Kjeldahl flask
date: label: date made
content: after 1884
name: label: maker
content: Jena Glasswork, Schott & Associates
notes: label: Description
content: This 100 mL Kjeldahl flask was made by Schott & Genossen. In 1883 Danish chemist Johan Kjeldahl (1849–1900) of the Carlsberg Laboratory published the Kjeldahl method. It was the first accurate, simple, and speedy way to determine nitrogen content in organic matter.
label: Description
content: Kjeldahl’s employer, Carlsberg Laboratory, had been originally established as a place for scientific research to perfect the process of beer making. Later, the laboratory took on a broader mission to contribute to pure research. The need for the Kjeldahl method grew from his analysis of the protein content of grains for beers at different stages—from germination to fermentation as beer wort. Analyses of nitrogen content can be used to quantify the amount of protein in a sample, and protein content of grains influences the volume of beer they produce.
label: Description
content: The Kjeldahl method proved to have wide-ranging applications and was quickly adopted by scientists from a variety of fields. In the mid-2010s, the method (with minor modifications) was still in use for purposes ranging from analysis of protein in foods to nitrogen content in soil samples. To “Kjeldahl” a sample has become a verb in chemical parlance, considered by some the greatest honor bestowed by the chemical community.
label: Description
content: Along with his method, Kjeldahl’s name also became attached to a piece of laboratory equipment he developed in 1888. The long-necked, round-bottomed flask was ideal for avoiding splashback when heating solutions. Splashback was a threat during the first step of the Kjeldahl method—which requires heating the sample in concentrated sulfuric acid.
label: Description
content: Glastechnisches Laboratorium Schott und Genossen (Glass Technology Laboratory, Schott & Associates), later the Jenaer Glasswerk Schott & Gen. (Jena Glassworks, Schott & Associates), was founded in 1884 by Otto Schott (1851–1935), Ernst Abbe (1840–1905), Carl Zeiss (1816–1888), and Zeiss' son Roderick.
label: Description
content: In 1881 Schott, a chemist from a family of glassmakers, and Abbe, a physicist with an interest in optics, formed a research partnership. Together they hoped to perfect a chemical glass formula for lenses in optical instruments like microscopes and telescopes. Their original goal was to develop glasses of high quality and purity with consistent optical properties. As their research expanded, they eventually developed the first borosilicate glasses. Their strength against chemical attack and low coefficient of thermal expansion made them better suited to the harsh circumstances of the chemical laboratory than any other glass.
label: Description
content: Jena Glass quickly became a success among the scientific community, widely considered the best on the market until World War I.
label: Description
content: This object is part of a collection donated by Barbara Keppel, wife of C. Robert Keppel. Robert Keppel taught at the University of Nebraska-Omaha after receiving his B.S. in Chemistry from the University of California, Berkeley, and his Ph.D. in organic chemistry from M.I.T. The glassware in the Keppel collection covers the 19th and early 20th centuries.
label: Description
content: Sources:
label: Description
content: Baker, Ray Stannard. Seen in Germany. Chautauqua, N. Y.: 1908. http://hdl.handle.net/2027/nyp.33433043165608.
label: Description
content: Burns, D. Thorburn, and W. I. Stephen. “Kjeldahl Centenary Meeting.” Analytical Proceedings 21, no. 6 (1984): 210–20. doi:10.1039/AP9842100210.
label: Description
content: Cauwood, J.D., and W.E.S. Turner. “The Attack of Chemical Reagents on Glass Surfaces, and a Comparison of Different Types of Chemical Glassware.” Journal of the Society of Glass Technology 1 (1917): 153–62.
label: Description
content: Hovestadt, Heinrich. Jena Glass and Its Scientific and Industrial Applications. London, New York: Macmillan, 1902.
label: Description
content: National Museum of American History Accession File #1985.0311
label: Description
content: Pfaender, H. G. Schott Guide to Glass. Springer Science & Business Media, 2012.
label: Description
content: Sáez-Plaza, Purificación, Tadeusz Michałowski, María José Navas, Agustín García Asuero, and Sławomir Wybraniec. “An Overview of the Kjeldahl Method of Nitrogen Determination. Part I. Early History, Chemistry of the Procedure, and Titrimetric Finish.” Critical Reviews in Analytical Chemistry 43, no. 4 (2013): 178–223. doi:10.1080/10408347.2012.751786.
label: Description
content: Sella, Andrea. 2008. “Classic Kit: Kjeldahl Flask.” Chemistry World. http://www.rsc.org/chemistryworld/Issues/2008/May/KjeldahlFlask.asp.
label: Description
content: “University of Nebraska Omaha.” 2015. Accessed May 4. http://www.unomaha.edu/college-of-arts-and-sciences/chemistry/student-opportunities/scholarships.php.
label: Description
content: Walker, Percy H. Comparative Tests of Chemical Glassware. Washington, D.C.: 1918. http://hdl.handle.net/2027/mdp.39015086545707.
label: Location
content: Currently not on view
topic: label: Subject
content: Science & Scientific Instruments
setName: label: See more items in
content: Medicine and Science: Chemistry
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content: Science Under Glass
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content: Science & Mathematics
creditLine: label: Credit Line
content: Gift of Barbara A. Keppel
dataSource: label: Data Source
content: National Museum of American History
identifier: label: ID Number
content: 1985.0311.049
label: catalog number
content: 1985.0311.049
label: accession number
content: 1985.0311
objectType: label: Object Name
content: flask, Kjeldahl
label: Object Name
content: flask, kjeldahl
physicalDescription: label: Physical Description
content: glass (overall material)
label: Measurements
content: overall: 22.9 cm x 1.125 cm; 9 in x 7/16 in
label: Measurements
content: overall: 9 in x 2 3/16 in; 22.86 cm x 5.55625 cm