# Investigation of Light Absorption in a ZnS Quantum Dot

Authors: Hojjatollah K. Salehani; Maedeh Zakeri
Journal: Journal of Spectroscopy
 (2013)

---

## Abstract

The light absorption of a ZnS quantum dot with a parabolic confinement potential is studied in this paper in the presence of magnetic field perpendicular to dot plane. The Schrodinger equation of a single electron is solved numerically, and energy spectra and wave functions are obtained. Then, the optical absorption coefficients in transition from ground state to different excited states are calculated. The effects the magnetic field and quantum dot width on the optical absorption are investigated. It is found that the optical absorption coefficient has a blue shift by increasing of magnetic field or confinement strength of quantum dot.


---

## Body

## 1. Introduction

During the last ten years, with great progress in nanofabrication techniques, it is possible to grow semiconductor quantum dots (QDs) with various shapes and sizes [1]. QDs are semiconductor nanocrystals that can be considered as artificial atoms because they have discrete energy levels and shell structure [2]. The main advantage of QD relative to real atom is that the physical properties of QDs can be controlled by tuning their size and shapes. The QDs have various applications; in particular in the mid- and far-infrared regions, they can be used for pollution detection, thermal imaging object location, and remote sensing as well as infrared imaging of astronomical objects [3]. This nanostructure can be formed by modern growth methods such as molecular beam epitaxy [4] and the Stranski-Krastanov growth method [5, 6].Recently, the synthetic chrysotile nanotubes have been synthesized by Roveri et al. [7]. These geoinspired nanotubes can be prepared with specific properties, finalized to focused achievements such as preparation of new quantum wires. On the other hand, an experimental study is carried out on assembling ZnS QDs in synthetic chrysotile nanotubes [8]. These assembling QDs affect significantly the optical properties of the synthetic chrysotile nanotube. Due to potential application of these nanotubes as nonlinear optical and conducting technological devices, investigation of the electronic and optical properties of these systems is essential. In this paper, we investigate the light absorption in a ZnS QD. The effects of magnetic field and geometrical size of ZnS QD on the light absorption are investigated theoretically.Thus far, the optical properties of QDs are studied by some authors [9–13]. The first study of optical absorption in QD has been carried out theoretically by Efros and his colleague [9]. They have investigated the peculiarities of interband optical absorption in spherical QD. In [10], the authors have studied the light absorption in a cylindrical QD. In the presence of the electric and magnetic fields, the interband light absorption of parabolic QD has been investigated theoretically [11]. The electron states and direct interband absorption of light in a strongly prolate ellipsoidal QD are studied at three regimes [12]. However, as far as we know, the effect of QD size on the light absorption of a ZnS parabolic QD is not investigated. The purpose of the present paper is to study the geometrical size and magnetic field effects on the optical properties of a ZnS QD. Therefore, we solve the Schrodinger equation of a single electron; and the energy spectra and absorption coefficients of parabolic QD are obtained. This paper is organized as follows. In Section 2, we present the theoretical model. In Section 3, the results of a numerical study are presented and discussed. Finally, Section 4 ends the paper with conclusion.


## 2. Theoretical Model

Consider a two-dimensional QD in ax-y plane. The confinement potential of the QD is considered to be parabolic; is shown schematically in Figure 1, and can be written as
(1)Vc(r)=12μω2r2,
where μ is the effective mass of electron, ω is the confinement potential strength, and r is the radial distance of origin.Figure 1
Schematic view of a parabolic confinement potential for a two-dimensional QD.In the presence of a magnetic field perpendicular on QD plane, the Hamiltonian of a single electron can be written as(2)H=ℏ22μ[-∂2∂r2-1r∂∂r-1r2∂2∂φ2-eBi∂ℏ∂φ+e2B2r24ℏ2]H=+Vc(r),
where i is a square root of −1 (i.e., i=-1), h=2πℏ is the Planck constant, -e is the charge of electron, B is the magnetic field, and r and φ are, respectively, the radial and angular coordinates of polar coordinates system. The electron wave function in a QD with circular symmetry can be written as
(3)ψnL(r,φ)=12πeiLφRn(r),L=0,±1,±2,…,
where n and L are radial and angular quantum numbers, respectively. Also, Rn(r) is nth radial wave function. Operating on the previous wavefunction (see (3)) with the Hamiltonian (see (2)) gives the following Schrodinger equation:
(4)ℏ22μ[-∂2∂r2-1r∂∂r-L2r2-eBLℏ+e2B2r24ℏ2]R(r)0000+Vc(r)R(r)=ER(r),
where E is energy of a single electron.


