natgillin/translations-raw huggingface dataset:
Alle identifikationer af stoffer er foretaget ud fra massespektret ved sammenligning med massespektre i et databibliotek.
All identifications of substances were made on the basis of the mass spectrum compared with mass spectra in a data library.
Indholdet blev beregnet kvantitativt ved brug af ekstern standard samt responsfaktorer for eksterne standarder.
The contents were calculated quantitatively by use of an external standard and response factors for external standards.
For produkter på sprayform, som indeholdt drivmidler (propan/butan), blev analysen foretaget efter, at drivmidlet var blevet afdampet.
For spray products with contents of propellants (propane/butane), the analysis was made after the propellant had evaporated.
Analyserne blev udført som dobbeltbestemmelser og angivet som gennemsnit af de to bestemmelser.
Analyses were made as repeat determinations and were calculated as the mean of the two determinations.
Rapporteringsgrænsen var 500 mg kg
The reporting limit was 500 mg kg
En delprøve blev ekstraheret med methanol og analyseret direkte ved omvendt fase-kolonne væskekromatografi med massespektrometrisk detektion (HPLCMS).
A subsample was extracted with methanol followed by direct analysis of the extract by reverse phase column liquid chromatography with mass spectrometric detector (HPLC-MS).
Den anvendte detektionsmetode var elektrospray ionisering i negativ mode.
The detection was made by electrospray ionization in negative mode.
Der blev anvendt kalibrering med eksterne standarder analyserede i serie med prøverne.
The calibration was made with external standards analysed in series with the sample.
Én af prøverne (produkt nr. 7) kunne ikke opløses/opslemmes i methanol.
One of the samples (product no. 7) was not dissolvable/suspendable in methanol.
Der blev i stedet anvendt en blanding af methanol og vandig ammoniumacetat.
Instead a mixture of methanol and aqueous ammonium acetate was used.
Analyserne blev udført som dobbeltbestemmelser og angivet som gennemsnit af de to bestemmelser.
The analyses were made as repeat determinations and were calculated as the mean of the two determinations.
Detektionsgrænsen var 0,1 mg kg
The detection limit was 0.1 mg kg
og analyseusikkerheden var 10 - 15 %
and the analytical uncertainty was 10 - 15
Der blev analyseret for opløsningsmidler i alle 14 produkter.
All 14 products were analysed for solvents.
Resultaterne af analyserne er angivet i tabel 4.2.
Table 4.2 shows the results of the analyses.
Værdierne er angivet i vægt-%.
Values are given in weight percentages.
Resultater af analyse for opløsningsmidler (gennemsnit af dobbeltbestemmelser).
Results of analysis for solvents (mean of repeat determinations).
Resultaterne er angivet i vægt-%.
The results are stated in weight %
N-methyl-2-pyrrolidon 15
N-methyl-2-pyrrolidone 15
Sum af organiske syrer heriblandt eddikesyre
Sum of organic acids including acetic acid
-: betyder mindre end den angivne detektionsgrænse (500 mg/kg) *: beregnet semikvantitativt
-: less than the stated detection limit (500 mg/kg) *: semiquantitatively determined
Fire af produkterne blev analyseret for 9 specifikke PFOS-forbindelser.
Four of the products were analysed for 9 specific PFOS compounds.
Opløsningsmidler indgår i varierende koncentrationer i de analyserede produkter.
Solvents form part of the analysed products in varying concentrations.
I tabel 4.3 ses summen af de opløsningsmidler, der blev identificerede ved analyse af produkter til rengøring af henholdsvis ovn og glaskeramiske kogeplader.
Table 4.3 shows the sum of the solvents identified by analysing products for cleaning of ovens and ceramic cooktops, respectively.
Totalt analyseret indhold af organiske opløsningsmidler i ovnrens og glaskeramisk pladerens (i vægt-%)
Total contents of analysed organic solvents in oven cleaners and ceramic cooktop cleaners (in weight %)
Total koncentration af opløsningsmidler i vægt %
Total concentration of solvents in weight %
11 (creme) 13 (creme) 14 (creme) 16 (creme) 17 (creme)
11 (cream) 13 (cream) 14 (cream) 16 (cream) 17 (cream)
Gennemsnit Bemærk: Analyse på sprayprodukter er foretaget efter, at drivmidlet er blevet afdampet
Average Note: Analyses of spray products have been made after evaporation of the propellant
Produkter til rengøring af ovne indeholdt som ventet de højeste koncentrationer af opløsningsmidler, op til 33 % på vægtbasis.
