# Effects of Zinc-Free Processing Aids on Silica-Reinforced Tread Compounds for Green Tires

Authors: Nam Chul Kim; Sung Ho Song
Journal: International Journal of Polymer Science
 (2019)

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## Abstract

With the development of “green tires” in the tire industry, the conventional carbon black filler that is used in tread formulations is being replaced with silica. Generally, this requires the addition of a processing aid, containing zinc ion, which acts as a lubricant and dispersing agent. However, because zinc is a heavy metal, zinc-free processing aids (ZFAs) are required to satisfy worldwide environmental concerns. We present herein a series of catalytically synthesized ZFAs and evaluate the effects of replacing zinc ion-containing processing aids (ZCAs) on a silica tread formulation. Interestingly, replacing ZCA with ZFA in a two parts per hundred rubber (phr) by weight formulation improved both its tensile strength and elongation by as much as 31% and 20%, respectively. ZFA-rubber formulations also exhibited a twofold enhancement in fatigue properties over those of ZCA-rubber formulations. Furthermore, pneumatic tires were fabricated from our ZFA-rubber formulation and compared against tires containing ZCAs. The ZFA-rubber composite exhibited improved dry and wet braking and rolling resistance due to enhanced dispersion of silica in the rubber matrix. These results show that rubber composites prepared with ZFAs may be promising in tire engineering applications.


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## Body

## 1. Introduction

Carbon black is an important filler that enhances the physical and mechanical properties, including tear strength, hardness, and abrasion resistance, of almost all industrial rubbers [1–3]. In recent years, however, “green tires” made with silica fillers instead of carbon black have exhibited greater abrasion resistance and wet grip, as well as lower rolling resistance [4–6]. Silica, which bears silanol and siloxane functional groups, differs from carbon black in both chemical composition and method of manufacture [7]. Silanol groups are acidic [8] and interact with basic accelerators, thereby slowing cure rates and lowering the cross-link density in sulfur-cured systems [9]. The viscosity of a formulation increases with the amount of silica particles, which tend to interact strongly with themselves due to their polar and hydrophilic nature [10]. Thus, silica-containing formulations are more difficult to process, and silica particles are relatively difficult to disperse in a rubber matrix [11–14]. Silane coupling agents have been used to modify the surface of silica particles to enhance rubber-filler interactions. These include TESPT (bis(triethoxysilylpropyl)tetrasulfide) and TESPD (bis(triethoxysilylpropyl)disulfide), which, due to their bifunctional characteristics, act as chemical bonding agents between the rubber matrix and silica during vulcanization [15–17].The processing agents used in the manufacture of tire rubbers are classified according to their chemical structure and include hydrocarbons, low molecular weight polymers, fatty acid derivatives, synthetic resins, and other organic compounds. Several additives, such as fatty acid esters, act as lubricants and/or dispersion agents. In particular, bifunctional silanes containing sulfur have been used to improve processability during mixing and the chemical bonding between silica and rubber. Currently, zinc soaps such as zinc stearate, zinc naphthenate, and zinc resinate are used as processing agents in rubber formulations. Most zinc soaps act as intermolecular lubricants because they are rubber-soluble. However, zinc consumption is a worldwide environmental concern, and the automotive industry, as a main contributor, is under increasing pressure to decrease its share. Although large amounts of zinc-containing additives are used in the automotive industry, there are relatively few studies that address zinc-free processing aids (ZFAs).The current study describes the catalytic fabrication of ZFAs having hydrophilic groups and fatty acid at opposite ends of the molecule. This structure serves to enhance the dispersion of silica in the rubber matrix. The fatty acid group reacts with double bonds on the rubber chain [18, 19], while the hydrophilic group reacts with silanols on the silica surface [20, 21]. This report also evaluates the effects of conventional and silica-based processing aids in styrene butadiene rubber (SBR) during mixing and after vulcanization. A master batch of SBR, made with typical processing aids and a silica filler, was used to improve their dispersion in a rubber latex matrix through a latex mixing method. This method was a scalable, versatile, inexpensive, fast, and convenient method of enhancing the performance of rubber composites. Silica rubbers containing ZFAs exhibited more desirable mechanical, fatigue, and abrasion properties than those of zinc ion-containing processing aids (ZCAs). Furthermore, ZFAs were added to the SBR tread compound used to manufacture a pneumatic tire to represent the possibility of “green tires” containing the silica fillers. This tire boasted a low rolling resistance and highly improved grip in both dry and wet conditions. This research shows the advantages and potential of silica-based fillers for tire engineering.


