# Numerical Study on the Denitrification Efficiency of Selective Noncatalytic Reduction Technology in Decomposing Furnace

Authors: Shunsheng Xu; Jiazhen He; Fei Pei; Kun Li; Lele Liu; Zhiyong Dai
Journal: Journal of Chemistry
 (2020)

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## Abstract

In order to reduce the nitrogen oxide emission of cement plant, the denitrification of decomposing furnace is studied in this paper. Based on Fluent software platform, the 2500 t/d new dry-process cement kiln decomposing furnace of a plant is modeled and simulated by using air fractional combustion technology combined with selective noncatalytic reduction technology. The model and simulation methods are verified by the field test. The effects of the urea injection position and ammonia-nitrogen molar ratio on NO, NH3, and denitrification efficiency are studied by numerical simulation. The results show that the optimal injection position of the urea solution is 12 m, the optimal ammonia/nitrogen molar ratio is 1.8, and the optimal injection velocity of the urea solution is 40 m/s. The simulation results obtained under the optimal parameters are as follows: NO concentration is 187.60 mg/m3, NH3 escape is 32.40 mg/m3, and denitrification efficiency is 74.75%.


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## Body

## 1. Introduction

Cement industry is the third largest source of NOx pollution in China [1], and the resulting NOx can cause environmental problems such as acid rain and photochemical smog [2, 3], so it is urgent to carry out energy-saving and emission reduction technology transformation. At present, NOx emission reduction technologies mainly include low NOx burners, fractional combustion (fuel classification or air classification), selective catalytic reduction (SCR), and selective noncatalytic reduction (SNCR) [4]. SCR denitrification technology is highly efficient, but it is expensive and complicated, involving ammonia supply system, ammonia injection system, catalyst, and other systems [5, 6]. In contrast, SNCR denitrification technology has a low operating cost and can be applied in combination with various nitrogen oxide emission reduction technologies [7–10].Han et al. [11] conducted SNCR denitrification tests on power station boilers. The results showed that the optimal reaction temperature for denitrification of ammonia and urea solutions is about 1000°C, and the maximum denitrification efficiency of SNCR is about 90% under typical test conditions with an ammonia-nitrogen ratio of 1.5. Li and Wu [12] completed the simulation process of SNCR of the experimental device in CRF by numerical simulation. Li et al. [13] conducted a simulation study on the CFB boiler cyclone separator and analyzed the influence of temperature window and ammonia-nitrogen molar ratio (NSR) on denitrification efficiency. They found that the optimal temperature window is 850∼1050°C, and the optimal NSR is 1∼1.5. At present, SNCR technology research is mostly concentrated in the field of power station boilers. Due to the inhibitory effect of calcium compounds such as limestone on the reaction of SNCR in the decomposing furnace, there are relatively few research studies on SNCR in the field of cement decomposing furnace, which leads to the limitation of the development of this technology in the cement industry. However, because of its economy and convenience, SNCR technology has great potential in optimizing SNCR denitrification and improving SNCR denitrification efficiency of the decomposing furnace.Based on previous studies, this paper, based on Fluent software platform, simulates the SNCR denitrification based on the new dry cement kiln decomposing furnace air fractional combustion. The effects of the injection location of urea solution along the height of the decomposing furnace, the ammonia-nitrogen molar ratio, and the injection velocity of urea solution on the NO concentration, NH3 escape amount, and denitrification efficiency are studied in this paper. The formulated SNCR denitrification process parameters with better denitrification efficiency are obtained.


## 2. Numerical Simulation of SNCR in Decomposing Furnace

### 2.1. The Geometric Model

The object of this simulation is a decomposing furnace with an output of 2500 t/d in a cement plant in Hunan. The model of the decomposing furnace is modeled according to the actual scale, as shown in Figures1 and 2. The pulverized coal and primary air in the decomposing furnace are sprayed into the furnace through the coal injection pipes on both sides of the lower column. The high-temperature flue gas from the end of the decomposing kiln enters the furnace through the bottom of the cone and is mixed with the pulverized coal airflow and the tertiary air for ignition and combustion [14]. The burnout air is sprayed into the furnace from the middle of the lower column, so that the pulverized coal and raw materials escaping from the core combustion zone continue to burn and decompose [15].Figure 1
Geometry model of the decomposing furnace.Figure 2
Dimensions of the decomposing furnace.This article uses the ICEM software for simulating structural mesh, for improving the quality of the mesh, on the whole decomposing furnace using O-mesh technology, and the decomposing furnace reducing part and each entrance area mesh refinement processing, the calculation mesh is shown in Figure3. The total number of grids was determined to be about 850,000 through mesh independence verification.Figure 3
Decomposing furnace meshing diagram.