As expected, the products for cleaning of ovens contained the highest concentrations of solvents, up to 33 % based on weight.
Ovnrensemidler på sprayform havde ifølge analyserne et højt indhold af organiske opløsningsmidler (13 - 33 %), mens de to øvrige ovnrenseprodukter indeholdt < 1 % eller ingen organiske opløsningsmidler.
According to the analyses, the oven cleaners on spray form had high contents of organic solvents (13 - 33 %), whereas the two other oven cleaners contained < 1 % or no organic solvents.
For produkter på sprayform er den reelle koncentration af opløsningsmidler i det samlede produkt inklusive drivmidlet lavere end vist i tabel 4.3, idet analysen som nævnt blev foretaget efter, at drivmidlet var blevet afdampet.
For spray products the real concentration of solvents in the total product, including the propellant, is lower than shown in Table 4.3, as the analysis as mentioned was made after evaporation of the propellant.
I produkterne til glaskeramiske kogeplader blev organiske opløsningsmidler identificerede i 8 af de 9 analyserede produkter.
In the products for ceramic cooktops, organic solvents were identified in 8 of the 9 analysed products.
I produkt nr. 2 blev der ikke identificeret opløsningsmidler ved kemisk analyse.
In product no. 2, no solvents were identified by chemical analysis.
Opløsningsmidlerne er fundet i koncentrationer fra 0,56 - 13 % (baseret på vægt).
The solvents were found in concentrations of 0.56 - 13 % (based on weight).
Blandt de opløsningsmidler, der blev identificerede i analyserne, er seks af stofferne klassificerede i henhold til Miljøstyrelsens Liste over farlige stoffer (LOFS), som angivet i tabel 4.4.
Of the solvents identified by analyses, six of the substances were classified in accordance with the Danish EPA's List of dangerous substances (LODS) as stated in Table 4.4.
Klassificerede opløsningsmidler analyseret i produkterne Kemisk navn
Classified solvents analysed in the products Chemical name
Diverse CAS nr. f.eks. 8008-20-6
Various CAS Nos., e.g. 8008-20-6
108-31-6 Xn; R22 C; R34 R42/43 * Nedre koncentrationsgrænse for klassificering af produkt: 10 % ** I analyserne blev der identificeret ”alkyleret furandion”.
108-31-6 Xn; R22 C; R34 R42/43 * Lower concentration limit for classification of product: 10 % ** In the analyses,”alkylised furandione” was identified.
Stoffet kunne ikke præcist identificeres
The exact identity of the substance could not be determined.
I produkt nr. 1 (ovnrens, spray) er indholdet af N-methyl-2-pyrrolidon målt til 15 % efter, at drivmidlet var blevet afdampet.
In product no. 1 (oven cleaner, spray), the contents of N-methyl-2pyrrolidone were measured to 15 % after evaporation of the propellant.
Mængden af drivmiddel er i sikkerhedsdatabladet angivet til max 10 %, hvilket giver en koncentration af N-methyl-2-pyrrolidon på 13,5 % i det samlede produkt inkl. drivmiddel.
The amount of propellant is stated in the safety data sheet to be max. 10 %, which gives a concentration of N-methyl-2-pyrrolidone of 13.5 % in the total product, including the propellant.
I forbindelse med forberedelse til 31. tilpasning til stofdirektivet (67/548/EEC) har det endvidere været diskuteret, at N-methyl-2-pyrrolidon skulle klassificeres som reproduktionsskadelig (T; R61 Kan skade barnet under graviditeten), og dermed også produkter, som indeholder N-methyl-2-pyrrolidon.
