mlsa-iai-msu-lab/ru_sci_bench_zho_cite_reranking huggingface dataset:
Tris(trimethylsilyl) borate as an electrolyte additive for high-voltage lithium-ion batteries using LiNi_(1/3)Mn_(1/3)Co_(1/3)O_2 cathode

The influence of tris(trimethylsilyl) borate (TMSB) as an electrolyte additive on lithium ion cells have been studied using Li/LiCo_(1/3)Ni_(1/3)Mn_(1/3)O_2 cells at a higher voltage, 4.7 V versus Li/Li~+. 1wt% TMSB can dramatically reduce the capacity fading that occurs during cycling at room temperature (RT) and elevated temperature (60 ℃). After 150 cycles at 1C rate (1C= 278mAh/g), the capacity retention of Li/LiCo_(1/3)Ni_(1/3)Mn_(1/3)O_2 is up to near 72% in the electrolyte with TMSB added, while it is only about 35% in the baseline electrolyte. The electrochemical behaviors, the surface chemistry and structure of Li/LiCo_(1/3)Ni_(1/3)Mn_(1/3)O_2 cathode are characterized with charge/discharge test, linear sweep voltammetry (LSV), X-ray photoelectron spectroscopy (XPS), electrochemical impedance spectroscopy (EIS), thermal gravimetric analyses (TGA), scanning electron microscope (SEM) and transmission electron microscopy (TEM). These analysis results reveal that the addition of TMSB is able to protectively modify the electrode CEI film in a manner that suppresses electrolyte decomposition and degradation of electrode surface structure, even though at both a higher voltage of 4.7 V and an elevated temperature of 60 ℃.
Theoretical insight into the enhanced CH4 desorption via H2O adsorption on different rank coal surfaces

The density functional theory was used to investigate the adsorption of CH_4 and H_2O on different rank coal surfaces. The coal rank is the dominant factor in affecting the adsorption capacity of coal. In order to better understand gas and water interaction with coal of different maturity, we developed fourteen coal models to represent the different rank coal. The interactions of CH_4 and H_2O with coal surfaces were studied and characterized by their adsorption energies, Mulliken charges and electrostatic potential surfaces. The results revealed that the interaction between coal and CH_4 was weak physical adsorption, and that the interaction between coal and H_2O consisted of physical and chemical adsorption. Adsorption energy of coal-H_2O system was larger than that of coal-CH_4 on all rank coals, suggesting that the adsorption priority in the coal models is H_2O > CH_4. Consequently, the injection of H_2O into the different rank coal could effectively enhance the coal bed methane (CBM) recovery.
Interlayer interference mechanism of multi-seam drainage in a CBM well:An example from Zhucang syncline

Based on the characteristics of the strong volatility of physical property in vertical direction, high gas content, high resource abundance and large exploitation potentiality of coal reservoir in Bide-Santang basin of Zhina coal field, we study the generation mechanism of interlayer interference, propagation rules of reservoir pressure drop and influencing factors of gas productivity in CBM multi-seam drainage in the paper. On the basis of the actual production data of X-2 well of Zhucang syncline in Bide-Santang basin,by simulating the gas production process of a CBM well under the condition of multiple seam with COMET3 numerical simulation software, we analyze the influencing factors of gas productivity during the process of multi-seam drainage, and illuminate the interlayer interference mechanism of multiseam drainage. The results show that permeability, reservoir pressure gradient, critical desorption pressure and fluid supply capacity of stratum have great influence on gas productivity of multi-seam drainage while coal thickness has little influence on it. Permeability, reservoir pressure gradient and fluid supply capacity of stratum affect the propagation velocity of reservoir pressure drop and thereby affect the final gas productivity. Moreover, the influence of critical desorption pressure on gas productivity of multiseam drainage is reflected in the gas breakthrough time and effective desorption area.
Strategic mining options optimization:Open pit mining, underground mining or both

