natgillin/translations-raw huggingface dataset:
Produkternes indholdsdeklarationer eller leverandørbrugsanvisninger er blevet gennemgået med henblik på at identificere, hvilke akrylater, der indgår i akrylpulvere, - væsker, -geléer og lime.
The declaration list on the products or material safety data sheets from the suppliers have been reviewed to identify which acrylates are contained in acrylic powders, -liquids, - gels and glues.
Stofferne er blevet identificeret, og fremgår af tabel 3.7 nedenfor.
The substances have been identified and listed in table 3.7 below.
Urethan methakrylat oligomer
Urethane Methacrylate Oligomers
Ud over akrylaterne nævnt i tabel 3.7 er det oplyst i udleverede sikkerhedsdatablade eller på indholdsdeklarationer at følgende stoffer er indeholdt i akrylpulvere:
Besides the acrylates mentioned in table 3.7, it appears from safety data sheets or declaration lists available to us that the following substances are contained in acrylic powders:
Benzoylperoxid (polymeriserings initiator).
Benzoylperoxide (polymerisation initiator).
Pulverne kan også indeholde Silica (fyldstof) og Titanium Dioxide (pigment).
The powders may also contain silica (filler) and titanium dioxide (pigment).
Benzophenon (UV-filter), Dimethyltolylamin, Dimethylparatoluidin (katalysator), MeHQ (stabilisator)
Benzophenone (UV-filter), dimenthyltolylamine, dimethylparatoluidine (catalysator), MeHQ (stabilisator).
Hydroxycyclohexylphenylketon, Benzophenon (UV-filter), Benzoyl Isopropanol (polymeriserings initiator), Calcium Pantothenat (vitamin), Silica (fyldstof).
Hydroxycyclohexylphenylketone, benzophenone (UV-filter), benzoyl isopropanol (polymerisation initiator), calcium pantothenate (vitamin), silica (filler).
Pigmenter i form af blå eller violette farver kan være tilsat.
Pigments in the form of blue or violet colours may be added.
Boron Trifluorid (styrke), BHA (antioxidant), Citronsyre (pH-regulator), 2Bromo-2-Nitropropane-1,3-Diol (konserveringsmiddel), Hydroquinon (stabilisator), Silikat (fyldstof), Alkohol (opløsningsmiddel), Svovldioxid.
Boron trifluoride (strength), BHA (antioxidant), citric acid (pH-regulator), 2bromo-2-nitropropane-1,3-diol (preservative), hydroquinone (stabilisator), silica (filler), alcohol (solvent), sulfur dioxide.
Stofferne er tilsat i mængder under 1 %, og fungerer som katalysatorer og stabilisatorer i polymeriseringsprocessen.
The substances are added in amounts below 1% and act as catalysators and stabilisators in the polymerisation process.
Restindholdet i den kunstige negl forventes derfor at være yderst begrænset.
The remainder in the artificial nail is therefore expected to be extremely limited.
I samråd med Miljøstyrelsen blev det besluttet hvilke stoffer, der skulle analyseres for, i de pågældende produkter (se afsnit 4).
In cooperation with the Danish Environmental Protection Agency, it was determined which substances to analyse for in the products concerned (See Chapter 4).
4.1 Kvantitativ bestemmelse af formaldehyd i neglehærdere
4.1 Quantification of formaldehyde in nail hardeners
Efter samråd med Miljøstyrelsen blev der udvalgt en række neglehærdere til analyse for indhold af formaldehyd.
In cooperation with the Danish Environmental Protection Agency, a number of nail hardeners were selected to be analysed for content of formaldehyde.
Seks af de syv indkøbte neglehærdere blev analyseret.
Six of the seven purchased nail hardeners were analysed.
4.1.1 Analysemetode for kvantitativ GC-MS metode
4.1.1 Quantitative GC-MS method of analysis
Inden prøvens forsegling brydes, rystes prøven grundigt.
Before breaking the sealing of the sample, the sample is heavily shaken.
Målekolben fyldes til mærket med dichlormethan.
