# Rare Earth Doped Lanthanum Calcium Borate Polycrystalline Red Phosphors

Authors: H. H. Xiong; C. Zhu; X. Zhao; Z. Q. Wang; H. Lin
Journal: Advances in Materials Science and Engineering
 (2014)

---

## Abstract

Single-phased Sm3+ doped lanthanum calcium borate (SmxLa2−xCaB10O19, SLCB, x
=
0.06) polycrystalline red phosphor was prepared by solid-state reaction method. The phosphor has two main excitation peaks located at 398.5 nm and 469.0 nm, which are nicely in accordance with the emitting wavelengths of commercial near-UV and blue light emitting diode chips. Under the excitation of 398.0 nm, the dominant red emission of Sm3+ in SLCB phosphor is centered at 598.0 nm corresponding to the transition of 4G5/2 → 6H7/2. The Eu3+ fluorescence in the red spectral region is applied as a spectroscopic probe to reveal the local site symmetry in the host lattice and, hence, Judd-Ofelt parameters Ω
t
(
t
=
2
,
4
) of Eu3+ in the phosphor matrix are derived to be 3.62
×
10
-20 and 1.97
×
10
-20 cm2, indicating a high asymmetrical and strong covalent environment around rare earth luminescence centers. Herein, the red phosphors are promising good candidates employed in white light emitting diodes (LEDs) illumination.


---

## Body

## 1. Introduction

White light emitting diodes (LEDs) are considered as the next generation solid-state lighting systems because of their excellent properties such as high efficiency, low power consumption, long lifetime, and lower toxicity [1–6]. The LED based solid-state lighting techniques have gained great achievements since the white LEDs became commercially available by Nichia Chemical Co. in 1997 [7–9]. There are three ways to produce white LEDs: (i) combining a blue LED with a yellow phosphor, for example, Y3Al5O12:Ce
3
+, (ii) mixing red, green, and blue emissions from three LEDs, and (iii) exciting red/green/blue tricolor phosphors with a near-UV LED (370–410 nm). The third is a flexible and convenient way to obtain high quality white LEDs due to the following advantages, generated white color by phosphors, that is, high tolerance to UV chips’ color variation and excellent color rendering index [10]. The main tricolor phosphors for near-UV InGaN-based LEDs are still under developing just as BaMgAl10O17:Eu
2
+ for blue, ZnS:Cu
+/Al
3
+ for green, and Y2O2S:Eu
3
+ for red [11–13]. Among them, the red phosphor has received much attention due to the fact that it can improve color rendering index; therefore it is meaningful to develop numerous red phosphors with higher efficiency to improve the performance of white LEDs [13–17].During the past decades, rare earth ions doped in various host materials have been widely studied due to their characteristic luminescence properties. Among the rare earth ions,Sm
3
+, Eu
3
+, Tb
3
+, and Dy
3
+ are important activator ions for producing visible light [18–25]. Sm
3
+ activated luminescent materials have received much attention at present [26, 27]. They show bright emissions in orange and red regions attributed to the transitions from the excited state 4G5/2 to the ground state 6H5/2 and the other state H
6
J (J
=
7
/
2
,
9
/
2, and 11/2), which can be used in high density optical storage, temperature sensors, under sea communication, various fluorescent devices, color display, and visible solid-state lasers [2, 28–30]. Luminescence of Eu
3
+ is especially useful to probe the local structure of luminescent centers in a host lattice because of its simple energy level structure, great sensitivity to ligand field, and similar lanthanide chemical properties to the other rare earth ions [31–33].Growing interest recently has been focused on luminescence of trivalent rare earth ions in phosphates, tungstates, borates, molybdates, and aluminates, among which rare earth doped borates are especially attractive because of their wide UV transparency, exceptional optical damage thresholds, excellent chemical and thermal stability, and high luminescence efficiency [34–42]. Hence, a borate phosphor which efficiently emits red fluorescence under the UV and blue light excitation is of great significance to be synthesized for practical applications. The compound La2CaB10O19 (LCB) is chemically stable and nonhygroscopic, which belongs to the monoclinic system with the space group of C2 and the lattice parameters a
=
1.1043 nm, b
=
0.6563 nm, c
=
0.9129 nm, α
=
γ
=
90°, and β
=
91.47° [43, 44]. The effect of Sm
3
+ doping in LCB host is seductive to be developed as a red phosphor for solid-state LED lighting.Herein,Sm
3
+ activated lanthanum calcium borate phosphor (SmxLa2−xCaB10O19, SLCB) was prepared by the solid-state reaction technique, and an attempt was made to investigate its luminescence characteristics. Eu
3
+ was adopted as a probe in ELCB (EuxLa2−xCaB10O19, ELCB) phosphor through the calculation of J
-
O parameters to reflect the local microenvironment around the rare earth ions in the compounds. The bright red fluorescence obtained from SLCB phosphor suggests that the as-prepared phosphor is a promising red luminescent material for white LEDs.