Near-surface deposits that extend to considerable depths are often amenable to both open pit mining and/or underground mining. This paper investigates the strategy of mining options for an orebody using a Mixed Integer Linear Programming(MILP) optimization framework. The MILP formulation maximizes the Net Present Value(NPV) of the reserve when extracted with(i) open pit mining,(ii) underground mining, and(iii) concurrent open pit and underground mining. Comparatively, implementing open pit mining generates a higher NPV than underground mining. However considering the investment required for these mining options, underground mining generates a better return on investment than open pit mining. Also, in the concurrent open pit and underground mining scenario, the optimizer prefers extracting blocks using open pit mining. Although the underground mine could access ore sooner, the mining cost differential for open pit mining is more than compensated for by the discounting benefits associated with earlier underground mining.
Asia dust production ramped up since latest Oligocene driven by Tibetan Plateau uplift

Eolian dust is an integral component of the Earth system dynamics, participating in a range of physical, chemical and biogeological processes of the Earth system at various temporal and spatial scales [1] (Fig. 1). Great advance has been achieved in recent years in understanding eolian dust cycles through instrumental investigations and numericalmodeling as well as tracing geological records [1]. The Asian dust cycle is one of the major dust systems on Earth, playing important roles in many processes and exerting impacts well beyond the region [2]. From a geological perspective, the production, emission, transportation and deposition of Asian dust are closely associated with regional tectonic-geomorphic-climatic configurations, and thus preserving valuable archives for deciphering regional tectonic and climatic history. Among others, uplift of Tibetan Plateau and aridification of Asian interior is of great interest and global relevance.
Optimization of MgO/Al_2O_3 ratio for the maximization of active site densities in the Ni_2P/MgAlO catalysts for the hydrotreating reactions

The Ni_2P/MgAlO catalysts with different MgO/Al_2O_3 ratios were prepared by the phosphidation of corresponding Ni/MgAlO catalysts with triphenylphosphine in liquid phase. It was found that the MgO/Al_2O_3 ratio affected the Ni2P/MgAlO catalysts significantly. The Ni_2P/MgAlO catalyst with the MgO/Al_2O_3 ratio of 3 (w/w) exhibited the highly dispersed Ni2P particles (~9 nm) with the highest CO uptake (344 μmol/g) and thus the highest activities for the hydrotreating reactions. However, based on the CO uptakes on the used catalysts, the TOF values for the hydrodesulphurization of dibenzothiophene as well as those for the hydrogenation of tetralin on all the Ni2P/MgAlO catalysts were respectively similar, indicating that the MgO/Al_2O_3 ratio did not affect the intrinsic activities of Ni_2P supported on the MgAlO support for the hydrotreating reactions.
Thermal evolution characteristics of Triassic coal in Chuxiong Basin and its geological significance

Chuxiong Basin in Yunnan is a typical Mesozoic foreland basin which is enriched in widely distributed Triassic coal resources with thick deposits and of important strategic significance. By applying vitrinite reflectance measurement, inclusion thermometry, fission track dating and EASY% Ro numerical simulation, the Triassic coal thermal evolution history of the Chuxiong Basin was analyzed, and the results were concluded. The vitrinite reflectance of Chuxiong Basin is higher in the west and south in general.Vertically, in the east, west, and north of the basin, the vitrinite reflectance increases with increasing depth, and in the northern part, exceptionally high values occur, and there is no significant regularity in the east. The formation of inclusions inside quartz veins in Chuxiong Basin Triassic coal are unrelated with magmatic hydrothermal fluid, and there are multi-phase inclusions formed in three or four sections of tectonic movements. The main heating period(apparent age) of the Triassic coal is concentrated in the late Cenozoic, during which the coal was subjected to repeated thermal disturbance, resulting in a multimodal distribution of the fission track data, which reveals mild burial features of the early stages of the Late Cenozoic. The Triassic coal of Chuxiong Basin has experienced two major temperature increasing processes, which occurred in the early-mid Yanshan and the early Himalayan, respectively. The first hydrocarbon generation period of coal organic matter occurred in the formation stage of the foreland basin, during which the south and west of the basin generated large amounts of hydrocarbon, but little was preserved. The second generation stage in the Early Himalayan had conditions suitable for high gas accumulation, especially in the western and southern regions. The upper Triassic coal is of moderate burial depth and is less affected by the strike-slip effect. There are key areas of Chuxiong Basin oil and gas exploration, such as the Yanfeng Basin in the north-central, Yongren and Yunlong areas.
Experimental research on coal seam similar material proportion and its application

