# Experimental and Modeling Study of the Turning Process of PA 6/Nano Calcium Carbonate Composite

Authors: Mehdi Haghi; Reza Farshbaf Zinati; Mohammad Reza Razfar
Journal: Journal of Composites
 (2013)

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## Abstract

Nowadays, polymeric nanocomposites have emerged as a new material class with rapidly growing use in industrial products because of good mechanical, thermal, and physical properties. Recently, the requirement of the direct machining of these materials has increased due to the production of the most of them by extrusion method in simple cross section and the increased demand for personalized products. In this work, the effect of turning parameters (cutting speed and feed) and nano calcium carbonate content on the machinability properties of polyamide 6/nano calcium carbonate composites was investigated by analysis of variance. A novel modeling approach of modified harmony search-based neural network was also utilized to create predictive models of surface roughness and total cutting force from the experimental data. The results revealed that the nano calcium carbonate content on polyamide 6 decreased the cutting forces significantly but did not have a significant effect on surface roughness. Moreover, the results for modeling total cutting forces and surface roughness showed that modified harmony search-based neural network is effective, reliable, and authoritative in modeling the turning process of polyamide 6/nano calcium carbonate composite.


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## Body

## 1. Introduction

Calcium carbonate, with 85 percent share of consumption among fillers, becomes the most widely consumed filler in the polymer industry; nevertheless, most of the studies in the field of polyamide 6 (PA 6) deal with the nanofiller of clay, and only a few studies deal with nanocomposites of polyamide 6/nano calcium carbonate (PA 6/NCC). On the other hand, findings reveal that adding nanoclay particles to polymer reduces the impact strength of the produced composite and makes it brittle whereas adding NCC increases the tensile strength of the composite thereby not making it brittle [1].NCC has been used widely as a filler for a wide variety of resins such as polyamide (PA), polyvinyl chloride (PVC), polystyrene (PS), and polypropylene (PP) [2] because of its capability to provide increased stiffness, toughness, and dimensional stability.Substantial improvements in mechanical, thermal, and physical properties of polymer nanocomposites have widened the use of these polymers in industry. In the late 1980s, the Toyota Motor Company commercialized a timing belt cover made from nylon 6/nanoclay composites for one of its car models, demonstrating that thermoplastic nanocomposites are one of the most promising materials to use in domestic and industrial applications [3].An increase in the desire for personalized products has led to the need for the direct machining of polymers. The ability to machine soft materials such as polymers offers distinct advantages for producing personalized soft products using direct machining, but the machining of polymers often presents challenges to engineers in terms of close tolerances and softness, which means that it behaves differently compared to conventional metal cutting [4]. Particularly, the production of complex and unusual geometries of soft polymers by machining makes it difficult for the engineers to achieve close geometrical tolerances.Surface roughness and total cutting force are two important criteria used to evaluate the machinability of a material. Surface properties of polymeric materials are critically important in many applications and are strongly influenced by the structure and composition of the outermost molecular layers. Appropriate surface quality is required for procedures such as coating in order to approach special surface properties like hardness, wear resistance, and friction. Cutting force analysis plays a vital role in studying the various characteristics of a machining process, like dynamic stability, positioning accuracy of the tool, and roughness of the machined surface [5].However, a lot of information is available about the machining of metals, but not enough information exists on the machining of polymers and their composites. In recent years, a few studies have been done about the machining operations of the polymer composites. In 2006, Mata et al. [6] developed a physical cutting model for the 30 percent glass fiber reinforced PA66. In 2007, Davim and Mata [7] studied the turning process of 30 percent glass fiber reinforced and unreinforced PA 6, and Dhokia et al. [8] developed a prediction model for the surface roughness of machined polypropylene products. In 2008, Dhokia et al. [9] optimized the machining parameters for a specific surface roughness in ball-end machining of polypropylene. In 2009, Davim et al. [10] studied the machinability of 30 percent glass fiber reinforced and unreinforced PA 6 in precision turning using four distinct tool materials.Various process-dependent factors influence the mechanism of surface roughness and cutting forces in addition to cutting parameters. Thus, it is necessary to have an effective and accurate predictive model which can be of two types: mechanistic and empirical. The mechanistic model is recognized as a functional correlation between input-output parameters appointed analytically. However, lack of accuracy and effectiveness, in addition to shortage of existing mechanistic models for surface roughness mechanism and cutting forces, has forced the researchers to rely on the empirical models. ANNs, as empirical models, are widely utilized for system modeling and optimization because it can develop nonlinear input(s)-output(s) correlation in a process without close investigation of the existing mathematical complexity in process parameters relation [11, 12].In the current work, the effect of turning parameters (cutting speed and feed) and NCC content on the machinability properties of PA 6/NCC composites was studied through ANOVA and MHSNN.


