MODOK ,  Mole Man . S.H.I.E.L.D. appears in  The Avengers: Earth's Mightiest Heroes , where members  Maria Hill ,  Clay Quartermain ,  Jimmy Woo  and  Nick Fury  are named agents who also appear. [ citation needed ] [ edit ] Films In 1998 there was a  Nick Fury: Agent of S.H.I.E.L.D.  TV