# Baseline Moisture Resistance of PWP Cement Composite Boards Reinforced with Internal Glass Fiber Reinforcement under Accelerated Wet-Dry Aging

Authors: Woraphot Prachasaree; Sitthichai Piriyakootorn; Suchart Limkatanyu; Abideng Hawa
Journal: Journal of Composites
 (2014)

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## Abstract

The purpose of this study was to improve the mechanical characteristics and moisture resistance of parawood particle (PWP) cement composite board developed by the authors. PWP cement composites were prepared with a mixture containing 15.0% parawood particles, 43.0% cement, 41.2% water, and 0.86% CaCl2 (by weight) and the PWP cement composite boards were internally reinforced with bidirectional glass fiber woven roving [0°/90°]. The board properties were evaluated under accelerated aging with wet-dry cycles to establish the durability and moisture resistance and the effect on flexural strength of the composite boards. The mechanical characteristics determined were the equivalent modulus of rupture (eMOR), the equivalent modulus of elasticity (eMOE), and the deformability factor (DF). The experimental results suggest that the strength and stiffness of the PWP composite boards with internal reinforcement are four times higher than those of the original PWP composite boards under accelerated aging based on 100 wet-dry cycles, implying better durability of the boards in outdoor use. The results provide a baseline to which improved formulations and reinforcements or designs can be compared using the same measurement methodology.


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## Body

## 1. Introduction

Para rubberwood is extensively cultivated in South-East Asian countries, where most of the world’s rubber tree plantations are currently located. The trees have a limited service life due to their eventual loss of productivity, and they need to be felled to make land available for replanting. Only a small part of the wood materials from felled trees can be used as timber, and converting trees to timber generates a large though biodegradable waste stream of sawdust, chips, trimmings, branches, and even whole trunks. These can be used as fuel or disposed of in landfills, but increasing the range of value-added uses as filler or fibrous reinforcement in composites would be a better option, for both economic and environmental reasons. Recently, there has been considerable interest and active research into a type of material used for construction and decorative materials known as cement composites.In previous research on cement composites incorporating wood wastes, concrete mixes with ground hazelnut shell, wood sawdust, and tea wastes have been experimentally investigated and their mechanical properties determined [1]. When wood particles from construction wastes were bonded with cement to form composites, the load-deflection characteristics demonstrated elastoplastic behavior [2]. Composite boards with rice straw and wood particles have also been developed for commercial use as insulation boards [3] and the properties of composites incorporating wood particles from CCA-treated southern yellow pine in cement have been evaluated in compressive tests [4]. Further, the use of thermomechanical pulp (TMP) has been compared with both unbleached and bleached kraft pulp as a fiber reinforcement in cement composites [5, 6]. The flexural behavior and performance of cement composites reinforced with weld square geogrid mesh were also evaluated in [7] and it was found that the first crack and ultimate load capacity increased with an increase in the amount of reinforcement. Additionally, the effect of fiber alignment on the mechanical behavior of cement based matrix composites reinforced with aligned pulp fiber sheets was investigated in [8].The durability of a lightweight concrete composite, based on wood chippings, was investigated under various environmental exposures in [9] and the use of wood sawdust and limestone dust as fine aggregates leads to the development of a lightweight composite product in [10]. AR glass and PE fabric reinforced composites have also been developed and studied under a three-point bending condition using both a static and drop weight impact system. There were three main test parameters including fabric type, specimen orientation, and drop height of the hammer. The impact load capacity and deflection were found in [11] to be highly influenced by the direction of the fabric in the composites. In [12], cement composites reinforced with Sisal Organosolv pulp and polypropylene fibers were evaluated using accelerated carbonation aging and soak-dry cycles. The influence of reinforcement with metal and woven synthetic nets on the properties of medium density fiberboard was studied in [13] and it was found that the mechanical properties of medium density fiberboard were improved by such reinforcement. Cement composites with parawood particle wastes were found to be acceptable for use in structural members with a low load carrying capacity and for some other construction uses in [14].However, the use of Para rubberwood product wastes in building materials is still not commercially significant, partly because there are gaps in knowledge that research can address. In particular, the moisture resistance of such products is of concern in construction applications and needs further assessment and potential improvement from the current baseline. This study documents that baseline and its main objectives were to develop parawood particle cement composite boards with internal glass fiber reinforcement and to study their performance and durability under wet-dry cycles. This study will aid the development of building and construction uses for parawood cement composites and will establish the baseline from which further improvements in moisture resistance capable of expanding the potential uses of such composites can be measured.


