natgillin/translations-raw huggingface dataset:
Den anvendte samplingsmetode, på baggrund af Solid Phase Micro Extraction (SPME), måler for organiske forbindelser fra flygtige, organiske solventer (ethanol, acetone etc.) til de mere semiflygtige forbindelser (parabener, phthalater etc.).
The applied sampling method, on the basis of Solid Phase Micro Extraction (SPME), measures organic compounds from volatile, organic solvents (ethanol, acetone etc.) to the more semi-volatile compounds (parabenes, phthalates etc.).
Der er i forbindelse med gennemgangen af deklarationen af de undersøgte produkter ikke fundet indikationer for indholdsstoffer, der ikke er medtaget af den anvendte målemetode.
In connection with the survey of the informative labelling of the examined products no indication of substances appeared that had not been included in the applied measuring method.
I forbindelse med prøveforberedelsen afvejes 1,0 g prøve i et 20 ml membranglas.
In connection with the test preparation, a 1.0 g sample was weighed in a 20 ml membrane glass.
Headspace blev samplet i 15 min. ved SPME og efterfølgende analyseret ved gaschromatografi med massespektrometrisk detektion (GC/MS).
Headspace was sampled for 15 min. at SPME and subsequently analysed by means of gas chromatography with mass spectrometric detection (GC/MS).
Følgende parametre blev anvendt:
The following parameters were applied:
Bæregas: Helium, constant flow: 1,0 ml/min.
Carrier gas: Helium, constant flow: 1.0 ml/min.
Påviste komponenter er alene identificeret ved brug af NIST-bibliotek (The NIST Mass Spectral Search Program) over massespektre og manuel fortolkning af spektrene samt ved anvendelse af AMDIS-dekonvoleringssoftware.
The demonstrated components were solely identified by using NIST library (The NIST Mass Spectral Search Program) covering mass spectra and manual interpretation of the spectra and the use of AMDIS deconvolation software.
Det er således overvejede sandsynligt, at de i forbindelse med den udførte screening identificerede stoffer er til stede, hvor disse er påvist.
Therefore, it is very probable that the substances identified in connection with the performed screening exist where they were demonstrated.
Der er i forbindelse med den udførte kvalitative screening ikke foretaget nogen kvantitativ vurdering af indholdet af de identificerede, organiske forbindelser.
In connection with the performed qualitative screening no quantitative evaluation of the content of the identified, organic compounds was carried out.
De samlede resultater fra screeningen af de 21 undersøgte produkter er vist i Tabel 2.1.
The total results from the screening of the 21 analysed products appear from Table 2.1.
Grundet forsinket leverance er produkt nr. 24 ikke medtaget i screeningfasen.
Due to delayed delivery, product 24 was not included in the screening phase.
Tabel 2.1 Indledende kemisk screening af sexcremer
Table 2.1 Initial chemical screening of pleasure gels
1-Phenooxy propan-2-ol α-Pinen
1-Phenooxy propan-2-ol α-Pinene
β-Guiene Benzaldehyd
β-Guiene Benzaldehyde
Benzosyre methyl ester Benzyl alkohol
Benzosyre methyl ester Benzyl alcohol
Cinnamyl alkohol acetat
Cinnamyl alcohol acetat
Eddikesyre 2-phenyl ethyl ester
Acetic acid 2-phenyl ethyl ester
Eddikesyre benzyl ester
Acetic acid benzyl ester
Geraniol acetat Hexyl cinnemaldehyd
Geraniol acetat Hexyl Cinnamaldehyde
Vanillin Tabel 2.1 - fortsat - Indledende kemisk screening af sexcremer
Vanillin Table 2.1 continued - Initial chemical screening of pleasure gels
Eddikesyre 2-phenyl ethyl ester Eddikesyre benzyl ester
Acetic acid 2-phenyl ethyl ester Acetic acid benzyl ester
Menthol acetat Menthone
Menthol acetate Menthone
p-Anisaldehyd p-Cymene Phenol
p-Anisaldehyde p-Cymene Phenol
Phenyl ethyl alkohol
Phenyl ethyl alcohol
Det var ikke forudset, at der blev identificeret så mange forskellige stoffer ved den indledende kemiske screening, og der blev derfor gennemført en udvælgelse af stoffer til den sundhedsmæssige screening.
