No. You cannot do this. One reason is because if you were able to bet either red or black, you would win 50% of the time. There isn’t any game in a casino that has that kind of advantage for players.It could be disastrous to the business of a casino to allow you to have a 50% shot of winning, especially if you place a large bet. This is similar to betting on a coin flip. It’s not ideal from the casinos’ perspective.