It is implied that you can do this on the Global Transfer page, as phone numbers are listed for both personal and business card teams. However, when applying online for business American Express cards, I did not see an option to initiate the Global Transfer. If anyone has insights into this question, data points would be appreciated. Leave a comment on your experience!  Regardless, we would generally recommend you get a personal credit card first if this is your first US credit card, as you want to build your credit history. Business cards are not reported to bureaus for this purpose.