## 2. Experimental Section

### 2.1. Materials

An SBR (SBR 1500) consisting of 23% styrene and 77% butadiene was purchased from Kumho Petrochemical Co. Ltd., Korea. The silica and coupling agent used in this study were supplied by Solvay. Silicas and zinc ion processing aids were obtained from Struktol Co., USA. Also, carbon black (N 330) was obtained from OCI Co. Ltd., Korea, and N-tert-butyl-benzothiazole sulfonamide (TBBS) were purchased from Shangdong Shanxian Co. Ltd., China. Zinc oxide (ZnO), stearic acid (S/A), and sulfur were purchased from Sigma-Aldrich.


### 2.2. Preparation of ZFAs

Glycerol was formed through the catalytic reaction of triglycerides, KOH, and NaOH in methanol. The molar ratio of glycerol and fatty acid is 2 : 1 and mixed with a metal catalyst until the acid value was zero at 400 rpm at 200°C for 5 h in an inert atmosphere.


### 2.3. Preparation of Rubber Composites

SBR/silica composites with processing aids were fabricated by the standard processes in TablesS2 and S3. In Table S2, firstly, an SBR latex (20 phr (parts per hundred rubber) by weight) containing 20 phr silica with ZFAs and ZCAs was mixed by vigorous stirring for 24 h. An SBR latex (20 phr) was also prepared with silica (20, 40, and 60 phr) and contained ZFAs and ZCAs at 2 phr in Table S3. This mixture was also mixed for 24 h. The processing aids/silica-SBR composites were then coagulated with a sulfuric acid solution (1.0 phr). The composites were rinsed with water until the pH of the rinsate was 6~7 and then dried in an oven at 50°C for 24 h. Then, SBR (80 phr) and silica (20 phr)/SBR (20 phr) latex and various additives in a Banbury mixer at a rotor speed of 60 rpm were mixed. Finally, to initiate the curing process, the vulcanization agents and additives were added at the end of mixing. The fabrication process of the SBR composites is presented in Tables S2 and S3.


### 2.4. Characterization

Scanning electron microscopy (SEM; JEOL JSM-6490LV) was used to observe the morphology of fractured surfaces of rubber composites. The moving die rheometer test (MCR 702; Anton Paar) was observed to analyze the cure properties of the resulting materials under pressure. Mechanical tests (modulus, tensile strength, and elongation) were conducted with dumbbell-shaped samples (length: 100 mm, width: 5 mm) by using an Instron tensile machine (Instron Co., UK) at a speed of 300 mm/min. At least four tests were conducted for each type of sample. Dynamic properties were carried out in a tensile mode in a dynamic mechanical analyzer (DMA 50N01Db-METRAVIB). Also, the tan delta (temperature sweep of the loss factor) and the storage modulus were measured from 20°C to 120°C (heating rate: 3°C/min, frequency: 10 Hz).


## 2.1. Materials

An SBR (SBR 1500) consisting of 23% styrene and 77% butadiene was purchased from Kumho Petrochemical Co. Ltd., Korea. The silica and coupling agent used in this study were supplied by Solvay. Silicas and zinc ion processing aids were obtained from Struktol Co., USA. Also, carbon black (N 330) was obtained from OCI Co. Ltd., Korea, and N-tert-butyl-benzothiazole sulfonamide (TBBS) were purchased from Shangdong Shanxian Co. Ltd., China. Zinc oxide (ZnO), stearic acid (S/A), and sulfur were purchased from Sigma-Aldrich.


## 2.2. Preparation of ZFAs

Glycerol was formed through the catalytic reaction of triglycerides, KOH, and NaOH in methanol. The molar ratio of glycerol and fatty acid is 2 : 1 and mixed with a metal catalyst until the acid value was zero at 400 rpm at 200°C for 5 h in an inert atmosphere.


## 2.3. Preparation of Rubber Composites

SBR/silica composites with processing aids were fabricated by the standard processes in TablesS2 and S3. In Table S2, firstly, an SBR latex (20 phr (parts per hundred rubber) by weight) containing 20 phr silica with ZFAs and ZCAs was mixed by vigorous stirring for 24 h. An SBR latex (20 phr) was also prepared with silica (20, 40, and 60 phr) and contained ZFAs and ZCAs at 2 phr in Table S3. This mixture was also mixed for 24 h. The processing aids/silica-SBR composites were then coagulated with a sulfuric acid solution (1.0 phr). The composites were rinsed with water until the pH of the rinsate was 6~7 and then dried in an oven at 50°C for 24 h. Then, SBR (80 phr) and silica (20 phr)/SBR (20 phr) latex and various additives in a Banbury mixer at a rotor speed of 60 rpm were mixed. Finally, to initiate the curing process, the vulcanization agents and additives were added at the end of mixing. The fabrication process of the SBR composites is presented in Tables S2 and S3.