The measuring flask is filled up to the marking dicloromethane.
Prøverne opløses/ekstraheres over en periode på 2 timer.
The samples are dissolved/extracted during a period of approx. 2 hours.
Efter endt ekstraktion/opløsning overføres en delmængde af dichlormethanfasen til GCvial, hvorefter den er klar til analyse.
After extraction/dissolution, part of the dichlormethane phase is transferred to GCvial, whereupon it is ready for analysis.
Ved meget tyktflydende ekstrakter fortyndes prøven passende inden analyse (typisk 10*).
In connection with very viscuous extracts, the sample is appropriately diluted before analysis (typical 10*).
Der fortyndes med den samme dichlormethan, som der er anvendt til analysen.
The dichloromethane used for the analyses is also used to dilute the sample.
De to produkter med de laveste fundne indhold af formaldehyd (produkt 9 og 20) har ikke deklareret indholdet af formaldehyd på produktet.
The formaldehyde of the two products with the lowest content of formaldehyde (product no. 9 and 20) has not been declared.
Det angivne indhold er gennemsnittet af dobbeltbestemmelsen.
The indicated content is the average of the double determination.
Afvigelsen imellem de to bestemmelser varierer mindre end 3 % for alle prøver på nær for produktidentifikation 20, der varierer 9 %.
The difference between the two determinations varies less than 3% for all samples except for product identification 20 that varies 9%.
Derudover er der angivet for hvert produkt om de har deklareret formaldehyd (√) eller ej (-).
Besides it is indicated for each product if formaldehyde is declared (√) or not (-).
Efter samråd med Miljøstyrelsen blev der udvalgt en række negleprodukter til analyse for indhold af forskellige akrylforbindelser.
In cooperation with the Environmental Protection Agency, a number of nail products were selected for analysis of content of different acrylic compounds.
Produkterne blev udvalgt indenfor kategorierne gelnegle, akrylpulvere til opbygning af akrylnegle samt væsker der også anvendes ved dannelse af akrylnegle (se afsnit 3).
The products were selected within the categories gel nails, acrylic powders for building up acrylic nails and liquids that are also applied for formation of acrylic nails (see Chapter 3).
Polymerer er sundhedsmæssigt ikke specielt interessante da disse betragtes som værende af lav toksicitet på grund af deres store størrelse.
In accordance with the safety data sheets, the artificial nail products contain different forms of polymers.
Derfor fokuseres der på monomererne i analyserne, for at anskueliggøre niveauerne af monomerer i de forskellige produkter.
On the other hand, polymers may contain small amounts of monomers (the starting material of the polymers) that may have a high toxicity.
Det angivne indhold er gennemsnittet af en dobbeltbestemmelse.
The indicated content is the average of a double determination.
(-) angiver at stoffet er under detektionsgrænsen på 0,001 %
(-) indicates that the substance is below the detection limit of 0.001%.
Analyserne for akrylforbindelser viser, at produkterne til fremstilling af kunstige negle (akrylnegle og gelnegle) kun i begrænsende mængder indeholder de testede forbindelser.
The analyses for acrylic compounds show that the amount of tested compounds contained in the products for production of artificial nails (acrylic nails and gel nails) is limited.
Generelt kan man se, at produkterne til dannelse af gelnegle indeholder flere af de testede akrylforbindelser.
Generally, it can be seen that the products for formation of gel nails contain several of the tested acrylic compounds.
Analysen viser, at produkterne til fremstilling af gelnegle generelt indeholder stoffet 2-Hydroxyethylakrylat i højeste koncentrationer (3 - 8 %) og kun et produkt ud af syv testede indeholder ikke stoffet (tabel 4.2).
The analysis shows that the products for manufacture of gel nails generally contain the substance 2-hydroxyethyl acrylate in the highest concentrations (3-8%) and only one product out of seven tested does not contain the substance (table 4.2).
Dette produkt (produktnummer 17) indeholder så i modsætning til de andre produkter mest 2-hydroxypropylmethakrylat.
