The 10 most expensive perfumes in the world: Parfum VI by Gianni Vive Sulman: $89,000. 1 million, LUXE edition by Paco Rabanne: $57,000. Les Larmes Sacrées de Thebes by Baccarat: $6,800. Le N°5 Parfum Grand Extrait by Chanel: $3,500. Poivre by Caron: $1,000. Joy by Jean Patou: $850. More items...