## 2. Modified Harmony Search-Based Neural Network (MHSNN) Algorithm

A detailed flowchart for the MHSNN is given in Figure1. As shown in this flowchart, the MHSNN algorithm consists of 12 steps as follows.Figure 1
Flowchart for the MHSNN.Step 1 (initialization of neural network’s number of layers and neurons).
The first step is initializing number of layers such as input layer, hidden layers, and output layer, together with each layer’s number of neurons.Step 2 (initialization of data set).
In the second step, all data composed of input and output data sets are initialized for the algorithm.Step 3 (normalization of initialized data set).
In the third step, the input and output parameters were normalized between −1 and 1 by the following substitution:(1)xi=2(x-xminxmax-xmin)-1.Step 4 (randomly selecting 10 percent of initialized data for test data set).
In the forth step, 10 percent of data are selected randomly from initialized data for testing of the trained neural network. The selected data are then removed from initialized data, and the remaining data sets are assigned as training data set.Step 5 (initializing the range of neurons’ weights and bias along with algorithm parameters).
The range of neurons’ weights and bias together with modified harmony search (MHS) algorithm’s parameters such as harmony memory size (HMS), harmony memory considering rate (HMCR), pitch adjusting rate (PAR), and number of improvisations (NI) are designated in this step.Step 6 (initializing the harmony memory).
In the sixth step, the HM matrix is filled with the number of HMS random values, in the acceptable range of each decision variable.Step 7 (improvising a new set of neuron’s weights and bias).
In this step, a new set of values for all neurons’ weights and bias is produced based upon considering the members existing in HM, random production of values, and pitch adjustment rule. A detailed flowchart for the continuous harmony search strategy based on the HS metaheuristic algorithm is given in Figure2.Figure 2
Harmony improvisation flowchart for continuous variables; (In which ran is Random numbers in the range 0–1, PVB is the possible value bound forxi, NCHV(i) is a new continuous harmony vector improvised in step 3 and bw is an arbitrary distance bandwidth.).Step 8 (calculating the output of MHSNN for each training dataset).
In Step8, the outputs of each neuron in hidden layers and finally the output of outputlayer as the output of MHSNN are calculated according to the neuron’s weights and bias values assigned by MHS algorithm.Step 9 (calculation of mean square error (MSE)).
In the ninth step, MSE for the assigned set of neuron’s weights and bias is calculated according to the neural network’s output and actual output of each training data set. The calculated MSE is designated as the fitness function value for the assigned set of neuron’s weights and bias.Step 10 (calculation of maximum error of training data set as constrained function).
In the tenth step, maximum error of the assigned set of neuron’s weights and bias is calculated according to the neural network’s output and actual output of each training data set. The calculated maximum error of training data sets is allocated as the constrained function value of assigned set of neuron’s weights and bias.Step 11 (updating the harmony memory).
In step 11, the worst member of the ranked HM,x#, is selected and compared with the new solution vector, x′. Note that the x′  does not need to be feasible. x′ will be replaced with x# only in one of the following three cases.(1)
x′ is feasible and x# is infeasible.(2)
Bothx′ and x# are feasible and F(x′)<F(x#).(3)
Bothx′ and x# are infeasible and x′ dominates x#.Step 12 (repeating Steps6 to 10 until the termination criterion is satisfied).
In Step12, when the termination criterion is satisfied, the computations will be terminated. Otherwise, Steps 7 to 11 will be repeated. More detailed information about the MHSNN can be obtained from [11, 12].


