# Composition Optimization of Glass-Like Casing and Its Novel Application in Mending Instable Borehole Wall

Authors: Zhi-jun Li; Yu Wang; Bao-lin Liu; Chun Yang
Journal: Advances in Materials Science and Engineering
 (2015)

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## Abstract

A glass-like casing was developed to mend the instable borehole due to its great similarities in compositions and structure. In order to boost the casing’s mechanical properties and lower its cost, different wt% additions of aluminum and quartz sand are added into the composition. Based on the outcomes of differential scanning calorimeter (DSC), it is suggested to be sintered at the temperature of 700°C. The results of X-ray diffraction (XRD) show that aluminum and SiO2 are its main crystalline phases. Its compression strength and the tensile strength range 5–14 Mpa and 0.5–4.5 Mpa, respectively, with the relative densities of between 1.00 g/cm3 and 1.19 g/cm3. In the end, a glass-based formula with 30 wt% aluminum and 40 wt% quartz sand is developed and experimentally applied.


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## Body

## 1. Introduction

Nowadays, wellbore instability has severely influenced the drilling efficiency [1]. In the past, the casing running is most frequently used to protect the well from being damaged. Mostly, however, the holes will be damaged at some certain parts; therefore, there is little point in practically mending the whole borehole wall. However, in most practical cases, the casing running will be applied from hole’s bottom to the orifice, a huge waste of steel casing. In order to reduce the huge cost, a novel technology of hot melting casing is developed. The original concept of this technology is derived from Subterrene drilling, which makes holes in rocks and soils through progressive melting instead of mechanical chipping. During the process of the Subterrene drilling, a glass-like casing can be formed according to the research conducted by Los Alamos National Lab [2–5].However, there are few attempts that have been made to research the composition as the glass-like casing. It is also a new attempt that combines the advanced material with the earth science—especially in geological engineering. Therefore, in order to make matters more understandable, a rough sketch Figure1 is sketched to show the process of the casing forming through the technology of hot melting [5, 6].Figure 1
Heat distribution during developing a hot melting casing.As is shown in Figure1, the heat is primarily generated from a center that is made of Carbon-Carbon. The heat is sequentially transferred to the crust and the glass-like material. When the glass-like material is heated to the transition temperature (Tg), it gradually gets transformed into liquid with certain liquidity so that the glass-like casing can be formed. However, the thermal diffusivities of the glass-like casing and the borehole wall are different, leading to a temperature gap at their interface, which makes the glass-like casing forming a reality [5].In this process, the heating temperature of the composition should be researched first since it has close relationships with the heating temperature and the design of other parts of the device. A relatively approximate melting temperature can be easily determined through the results of the DSC of the compositions.This heating temperature is the key to optimize the makings of other components of the hot melting machine, especially the coating of the heater shell. This heating temperature is primarily related to the composition’s fluidity. If the fluidity is lower enough, the glass-like composition will consequently stick to the shell. As a consequence, a coat has to be made onto the shell to prevent it from being damaged. Therefore, the research on the properties of the glass ceramic can be of great significance when it comes to the overall design of this technology.In this paper, a composition that is similar to the shale has been developed. It is the first time to apply this glass-like casing to mend the broken borehole wall and many problems have come into being [7]. For example, in field, there is commonly no time to make the material insulated for a long time; therefore, it is highly suggested to cool it down in one minute. This makes the heat treatment more complicated to be under control, especially when the heat treatment happens underground. In order to make experiments conditions similar to the actual field conditions as much as possible, the heat insulation has been gave up, and the material has been cooled down directly in air. Furthermore, the glass-like casing is formed in an irregular shape, making some researches, the electron probe, for example, inaccurately unavailable. Although it is uneasy to deal with the natural problems above, the influence of different additives on the compositions in terms of heating stability, crystal phase growth, and field application has also been researched [8].


