# A Study of the Differences in the Gas Diffusion and Migration Characteristics of Soft and Hard Coal in High Gas Coal Seams

Authors: Anying Yuan
Journal: Advances in Civil Engineering
 (2020)

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## Abstract

At the present time, it is of major significance to examine the differences in the gas diffusion and migration characteristics of soft and hard coal in order to prevent and control safety hazards in high gas coal seams. In this study, the differences in the gas diffusion and migration characteristics between soft coal and hard coal were examined in detail using macrostructural, mesostructural, and microstructural research methods. The root causes of the differences in the gas diffusion and migration between soft coal and hard coal were revealed in the obtained research results. The study shows that, in terms of the macrostructures, the soft coal particle grains were flakey and with shapes resembling fingernails. Meanwhile, the hard coal particle grains were observed to be in the shapes of complete blocks. In addition, in terms of the mesostructures of the different coal types, it was found that the proportion of granular coal below the particle size limit of 6 mm in the soft coal was much higher than that of the hard coal. Also, from the aspect of the characteristics of the microstructures, the pores and fissures on the soft coal surfaces were observed to be better developed, and the BJH specific surface areas of the soft coal were more than twice those of the hard coal. That is to say, the gas diffusion and migration conditions of the soft coal were better than those of the hard coal. At the same time, the increments of the specific surface areas and volumes of the pores of soft coal were above 100 nm, which provided channels for gas diffusion and migration at rates of more than twice those of the hard coal. Therefore, the soft coal was more conducive to gas emissions. This study conducted gas desorption experiments on both soft and hard coal samples and found that the initial gas desorption speed of the soft coal was significantly higher than that of the hard coal. Since the instantaneous gas emissions of the soft coal were significantly higher than those of the hard coal, it was considered to be more likely that gas outbursts and transfinite accidents could potentially occur in the soft coal layers of a project site. This study’s results provided a foundation and basis for effective gas control measures in coal seams composed of soft coal layers, which will be of major significance to the safety of coal mining activities in the future.


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## Body

## 1. Introduction

Gas emissions are a type of disastrous gas hazard which may potentially impact the safe production processes of coal mines [1]. Coal seams that contain high content levels of gas are known to be easily affected by gas outburst accidents resulting in casualties and property losses [2–4]. However, within the same coal seam, different types of coal bodies may display significant differences in gas emission amounts, which pose greater challenges for the prevention and control of gas emissions in mine working faces [5–7].It was determined that several of the examined examples of coal and gas outbursts indicated that outburst accidents with prediction and effect inspection indexes not exceeding the standard limits had occurred in the soft layers of the coal seam, and the gas desorption laws of the soft and hard coal bodies were quite different [8–10]. It was observed that using the desorption laws of hard coal to test the gas content levels in soft coal seams, along with the gas desorption indexes of drill cuttings, would potentially lead to large errors in the test results.Previously, many experts and scholars in the field have conducted in-depth research regarding the characteristics of gas diffusion and migration in coal seams [11–13]. Some researchers believe that the majority of coal and gas outburst accidents occur on the roadways of driving faces and at both ends of working faces. This is due to the fact that the aforementioned areas tend to be disturbed by mining activities, and a general phenomenon of stress concentration is present, which plays a leading role in gas outburst events [14–17]. Second, some researchers have theorized that coal deposits, as the main carrier of coal and gas outbursts, are the objects of the gas outbursts, and the mechanical characteristics, pore structure characteristics, and other factors of the coal bodies themselves play important roles in the gas emission processes [18–22].Therefore, in view of the gas emission laws of coal bodies, experts in the field have adopted many research methods, including gas adsorption and desorption experiments, microscanning, micropore structure analyses, and mercury injection experiments [23–25]. However, the majority of the research studies generally utilize one or two of the aforementioned methods to examine the gas desorption laws of coal bodies. As a result, different research findings have been presented. In particular, there have been relatively few studies conducted regarding the phenomena observed in soft and hard coal bodies within the same coal seam.In the present research, from the aspects of the macrostructures, mesostructures, and microstructures of soft coal and hard coal, gas desorption experiments were conducted in order to comprehensively analyze the root causes of the differences in the characteristics of gas diffusion and migration in soft coal and hard coal. The results of the experimental processes revealed the mechanism of the differences in the gas emissions of soft coal and hard coal, which provided a foundation and basis for the prevention and control of coal seam gas disasters under similar conditions, which was considered to be of major significance to future coal mining projects.