In accordance with the 31st adaptation to the Dangerous Substance Directive (67/548/EC), which has not yet been adopted, it has been discussed to classify N-methyl-2-pyrrolidone as reproduction toxic (T;R61 May cause harm to the unborn child), and consequently also products containing Nmethyl-2-pyrrolidone.
Produkt nr. 3 indeholder 13 % petroleum.
Product No. 3 contains 13 % of petroleum.
Produkter med en viskositet lavere end 7  10
For products with a viscosity of less than 7  10
og indhold af petroleum i koncentrationer > 10 % skal klassificeres og mærkes som sundhedsskadelig (Xn) med R65 (Farlig: kan give lungeskade ved indtagelse).
, a petroleum content of > 10 % will result in a classification of a product as “Harmful” (Xn) with R65 (Harmful: may cause lung damage if swallowed).
Da produktet er et cremeprodukt, som har en høj viskositet, skal produktet ikke klassificeres pga. indhold af petroleum.
As the product, however, is a cream product with high viscosity, the product will not have to be classified due to its contents of petroleum.
Ingen af de øvrige opløsningsmidler i tabel 4.4 er indeholdt i koncentrationer, der giver anledning til klassificering af produkterne.
None of the other solvents in Table 4.4 are contained in concentrations resulting in a classification of the products.
De analyserede produkter er alle produkter til rengøring af glaskeramiske kogeplader.
All of the analysed products are ceramic cooktop cleaners.
Silikoneforbindelser har som nævnt samme funktion i produkterne som PFOS-forbindelser og anvendes som alternativ til PFOS.
As already mentioned, silicone compounds have the same function in the products as PFOS compounds, and are used as an alternative to PFOS.
4.5 Sammenfatning af analyseresultater og tilgængelige produktoplysninger
4.5 Summary of results of chemical analyses and available product information
I tabel 4.5 er de kemiske analyseresultater sammenholdt med de oplysninger, der er fundet om produkternes sammensætning i produkternes indholdsdeklarationer samt i sikkerhedsdatablade (SDB).
In Table 4.5, the results of the chemical analyses are compared with the information on the composition of the products found in their listings of ingredients and in their safety data sheets (SDS).
Sammenligning af analyseresultater og leverandøroplysninger
Comparison of results of chemical analyses and information from suppliers Product no.
Produkt nr. Produkttype
Type of product
Stoffer identificeret ved kemisk analyse (% i produktet)
Substances identified by chemical analysis (% in the product)
(Begge er heterocykliske aromatiske forbindelser)
(Both substances are heterocyclic aromatic compounds)
Af indholdsdeklarationen fremgår indhold af "opløsningsmidler".
A content of “solvents” was stated in its listing of ingredients.
I SDB er angivet "heterocykliske forbindelser” i en koncentration på 1-5 % med klassificering Xi; R36/38.
Its SDS stated “heterocyclic compounds” in a concentration of 1 - 5 % with the classification Xi; R36/38.
Oplysningerne stemmer ikke overens, idet koncentrationen af de fundne heterocykliske forbindelser ved analyse overstiger 1 - 5 %.
The data disagree as the concentration of the heterocyclic compounds found at the analysis exceeded 1 - 5 %.
Der vil være krav om mærkning af produktet, hvis indholdet af N-methyl-2-pyrrolidon er over 10 % (Xi, R36/38)
There will be a demand for labelling of the product if the contents of N-methyl-2pyrrolidone is above 10 % (Xi;R36/38).
Produktet indeholder citronsyre ifølge indholdsdeklaration.
According to its listing of ingredients, the product contained citric acid.
Der er ikke fundet organiske syrer >0,05 % ved analyse.
No organic acids > 0.05 % were found at the analysis.
Produktet indeholder ifølge indholdsdeklarationen petroleumsdestillater i overensstemmelse med den kemiske analyse.
According to its listing of ingredients, the product contained petroleum distillates, which agreed with the analysis.
I SDB er angivet 25 - 50 % alifatiske kulbrinter, hvilket overstiger det analyserede indhold.
Its SDS stated 25 - 50 % aliphatic hydrocarbons, which exceeded the content found at the analysis.
Der er desuden angivet indhold af citronsyre < 1 % i SDB (ej identificeret i analysen < 0,05 %).
