# Quality Control of Lead-Acid Battery according to Its Condition Test for UPS Supplier and Manufacturers

Authors: Tsung-Chih Hsiao; Tzer-Long Chen; Chia-Hui Liu; Chih-Ming Lee; Hsin-Chun Yu; Tzer-Shyong Chen
Journal: Mathematical Problems in Engineering
 (2014)

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## Abstract

The risk of insufficient petroleum resources has forced human beings to emphasize the acquisition and storage of energy. To avoid such situation, this study tends to explore the effective management of lead-acid batteries for effective utilization conforming to the industrial requirements.


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## Body

## 1. Introduction

The advance of information technology has enhanced people’s requirements for the quality of life. Nevertheless, the risk of insufficient petroleum resources has forced human beings to emphasize the acquisition and storage of energy. In 2006, two types of batteries appeared in the US top ten technology plan, in which lead-acid batteries covered one-third of the gross sales in the battery industry. In addition to the close relations with power, traffic, and information, lead-acid batteries presented the control power in the transportation, like vehicles and various uninterruptible power systems so as to become a necessary product in human life. Lead-acid batteries [1] would become the new green energy system with the best development and application in the 21st century.The boom of green industry makes resource reengineering and energy conservation the key issues for enterprises to invest in a lot of resources to protect the environment. For instance, green economy or green industry has been regarded as the key development in China’s 12th Five-Year Plan. Apparently, green industry is not only an emerging industry but also a trend. Particularly, the global focus on energy protection in the past years has promoted the concepts of energy conservation and carbon reduction. Besides, the shortage of oil production, natural gas, and coal makes the resource application extraordinarily important. A lot of researchers therefore constantly study energy conservation, aiming to effectively utilize the present resources on the earth for the extreme benefits. This study aims to achieve the energy conservation and environmental protection through the effective management of lead-acid batteries.According to the reports in Mainland China, lead-acid battery producers are requested to recycle the products, meeting the requirements of the industrial management in Mainland China for it is the embodiment of social responsibility as well as the key in the sustainable development of green economy. For enterprises, secondary lead, as the cold iron in reducing costs and enhancing efficiency, has played a critical role in the increasing production of lead-acid batteries [2]. Meanwhile, the pollution risk is increasing in the secondary lead processing that the nation is promoting the recycling industry. The environmental capacity of lead-acid battery recycle system is practiced in the nation based on provinces, and the threshold for the industries is enhanced. Apparently, the officials in Mainland China have constantly planned and invested in green economy and presented regulations for the production of lead-acid batteries in order to protect the citizens’ health and the economic development from being damaged by lead-acid battery pollution.The lead-acid battery industry is the key in the development of secondary energy that battery enterprises have stressed on the applications to consumer products. Lead-acid batteries, which are mainly applied to the energy storage of vehicles, uninterruptible power supply (UPS), electric cars, medical equipment, and communication devices, have been used for a century land provided that the market structure is mature and stable. In order to maintain the normal operation of precision instruments in high-tech plants and medical industry, uninterruptible power supply is often utilized for keeping the power supply stable. Nevertheless, uninterruptible power supply requires a large amount of lead-acid batteries [3], which could lead to heavy metal pollution and endanger the citizens’ health if it lacks proper management. Moreover, plug-in electric vehicles, as one of the seven strategic emerging industries, are considered promising but still encounter problems in costs, markets, and security, showing the extraordinary importance of lead-acid battery management in the environmental pollution. To avoid such a situation, this study tends to explore the effective management of lead-acid batteries for effective utilization conforming to the industrial requirements.Lead-acid batteries are widely applied and play a primary role in human demands, such as the equipment of information, telecommunication, traffic, industry, and medical systems. Lead-acid batteries are mainly applied to high-tech plants and medical industry, particularly to uninterruptible power supply, which has to be discarded every few years as it is used as a spare. The chemical pollution of lead and sulfuric acid in the process of dealing with used batteries could seriously impact the environment. Hence, the effective management of lead-acid batteries is considered as a critical issue [4, 5]. Nonetheless, it is currently not easy to test the residual capacity and the service life of lead-acid batteries, which are affected by the battery structure, environmental temperature, depth of previous discharge, self-discharge of batteries, discharge current, charge method, and end of discharge voltage [6, 7]. Besides, the capacity change during the lead-acid battery discharge is not linear, and some aged batteries would appear decreased in voltage. In the real situation, not all batteries could be measured offline, and the charge voltage measured online could result in misjudging the battery voltage. Besides, not all aged batteries would present decreased voltage. In this case, battery voltage could not entirely be used for judging battery ageing. It is regarded as a dilemma to test lead-acid batteries [8]. As a result, a lot of battery-capacity detecting technologies are proposed in the market, including open circuit voltage, electrolyte specific gravity, load voltage, internal resistance, charge ripple current monitoring, and offline load control, for various conditions [9–12]. In consideration of time, accuracy, and online detection, this study aims to discuss the state of availability, residual capacity, and service life of lead-acid batteries with the introduction of scene management.The dynamic characteristics of lead-acid batteries are complicated and would change with battery ageing. However, the research on the management of lead-acid battery testing tends to explore the effectiveness of lead-acid batteries for the users to understand the power supply, the capacity, and the discard time to ensure the system stability and the maximal effectiveness. The maintenance cost could be reduced by verifying the health of each battery and providing managerial strategies to ensure the discard time of batteries, and the maintenance strategy is adjusted from advancing the currently time-based regular discard to condition-based according to the real discharge testing. Instantaneous current discharge, a highly reliable online testing with low destruction, is introduced and can actually record DC resistance, float voltage, discharge voltage, and recovery voltage in the discharge process for analyzing the single battery capacity and capability. Moreover, it allows online testing and the reliability of uninterruptible power supply in plants to be maintained. Such an approach is expected to accurately estimate the state of availability to find out the degraded batteries for early discard and ensure the system reliability. This study aims to(1)
find out degraded batteries for early discard and ensure the reliability of uninterruptible power supply,(2)
verify the health of each battery to ensure the actual discard time and reduce the maintenance costs,(3)
test online without affecting the normal operation of systems.This paper is expected to achieve the objectives of predictive maintenance and effective utilization of batteries, energy conservation, cost reduction, and environmental protection. The managerial experiences and approaches of lead-acid battery suppliers and technology plants are considered as the reference of this study. By analyzing and recording the data, the research results are inferred from the effective data, which could be the reference of enterprises and the academia. The enterprises therefore could decrease the waste of lead-acid battery discard and reduce the discard cost. What is more, the heavy metal pollution caused by lead-acid battery discard could be reduced through the effective management of lead-acid batteries so as to protect the environments and contribute to the earth.