## 2. Differences in the Characteristics of the Macrostructures and Mesostructures of Soft Coal and Hard Coal

In order to examine the differences in the gas diffusion processes between the soft coal and hard coal in high gas coal seams, the characteristics of macrostructures and mesostructures of soft and hard coal samples were first analyzed. In this study, soft coal and hard coal samples obtained from the No. 6 and No. 11 high gas coal seams of the Xieqiao Coal Mine in China’s Huainan mining area were selected. The No. 6 coal seam and No. 11 coal seam both contained soft layers (hereinafter referred to as the soft coal), and the physical and mechanical properties of soft layers and normal coal bodies (hereinafter referred to as the hard coal) were obviously different.Figure1 shows the macro characteristics of the soft coal and hard coal in each coal seam. It can be seen in the figure that the soft coal in each coal seam generally contained no large blocks, and the coal particles were generally uniform in size, displaying approximately nail-shaped flakey particles. Meanwhile, the hard coal was mainly in the form of blocks.Figure 1
Macroscopic characteristics of soft coal and hard coal. (a) Soft coal. (b) Hard coal.
(a)(b)An artificial crushing method was adopted in this study to simulate the crushing processes, which occur during the mining of a working face. A standard sieve was used to screen the soft coal and hard coal samples in order to obtain the fine particle size distribution law of the soft coal and hard coal, as shown in Figure2. The results indicated that there was a particle size limit during the process in which the particle sizes influenced the desorption and diffusion of the coal particle gas. The limit of the particle size was considered to be the inherent particle size of the coal, which was related to the degree of damage and metamorphism of the coal, with a maximum size of no more than 6 mm. It was observed that, in the ranges less than the particle size limit, the gas desorption strength and attenuation coefficient decreased with the increases in the coal particle sizes. However, when the coal particle sizes were larger than the particle size limit (6 mm), the decreasing trends of the gas desorption strength and attenuation coefficient with the increases in the coal particle sizes were not obvious. Therefore, this study selected a 6 mm particle size as the boundary for the purpose of analyzing the particle size distributions in the raw coal.Figure 2
Percentages of soft coal and hard coal with particle sizes less than 6 mm in each coal seam.The results of this study’s comparative analysis showed that the proportions of coal particles below 6 mm in the soft coal of the No. 6 and No. 11 coal seams were 54.63% and 68.54%, respectively. The proportions of the coal particles below 6 mm in the hard coal of the No. 6 and No. 11 coal seams were determined to be 17.72% and 21.45%, respectively. Therefore, the proportions of coal particles below 6 mm in soft coal were more than 3 times those of the hard coal. In other words, the proportions of coal particles below 6 mm in the soft coal of each examined coal seam were far higher than those of the hard coal.


## 3. Differences in the Micropore Structures of the Soft Coal and Hard Coal

In order to further explore the underlying mechanism of the differences in the gas diffusion and migration between the soft coal and hard coal, this study examined the micropore structures of each type of coal. A Micrometrics ASAP 2460 multistation specific surface and porosity analyzer was used for the determination of the micropore structural parameters, as shown in Figure3.Figure 3
ASAP 2460 multistation specific surface and porosity analyzer.


