Yes. With most VPNs, you can choose the location of a server you would like to connect to. After establishing that connection, the VPN app will forward your traffic through that VPN server, and you will be seen as if you had his IP. Therefore, you can pick a location to get around some geo-restricted websites and online censorship with a VPN.
Nevertheless, websites and streaming services tend to block some servers. So, getting a VPN with many servers and locations allows switching between them if one doesn’t work for you.