At Starbucks, an affogato means something else entirely. In place of Espresso being poured over gelato, an affogato is an espresso shot poured over any beverage, most commonly a Frappuccino. Ask for an affogato-style espresso shot if you want a drink with an espresso shot on top but not blended in. A shot of Espresso will be poured on top after the drink has been prepared. In addition to the Frappuccinos listed above, you can order them on any Frappuccino.