## 3. Experimental Procedure

### 3.1. Material

The PA 6 with brand of  “Akulon, F232-D” from DSM company was used as matrix of the composites and the NCC particles of   “Socal 312” from Solvay Company with good adhesion to PA 6 used as the filler of the composites. The polypropylene modified by maleic anhydride was utilized to modify the adhesion among the polymer and nanoparticles and increase the dispersion of the nanoparticles in the polymeric matrix.


### 3.2. Tool and Machine Tool

The machining experiments were executed for finishing longitudinal turning on a high precision geared TN50BR lathe with 5.5 kW spindle motor, maximum spindle speed of 2000 rpm, and maximum feed of 6.4 mm/rev.The used inserts were fromWIDIA Company designated as ISO number of TPGN160308 and the tool holder was CTGPR-2020 K16 from MAROX Company.Turning dynamometer 9121 model of KISTLER Company with three components as utilized to measure cutting forces. The dynamometer was fixed on tool post and the tool holder was mounted on it. During cutting operation, forces applied on the tool are converted to signals by dynamometer and amplified by charge amplifier. The amplified signals are then transferred to data acquisition card to be evaluated by DynoWare software in computer. The schematic lay out of the experimental setup is shown in Figure3(a).Experimental setup: (a) the schematic layout of the experimental setup and (b) the photograph of surface roughness tester.
(a)
(b)


### 3.3. Surface Roughness Measurement

Surface roughness tool of SURTRONIC 3+ from Taylor-Hobson Company was used to measure the surface roughness(Ra) of each experiment. To this end, three small regions on the machined surface were determined for measurements. The measurements in these regions were conducted, and the average value of three measurements was recorded as the Ra value. The tracing velocity and the sampling length were fixed at 0.5 mm/s and 0.8 mm, respectively. A picture of the used tool is shown in Figure 3(b).


### 3.4. Design of Experiments

In this work, 45 samples based on full factorial design of the experiments employing three-level cutting parameters and five-level NCC content are given in Table1. The depth of cut for all experiments was 1 mm. The levels of cutting parameters were selected considering the recommendations of tool catalogue and [13].Table 1
Levels of parameters.
Parameter
levels
NCC (wt%)
0, 2.5, 5, 7.5, 10
Cutting speed (m/min)
21, 35, 43
Feed (mm/rev)
0.1, 0.15, 0.2


## 3.1. Material

The PA 6 with brand of  “Akulon, F232-D” from DSM company was used as matrix of the composites and the NCC particles of   “Socal 312” from Solvay Company with good adhesion to PA 6 used as the filler of the composites. The polypropylene modified by maleic anhydride was utilized to modify the adhesion among the polymer and nanoparticles and increase the dispersion of the nanoparticles in the polymeric matrix.


## 3.2. Tool and Machine Tool

The machining experiments were executed for finishing longitudinal turning on a high precision geared TN50BR lathe with 5.5 kW spindle motor, maximum spindle speed of 2000 rpm, and maximum feed of 6.4 mm/rev.The used inserts were fromWIDIA Company designated as ISO number of TPGN160308 and the tool holder was CTGPR-2020 K16 from MAROX Company.Turning dynamometer 9121 model of KISTLER Company with three components as utilized to measure cutting forces. The dynamometer was fixed on tool post and the tool holder was mounted on it. During cutting operation, forces applied on the tool are converted to signals by dynamometer and amplified by charge amplifier. The amplified signals are then transferred to data acquisition card to be evaluated by DynoWare software in computer. The schematic lay out of the experimental setup is shown in Figure3(a).Experimental setup: (a) the schematic layout of the experimental setup and (b) the photograph of surface roughness tester.
(a)
(b)


## 3.3. Surface Roughness Measurement

Surface roughness tool of SURTRONIC 3+ from Taylor-Hobson Company was used to measure the surface roughness(Ra) of each experiment. To this end, three small regions on the machined surface were determined for measurements. The measurements in these regions were conducted, and the average value of three measurements was recorded as the Ra value. The tracing velocity and the sampling length were fixed at 0.5 mm/s and 0.8 mm, respectively. A picture of the used tool is shown in Figure 3(b).


