As of today, the most expensive deck of playing cards in the world is the Venexiana Gold. The cost of this 52-deck of cards is roughly over $400. This deck is a gold foil-stamped deck that is why it is costly. Likewise, there are only 212 pieces of this kind in the market. Next is the White Centurions. IT has an astonishing price of over $300 with about 1,000 decks available in the marketplace.