Yep! It is 100% safe to bake frozen meat without defrosting, per the USDA Food Inspection and Safety department. They say it may take up to one and a half times longer to cook (Source: USDA). It may take a bit longer, but cooking frozen pork chops is super easy! Just rub pork chops with a spice rub or dry rub and bake until the internal temperature of the chops reaches 145°F. Easy breezy!