To make friends on Chatruletka, follow these steps: 1. Visit the Chatruletka website. 2. Allow access to your webcam and microphone. 3. Click on the 'Start' button to begin the chat. 4. Engage in conversation with the random person displayed on your screen. 5. If you find someone interesting, you can continue the conversation or click on the 'Next' button to match with a new person.