## 3.4. Design of Experiments

In this work, 45 samples based on full factorial design of the experiments employing three-level cutting parameters and five-level NCC content are given in Table1. The depth of cut for all experiments was 1 mm. The levels of cutting parameters were selected considering the recommendations of tool catalogue and [13].Table 1
Levels of parameters.
Parameter
levels
NCC (wt%)
0, 2.5, 5, 7.5, 10
Cutting speed (m/min)
21, 35, 43
Feed (mm/rev)
0.1, 0.15, 0.2


## 4. Process Modeling through MHSNN

In this work, two neural networks composed of one hidden layer with three inputs and one output were used to model the processes, as shown in Figure4. The three most important input parameters are cutting speed, feed, NCC content, and the output parameters including average surface roughness and total cutting force.Figure 4
Architecture of neural network.The experimental data comprising 45 groups was distributed because the training subset includes 40 groups (90%) of the data, and the randomly selected testing subset includes 5 groups (10%) of the data. In order to find the suitable architecture of the networks, different architectures with five different combinations of training-testing data sets were studied. After 1,950 iterations of MHSNN, the 3-9-1, 3-7-1 architectures were found to be the most suitable ones for mean surface roughness and total cutting force, respectively. The critical parameters of harmony memory size (30), harmony memory considering rate (0.5), pitch adjusting rate (0.2), number of improvisations (1950), and distance bandwidth((xU-xL)/100) were used. The comparison of MHSNN predictions with the experimental measurements for test datasets of the average surface roughness and total cutting force is illustrated in Tables 2 and 3, respectively.Table 2
Comparison of neural network predictions with experimental measurement for test sets of surface roughness.
Cutting condition
Surface roughness value
Cutting speed (m/min)
f (mm/rev)
NCC (wt%)
Experiment
Predicted
Error (%)
21
0.1
2.5
1.346
1.453
7.95
43
0.2
2.5
5.916
6.121
3.47
35
0.15
7.5
1.506
1.469
2.46
43
0.15
10
2.868
3.008
4.88
43
0.15
0
2.105
2.118
0.62Table 3
Comparison of neural network predictions with experimental measurement for test sets of total cutting force.
Cutting condition
Total cutting force
Cutting speed (m/min)
f (mm/rev)
NCC (wt%)
Experiment
Predicted
Error (%)
21
0.2
0
26.317
25.739
2.20
43
0.2
5
23.696
23.870
0.73
35
0.15
7.5
19.769
20.759
5.01
21
0.1
10
16.961
17.639
4.00
43
0.2
10
23.511
23.049
1.97


