No, the Cadillac XT6 does not have captain's chairs. Instead, it has two bucket seats in the first row, three-passenger bench seating in the second, and an additional two seats in its third row. In total, the XT6 can accommodate up to seven occupants, the same as many SUVs with captain's chairs, but this Cadillac SUV makes the most of its interior with its smart seven-passenger seating.