The answer for this question is multifaceted and should be discussed with a breastfeeding specialist. Breastmilk has come to be known as "liquid gold" because mothers produce milk that's uniquely formulated to meet their baby's specific needs. So typically, when moms know they're going to wean the baby from breastfeeding (or supplementing). It's happening on an announced and planned out timeline and not all of a sudden like you mention in your question.
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There are a number of possible reasons a baby might scream or breast refusal when fed. Of course it can be because the baby is hungry and needs food to eat. But it can also be because the child doesn't like being in your arms or sitting up. In addition, if there is something in the breast milk that causes discomfort for your toddler. Then he or she will react accordingly when attempting to feed from your breast.