### 3.1. Comparative Analysis of the Specific Surface Areas of the Soft Coal and Hard Coal

Figure4 shows this study’s comparative analysis diagram of the BET specific surface areas and BJH specific surface areas of the soft coal and hard coal in the different coal seams. Table 1 shows this study’s pore structural parameters of the soft coal and hard coal in the different coal seams. It can be seen in Figure 4 and Table 1 that the BET specific surface areas of the soft coal and hard coal in the No. 6 coal seam were 3.5421 m2/g and 1.8008 m2/g, respectively. That is to say, the BET specific surface area of soft coal in the No. 6 coal seam was approximately twice that of the hard coal, which indicated that the gas adsorption conditions of the soft coal in the No. 6 coal seam were superior to those of the hard coal. In addition, it was determined that the BET specific surface areas of the soft coal and hard coal in the No. 11 coal seam were 1.6179 m2/g and 0.8278 m2/g, respectively. Therefore, the BET specific surface area of the soft coal in the No. 11 coal seam was confirmed to be approximately twice that of the hard coal, indicating that the gas adsorption conditions of the soft coal in the No. 11 coal seam were also better than those of the hard coal. As detailed in Figure 3, the BJH specific surface areas of the soft coal and hard coal in the No. 6 coal seam were 2.9642 m2/g and 1.4593 m2/g, respectively. Therefore, the BJH specific surface areas of the soft coal were more than twice those of the hard coal, which indicated that the gas diffusion and migration conditions of the soft coal in the No. 6 coal seam were superior. The BJH specific surface areas of the soft coal and hard coal of the No. 11 coal were 1.4921 m2/g and 0.453 m2/g, respectively. Therefore, it was determined that the BJH specific surface areas of the soft coal were more than three times those of the hard coal, which indicated that the gas diffusion and migration conditions of the soft coal in the No. 11 coal seam were better than those of the hard coal within the same coal seam.Figure 4
Specific surface areas of the coal bodies in the different coal seams.Table 1
Pore structural parameters of the soft coal and hard coal in the different coal seams.
Pore structural parameters (m2/g)Soft coal and hard coal bodies of the different coal seamsNo. 6 softNo. 6 hardNo. 11 softNo. 11 hardBET specific surface areas3.54211.80081.61790.8278BJH specific surface areas2.96421.45931.49210.453In conclusion, the BET specific surface areas and BJH specific surface areas of soft coal were found to be significantly larger than those of the hard coal. As a result, it was concluded that the conditions for gas adsorption and diffusion migration of the soft coal were stronger than those of the hard coal.


### 3.2. Relationships between the Pore Sizes, Specific Surface Areas, and Pore Volumes

Figures5 and 6 show the relationships between the increments of the pore sizes and specific surface areas, as well as the relationships between the increments of pore sizes and pore volumes, of the soft coal and hard coal in the No. 6 coal seam, respectively. It can be seen in the aforementioned figures that the increments of the specific surface areas and pore volumes corresponding to the soft coal pore sizes above 100 nm were significantly larger than those of the hard coal. The maximum increment of the pore volumes corresponding to the pore sizes greater than 100 nm in the soft coal was 9 × 10−5 cm3/g. In addition, the maximum increment of the pore volume corresponding to the pore sizes above 100 nm in the hard coal was 3.5 × 10−5 cm3/g. Therefore, the increment of the soft coal was approximately 2.6 times that of the hard coal, as shown in the blue-dashed boxes in Figures 5(b) and 6(b).Figure 5
Diagram of the relationships between the increments of the pore sizes and the specific surface areas and the increments of the pore volumes of the soft coal of the No. 6 coal seam. (a) Relationships between the increments of the pore sizes and the specific surface areas. (b) Relationship between the increments of the pore sizes and the pore volumes; A is 10−1 nm.
(a)(b)Figure 6
Diagram of the relationships between the increments of the pore sizes and the specific surface areas and the increments of the pore volumes of the hard coal in the No. 6 coal seam. (a) Relationships between the increments of the pore sizes and the specific surface areas. (b) Relationships between the increments of the pore sizes and the pore volumes; A is 10−1 nm.
(a)(b)Figures7 and 8 show the relationships between the increments of the pore sizes and specific surface areas and the relationships between the increments of the pore sizes and pore volumes of the soft and hard coal in the No. 11 coal seam, respectively. It can be seen in the figure that the increments of the specific surface areas and pore volumes corresponding to the pore sizes greater than 100 nm in the soft coal were significantly larger than those of the hard coal, wherein the maximum increment of pore volume corresponding to the pore sizes greater than 100 nm in the soft coal was 12.5 × 10−5 cm3/g. The maximum increment of the pore volume corresponding to the pore sizes greater than 100 nm in the hard coal was determined to be 6.2 × 10−5 cm3/g. Therefore, the increment of the soft coal was approximately 2 times that of the hard coal, as indicated in the blue-dashed boxes in Figures 7(b) and 8(b).Figure 7
Diagram of the relationships between the increments of the pore sizes and the specific surface areas and the increments of pore volumes of the hard coal of the No. 11 coal seam. (a) Relationships between the increments of the pore sizes and the specific surface areas. (b) Relationships between the increments of the pore sizes and the pore volumes; (A) is 10−1 nm.
(a)(b)Figure 8
Diagram of the relationships between the increments of the pore sizes and the specific surface areas and the increments of the pore volumes of the hard coal of the No. 11 coal seam. (a) Relationships between the increments of the pore sizes and the specific surface areas. (b) Relationships between the increments of the pore sizes and the pore volumes; (A) is 10−1 nm.
(a)(b)Based on the above analysis of the increments of the pore diameter and specific surface areas and the increments of the pore volumes of the soft coal and hard coal in the two examined coal seams, it was concluded that the pore specific surface area increments and the pore volume increments of the soft coal with apertures larger than 100 nm were more than twice those of the hard coal. These findings indicated that the soft coal provided better conditions for gas diffusion and migration. In other words, the soft coal was determined to be more conducive to gas desorption and diffusion.