## 2.4. Characterization

Scanning electron microscopy (SEM; JEOL JSM-6490LV) was used to observe the morphology of fractured surfaces of rubber composites. The moving die rheometer test (MCR 702; Anton Paar) was observed to analyze the cure properties of the resulting materials under pressure. Mechanical tests (modulus, tensile strength, and elongation) were conducted with dumbbell-shaped samples (length: 100 mm, width: 5 mm) by using an Instron tensile machine (Instron Co., UK) at a speed of 300 mm/min. At least four tests were conducted for each type of sample. Dynamic properties were carried out in a tensile mode in a dynamic mechanical analyzer (DMA 50N01Db-METRAVIB). Also, the tan delta (temperature sweep of the loss factor) and the storage modulus were measured from 20°C to 120°C (heating rate: 3°C/min, frequency: 10 Hz).


## 3. Characterization of Results and Discussions

We present a series of ZFAs fabricated by the catalytic reaction shown in Figure1. Figure 1 presents the preparation of glycerol using triglycerides and a metal catalyst in methanol through catalytic reaction. This process afforded ZFAs bearing both hydrophilic and hydrophobic groups in large quantities. Due to the absence of zinc in the former, the melting points of the ZFAs were lower than those of the corresponding ZCAs, as shown in Table S1. The ZFAs were pelletized so that they were more easily incorporated into tire engineering applications. The properties of ZFAs are confirmed by the spectroscopic analysis and thermogravimetric analysis (TGA) in Figure S1. The chemical structure of the ZFAs was analyzed by X-ray photoelectron spectroscopy (XPS). The C1s signal consisted of three different peaks: the C-C bond (284.5 eV), C-O (286.6 eV), and C=O (288.2 eV) of the carbonyl groups in Figure S1a. Also, the peaks of O1s and C=O peaks (530.5 eV and 532.8 eV) were showed in the ZFAs from the O1s scan (Figure S1c). In the FT-IR spectra, ZFAs are shown C-H stretching and C-OH stretching peaks in carbonyl and carboxylic acid groups in Figure S1d. Furthermore, in the TGA result, mass of ZFAs begins to lose at 100°C and completely decomposes at 400°C.Figure 1
A schematic diagram showing the preparation of zinc-free processing aids (ZFAs).Figures2(a) and 2(b) show a comparison of the modulus, tensile strength, and elongation of SBR composites as a function of increasing ZFA or ZCA content. Modulus and tensile strength decreased with increasing amounts of processing aid, while elongation increased due to increasing viscosity. The modulus and tensile strength of composites containing ZFAs (2 phr) were as much as 11% and 31% greater than those containing ZCAs, respectively. This performance enhancement was due to the amphoteric nature of ZFAs and the resulting stronger interfacial bonding and improved dispersion of silica within the elastomer matrix and the restriction of segmental elastomer chain motion. Figure 2(b) shows that the elongation at break of ZFA/SBR composites (490%) was greater than that of ZCA composites (410%). The increased reinforcement can be attributed to the large contact area between silica and the elastomer matrix. Figure 2(c) shows the abrasion properties of SBR composites containing ZFAs or ZCAs. The amount of abrasion loss, on the whole, increased with the amount of processing aid due to the increasing viscosity of the composites. Note that the ZFA/SBR composites exhibited greater wear resistance (William wear 4.03%) due to enhanced silica dispersion and cross-linking density. The dynamic mechanical properties (DMA), such as tanδ (the ratio of loss modulus to storage modulus), of SBR composites containing ZFAs and ZCAs are shown as a function of temperature in Figure 2(d). DMA tests can be used to predict both wet traction and rolling resistance [22]. With the addition of ZFAs, the tanδ of 0°C was about 5% higher than that of SBR composites containing ZCAs. This implies that pneumatic tires incorporating ZFAs have the potential for improved wet grip tire performance. Furthermore, the 60°C tanδ of the ZFA/SBR composites was about 5% lower than that of the ZCA/SBR composites, indicating a potentially lower rolling resistance of the former [23, 24].Figure 2
(a) Modulus and tensile strength, (b) elongation, (c) William abrasion, and (d) dynamic properties (tanδ) of rubber composites with zinc ion-containing processing aids (ZCAs) and ZFAs.
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(d)The physical properties of SBR composites with ZFCs and containing other processing aids were studied. The constrained region (rubber chains immobilized on the surface of fillers) serves as a commercializer in rubber composites. This reinforcement is enhanced by the filler and prevents phase separation, and the weight fraction of rubber chains immobilized on the surface of fillers (χm) can be calculated as follows:
(1)ΔCpn=ΔCp1–ω,χim=ΔCp0–ΔCpnΔCp0,where ΔCp is the heat capacity jump at the glass transition temperature (Tg), ΔCpn is the heat capacity jump normalized to the rubber fraction, ΔCp0 represents the heat capacity jump at the Tg of the neat rubber, and ω is the weight fraction of fillers in the composites. Also, the heat capacity changes were measured by differential scanning calorimetry (DSC). In Table S4, the value of χim for ZFCs/SBR is much higher than those of the ZCAs/SBR compositions.The SEM micrographs in Figures3(a) and 3(b) and S1 show that silica (20 phr) disperses evenly throughout ZFA/SBR composites without coagulation. Figure S2 also shows that increasing the proportion of ZFA decreased the number of coagulated particles in the rubber matrix. This result supports the Garvey Die Extrusion tests. A Garvey die in a Haake torque rheometer was used to monitor the sheet forming and extrusion behavior of the SBR composites. Figures 3(c)–3(f) show extrusion quality as a function of the type of processing aid. Figures 3(c) and 3(d) and S3 show that rubber extrusions containing a high loading of ZFA exhibited smoother and more stable edges. This effect was likely due to the relatively high viscosity of the ZFA formulations. Figures 3(e) and 3(f) show that extrusions made with the ZCA/SBR composites had rougher surfaces and more unstable edges.Figure 3
Scanning electron microscopy (SEM) micrograph of rubber composites made with (a) ZFAs and (b) ZCAs. (c) Images of Garvey die extrusions of rubber composites made with (c) ZFAs (enlarged image in (d)) and (e) ZCAs (enlarged image in (f)).Tensile strength and elongation of SBR composites are shown as a function of silica loading in Figures4(a) and 4(b). While the addition of silica resulted in significant increases in tensile strength (Figure 4(a)), it also resulted in decreased elongation (Figure 4(b)). Compared to ZCA/SBR composites, the tensile strength and elongation of ZFA/SBR composites containing 60 phr silica increased to 218 MPa and 450%, corresponding to enhancements of 8% and 12.5%, respectively, while the modulus remained unchanged (Figure S4). Figure 4(c) shows that abrasion resistance also increased with increasing silica content. The William abrasion test of ZFA-rubber composites was lower than that of ZCA composites, implying improved dispersion of silica in the rubber matrix. The fatigue properties of SBR composites with various processing aids are shown in Figure 4(d). In general, reductions in fatigue life were observed with increasing silica content. However, the fatigue life of ZFA/SBR composites was more than twice that of ZCA/SBR composites. This is likely due to the more uniform dispersion of ZFAs in the rubber matrix.Figure 4
(a) Tensile strength, (b) elongation, (c) William abrasion, and (d) fatigue properties (fatigue crack generation) of rubber composites containing ZCAs or ZFAs with varying degrees of silica loading.
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(d)SEM micrographs of silica (60 phr)/SBR composites containing 2 phr of processing aids show that the silica was evenly dispersed in the ZFA/SBR composites without coagulation (Figures5(a) and 5(b) and S5). Furthermore, Figure S4 shows that both the degree of dispersion and the uniformity of distribution of silica were enhanced with the use of ZFAs. This result is also supported by the fatigue properties of silica treads shown in Figure S5. After 10,000 cycles, the crack length in silica treads made with ZFA/SBR composite was approximately 26% greater than that of treads made with ZCA/SBR. Figures 5(c)–5(f) show that ZFA (2 phr)/SBR composites yielded smoother extrusions with more stable edges compared to those made with ZCA/SBR composites.Figure 5
SEM micrographs of (a) ZFA- and (b) ZCA-rubber composites with 60 parts per hundred rubber (phr) silica. Garvey die extrusion images of (c) ZFA (2 phr)- and (d) ZCA (2 phr)-rubber composites with 40 phr silica and (e) ZFA (2 phr)- and (f) ZCA (2 phr)-rubber composites with 60 phr silica.
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(f)Pneumatic tires were made with each composite to confirm the superior performance of the ZFA/SBR composites. The results of mechanical tests are given in Figure6. Figure 6(a) compares the physical properties of SBR composites made with different processing aids. The modulus and tensile strength of tread compounds made with ZFA/SBR were as much as 3% and 12% greater than those of the control, respectively. In addition, the elongation of ZFA/SBR treads was significantly greater than that of ZCA/SBR treads. The elongation of ZFA/SBR treads increased by 8%. As discussed above, this enhancement is attributed to strong interfacial bonding and improved dispersion of silica within the rubber matrix.Figure 6
(a) Modulus, tensile strength, and elongation, (b) dynamic properties (tanδ), (c) abrasion and rebound, and (d) Garvey die extrusion images of tire tread compounds made with ZCA/styrene butadiene rubber (SBR) or ZFA/SBR composite.