In this paper, the optimization design of the low strength mechanical test and orthogonal test have been analyzed in order to simulate the mechanical properties of thick and extra-thick coal seam accurately in a similar material simulation test. The results show that the specimen can reach a wider range of strength when cement has been used compared to that of gypsum, suggesting that cement is more suitable for making coal seam in similar material simulation tests. The uniaxial compressive strength is more sensitive to cement than coal or sand. The proportion of coal and sand do not play a decisive role in uniaxial compressive strength. The uniaxial compressive strength and specimen density decrease as the mass percent of coal and aggregate–binder ratio rise. There is a positive correlation between uniaxial compressive strength and density. The No. 5 proportion(cement: sand: water: activated carbon: coal = 6:6:7:1.1:79.9)was chosen to be used in the similar material simulation test of steeply dipping and extra-thick coal seam with a density of 0.913 g/cm~3 and an uniaxial compressive strength of 0.076 MPa which are in accordance with the similarity theory. The phenomenon of overburden stratum movement, fracture development and floor pressure relief were obtained during the similar material simulation test by using the proportion.
Mechanical analysis of roof stability under nonlinear compaction of solid backfill body

Based on the compaction characteristic test and the nonlinear compaction deformation characteristics of backfill material, this paper applies the theory of nonlinear elastic foundation of thin plate to establish a mechanical model of backfill body and roof in solid dense backfill coal mining. This study critically analyses the deflection equation of the roof by the energy method, derives the conditions of roof breakage and combined with concrete engineering practice analyses, determines roof movement regularity and stability in solid dense backfill mining. Analysis of the engineering practice of the 13,120 backfill panel of Pingmei 12# mine shows the theoretical maximum of roof convergence in backfill mining to be415 mm which is in significant agreement with the measured value. During the advancing process of solid backfill mining at the panel, the maximum tensile stress on the roof is less than its tensile strength which does not satisfy the conditions for roof breakage. Drilling results on the roof and ground pressure monitoring show that the integrity of roof is strong, which is consistent with the theoretical calculations described in this study. The results presented in the study provide a basis for further investigation into strata movement theory in solid dense backfill mining.
A methodology for lining design of circular mine shafts in different rock masses

In this study, the finite element numerical modelling of 2D shaft sections in a Hoek–Brown medium are carried out in a non-hydrostatic stress state in an attempt to predict pressures developing around mine shafts. An iterative process of applying support pressure until observing no failure zone around the shaft is used to simulate the required lining support pressure for different shaft models. Later, regression analysis is carried out to find a generic shaft pressure equation representing the rock mass and the stress state. Finally, the developed pressure equation which shows a good agreement with a case study is used in elastic "thick-walled cylinder" equation to calculate the lining thickness required to prevent the development of a failure zone around the shaft. At the end of the study, a user-friendly object-oriented computer program "Shaft 2D" is developed to simplify the rigorous shaft lining thickness calculation process.
Strength evolution and deformation behaviour of cemented paste backfill at early ages: Effect of curing stress, filling strategy and drainage

In this study, a pressure cell apparatus is developed to investigate the early age evolution of the strength and deformation behaviour of cemented paste backfill(CPB) when subjected to various loading conditions under different curing scenarios. The different curing scenarios that are simulated include:(1)drained and undrained conditions,(2) different filling rates,(3) different filling sequences, and(4) different curing stresses. The findings show that drainage, curing stress, curing time and filling rate influence the mechanical and deformation behaviours of CPB materials. The coupled effects of consolidation, drainage and suction contribute to the strength development of drained CPB subjected to curing stress. On the other hand, particle rearrangement caused by the applied pressure and suction development due to self-desiccation plays a significant role in the strength gain of undrained CPB cured under stress.Furthermore, curing stress induces slightly faster rate of cement hydration, which can contribute to strength acquisition.
Support technology of deep roadway under high stress and its application

