Yes, but only if their country is in the same region because Valorant bars cross-region play. Valorant’s regions are Southeast Asia/Asia-Pacific (AP), Europe (EU), Korea (KR), Brazil (BR), Latin America (LATAM), and North America (NA). Your Valorant account is automatically assigned to one of these regions based on your physical location at the time of creation.
The easiest way to play Valorant with someone from a different region is with a VPN. With a VPN, you can spoof your physical location and create a Valorant account assigned to a region that you don’t reside in — just follow this short and simple guide. I recommend using ExpressVPN as it’s easy to use, has servers in 90+ countries, is very secure, and is the fastest VPN on the market, allowing you to maintain low ping while gaming.