## 2. Experiments

SLCB phosphor was synthesized by a solid-state reaction route at high temperature using the following chemical reaction:(1)
x
S
m
2
O
3
+
(
2
-
x
)
L
a
2
O
3
+
2
CaC
O
3
+
20
H
3
B
O
3
⟶
2
S
m
x
L
a
2
-
x
Ca
B
10
O
19
+
2
C
O
2
↑
+
30
H
2
O
↑
.Here, thex value of SLCB sample is the molar replacement of La
3
+ by Sm
3
+, which is adopted to be 0.06 to maintain the brightness of phosphors and avoid the fluorescence quenching because of high concentration doping. Reagents La2O3 (99.99%), CaCO3 (99.99%), H3BO3 (99.9%), and Sm2O3 (99.99%) were used as raw materials. They were weighed according to the stoichiometric proportion, except for H3BO3 with an excess of 6.5 wt% to compensate for the volatilization of B2O3 at high temperature. After being ground and mixed thoroughly in an agate mortar, the mixture was placed into an electric furnace and preheated at 500°C for 10 h. Being cooled and ground again, the mixture was sintered at 930°C for 24 h twice with the intermediate grinding.The crystallographic structure of SLCB powders was characterized by X-ray powder diffraction analysis using a D/Max-3B X-ray diffractometer with 40 kV, 20 mA. The excitation and emission spectra were recorded on a Jobin Yvon FluoroLog-3 spectrophotometer with a R928 photomultiplier tube (PMT) detector, and a commercial CW Xe-lamp was used as pump source. A JSM-6460LV scanning electron microscopy was used for the observation of particle morphology. The photographs of the samples were taken by a Sonyα
200 digital camera. ELCB phosphor was prepared by the same way except that Eu2O3 was used instead of Sm2O3 and the measurements were carried out at the same condition as SLCB phosphor.


## 3. Results and Discussion

### 3.1. X-Ray Diffraction Analysis

To check the phase purity and the structure of the sample, the powder X-ray diffraction (XRD) measurement for the sample was carried out. Figure1 presents a comparison between the experimental result for SLCB phosphor and JCPDS card 54-0033 (La2CaB10O19). The observed peaks are in good agreement with the JCPDS data indicating that the main phase of the prepared phosphor is LCB. Because of lanthanide contraction, rare earth ions have similar radius, coordination environment, and physical-chemical properties. When La
3
+ in the lattice is replaced by Sm
3
+, the crystal structure does not change dramatically. The doped product crystallizes as monoclinic structure with a space group of C2 and lattice parameters values a
=
1.1028 nm, b
=
0.6556 nm, c
=
0.9114 nm, and β
=
91.431°, which is almost consistent with pure LCB phase [44, 45]. These results show that the Sm
3
+ has been incorporated into LCB lattices successfully and the small amount of Sm
3
+ ions has negligible effect on the basic crystal structure of LCB. The same result was verified in ELCB phosphor.Figure 1
X-ray diffraction patterns of SLCB phosphor and the referenced LCB (JCPDS number 54-0033).