## 5. Results

The analysis of variance (ANOVA) has been employed byMinitab to investigate the influence of cutting parameters and NCC content on the surface roughness and total cutting force. The mean effects of the factorial experiments on the surface roughness and total cutting force were illustrated in Figure 5. Tables 4 and 5 show the analysis of variance with the surface roughness and total cutting force, respectively. These analyses were carried out for a level of significance of 5%, that is, for a level of confidence of 95%.Table 4
Table ANOVA for the surface roughness.
Source of variance
D.F.
Sum of square (SS)
Variance(V)
F
F
α
=
5
%
P (%)
V(m/min)
2
1.065
0.533
1.75
3.21
0.64
f (mm/rev)
2
152.417
76.208
250.68
3.21
91.64
NCC (wt%)
4
1.873
0.468
1.54
2.59
1.13
Error
36
10.960
0.304
—
—
6.59
Total
44
166.316
—
—
—
100Table 5
Table ANOVA for the total cutting force.
Source of variance
D.F.
Sum of square (SS)
Variance(V)
F
F
α
=
5
%
P (%)
V (m/min)
2
5.561
2.781
19.01
3.21
1.44
f (mm/rev)
2
363.828
181.914
1204.72
3.21
93.89
NCC  (wt%)
4
12.657
3.164
20.95
2.59
3.26
Error
36
5.443
0.151
—
—
1.41
Total
44
387.490
—
—
—
100The mean effects of the factorial experiments on the surface roughness and total cutting force.
(a)
(b)
(c)
(d)From Table4 it is clear that the feed factor (P=91.64%) has statistical and physical significance on the surface roughness.From Table5 it is apparent that the cutting speed factor (P=1.44%), feed factor (P=93.89%), and NCC content factor (P=3.26%) have statistical and physical significance on the total cutting force.The factors and interactions present a statistical and physical significance, becauseF>Fα=5%. Note that the errors associated with table ANOVA for surface roughness and total cutting force are approximately 6.59% and 1.41%, respectively.


## 6. Discussion

Figure5(a) shows the relationship between NCC content and total cutting force. As illustrated in this figure, the forces recorded when turning the PA 6/NCC composites are considerably lower compared to the pure PA 6. This is so because the NCC particles act as a lubricant in the cutting area. Therefore, the friction between the tool workpiece and chip tool decreases and causes the reduction of the total cutting force. But, the cutting area is saturated with excessive increasing of the lubricant particles and the reduction of the friction becomes negligible. Thus, the slope of decreasing force is decreased by increasing the NCC content.Figures5(b) and 5(c) demonstrate that the Fw increases with feed rate but decreases with the cutting speed. The first phenomenon is due to the increase of the cross-sectional area of the uncut chip which results in greater resistance in chip formation and consequently larger total cutting force. The second one is due to the thinning of the chips and the increasing of the shear angle which results in the plastic deformation of workpiece with lower strain thereby reducing the total cutting force and required power [13, 14].Figure5(d) shows that the value of  Ra increases when the feed rate does. According to the results of ANOVA on the surface roughness data, the cutting speed and NCC content do not have any statistical and physical effect on the surface roughness.As proved for all machining processes, two independent factors affect the final surface roughness [13, 15].(a)
The geometry of tool and the machining parameter of  feed rate affect the final surface roughness with clear trend and result in the ideal surface roughness.(b)
The irregularities and uncontrollable factors such as vibration in the cutting operation affect the final surface roughness with unknown trend and result in the natural surface roughness.The results illustrate that the turning of PA 6/NCC composites also follows from the general rule.


## 7. Conclusion

This research studied the effect of NCC content on the machinability of PA 6/NCC composite and modeling its machinability parameters using MHSNN. Total cutting force and surface roughness were investigated through turning process of PA 6/NCC composite and compared with that of the pure PA 6.The turning of PA 6/NCC composite proved to require less total cutting force than pure PA 6. This means that the NCC particles act as a lubricant to decrease the total cutting force. The turning of PA 6/NCC composites with different NCC content and pure PA 6 proved that the NCC is inefficient in terms of surface roughness. On the other hand, the effect of cutting parameters such as cutting speed and feed on the total cutting force and surface roughness in the turning of PA 6/nano CaCO3 composites is similar to that in the turning of metals.Modeling the mechanism of surface roughness formation and total cutting force were done by using MHSNN. The low errors in the predictions of neural networks illustrate the reliability and authority of MHSNN in modeling of PA 6/NCC composite’s turning. Therefore, the obtained MHSNN models for total cutting force and surface roughness can be used to optimize the turning process. Thus, to use the proposed procedure (prediction of surface roughness and total cutting force using MHSNN for obtaining an optimal surface finish or total cutting force) similar experiments must be done, the neural network must be trained to predict the surface roughness or total cutting force in the given conditions, and the predictive model must be optimized by an appropriate optimization algorithm such as harmony search algorithm.



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