No, Xylene does not remove paint from a surface. In fact, Xylene is a complex compound and does not react with paint in any way. In case you are wondering, Xylene is a derivative of benzene, and is a common solvent and component of different products ranging from paint remover to detergent. It is important to note that Xylene is sometimes used as a substitute for paint remover. However, it is not actually a paint remover. It can, however, be used to clean paint brushes and rollers after a paint job is complete.