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(d)The DMA of a particular rubber formulation is important because rubber composites are frequently subjected to dynamic loading. Figure6(b) shows the DMA of pneumatic tires, including tanδ of the control and ZFA/SBR composite tires, as a function of temperature. While the tanδ of 0°C for ZFA/SBR treads was about 5% higher than that of the control, the tanδ of 60°C was about 11% lower than that of the control. These data demonstrate the potential of pneumatic tires with ZFAs for enhanced rolling resistance and wet grip [23, 24]. The abrasion and rebound properties of silica tread compounds are shown in Figure 6(c). The William abrasion test of pneumatic tires made with ZFAs was more than two orders of magnitude higher than that of the control. This is attributed to rubber-filler interactions among ZFA particles. The effect of ZFA loading on rebound resilience at room temperatures is given in Figure 6(c). The percent rebound resilience of ZFA/SBR composites was about 9% greater than that of ZCA/SBR composites. This result indicates that the presence of ZFAs improves the elasticity of rubber composites due to increased cross-link density between silica and the rubber matrix. This agrees with the results of Garvey die extrusion tests shown in Figure 6(d). Due to the higher viscosity of the ZFA formulations, extrusions made with ZFA/SBR composites exhibited stable edges and a smoother shape than those made with the control composite.Finally, virtual tests were performed using a vehicle-mounted pneumatic tire made with ZFA/SBR or ZCA/SBR composite rubbers. The results are shown in Figure7. Generally, the high-speed durability and rolling resistance of the tires play important roles in characteristics of vehicle dynamics [25, 26]. The data in Figures 7(a) and 7(b) show that treads made with ZFA/SBR composites exhibited lower rolling resistance with increased grip under braking in both wet and dry conditions. The pneumatic tire with ZFA/SBR compounds shows dry and wet braking properties improved by 4% and 3% compared to the control compound, respectively. Also, in Figure 7(b), the pneumatic tire with the ZFA/SBR compound (9.21 N/kN) exhibits an improved rolling resistance coefficient compared to the control compound (9.7 N/kN). These results are due to the improved viscoelastic properties by strong interfacial interactions between silica and the rubber matrix in ZFA/SBR composites. Finally, Figures 7(c) and 7(d) show the results of high-speed endurance tests of the ECE (Economic Commission for Europe) #30 HSP and DOT (US Department of Transportation) 139. The DOT guidelines ensure that a tire meets or exceeds the safety requirements of the US Department of Transportation, and ECE#30 is a European guideline that sets requirements for tire size, rolling resistance, braking, and high-speed durability. In general, tire failure occurs in belt separation due to the heat generated by external impact and movement in high-speed tests. In Figure 7(c), though the pneumatic tire with the ZCA/SBR compound generated chunks due to reduced durability, belt separation occurs in the pneumatic tires with the ZFA/SBR compound. Furthermore, similar results were obtained in DOT tests in Figure 7(d). The closer the silica filler aggregates to each other, the greater the desorption and heat concentration, which means that polymer chains can more easily break away from the silica particles, resulting in a drop in mechanical properties [27, 28].Figure 7
(a) Dry and wet braking properties, (b) rolling resistance coefficients, (c) high-speed durability (ECE#30 HSP), and (d) high-speed durability (DOT 139) of pneumatic tires made with ZCA/SBR or ZFAs/SBR composite.
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## 4. Conclusion

ZFAs were synthesized using a catalytic reaction and evaluated in rubber compositions used for tire treads. The incorporation of ZFAs into SBR rubber matrices resulted in remarkable improvements in modulus, tensile strength, elongation, and dynamic properties. These enhancements were attributed to uniform dispersion of silica particles, and enhanced interfacial bonding between these particles and the SBR, in the rubber matrix. This study also demonstrates the ease with which ZFA/SBR composites can be integrated into a rubber matrix using a new, versatile, and simple approach based on latex technology. Furthermore, ZFA/SBR composites were employed directly as additives in the tread of a pneumatic tire. Tires fabricated with the ZFA/SBR composite exhibited significantly improved dry and wet braking, rolling resistance, and high-speed durability due to enhanced dispersion of silica in the compounds. These results also demonstrate the effectiveness of ZFA processing aids in the production of elastomer composites for use at low loading levels.



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*Source: 9123635-2019-06-25.xml*