### 3.2. Photoluminescence Characteristics of SLCB Phosphor

The excitation spectrum of SLCB phosphor monitored at 598.0 nm consists of several bands peaking at 245.0, 340.0, 358.0, 370.0, 398.5, 412.5, and 469.0 nm as depicted in Figure2. The broadband around 245.0 nm is due to the charge transfer (CT) band of Sm
3
+–O2− [45, 46]. The other excitation peaks at 340.0, 358.0, 370.0, 398.5, 412.5, and 469.0 nm have been assigned to the 4f-4f inner shell transitions of Sm
3
+ [47–49]. The efficient excited wavelength range of Sm
3
+ in SLCB phosphor covers the whole long-wavelength UV, purple, blue, and bluish-green spectral regions. This suggests that the effective excitation range matches the output wavelengths of InGaN-based LED chips well; thus the phosphors have potential application in the solid-state LED lighting.Figure 2
Excitation spectrum of SLCB phosphor (λ
em
=
598.0 nm).Figure3 is the emission spectrum of SLCB phosphor excited by 398.0 nm. The characteristic emissions of SLCB phosphor consist of five emission bands, which are attributed to the transitions from 4G5/2 state to H
6
J (J
=
5
/
2
,
7
/
2
,
9
/
2
,
11
/
2, and 13/2) states of Sm
3
+. Among these, the strongest emission peak located at 598.0 nm originates from the typical transition 4G5/2→6H7/2 and the other peaks at 562.0, 646.5, 706.0, and 735.0 nm are attributed to the transitions of 4G5/2→6H5/2, 4G5/2→6H9/2, 4G5/2→6H11/2, and 4G5/2→6H13/2, respectively [50–54]. Among these emission peaks, the transition emission 4G5/2→6H7/2 (598.0 nm, orangish red) with Δ
J
=
±
1 is a magnetic dipole (MD) allowed one, but it is also electric dipole (ED) dominated one and the other transition 4G5/2→6H9/2 (646.5 nm, red) is purely an ED one. The MD transition does not appreciably depend on the chemical surroundings of the luminescent center and its symmetry; however, the ED transition belongs to hypersensitive transitions. Generally, the intensity ratio of ED to MD transitions has been used to evaluate the symmetry of the local environment of the trivalent 4f ions. The greater the intensity of the ED transition, the more the asymmetry nature [55]. In this work, the emission due to 4G5/2→6H9/2 (ED) transition of Sm
3
+ is more intense than 4G5/2→6H5/2, specifying the asymmetric nature of host matrix. And the three main emission peaks of SLCB phosphor always split just similarly to the reports of LiBaBO3:Sm
3
+ [56], Gd2MoO6:Sm
3
+ [57], and GdVO4:Sm
3
+ [58]. Those splits result from the crystal field effects, and the spilt extents are related to the structure characteristic of the crystal field.Figure 3
Emission spectrum of SLCB phosphor (λ
ex
=
398.0 nm). Inset of (a): fluorescence from SLCB phosphor under 365.0 nm radiation. Inset of (b): SLCB phosphor under natural light.


