Yes, this is possible. To withdraw funds from a 529 plan, first determine the amount of eligible educational costs. Make sure your spending falls inside the permitted range. Choose which 529 account to withdraw from first if the beneficiary has multiple accounts. Use a parent account first, and then, in the student's last years, a relative account. After that, you can start the withdrawal request. You may use an online platform, send a completed withdrawal request form, or call, depending on your loan servicer.