### 2.2. Calculation Model

The decomposing furnace model is complex and contains multiple high-speed airflow and mixed flow. The RNGk-ε model can better deal with the strong turbulent flow with high strain velocity and large flow line bending degree [16, 17], which is adopted for the gas-phase turbulence model in this study. The calculation formula is shown in the following equations:(1)∂ρk∂t+∂ρkμi∂xi=∂∂xjαkμ+μt∂k∂xj+Gk+ρε,(2)∂ρε∂t+∂ρεμi∂xi=∂∂xjαεμ+μt∂k∂xj+C1ε∗kGk−C2ερε2k,where ρ is the density of the gas, kg/m3; k is turbulent kinetic energy, J; ε is the turbulent dissipation velocity; μ is the molecular viscosity coefficient; μt is the turbulent viscosity coefficient; and C is the constant term coefficient.Based on the detailed chemical reaction process of turbulent combustion in the decomposing furnace, component transport model and eddy dissipation conceptual model (EDC) are selected in this paper, in which the diffusion/dynamic model is used for coke combustion and limestone decomposing. The moisture only considers evaporative heat absorption. The NOx reaction model included in Fluent is selected for the pollutant model. Since under the condition of fractional air and furnace temperature (less than 1000°C) of the decomposing furnace, the rapid NOx and thermal NOx generated by the combustion of pulverized coal particles are few and negligible, only fuel NOx is considered in the simulation, and the SCNR model is activated to use urea as the reducing agent of the reaction. According to the characteristics of pulverized coal particles and urea particles in the furnace, the discrete phase model (DPM) is used to calculate the particle phase flow, and the diameter of urea droplets is set at 50–200 μm. Since the proportion of particles in the mixed phase is less than 10%, the particles (assumed to be spherical) are regarded as the dilute phase, and the interactions between particles could be ignored, and only the resistance and gravity are taken into account [18, 19]. The temperature in the furnace is relatively high, and the temperature in the core combustion zone is about 1250 K. The main heat transfer mode is radiation heat transfer, so the radiation model adopts p1 model [20]. The chemical reaction mechanism of all NOx involved in the decomposing furnace with limestone is shown in Table 1.Table 1
The equations of the conversion of NOx and limestone.
No.Reactionskf=ATbexp−E/RTA (s−1)bE (kJ/mol)(R1)NH3+1.25O2⟶NO+1.5H2O3.10E + 0808.31E + 07(R2)NH3+0.75O2⟶0.5N2+1.5H2O4.96E + 0808.31E + 07(R3)HCN+0.75O2⟶CNO+0.5H2O2.14E + 0408.31E + 07(R4)CNO+0.5O2⟶NO+CO1.02E + 1202.12E + 08(R5)CNO+NO⟶N2O+CO1.02E + 1202.12E + 08(R6)NO+NH3+0.25O2⟶N2+1.5H2O1.10E + 1202.77E + 04(R7)NO+CO⟶0.5N2+CO21.95E + 0701.58E + 08(R8)NO2+0.5O2⟶N2+O21.50E + 1101.68E + 08(R9)N2O+CO⟶N2+CO21.24E + 0904.92E + 07(R10)CONH22⟶NH3+HNCO1.27E + 0401.55E + 04(R11)CONH22+H2O⟶2NH3+CO26.13E + 1002.10E + 04(R12)CaCO3⟶CaO+CO26.08E + 0402.05E + 08


### 2.3. The Boundary Conditions

The boundary conditions of decomposing furnaces are summarized as shown in Tables2 and 3 through the operating parameters, coal burning analysis data, and reasonable assumptions of running kilns.Table 2
Boundary conditions.
The boundary conditionsTemperature (K)Mass flow (kg/s)Velocity (m/s)Pressure (Pa)Tertiary air (reducing air/burnout air)130018.57 (15.83/2.74)——Decomposing furnace flue gas1400—30—Pulverized coal3212.68——Primary air321—45—CaCO3120035.45——Decomposing furnace outlet———−1200Table 3
Ultimate analysis of coal.
Ultimate analysis (wt. %)Lower heating valueQnet (kJ/kg)CarHarOarNarSarAarMarVdaf62.162.876.310.760.9119.767.2324.6932789.3


### 2.4. SNCR Denitrification Design

In the process of SNCR denitrification, the main factors influencing the denitrification effect are reaction temperature, residence time of reducing agent, mixing degree of reducing agent, and flue gas and ammonia-nitrogen molar ratio. Combined with the actual situation of the cement manufacturing process, this paper mainly studied the effect of the injection location of urea solution, NSR, and injection speed of urea solution on denitrification. At the same time, in order to achieve the uniform mixing of the urea solution and the NOx in the flue gas, this article will arrange four symmetrical nozzles along the different decomposing furnace height positions, and the specific layout position is shown as 1, 2, 3, and 4 in Figure 1.The SNCR denitrification was studied using numerical simulation combined with experimental study, and the details are as follows:(1)
Firstly, a combustion model of the 2500 t/d decomposing furnace was established. According to the established combustion model, the numerical simulation of the decomposing furnace was carried out by Fluent software. In order to validate the reliability of the combustion model, a series of experiments was performed on the 2500 t/d decomposing furnace. The temperature of the furnace outlet was measured by the gas pump thermocouple, and the flue gas composition was measured by the KM940 flue gas analyzer. The simulation results were compared with the experimental results to obtain a more reliable decomposing furnace combustion model.(2)
Secondly, the SNCR denitrification reaction is added to the obtained combustion model. The effects of the injection location of the urea solution, NSR, and the injection speed of the urea solution on SNCR denitrification were studied by numerical simulation. The urea solution is injected into the furnace at the heights of 6, 8, 10, 12, 14, 16, and 18 m, respectively. The NSR gradually increases from 1.0 to 2.0, whose increment is 0.2. The injection velocities of the urea solution are 20, 40, 60, and 80 m/s, respectively. The desulfurization efficiency and nitrogen oxide emissions under various parameters can be obtained by numerical simulation, and the process parameters with the best desulfurization effect can be concluded.(3)
Finally, based on the simulation results, the operation parameters of the 2500 t/d decomposition furnace were adjusted, and the temperature and flue gas composition of the decomposition furnace outlet were measured again. Then the measured results are compared with the simulation results to provide a reliable basis for the simulated parameters.


## 2.1. The Geometric Model

The object of this simulation is a decomposing furnace with an output of 2500 t/d in a cement plant in Hunan. The model of the decomposing furnace is modeled according to the actual scale, as shown in Figures1 and 2. The pulverized coal and primary air in the decomposing furnace are sprayed into the furnace through the coal injection pipes on both sides of the lower column. The high-temperature flue gas from the end of the decomposing kiln enters the furnace through the bottom of the cone and is mixed with the pulverized coal airflow and the tertiary air for ignition and combustion [14]. The burnout air is sprayed into the furnace from the middle of the lower column, so that the pulverized coal and raw materials escaping from the core combustion zone continue to burn and decompose [15].Figure 1
Geometry model of the decomposing furnace.Figure 2
Dimensions of the decomposing furnace.This article uses the ICEM software for simulating structural mesh, for improving the quality of the mesh, on the whole decomposing furnace using O-mesh technology, and the decomposing furnace reducing part and each entrance area mesh refinement processing, the calculation mesh is shown in Figure3. The total number of grids was determined to be about 850,000 through mesh independence verification.Figure 3
Decomposing furnace meshing diagram.