Roadway instability has been a major concern in the fields of mining engineering. This paper aims to provide practical and efficient strategy to support the roadways under high in-situ stress. A case study on the stability of deep roadways was carried out in an underground mine in Gansu province, China. Currently,the surrounding rock strata is extremely fractured, which results in a series of engineering disasters, such as side wall collapse and severe floor heave in the past decades. Aiming to solve these problems, an improved support method was proposed, which includes optimal bolt parameters and arrangement, floor beam layout by grooving, and full length grouting. Based on the modeling results by FLAC3D, the new support method is much better than the current one in terms of preventing the large deformation of surrounding rock and restricting the development of plastic zones. For implementation and verification, field experiments, along with deformation monitoring, were conducted in the 958 level roadway of Mining II areas. The results show that the improved support can significantly reduce surrounding rock deformation, avoid frequent repair, and maintain the long-term stability of the roadway. Compared to the original support, the new support method can greatly save investment of mines, and has good application value and popularization value.
Peptide recognition by functional supramolecular nanopores with complementary size and binding sites

The precise control of the conformations of biomolecules adsorbed on a surface at the single-molecule level is significant. However, it remains a huge challenge because of the complex structure and conformation diversity of biomolecules. Herein, a “nanopore-confined recognition” strategy is proposed to manipulate the adsorption of individual valinomycin molecules at room temperature through precise design of functionalized conjugated macrocycle (CPN8) supramolecular nanopores with complementary architectures and binding sites. We revealed that CPN8 prefers to selectively recognizing valinomycin with complementary architecture because of the strong synergistic interactions between the isopropyl groups of valinomycin and the amino groups of CPN8, with valinomycinhighly oriented pyrolytic graphite (HOPG) interactions. Our perspectives at the single-molecule level will provide valuable insights to improve the design of supramolecular nanopores for conformation-selective recognition of non-conjugated molecules.
Effects of uniaxial compressive strain on the electronictransport properties of zigzag carbon nanotubes

Recently, substantial attention has been paid to the strain sensitivity of the carbon nanotubes’ (CNTs’) electronic properties. In this study, the relationships between the geometric structures and electronic states of zigzag CNTs under uniaxial compressive strain were investigated. We found that different factors dominate the electronic states of zigzag CNTs depending on the strain regions: the initial stage of the strain loading, which lasts until column-buckling deformation begins, and the strain regions corresponding to column- and shell-buckling deformations. Because shell-buckling deformation significantly increases the π-orbital angle, the angle between the π orbital axis vectors of adjacent atoms, strong localization of the density of states (LDOS) occurs in the buckled area. We also analyzed the current able to pass through deformed CNTs using a tight-binding-based Green’s function approach and determined that the current can be significantly suppressed by applying uniaxial compressive strain. Our method of predicting the electronic state of a deformed CNT based on the π-orbital angle is expected to be useful for predicting the electronic properties of CNT-based electronic devices and sensors.
TbF_3 nanoparticles as dual-mode contrast agents for ultrahigh field magnetic resonance imaging and X-ray computed tomography

Considering the development of magnetic resonance imaging (MRI) under ultrahigh magnetic field (>3 T), the exploration of novel contrast agents (CAs) for ultrahigh field MRI is urgently needed. Herein, we report polyethyleneimine (PEI)-coated TbF_3 nanoparticles (NPs), which were synthesized by a facile solvothermal method, as potential dual-mode CAs for ultrahigh field MRI and X-ray computed tomography (CT). Owing to their strong paramagnetism, the TbF_3 NPs showed excellent transverse relaxivity (395.77 mM~(–1)·s~(–1)) and negligible longitudinal relaxivity under an ultrahigh magnetic field (7 T) with a great potential as a T_2-weighted MRI contrast agent. Furthermore, by comparison with the clinically used CT CAs (iohexol), the TbF_3 NPs showed superior X-ray attenuation ability. The practical application for T_2-weighted MRI and CT imaging was demonstrated with an animal model. Moreover, cell cytotoxicity and in vivo toxicity assessments implied the low toxicity of TbF_3 NPs. In summary, the above results indicate that TbF_3 NPs are promising candidates for ultrahigh field MRI and CT dual-mode imaging.
Distance dependence of atomic-resolution near-field imaging on α-Al2O3 (0001) surface with respect to surface photovoltage of silicon probe tip