## 2. Related Work

### 2.1. State and Characteristics of Lead-Acid Batteries

The battery state could be divided into state of charge and state of health, in which several correlations and parameters that could affect the battery performance [4, 13] are contained. The relations between the states are shown in Figure 1.Figure 1
Battery state flow.Lead-acid batteries present the characteristics of battery capacity and voltage, discharge characteristics, and preservation of lead-acid batteries [14], which are further introduced as follows.(1) Battery Capacity and Voltage. For a battery with fixed capacity, the relations between the discharge current and the discharge time are not linear, and the discard time would change with changing discharge current. When discharging a battery with rated current, the provided capacity conforms to the rated capacity. However, the battery capacity would obviously decrease when the battery is discharged with the current larger than the rated current. For this reason, the setting of end of discharge voltage (EODV) normally would change with changing discharge current. Battery capacity would be affected by the end voltage, discharge current, and environmental temperature. The rated capacity of close lead-acid batteries is set by a 20 h discharge rate (20 HR). The battery capacity is also influenced by the environmental temperature that the environmental temperature about 0–40°C is the optimal range for discharge. When the environmental temperature is higher than 40°C, the battery performance would degrade. The potential difference between the negative and the positive poles is regarded as the battery voltage. The voltage of a single lead-acid battery is about 2 V. The concentration of sulfuric acid could present the changes of battery capacity. In this case, measuring the open circuit voltage could acquire the battery capacity [15–18].(2) Discharge Characteristics. During discharge, lead-acid batteries show the characteristics of larger capacity being supplied by the discharge with low current and smaller capacity being supplied by high-current discharge. Such factors could cause difficulties in judging the residual capacity and service life of a battery. The discharge current reveals correlations with the end voltage of a battery that the lower end voltage appears on the higher discharge current. Since the chemical reaction in the end of battery discharge causes bad conductivity in a battery, the internal resistance increases and the voltage rapidly decreases so that the end voltage of valve regulated lead-acid batteries would change with the discharge rate. Low end voltage would be set for high-current discharge, while high end voltage is set for low-current discharge. Since the product would be decreased when discharging with high current, the polar plate would not be damaged with low discharge voltage. Nonetheless, low-current discharge for a long time could result in product obstruction on the negative polar plate to deform the polar plate, cause short circuit, and directly affect the service life that the end voltage is generally higher. Consequently, the discharge voltage for valve regulated lead-acid batteries could not be lower than the estimated end of discharge voltage; otherwise, the batteries might fail and can no longer be charged when being overdischarged [17, 19].(3) Preservation of Lead-Acid Batteries. The optimal storage conditions for lead-acid batteries container are −15~30°C, and the relative humidity is 25~85%, not being directly exposed in sun and dust-free places. Lead-acid batteries present internal self-discharge reaction, that is, the reaction between lead and sulfuric acid generating sulfuric acid lead and hydrogen. Such a reaction would be accelerated with increasing temperature to decrease the capacity and reduce the voltage. For this reason, batteries kept for more than 3 months should be recharged before the delivery. In the process of packaging, transit, and storage, the battery capacity would be slightly reduced due to the self-discharge and temperature. The capacity of lead-acid batteries therefore would gradually decrease with time. When the self-discharge exceeds the normal range, the open circuit voltage would decrease that too much sulfuric matter on the polar plate would permanently reduce the battery capacity and advance the failure. As a result, batteries should be stored in cool and dry places as the higher temperature a battery is kept in the higher discharge rate.


### 2.2. Service Life of Lead-Acid Batteries and the Check Standard

Regarding the irreversible life of lead-acid batteries, a battery is considered terminated when the dischargeable capacity is lower than 80% of rated capacity, according to IEEE Std 1188. In accordance with the discharge capability, the service life of lead-acid batteries could be divided into(1)
stable phase, with more than 100% discharge capability,(2)
decline phase, with 100%~80% discharge capability,(3)
breakdown phase, with 80%~35% discharge capability.When the discharge capability is lower than 80%, the internal polar plate would rapidly degrade and enter breakdown phase, when the battery should be discarded, according to IEEE Std 1188. Nevertheless, a battery can still serve for a long period of time after the time point. In consideration of the operation costs, lowering the discharge capability standard for battery discard could reduce the cost and increase the profit. However, the internal polar plate enters breakdown phase with rapid degradation that the quality of power supply for equipment might be affected and even cause operation risks and loss when the discard time is delayed. Therefore, it is a major issue for battery managers making the optimal discard time.The judgment of battery life is generally defined according to the usage, including cycle life and float life.(1) Cycle Life. It refers to the number of times a battery is being charged and discharged, which is used as the key power with frequent charge/discharge, being repeatedly charged and discharged when the capacity decreases down to a certain value (60% or 80%) of the initial value. Depth of discharge (DOD) is the major factor in cycle life of lead-acid batteries that the higher depth of discharge would reduce the number of times of cycle life [13].(2) Float Life. Float life indicates treating the batteries as the standby power, such as uninterruptible power supply (UPS), when the battery life is calculated by time. For instance, lead-acid batteries in uninterruptible power supply in technology plants are used as a spare, with the float state, and merely discharged when the normal power is exceptionally interrupted. Charge current is the major factor in float life that continuous charge current could result in the erosion of electrode plates [20]. Temperature, which could accelerate the erosion of electrode plates, is regarded as another factor in float life that being in a high-temperature environment could rapidly damage the batteries. Since the charge way and temperature could affect the service life of batteries, the factors in shortening the battery life are concluded [21].(a)
Depth of discharge: overdischarge could shorten cycle life.(b)
Large-current discharge: discharge with small capacity and then large current could shorten the service life.(c)
Large-current charge: the gas generated by extreme charge current could exceed the absorption rate of batteries at a certain amount to increase the internal pressure causing the gas being exhausted from the security valve. The electrolyte therefore would be largely consumed to damage the components in the battery.(d)
Overcharge: the components in a battery would be damaged by the electrolyte resulting from overcharge.(e)
Effects of environmental temperature: high temperature would accelerate the degradation of components in a battery. The battery life would be shortened when charging with fixed voltage but unnecessary large current in high temperature. Hydrogen generated in extreme low-temperature charge could increase the internal pressure or decrease the electrolyte to shorten the service life.


