmethyl sulfid Thiabendazole
Øvrige uidentificerede -: betyder mindre end detektionsgrænsen ( ): betyder at identifikation ikke er mulig; stofnavnet det mest sikre estimat *: betyder kvantificeret overfor ekstern standard ^:betyder kvantificeret ved fortyndet prøve
Other unidentified -: lower than detection limit ( ): identification not possible; name of substance the most viable estimate *: quantified against external standards ^:quantified using diluted sample
Dimethyloxazolidin Butylether (Hexylen glycol) 2,2-oxydiethanol* Hexanol
Dimethyloxazolidine Butylether (Hexylen glycol) 2,2-oxydiethanol* Hexanol
Chloralkaner (to toppe)
Chloralkanes (two peaks)
Methyl-benzensulfonamid (sum af to toppe)*
Methyl-benzensulfonamid (sum of two peaks)*
(Methenamin) Hydroxybiphenyl Uid. phthalater (sum af to toppe) (Dibutylphthalat) DEHP
(Methenamine) Hydroxybiphenyl Unidentified phthalates (sum of two peaks) (Dibutylphthalate) DEHP
Uid. alkaner, alkener, alkoholer, cycloalkaner/alkener
Unidentified alkanes, alkenes, alkoholes, cycloalkanes/- alkenes
Uid. carboxylsyrer, estre, ketoner, aldehyder og amider
Unidentified carboxylicacids, esters, ketones, aldehydes and amides
Uid. glycoler og oxyforbindelser
Unidentified glycoles and oxycompounds
Uidentificerede aromatiske forbindelser
Unidentified aromatic compounds
I Tabel 5.4 følger resultaterne for røntgenanalyserne.
Table 5.4 shows the results of the X-ray analysis.
De grundstoffer der ikke er anført i tabellen, blev ikke detekteret ved analysen.
The elements not listed in the table were not detected by the analysis.
Analysen er foretaget i enkeltbestemmelse pga. sikkerheden af analysen.
Only single determination analysis were made due to the precision of the analysis.
Detektionsgrænsen er 10 mg/kg.
The detection limit is 10 mg/kg.
Resultater for røntgenanalyser.
Results of X-ray analysis.
Resultaterne er angivet i mg/kg. V1 V2 V3
Results are given in mg/kg. V1 V2 V3
Bly Brom 320 150-: betyder mindre end detektionsgrænsen *: detektionsgrænsen hævet til 50 mg/kg
320 150-: lower than detection limit ( ): detection limit increased to 50 mg/kg
Neden for ses resultaterne for analyserne for vandindhold.
The tables below show the results of the analysis for water content.
De to værdier angiver dobbeltbestemmelserne.
The two results refer to the double determinations.
Resultaterne er angivet i %.
Results are given in %.
Niveauerne i de forskellige produkter er fra 2,3 til 5500 mg/kg svarende til 0,00023% til 0,55% i produkterne.
The levels contained in the various products vary between 2.3 and 5500 mg/kg, equivalent to 0.00023% to 0.55% in the products.
Øvrige stoffer er fundet i koncentrationer fra ca. 1 mg/kg (0,0001%) og op til ca. 1000 mg/kg (0,1%), flest i den lave ende.
Other substances were found in concentrations from approx. 1 mg/kg (0.0001%) and up to approx. 1000 mg/kg (0.1%), mostly at the lower end.
Det gælder også de stoffer, som er udvalgt til toksikologisk vurdering på baggrund af de kemiske analyser.
This was also the case with products selected for toxicological assessment based on the chemical analysis.
Det drejer sig om stofferne vist i Tabel 5.7.
The substances concerned are those shown in Table 5.7.
Blandt metallerne er der fundet bly, kobber, aluminium og titanium.
Among the metals found were lead, copper, aluminium and titanium.
Bly er fundet i to produkter i koncentrationer på henholdsvis 12 og 17 mg/kg svarende til 0,0012 og 0,0017% i produkterne.
Lead was detected in two products in concentrations of 12 and 17 mg/kg, respectively, equivalent to 0.0012 and 0.0017% in the products.
Ved kortlægningen er der fundet oplysninger om det ene af produkterne.
During the survey information was found about one of the products.
Disse oplysninger tyder ikke på, at produktet indeholder blyholdigt pigment og der kan være tale om en urenhed.
This information does not indicate that the product contains lead-containing pigments and an impurity might be involved.
For det andet produkt er der ikke udleveret oplysninger fra leverandør eller producent.
In the case of the other product, neither supplier nor manufacturer submitted any information.
