Absolutely! In fact, this is the best way to melt chocolate. However, the microwave is a quicker solution. To use the double boiler method, you don’t need a double boiler. Simply fill a bigger pot with 2” of water, and then place a smaller pot on top with your chocolate. Simmer the pot of water until the chocolate is melted. The steam from the water stays trapped between the two pots which heats the chocolate in the top pot.