## 2.2. Calculation Model

The decomposing furnace model is complex and contains multiple high-speed airflow and mixed flow. The RNGk-ε model can better deal with the strong turbulent flow with high strain velocity and large flow line bending degree [16, 17], which is adopted for the gas-phase turbulence model in this study. The calculation formula is shown in the following equations:(1)∂ρk∂t+∂ρkμi∂xi=∂∂xjαkμ+μt∂k∂xj+Gk+ρε,(2)∂ρε∂t+∂ρεμi∂xi=∂∂xjαεμ+μt∂k∂xj+C1ε∗kGk−C2ερε2k,where ρ is the density of the gas, kg/m3; k is turbulent kinetic energy, J; ε is the turbulent dissipation velocity; μ is the molecular viscosity coefficient; μt is the turbulent viscosity coefficient; and C is the constant term coefficient.Based on the detailed chemical reaction process of turbulent combustion in the decomposing furnace, component transport model and eddy dissipation conceptual model (EDC) are selected in this paper, in which the diffusion/dynamic model is used for coke combustion and limestone decomposing. The moisture only considers evaporative heat absorption. The NOx reaction model included in Fluent is selected for the pollutant model. Since under the condition of fractional air and furnace temperature (less than 1000°C) of the decomposing furnace, the rapid NOx and thermal NOx generated by the combustion of pulverized coal particles are few and negligible, only fuel NOx is considered in the simulation, and the SCNR model is activated to use urea as the reducing agent of the reaction. According to the characteristics of pulverized coal particles and urea particles in the furnace, the discrete phase model (DPM) is used to calculate the particle phase flow, and the diameter of urea droplets is set at 50–200 μm. Since the proportion of particles in the mixed phase is less than 10%, the particles (assumed to be spherical) are regarded as the dilute phase, and the interactions between particles could be ignored, and only the resistance and gravity are taken into account [18, 19]. The temperature in the furnace is relatively high, and the temperature in the core combustion zone is about 1250 K. The main heat transfer mode is radiation heat transfer, so the radiation model adopts p1 model [20]. The chemical reaction mechanism of all NOx involved in the decomposing furnace with limestone is shown in Table 1.Table 1
The equations of the conversion of NOx and limestone.
No.Reactionskf=ATbexp−E/RTA (s−1)bE (kJ/mol)(R1)NH3+1.25O2⟶NO+1.5H2O3.10E + 0808.31E + 07(R2)NH3+0.75O2⟶0.5N2+1.5H2O4.96E + 0808.31E + 07(R3)HCN+0.75O2⟶CNO+0.5H2O2.14E + 0408.31E + 07(R4)CNO+0.5O2⟶NO+CO1.02E + 1202.12E + 08(R5)CNO+NO⟶N2O+CO1.02E + 1202.12E + 08(R6)NO+NH3+0.25O2⟶N2+1.5H2O1.10E + 1202.77E + 04(R7)NO+CO⟶0.5N2+CO21.95E + 0701.58E + 08(R8)NO2+0.5O2⟶N2+O21.50E + 1101.68E + 08(R9)N2O+CO⟶N2+CO21.24E + 0904.92E + 07(R10)CONH22⟶NH3+HNCO1.27E + 0401.55E + 04(R11)CONH22+H2O⟶2NH3+CO26.13E + 1002.10E + 04(R12)CaCO3⟶CaO+CO26.08E + 0402.05E + 08


## 2.3. The Boundary Conditions

The boundary conditions of decomposing furnaces are summarized as shown in Tables2 and 3 through the operating parameters, coal burning analysis data, and reasonable assumptions of running kilns.Table 2
Boundary conditions.
The boundary conditionsTemperature (K)Mass flow (kg/s)Velocity (m/s)Pressure (Pa)Tertiary air (reducing air/burnout air)130018.57 (15.83/2.74)——Decomposing furnace flue gas1400—30—Pulverized coal3212.68——Primary air321—45—CaCO3120035.45——Decomposing furnace outlet———−1200Table 3
Ultimate analysis of coal.
Ultimate analysis (wt. %)Lower heating valueQnet (kJ/kg)CarHarOarNarSarAarMarVdaf62.162.876.310.760.9119.767.2324.6932789.3


## 2.4. SNCR Denitrification Design

In the process of SNCR denitrification, the main factors influencing the denitrification effect are reaction temperature, residence time of reducing agent, mixing degree of reducing agent, and flue gas and ammonia-nitrogen molar ratio. Combined with the actual situation of the cement manufacturing process, this paper mainly studied the effect of the injection location of urea solution, NSR, and injection speed of urea solution on denitrification. At the same time, in order to achieve the uniform mixing of the urea solution and the NOx in the flue gas, this article will arrange four symmetrical nozzles along the different decomposing furnace height positions, and the specific layout position is shown as 1, 2, 3, and 4 in Figure 1.The SNCR denitrification was studied using numerical simulation combined with experimental study, and the details are as follows:(1)
Firstly, a combustion model of the 2500 t/d decomposing furnace was established. According to the established combustion model, the numerical simulation of the decomposing furnace was carried out by Fluent software. In order to validate the reliability of the combustion model, a series of experiments was performed on the 2500 t/d decomposing furnace. The temperature of the furnace outlet was measured by the gas pump thermocouple, and the flue gas composition was measured by the KM940 flue gas analyzer. The simulation results were compared with the experimental results to obtain a more reliable decomposing furnace combustion model.(2)
Secondly, the SNCR denitrification reaction is added to the obtained combustion model. The effects of the injection location of the urea solution, NSR, and the injection speed of the urea solution on SNCR denitrification were studied by numerical simulation. The urea solution is injected into the furnace at the heights of 6, 8, 10, 12, 14, 16, and 18 m, respectively. The NSR gradually increases from 1.0 to 2.0, whose increment is 0.2. The injection velocities of the urea solution are 20, 40, 60, and 80 m/s, respectively. The desulfurization efficiency and nitrogen oxide emissions under various parameters can be obtained by numerical simulation, and the process parameters with the best desulfurization effect can be concluded.(3)
Finally, based on the simulation results, the operation parameters of the 2500 t/d decomposition furnace were adjusted, and the temperature and flue gas composition of the decomposition furnace outlet were measured again. Then the measured results are compared with the simulation results to provide a reliable basis for the simulated parameters.


