The Most Educational TV Shows for Toddlers Super Why! Super Why! is all about the power of reading. ... Daniel Tiger's Neighborhood. This show stars Daniel Tiger from the original Mr. ... Octonauts. For the curious, animal-loving child, we have the Octonauts. ... Word World. ... Doc McStuffins. ... Sid the Science Kid. ... Timmy Time. ... Bubble Guppies. More items...