No, a 5x114 wheel will not fit on a 5x108 bolt pattern. The two measurements refer to the number of lug holes and the distance between them, respectively. A 5x114 wheel has five lug holes that are spaced 114mm apart, while a 5x108 wheel has five lug holes that are spaced 108mm apart. Because the measurements differ, it is not possible for a 5x114 wheel to be compatible with a vehicle using a 5x108 bolt pattern. Therefore, if you have wheels with one measurement and your vehicle requires another, you must purchase new wheels in order to ensure proper fitment.