De fundne koncentrationsgrænser er dog under de 0,15% som udløser krav om særlig mærkning af blyholdige produkter, der skal anvendes som maling eller lakker, i henhold til Miljøministeriets bekendtgørelse nr. 329 af 16. maj 2002 om klassificering, emballering, mærkning, salg og opbevaring af kemiske stoffer og produkter.
However, the concentration limits found were below the 0.15% which triggers requirements for special marking of lead-containing products for use as paint or varnish under Statutory Order no. 329 of the Danish EPA dated 16 May 2002 on the classification, marking, sale and storage of chemical substances and products.
Ved analyserne er der således bestemt ca. 50% af produkternes indhold.
Thus the analysis determined approx. 50% of the products' contents.
Øvrige indholdskomponenter vil primært udgøres af bindemiddel, som eksempelvis acrylharpiks, og af fyldstoffer.
Other constituent substances will primarily consist of paint binders such as acrylic resins and fillers.
6 Udvælgelse af stoffer og datasøgning
6 Selected substances and data searching
6.1 Baggrund for udvælgelse af stoffer
6.1 Basis for the selection of substances
Ved den indledende kortlægning blev der identificeret 20 stoffer i gruppen af pigmenter, 7 stoffer i gruppen af bindemidler og deres restmonomerer samt 18 stoffer i gruppen af tilsætningsstoffer.
During the initial survey, 20 substances were identified in the pigment group, 7 in the paint binder and their residual monomers group and 18 substances were identified in the additive group.
Blandt disse stoffer, som både er identificeret på baggrund af generelle oplysninger om indholdsstoffer i vinduesfarver og konkrete oplysninger om testprodukterne, er kun 4 stoffer genfundet i forbindelse med de kemiske analyser.
Among these substances, which were identified based on general information about the constituent substances contained in window colours and specific information on the test products, only 4 were re-encountered in connection with the chemical analysis.
Det skal i den forbindelse understreges, at screeningsanalyserne ikke udspecificerer alle stoffer.
In this connection, we must stress that the screening analysis do not identify all substances individually.
En række stoffer er grupperet under samlebetegnelserne alkaner, alkener, alkoholer, cykloalkaner/-alkener, glycoler og oxyforbindelser, aromatiske forbindelser og andre uidentificerede stoffer.
A number of substances are grouped by their group names alkanes, alkenes, alcohols, cycloalkanes/cycloalkenes, glycols and oxygen compounds, aromatic compounds and other unidentified substances.
Mange af de stoffer, som er fundet ved kortlægningen, må derfor antages at gemme sig under disse samlebetegnelser.
Many of the substances which were found during the survey must therefore be assumed to be included under these group names.
Det gælder i høj grad de tilsætningsstoffer, som er identificeret ved kortlægningen, og vist i Tabel 4.3.
This most certainly applies to the additives identified during the survey and shown in Table 4.3.
Kortlægningen omfatter endvidere ganske mange pigmenter, som man ikke vil kunne forvente at finde ved screeningsanalyse af kun 10 produkter.
The survey also covers a relatively large number of pigments, which one would not expect to find through a screening analysis of just 10 products.
Miljøstyrelsen har på baggrund af resultaterne fra dels kortlægningen og dels den kemiske analyse af testprodukterne, udvalgt ti stoffer, som er ønsket vurderet med hensyn til deres sundhedsmæssige egenskaber.
Based partly on the results of the survey and partly on the chemical analysis of the test products, the Danish EPA has selected ten substances for assessment of their health implications.
For disse stoffer er der udarbejdet en toksikologisk profil, baseret på den umiddelbart tilgængelige litteratur.
A toxicological profile based on the immediately accessible literature was drawn up for these substances.
Der er ved udvælgelsen taget hensyn til stoffernes koncentration og allerede eksisterende viden om/eller vurderinger af stofferne i forbindelse med forbrugerprodukter.
In making the selection, account was taken of the concentration of the substances and any already existing knowledge on/or assessments of the substances in connection with consumer products.
De udvalgte stoffer repræsenterer således de stoffer, der er fundet i størst koncentration i testprodukterne og de stoffer, som Miljøstyrelsen har ønsket yderligere belyst.
Thus, the selected products represent those products found in the highest concentrations in the test products and those substances about which the Danish EPA wishes further information.
I Tabel 6.1 er vist en oversigt over de stoffer, som er udvalgt, med henblik på vurdering af deres sundhedsmæssige egenskaber.
Tabel 6.1 lists the substances selected with a view to assessment of their implications for health.
Tabellen viser desuden om stofferne er identificeret ved kemiske analyse eller på baggrund af oplysninger fra leverandører og i hvilke koncentrationer stofferne findes.
The table also shows whether the substances were identified by chemical analysis or based on information from suppliers, and the concentrations of the substances.
Endelig er stoffernes formodede funktion i produkterne angivet.