Furthermore, a content of citric acid < 1 % was stated in its SDB (not identified at the analysis > 0.05 %).
N-methyl-2-pyrrolidon (heterocyklisk forbindelse) (4,1 %)
N-methyl-2pyrrolidone (heterocyclic compound) (4.1 %)
Der er ingen oplysninger om indhold af organiske opløsningsmidler på produktets indholdsdeklaration.
Its listing of ingredients did not state any contents of organic solvents.
Der er ingen oplysninger om indhold af organiske opløsningsmidler i indholdsdeklarationen.
Its listing of ingredients did not state any contents of organic solvents.
Alkyleret furandion (heterocyklisk forbindelse) (0,56 %)
Alkylised furandione (heterocyclic compound) (0.56 %)
I indholdsdeklarationen er angivet organisk syre.
Its listing of ingredients stated an organic solvent.
Ifølge SDB indeholder produktet 1-5 % citronsyre.
According to its SDS, the product contained 1 - 5% citric acid.
Der er ikke fundet organiske syrer >0,05 % ved kemisk analyse.
No organic solvents > 0.05% were found by chemical analysis.
Der er ingen oplysninger om indhold af heterocykliske forbindelser.
There was no information of a content of heterocyclic compounds.
I indholdsdeklarationen er angivet indhold af organisk syre.
Its listing of ingredients stated a content of organic solvent.
Petroleum (8,7 %) Ingen indholdsdeklaration/SDB
Petroleum (8.7 %) No listing of ingredients/SDS
Ingen indholdsdeklaration/SDB
No listing of ingredients/SDS
Ifølge indholdsdeklaration og SDB indeholder produktet citronsyre (1-5 %).
According to its listing of ingredients and SDS, the product contained citric acid (1 - 5 %).
Der er ikke fundet organiske syrer > 0.05 %.
No organic acids > 0.05 % were found by chemical analysis.
Butyldiglycol (2,6 %) Produktet indeholder alkohol i henhold til indholdsdeklarationen, hvilket er i overensstemmelse med analyseresultatet.
Butyl diglycol (2.6 %) According to its listing of ingredients, the product contained alcohol, which agreed with the results of the analysis.
Det fremgår af tabel 4.5, at de tilgængelige vareinformationer i enkelte tilfælde ikke stemmer overens med de analyserede data for opløsningsmidler.
Table 4.5 shows that a few of the available listings of ingredients do not agree with the analytical data on solvents.
Der er generelt ikke fundet store mængder af farlige stoffer ved analyserne.
In general, no large amounts of dangerous substances were identified by the analyses.
For flere af produkterne står analyseresultaterne alene, idet der ikke var tilgængelige oplysninger på produkternes etiketter eller i deres sikkerhedsdatablade (SDB).
For several products, the results of the chemical analysis are the only data, as no information was available on the product labels or in the safety data sheets (SDS).
Analyseresultaterne indikerer, at andel og sammensætning af opløsningsmidler varierer alt efter et produkts anvendelsesområde og form.
The analysed parameters indicate that the share and composition of solvents vary according to the application area and form of a product.
De højeste koncentrationer af organiske opløsningsmidler blev fundet i sprayprodukter til ovnrengøring, mens koncentrationerne i de øvrige produkter var lavere.
The highest concentrations of organic solvents were thus found in spray products for oven cleaning, whereas the concentrations in the other analysed produces were lower.
Datamaterialet er dog ikke stort nok til, at der kan drages entydige konklusioner om sammensætning og indhold af opløsningsmidler de forskellige produkttyper imellem.
The data material, however, is not extensive enough to draw unambiguous conclusions on the composition and contents of solvents according to the different types of products.
4.6 Sammenligning med skurecremer
4.6 Comparison with scouring cream
Et delformål med kortlægningen og de kemiske analyser af ovn- og pladerens var at sammenligne indhold i rensemidler til glaskeramiske plader med almindelige skurecremer.
A sub-objective of this survey and the chemical analyses of oven and ceramic cooktop cleaners were to compare the contents of ceramic cooktop cleaners with common scouring creams.
