# Surface Plasmon Resonance in Periodic Hexagonal Lattice Arrays of Silver Nanodisks

Authors: Jinlian Hu; Cong Wang; Shikuan Yang; Fei Zhou; Zhigang Li; Caixia Kan
Journal: Journal of Nanomaterials
 (2013)

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## Abstract

The surface plasmon resonance (SPR) of periodic hexagonal lattice arrays of silver nano-disks positioned on glass slides is studied using finite-difference time domain (FDTD) simulations. We investigate numerically the influence of diameter of nano-disks and the gap between nano-disks on SPR transmission spectra and electric field enhancement. We find a strong dependence of resonance wavelength on diameter of the nanodisks. With increasing the gap, electric field enhancement factor could significantly increase and reach a maximum value, which indicates that a special long-range interaction plays an important role. This study is useful for optical modulation applied in near or far field optics, sensing and data storage, and solar cell.


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## Body

## 1. Introduction

Surface plasmon resonance (SPR) can be generated in metal nanostructures such as gold, silver, and copper, which are promising materials in the fields of optoelectronics and plasmonics [1–5]. The SPR in periodic arrays has aroused great interest because of its uniform optical properties which can be applied in integrated optoelectronics device [6–10]. Previously, a silver nanostructure in periodic square lattice for label free nano-biosensors was proposed in [6] and SPR in periodic square lattice of gold nanodisks for broadband light harvesting was investigated in [7]. Recently, Yang et al. [11] developed surface pattern fabrications via a dewetting process on the surface of a bowl template derived from a monolayer colloidal crystal template composed of polystyrene (PS) spheres in periodic hexagonal lattice arrays, and each bowl in the template can be treated as a separate reactor, resulting in uniformly structured surface patterns, and then the periodic hexagonal lattice arrays of metal nanodisks can be easily formed. However, the theoretical simulation about the SPR properties of periodic hexagonal lattice arrays of silver nanodisks has scarcely been reported.In this study, we show how by tuning the diameter and the gap to control the transmission andE-field enhancement properties of periodic hexagonal lattice arrays of silver nanodisks through the interactions of nanodisks. The long-range interaction of nano-particles is observed when E-field enhancement reaches a maximum value at the critical gap. The optical properties (transmission spectra and field enhancement) of silver nanodisk arrays are systematically studied numerically using Finite Difference Time Domain method.


## 2. Sample and Methods

Figure1 shows the schematic representation of periodic hexagonal lattice arrays of Ag nanodisks on SiO2 glass substrate. The height of nanodisk is held constant at 20 nm. The transmission spectra and E-field enhancement for the hexagonal array was calculated using a finite-difference time domain method (FDTD Solutions, from Lumerical). The calculations are set up as a three-dimensional system with a 2-nm resolution grid, for 500 fs. A plane wave source is chosen at a working wavelength range of 300–700 nm. The arrays are illuminated by a x-polarized plane wave source shining from the glass side towards the positive z-direction, which is perpendicular to the plane of the platform. Perfectly matched layers (PMLs) are used on the z-axis boundaries, while periodic boundaries conditions (PBCs) are placed on the x- and y-axis ones. The transmitted power is collected at positive z-direction at ends of the domain. The dielectric constant of the glass (silicon dioxide) and silver are described by the Palik values [12], which were provided in the material database from the software. The calculation of electric field enhancement factor, the relative total electric field intensity, and its image plot are obtained from |E|2/|E0|2, and they are calculated on the top surface of nanodisks.Figure 1
The schematic representation of periodic hexagonal lattice arrays of silver nanodisks positioned on glass slides.


## 3. Results and Discussion

For comparison, Figures2(a), 2(b), and 2(c) show relative field intensities |E|2/|E0|2 distribution on the top surface of nanodisks along xy plane at respective resonance wavelength for three different patterns (i.e., single nanodisk, seven nanodisks system, and periodic hexagonal arrays). The transmission spectra of the above three patterns are presented in Figure 2(d). In the Figure 2, the diameter and the gap are 100 nm and 70 nm, respectively. It can been seen that the periodic hexagonal array has a strong SPR transmission peak at 555 nm, which is slightly different from the peak of seven nanodisks system at 564 nm, and much more different from the one of the single nanodisk at 600 nm. As for the E-field enhancement factor at respective resonance wavelength, the maximum value |Emax|2/|E0|2 of periodic hexagonal array is about 180, which is also slightly different from the maximum value of seven nanodisks system of 350, and much more different from the single nanodisk of 700. These results indicate that the interaction between nanodisks cannot be ignored. In the following, we present the influence of nanodisks diameter and gap on SPR transmission spectra and E-field enhancement considering electromagnetic interaction.The relative field intensities (|E|2/|E0|2) distribution on the top surface of nanodisks along xy plane at respective resonance wavelength for three different patterns: (a) single nanodisk, (b) seven nanodisks system, and (c) periodic hexagonal arrays. (d) The transmission spectra of the above three patterns. The diameter and the gap are 100 nm and 70 nm, respectively.
(a)
(b)
(c)
(d)