### 3.3. Comparative Analysis Results of the Microscanning of the Soft Coal and Hard Coal

In the present study, a FlexSEM 1000 scanning electron microscope was used to conduct microscopic scanning of the soft coal and hard coal, respectively. The results are shown in Figure9. It can be seen in the figure that the soft coal surfaces of the two coal seams were very rough and uneven, and the gas pores were relatively developed (as shown in Figures 9(a) and 9(c)). The pore edges were mainly zig-zagged in appearance, with significant differences observed in the pore sizes. In addition, pores ranging from several microns to dozens of microns were developed. The most direct impact of these relatively developed pores in the high gas coal seam was the corresponding increases in the gas adsorption capacity. There were many crush marks and stepped fracture scale structures were also observed. These structures had greatly increased the surface areas of the coal bodies, which had contacts outside the coal seams. At the same time, the crush marks formed under the action of the structural compressive stress had led to the obvious development of microcracks, as well as good connectivity between the pores. This had resulted in the formations of dominant channels for gas flow. In contrast, the surfaces of the hard coal were found to be more complete, with the characteristics of thin-layer shear fractures, thin sections, and crumpled deformations. In addition, local roughness and unevenness, scattered minerals, and coal chips on the surfaces were observed, with few pores in local areas and no obvious cracks. Therefore, based on the above analysis results, it was concluded that the development of pores and fractures in the soft coal had provided “good” conditions for gas adsorption and desorption, respectively. Therefore, more attention should be paid to the gas emissions of soft coal during coal mining processes.Figure 9
Microscanning results of the soft coal and hard coal. (a) No. 6 soft coal. (b) No. 6 hard coal. (c) No. 11 soft coal. (d) No. 11 hard coal.
(a)(b)(c)(d)