It was not anticipated that so many different substances would be identified at the initial chemical screening and therefore substances were selected for the health screening.
Udvælgelsen blev foretaget på baggrund af oplysninger anført i Tabel 2.2 i samråd med Miljøstyrelsen.
The selection was carried out in the light of information stated in Table 2.2 in consultation with the Danish Environmental Protection Agency.
Tabel 2.2 Stoffer fundet ved screening af udvalgte produkter Navn
Table 2.2 Substances found during screening of selected products Name
Forekomst Antal produkter
Occurrence Number of products
De stoffer, der er mærket ”*”, er af EU's videnskabelige komite for kosmetik vurderet som allergifremkaldende parfumestoffer.
Substances that EU scientific committee for cosmetics has evaluated as allergic odorous substances have been marked with ”*”.
For de stoffer, som er mærket med ”**”, er klassificeringen hentet fra den vejledende liste til selvklassificering (Vejledende liste, 2001).
In connection with substances marked with”**” classification was obtained from the Danish advisory list for self-classification (Vejledende liste, 2001).
Hvor der under Klassificering er angivet ”-”, betyder det, at stoffet hverken er optaget på Listen over farlige stoffer eller på den vejledende liste.
An ”-” stated under the column "Classification" means that the substance neither was entered on the dangerous substance list nor on the Danish advisory list.
For produkt 15 er det nævnt, at det indeholder spansk flue (cantharidin).
In connection with product 15 it was declared that it contained Spanish fly (cantharides).
Der er i forbindelse med den udførte kemiske screening ikke fundet indhold af cantharidin i produktet.
In connection with the performed chemical screening no content of cantharides was found in the product.
For de i alt 28 udvalgte stoffer er der gennemført en sundhedsmæssig screening.
A health screening was carried out for the 28 selected substances.
I Tabel 2.3 er vist udvalgte fysisk-kemiske data for disse stoffer.
Table 2.3 shows selected physical-chemical data of the substances.
Fysisk-kemiske data for de udvalgte stoffer er fundet ved søgninger i chemid og HSDB under TOXNET.
The physical-chemical data of the selected substances was found by searching in chemid and HSDB under TOXNET.
Molekylvægt er fundet i HSDB, medmindre andet er anført.
Molecule weight was found in HSDB, unless something else is stated.
Data om kogepunkt, smeltepunkt, Log KOW, vandopløselighed og damptryk er hentet fra TOXNET/chemid/physical prop.
Data about boiling point, melting point, Log KOW, water solubility and steam pressure was found in TOXNET/chemid/physical prop.
Damptryk mm Hg
Steam pressure mmHg
2-Phenoxy ethanol Benzaldehyd Benzyl alkohol Cantharidin
2-Phenoxyethanol Benzaldehyde Benzyl alcohol Cantharidin
Kogepunktet ligger for de fleste stoffer omkring eller over 200 °C.
For most of the substances, the boiling point is in the area of/or above 200 °C.
Kun stoffet pyrazin har et kogepunkt på 115 °C.
Only the substance pyrazin has a boiling point of 115 °C.
Dertil kommer stoffet cantharidin, som går fra fast stof til gasfase ved 84 °C (sublimerer).
In addition, the substance cantharides changes from fixed substance to gas phase at 84 °C (sublimes).
Der er fundet damptryk for relativt få af stofferne.
A steam pressure was found for rather few substances.
Damptrykkene er lave - for D-Limonen er det 2 mm Hg og mindre end 1 mm Hg for alle øvrige.
The steam pressures are low - for D-Limonene it is 2 mm Hg and less than 1 mm Hg for all others.
Hermed vil kun en begrænset mængde af stofferne fordampe og kunne indtages via luftvejene.
Therefore, only a limited amount of the substances will evaporate and be taken in through the respiratory passages.
Ingen af de udvalgte stoffer er fuldt blandbare med vand.
None of the selected substances are fully miscible with water.
