Yes. You can freeze unbaked cinnamon rolls and then let them thaw overnight in the fridge when you want to make them and allow them to double in size before baking. You can also bake your cinnamon rolls, cool them completely and then freeze them. Place the individual frozen rolls in a freezer-safe, air-tight bag and then remove as needed, popping them in the microwave for 1-2 minutes and glazing just before eating.