Recently, we achieved atomic-resolution optical imaging with near-field scanning optical microscopy using photon-induced force detection. In this technique, the surface photovoltage of the silicon-tip apex induced by the optical near field on the surface is measured as the electrostatic force. We demonstrated atomicresolution imaging of the near field on the α-Al2O3 (0001) surface of a prism. We investigated the spatial distribution of the near field by scanning at different tip-sample distances and found that the atomic corrugation of the near-field signal was observed at greater distances than that of the atomic force microscopy signal. As the tip-sample distance increased, the normalized signal-to-noise ratio of the near field is in a gradual decline almost twice that of the frequency shift (Δf).
Nano-confinement of biomolecules: Hydrophilic confinement promotes structural order and enhances mobility of water molecules

Molecular dynamics simulations have been used to investigate the confinement packing characteristics of small hydrophilic (N-acetyl-glycine-methylamide, Nagma) and hydrophobic (N-acetyl-leucine-methylamide, Nalma) biomolecules in large diameter single-wall carbon nanotubes (SWCNTs). We find that hydrophilic biomolecules easily fill the nanotube and self organize into a geometrical configuration which reminds the water structural organization under SWCNT confinement. The packing of hydrophilic biomolecules inside the cylinder confines all water molecules in its core, which enhances their mobility. Conversely, hydrophobic biomolecules accommodate into the nanotubes with a trend for homogeneous filling, which generate unstable small pockets of water and drive toward a state of dehydration. These results shed light on key parameters important for the encapsulation of biomolecules with direct relevance for long-term storage and prevention of degradation.
Ballistic transport in single-layer MoS_2 piezotronic transistors

Because of the coupling between semiconducting and piezoelectric properties in wurtzite materials, strain-induced piezo-charges can tune the charge transport across the interface or junction, which is referred to as the piezotronic effect. For devices whose dimension is much smaller than the mean free path of carriers(such as a single atomic layer of MoS_2), ballistic transport occurs. In this study, transport in the monolayer MoS_2 piezotronic transistor is studied by presenting analytical solutions for two-dimensional (2D) MoS_2. Furthermore, a numerical simulation for guiding future 2D piezotronic nanodevice design is presented.
Near-infrared light-activated cancer cell targeting and drug delivery with aptamer-modified nanostructures

Stimuli-activated targeted delivery systems for highly accurate treatment of tumors have received considerable attention in recent years. Herein, we reveal a light-activable cancer-targeting strategy that uses a complementary DNA sequence to hybridize and mask sgc8 aptamers conjugated onto photothermal agents such as gold nanorods or single-walled carbon nanotubes (SWNTs). Upon exposure to near-infrared (NIR) laser, localized photothermal heating of the surface of those nano-agents results in dehybridization of the double-stranded DNA and uncaging of the aptamer sequence to allow specific cancer-cell targeting. Utilizing doxorubicin-loaded SWNTs as a model system, targeted drug delivery to cancer cells activated by NIR light was achieved. This work demonstrates the concept of NIR-activable tumor-targeting delivery systems with controllable cancer-cell binding to potentially enable highly specific and efficient cancer therapy.
Verification of monocular and binocular pose estimation algorithms in vision-based UAVs autonomous aerial refueling system

With the high focus on autonomous aerial refueling (AAR), it becomes increasingly urgent to design efficient methods or algorithms for solving the AAR problems in complicated aerial environments. A vision-based technology for AAR is developed in this paper, and five monocular and binocular visual algorithms for pose estimation of the unmanned aerial vehicles (UAVs) are adopted and verified in this AAR system. The real-time on-board vision system is also designed for precise navigation in the UAVs docking phase. A series of out-door comparative experiments for different pose estimation algorithms are conducted to verify the feasibility and accuracy of the vision algorithms in AAR.