### 3.4. Differences in the Gas Desorption and Diffusion Laws of the Soft Coal and Hard Coal

Figure10 shows the gas desorption speeds of the soft coal and hard coal and the change laws of the gas desorption amounts with time. It can be seen in Figure 10(a) that the gas desorption speeds of the soft coal and hard coal continuously decreased with the increases of time. During the initial stage of the desorption, the gas desorption speeds had decreased violently. Then, with the increases in duration, the gas desorption speeds slowly decreased. It can be seen from the curve in the red-dotted line box of Figure 10(a) and the data in Table 2 that the initial gas desorption speed of the soft coal was significantly higher than that of the hard coal. Due to the fact that the initial gas desorption speed represents the initial instantaneous gas emission in a coal body, the instantaneous gas emission of the soft coal was found to be significantly higher than that of the hard coal. Therefore, it was considered to be more likely to cause gas outbursts and transfinite accidents in the project site. It was ascertained from the data shown in Figure 10(b) and Table 2 that the gas desorption capacities of the soft coal and hard coal in each coal seam had gradually increased with time. However, the increasing trend had gradually slowed down. It was observed that the gas desorption capacity of the soft coal was also significantly higher than that of the hard coal, and the gas desorption speed and gas desorption capacity of the No. 6 coal seam were higher than those of the No. 11 coal seam.Figure 10
Gas desorption laws of the soft coal and hard coal. (a) Gas desorption speeds of the soft coal and hard coal. (b) Gas desorption capacities of the soft coal and hard coal.
(a)(b)Table 2
Gas desorption parameters of the soft coal and hard coal in the different coal seams.
Gas desorption parametersSoft coal and hard coal bodies of the different coal seamsNo. 6 softNo. 6 hardNo. 11 softNo. 11 hardInitial speed of the gas desorption (ml/min)1993.261775.021924.531695.36Gas desorption (ml)643.45539.74630.98532.02


## 3.1. Comparative Analysis of the Specific Surface Areas of the Soft Coal and Hard Coal

Figure4 shows this study’s comparative analysis diagram of the BET specific surface areas and BJH specific surface areas of the soft coal and hard coal in the different coal seams. Table 1 shows this study’s pore structural parameters of the soft coal and hard coal in the different coal seams. It can be seen in Figure 4 and Table 1 that the BET specific surface areas of the soft coal and hard coal in the No. 6 coal seam were 3.5421 m2/g and 1.8008 m2/g, respectively. That is to say, the BET specific surface area of soft coal in the No. 6 coal seam was approximately twice that of the hard coal, which indicated that the gas adsorption conditions of the soft coal in the No. 6 coal seam were superior to those of the hard coal. In addition, it was determined that the BET specific surface areas of the soft coal and hard coal in the No. 11 coal seam were 1.6179 m2/g and 0.8278 m2/g, respectively. Therefore, the BET specific surface area of the soft coal in the No. 11 coal seam was confirmed to be approximately twice that of the hard coal, indicating that the gas adsorption conditions of the soft coal in the No. 11 coal seam were also better than those of the hard coal. As detailed in Figure 3, the BJH specific surface areas of the soft coal and hard coal in the No. 6 coal seam were 2.9642 m2/g and 1.4593 m2/g, respectively. Therefore, the BJH specific surface areas of the soft coal were more than twice those of the hard coal, which indicated that the gas diffusion and migration conditions of the soft coal in the No. 6 coal seam were superior. The BJH specific surface areas of the soft coal and hard coal of the No. 11 coal were 1.4921 m2/g and 0.453 m2/g, respectively. Therefore, it was determined that the BJH specific surface areas of the soft coal were more than three times those of the hard coal, which indicated that the gas diffusion and migration conditions of the soft coal in the No. 11 coal seam were better than those of the hard coal within the same coal seam.Figure 4
Specific surface areas of the coal bodies in the different coal seams.Table 1
Pore structural parameters of the soft coal and hard coal in the different coal seams.
Pore structural parameters (m2/g)Soft coal and hard coal bodies of the different coal seamsNo. 6 softNo. 6 hardNo. 11 softNo. 11 hardBET specific surface areas3.54211.80081.61790.8278BJH specific surface areas2.96421.45931.49210.453In conclusion, the BET specific surface areas and BJH specific surface areas of soft coal were found to be significantly larger than those of the hard coal. As a result, it was concluded that the conditions for gas adsorption and diffusion migration of the soft coal were stronger than those of the hard coal.