Unlike the other products, this product (product number 17) contains mainly 2-hydroxypropyl methacrylate.
De andre testede akrylforbindelser findes kun i små mængder (< 0,8 %) i de testede produkter.
The other tested acrylic compounds are only found in small amounts (< 0.8%) in the tested products.
I pulverne til fremstilling af akrylnegle er der ikke fundet nogle af de testede akrylforbindelser med undtagelse af et lille fund af ethylendimethakrylat i produkt nummer 25 (0,015 %) (tabel 4.3).
Except for a small amount of ethylene dimethacrylate found in product no. 25 (0.015%) (table 4.3), none of the tested acrylate compounds were found in the powders for manufacture of acrylic nails.
Dette er en smule overraskende, men kan muligvis forklares ved, at indholdet i denne type produkter hovedsageligt er polymerer, mens indholdet af monomerer i produkterne er lavt.
This is somewhat surprising but the reason may be that the content of this type of products are mainly polymers, whereas the content of monomers in the products are low.
I væskerne, der sammen med pulverne anvendes til fremstilling af akrylnegle, varierer mængde og type af akrylforbindelse en del mellem produkterne.
In the liquids which together with the powders are used for manufacture of acrylic nails, the amount and type of acrylic compounds vary to some extent between the products.
Ifølge sikkerhedsdatablade (MSDS) på et par af produkterne fremgår det, at denne type produkt ofte indeholder en ret stor mængde af ethylmethakrylat (op til 80 %).
From the Safety Data Sheets for a couple of the products it appears that this type of product often contains quite a considerable amount of ethyl methacrylate (up to 80%).
Et formodet indhold af ethylmethakrylat blev også set i screeningen (afsnit 4.3.2 - tabel 4.5).
An assumed content of ethyl methacrylate was also identified during the screening (Chapter 4.3.2 - table 4.5).
4.3 Screening for indholdsstoffer i produkter til fremstilling afkunstige negle
4.3 Screening for ingredients in products for manufacture of artificial nails
De kvantitative analyser for akrylforbindelser viste, at negleprodukterne i høj grad må indeholde andre indholdsstoffer end monomerer af de analyserede 6 akrylforbindelser idet der ved GC-MS analysen viste sig mange andre toppe i massespektrene end de 6 akrylforbindelser.
The quantitative analyses for acrylic compounds showed that it is very obvious that the nail products contain other ingredients than the analysed 6 acrylic compounds due to the fact that the GC-MS analysis showed many other peaks in the mass spectres than the 6 acrylic compounds.
Derfor blev det besluttet at lave en screeningsundersøgelse (GC-MS-SCAN) af de indholdsstoffer, som fremgik med de højeste toppe i GC-MS på baggrund af de kvantitative analyser.
Consequently it was decided to perform a screening (GC-MS-SCAN) of the ingredients that appeared with the highest peasks in GC-MS based on the quantitative analyses.
Hermed kan man med rimelig sandsynlighed gætte på produkternes indholdsstoffer for de højeste toppe.
With a reasonable probability it will be possible by this method to assume the ingredients of the highest peaks.
En kendt prøvemængde opløses/ekstraheres med dichlormethan.
A well-known amount of sample is diluted/extracted with dichlormethane.
Ekstraktet analyseres på GC-MS-SCAN.
The extract is analysed using the GC-MS-SCAN.
Ved analysen optages massespektrene for de stoffer, der er i prøven.
During the analysis the mass- spectres of the substances contained in the sample are absorbed.
Forskellige stoffer har forskellige massespektre, dog kan isomerer (for eksempel xylener) have (næsten) identiske massespektre.
Different substances have different mass-spectres; however isomers (for instance xylenes) may have (almost) identical mass-spectres.
De optagne massespektre sammenlignes med massespektrene i et bibliotek indeholdende over 100.000 massespektre.
The absorbed mass-spectres can be compared with the mass-spectres in a library containing more than 100,000 mass-spectres.