Halvdelen af stofferne har en opløselighed i vand på mellem 1 og 200 gram, mens den anden halvdel har en opløselighed på under 1 gram pr. liter vand.
Half of the substances have a solubility in water of between 1 and 200 g while the other half has a solubility of less than 1 g per litre water.
Stoffet pyrazin, som har en opløselighed på 200 gram/liter, har en negativ Log KOW, hvilket vil sige, at stoffet er væsentligt mere opløseligt i vand end i fedtstoffer (octanol).
The substance pyrazin, with a solubility of 200 g/litre, has a negative Log KOW, meaning that the substance is much more soluble in water than in fatty substances (octanol).
Kun et enkelt stof, D-Limonen har en Log KOW på over 4, som jf. anvisningerne for risikovurdering (TGD, 2003) betyder, at stoffet kan optages gennem huden i begrænset omfang.
Only one single substance, D-Limonene, has a Log KOW of more than 4, which according to the directions for risk assessment (TGD, 2003) means that the substance to a limited degree can be absorbed through the skin.
Relativt mange stoffer med høj vandopløselighed har en Log KOW på mellem 1 og 2, mens de stoffer, der har en lav vandopløselighed, har en Log KOW på mellem 3 og 4.
A rather large amount of substances with high water solubility have a Log KOW of between 1 and 2, while the substances with low water solubility have a Log KOW of between 3 and 4.
Med hensyn til klassificering er der søgt i Listen over farlige stoffer samt i Miljøstyrelsens vejledende liste til selvklassificering.
With regard to classification a search was performed in the list of dangerous substances and in the advisory list for self-classification from the Danish Environmental Protection Agency.
De data, der er hentet fra den vejledende liste, er mærket med ”**”.
The data found in the advisory list is marked with”**”.
Der er søgt efter samtlige stoffer i databasen for INCI (INCI , 2005).
All substances were searched for in the INCI database (INCI , 2005).
Det er anført, om stofferne findes på listen, samt hvilke oplysninger listen giver om stoffernes funktion og begrænsninger.
It is stated if the substances are on the list and which information the list gives about the function and limitations of the substances.
Begrænsninger mv. fra kosmetiklovgivningen er ligeledes anført.
The limitations etc. in the law on cosmetics are also stated.
Endvidere er det angivet, om stoffet er anført på EU's videnskabelige komite for kosmetiks liste over allergifremkaldende stoffer.
In addition, it is mentioned if the substance appears on the EU's scientific committee for cosmetic's list of allergenic perfume substances.
Hvis kravene i kosmetikbekendtgørelsen var gældende for sexcreme, skulle alle indholdsstoffer deklareres.
If the requirements in the Statutory Order on cosmetics were valid for pleasure gel, all substances would have to be declared.
Kan udløse allergisk reaktion”.
Allergic reaction can arise".
Tabel 2.4 Klassificering, funktion, krav og begrænsninger for udvalgte stoffer i sexcremer Navn
Table 2.4 Classification, function, requirements and limitations of selected substances in pleasure gel Name
Klassificering EU's allergiliste
Classification EU allergy list
Krav og begrænsninger jf. Kosmetikbekendtgørelsen
Requirements and limitations cf. Statutory Order on cosmetics
67, III/54: Må kun anvendes i produkter, der renses af efter brug.
67, III/54: Only to be used in products that are cleaned off after use.
Forbudt i mundplejemidler.
Forbidden in dental hygiene products.
Konserveringsmiddel/ opløsningsmiddel; III/1,45-VI/1,34 samt parfume
Preservative/ solvent; III/1,45VI/1,34 and perfume
Hvis anvendt som parfume, deklareres når koncentrationen overstiger 0,001 % i produkter, som ikke afrenses, og 0,01 % i produkter, som afrenses
If used as perfume labelling is necessary when the concentration exceeds 0.001 % in products that are not cleaned off and 0.01 % in products that are cleaned off.