### 3.3. Intensity Parameters of the Spectroscopic ProbeEu
3
+ in ELCB Phosphor

Figure4 presents the emission spectrum of ELCB phosphor excited at 391.0 nm in the wavelength of 560–720 nm. There are several typical emission bands around 560–720 nm assigned to the D
5
0→F
7
J  (
J
=
0
–
4
) transitions of Eu
3
+ [59–63], of which the red emission band at 617 nm is the most intense one due to the electric dipole transition 5D0→7F2.Figure 4
Emission spectrum of ELCB phosphor (λ
ex
=
391.0 nm). Inserted photo: fluorescence from ELCB phosphor under 365.0 nm excitation.Luminescence ofEu
3
+ is especially useful to probe the local symmetry and bonding characteristics of luminescent centers in a host lattice on account of its unsplit 7F0 ground state and relatively simple energy level scheme. The symmetry of the crystal site in which Eu
3
+ is located can be determined by the intensity ratio between 5D0→7F2 and 5D0→7F1 transition emissions in ELCB [64–67]. Here, the ratio is 1.9076 in ELCB phosphor from Figure 4, indicating that 5D0→7F2 electric dipole transition is dominated and Eu
3
+ is in an inversion asymmetrical site.Moreover, in order to further identify the asymmetry ofEu
3
+ in ELCB phosphor, the intensity parameters are calculated. Generally, J
-
O intensity parameters are derived from absorption spectra; however, in consideration of the special energy level structure of Eu
3
+, they should be calculated from the emission spectra because the recorded absorption peaks are not enough to get accurate results [68–70]. The transitions of Eu
3
+ from 5D0 to 7FJ  (J
=
2
,
4, and 6) are electronic dipole allowed ones and hypersensitive to the local environment around Eu
3
+. The spontaneous emission probability A
ed from |
ψ
J
〉 to |
ψ
′
J
′
〉 is given by the following expression:
(2)
A
ed
=
64
π
4
e
2
ν
3
3
h
(
2
J
+
1
)
n
(
n
2
+
2
)
2
9
×
∑
t
=
2,4
,
6
Ω
t
〈
ψ
J
∥
U
(
t
)
∥
ψ
′
J
′
〉
2
,
where e is the electron charge, v is the emission peak wavenumber, h is the Planck constant, n is the refractive index, 2
J
+
1 is the degeneracy of the excited state, and 〈
ψ
J
∥
U
(
t
)
∥
ψ
′
J
′
〉
2 is the square of the reduced matrix elements of the tensor operator, which connects the initial state |
ψ
J
〉 with the final state |
ψ
′
J
′
〉 and is considered to be independent of host matrix. The 5D0→7F1 transition of Eu
3
+ is magnetic-dipole allowed one and insensitive to the host matrix. The spontaneous emission probability of it (A
md) is given by
(3)
A
md
=
64
π
4
ν
3
3
h
(
2
J
+
1
)
n
3
S
md
,
where the magnetic dipole line strength S
md is constant and independent of the matrix, so the value of A
md can be estimated by the value of fluoride glass (A
md
′
=
60.3
s
-
1). The relationship is
(4)
A
md
=
(
n
n
′
)
3
A
md
′
,
where n  (
=
1.679
) and n
′  (
=
1.522
) are the refractive indices of ELCB crystal [71] and fluoride glass [72], respectively.Based on the calculatedA
rad, the selection rules, and the characteristic of transition intensities of Eu
3
+, each of the 〈
ψ
J
∥
U
(
t
)
∥
ψ
′
J
′
〉
2 parameters decides the intensities of transitions because the remaining two are zero. Thus, the Ω
t can be estimated from the intensity ratios of 5D0→7F2,4 transitions to 5D0→7F1 transition as
(5)
∫
I
(
v
)
d
v
∫
I
md
(
v
)
d
v
=
A
J
A
md
=
64
π
4
e
2
ν
3
3
h
(
2
J
+
1
)
n
(
n
2
+
2
)
2
9
A
md
Ω
t
〈
ψ
J
∥
U
(
t
)
∥
ψ
′
J
′
〉
2
.
The calculated Ω
t (t
=
2 and 4) values of Eu
3
+ in ELCB phosphor are 3.62 × 10−20 and 1.97 × 10−20 cm2, respectively. This result confirms a high inversion asymmetric and strong covalent environment of Eu
3
+ in the phosphor. The value of Ω
6 cannot be given since the 5D0
→
7F6 emission is unable to be experimentally detected in this work.Figure5 presents the SEM pictures of the as-prepared SLCB and ELCB phosphors. The two samples have similar morphology and particle size distribution. Also, they have good dispersion and relatively narrow size distribution with the average size of about 0.5~6 μm. However, the particles have no regular and uniform shape, and some of them are agglomerated. The main reasons are that the primary nanocrystals with high energy would assemble to minimize the surface energy and they would be sintered in the heat treatment process.SEM images of as-prepared SLCB (a) and ELCB (b).
(a)
(b)