Formålet med dette var at vurdere om, de samme stoffer indgår i disse to typer produkter, særligt hvad angår anvendelse af slibemidler.
The purpose of this comparison was to assess whether it is the same substances that form part of these two types of products, especially with respect to the use of abrasives.
Afhængig af kornstørrelsen på slibepartiklerne kan slibemidler lave ridser i de overflader, der rengøres.
Depending on the grain size of the abrasive particles, the abrasives may scratch the surfaces cleaned.
Til dette formål blev der indkøbt tre almindelige skurecremer i perioden majjuli 2005.
For this purpose, three common scouring creams were purchased in MayJuly 2005.
I tabel 4.6 ses typiske indholdsstoffer i skurecremer, identificeret ud fra indholdsdeklarationerne på de tre produkter.
Table 4.6 shows the typical constituents of scouring creams identified on the basis of the listings of ingredients of the three products.
Stof identificeret i glaskeramisk pladerens
Substance identified in ceramic cooktop cleaners
Alkohol ethoxylat, C13-iso, 3 EO
Alcohol ethoxylate, C13-iso, 3EO
Alkohol ethoxylat, C13, 10 EO
Alcohol ethoxylate, C13, 10EO
Methylchloroisothiazolinon 26172-55-4 < 5 % Nej Calciumcarbonat
Methylchloroisothiazolinone 26172-55-4 < 5 % No Calcium carbonate
Det fremgår af tabel 4.6, at der er et vist sammenfald af kemiske stoffer, som anvendes i henholdsvis skurecremer og produkter til rengøring af glaskeramiske kogeplader, f.eks. hvad angår indholdet af tensider (overfladeaktive stoffer).
Table 4.6 indicates a certain coincidence of chemical substances used in scouring creams and ceramic cooktop cleaners, respectively, e.g. regarding surfactants (surface-active substances).
De tilgængelige informationer om produkternes specifikke sammensætning er dog begrænsede, og sammenligningen er kun baseret på et mindre antal produkter.
The available information on the specific composition of the products is, however, limited and the comparison is only based on a small number of products.
Det er derfor muligt, at der er større overlap blandt indholdet af kemiske stoffer end skitseret i tabel 4.6.
It is thus possible that the overlap in the contents of chemical substances is even larger than indicated in Table 4.6.
En væsentlig forskel på de to typer af produkter er, at der ikke indgår silikone i skurecremerne.
A substantial difference between the two types of products is that silicone does not form part of the scouring creams.
Koncentrationen af opløsningsmiddel i skurecremer er kun oplyst for et af de tre produkter, hvori der indgår mindre end 5 % opløsningsmiddel.
The concentration of solvents in scouring creams is only stated for one of three products, which contains less than 5 % of solvent.
Der anvendes forskellige slibemidler til skurecremer og produkter til glaskeramisk pladerens.
Various abrasives are used for scouring creams and ceramic cooktop cleaners.
I skurecremer anvendes typisk calciumcarbonat (kridt) i større mængder samt aluminiumsilicat.
In scouring creams, calcium carbonate (chalk) is typically used in considerable amounts together with aluminium silicate.
I rengøringsprodukter til glaskeramiske plader anvendes fortrinsvis aluminiumoxid og kaliumcarbonat (potaske), som vist i tabel 4.7
In ceramic cooktop cleaners, mainly aluminium oxide and potassium carbonate (potash) are applied as shown in Table 4.7.
Slibemidler anvendt i skurecreme henholdsvis produkter til glaskeramiske plader
Abrasives used in scouring creams and ceramic cooktop cleaners, respectively
Det ses, at slibemidler i begge produkttyper kan udgøre en væsentlig andel.
It was not possible to get any information on the grain size of the different abrasives.
5 Sundheds- og miljømæssig vurdering af indholdsstoffer
5 Health and environmental assessment of ingredients
5.1 Sundheds- og miljømæssig vurdering af indholdsstoffer identificeret i kortlægningen
5.1 Health and environmental assessment of ingredients identified by the survey
I det følgende er de forskellige typer af indholdsstoffer, der blev identificerede i kortlægningen, blevet screenet med hensyn til farlighed for sundhed og miljøet.
