Azula plays a significant role as an antagonist to Team Avatar. She is sent on a mission by Fire Lord Ozai to capture her brother, Zuko, and her uncle, Iroh. In the process, she forms a small and elite team with her closest friends, Mai and Ty Lee. Upon encountering Team Avatar, they establish them as a prime target. Azula's presence is a constant threat to the team, leading to several confrontations.