### 2.3. State Detection of Lead-Acid Batteries

Current technologies for measuring the lead-acid battery state contain open circuit voltage, electrolyte specific gravity, internal resistance, charge ripple current monitoring, and offline load control [22]. They are introduced in this section, and the measurement used for this experiment is selected [23].(1) Open Circuit Voltage. The residual capacity and the open circuit voltage of a battery appear in linear relationship that the open circuit voltage could be used for judging the battery state. However, after charging/discharging lead-acid batteries, the open circuit voltage required time, about 30 min–1 hr, for recovery and being stable. When the battery state is predicted with the open circuit voltage in this period, it would reveal certain errors. The measurement of float voltage could check seriously damaged open circuit and short circuit batteries but could not judge the discharge capability of each battery. For measuring the open circuit voltage, it required 2 hrs offline for balancing the electrolytic reaction so as to judge the state of charge. Moreover, batteries should be kept in the float state in uninterruptible power supply that open circuit voltage is rather unsuitable [24, 25].(2) Electrolyte Specific Gravity. The electrolyte is the mixture of pure sulfuric acid and distilled water under the temperature 80°F and the standard specific gravity 1.280. Hydrometer method is used for measuring the specific gravity change of the electrolyte in a battery, as the concentration of acid liquor in the electrolyte would decrease when discharging lead-acid batteries and is proportional to the battery state. A hydrometer therefore is utilized for measuring the specific gravity of the electrolyte as well as predicting the residual capacity of the battery [19]. Nonetheless, each battery has to be measured its electrolytic concentration which would consume more time and increase manpower costs. Besides, the electrolyte is limited that the spread speed and the specific gravity appear lower in the upper layer but higher in the lower layer during charging/discharging that stratification is generated to affect the estimation of the battery state.(3) Internal Resistance. For internal resistance, the resistance change, during the battery discharge, is used for estimating the residual capacity of a battery [18]. At the end of the battery discharge, the internal resistance would rapidly increase that the rapidly increasing resistance could be regarded as the end of the battery capacity. However, such an approach is restricted to the precision of resistance measurement, and the resistance have certain relations with the service life that a battery being used for a long period of time would appear in higher internal resistance, resulting in causing prediction errors. Internal resistance is likely affected by online charge current and ripples so that the reproducibility of the read value is bad (the rate of change about 20~25%). Internal resistance could orientate the exceptional resistance, which is one of the key judgments in battery failure [26–29].(4) Charge Ripple Current Monitoring. When ageing and passivation appear in a series of batteries, the capacitive reactance change would affect the ripple current in the charge current. Such an approach could establish a long-term ageing judgment of a series of batteries but could not diagnose a single battery. Besides, the ripple current could have errors because of the capacitor failure of rectifier, charger, load change, and DC Bus that other testing methods should be taken into account.(5) Offline Load Control. To test the left capacity of a battery, off-line load control, is suitable for the acceptance of uninterruptible power supply. However, the setting of the end voltage should be emphasized in deep discharge to prevent the battery from being damaged.(6) Instantaneous Current Discharge. The batteries provide the power through electrochemical reaction. The chemical voltage measured in a short period of time could be an online test with high reliability and low destruction. The external load is utilized for instantaneous current discharge when DC resistance, float voltage, discharge voltage, and recovery voltage are recorded. It allows measuring batteries without stopping the devices and easily controlling the single battery capacity and capability.In accordance with the experimental requirements in this study, instantaneous current discharge is chosen for measuring lead-acid batteries for it could easily control the current state of batteries and exclude unnecessary resistance errors. Hence, the testing data are more precise for analyzing the state and the discharge capability of lead-acid batteries. In order to achieve the effective management of lead-acid batteries, the successive management is further evaluated according to the analyzed data.


## 2.1. State and Characteristics of Lead-Acid Batteries

The battery state could be divided into state of charge and state of health, in which several correlations and parameters that could affect the battery performance [4, 13] are contained. The relations between the states are shown in Figure 1.Figure 1
Battery state flow.Lead-acid batteries present the characteristics of battery capacity and voltage, discharge characteristics, and preservation of lead-acid batteries [14], which are further introduced as follows.(1) Battery Capacity and Voltage. For a battery with fixed capacity, the relations between the discharge current and the discharge time are not linear, and the discard time would change with changing discharge current. When discharging a battery with rated current, the provided capacity conforms to the rated capacity. However, the battery capacity would obviously decrease when the battery is discharged with the current larger than the rated current. For this reason, the setting of end of discharge voltage (EODV) normally would change with changing discharge current. Battery capacity would be affected by the end voltage, discharge current, and environmental temperature. The rated capacity of close lead-acid batteries is set by a 20 h discharge rate (20 HR). The battery capacity is also influenced by the environmental temperature that the environmental temperature about 0–40°C is the optimal range for discharge. When the environmental temperature is higher than 40°C, the battery performance would degrade. The potential difference between the negative and the positive poles is regarded as the battery voltage. The voltage of a single lead-acid battery is about 2 V. The concentration of sulfuric acid could present the changes of battery capacity. In this case, measuring the open circuit voltage could acquire the battery capacity [15–18].(2) Discharge Characteristics. During discharge, lead-acid batteries show the characteristics of larger capacity being supplied by the discharge with low current and smaller capacity being supplied by high-current discharge. Such factors could cause difficulties in judging the residual capacity and service life of a battery. The discharge current reveals correlations with the end voltage of a battery that the lower end voltage appears on the higher discharge current. Since the chemical reaction in the end of battery discharge causes bad conductivity in a battery, the internal resistance increases and the voltage rapidly decreases so that the end voltage of valve regulated lead-acid batteries would change with the discharge rate. Low end voltage would be set for high-current discharge, while high end voltage is set for low-current discharge. Since the product would be decreased when discharging with high current, the polar plate would not be damaged with low discharge voltage. Nonetheless, low-current discharge for a long time could result in product obstruction on the negative polar plate to deform the polar plate, cause short circuit, and directly affect the service life that the end voltage is generally higher. Consequently, the discharge voltage for valve regulated lead-acid batteries could not be lower than the estimated end of discharge voltage; otherwise, the batteries might fail and can no longer be charged when being overdischarged [17, 19].(3) Preservation of Lead-Acid Batteries. The optimal storage conditions for lead-acid batteries container are −15~30°C, and the relative humidity is 25~85%, not being directly exposed in sun and dust-free places. Lead-acid batteries present internal self-discharge reaction, that is, the reaction between lead and sulfuric acid generating sulfuric acid lead and hydrogen. Such a reaction would be accelerated with increasing temperature to decrease the capacity and reduce the voltage. For this reason, batteries kept for more than 3 months should be recharged before the delivery. In the process of packaging, transit, and storage, the battery capacity would be slightly reduced due to the self-discharge and temperature. The capacity of lead-acid batteries therefore would gradually decrease with time. When the self-discharge exceeds the normal range, the open circuit voltage would decrease that too much sulfuric matter on the polar plate would permanently reduce the battery capacity and advance the failure. As a result, batteries should be stored in cool and dry places as the higher temperature a battery is kept in the higher discharge rate.


