1794 – 1795 Charles Lee 1795 – 1797 Postmaster General Samuel Osgood 1789 – 1791 Timothy Pickering 1791 – 1795 Joseph Habersham 1795 – 1797 Portrait by Gilbert Stuart , 1795. Added by PhloxBot The Electoral College elected Washington unanimously in 1789 , and again in the 1792 election ; he remains the only president to receive 100% of electoral votes. John