## 3. Combustion Simulation and Experimental Verification

### 3.1. Simulation Analysis of Temperature Field and Concentration Field

The simulation results of combustion temperature and concentration of each component in the decomposing furnace are shown in Figure4. The combustion temperature in the decomposing furnace is shown in Figure 4(a). The junction of the bottom cone and the lower column of the decomposing furnace is the core combustion zone. The highest combustion temperature is 1400 K and the average temperature is about 1250 K. The temperature distribution in the decomposing furnace is relatively uniform, which basically meets the requirements of the raw material decomposing process. After passing through the core combustion zone, the temperature gradually decreases along the Z-axis direction, and the temperature rises slightly when passing through the upper column, until the outlet temperature of the decomposing furnace drops to 1200 K. The distribution of O2, CO2, and CO is shown in Figures 4(b)–4(d). In the core combustion area, pulverized coal burns violently, and due to the large consumption of oxygen, the O2 concentration drops sharply. Meanwhile, the CO2 concentration increases rapidly and is accompanied by the generation of CO. The O2 concentration at the outlet of the decomposing furnace drops to 1.26%, the CO2 concentration increases to 31%, and the CO concentration value is 0.88%. The distribution cloud diagram of NO is shown in Figure 4(e). The concentration of NO in the cone of the decomposing furnace is relatively small, and in a local area, NO is generated in large amount with the pyrolysis of volatiles, and its peak value is 1648 mg/m3. As the height of the furnace increases, the tertiary air enters the furnace in stages, and a reducing atmosphere is generated due to fuel-rich combustion above the core combustion zone. Part of the NO is reduced along the height of the decomposing furnace, which gradually reduces the NO concentration. The unburned residual pulverized coal in the core area will be burned with the over-fire air as the smoke rises, and the secondary combustion will occur, which will increase the CO2 concentration in the flue gas and gradually increase the NO concentration. The final NO concentration at the outlet of the decomposing furnace is 743 mg/m3.Figure 4
Numerical simulation of combustion in the decomposing furnace. (a) Temperature. (b) O2. (c) CO2. (d) CO. (e) NO.
(a)(b)(c)(d)(e)


### 3.2. Experimental Verification

In this paper, based on the feasibility of measurement, the flue gas temperature and component concentration at the outlet of the Chenzhou 2500 t/d decomposing furnace are measured and compared with the simulation results. Four measuring points are set at the outlet of the decomposing furnace, and the positions are 0, 0.5, 1.0, and 1.5 m away from the center of the measuring point. Exhaust thermocouple (s-type thermocouple, Siemens (China) Co., LTD.) was used to measure the temperature of flue gas. The KM940 flue gas analyzer made in Britain with high test accuracy and high temperature adaptability is used to measure the concentration of flue gas components. In order to reduce the influence of zero drift of the instrument itself on the accuracy of the test, the instrument used before the test shall be strictly calibrated according to the regulations. Test values and simulation values of decomposing furnace outlet parameters are summarized in Table4. It can be found from Table 4 that the error between the simulation results and the actual measured values is small, so the experimental results can be replaced by simulation. The simulation data used to support the findings of this study are included within the article, and the experimental data used to support the findings of this study are available from the corresponding author upon request.Table 4
Comparison of the measured data and simulated data.
Data categoriesDecomposing furnace outlet flue gas temperature (K)Mass fraction (%)Concentration (mg/m3)abcdO2CO2CONOExperimental data1302.81310.41303.41283.23.1073.10.18787.30Simulation data1327.11337.71266.01240.02.9069.30.19743Relative error1.872.082.943.346.755.105.565.97


## 3.1. Simulation Analysis of Temperature Field and Concentration Field

The simulation results of combustion temperature and concentration of each component in the decomposing furnace are shown in Figure4. The combustion temperature in the decomposing furnace is shown in Figure 4(a). The junction of the bottom cone and the lower column of the decomposing furnace is the core combustion zone. The highest combustion temperature is 1400 K and the average temperature is about 1250 K. The temperature distribution in the decomposing furnace is relatively uniform, which basically meets the requirements of the raw material decomposing process. After passing through the core combustion zone, the temperature gradually decreases along the Z-axis direction, and the temperature rises slightly when passing through the upper column, until the outlet temperature of the decomposing furnace drops to 1200 K. The distribution of O2, CO2, and CO is shown in Figures 4(b)–4(d). In the core combustion area, pulverized coal burns violently, and due to the large consumption of oxygen, the O2 concentration drops sharply. Meanwhile, the CO2 concentration increases rapidly and is accompanied by the generation of CO. The O2 concentration at the outlet of the decomposing furnace drops to 1.26%, the CO2 concentration increases to 31%, and the CO concentration value is 0.88%. The distribution cloud diagram of NO is shown in Figure 4(e). The concentration of NO in the cone of the decomposing furnace is relatively small, and in a local area, NO is generated in large amount with the pyrolysis of volatiles, and its peak value is 1648 mg/m3. As the height of the furnace increases, the tertiary air enters the furnace in stages, and a reducing atmosphere is generated due to fuel-rich combustion above the core combustion zone. Part of the NO is reduced along the height of the decomposing furnace, which gradually reduces the NO concentration. The unburned residual pulverized coal in the core area will be burned with the over-fire air as the smoke rises, and the secondary combustion will occur, which will increase the CO2 concentration in the flue gas and gradually increase the NO concentration. The final NO concentration at the outlet of the decomposing furnace is 743 mg/m3.Figure 4
Numerical simulation of combustion in the decomposing furnace. (a) Temperature. (b) O2. (c) CO2. (d) CO. (e) NO.
(a)(b)(c)(d)(e)