## 2.2. Service Life of Lead-Acid Batteries and the Check Standard

Regarding the irreversible life of lead-acid batteries, a battery is considered terminated when the dischargeable capacity is lower than 80% of rated capacity, according to IEEE Std 1188. In accordance with the discharge capability, the service life of lead-acid batteries could be divided into(1)
stable phase, with more than 100% discharge capability,(2)
decline phase, with 100%~80% discharge capability,(3)
breakdown phase, with 80%~35% discharge capability.When the discharge capability is lower than 80%, the internal polar plate would rapidly degrade and enter breakdown phase, when the battery should be discarded, according to IEEE Std 1188. Nevertheless, a battery can still serve for a long period of time after the time point. In consideration of the operation costs, lowering the discharge capability standard for battery discard could reduce the cost and increase the profit. However, the internal polar plate enters breakdown phase with rapid degradation that the quality of power supply for equipment might be affected and even cause operation risks and loss when the discard time is delayed. Therefore, it is a major issue for battery managers making the optimal discard time.The judgment of battery life is generally defined according to the usage, including cycle life and float life.(1) Cycle Life. It refers to the number of times a battery is being charged and discharged, which is used as the key power with frequent charge/discharge, being repeatedly charged and discharged when the capacity decreases down to a certain value (60% or 80%) of the initial value. Depth of discharge (DOD) is the major factor in cycle life of lead-acid batteries that the higher depth of discharge would reduce the number of times of cycle life [13].(2) Float Life. Float life indicates treating the batteries as the standby power, such as uninterruptible power supply (UPS), when the battery life is calculated by time. For instance, lead-acid batteries in uninterruptible power supply in technology plants are used as a spare, with the float state, and merely discharged when the normal power is exceptionally interrupted. Charge current is the major factor in float life that continuous charge current could result in the erosion of electrode plates [20]. Temperature, which could accelerate the erosion of electrode plates, is regarded as another factor in float life that being in a high-temperature environment could rapidly damage the batteries. Since the charge way and temperature could affect the service life of batteries, the factors in shortening the battery life are concluded [21].(a)
Depth of discharge: overdischarge could shorten cycle life.(b)
Large-current discharge: discharge with small capacity and then large current could shorten the service life.(c)
Large-current charge: the gas generated by extreme charge current could exceed the absorption rate of batteries at a certain amount to increase the internal pressure causing the gas being exhausted from the security valve. The electrolyte therefore would be largely consumed to damage the components in the battery.(d)
Overcharge: the components in a battery would be damaged by the electrolyte resulting from overcharge.(e)
Effects of environmental temperature: high temperature would accelerate the degradation of components in a battery. The battery life would be shortened when charging with fixed voltage but unnecessary large current in high temperature. Hydrogen generated in extreme low-temperature charge could increase the internal pressure or decrease the electrolyte to shorten the service life.


## 2.3. State Detection of Lead-Acid Batteries

Current technologies for measuring the lead-acid battery state contain open circuit voltage, electrolyte specific gravity, internal resistance, charge ripple current monitoring, and offline load control [22]. They are introduced in this section, and the measurement used for this experiment is selected [23].(1) Open Circuit Voltage. The residual capacity and the open circuit voltage of a battery appear in linear relationship that the open circuit voltage could be used for judging the battery state. However, after charging/discharging lead-acid batteries, the open circuit voltage required time, about 30 min–1 hr, for recovery and being stable. When the battery state is predicted with the open circuit voltage in this period, it would reveal certain errors. The measurement of float voltage could check seriously damaged open circuit and short circuit batteries but could not judge the discharge capability of each battery. For measuring the open circuit voltage, it required 2 hrs offline for balancing the electrolytic reaction so as to judge the state of charge. Moreover, batteries should be kept in the float state in uninterruptible power supply that open circuit voltage is rather unsuitable [24, 25].(2) Electrolyte Specific Gravity. The electrolyte is the mixture of pure sulfuric acid and distilled water under the temperature 80°F and the standard specific gravity 1.280. Hydrometer method is used for measuring the specific gravity change of the electrolyte in a battery, as the concentration of acid liquor in the electrolyte would decrease when discharging lead-acid batteries and is proportional to the battery state. A hydrometer therefore is utilized for measuring the specific gravity of the electrolyte as well as predicting the residual capacity of the battery [19]. Nonetheless, each battery has to be measured its electrolytic concentration which would consume more time and increase manpower costs. Besides, the electrolyte is limited that the spread speed and the specific gravity appear lower in the upper layer but higher in the lower layer during charging/discharging that stratification is generated to affect the estimation of the battery state.(3) Internal Resistance. For internal resistance, the resistance change, during the battery discharge, is used for estimating the residual capacity of a battery [18]. At the end of the battery discharge, the internal resistance would rapidly increase that the rapidly increasing resistance could be regarded as the end of the battery capacity. However, such an approach is restricted to the precision of resistance measurement, and the resistance have certain relations with the service life that a battery being used for a long period of time would appear in higher internal resistance, resulting in causing prediction errors. Internal resistance is likely affected by online charge current and ripples so that the reproducibility of the read value is bad (the rate of change about 20~25%). Internal resistance could orientate the exceptional resistance, which is one of the key judgments in battery failure [26–29].(4) Charge Ripple Current Monitoring. When ageing and passivation appear in a series of batteries, the capacitive reactance change would affect the ripple current in the charge current. Such an approach could establish a long-term ageing judgment of a series of batteries but could not diagnose a single battery. Besides, the ripple current could have errors because of the capacitor failure of rectifier, charger, load change, and DC Bus that other testing methods should be taken into account.(5) Offline Load Control. To test the left capacity of a battery, off-line load control, is suitable for the acceptance of uninterruptible power supply. However, the setting of the end voltage should be emphasized in deep discharge to prevent the battery from being damaged.(6) Instantaneous Current Discharge. The batteries provide the power through electrochemical reaction. The chemical voltage measured in a short period of time could be an online test with high reliability and low destruction. The external load is utilized for instantaneous current discharge when DC resistance, float voltage, discharge voltage, and recovery voltage are recorded. It allows measuring batteries without stopping the devices and easily controlling the single battery capacity and capability.In accordance with the experimental requirements in this study, instantaneous current discharge is chosen for measuring lead-acid batteries for it could easily control the current state of batteries and exclude unnecessary resistance errors. Hence, the testing data are more precise for analyzing the state and the discharge capability of lead-acid batteries. In order to achieve the effective management of lead-acid batteries, the successive management is further evaluated according to the analyzed data.


## 3. Measurement and Practice of ACID Batteries

### 3.1. Research Variables

Based on the research variables of batteries, current, voltage, and battery state, the unit and codes are defined as follows:(1)
Battery Code (NO.).(2)
Service Time (Time; Unit: Month).(3)
Float Voltage (FV; Unit: V).(4)
Discharge Voltage (DV; Unit: V).(5)
Discharge Current (DA; Unit: A).(6)
Internal Resistance (R; Unit: mΩ).(7)
Battery State (Check; 1: OK, 2: WARNING, 3: EXCEPTION).


### 3.2. Research Hypotheses

The following hypotheses are proposed for the batteries so as to exclude some special situations and make the research results more precise.(1)
The longer service time (Time), the lower discharge voltage (DV).(2)
The longer service time (Time), the higher internal resistance (R).(3)
Battery state (Check) is correlated with service time (Time), discharge voltage (DV), and internal resistance (R).


### 3.3. Research Design

To effectively test the state and discharge capability of lead-acid batteries in uninterruptible power supply in technology plants, instantaneous current discharge is selected as the measurement in this study by testing the battery state with a measuring device and analyzing the tested discharge data with software.According to the process, more than two people are required to securely and accurately complete the research. The measuring devices are checked in the beginning of the research to ensure the usability. The condition of uninterruptible power supply is further confirmed to exclude the exception. The operation and evacuation routes are also confirmed for the operators’ security. Furthermore, the measuring device parameters are set for starting the experiment. In the testing process, each cell checked the discharge characteristics every 0.5 sec, and the characteristics of recovery voltage are also measured every 0.5 sec for testing the terminal voltage change. In addition, the voltage monitoring terminal is connected to the terminal of energy storage pool and the discharge current probe is directly linked to the battery terminal for diagnoses. The device is also checked for the misconnection. When there is exception resulting from misconnection, the device would alert the operator to ensure the operation security. Finally, the measured data are read for data analyses to explore the effective information for the effective management of the personnel in technology plants and cost reduction.


