On these high-core-count systems, Windows groups the CPUs in packs of 64. Therefore, you will add multiple sets to the CPU Sets to span more than one group. That's what the left-most list is for. Use the '+' button under the left 'CPU Sets' list. Then select another processor group from the dropdown in the upper-right. Select the CPUs from that group to add a second CPU Set. That is why the term 'CPU Sets' is plural, because you can specify more than one set.