Ud fra overensstemmelsen mellem det optagne spektrum og bibliotekets spektrum fremkommer et bud på, hvilket stof, der kan være tale om.
Based on the congruity between the absorbed spectres and the spectres of the library, the possible substance is suggested.
Biblioteket kommer ligeledes med en kvalitetsvurdering af buddet.
Also the library shows a quality assessment of the suggested substance.
Denne angives som et tal mellem 0 og 100.
This is indicated as a number between 0 and 100.
Jo tættere på 100 jo bedre er overensstemmelsen, og jo større er sandsynligheden for, at ”gættet” er rigtigt.
The closer to 100 the better is the congruity, and the greater the probability that the suggestion is correct.
Det er laboratoriets erfaring, at bud med en kvalitet over 80 som oftest er rigtige.
The laboratory has experienced that suggestions of a quality above 80 are often correct.
Det skal dog understreges, at det ikke kan bekræftes som en endelig verifikation, før der er analyseret en standard indeholdende det stof, der bliver gættet på.
However it should be emphasized that it cannot be finally verified, until a standard containing the suggested substance has been analysed.
Tabel 4.4 og 4.5 viser, hvilke komponenter, der ved GC-MS-SCAN er blevet identificeret ved hjælp af bibliotekssøgning.
Table 4.4 and 4.5 show the components that have been suggested using GCMS-SCAN through library search.
Antallet af identificerede komponenter varierer fra 1 til 6.
The number of suggested components varies from 1 to 6.
Tabellerne er IKKE et udtryk for det totale antal komponenter i produkterne, tværtimod vurderes det, at der i langt de fleste produkter er mellem 50 og 100 komponenter.
The tables do NOT reflect the complete number of components in the products, on the contrary it is estimated that by far the most products contain between 50 and 100 components.
21 produkter til anvendelse i forbindelse med opbygning af kunstige negle (akrylnegle og gelnegle) blev screenet for indholdsstoffer.
21 products to be applied for artificial nails (acrylic nails and gel nails) were screened for ingredients.
For hvert produkt er der screenet for de indholdsstoffer, som gav de højeste toppe ved de kvantitative GC-MS analyser for akrylforbindelser.
Each product has been screened for the ingredients showing the highest peaks during the quantitative GC-MS analyses for acrylic compounds.
Azobenzen eller Benzophenon
Azobenzene or Benzophenone
2-Butenoic acid, methyl ester
2-Butenoic acid, ethyl ester
Analysens detektionsgrænse var på 0,01 %.
The detection limit of the analysis amounted to 0.01%.
Produkterne skal være mærket med følgende på beholder og emballage:
The products must be labelled as follows on box and packing.
♦ Firmanavn og adresse eller hovedsæde for den virksomhed der er ansvarlig for markedsføringen af produktet.
• Name of company and address or head office of the company responsible for marketing the product.
♦ Vægt/volumen af produktet.
• Weight/volume of the product
♦ Holdbarhedsdato, hvis holdbarhed for produktet i uåbnet stand er mindre end 30 måneder.
• Expiry date, if validity of the product unopened is less than 30 months.
♦ Med holdbarhed over 30 måneder, angives holdbarhed efter åbning med angivelse af symbol for åben dåse.
• If the validity is more than 30 months, validity after opening with indication of symbol for open box is indicated.
♦ Sikkerhedsforskrifter for hvordan kunden bruger kosmetikken rigtigtherunder særlige hensyn for kosmetiske produkter, som bruges til erhverv.
• Safety declarations for correct use of the cosmetic product - including special considerations with respect to cosmetic products used professionally.
♦ Fabrikationsseriens nummer (batchnummer), evt. kun på beholder.
• The manufacturing number (batch number), possibly only on box.
Ingredienser skal opgives med INCI (International Nomenclature of Cosmetic Ingredients) navn og listes efter aftagende vægt i produktet.
The ingredients must be stated with INCI (International Nomenclature of Cosmetic Ingredients) name and listed by decreasing weight in the product.
♦ Parfumerende og aromatiske forbindelser og deres råmaterialer skal stå som "parfume" eller "aroma".
