Incorrect alignment settings can adversely affect handling. Tolerable camber, caster and toe settings can be verified by a print-out from your alignment/tire shop or vehicle dealer.
If the tires are evenly worn, the alignment is in order and there is still a pull, the front tires should be criss-crossed (as long as they are not a directional tread design) to see if the pull changes directions.
This should be performed by a participating dealer.