The short answer to this is no, but the longer answer is that it kind of depends a little bit! Specifically it depends on practicing. Clicking your clipless cleats into and off of the pedals is, obviously, not as easy as simply lifting your feet off of a standard pedal.
It require a sideways twisting motion that you need to get into the habit of doing to disconnect your feet from the pedals. At the same time, you also need to practice when to remove your cleats from their connection. After a while, you will begin to easily notice hazards in front of you – stop signals or red lights for example – and know to release your feet or foot in plenty of time to support you and the bike when you stop.