• Scenting and aromatic compounds and their raw materials must be named “perfume” or “aroma”.
De indkøbte produkter er gennemgået for eventuelle mangler i mærkningen.
The purchased products have been reviewed for possible lack of labelling.
Generelt kunne der konstateres mange mangler i mærkningen, især ved akrylprodukterne til fremstilling af kunstige negle.
Generally, the labelling showed many discrepancies, especially the acrylic artificial nail products.
For de indkøbte produkter går følgende forhold igen som mangler på mange af produkterne:
The following discrepancies were recurred on many of the purchased products.
For flere af produkterne var funktionen af produktet ikke klar, og indholdsdeklarationen fulgte ikke reglerne i kosmetikbekendtgørelsen.
The functioning of most of the products was unclear, and the list of ingredients did not comply with the rules in the Statutory Order on Cosmetic
neglehærdere blev der konstateret færre mangler i mærkningen i forhold til produkter til opbygning af kunstige negle.
In the labelling of the nail hardeners were observed fewer discrepancies than in that of artificial nails.
Klassificeringen af indholdsstoffer i de indkøbte og analyserede negleprodukter er undersøgt i henhold til kemikalielovgivningen og kravene i forhold til kosmetiklovgivningen.
The classification of ingredients in the purchased and analysed nail products has been investigated in accordance with the chemicals legislation and the demands stipulated in the cosmetics legislation.
Det er vigtigt at pointere at denne klassificering gælder for produkter markedsført under kemikalielovgivningen og ikke for kosmetik.
It is important to emphasize that this classification applies to products that are marketed in accordance with the chemicals legislation and not the cosmetics legislation.
Klassificeringen kan dog give gode indikationer for, om produkterne indeholder sundhedsfarlige stoffer.
However, the classification may indicate if the products contain hazardous substances.
Lime til påsætning af kunstige negle tilhører et såkaldt ”borderline” område, hvilket betyder, at de enten klassificeres som kosmetik eller som kemiske produkter afhængigt af produktets formål, anvendelse og hvordan det præsenteres for forbrugerne.
Glues for fixing artificial nails belong under a so-called “borderline” area meaning that they are either classified as cosmetic products or as chemical products depending on the purpose, the application, and how the product is presented to the consumer.
5.2.1 Klassificering af formaldehyd
5.2.1 Classification of formaldehyde
Formaldehyd indeholdes i neglehærdere som set i analyserne udført på 6 forskellige neglehærdere på det danske marked.
The content of formaldehyde in the nail hardeners is shown in the analyses of 6 different nail hardeners on the Danish market.
Tilladt i neglehærdere op til 5 %
Permitted in nail hardeners up to 5%
Ifølge kosmetikbekendtgørelsen (1) må neglehærdere indeholde op til 5 % total formaldehyd.
In accordance with the Statutory Order on Cosmetic Products (1), the allowed content of formaldehyde in nail hardeners is up to 5% total formaldehyde.
Derudover skal alle færdige produkter, der indeholder formaldehyd eller stoffer, der kan fraspaltes formaldehyd (se afsnit 3.4.2), være forsynet med teksten: »Indeholder formaldehyd«, på etiketten såfremt koncentrationen af formaldehyd i det færdige produkt overstiger 0,05 %.
In addition, all final products containing formaldehyde or substances from which formaldehyde can be decomposed (see Chapter 3.4.2) can be labelled with the text “contains formaldehyde”, if the concentration of formaldehyde in the final product exceeds 0.05%.
Hvis formaldehyd er tilsat som konserveringsmiddel er den tilladte koncentration max. 0,2 %.
If formaldehyde has been added as a preservative, the maximum permitted concentration is 0.2%.
5.2.2 Klassificering af akrylforbindelser
5.2.2 Classification of acrylic compounds
Akrylforbindelser findes i et udvalg af produkter til fremstilling af kunstige negle indkøbt på det danske marked.
Acrylic compounds are found in a selection of products for manufacture of artificial nails purchased on the Danish market.