Below, the various types of ingredients identified by the survey were screened with respect to their health and environmental hazard.
Når det i det følgende nævnes, at et stof ikke er klassificeret i Listen over farlige stoffer (LOFS), er det vigtigt at være opmærksom på, at det ikke dermed kan konkluderes, at stoffet ikke kan have farlige egenskaber.
When mentioned below that a substance is not classified in the List of dangerous substances (LODS), it is important to realize that it cannot necessarily be concluded that the substance cannot have dangerous properties.
Grunden til manglende klassificering kan være, at stoffet ikke er vurderet af myndighederne.
The reason for the lack of classification may be that the substance has not been evaluated by the authorities.
5.1.1 Overfladeaktive stoffer (tensider)
5.1.1 Surface-active substances (surfactants)
Mindst 10 af de 21 produkter indeholdt nonioniske tensider, og mindst 12 produkter indeholdt anioniske tensider.
At least 10 of the 21 products contained non-ionic surfactants and at least 12 products contained anionic surfactants.
Et produkt indeholdt et amfotert tensid.
One product contained amphoteric surfactants.
Tensiderne indgår i produkterne i koncentrationer på 1-5 %.
The surfactants form part of the products in concentrations of 15 %.
Dog indgik fedtsyresæber (anioniske tensider) i koncentrationer på 10-20 % i et enkelt produkt.
However, fatty acid soaps (anionic surfactants) occurred in concentrations of 10 - 20 % in a single product.
De nonioniske tensider udgøres hovedsaglig af alkoholethoxylater med varierende antal ethoxylat(EO)grupper.
The non-ionic surfactants mainly consist of alcohol ethoxylates with varying numbers of ethoxylate(EO)groups.
De anioniske tensider udgøres hovedsagelig af sekundære alkansulfonater samt fedtsyresæber.
The anionic surfactants consist of secondary alkane sulfate and fatty acid soaps.
Tensider virker irriterende på hud og øjne og har ofte en affedtende effekt på huden.
Surfactants are irritating to skin and eyes, and often they have a degreasing effect on the skin.
Generelt virker anioniske tensider mest irriterende; amfotere tensider virker mindre irriterende.
In general, the anionic surfactants are the most irritating; the amphoteric surfactants are less irritating.
Ifølge CESIO (Comité Européen des agents de Surface et de leurs Intermédiaires Organiques) er alkoholethoxylater anbefalet klassificeret som sundhedsskadelige (Xn) med R22 (farlig ved indtagelse)(515 EO) og lokalirriterende (Xi) med R41 (risiko for alvorlig øjenskade).
According to CESIO (Comité Européen des agents de Surface et de leurs Intermédiaires Organiques), it is recommended to classify alcohol ethoxylates as Harmful (Xn) with R22 (Harmful if swallowed) (5 -15 EO) and Irritant (Xi) with R41 (Risk of serious damage to eyes).
Irritationspotentialet afhænger af ethoxyleringsgraden og alkylkædelængden.
The potential for irritation depends on the degree of ethoxylation and the length of the alkyl chain.
De anioniske tensider anbefales klassificeret som lokalirriterende (Xi) med R38-41 (irriterer huden, risiko for alvorlig øjenskade), de amfotere tensider anbefales klassificeret som lokalirriterende (Xi) med R36 (irriterer øjnene).
It is recommended to classify the anionic surfactants as Irritant (Xi) with R38-41 (Irritating to skin - Risk of serious damage to eyes) and to classify the amphoteric surfactants as Irritant (Xi) with R36 (Irritating to eyes).
Hvad de miljømæssige egenskaber angår, vurderes alle de identificerede tensider at være let nedbrydelige.
As regards the environmental properties, all of the identified surfactants are considered readily degradable.
Således vil kun en meget lille andel forventes at blive udledt til miljøet med renset spildevand efter ophold i renseanlæg.
Only a very small part is thus expected to be discharged into the environment with treated waste water after retention in a waste water treatment plant.
Flere af de nonioniske tensider har en høj akut giftighed.
Several of the non-ionic surfactants have high acute toxicity.