### 3.1. The Influence of Diameter of Nanodisks on Transmission Spectra andE-Field Enhancement

The SPR transmission spectra of the periodic structures have been calculated for diameter between 20 and 300 nm with fixed gap of 70 nm, as shown in Figure3(a). As we can see, the SPR peak significantly red shifts from 414 nm to 633 nm with great change about 221 nm when the particle diameter increases from 20 nm to 150 nm. The full width at half maximum (FWHM) and intensity of the SPR peak also greatly increase with increasing diameter.(a) The transmission spectra of periodic arrays with different diametersD between 20 nm and 150 nm. (b) E-field enhancement factor of periodic arrays with different diameters illuminated at three laser light wavelengths (488 nm, 532 nm, 632.8 nm). The gap between the nanodisks is fixed at 70 nm.
(a)
(b)In Mie theory, extinction is directly proportional with the density of the nanostructures [1]. Obviously, the increase in diameter keeping the gap constant is expected to increase a real density of Ag in the periodic hexagonal arrays, which leads to the increase in the amplitude of resonance intensity. With increasing the size of each particle, the electromagnetic wave incident on the particles should no longer be considered to have a negligible phase difference across the single particle dimension, and the dipole resonance peak starts to shift towards longer wavelengths and SPR peak gets wider due to phase retardation [1, 2]. Here, phase retardation plays a dominant role in leading to the significant change in peak position and FWHM When the diameter of each nanodisk changes. In addition to phase retardation, maybe the near field coupling between nanodisks gets stronger, which leads to broader peak when the diameter increase.Figure3(b) shows E-field enhancement factor of periodic arrays with fixed gap of 70 nm and different diameters illuminated at three laser wavelengths (488 nm, 532 nm, 632.8 nm). It can be seen that irradiation by the laser light with a wavelength of 532 nm or 632.8 has better E-field enhancement effect than by the laser light with a wavelength of 488 nm when the diameter increases up to 100 nm because the resonance wavelength red shifts with the increase in diameter.


### 3.2. The Influence of the Gap between Nanodisks on Transmission Spectra andE-Field Enhancement

The SPR transmission spectra of the periodic structures have been calculated for different gaps with fixed diameter of 100 nm, as shown in Figure4(a). With increasing gap, the intensity of the SPR extinction peak decreases as the density of silver nanodisks decreases and the SPR peak position has slight change. However, the FWHM of the peak gets much narrower with the increase in the gap, which could indicate the near-field coupling becomes weak. The strength of near-field coupling could be estimated from the FWHM of SPR peak.(a) The transmission spectra of periodic arrays with different gaps. (b)E-field enhancement factor on the top surface of nanodisks along xy plane for periodic hexagonal arrays with different gaps illuminated at three laser wavelengths (488 nm, 532 nm, 632.8 nm). (c) E-field enhancement factor at the top of nanodisks along xy plane for periodic hexagonal arrays with different gaps illuminated at their own resonance wavelengths. The diameter of the nanodisks is fixed at 100 nm.
(a)
(b)
(c)In principle, two types of interaction can be distinguished: near-field coupling and far-field (dipolar) interaction. Near-field coupling is relevant for nearly touching particles due to the short range of the electromagnetic near fields in the order of some tens of nm. On the other hand, far-field interaction is mediated by the nanostructures’ scattered light fields [13]. The near-field coupling of silver nano-particles pairs is efficient at few tens nanometers distance and gradually vanishes when the (D+gap)/D>2.5 and long range dipole-dipole interaction is stronger as the gap increases in the periodic pattern [14].Figure4(b) shows E-field enhancement factor on the top of nanodisks along xy plane for periodic hexagonal arrays with fixed diameter of 100 nm and different gaps illuminated at three laser wavelengths (488 nm, 532 nm, 632.8 nm), which suggests the irradiation by the laser light with a wavelength of 532 nm or 632.8 nm has better E-field enhancement effect than by laser light with a wavelength of 488 nm under such condition.Figure4(c) presents E-field enhancement factor on the top surface of nanodisks along xy plane for periodic hexagonal arrays with different gaps and fixed diameter of 100 nm illuminated at their own resonance wavelength. It is interesting that with increasing the gap the electric field enhancement factor significantly increases and reaches a maximum value of about 2650 at a particular gap of 300 nm. Previously, such strong enhancements were only obtained with nano-gap structures (via short-range dipole-dipole interaction) but not easily seen in patterns with large intra-particle distance. Here, the interesting result suggests that a special long-range interaction plays an important role, which is very complicated and needs detailed research in near future.


