The boiling point of pure water is \\\\(100^{\\circ}C\\\\) at \\\\(1 atm\\\\). The freezing point of pure water is \\\\(O^{\\circ}C\\\\). The sample of water under study boils at \\\\(102^{\\circ}C\\\\) at normal pressure. Hence, the sample is not pure water. Since the sample of water is not pure, it will not freeze at \\\\(O^{\\circ}C\\\\). It will freeze at a temperature below \\\\(O^{\\circ}C\\\\).