## 2. Experiments

In terms of any material, lower cost shall be an essential requirement for its future application in field. The composition provided by Zhuhai Xuanyang Limited is selected to be the raw material (RM). Due to the raw material’s poor toughness and relatively high cost (RMB140 per 500 g), different wt% additives, aluminum (Al, RMB15 per 500 g), and quartz sand (QS, RMB 0.09 per 500 g) are added into the raw material. The components of different compositions are shown in Table1.Table 1
Components of different compositions for making a borehole casing.
Sample
RM (wt%)
Al (wt%)
QS (wt%)
A1
90
10
0
A2
80
20
0
A3
75
25
0
A4
70
30
0
B1
70
10
20
B2
50
20
30
B3
40
30
30
B4
30
30
40There are some advantages both in Al and in quartz sand as for a high-quality additive, due to not only its lower cost but also good toughness [9]. As a matrix in bulk metallic glass due to its good performance in good toughness, the addition of Al also predominately contributes to the mechanical properties of the compositions in our research [8]. Similarly, quartz sand has good performance in wear resistance and lower cost [10].XRD was applied to analyze the crystal phase because whether the crystal phase is beneficial for practical use or not is still unknown. For example, in our research, the crystal phase plays a positive role because it can boost material’s mechanical properties while having little influence on fluidity. In addition, in order to figure out the influence of adding different additives on the crystalline phase growth, the scanning electron microscope (SEM) was also applied. For its future practical use, the optimized composition was applied in a model prototype [7].


## 3. Results and Discussions

In order to heat the composition at a proper temperature, the DSC was applied to find out the specificTg. The results are plotted as in Figure 2 and Table 2.Table 2
T
g and melting point performance of different compositions.
Samples
T
g (°C)
Melting point (°C)
RW
460
770
A3
657
664
B4
657
666Figure 2
DSC results of samples RM,A3, and B4, respectively.The results show that theTg increases with the add-in Al, while the melting point decreases in terms of RM and A3. That mainly accounted for the lower melting point of Al—660°C, which is so close to the Tg of A3 and B4. So the add-in Al makes great contribution to lower the melting points of the compositions. The results above make great sense in figuring out a proper heating temperature (700°C). In addition, 7°C/second was selected to heat the composition, the maximum heating rate that our device can reach.However, whether the add-in Al or the newly generated crystal can improve the composition’s physical properties is still unknown. Therefore, the XRD (shown in Figure3) is performed on the samples.Figure 3
XRD patterns of different samples under the same condition, marked (a), (b), and (c).
(a)
(b)
(c)The results in Figure3(a) show that there is no typical crystal phase in RM, though it has a trend to form a peak, which is one of the typical properties of glass. However, the composition with add-in Al performs well in crystal phase (Figure 3(b)). Three different peaks represent different compounds phases: label “P” stands for the distribution of Al, label “S” stands for the distribution of SiO2, and label “Z” stands for the distribution of ZnO. This actually proves that the add-in Al contributes to the appearance of the crystal phases, including ZnO and SiO2, both of which did not actually appear in the RM.After QS is added into the composition, the “S” peak greatly goes up. Similarly, this is mainly because SiO2 is the main making of the QS. At the same time, the “Z” peak goes down with the addition of QS. However, whether the newly appearing crystal phase is beneficial for the composition’s mechanical properties or not is still unknown so far.In order to make a better comparison to the rock, the Brazilian Formula experiment for testing the tensile strength of the rock was applied to the samples of three. Since the tensile strength is far greater than the compressive strength of the rock, the sample at this condition is always in tension rather than compression failure of damage. This is the Brazilian method to test the tensile strength of brittle material mechanics theory.The results in Table3 show that the bulk density generally decreases with the add-in Al and QS, no matter for sample A or B. This is probably associated with the large porosity rates of the compositions. The results shown in the following SEM are also another proof to illustrate this. The compressive and tensile strength are roughly boosted by the addition of Al and QS. This is another proof that shows that the newly generated crystal definitely contributes to the increased the values of the compositions.Table 3
Physical and mechanical characteristics of the samples.
Samples
Bulk density,ρ
Compressive strength
Tensile strength
(g/cm3)
(Mpa)
(Mpa)
RW
3.20
6.5
1.5
A1
1.11
5.7
1.3
A2
1.03
6.0
1.4
A3
1.10
10.1
2.1
A4
1.12
6.9
1.7
B1
1.03
5.7
0.6
B2
1.12
11.3
2.8
B3
1.16
11.5
4.2
B4
1.19
14.0
4.4The outcomes of SEM (Figure4) suggest that samples A and B have much more porosity in comparison to RM. The lower bulk density, representing higher porosity, is accounted for as a consequence of different compositions and physical characteristics of the viscous flow during the heat treatment [11]. Interestingly, the overall rate of pores goes up at first and then down at the point of adding in 25 wt% Al. The increased pore rate is associated with the difficult in releasing CO2, due to the lack of insulation or the deformation of calcite (probably from the RM). The add-in Al also boosts the process of deformation, causing CO2 encapsulated by the crystal of Al [12–14]. When the Al is the only additive added into the composition, the interconnected pore is characterized by layered shape with the same size.Figure 4
SEM micrographs of (a) RM, (b)A1, (c) A2, (d) A3, (e) A4, (f) B1, (g) B2, (h) B3, and (i) B4.
(a)
(b)
(c)
(d)
(e)
(f)
(g)
(h)
(i)However, the layered shape of the pore is broken into more irregular ones with the add-in QS, reducing the overall porosity rate of the composition. This greatly contributes to the improved bulk density and mechanical properties. As is shown in Figure4(i), the pore line is obscure to be seen, of which the mechanical properties perform best among the all compositions.The results of Table3 and Figure 4 show that, with the increasing add-in Al, both of the compressive and tensile strength perform better, with the maximum 14.0 Mpa and 4.4 Mpa in B4 (30% RW, 30% Al, and 40% QS). In addition, its cost is relatively lower than others due to the greatest proportion of add-in QS, whose cost is comparatively lower than Al and RW. Taking the compressive and tensile strength and the lower cost together, the B4 with 30% Al, 30% RW, and 40% QS is eventually selected as the composition to be initially used in laboratory experiment.