### 3.4. Research Methodology

Instantaneous current discharge is selected as the measurement in this study, as it is suitable for measuring the state of lead-acid batteries in uninterruptible power supply in technology plants with the following advantages.(1)
Instantaneous current discharge could control the capacity state and the starting ability of a single battery.(2)
DC resistance measured from the real discharge could be used for analyzing the degradation of polar plates and the terminal break and false welding of power collector as well as avoiding AC resistance errors.(3)
The float voltage data are applied to understanding the balance analysis of charge voltage and the examination of short circuit batteries.(4)
The recovery voltage data allow analyzing the factors in the electrolytic degradation.An instantaneous discharge device is utilized in this study for finding out the degraded batteries with the testing information and preceding the control according to the current time and state of lead-acid batteries to assist technology plants in achieving the effective management.In accordance with instantaneous current discharge, the relationship between lead-acid battery voltage and time is applied to collecting the testing data for the statistical analyses of service time, internal resistance, discharge voltage, and float voltage, which are compared with basic statistical analysis, regression analysis, and discriminated analysis for the effective management.


### 3.5. Research Devices and Practice

Based on the above research process, this study practiced measuring device checking, uninterruptible power supply checking, researcher security, measuring equipment parameter setting, float voltage testing, and discharge testing for effectively testing the battery state and understanding the real change time of batteries to reduce the costs.(1) Measuring Device Checking. The state and maintenance of the measuring devices should be checked before the measurement so as to accurately test the state of lead-acid batteries in uninterruptible power supply and reduce errors. Five minutes are expected to check the measuring devices and the accessories, including the measuring devices of operational power, voltage measuring tool, discharge probe, data transmission line, 13 mm spanner, and analysis software, the other tools of multimeter, standby battery, and discharge probe levelling tools of sandpaper, wirecutter, and needle-nose plier. The specific check proceeds after completing the checking and preparations.(2) Uninterruptible Power Supply Checking. Uninterruptible power supply in technology plants is regarded as the research subject in this study. Proceeding with uninterruptible power supply checking to confirm the state of uninterruptible power supply could prevent the experimental errors and protect the security of the personnel. Five minutes are estimated for the confirmation of uninterruptible power supply, including uninterruptible power supply operating state, lead-acid battery appearance, environmental condition, charge setting, and operating space, and the other tools and machinery of multimeter, uninterruptible power supply panel, thermometer, and visual inspection and hands. The specific confirmation proceeds after the checking and preparations.(3) Researcher Security. There are risks in instantaneous current discharge that complete preparations are required for ensuring the researchers’ security. It takes about three minutes for the researchers to put on the protective garments, including Insulating Gloves, Long-Sleeves Work Suit, and Insulating Tool. Measuring operation manual is followed for the operation and wearing so as to ensure the researchers being in the optimal security. The specific confirmation proceeds after the checking and preparations.(4) Measuring Device Parameter Setting. The measuring device parameters are set after the preparations in order to precisely measure the experimental data. The devices are functioned DATE, USER CODE, BATT GROUP, BATT NO., DATE OF MFG, and CURRENT. The parameters are set and operated according to measuring body device, battery specification, and measuring operation manual.(5) Float Voltage Testing. Float voltage testing is done before the discharge testing. Connecting the voltage probe for float voltage measurement, the conducting strip of the battery is checked to ensure the tight lock. The testing system is further checked to avoid invalid data caused by errors. The devices cover measuring body device, measuring tool-voltage probe, battery specification, and measuring operation manual.(6) Discharge Testing. A discharge probe needs to be equipped in the initial discharge testing. The discharge testing of a single lead-acid battery can be completed within 1 sec (including discharge for 0.5 sec). The data are further confirmed to avoid invalidity. The devices include measuring body device, measuring operation manual, discharge work-current probe, and measuring tool-voltage clamp.


## 3.1. Research Variables

Based on the research variables of batteries, current, voltage, and battery state, the unit and codes are defined as follows:(1)
Battery Code (NO.).(2)
Service Time (Time; Unit: Month).(3)
Float Voltage (FV; Unit: V).(4)
Discharge Voltage (DV; Unit: V).(5)
Discharge Current (DA; Unit: A).(6)
Internal Resistance (R; Unit: mΩ).(7)
Battery State (Check; 1: OK, 2: WARNING, 3: EXCEPTION).


## 3.2. Research Hypotheses

The following hypotheses are proposed for the batteries so as to exclude some special situations and make the research results more precise.(1)
The longer service time (Time), the lower discharge voltage (DV).(2)
The longer service time (Time), the higher internal resistance (R).(3)
Battery state (Check) is correlated with service time (Time), discharge voltage (DV), and internal resistance (R).


## 3.3. Research Design

To effectively test the state and discharge capability of lead-acid batteries in uninterruptible power supply in technology plants, instantaneous current discharge is selected as the measurement in this study by testing the battery state with a measuring device and analyzing the tested discharge data with software.According to the process, more than two people are required to securely and accurately complete the research. The measuring devices are checked in the beginning of the research to ensure the usability. The condition of uninterruptible power supply is further confirmed to exclude the exception. The operation and evacuation routes are also confirmed for the operators’ security. Furthermore, the measuring device parameters are set for starting the experiment. In the testing process, each cell checked the discharge characteristics every 0.5 sec, and the characteristics of recovery voltage are also measured every 0.5 sec for testing the terminal voltage change. In addition, the voltage monitoring terminal is connected to the terminal of energy storage pool and the discharge current probe is directly linked to the battery terminal for diagnoses. The device is also checked for the misconnection. When there is exception resulting from misconnection, the device would alert the operator to ensure the operation security. Finally, the measured data are read for data analyses to explore the effective information for the effective management of the personnel in technology plants and cost reduction.


## 3.4. Research Methodology

Instantaneous current discharge is selected as the measurement in this study, as it is suitable for measuring the state of lead-acid batteries in uninterruptible power supply in technology plants with the following advantages.(1)
Instantaneous current discharge could control the capacity state and the starting ability of a single battery.(2)
DC resistance measured from the real discharge could be used for analyzing the degradation of polar plates and the terminal break and false welding of power collector as well as avoiding AC resistance errors.(3)
The float voltage data are applied to understanding the balance analysis of charge voltage and the examination of short circuit batteries.(4)
The recovery voltage data allow analyzing the factors in the electrolytic degradation.An instantaneous discharge device is utilized in this study for finding out the degraded batteries with the testing information and preceding the control according to the current time and state of lead-acid batteries to assist technology plants in achieving the effective management.In accordance with instantaneous current discharge, the relationship between lead-acid battery voltage and time is applied to collecting the testing data for the statistical analyses of service time, internal resistance, discharge voltage, and float voltage, which are compared with basic statistical analysis, regression analysis, and discriminated analysis for the effective management.