## 2. Materials

In this study, waste PWP in their original form were mixed with ordinary Portland cement to make PWP cement composites. The PWP were obtained by collecting wood dust, created in the furniture industry during the surface abrasion of parawood boards. An image of the PWP is shown in Figure1. The PWP sizes ranged up to 1180 μm. Their specific gravity and moisture content were determined according to ASTM D 1037-99 [15]. The chemical compositions of the PWP and Portland cement were determined using X-ray fluorescence spectrometry. The ordinary Portland cement (OPC-ASTM Type I cement) in this study was obtained from a local supplier. The physical properties and chemical compositions are given in Table 1. It should be noted that the ratio of combined CaO and K2O to SiO2 is higher than suggested by European Standard EN 197-1:2000 [15]. Thus, high alkalinity and hydration activity can be expected in these parawood cement composites. The glass woven roving used in this study consisted of fibers held together in a bidirectional arrangement. The glass strands were orientated in both the horizontal and the perpendicular [0°/90°] directions with a density of 800 g/m2. The tensile strength of individual glass fibers ranged from 1300 to 3400 MPa. The tensile modulus of elasticity was around 73 GPa.Table 1
Physical properties and chemical composition.
(a)
Chemical composition (%)
Materials
Al2O3
CaO
SiO2
Fe2O3
MgO
K2O
SO3
Portland cement
2.56
70.85
11.59
4.40
1.17
1.37
4.20
PWP
0.28
16.84
1.42
0.71
0.68
2.70
0.82
(b)
Physical properties
Materials
Specific gravity
Moisture content(% weight)
(% weight)Loss on ignition
pH
Portland cement
3.15
0.34
1.05
12
PWP
1.56
2.92
74.7
8Figure 1
Parawood particle particle.


## 3. PWP Cement Composite Boards

The mix proportions of the composite used to produce the boards were 15.0% parawood particles, 43.0% cement, 41.2% water, and 0.86% CaCl2 (by weight) and represent a reasonable compromise between high strength and high content of wood particles [16]. Composite boards with dimensions of 300 × 300 × 20 mm were produced from PWP and cement from the above formulation. The boards had an apparent specific gravity of 1.324 (ignoring porosity) based on weight and dimensions. To produce the boards, first, the PWP were mixed with Portland cement; then the water and CaCl2 were added. The slurry was manually stirred thoroughly until it was uniform. The mixture was then poured into steel molds and the glass fabric reinforcement was placed in the mixture. The composite boards were cold-pressed to attain the desired dimensions. Two different patterns of internal reinforcement were used as shown in Figure 2.Figure 2
PWP cement composite boards reinforced with glass fabric.After 24 hours at room temperature, the PWP cement composite boards were demolded and cured under damp burlap for 3 days before being tested and wet-dry aged. To evaluate the strength of control samples, a flexural test was performed on the composite boards without accelerated aging, after they had been cast and cured for 4 days. In total, twenty-four test samples of the PWP cement composite boards (6 samples without reinforcement, 9 samples with single layer reinforcement, and 9 samples with double layer reinforcement) were prepared for performance and durability tests. For PWP cement composite boards with single layer reinforcement, it should be noted that the glass reinforcement was positioned in the middle of the PWP board thickness. In general, the tensile properties of cement composite materials are weak. Glass fiber reinforcement should be placed on the tension side of the cement composite boards. However, it can make users confused that the PWP cement boards must be properly installed in the correct side of the PWP cement board surfaces. Thus, the glass reinforcement was positioned in the middle of thickness for this study.


