What time you can buy alcohol at u003ca href=u0022https://www.safeway.comu0022u003eSafewayu003c/au003e varies based upon state regulations. Wine and other alcoholic beverages usually can only be purchased within a set number of hours. In California, one of the most popular states for Safeway, customers can typically buy wine between 6 am and 2 am, Sundays included. You have to check with your state to see what guidelines exist, but the hours are pretty expansive.