## 3.5. Research Devices and Practice

Based on the above research process, this study practiced measuring device checking, uninterruptible power supply checking, researcher security, measuring equipment parameter setting, float voltage testing, and discharge testing for effectively testing the battery state and understanding the real change time of batteries to reduce the costs.(1) Measuring Device Checking. The state and maintenance of the measuring devices should be checked before the measurement so as to accurately test the state of lead-acid batteries in uninterruptible power supply and reduce errors. Five minutes are expected to check the measuring devices and the accessories, including the measuring devices of operational power, voltage measuring tool, discharge probe, data transmission line, 13 mm spanner, and analysis software, the other tools of multimeter, standby battery, and discharge probe levelling tools of sandpaper, wirecutter, and needle-nose plier. The specific check proceeds after completing the checking and preparations.(2) Uninterruptible Power Supply Checking. Uninterruptible power supply in technology plants is regarded as the research subject in this study. Proceeding with uninterruptible power supply checking to confirm the state of uninterruptible power supply could prevent the experimental errors and protect the security of the personnel. Five minutes are estimated for the confirmation of uninterruptible power supply, including uninterruptible power supply operating state, lead-acid battery appearance, environmental condition, charge setting, and operating space, and the other tools and machinery of multimeter, uninterruptible power supply panel, thermometer, and visual inspection and hands. The specific confirmation proceeds after the checking and preparations.(3) Researcher Security. There are risks in instantaneous current discharge that complete preparations are required for ensuring the researchers’ security. It takes about three minutes for the researchers to put on the protective garments, including Insulating Gloves, Long-Sleeves Work Suit, and Insulating Tool. Measuring operation manual is followed for the operation and wearing so as to ensure the researchers being in the optimal security. The specific confirmation proceeds after the checking and preparations.(4) Measuring Device Parameter Setting. The measuring device parameters are set after the preparations in order to precisely measure the experimental data. The devices are functioned DATE, USER CODE, BATT GROUP, BATT NO., DATE OF MFG, and CURRENT. The parameters are set and operated according to measuring body device, battery specification, and measuring operation manual.(5) Float Voltage Testing. Float voltage testing is done before the discharge testing. Connecting the voltage probe for float voltage measurement, the conducting strip of the battery is checked to ensure the tight lock. The testing system is further checked to avoid invalid data caused by errors. The devices cover measuring body device, measuring tool-voltage probe, battery specification, and measuring operation manual.(6) Discharge Testing. A discharge probe needs to be equipped in the initial discharge testing. The discharge testing of a single lead-acid battery can be completed within 1 sec (including discharge for 0.5 sec). The data are further confirmed to avoid invalidity. The devices include measuring body device, measuring operation manual, discharge work-current probe, and measuring tool-voltage clamp.


## 4. Measuring Results and Analysis

### 4.1. Collection and Organization of Variable Data

The batteries in uninterruptible power supply in technology plants are discussed in this study. Total 16 batteries are recorded in the actual measurement, and total 64 pieces of data are acquired by recording Battery code (NO.), service time (Time; Unit: month), float voltage (FV; Unit: V), discharge voltage (DV; Unit: V), discharge current (DA; Unit: A), internal resistance (R; Unit: mΩ), battery state (Check; 1: OK, 2: WARNING, 3: EXCEPTION) at the time points at 8, 49, 89, and 102 months. For judging battery state (Check), a battery is first judged as exceptional when the discharge current is less than 80% (80 A) of the set 100 A. Second, an unfavorable discharge voltage condition is considered when discharge voltage DV < 90% (12.15 V) of the rated 13.5 V. Third, when the resistance is 1.75 times (7 mΩ) larger than the initial 4 mΩ, the internal resistance is unfavorable. Each unfavorable condition is added 1 to the battery state. Moreover, float voltage (FV) is affected by the charge voltage during online measurements that the measured value is merely regarded as the reference but not considered for the judgment. According to the statistical data diagram of lead-acid batteries at 8, 49, 89, and 102 months (Figure 2), float voltage of the lead-acid batteries at the 8th month is higher than the values of other aged lead-acid batteries, while float voltage at other months is not significantly related to battery time, possibly because of the effects of series-connected charge voltage.Figure 2
Float charge voltage of the lead-acid batteries.The experimental results show that discharge voltage of lead-acid batteries tends to be stable with the value in 12.7–12.2. However, comparing the batteries which are placed for 102 months with the control lead-acid batteries, discharge voltage gradually decreases. From the line graph of discharge voltage (Figure3), the voltage of lead-acid batteries, which are placed for 102 months, obviously weakens, presenting the positive proportion of the degradation and time.Figure 3
Discharge voltage of lead-acid batteries.In accordance with the statistical data of batteries at 8, 49, 89, and 102 months, the internal resistance at the 8th month is smaller, while the relative large value is revealed at the 102nd month when problems are likely to appear. From Figure4, batteries with longer service time would start degrading internally, resulting in increasing internal resistance.Figure 4
Internal resistance of lead-acid batteries.By observing the testing data, 16 batteries in 8 months are OK, showing the low probability of EXCEPTION; 15 batteries in 89 months are OK; merely one presents WARNING, showing that the batteries start degrading but are still secure. The battery state change therefore should be concerned for the management. Three batteries in 102 months show WARNING, and the rest 12 batteries reveal EXCEPTION, presenting the serious battery degradation that batteries after 102 months can no longer be used. In this case, the managers should make decisions on the battery discard.


### 4.2. Statistical Analyses

Table1 shows the statistics of mean, median, maximum, minimum, and standard deviation.Table 1
Basic statistics.
Variable
Time
FV
DV
DA
R
Check
Mean
62
13.431
12.224
98.656
12.605
1.438
Median
69
13.393
12.533
100
4.697
1
Maximum
102
13.624
12.695
100
461.551
3
Minimum
8
13.292
0.666
14
3.906
1
Standard deviation
37.081
0.097
1.496
10.750
57.032
0.794The regression analysis of the samples involve service time (Time) and discharge voltage (DV); according to the analysis, the model correlation coefficient is low as shown as Table2, and the data are checked for excluding the outlier.Table 2
Service time and discharge voltage of regression analysis.
Variable
Coefficient estimates
Standard deviation
t-value
P value
Significant
R-square
Constant
12.937
0.354
36.54
<0.0001
1%
0.0665
Time
−0.0115
0.0049
−2.34
0.0224
5%After excluding the outlier, the test on service time (Time) and discharge voltage (DV) keeps do regression analysis; according to it, the model correlation coefficient increases up to 0.6072. Apparently, discharge voltage of lead-acid batteries would be affected by service time that the negative correlation appears under the significance 5%. It shows that the longer service time would reduce discharge voltage (Table3).Table 3
Regression analysis (excluding outliers).
Variable
Coefficient estimates
Standard deviation
t-value
P value
Significant
R-square
Constant
12.787
0.0450
283.93
<0.0001
1%
0.6072
Time
−0.0062
0.0006
−9.84
<0.0001
5%The regression analysis on service time (Time) and internal resistance (R) goes on, by which the model correlation coefficient reveals 0.6538, presenting the effects of service time on lead-acid battery resistance. The positive correlations appear under the significance 1% that the longer service time could enhance internal resistance (Table 4).Table 4
Service time and internal resistance of regression analysis.
Variable
Coefficient estimates
Standard deviation
t-value
P value
Significant
R-square
Constant
3.2847
0.2354
13.96
<0.0001
1%
0.6538
Time
0.0358
0.0033
10.87
<0.0001
1%Regression analysis is preceded for battery state (Check) towards internal resistance (R) and discharge voltage (DV). The model correlation coefficient shows 0.7507, revealing the negative correlation between lead-acid battery state and discharge voltage under the significance 1%. It presents that the lower discharge voltage would worsen the battery condition. The remarkable correlation between internal resistance and battery state is not as good as discharge voltage, showing that both discharge current (DA) and discharge voltage should be measured for judging the battery condition (Table 5).Table 5
Battery state, internal resistance, and discharge voltage.
Variable
Coefficient estimates
Standard deviation
t-value
P value
Significant
R-square
Constant
86.9502
14.9149
5.83
<0.0001
1%
0.7507
DV
−6.5462
1.1146
−5.87
<0.0001
1%
R
−0.7881
0.2002
−3.94
0.0002
1%Finally, the measurement of discriminant analysis has to be done. The normal (OK) samples present 75%, the ones with WARNING show 6.25%, and the defective ones (NG) reveal 18.75%, where misjudging OK as NG appears once, 2.08%. In summary, the normal judgment (OK) appears to be 97.92%, the ones of WARNING present 100%, and the defective ones (NG) are 100%. The overall misjudgment proportion presents the accuracy of the verification. Table6 shows the data in check discriminant analysis.Table 6
Battery state of discriminant analysis.
Check
OK
Warning
NG
Total
OK
47
0
1
48
97.92%
0%
2.080%
100%
Warning
0
4
0
4
0%
100%
0%
100%
NG
0
0
12
12
0%
0%
100%
100%