## 3.2. Experimental Verification

In this paper, based on the feasibility of measurement, the flue gas temperature and component concentration at the outlet of the Chenzhou 2500 t/d decomposing furnace are measured and compared with the simulation results. Four measuring points are set at the outlet of the decomposing furnace, and the positions are 0, 0.5, 1.0, and 1.5 m away from the center of the measuring point. Exhaust thermocouple (s-type thermocouple, Siemens (China) Co., LTD.) was used to measure the temperature of flue gas. The KM940 flue gas analyzer made in Britain with high test accuracy and high temperature adaptability is used to measure the concentration of flue gas components. In order to reduce the influence of zero drift of the instrument itself on the accuracy of the test, the instrument used before the test shall be strictly calibrated according to the regulations. Test values and simulation values of decomposing furnace outlet parameters are summarized in Table4. It can be found from Table 4 that the error between the simulation results and the actual measured values is small, so the experimental results can be replaced by simulation. The simulation data used to support the findings of this study are included within the article, and the experimental data used to support the findings of this study are available from the corresponding author upon request.Table 4
Comparison of the measured data and simulated data.
Data categoriesDecomposing furnace outlet flue gas temperature (K)Mass fraction (%)Concentration (mg/m3)abcdO2CO2CONOExperimental data1302.81310.41303.41283.23.1073.10.18787.30Simulation data1327.11337.71266.01240.02.9069.30.19743Relative error1.872.082.943.346.755.105.565.97


## 4. Analysis of SNCR Simulation Results

### 4.1. Analysis of Results of Urea Solution Injection Position

The injection position of the urea solution determines the residence time of the urea in the furnace and the temperature conditions under which the urea reacts. When injected into the low position, the residence time is long, but the reaction temperature is too high, and the urea is easily oxidized; when injected into the high position, the reaction temperature is too low and the residence time is short, which easily leads to an increase in the amount of NH3 escape. This article selects the urea solution spray into the position, respectively, along the height direction (the Z-axis) of the decomposing furnace is 6, 8, 10, 12, 14, 16, and 18 m, and its temperature ranges from 950 to 1250 K.The distribution of NO and NH3 mass flow at different heights of the decomposing furnace under different injection positions of urea solution is shown in Figure 5. Under different incident positions of urea solution, the concentration of NO and NH3 in the decomposing furnace generally increases first and then decreases. The combustion of pulverized coal particles in the core combustion zone and the reducing tertiary air produces a large amount of NO, which causes a sharp increase in the NO concentration at the junction of the decomposing furnace cone and the lower half of the cylinder. Fuel-rich combustion in the core combustion zone consumes a large amount of oxygen due to the tertiary air classification. A reducing atmosphere is generated above the core combustion zone to reduce part of the NO, and the increase in NO concentration becomes slower. When the urea solution is injected into the decomposing furnace from a low height, the residence time of the urea solution is long and the reaction temperature is too high, which causes the urea to be easily oxidized. When the urea solution is injected into the decomposing furnace from a high height, the residence time of the urea solution is short and the reaction temperature is too low, which results in an increase in the concentration of NH3 escape. The distribution curve of NO and NH3 concentrations in the cross section of different injection heights of decomposing furnaces is shown in Figures 5(a) and 5(b). From Figures 5(a) and 5(b), when the injection height is 6 m, the peak concentrations of NO and NH3 are lower. The reason is that the urea solution enters the furnace at a lower position, which is close to the core combustion zone. And its average temperature is about 1300 K, which causes some of the NH3 and HNCO produced by the decomposing of urea to be oxidized to NO. Combined with the reducing ability of the urea decomposing product itself and the reason for being oxidized at high temperature, the two restrict each other and cause the lower peak concentration of NO and NH3 in the furnace. When the injection heights are 16 and 18 m, the NO concentration is increasing under the height of the decomposing furnace below 15 m, and its peak value is 1491 mg/m3. And when the injection height is 16 m, the NH3 escape amount is the largest, which is caused by the urea solution injection position being too high and the residence time shortened.Figure 5
Flow curves of NO and NH3 in the decomposing furnace under different injection positions. (a) NO and (b) NH3.
(a)(b)From the above analysis, it can be seen that the injection position of the urea solution has a significant influence on the ability to reduce nitrogen oxides. The variations of NO concentration and NH3 escape concentration with injection height of urea solution are shown in Figure 6, and the variation of denitrification efficiency with injection height of urea solution is shown in Figure 7. The NO concentration and NH3 escape concentration curves are “U” and “M,” respectively. When the injection height of the urea solution increases, the NO concentration at the outlet of the decomposing furnace decreases first and then increases. Especially when the injection position is more than 16 m, the NO concentration rapidly increases from 207 mg/m3 to 320 mg/m3, and the amount of NH3 escaping decreased significantly from 83.46 mg/m3 to 39.65 mg/m3. The reason is that the wind is divided into three winds (burnout wind) into the furnace and mixes with the flue gas, and the combustion of residual coal powder increases the temperature of the upper half of the column in the decomposing furnace, so that part of NH3 is oxidized to NO. When the injection height is 12 m, the NO concentration and the escape amount of NH3 are at a low level. It can be seen from Figure 7 that the SNCR denitrification efficiency curves at different heights are “inverted U,” and the denitrification nitration efficiency increases first and then decreases as the injection position increases. A comprehensive analysis of the simulation results of SNCR at different injection heights of urea solution shows that the optimized injection height is 12 m. At this time, the NO concentration is 176 mg/m3, the amount of NH3 escape is 39.98 mg/m3, and the denitrification efficiency is 76.26%.Figure 6
NO concentration and NH3 of outlet under different injection positions.Figure 7
Denitrification efficiency under different injection positions.