Findes ikke i INCI
Classification EU allergy list
Duftstof som t-cinnamic acid
Fragrance as tcinnamic acid
24, III/69: Hvis anvendt som parfume, deklareres når koncentrationen overstiger 0,001 % i produkter, som ikke afrenses, og 0,01 % i produkter, som afrenses
24, III/69: If used as perfume labelling is necessary when the concentration exceeds 0.001 % in products that are not cleaned off and 0.01 % in products that are cleaned off.
D-Limonen 5989-27-5 R10 Xi; R38, R43
5989-27-5 R10 Xi; R38, R43
Duftstof som 4allylanisole
Fragrance as 4allylanisole
Findes ikke i INCI
Nonexistent on INCI
Antimikrobielt middel/ denatureringsmiddel/st of i deodorant ; III/1,19
Antimicrobials/ denaturants/deodoran t agents; III/1,19
Duftstof under geraniol
Fragrance under geraniol
Kan udløse allergisk reaktion", hvis koncentrationen er > = 0,1 %
Allergic reaction can arise" if the concentration is > = 0.1 %.
Som det fremgår af Tabel 2.4, er 21 ud af de 28 stoffer klassificeret, enten på listen over farlige stoffer eller på den vejledende liste til selvklassificering
Table 2.4 shows that 21 out of 28 substances were classified either on the list of dangerous substances or on the Danish advisory list for self-classification.
Blandt de klassificerede stoffer er der et stof, phenol, og et selvklassificeret stof, eugenol, for hvilket det er angivet, at der er risiko for genetiske skader.
Among the classified substances there is one substance, phenol, and one selfclassified substance, eugenol, for which it is stated that there is a risk of genetic damages.
En række stoffer er klassificeret R43: Kan give overfølsomhed ved kontakt med huden.
A number of substances are classified R43: Can cause allergy when in contact with the skin.
Det drejer sig om 10 stoffer.
10 substances are in question.
Dertil kommer, at 13 stoffer er på EU's videnskabelige komite for kosmetiks liste over allergifremkaldende parfumestoffer.
In addition, 13 substances have been entered on the EU's scientific committee for cosmetics list of allergenic perfume substances.
Phenol er i den seneste liste over farlige stoffer blevet opklassificeret fra giftigt og ætsende i ren form til også at være ”Sundhedsfarligt ved længere tids påvirkning (R48)” og med ”Mulighed for varig skade på helbredet (R68)”.
On the most recent list of dangerous substances phenol has been upgraded from poisonous and caustic in pure condition to also being injurious to health during prolonged exposure (R48) and with possible permanent damage to health (R68).
Da stoffet forekommer i meget små mængder, vil disse akutte eller kroniske sundhedsmæssige effekter næppe komme til udtryk.
As the substance appears in very small amounts such acute or chronic health effects will hardly manifest themselves.
En række stoffer er klassificeret R22: Farlig ved indtagelse.
A number of substances are classified R22: Intake is dangerous.
Denne risikoangivelse betragtes som mindre væsentlig, da stofferne antages at forekomme i meget små mængder.
This risk specification is considered less essential as the substances are assumed to appear in very small quantities.
Som det fremgår af resultaterne fra søgning i INCI-listen, er 23 ud af de 28 stoffer optaget på listen.
As it appears from the results from the search on the INCI list, 23 out of the 28 substances have been entered on the list.
Stofferne Cantharidin og Lidocain er ikke optaget på INCI-listen og er ifølge kosmetikbekendtgørelsen forbudt.
The substances cantharides and lidocain have not been entered on the INCI list and according to the Statutory Order on cosmetics they are forbidden.
Dertil kommer en række stoffer, som er optaget i kosmetikbekendtgørelsens bilag 3 om begrænsninger og betingelser.
In addition, there are a number of substances that are entered on enclosure 3 of the Statutory Order on cosmetics concerning limitations and conditions.
Her findes 13 stoffer, for hvilke det kræves, at de deklareres, når de forekommer i en koncentration på over 0,001 % (10 µg/gram) i produkter, som ikke afrenses, og 0,01 % (100 µg/gram) i produkter, som afrenses.
13 substances exist that have to be labelled when they appear in concentrations exceeding 0.001 % (10 µg/gram) in products that are not washed off and 0.01 % (100 µg/gram) in products that are washed off.