### 4.3. Management Structure

The experimental results of lead-acid batteries show the positive proportion between the battery degradation and time. The change appears on the end of battery life when it accelerates the degradation. Figure5 shows the discharge voltage/internal resistance distribution of the 64 batteries. Similar to the previous analyses, the longer service time would decrease discharge voltage and enhance internal resistance.Figure 5
Discharge voltage/internal resistance distribution.It is suggested in IEEE Std 1188 that lead-acid batteries with the discharge capability lower than 80% should be discarded. Nevertheless, batteries can still be used for a period of time after the time point (as the measured discharge voltage in Figure5 merely shows 1 sample not being able to be discharged, while the rest of the samples could meet the requirement of the rated discharge current). In consideration of the operation cost, lowering the limit for discard could reduce the cost. However, the late changing time might affect the stable device operation and influence the operation of the plant to cause loss.Based on the internal standard process, the lead-acid batteries in uninterruptible power supply should be discarded after 4 years (48 months). When the data showed WARNING, service time might be prolonged to 7 years. In the case company, total 9,559 lead-acid batteries were purchased in different years. According to the standard process, about 136.8 million NT dollars are required for battery discard in 2004–2020. When the discard time is prolonged to 7 years (84 months), total 88.215 million NT dollars is required for battery discard in 2004–2020. Total 48.595 million NT dollars therefore could be reduced in the 16 years that about 3 million NT dollars is reduced annually.The analysis results show that the approach could accurately judge the battery state. Except bad quality or end of battery life, internal resistance and discharge voltage degrade slowly and continuously, which might be measured after several months. Based on the concept, the battery maintenance is classified into new, midterm, and end-term for tests. New batteries are the ones newly purchased, which could be defined as feedstock tests when the batteries are tested in the beginning of purchase so as to reduce the risk of bad quality. Moreover, there are several factors in the residual capacity and service life of lead-acid batteries, including battery structure, environmental temperature, depth of previous discharge, self-discharge, discharge current, charge method, and end of discharge voltage. The end-term batteries are therefore defined as service time over a half of the battery life. The test is then shortened from 6 months to 3 months, expecting to find out the breakdown, proceeding with maintenance and discard, and ensure the system reliability, other than those defined as midterm batteries, which are relatively stable and show lower risks of breakdown. The test proceeds once a year to reduce the work load of the testing personnel.


## 4.1. Collection and Organization of Variable Data

The batteries in uninterruptible power supply in technology plants are discussed in this study. Total 16 batteries are recorded in the actual measurement, and total 64 pieces of data are acquired by recording Battery code (NO.), service time (Time; Unit: month), float voltage (FV; Unit: V), discharge voltage (DV; Unit: V), discharge current (DA; Unit: A), internal resistance (R; Unit: mΩ), battery state (Check; 1: OK, 2: WARNING, 3: EXCEPTION) at the time points at 8, 49, 89, and 102 months. For judging battery state (Check), a battery is first judged as exceptional when the discharge current is less than 80% (80 A) of the set 100 A. Second, an unfavorable discharge voltage condition is considered when discharge voltage DV < 90% (12.15 V) of the rated 13.5 V. Third, when the resistance is 1.75 times (7 mΩ) larger than the initial 4 mΩ, the internal resistance is unfavorable. Each unfavorable condition is added 1 to the battery state. Moreover, float voltage (FV) is affected by the charge voltage during online measurements that the measured value is merely regarded as the reference but not considered for the judgment. According to the statistical data diagram of lead-acid batteries at 8, 49, 89, and 102 months (Figure 2), float voltage of the lead-acid batteries at the 8th month is higher than the values of other aged lead-acid batteries, while float voltage at other months is not significantly related to battery time, possibly because of the effects of series-connected charge voltage.Figure 2
Float charge voltage of the lead-acid batteries.The experimental results show that discharge voltage of lead-acid batteries tends to be stable with the value in 12.7–12.2. However, comparing the batteries which are placed for 102 months with the control lead-acid batteries, discharge voltage gradually decreases. From the line graph of discharge voltage (Figure3), the voltage of lead-acid batteries, which are placed for 102 months, obviously weakens, presenting the positive proportion of the degradation and time.Figure 3
Discharge voltage of lead-acid batteries.In accordance with the statistical data of batteries at 8, 49, 89, and 102 months, the internal resistance at the 8th month is smaller, while the relative large value is revealed at the 102nd month when problems are likely to appear. From Figure4, batteries with longer service time would start degrading internally, resulting in increasing internal resistance.Figure 4
Internal resistance of lead-acid batteries.By observing the testing data, 16 batteries in 8 months are OK, showing the low probability of EXCEPTION; 15 batteries in 89 months are OK; merely one presents WARNING, showing that the batteries start degrading but are still secure. The battery state change therefore should be concerned for the management. Three batteries in 102 months show WARNING, and the rest 12 batteries reveal EXCEPTION, presenting the serious battery degradation that batteries after 102 months can no longer be used. In this case, the managers should make decisions on the battery discard.


