No. Klopp can get as angry as he wants but he still won’t win you your booking points bet. Most, if not all, of the bookies offering booking points markets point out that only cards shown during ‘active play’ in the regulation 90 minutes plus injury time count towards the total score. That means that the following do not count:
Cards shown to managers/non-playing staff
Cards shown to substitutes off the pitch
Cards shown after the half-time or full-time whistle
Cards shown during extra time or penalties