3.1 Kvantitativ bestemmelse af flygtige og semiflygtige forbindelser
3.1 Quantitative determination of volatile and semi-volatile compounds
Der er anvendt samme analyseprincip som under den kvalitative screening, SPME kombineret med GC/MS. Der er dog i forbindelse med de kvantitative målinger anvendt en anden SPME-fiber med en større kapacitet.
The same analysis principle was used as in connection with qualitative screening, SPME combined with GC/MS. However, in connection with quantitative measurements another SPME fibre with greater capacity was used.
Anvendelsen af denne SPME-fiber var nødvendig for at kunne foretage kvantificeringen, hvilket dog samtidig har bevirket, at analysemetodens følsomhed er forringet i forhold til den anvendte metode under screeningen.
The application of this SPME fibre was necessary in order to carry out the quantification which simultaneously resulted in reduced sensitivity of the analysis method compared to the applied method during screening.
Disse forhold har bevirket, at enkelte komponenter, der kunne identificeres i forbindelse med den kvalitative undersøgelse, ikke kunne kvantificeres.
Due to these conditions, individual components identified in connection with the qualitative examination could not be quantified.
Der er foretaget kalibrering af metoden på 6 forskellige koncentrationsniveauer fra 0,1 til 50 µg pr. headspace-glas.
The method was calibrated at 6 different levels of concentration from 0.1 to 50 µg per headspace glass.
Prøven blev afvejet i et 20 ml membranglas.
The sample was weighed in a 20 ml membrane glass.
Der er afvejet forskellige mængder, afhængig af indholdet af organiske komponenter i de undersøgte produkter, fra 0,05 gram til 0,05 mg prøve pr. headspace-glas.
Different amounts were weighed depending on the content of organic components in the investigated products from 0.05 g to 0.05 mg sample per headspace glass.
Headspace blev samplet i 15 min. ved SPME og efterfølgende analyseret ved gaschromatografi med massespektrometrisk detektion (GC/MS).
Headspace was sampled for 15 min. at SPME and subsequently analysed at gas chromatography with mass spectrometric detection (GC/MS).
Ovn prog: 40 ºC i 1 min., 10 ºC/min. til 260 ºC hold i 2 min.
Oven prog: 40 ºC for 1 min., 10 ºC/min. to 260 ºC hold for 2 min.
Detektionsgrænse: 1 mg/kg. Analyseusikkerhed: 10-25 % RSD, afhængig af komponent.
The detection limit: 1 mg/kg. Analysis uncertainty: 10-25 % RSD, depending on component.
De i forbindelse med den udførte GC/MS-analyse kvantificerede indhold er gengivet i Tabel 3.1.
The quantified contents from the performed GC/MS analysis appear from Table 3.1.
Der gøres opmærksom på, at produkt nr. 24 alene er medtaget i den kvantitative måling, da det ikke kunne fremskaffes tidligere i projektforløbet.
Please note that product no. 24 merely was included in the quantitative measurement as it could not be procured earlier in the project.
Produktet består af 3 smagsvarianter (i samme pakning), hvoraf kun den ene variant er analyseret.
The product consists of 3 different flavours (in the same package) and only one variety was analysed.
Tabel 3.1 Resultater af GC/MS screeningen af sexcremer
Table 3.1 Results from GC/MS screening of pleasure gel
Prøvemærkning [mg/kg]
Sample marking [mg/kg]
”<1” betyder at indholdet er mindre end detektionsgrænsen for den anvendte analysemetode.
”<1” means that the content is less than the detection limit of the applied analysis method.
Tabel 3.1 fortsat - Resultater af GC/MS screeningen af sexcremer
Table 3.1 - continued - Results from GC/MS screening of pleasure gel
Komponent 1-Phenoxy propan-2-ol <1
Component 1-Phenoxy propan-2-ol <1
Komponent P-Propenyl anisol
Component P-Propenyl anisol
Detektionsgrænse: 1 mg/kg. Analyseusikkerhed: 10-25 % RSD, afhængig af komponent.