### 4.2. Analysis of Ammonia-Nitrogen Molar Ratio (NSR) Results

According to the above SNCR chemical reaction principle, it is known that theoretically reducing 1 mol of NO requires 1 mol of NH3, which is NSR is equal to 1. However, in practical engineering applications, it cannot guarantee that all decomposed NH3 completely reacts with NO in the flue gas due to the complicated chemical reaction of urea and the complicated mixing process of the gas flow in the decomposing furnace. When NSR is greater than 2, excessive consumption of reducing agent will increase the running cost and increase the amount of NH3 escape. The research scheme of the effect of different ammonia-nitrogen ratios (NSR) on denitrification is as follows: keep other parameter settings unchanged (from the above analysis results, the injection height of the urea solution is maintained at 12 m, and the NSR gradually increased from 1.0 to 2.0 (successive increments are 0.2)), and carry out simulation research on five sets of NSR schemes.The variations of concentrations of NO and NH3 in the decomposing furnace with NSR are shown in Figure 8. From the analysis in Figure 8, with different NSR, changes in the NOx and NH3 concentration in the decomposing furnace are more obvious. When the decomposing furnace height is below 11 m, the changes of NO and NH3 concentrations in the furnace are basically synchronized. Between 11 m and 13 m, as the NSR increases, the peak value of NO concentration in the furnace decreases, and the peak value of NH3 concentration increases. When the height of the decomposing furnace is more than 15 m, the NO concentration in the decomposing furnace generally decreases, and the slope of the NO curve increases with the increase of NSR. The reason is that when NSR is 1, the reduction reaction velocity increases with the increase of NSR, so more NO will be reduced. However, when NSR reached 1.8, NO in the decomposer had reached a low concentration and could not be reduced easily. If NH3 continues to be increased, it will not only improve the denitrification efficiency, but also increase the NH3 escapement.Figure 8
Flow curves of NO (a) and NH3 (b) in the decomposing furnace with different NSR.
(a)(b)The variations of NO concentration and NH3 escape amount at the outlet of the decomposing furnace with NSR are shown in Figure 9. It can be seen from Figure 9 that the change trend of the NO concentration and the NH3 escape amount line is just the opposite. With the increase of NSR, the NO concentration gradually decreases and the NH3 escape amount gradually increases. When the NSR is 1.0, the NO concentration and NH3 escape concentration are 373.94 mg/m3 and 16.42 mg/m3, respectively. At this time, the NO concentration of the decomposing furnace is the highest. When the NSR is greater than 1.8, the NH3 escape concentration rises linearly, and the NO concentration decreases slowly at this time, indicating that the urea’s ability to reduce NO tends to be saturated. The denitrification efficiency curves at different NSR are shown in Figure 10. It can be seen from Figure 10 that the denitrification efficiency increases with increasing NSR. Comprehensive analysis of SNCR simulation results under different NSR shows that when the NSR is increased from 1.0 to 1.8, the denitrification efficiency is relatively evenly improved. This is because the NO concentration in the furnace is higher at this time, and the SNCR reaction is stronger. Increasing NSR will allow more NO to be reduced. But when the NSR is greater than 1.8, the denitrification efficiency rise velocity begins to decrease, and the amount of NH3 escape will increase much, so the optimal NSR is 1.8. Under this condition, the NO concentration of the decomposing furnace is 187.60 mg/m3, the NH3 escape concentration is 32.40 mg/m3, and the denitrification efficiency is 74.75%.Figure 9
Variation of NO concentration and NH3 escape concentration at the outlet of the decomposing furnace with NSR.Figure 10
Variation of denitrification efficiency with NSR.


### 4.3. Analysis of Urea Spray Velocity Results

The influence of the spraying velocity of the urea solution on the denitrification effect is mainly manifested in two aspects: the mixing degree of the urea solution with the mainstream smoke and the evaporation speed of the urea solution. Based on the above research, when the injection height of the reducing agent is 12 m and the molar ratio of ammonia and nitrogen is 1.8, simulations of different reducing agent injection velocity are performed. The jet velocity is from 20, 40, 60, and 80 m/s in order from low to high.The variations of evaporation time and denitrification efficiency of urea solution in the decomposing furnace with the spray velocity are shown in Figure11. The variation of NO concentration and NH3 escape concentration at the outlet of the decomposing furnace with the spray velocity of urea solution is shown in Figure 12. It can be seen from Figure 11 that the denitrification efficiency gradually increases with the increase in spraying velocity. Increasing the spray velocity and increasing the mixing speed of the urea solution and the flue gas in the decomposing furnace strengthen the heat transfer between the main flue gas stream and the urea solution, which accelerates the evaporation process of the urea solution and makes the urea decompose in advance in a suitable temperature window. At the same time, the increase of the spray velocity is conducive to extending the range of the urea solution in the depth direction of the decomposing furnace, thereby enhancing the degree of mixing of urea and the main flue gas stream and improving the denitrification efficiency. It can be seen from Figure 12 that the urea solution spray velocity increases, and the NH3 concentration at the outlet of the decomposing furnace decreases first and then increases. This indicates that there is an optimal value for the injection velocity, and beyond this optimal value, the denitrification effect is not significantly improved, and at the same time, the NH3 escape concentration at the outlet of the decomposing furnace is increased.Figure 11
Evaporation time of urea solution and denitrification efficiency at different injection velocities.Figure 12
The variations of NO and NH3 concentrations at the outlet of the decomposing furnace with spray velocity.Based on the analysis in Figures11 and 12, it can be seen that it is reasonable to choose a urea solution spray velocity of 40 m/s. At this time, the urea solution evaporation time is 0.038 s, and the NO concentration and NH3 escape concentration at the outlet of the decomposing furnace are 350 mg/m3 and 9.02 mg/m3, and the denitrification efficiency is 63.54%.


