Yes, you can. However, it would be highly impractical considering the size of the file and the 424kbps bit rate of NFC. The 424kbps bit rate allows you to transfer 53KB per second. A 100MB is about 102400KB, meaning sharing such a file will take slightly over 32 minutes. Using Bluetooth, you can transfer the file in a fraction of the time, depending on your Bluetooth version.