On-page SEO best practices in copywriting include creating SEO-friendly URLs that incorporate relevant keywords, optimizing heading tags (H1, H2, etc.) to structure content and incorporate keywords naturally, enhancing readability through the use of subheadings, bullet points, and clear paragraphs, and optimizing images with descriptive alt tags and appropriate file sizes. It's also important to ensure mobile responsiveness, proper URL structure, and incorporate engaging multimedia elements. By following these practices, SEO copywriters can improve search engine understanding of content and enhance the user experience.