## 4. Accelerated Wet-Dry Aging

This study was conducted in order to establish the durability and moisture resistance of the cement composite boards. The wet-dry accelerated aging employed was based on recommendations contained in the EN 494 Standards [17]. Each cycle involved the sample being immersed in water for 5 hours 50 minutes at 20±5°C, followed by air drying for 10 minutes, then 5 hours 50 minutes in a ventilated oven at 70±5°C, followed by air drying for 10 minutes. These cycles were repeated 50 or 100 times before flexural testing. The system of accelerated aging is illustrated in Figure 3.Figure 3
Accelerated wet-dry cycling process.


## 5. Experiment and Evaluations

The flexural mechanical properties of the PWP cement composite boards were investigated, as indicators of structural performance. The board samples were tested in a three-point bending scheme with a support test span of 240 mm. A concentrated line load was applied from above, at the midpoint of the test span of the samples. A linear variable differential transducer (LVDT) was mounted underneath at the midpoint to determine the induced deflection. A data acquisition system recorded the loads and deflections at a high sampling rate during each test. The setup is schematically illustrated in Figure4. To determine the flexural strength of the PWP cement composite board samples, the equivalent modulus of rupture (eMOR) was used. In general, the flexural strength of cement composite boards is evaluated from the maximum applied load before board rupture. The eMOR for the PWP cement composite boards is given in (A.1), Appendix A. In addition, the equivalent modulus of elasticity (eMOE) based on the slope (P/Δ) of the experimental load and deflection relation in the linearly elastic range is determined using (A.2), Appendix A.Figure 4
Schematic representation of the three-point bending test.The ductility or deformability of PWP cement composite boards can be evaluated by using experimental data in the post elastic range. Generally, the post elastic behavior of PWP cement composite boards is indicated by the deformability factor (DF). The DF of PWP cement composite boards can be defined as the ratio of deflection (or curvature or rotation, depending on which of these is observed) at the ultimate point (δu) to those values at the elastic point (δy) as given in
(1)DF=δuδy,
where δy and δu are elastic and ultimate deflections at the mid composite board. In general, the relations between load and deflection are not composed of linear segments. The elastic and ultimate deflections in (1) are not straightforward. To determine the DF, the procedure set out in EN 1995-1-1 [18] was modified and used to define elastic and ultimate points in this study (Appendix B).


## 6. Results and Discussion

Based on experimental results, the density of PWP cement composite boards with glass reinforcement is higher than that of PWP cement composite boards without reinforcement. Under accelerated wet-dry aging, the density of PWP cement composite boards decreases as the number of aging cycles increases as shown in Table2. It should be that the accelerated wet-dry aging has led to significant reduction in density and strength particularly in PWP cement composite boards without internal reinforcement. The results are summarized along with the relevant physical properties in Table 2. The mechanical properties determined from the flexural experiments were the equivalent modulus of rupture (MOR), equivalent modulus of elasticity (eMOE), and deformability factor (DF).Table 2
Physical and mechanical properties of PWP cement composite boards.
Reinforcement layer
Wet-dry cycles
Number of samples
Density (kg/m3)
Average mechanical properties
Average max load (kN)
eMOR (MPa)
eMOE (MPa)
DF factor
—
50
3
1288
0.609
7.31
1802
1.474
100
3
1158
0.400
4.80
1050
1.451
Single
0
3
1340
1.152
13.82
3657
2.230
50
3
1332
0.982
11.78
3610
2.205
100
3
1323
0.691
8.29
2215
1.522
Double
0
3
1357
2.170
26.00
6290
2.360
50
3
1354
1.710
20.50
5836
2.290
100
3
1349
1.627
19.52
5215
1.972


