High Paying Police Jobs Police Captain. Salary range: $87,000-$172,500 per year. ... Chief of Police. Salary range: $100,500-$165,000 per year. ... Police Lieutenant. Salary range: $75,500-$149,000 per year. ... Assistant Chief of Police. Salary range: $57,500-$139,000 per year. ... Special Agent In Charge. ... Sheriff. ... Lieutenant. ... Police Sergeant. More items...