## 4.2. Statistical Analyses

Table1 shows the statistics of mean, median, maximum, minimum, and standard deviation.Table 1
Basic statistics.
Variable
Time
FV
DV
DA
R
Check
Mean
62
13.431
12.224
98.656
12.605
1.438
Median
69
13.393
12.533
100
4.697
1
Maximum
102
13.624
12.695
100
461.551
3
Minimum
8
13.292
0.666
14
3.906
1
Standard deviation
37.081
0.097
1.496
10.750
57.032
0.794The regression analysis of the samples involve service time (Time) and discharge voltage (DV); according to the analysis, the model correlation coefficient is low as shown as Table2, and the data are checked for excluding the outlier.Table 2
Service time and discharge voltage of regression analysis.
Variable
Coefficient estimates
Standard deviation
t-value
P value
Significant
R-square
Constant
12.937
0.354
36.54
<0.0001
1%
0.0665
Time
−0.0115
0.0049
−2.34
0.0224
5%After excluding the outlier, the test on service time (Time) and discharge voltage (DV) keeps do regression analysis; according to it, the model correlation coefficient increases up to 0.6072. Apparently, discharge voltage of lead-acid batteries would be affected by service time that the negative correlation appears under the significance 5%. It shows that the longer service time would reduce discharge voltage (Table3).Table 3
Regression analysis (excluding outliers).
Variable
Coefficient estimates
Standard deviation
t-value
P value
Significant
R-square
Constant
12.787
0.0450
283.93
<0.0001
1%
0.6072
Time
−0.0062
0.0006
−9.84
<0.0001
5%The regression analysis on service time (Time) and internal resistance (R) goes on, by which the model correlation coefficient reveals 0.6538, presenting the effects of service time on lead-acid battery resistance. The positive correlations appear under the significance 1% that the longer service time could enhance internal resistance (Table 4).Table 4
Service time and internal resistance of regression analysis.
Variable
Coefficient estimates
Standard deviation
t-value
P value
Significant
R-square
Constant
3.2847
0.2354
13.96
<0.0001
1%
0.6538
Time
0.0358
0.0033
10.87
<0.0001
1%Regression analysis is preceded for battery state (Check) towards internal resistance (R) and discharge voltage (DV). The model correlation coefficient shows 0.7507, revealing the negative correlation between lead-acid battery state and discharge voltage under the significance 1%. It presents that the lower discharge voltage would worsen the battery condition. The remarkable correlation between internal resistance and battery state is not as good as discharge voltage, showing that both discharge current (DA) and discharge voltage should be measured for judging the battery condition (Table 5).Table 5
Battery state, internal resistance, and discharge voltage.
Variable
Coefficient estimates
Standard deviation
t-value
P value
Significant
R-square
Constant
86.9502
14.9149
5.83
<0.0001
1%
0.7507
DV
−6.5462
1.1146
−5.87
<0.0001
1%
R
−0.7881
0.2002
−3.94
0.0002
1%Finally, the measurement of discriminant analysis has to be done. The normal (OK) samples present 75%, the ones with WARNING show 6.25%, and the defective ones (NG) reveal 18.75%, where misjudging OK as NG appears once, 2.08%. In summary, the normal judgment (OK) appears to be 97.92%, the ones of WARNING present 100%, and the defective ones (NG) are 100%. The overall misjudgment proportion presents the accuracy of the verification. Table6 shows the data in check discriminant analysis.Table 6
Battery state of discriminant analysis.
Check
OK
Warning
NG
Total
OK
47
0
1
48
97.92%
0%
2.080%
100%
Warning
0
4
0
4
0%
100%
0%
100%
NG
0
0
12
12
0%
0%
100%
100%


## 4.3. Management Structure

The experimental results of lead-acid batteries show the positive proportion between the battery degradation and time. The change appears on the end of battery life when it accelerates the degradation. Figure5 shows the discharge voltage/internal resistance distribution of the 64 batteries. Similar to the previous analyses, the longer service time would decrease discharge voltage and enhance internal resistance.Figure 5
Discharge voltage/internal resistance distribution.It is suggested in IEEE Std 1188 that lead-acid batteries with the discharge capability lower than 80% should be discarded. Nevertheless, batteries can still be used for a period of time after the time point (as the measured discharge voltage in Figure5 merely shows 1 sample not being able to be discharged, while the rest of the samples could meet the requirement of the rated discharge current). In consideration of the operation cost, lowering the limit for discard could reduce the cost. However, the late changing time might affect the stable device operation and influence the operation of the plant to cause loss.Based on the internal standard process, the lead-acid batteries in uninterruptible power supply should be discarded after 4 years (48 months). When the data showed WARNING, service time might be prolonged to 7 years. In the case company, total 9,559 lead-acid batteries were purchased in different years. According to the standard process, about 136.8 million NT dollars are required for battery discard in 2004–2020. When the discard time is prolonged to 7 years (84 months), total 88.215 million NT dollars is required for battery discard in 2004–2020. Total 48.595 million NT dollars therefore could be reduced in the 16 years that about 3 million NT dollars is reduced annually.The analysis results show that the approach could accurately judge the battery state. Except bad quality or end of battery life, internal resistance and discharge voltage degrade slowly and continuously, which might be measured after several months. Based on the concept, the battery maintenance is classified into new, midterm, and end-term for tests. New batteries are the ones newly purchased, which could be defined as feedstock tests when the batteries are tested in the beginning of purchase so as to reduce the risk of bad quality. Moreover, there are several factors in the residual capacity and service life of lead-acid batteries, including battery structure, environmental temperature, depth of previous discharge, self-discharge, discharge current, charge method, and end of discharge voltage. The end-term batteries are therefore defined as service time over a half of the battery life. The test is then shortened from 6 months to 3 months, expecting to find out the breakdown, proceeding with maintenance and discard, and ensure the system reliability, other than those defined as midterm batteries, which are relatively stable and show lower risks of breakdown. The test proceeds once a year to reduce the work load of the testing personnel.


## 5. Conclusion

Aiming at the management of degrading lead-acid batteries in uninterruptible power supply in technology plants, a testing method not affecting the online testing is selected. A battery testing process is established according to the research results, expecting to change the time-based regular testing into active condition-based maintenance, which detects the device parameters and adopts proper maintenance before the exception or breakdown. Such a testing strategy presents the following features.(1)
In consideration of time, accuracy, and online detectability, the discharge is checked in short time, and DC resistance, float voltage, discharge voltage, and charge voltage are recorded in the process to provide a testing method for battery state.(2)
The battery management is provided for technology plants, expecting to verify the health of each battery, find out the degraded batteries for discard, and confirm the actual discard time of batteries. Hence, it is able to ensure the system reliability and provide users with managerial strategies.(3)
Aiming at reducing the maintenance cost, current time-based regular testing for advance discard is adjusted to condition-based maintenance based on the discharge tests.Under the fierce competition in modern technology industry, cost reduction is always the requirement of managers. Nevertheless, in consideration of device operation maintenance and system stability, the optimal device maintenance strategy could minimize the maintenance cost and maximize the system stability.In the regular testing process, setting the measuring cycle might be difficult. A long cycle might reduce the number of testing times but increase the risk of exceptional batteries not being checked. A short cycle could cause overmaintenance and manpower load because of the increasing number of testing times and testing manpower costs. Factors in battery life are numerous that instantaneous current discharge is applied to establishing a management method in this study. It could not only ensure the system stability in the plant but also acquire the maximal use effectiveness, reduce the maintenance cost, enhance the company competitiveness, and reduce the impact of used batteries on the environment by decreasing unnecessary battery discard so as to contribute to the environmental protection and waste reduction.



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*Source: 910820-2014-09-25.xml*