## 3.2. Relationships between the Pore Sizes, Specific Surface Areas, and Pore Volumes

Figures5 and 6 show the relationships between the increments of the pore sizes and specific surface areas, as well as the relationships between the increments of pore sizes and pore volumes, of the soft coal and hard coal in the No. 6 coal seam, respectively. It can be seen in the aforementioned figures that the increments of the specific surface areas and pore volumes corresponding to the soft coal pore sizes above 100 nm were significantly larger than those of the hard coal. The maximum increment of the pore volumes corresponding to the pore sizes greater than 100 nm in the soft coal was 9 × 10−5 cm3/g. In addition, the maximum increment of the pore volume corresponding to the pore sizes above 100 nm in the hard coal was 3.5 × 10−5 cm3/g. Therefore, the increment of the soft coal was approximately 2.6 times that of the hard coal, as shown in the blue-dashed boxes in Figures 5(b) and 6(b).Figure 5
Diagram of the relationships between the increments of the pore sizes and the specific surface areas and the increments of the pore volumes of the soft coal of the No. 6 coal seam. (a) Relationships between the increments of the pore sizes and the specific surface areas. (b) Relationship between the increments of the pore sizes and the pore volumes; A is 10−1 nm.
(a)(b)Figure 6
Diagram of the relationships between the increments of the pore sizes and the specific surface areas and the increments of the pore volumes of the hard coal in the No. 6 coal seam. (a) Relationships between the increments of the pore sizes and the specific surface areas. (b) Relationships between the increments of the pore sizes and the pore volumes; A is 10−1 nm.
(a)(b)Figures7 and 8 show the relationships between the increments of the pore sizes and specific surface areas and the relationships between the increments of the pore sizes and pore volumes of the soft and hard coal in the No. 11 coal seam, respectively. It can be seen in the figure that the increments of the specific surface areas and pore volumes corresponding to the pore sizes greater than 100 nm in the soft coal were significantly larger than those of the hard coal, wherein the maximum increment of pore volume corresponding to the pore sizes greater than 100 nm in the soft coal was 12.5 × 10−5 cm3/g. The maximum increment of the pore volume corresponding to the pore sizes greater than 100 nm in the hard coal was determined to be 6.2 × 10−5 cm3/g. Therefore, the increment of the soft coal was approximately 2 times that of the hard coal, as indicated in the blue-dashed boxes in Figures 7(b) and 8(b).Figure 7
Diagram of the relationships between the increments of the pore sizes and the specific surface areas and the increments of pore volumes of the hard coal of the No. 11 coal seam. (a) Relationships between the increments of the pore sizes and the specific surface areas. (b) Relationships between the increments of the pore sizes and the pore volumes; (A) is 10−1 nm.
(a)(b)Figure 8
Diagram of the relationships between the increments of the pore sizes and the specific surface areas and the increments of the pore volumes of the hard coal of the No. 11 coal seam. (a) Relationships between the increments of the pore sizes and the specific surface areas. (b) Relationships between the increments of the pore sizes and the pore volumes; (A) is 10−1 nm.
(a)(b)Based on the above analysis of the increments of the pore diameter and specific surface areas and the increments of the pore volumes of the soft coal and hard coal in the two examined coal seams, it was concluded that the pore specific surface area increments and the pore volume increments of the soft coal with apertures larger than 100 nm were more than twice those of the hard coal. These findings indicated that the soft coal provided better conditions for gas diffusion and migration. In other words, the soft coal was determined to be more conducive to gas desorption and diffusion.