### 6.1. Behavior and Failure Mode

As expected, the mechanical properties degraded along with the decrease in the amount of glass reinforcement and the increase in the number of wet-dry cycles. From the experimental results, it can be clearly observed that the mechanical properties of the PWP cement composite boards under wet-dry cycles can be improved by using internal glass reinforcement. For the PWP cement composite boards without any internal reinforcement both prior to and after wet-dry cycling, the deflection increased almost linearly with the applied load, until the first major crack emerged. During testing, the formation of the first major crack was typically observed, immediately preceding the sudden failure of the board, which was similar to the failure behavior of the PWP cement composite boards with internal reinforcement. However, smaller cracks were also found in the samples with internal reinforcement.The failure mode of the PWP cement composite boards with internal reinforcement is summarized in Figure5. In addition, the load-deflection responses of the PWP cement composite boards under wet-dry aging are presented in Figures 6 and 7.Figure 5
Failure mode of the PWP cement composite boards.Figure 6
Load-deflection relations: effect of reinforcement.Figure 7
Percent increase in strength of PWP cement composite boards.


### 6.2. Effect of Wet-Dry Cycles and Reinforcement on Strength and Stiffness

The flexural strengths of the PWP cement composite boards with single and double layers of glass fabric reinforcement were compared with those of the boards without reinforcement under wet-dry aging conditions and were found to be, respectively, 1.6-1.7 and 3.0-4.0 times those of the composite boards without reinforcement, as shown in Figure6. The average percent increase in the strength of the PWP cement composite boards with internal reinforcement was summarized as shown in Figure 7. In addition, the flexural stiffness was observed to be proportional to the slope of the load-deflection curve and increased directly with the increase in internal glass reinforcement. However, the flexural strength and stiffness indicated a trend of decrease with increasing aging cycles as shown in Figure 8. Thus, aging by wet-dry cycling significantly reduced the strength, stiffness, and postcracking. Based on previous research [16], the strength reduction of PWP cement composite board without internal reinforcement under wet-dry aging has been found to be close to 70% after 100 aging cycles. In this study, however, the strength reduction at 100 wet-dry cycles was found to be 40% and 25%, respectively, for the PWP cement composite boards with single and double layers of reinforcement. Summary of the strength reduction under accelerated wet-dry cycles was presented in Figure 9. The experimental results show that internal glass fabric reinforcement significantly improves the overall mechanical properties of the PWP cement composite boards.Figure 8
Load-deflection relations: effect of wet-dry cycles.Figure 9
Strength reduction of PWP cement composite boards under wet-dry aging.


### 6.3. Effect of Wet-Dry Cycles and Reinforcement on the Equivalent Modulus of Elasticity

As can be seen from Table2, the eMOE was less sensitive to aging by wet-dry cycling than the average maximum load capacity or the eMOR. The eMOE shows a less significant change at 50 wet-dry cycles, and there was only a small decrease in the eMOE found between 50 and 100 wet-dry cycles. It should be noted that the trend of eMOE reduction under wet-dry aging is quite different for the PWP cement composite boards with and without internal reinforcement, since the load-deflection behavior of the PWP cement composite boards without internal reinforcement was almost linear until brittle failure, particularly after 100 wet-dry cycles [16]. The internal glass fabric reinforcement therefore serves to reduce the brittle behavior and increase the ductility of the PWP cement composite board.


### 6.4. Deformability Factor (DF)

The trend of the DF was similar to that of the eMOE for the PWP cement composite boards with internal glass fiber reinforcement. The maximum reductions in the DF obtained from the PWP cement composite boards after 100 wet-dry cycles were 31.7% and 16.4%, respectively, for single and double layer reinforcement. The DF showed little change at 50 cycles but was significantly reduced after 100 wet-dry cycles.