## 3.1. The Influence of Diameter of Nanodisks on Transmission Spectra andE-Field Enhancement

The SPR transmission spectra of the periodic structures have been calculated for diameter between 20 and 300 nm with fixed gap of 70 nm, as shown in Figure3(a). As we can see, the SPR peak significantly red shifts from 414 nm to 633 nm with great change about 221 nm when the particle diameter increases from 20 nm to 150 nm. The full width at half maximum (FWHM) and intensity of the SPR peak also greatly increase with increasing diameter.(a) The transmission spectra of periodic arrays with different diametersD between 20 nm and 150 nm. (b) E-field enhancement factor of periodic arrays with different diameters illuminated at three laser light wavelengths (488 nm, 532 nm, 632.8 nm). The gap between the nanodisks is fixed at 70 nm.
(a)
(b)In Mie theory, extinction is directly proportional with the density of the nanostructures [1]. Obviously, the increase in diameter keeping the gap constant is expected to increase a real density of Ag in the periodic hexagonal arrays, which leads to the increase in the amplitude of resonance intensity. With increasing the size of each particle, the electromagnetic wave incident on the particles should no longer be considered to have a negligible phase difference across the single particle dimension, and the dipole resonance peak starts to shift towards longer wavelengths and SPR peak gets wider due to phase retardation [1, 2]. Here, phase retardation plays a dominant role in leading to the significant change in peak position and FWHM When the diameter of each nanodisk changes. In addition to phase retardation, maybe the near field coupling between nanodisks gets stronger, which leads to broader peak when the diameter increase.Figure3(b) shows E-field enhancement factor of periodic arrays with fixed gap of 70 nm and different diameters illuminated at three laser wavelengths (488 nm, 532 nm, 632.8 nm). It can be seen that irradiation by the laser light with a wavelength of 532 nm or 632.8 has better E-field enhancement effect than by the laser light with a wavelength of 488 nm when the diameter increases up to 100 nm because the resonance wavelength red shifts with the increase in diameter.


## 3.2. The Influence of the Gap between Nanodisks on Transmission Spectra andE-Field Enhancement

The SPR transmission spectra of the periodic structures have been calculated for different gaps with fixed diameter of 100 nm, as shown in Figure4(a). With increasing gap, the intensity of the SPR extinction peak decreases as the density of silver nanodisks decreases and the SPR peak position has slight change. However, the FWHM of the peak gets much narrower with the increase in the gap, which could indicate the near-field coupling becomes weak. The strength of near-field coupling could be estimated from the FWHM of SPR peak.(a) The transmission spectra of periodic arrays with different gaps. (b)E-field enhancement factor on the top surface of nanodisks along xy plane for periodic hexagonal arrays with different gaps illuminated at three laser wavelengths (488 nm, 532 nm, 632.8 nm). (c) E-field enhancement factor at the top of nanodisks along xy plane for periodic hexagonal arrays with different gaps illuminated at their own resonance wavelengths. The diameter of the nanodisks is fixed at 100 nm.
(a)
(b)
(c)In principle, two types of interaction can be distinguished: near-field coupling and far-field (dipolar) interaction. Near-field coupling is relevant for nearly touching particles due to the short range of the electromagnetic near fields in the order of some tens of nm. On the other hand, far-field interaction is mediated by the nanostructures’ scattered light fields [13]. The near-field coupling of silver nano-particles pairs is efficient at few tens nanometers distance and gradually vanishes when the (D+gap)/D>2.5 and long range dipole-dipole interaction is stronger as the gap increases in the periodic pattern [14].Figure4(b) shows E-field enhancement factor on the top of nanodisks along xy plane for periodic hexagonal arrays with fixed diameter of 100 nm and different gaps illuminated at three laser wavelengths (488 nm, 532 nm, 632.8 nm), which suggests the irradiation by the laser light with a wavelength of 532 nm or 632.8 nm has better E-field enhancement effect than by laser light with a wavelength of 488 nm under such condition.Figure4(c) presents E-field enhancement factor on the top surface of nanodisks along xy plane for periodic hexagonal arrays with different gaps and fixed diameter of 100 nm illuminated at their own resonance wavelength. It is interesting that with increasing the gap the electric field enhancement factor significantly increases and reaches a maximum value of about 2650 at a particular gap of 300 nm. Previously, such strong enhancements were only obtained with nano-gap structures (via short-range dipole-dipole interaction) but not easily seen in patterns with large intra-particle distance. Here, the interesting result suggests that a special long-range interaction plays an important role, which is very complicated and needs detailed research in near future.


## 4. Conclusion

In this study, we have presented the influence of diameter and the gap between nanodisks on SPR spectra and electric field enhancement factor for periodic hexagonal lattice arrays of silver nanodisks. An increase of extinction spectra, significant peak red-shift, and a broader plasmon resonance occur with increasing the diameter due to phase retardation of single large nanodisk and the near field coupling between nanodisks. FDTD calculations also show that with increasing the gap, electric field enhancement factor could significantly increase and reach a maximum value due to special long-range interaction. This study is useful for optical modulation applied in sensing and data storage, and solar cell, and is also important to the understanding plasmon about near field coupling and long range interaction between nanoparticles.



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*Source: 838191-2013-03-10.xml*