## 3.3. Comparative Analysis Results of the Microscanning of the Soft Coal and Hard Coal

In the present study, a FlexSEM 1000 scanning electron microscope was used to conduct microscopic scanning of the soft coal and hard coal, respectively. The results are shown in Figure9. It can be seen in the figure that the soft coal surfaces of the two coal seams were very rough and uneven, and the gas pores were relatively developed (as shown in Figures 9(a) and 9(c)). The pore edges were mainly zig-zagged in appearance, with significant differences observed in the pore sizes. In addition, pores ranging from several microns to dozens of microns were developed. The most direct impact of these relatively developed pores in the high gas coal seam was the corresponding increases in the gas adsorption capacity. There were many crush marks and stepped fracture scale structures were also observed. These structures had greatly increased the surface areas of the coal bodies, which had contacts outside the coal seams. At the same time, the crush marks formed under the action of the structural compressive stress had led to the obvious development of microcracks, as well as good connectivity between the pores. This had resulted in the formations of dominant channels for gas flow. In contrast, the surfaces of the hard coal were found to be more complete, with the characteristics of thin-layer shear fractures, thin sections, and crumpled deformations. In addition, local roughness and unevenness, scattered minerals, and coal chips on the surfaces were observed, with few pores in local areas and no obvious cracks. Therefore, based on the above analysis results, it was concluded that the development of pores and fractures in the soft coal had provided “good” conditions for gas adsorption and desorption, respectively. Therefore, more attention should be paid to the gas emissions of soft coal during coal mining processes.Figure 9
Microscanning results of the soft coal and hard coal. (a) No. 6 soft coal. (b) No. 6 hard coal. (c) No. 11 soft coal. (d) No. 11 hard coal.
(a)(b)(c)(d)


## 3.4. Differences in the Gas Desorption and Diffusion Laws of the Soft Coal and Hard Coal

Figure10 shows the gas desorption speeds of the soft coal and hard coal and the change laws of the gas desorption amounts with time. It can be seen in Figure 10(a) that the gas desorption speeds of the soft coal and hard coal continuously decreased with the increases of time. During the initial stage of the desorption, the gas desorption speeds had decreased violently. Then, with the increases in duration, the gas desorption speeds slowly decreased. It can be seen from the curve in the red-dotted line box of Figure 10(a) and the data in Table 2 that the initial gas desorption speed of the soft coal was significantly higher than that of the hard coal. Due to the fact that the initial gas desorption speed represents the initial instantaneous gas emission in a coal body, the instantaneous gas emission of the soft coal was found to be significantly higher than that of the hard coal. Therefore, it was considered to be more likely to cause gas outbursts and transfinite accidents in the project site. It was ascertained from the data shown in Figure 10(b) and Table 2 that the gas desorption capacities of the soft coal and hard coal in each coal seam had gradually increased with time. However, the increasing trend had gradually slowed down. It was observed that the gas desorption capacity of the soft coal was also significantly higher than that of the hard coal, and the gas desorption speed and gas desorption capacity of the No. 6 coal seam were higher than those of the No. 11 coal seam.Figure 10
Gas desorption laws of the soft coal and hard coal. (a) Gas desorption speeds of the soft coal and hard coal. (b) Gas desorption capacities of the soft coal and hard coal.
(a)(b)Table 2
Gas desorption parameters of the soft coal and hard coal in the different coal seams.
Gas desorption parametersSoft coal and hard coal bodies of the different coal seamsNo. 6 softNo. 6 hardNo. 11 softNo. 11 hardInitial speed of the gas desorption (ml/min)1993.261775.021924.531695.36Gas desorption (ml)643.45539.74630.98532.02


## 4. Differential Mechanism Analysis of the Gas Diffusion and Migration Processes in the Soft Coal and Hard Coal

In accordance with the pore classification method, micropores and pores provide the majority of the specific surface areas in pore structures and are the main sites for gas adsorption and storage. The BET specific surface areas of the soft coal and hard coal were found to be quite different, which indicated that the gas adsorption capacities of the soft coal and hard coal were also different. The increments of the specific surface areas and pore volumes of the mesopores and large pores of the soft coal were found to be much larger than those of the hard coal. In addition, since the mesopores and large pores were the main paths and channels for gas desorption in the micropores and small pores, the increases of the specific surface areas and pore volumes of the mesopores and large pores provided more spacious and advantageous channels for gas diffusion in the micropores and small pores. That is to say, the smaller the damage degree of the coal dust was (e.g., the greater the firmness coefficient), the longer the paths of the gas diffusion in the micropores and small pores would be and in turn the greater the resistance would be. Therefore, the increases in the damage degrees were equivalent to widening the channels for gas desorption in the micropores and small pores, which subsequently shortened the paths of gas diffusion and reduced the resistance of gas diffusion. This resulted in increases in the initial velocity of the gas released in the micropores and small pores. The mesopores of the soft coal were observed to be much larger than those of the hard coal. It was found that when the gas stored in the mesopores was desorbed, it did not need to directly diffuse to the large pores or coal surfaces through the micropores or small pores. This had resulted in the initial velocity of the mesopore gas diffusion of the soft coal to be much faster than that of the hard coal. It was concluded in this study that this was the basic reason why the gas diffusion coefficient of the soft coal was larger than that of the hard coal. Therefore, the differences in the gas diffusion paths stored in different pores and locations could be considered as the reason why the gas diffusion coefficient of the coal particles had changed with time.