## 3. Results and Discussion

In this section, we present the results of a numerical study based on equations derived in the previous section. The Schrodinger equation (see (4)) is solved numerically using the finite difference method and exact diagonalization technique [14]. The energy spectra and eigenstates are obtained. In general, the optical absorption coefficient for a transition from initial state |n′,L′〉 to final state |n,L〉 is calculated as [15]
(5)α(ν)=∑nL〈n′,L′|e·r|n,L〉δ(EnL-En′L′-hν),
where n′ and L′ are the radial and angular quantum numbers of initial state and n and L are also the radial and angular quantum numbers of final state, respectively. The unit vector e indicates the direction of polarization of light. For in-plane polarization, the elements of transition matrix can be written as
(6)〈n′,L′|e·r|n,L〉=12π(ex+iey)δ|L-L′|1∫0∞drr2Rn′L′(r)RnL(r).
It is clear that the elements of transition matrix are not equal zero when δ|L-L′|1≠0 (i.e., L-L′=±1). For numerical calculation, the electron effective mass is taken to be m*=0.28mo (ZnS value) where mo is the free electron mass. The energy spectrum of a single electron is shown in Figure 2 as a function of magnetic field for different angular momentum quantum numbers. This is in agreement with the result of [16] which provides an analytical expression for energy eigenvalue. It is observed that for the two lowest energy levels there are not any angular momentum transition in this range of magnetic field. In the absence of magnetic field (i.e., B=0), energy levels with symmetric angular momentums are degenerate.Figure 2
The energy spectrum of a single electron as a function of magnetic field for different quantum numbers of angular momentum.In the absence of magnetic field, the optical absorption coefficients for transition from ground state (i.e.,|n′=1,L′=0〉) to the different excited states (i.e., |n=1,l=±1〉, |n=2,l=±1〉, |n=3,l=±1〉) are calculated in a QD with ℏω=6 meV and are shown in Figure 3 as a function of incident photon energy. It can be observed that the main peak corresponds to the transition from ground state (i.e., |n′=1,L′=0〉) to |n=1,L=±1〉 while for the other transitions the peak value decreases at least a thousand times. These results reveal that, in the experimental study of intraband spectra, the transition from ground state (i.e., |n′=1,L′=0〉) to |n=1,L=±1〉 states is remarkable and it is expected to be easily observed. The effect of magnetic field on the absorption coefficient is also calculated and shown in Figure 4. In this figure, the absorption coefficients are shown for transition from ground state (i.e., |n′=1,L′=0〉) to excited states |n=1,L=±1〉 for B=0, 2T and 4T as functions of incident photon energy. It can be observed that the magnetic field does not affect the peak value of the absorption coefficient, but increasing the magnetic field causes the QD to absorb photons with higher energies. To investigate the effect of QD size on the light absorption, we calculate the absorption coefficient for different confinement strengths. The confinement strength corresponds to the QD width via confinement potential (see (1)). In other words, according to the mentioned equation, increasing the confinement strength decreases the QD width and vice versa. Figure 5 shows the absorption coefficients for transition from ground state (i.e., |n′=1,L′=0〉) to |n=1,L=±1〉 states for different confinement strengths of the QD as a function of the incident photon energy. It can be observed that the peak value decreases when the QD width is decreased. In addition, it is observed that a wider QD absorbs the photons with lower energies.Figure 3
The optical absorption coefficients for transition from the ground state to the excited states as a function of incident photon energy forℏω=6 meV and B=0.Figure 4
The optical absorption coefficients for transition from ground state to the excited states as a function of the incident photon energy forℏω=6 meV and different magnetic fields.Figure 5
The optical absorption coefficients as a function of the incident photon energy forB=0 and different confinement strengths.


## 4. Conclusion

We have presented a theoretical study of light absorption in a two-dimensional ZnS QD. The absorption coefficients in transition from ground state to different excited states are calculated. The effects of magnetic field and QD width on the absorption coefficient are investigated. In the absence of magnetic field, it is found that the main peak corresponds to the transition from ground state to first excited state while for the other transitions the peak value is decreased at least a thousand times. Increasing of the applied magnetic field or the QD confinement strength causes the QD to absorb photons with higher energies.



---

*Source: 850352-2013-08-01.xml*