The answer is: it depends.
Just because you don't currently have a job, it doesn't mean you are automatically going to get rejected from a life insurance policy. While it is one of many factors that an insurer will consider with your application, it's not the only factor.
Depending on your situation, your insurer might review your application more rigorously than it would if you were fully employed. So, if you are out of work and applying for life insurance, prepare for a longer process during which you may be asked more questions than if you were still employed.