## 4.1. Analysis of Results of Urea Solution Injection Position

The injection position of the urea solution determines the residence time of the urea in the furnace and the temperature conditions under which the urea reacts. When injected into the low position, the residence time is long, but the reaction temperature is too high, and the urea is easily oxidized; when injected into the high position, the reaction temperature is too low and the residence time is short, which easily leads to an increase in the amount of NH3 escape. This article selects the urea solution spray into the position, respectively, along the height direction (the Z-axis) of the decomposing furnace is 6, 8, 10, 12, 14, 16, and 18 m, and its temperature ranges from 950 to 1250 K.The distribution of NO and NH3 mass flow at different heights of the decomposing furnace under different injection positions of urea solution is shown in Figure 5. Under different incident positions of urea solution, the concentration of NO and NH3 in the decomposing furnace generally increases first and then decreases. The combustion of pulverized coal particles in the core combustion zone and the reducing tertiary air produces a large amount of NO, which causes a sharp increase in the NO concentration at the junction of the decomposing furnace cone and the lower half of the cylinder. Fuel-rich combustion in the core combustion zone consumes a large amount of oxygen due to the tertiary air classification. A reducing atmosphere is generated above the core combustion zone to reduce part of the NO, and the increase in NO concentration becomes slower. When the urea solution is injected into the decomposing furnace from a low height, the residence time of the urea solution is long and the reaction temperature is too high, which causes the urea to be easily oxidized. When the urea solution is injected into the decomposing furnace from a high height, the residence time of the urea solution is short and the reaction temperature is too low, which results in an increase in the concentration of NH3 escape. The distribution curve of NO and NH3 concentrations in the cross section of different injection heights of decomposing furnaces is shown in Figures 5(a) and 5(b). From Figures 5(a) and 5(b), when the injection height is 6 m, the peak concentrations of NO and NH3 are lower. The reason is that the urea solution enters the furnace at a lower position, which is close to the core combustion zone. And its average temperature is about 1300 K, which causes some of the NH3 and HNCO produced by the decomposing of urea to be oxidized to NO. Combined with the reducing ability of the urea decomposing product itself and the reason for being oxidized at high temperature, the two restrict each other and cause the lower peak concentration of NO and NH3 in the furnace. When the injection heights are 16 and 18 m, the NO concentration is increasing under the height of the decomposing furnace below 15 m, and its peak value is 1491 mg/m3. And when the injection height is 16 m, the NH3 escape amount is the largest, which is caused by the urea solution injection position being too high and the residence time shortened.Figure 5
Flow curves of NO and NH3 in the decomposing furnace under different injection positions. (a) NO and (b) NH3.
(a)(b)From the above analysis, it can be seen that the injection position of the urea solution has a significant influence on the ability to reduce nitrogen oxides. The variations of NO concentration and NH3 escape concentration with injection height of urea solution are shown in Figure 6, and the variation of denitrification efficiency with injection height of urea solution is shown in Figure 7. The NO concentration and NH3 escape concentration curves are “U” and “M,” respectively. When the injection height of the urea solution increases, the NO concentration at the outlet of the decomposing furnace decreases first and then increases. Especially when the injection position is more than 16 m, the NO concentration rapidly increases from 207 mg/m3 to 320 mg/m3, and the amount of NH3 escaping decreased significantly from 83.46 mg/m3 to 39.65 mg/m3. The reason is that the wind is divided into three winds (burnout wind) into the furnace and mixes with the flue gas, and the combustion of residual coal powder increases the temperature of the upper half of the column in the decomposing furnace, so that part of NH3 is oxidized to NO. When the injection height is 12 m, the NO concentration and the escape amount of NH3 are at a low level. It can be seen from Figure 7 that the SNCR denitrification efficiency curves at different heights are “inverted U,” and the denitrification nitration efficiency increases first and then decreases as the injection position increases. A comprehensive analysis of the simulation results of SNCR at different injection heights of urea solution shows that the optimized injection height is 12 m. At this time, the NO concentration is 176 mg/m3, the amount of NH3 escape is 39.98 mg/m3, and the denitrification efficiency is 76.26%.Figure 6
NO concentration and NH3 of outlet under different injection positions.Figure 7
Denitrification efficiency under different injection positions.


## 4.2. Analysis of Ammonia-Nitrogen Molar Ratio (NSR) Results

According to the above SNCR chemical reaction principle, it is known that theoretically reducing 1 mol of NO requires 1 mol of NH3, which is NSR is equal to 1. However, in practical engineering applications, it cannot guarantee that all decomposed NH3 completely reacts with NO in the flue gas due to the complicated chemical reaction of urea and the complicated mixing process of the gas flow in the decomposing furnace. When NSR is greater than 2, excessive consumption of reducing agent will increase the running cost and increase the amount of NH3 escape. The research scheme of the effect of different ammonia-nitrogen ratios (NSR) on denitrification is as follows: keep other parameter settings unchanged (from the above analysis results, the injection height of the urea solution is maintained at 12 m, and the NSR gradually increased from 1.0 to 2.0 (successive increments are 0.2)), and carry out simulation research on five sets of NSR schemes.The variations of concentrations of NO and NH3 in the decomposing furnace with NSR are shown in Figure 8. From the analysis in Figure 8, with different NSR, changes in the NOx and NH3 concentration in the decomposing furnace are more obvious. When the decomposing furnace height is below 11 m, the changes of NO and NH3 concentrations in the furnace are basically synchronized. Between 11 m and 13 m, as the NSR increases, the peak value of NO concentration in the furnace decreases, and the peak value of NH3 concentration increases. When the height of the decomposing furnace is more than 15 m, the NO concentration in the decomposing furnace generally decreases, and the slope of the NO curve increases with the increase of NSR. The reason is that when NSR is 1, the reduction reaction velocity increases with the increase of NSR, so more NO will be reduced. However, when NSR reached 1.8, NO in the decomposer had reached a low concentration and could not be reduced easily. If NH3 continues to be increased, it will not only improve the denitrification efficiency, but also increase the NH3 escapement.Figure 8
Flow curves of NO (a) and NH3 (b) in the decomposing furnace with different NSR.
(a)(b)The variations of NO concentration and NH3 escape amount at the outlet of the decomposing furnace with NSR are shown in Figure 9. It can be seen from Figure 9 that the change trend of the NO concentration and the NH3 escape amount line is just the opposite. With the increase of NSR, the NO concentration gradually decreases and the NH3 escape amount gradually increases. When the NSR is 1.0, the NO concentration and NH3 escape concentration are 373.94 mg/m3 and 16.42 mg/m3, respectively. At this time, the NO concentration of the decomposing furnace is the highest. When the NSR is greater than 1.8, the NH3 escape concentration rises linearly, and the NO concentration decreases slowly at this time, indicating that the urea’s ability to reduce NO tends to be saturated. The denitrification efficiency curves at different NSR are shown in Figure 10. It can be seen from Figure 10 that the denitrification efficiency increases with increasing NSR. Comprehensive analysis of SNCR simulation results under different NSR shows that when the NSR is increased from 1.0 to 1.8, the denitrification efficiency is relatively evenly improved. This is because the NO concentration in the furnace is higher at this time, and the SNCR reaction is stronger. Increasing NSR will allow more NO to be reduced. But when the NSR is greater than 1.8, the denitrification efficiency rise velocity begins to decrease, and the amount of NH3 escape will increase much, so the optimal NSR is 1.8. Under this condition, the NO concentration of the decomposing furnace is 187.60 mg/m3, the NH3 escape concentration is 32.40 mg/m3, and the denitrification efficiency is 74.75%.Figure 9
Variation of NO concentration and NH3 escape concentration at the outlet of the decomposing furnace with NSR.Figure 10
Variation of denitrification efficiency with NSR.


