Yes, Xulane and the Ortho Evra patch are different versions, or generics, of the same birth control. That means they contain the same active ingredients and work in the same way (though Xulane has a slightly higher estrogen content). Generic versions of medications are all thoroughly tested, so you know they are safe to use.
Ortho Evra is currently discontinued, so Xulane is a good choice if you were previously prescribed Ortho Evra and liked it.