If you were doing work at the time of the accident, yes. Of course, you will need to report the accident to your supervisor as soon as possible. In some cases, your supervisor may try to talk you out of pursuing workers’ compensation, but you need to get your medical bills and lost wages paid. If your boss threatens you or suggests that filing a workers’ comp claim might have a negative impact on your employment status, contact a workers’ compensation attorney as soon as you leave work.
If you were driving a company vehicle off the clock, you will not be eligible for workers’ compensation. You can seek compensation from the other driver or their insurer if they were at fault. If they were not at fault, you may be able to go through your own insurance company depending on what kind of coverage you have.