## 4. Practical Application in Laboratory Experiment

In order to check whether the composition of the sampleB4 can be successfully applied in practice, as has been suggested as the most excellent candidate up to now, a device intended for this novel application was developed (shown in Figure 5). The composition was performed in different borehole wall using this device.Figure 5
Device for conducting this laboratory experiment.The laboratory experiment was conducted on a novel machine that was developed by our team. A carbon-carbon (C/C) was applied to generate heat, which is the original source for heating our selected compositions. The heat head consists of heat element of high strength graphite and external shell of GH742 alloy. The high strength graphite can work under 1200°C. Although the carbon-carbon composite is characterized by high strength and large thermal conductivity, it performs badly in resisting high temperature oxidation. Due to the special experiment equipment, the experimental test can be currently finished in our lab; however, the theoretically compressive and tensile pressure can be repeatedly obtained by the ordinary equipment to test mechanical properties.The results of Figure6 indicate that the compositions can be successfully used to form a glass-like casing with certain strength, no matter in rock or soil. However, many problems need to be solved through our further study, including the influences of heat treatment and components of compositions on its physical and mechanical properties.Figure 6
Experimental photos of the glass-like casing, (a) and (b) composition used in granite, heating up to 700°C, and (c) and (d) composition used in soil, heating up to 700°C.
(a)
(b)
(c)
(d)


## 5. Conclusions

Based on the researching results, the composition of sample B4 (30 wt% Al + 40 wt% QS + 30 wt% RM) has turned out to be a high potential for making glass-like casing. The add-in Al and QS contributes to the lower cost and the high-quality mechanical properties of the compositions due to the newly generated crystal, which has a positive influence on the composition that is intended for glass-like casing. Meanwhile, the addition of QS can boost the properties of the compositions by compressing its interconnected pores, lowering the overall porosity rate.



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*Source: 945475-2015-03-22.xml*