Yes. There is a range of electric and hybrid vehicles available on the Motability scheme however, it is certainly worth considering the two following points before deciding on a vehicle of this fuel type.
Charging the vehicle: In order to refuel at home, you will need to have an electric-charging point installed at your house. This will require either an off-road car parking space, a driveway, or a garage.
The range of the vehicle: Different cars have different ranges, dependent on the size of the battery. Therefore, before deciding on which car suits you, you should check whether it will cater to your requirements and day-to-day life.