Detection limit: 1 mg/kg. Analysis uncertainty: 10-25 % RSD, depending on the component.
3.3 Prioritering af stoffer i sexcremer På baggrund af den gennemførte sundhedsmæssige screening samt den kvantitative analyse er der valgt en række stoffer ud til en videre sundhedsmæssig vurdering.
3.3 Order of priority of substances in pleasure gel In the light of the performed health screening and the quantitative analysis, a number of substances were chosen for additional health assessment.
Det er vurderet, at de mest interessante stoffer er:
It was estimated that the most interesting substances are:
Dertil kommer stoffer vurderet i forbindelse med kortlægningen i projektet af sportscremer, hvor følgende stoffer er relevante for sexcremer:
Furthermore, there are substances that were estimated in connection with the survey of sports creams and the following substances are relevant for pleasure gels:
• Camphor • α-Pinen.
• Camphor • α-Pinene.
Sexcreme er en særlig type produkt, og den gældende lovgivning for denne type produkt er ikke altid entydig.
The regulations governing special products such as pleasure gels etc. are not always obvious.
Produkterne er omfattet af lov om kemiske stoffer og produkter (LBK nr. 21 af 16/01/1996).
The products are regulated by the law on chemical substances and products (LBK nr. 21 af 16/01/1996 om kemiske stoffer og produkter).
Det betyder, at bekendtgørelsen om klassificering og mærkning af kemiske stoffer og produkter (Klassificering, 2005) regulerer sexcremer.
Due this the pleasure gels are also regulated by the general Statutory Order on classification and labelling of chemical substances and products (Klassificering, 2005).
4.2 Klassificering af produkter
4.2 Classification of products
I en vurdering af, hvilke produkter der burde klassificeres, er der kun medtaget stoffer, der er fundet i mængder på mere end 0,01 % (100 mg/kg).
In the assessment of which products should be classified only substances detected in more than 0.01 percent (100 mg/kg) have been considered.
I det følgende vises en tabel for hver af de 22 prøver.
A table for each of the 22 samples is shown below.
For de stoffer, som står på EU-listen over allergiske duftstoffer (SCCNFP, 1999), er angivet “potentiel R43”, og stoffet og virkningerne indgår i klassificeringen af produktet.
For substances included in the EU-list on allergic fragrances (SCCNFP, 1999) is stated “potential R43” and the substance and its effect are included in the classification for the product.
Tabel 4.1 Klassificering af sexcreme nummer 1
Table 4.1 Classification for Pleasure-gel number 1
Bekendtgørelse om kosmetiske produkter nr. 422 af 4 maj 2006.
Statutory Order on cosmetic products No.422 of 4 May, 2006.
For stoffer som ikke er på ”Listen over Farlige Stoffer” gælder det, at producenten skal lave en selvvurdering af stofferne.
For substances that are not included at ”the list of dangerous substances” it is required that the producers of products must perform an evaluation and selfclassification of the substances.
Hvis produktet indeholder mere end 1 % af stoffet, skal produktet fareklassificeres.
If the product contains mire the 1 % of the substance the product has to be classified.
Her er det vist, hvilke konsekvenser for deklareringen af parfumestoffer på produkterne, det ville have, hvis bekendtgørelsen om kosmetiske produkter var gældende for disse produkter.
Here it is described which requirements to labelling of content of perfume; the products were regulated by if covered by the Statutory Order on cosmetics.
De grundlæggende krav i kosmetikbekendtgørelsen er:
The basic requirements in the Statutory Order on cosmetics are:
• Nogle stoffer er forbudte; ingen af dem der blev undersøgt for, er fundet i de kvalitative analyser
• some substances are prohibited; none of the these which were analysis were identified in the qualitative analysis
• Nogle stoffer må bruges i begrænsede mængder; få stoffer i denne kategori er blevet identificeret
• some substances can be used in limited quantities; a few substances of this category have been identified
• Nogle stoffer, såsom parfume og aromatiske forbindelser, skal deklareres ved navn på emballagen, hvis indholdet er større end en bestemt grænseværdi.
• some substances like perfume and flavours must be declared by name on the package if the content exceeds the limit value.