Finally, the table lists the substances' presumed application in the products.
Tabel 6.1 Oversigt over stoffer udvalgt til vurdering for sundhedsmæssige egenskaber
Tabel 6.1 Review of substances selected for assessment of their health implications.
Data for stoffernes fysisk-kemiske og sundhedsmæssige egenskaber blev indhentet fra en række internetbaserede databaser og opslagsværker.
Data on the physico-chemical properties and the health implications were obtained from a number of Internet-based databases and reference works.
Der vil være et vist overlap mellem flere af disse databaser.
There will be some overlapping between several of these databases.
Tabel 6.2 giver en oversigt over resultatet af datasøgningen.
Table 6.2 reviews the results of the data search.
Oversigten viser om de 14 databaser indeholdt data for de enkelte stoffer.
The list shows whether the 14 databases contain data on the individual substances.
Herudover er det undersøgt om stofferne er opført på Miljøstyrelsens kemikalielister, kosmetikbekendtgørelsens bilag eller på Fødevaredirektoratets positivliste (fortegnelse over tilsætningsstoffer til fødevarer).
In addition, we examined whether the substances appeared on the chemical lists of the Danish EPA, the annex to the Cosmetics Statutory Order or on the positive list of the Danish Veterinary and Food Administration (list of food additives).
Oversigt over resultatet af datasøgningen.
Review of data search results.
Numrene på databaser og datakilde henviser til følgende: 1.
The database and data source numbers refer to the following: 1.
+ indikerer fund af data.
+ indicates data found.
- indikerer at data ikke er fundet.
- indicates no data found.
6358-30-1 + + - + - + - - - - - - - -Dimethyloxazolidin 51200-87-4 + + - + + - - - - - - - - -Ethylmethyl pyridin 644-98-4
6358-30-1 + + - + - + - - - - - - - -Dimethyloxazolidine 51200-87-4 + + - + + - - - - - - - - -Ethylmethyl pyridine 644-98-4
Det ses af tabellen, at der for flere af stofferne kun er begrænsede data til rådighed i den undersøgte litteratur og for nogle af stoffernes vedkommende udelukkende fysisk-kemiske data.
The table shows that there is only limited data available in the literature examined on several of the substances, and in the case of some substances, only physico-chemical data.
Dette er tilfældet for ethylmethyl pyridin (CAS nr. 644-98-4), methylbenzensulfonamid (CAS nr. 5183-78-8) og de to pigmenter, som det fremgår af Tabel 6.2.
Such is the case with ethylmethyl pyridine (CAS no. 644-98-4), methylbenzenesulfonamide (CAS no. 5183-78-8) and the two pigments, as shown by Table 6.2.
Data for de enkelte CAS nr. fordeler sig på de forskellige toksikologiske egenskaber som illustreret i Tabel 6.3.
Data on the individual CAS nos. is divided according to the various toxicological properties as illustrated in Tabel 6.3.
Der primært er anvendt sekundære kilder og kvaliteten af de anvendte data er dermed meget varierende.
Secondary sources have been used in the main, as a result of which the quality of data varies greatly.
Fra de refererede kilder er der derfor overvejende medtaget resultater fra forsøg hvor forsøgsomstændighederne er rimeligt velbeskrevne.
In by far the majority of cases results have only been included from the sources referred to where the test conditions are reasonably well described.
Tabel 6.3 Identificerede humantoksikologiske data fordelt på de undersøgte CAS numre.
Tabel 6.3 Identified human toxicological data divided by CAS nos. identified.
7 Toksikologisk profil for udvalgtestoffer
7 Toxicological profile of selectedsubstances
1-Naphthol bruges i forbindelse med fremstilling af farver (f.eks. diazopigmenter), til syntetiske parfumer og til hårfarve.
1-Naphthol is used in the manufacture of paints and colours (e.g. diazo pigments), of synthetic perfumes and of hair dyes.
Stoffet bruges også til produktionen af insekticidet Sevin (carbaryl) og antioxidanter /12/.
The substance is also used in the production of the insecticide Sevin (carbaryl) and anti-oxidants /12/.
Følgende synonymer er fundet for 1-naphthol /12/:
The following synonyms have been found for 1-naphthol /12/:
Regulering EU/DK klassificering
Regulation EU/DK classification
Miljøstyrelsens vejledende liste til selvklassificering
The Danish EPA's guideline list for selfclassification
højeste tilladte koncentration i hårfarvningsmiddel er 2,0%
highest permitted concentration in hair dye is 2.0%
Forsøg med applikation af 1-naphthol på huden af mennesker indikerede at ca. 50% blev optaget percutant /8/.
Tests involving the application of 1-naphthol to human skin indicated approx. 50% was absorbed percutaneously /8/.