## 5. Engineering Case

According to the above research results, the combined mode of hydraulic perforation-hydraulic fracturing-gas drainage was adopted in the tunneling process of Xieqiao coal mine to preextract the gas in the coal body during the tunneling process, as shown in Figure11. Before mining the coal seam in the working face, the bottom plate was used to dig the gas predrainage roadway to extract part of the gas in the coal seam. Before mining in the working face, the gas in the coal seam was extracted by drilling along the seam, as shown in Figure 12.Figure 11
Schematic diagram of hydraulic perforation-hydraulic fracturing-gas drainage.Figure 12
Gas drainage diagram of coal seam in working face.Due to the fact that the soft coal body has the problems of soft crushing and being easy to slice, we designed and adopted a new type of rigid flexible composite active support system of “rigid support + flexible metal net,” which solved the problem of easy slicing of soft coal body in the coal seam and effectively prevented the sudden gas emission caused by the slice of coal wall, as shown in Figure13. The effect is very good.Figure 13
“Rigid support + flexible metal mesh” new rigid flexible composite active support system.


## 6. Conclusions

In the current research study, the differences in the characteristics of gas diffusion between soft coal and hard coal were examined from macroaspects, mesoaspects, and microaspects. The basic mechanism of the gas diffusion differences between the soft coal and hard coal was revealed and verified by the results of this study’s gas desorption experiments. Through the above analysis and research results for soft coal and hard coal, there are important guiding significance and promotion value for gas regional control in the field construction process of working face. The following conclusions were obtained:(1)
In view of the special situation of gas emission in coal mines, this paper makes an in-depth study on the nature of abnormal gas emission law of soft coal and hard coal from macroaspects, mesoaspects, and microaspects. The mechanism of gas emission difference between soft coal and hard coal is revealed, which provides basis for the prevention and control of coal seam gas disaster under similar conditions, and has important significance.(2)
In the macroaspects and mesostructures of the soft coal, the particles were observed to be flakey with fingernail-like shapes, and there were generally no complete blocks. However, the hard coal was mainly composed of complete block structures. In addition, the proportion of coal particles sized below the particle size limit (6 mm) of the soft coal was much higher than that of the hard coal.(3)
The pores and fissures of the soft coal were found to be more developed than those of the hard coal. The BET and BJH specific surface areas of the soft coal were found to be more than twice those of the hard coal. Furthermore, the pore specific surface area increments and pore volume increments of the soft coal particles greater than 100 nm were found to be more than twice those of the hard coal. Therefore, the gas adsorption and diffusion migration conditions of the soft coal were superior to those of the hard coal.(4)
The experimental results of the soft coal and hard coal gas desorption showed that the gas desorption speeds, gas desorption capacities, initial gas desorption speeds, and other parameters were significantly higher for the soft coal than for the hard coal. Therefore, it was concluded that the soft coal was more likely to cause gas outbursts and transfinite accidents in a project site.(5)
A combined method of hydraulic perforation-hydraulic fracturing-gas extraction was put forward to extract the gas in the process of roadway excavation. The gas in the working face is extracted by drilling along the layer. According to the problems of soft coal, such as being soft and broken and being easy to slice, we designed a new type of rigid flexible composite active support system of “rigid support + flexible metal net,” which solved the problem easy slicing of soft coal in the coal seam and effectively prevented the coal wall slice from causing the gas to gush out suddenly. The effect is very good.



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*Source: 8825625-2020-07-28.xml*