## 4.3. Analysis of Urea Spray Velocity Results

The influence of the spraying velocity of the urea solution on the denitrification effect is mainly manifested in two aspects: the mixing degree of the urea solution with the mainstream smoke and the evaporation speed of the urea solution. Based on the above research, when the injection height of the reducing agent is 12 m and the molar ratio of ammonia and nitrogen is 1.8, simulations of different reducing agent injection velocity are performed. The jet velocity is from 20, 40, 60, and 80 m/s in order from low to high.The variations of evaporation time and denitrification efficiency of urea solution in the decomposing furnace with the spray velocity are shown in Figure11. The variation of NO concentration and NH3 escape concentration at the outlet of the decomposing furnace with the spray velocity of urea solution is shown in Figure 12. It can be seen from Figure 11 that the denitrification efficiency gradually increases with the increase in spraying velocity. Increasing the spray velocity and increasing the mixing speed of the urea solution and the flue gas in the decomposing furnace strengthen the heat transfer between the main flue gas stream and the urea solution, which accelerates the evaporation process of the urea solution and makes the urea decompose in advance in a suitable temperature window. At the same time, the increase of the spray velocity is conducive to extending the range of the urea solution in the depth direction of the decomposing furnace, thereby enhancing the degree of mixing of urea and the main flue gas stream and improving the denitrification efficiency. It can be seen from Figure 12 that the urea solution spray velocity increases, and the NH3 concentration at the outlet of the decomposing furnace decreases first and then increases. This indicates that there is an optimal value for the injection velocity, and beyond this optimal value, the denitrification effect is not significantly improved, and at the same time, the NH3 escape concentration at the outlet of the decomposing furnace is increased.Figure 11
Evaporation time of urea solution and denitrification efficiency at different injection velocities.Figure 12
The variations of NO and NH3 concentrations at the outlet of the decomposing furnace with spray velocity.Based on the analysis in Figures11 and 12, it can be seen that it is reasonable to choose a urea solution spray velocity of 40 m/s. At this time, the urea solution evaporation time is 0.038 s, and the NO concentration and NH3 escape concentration at the outlet of the decomposing furnace are 350 mg/m3 and 9.02 mg/m3, and the denitrification efficiency is 63.54%.


## 5. SNCR Simulation Test Verification

The simulation results were verified by the test results of a decomposing furnace of a cement plant in Hunan Province. The NH3 escape concentration and NO concentration at the outlet of the decomposing furnace were measured for verification. The layout of the measurement points of the test is exactly the same with that of the simulation. Combined with verifying the actual operation of SNCR denitrification in the decomposing furnace, the SNCR denitrification parameter settings of the decomposing furnace are summarized in Table 5, and the comparison between the SNCR simulation results and the test results is summarized in Table 6. The simulation data used to support the findings of this study are included within the article, and the experimental data used to support the findings of this study are available from the corresponding author upon request.Table 5
Parameter settings of SNCR.
The injection location (x, y, z) (m)NSRVelocity (m/s)Grain diameter (m)12341.8400.0001(1.9, 1.9, 12)(1.9, −1.9, 12)(−1.9, −1.9, 12)(−1.9, 1.9, 12)Table 6
Comparison between SNCR simulation value and experiment value.
Data categoriesNO mass flow (mg/m3)NH3 mass flow (mg/m3)Denitrification efficiency (%)Experimental data208.0930.2173.57Simulation data187.6032.4074.75Relative error9.85%7.25%1.60After verification, the relative error between the test results and the simulation results is within 10%, which is within the allowable range. Therefore, the SNCR simulation calculation model has good reliability, and the simulation result can be used for production guidance.


## 6. Conclusion

SNCR numerical study was carried out based on a 2500 t/d new type dry cement kiln decomposing furnace in a plant of Hunan Province. The research conclusions are as follows:(1)
The molar ratio of ammonia to nitrogen has a significant effect on the NO reduction in the decomposing furnace: as the molar ratio of ammonia to nitrogen increases, the concentration of NO at the outlet of the decomposing furnace decreases and the overall denitrification efficiency increases, but the concentration of NH3 escaping also increases synchronously. Under the research conditions, a better ammonia-nitrogen molar ratio was 1.8.(2)
The molar ratio of ammonia to nitrogen has a significant effect on the NO reduction in the decomposing furnace: as the molar ratio of ammonia to nitrogen increases, the concentration of NO at the outlet of the decomposing furnace decreases and the overall denitrification efficiency increases, but the concentration of NH3 escaping also increases synchronously. Under the research conditions, a better ammonia-nitrogen molar ratio was 1.8.(3)
With the increase of the spray velocity of urea solution, the mixture of urea solution and main flue gas is more uniform. Meanwhile, the evaporation process of urea solution is shorter and the denitrification efficiency is further improved. Under the study conditions, the better urea solution injection velocity was 40 m/s.(4)
Under the study conditions, the optimal process parameters are as follows: the injection height of urea solution is 12 m, the NSR is 1.8, and the spray velocity of urea solution is 40 m/s. The simulation results under the optimal process parameters are as follows: the NO outlet concentration at the outlet of the decomposing furnace is 187.60 mg/m3, the NH3 escape concentration is 32.40 mg/m3, and the denitrification efficiency is 74.75%.In this paper, the inlet layout and particle size distribution of the urea solution are set as the same parameters in the simulation. However, according to the practical operation experience of cement plants, the particle size and particle size distribution of urea solution would also have a great impact on SNCR denitrification.



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*Source: 9484683-2020-07-09.xml*