5.2.3 Klassificering af screenede indholdsstoffer i produkter til fremstilling af kunstige negle
5.2.3 Classification of screened ingredients in products for manufacture of artificial nails
Der er søgt oplysninger for de fundne indholdsstoffers klassificering.
Information of the classification of the identified ingredients has been searched.
Disse oplysninger er søgt i Listen over farlige stoffer samt i Miljøstyrelsens vejledende liste til selvklassificering.
This information has been searched in the List of Hazardous Substances and in the consultative list for self classification of the Danish Environmental Protection Agency.
De data, der er hentet fra den vejledende liste, er mærket med '*'.
The data collected from the consultative list are marked with ‘*'.
Data hentet fra Miljøstyrelsens vejledende liste til selvklassificering er mærket med '*'.
Data are collected from the consultative list of the Danish Environmental Protection Agency marked with ‘*'.
Yderlig er der fundet data vedrørende indholdsstoffernes tilladelse til brug i kosmetiske produkter.
Also, data on the permitted use of the ingredients in cosmetic products have been identified
Kosmetikbekg. og andet
Statutory Order on Cosmetic Products
T;R23/24/25 R33 R52/53 (konc > 25%)
T;R23/24/25 R33 R52/53 (conc > 25%)
Data fra vejledende liste til selvklassificering
Data from guide for self classification
Flere af stofferne findes formentlig i produkterne som urenheder.
Ingredients are actively added substances that must be declared on the packing.
I kosmetiske produkter skelnes mellem ingredienser og urenheder.
The substances to be added legally, and in which the concentrations
Sådanne urenheder skal ikke deklareres, men bør dog så vidt muligt undgås, og det er altid producentens ansvar, at det færdige produkt ikke er til skade for menneskets sundhed.
Such impurities are not to be declared, however they should be avoided, and it is always the responsibility of the producer to ensure that the final product is not hazardous to human health.
Der er udført sundhedsvurderinger på formaldehyd fundet i neglehærdere samt på 2-hydroxyethylakrylat, 2 hydroxypropylakrylat, 2- hydroxypropyldimetakrylat og ethylendimetakrylat fundet i kunstige negleprodukter.
Safety assessments were performed on formaldehyde found in nail hardeners, and 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, 2-hydroxypropyl dimethacrylate and ethylene dimethacrylate found in artificial nail products.
Stoffernes toksikologiske effekt er beskrevet, herunder stoffernes evne til at inducere allergi.
The toxicological effects of the substances are described, including the ability of the substances to induce allergy.
Denne effekt anses for at være den mest kritiske på basis af den megen litteratur, der beskriver allergi efter brug af neglehærdere og/eller kunstige negle.
This effect is considered to be the most critical effect due to the amount of literature describing contact allergy after use of nail hardeners and/or artificial nails.
Når der var tilgængelige data, blev en NO(A)EL
When data were available, a NO(A)EL
for stoffernes kritiske effekt fastsat.
for the critical effect of the substances has been established.
NO(A)EL værdien anvendes i forbindelse med eksponeringsscenarier og risikovurderingerne i kapitel 7.
The NO(A)EL value is applied in Chapter 7 on exposure scenarios and risk assessments of the products.
6.1 Sundhedsvurdering af stoffer i neglehærdere
6.1 Safety assessment of substances in nail hardeners
Formaldehyd er en farveløs, brændbar reaktiv og let polymeriserende gas ved normal temperatur og tryk.
Formaldehyde is a colourless, flammable, reactive and readily polymerising gas at normal temperature and pressure.
Stoffet har en stram irriterende lugt (2).
It is a gas with a pungent, irritating odour (2).
Formaldehyd er en normal metabolit i pattedyrs organismer.
Formaldehyde is a normal metabolite in mammalian organisms.
Den kan dannes fra visse xenobiotiske eller endogene forbindelser, f.eks. aminosyrer (3).
It can be generated by the metabolism of certain xenobiotics or endogenous compounds, such as amino acids (3).