## 6.1. Behavior and Failure Mode

As expected, the mechanical properties degraded along with the decrease in the amount of glass reinforcement and the increase in the number of wet-dry cycles. From the experimental results, it can be clearly observed that the mechanical properties of the PWP cement composite boards under wet-dry cycles can be improved by using internal glass reinforcement. For the PWP cement composite boards without any internal reinforcement both prior to and after wet-dry cycling, the deflection increased almost linearly with the applied load, until the first major crack emerged. During testing, the formation of the first major crack was typically observed, immediately preceding the sudden failure of the board, which was similar to the failure behavior of the PWP cement composite boards with internal reinforcement. However, smaller cracks were also found in the samples with internal reinforcement.The failure mode of the PWP cement composite boards with internal reinforcement is summarized in Figure5. In addition, the load-deflection responses of the PWP cement composite boards under wet-dry aging are presented in Figures 6 and 7.Figure 5
Failure mode of the PWP cement composite boards.Figure 6
Load-deflection relations: effect of reinforcement.Figure 7
Percent increase in strength of PWP cement composite boards.


## 6.2. Effect of Wet-Dry Cycles and Reinforcement on Strength and Stiffness

The flexural strengths of the PWP cement composite boards with single and double layers of glass fabric reinforcement were compared with those of the boards without reinforcement under wet-dry aging conditions and were found to be, respectively, 1.6-1.7 and 3.0-4.0 times those of the composite boards without reinforcement, as shown in Figure6. The average percent increase in the strength of the PWP cement composite boards with internal reinforcement was summarized as shown in Figure 7. In addition, the flexural stiffness was observed to be proportional to the slope of the load-deflection curve and increased directly with the increase in internal glass reinforcement. However, the flexural strength and stiffness indicated a trend of decrease with increasing aging cycles as shown in Figure 8. Thus, aging by wet-dry cycling significantly reduced the strength, stiffness, and postcracking. Based on previous research [16], the strength reduction of PWP cement composite board without internal reinforcement under wet-dry aging has been found to be close to 70% after 100 aging cycles. In this study, however, the strength reduction at 100 wet-dry cycles was found to be 40% and 25%, respectively, for the PWP cement composite boards with single and double layers of reinforcement. Summary of the strength reduction under accelerated wet-dry cycles was presented in Figure 9. The experimental results show that internal glass fabric reinforcement significantly improves the overall mechanical properties of the PWP cement composite boards.Figure 8
Load-deflection relations: effect of wet-dry cycles.Figure 9
Strength reduction of PWP cement composite boards under wet-dry aging.


## 6.3. Effect of Wet-Dry Cycles and Reinforcement on the Equivalent Modulus of Elasticity

As can be seen from Table2, the eMOE was less sensitive to aging by wet-dry cycling than the average maximum load capacity or the eMOR. The eMOE shows a less significant change at 50 wet-dry cycles, and there was only a small decrease in the eMOE found between 50 and 100 wet-dry cycles. It should be noted that the trend of eMOE reduction under wet-dry aging is quite different for the PWP cement composite boards with and without internal reinforcement, since the load-deflection behavior of the PWP cement composite boards without internal reinforcement was almost linear until brittle failure, particularly after 100 wet-dry cycles [16]. The internal glass fabric reinforcement therefore serves to reduce the brittle behavior and increase the ductility of the PWP cement composite board.


## 6.4. Deformability Factor (DF)

The trend of the DF was similar to that of the eMOE for the PWP cement composite boards with internal glass fiber reinforcement. The maximum reductions in the DF obtained from the PWP cement composite boards after 100 wet-dry cycles were 31.7% and 16.4%, respectively, for single and double layer reinforcement. The DF showed little change at 50 cycles but was significantly reduced after 100 wet-dry cycles.


## 7. Conclusions

Composite boards prepared from PWP particles and cement (35% PWP content relative to cement), with and without internal glass fabric reinforcement, were tested for the effects of accelerated aging by wet-dry cycles, on their mechanical flexural properties. All of the mechanical properties of the PWP cement composite boards with double layer reinforcement increased significantly, indicating that these boards had improved moisture resistance and are suitable for outdoor applications. After 100 wet-dry cycles, the flexural strength and stiffness of boards with double layer reinforcement were about four times higher than those of boards without internal reinforcement. These composite boards may therefore be suitable for indoor use other than as structural members.



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*Source: 903497-2014-08-05.xml*