No, the vinyl adhesive used is not strong enough to pull paint off an adequately prepped/primed and painted surface (assuming the painted surface was  stable prior to installing the vinyl).   Applying a small amount of heat, such as a hair dryer or heat gun to the vinyl that you want to remove will allow the adhesive to soften, and make it easier to pull the vinyl away from the surface,  WITHOUT having to gouge or scrape the vinyl to bits to get it off.