## 3.1. X-Ray Diffraction Analysis

To check the phase purity and the structure of the sample, the powder X-ray diffraction (XRD) measurement for the sample was carried out. Figure1 presents a comparison between the experimental result for SLCB phosphor and JCPDS card 54-0033 (La2CaB10O19). The observed peaks are in good agreement with the JCPDS data indicating that the main phase of the prepared phosphor is LCB. Because of lanthanide contraction, rare earth ions have similar radius, coordination environment, and physical-chemical properties. When La
3
+ in the lattice is replaced by Sm
3
+, the crystal structure does not change dramatically. The doped product crystallizes as monoclinic structure with a space group of C2 and lattice parameters values a
=
1.1028 nm, b
=
0.6556 nm, c
=
0.9114 nm, and β
=
91.431°, which is almost consistent with pure LCB phase [44, 45]. These results show that the Sm
3
+ has been incorporated into LCB lattices successfully and the small amount of Sm
3
+ ions has negligible effect on the basic crystal structure of LCB. The same result was verified in ELCB phosphor.Figure 1
X-ray diffraction patterns of SLCB phosphor and the referenced LCB (JCPDS number 54-0033).


## 3.2. Photoluminescence Characteristics of SLCB Phosphor

The excitation spectrum of SLCB phosphor monitored at 598.0 nm consists of several bands peaking at 245.0, 340.0, 358.0, 370.0, 398.5, 412.5, and 469.0 nm as depicted in Figure2. The broadband around 245.0 nm is due to the charge transfer (CT) band of Sm
3
+–O2− [45, 46]. The other excitation peaks at 340.0, 358.0, 370.0, 398.5, 412.5, and 469.0 nm have been assigned to the 4f-4f inner shell transitions of Sm
3
+ [47–49]. The efficient excited wavelength range of Sm
3
+ in SLCB phosphor covers the whole long-wavelength UV, purple, blue, and bluish-green spectral regions. This suggests that the effective excitation range matches the output wavelengths of InGaN-based LED chips well; thus the phosphors have potential application in the solid-state LED lighting.Figure 2
Excitation spectrum of SLCB phosphor (λ
em
=
598.0 nm).Figure3 is the emission spectrum of SLCB phosphor excited by 398.0 nm. The characteristic emissions of SLCB phosphor consist of five emission bands, which are attributed to the transitions from 4G5/2 state to H
6
J (J
=
5
/
2
,
7
/
2
,
9
/
2
,
11
/
2, and 13/2) states of Sm
3
+. Among these, the strongest emission peak located at 598.0 nm originates from the typical transition 4G5/2→6H7/2 and the other peaks at 562.0, 646.5, 706.0, and 735.0 nm are attributed to the transitions of 4G5/2→6H5/2, 4G5/2→6H9/2, 4G5/2→6H11/2, and 4G5/2→6H13/2, respectively [50–54]. Among these emission peaks, the transition emission 4G5/2→6H7/2 (598.0 nm, orangish red) with Δ
J
=
±
1 is a magnetic dipole (MD) allowed one, but it is also electric dipole (ED) dominated one and the other transition 4G5/2→6H9/2 (646.5 nm, red) is purely an ED one. The MD transition does not appreciably depend on the chemical surroundings of the luminescent center and its symmetry; however, the ED transition belongs to hypersensitive transitions. Generally, the intensity ratio of ED to MD transitions has been used to evaluate the symmetry of the local environment of the trivalent 4f ions. The greater the intensity of the ED transition, the more the asymmetry nature [55]. In this work, the emission due to 4G5/2→6H9/2 (ED) transition of Sm
3
+ is more intense than 4G5/2→6H5/2, specifying the asymmetric nature of host matrix. And the three main emission peaks of SLCB phosphor always split just similarly to the reports of LiBaBO3:Sm
3
+ [56], Gd2MoO6:Sm
3
+ [57], and GdVO4:Sm
3
+ [58]. Those splits result from the crystal field effects, and the spilt extents are related to the structure characteristic of the crystal field.Figure 3
Emission spectrum of SLCB phosphor (λ
ex
=
398.0 nm). Inset of (a): fluorescence from SLCB phosphor under 365.0 nm radiation. Inset of (b): SLCB phosphor under natural light.


## 3.3. Intensity Parameters of the Spectroscopic ProbeEu
3
+ in ELCB Phosphor

Figure4 presents the emission spectrum of ELCB phosphor excited at 391.0 nm in the wavelength of 560–720 nm. There are several typical emission bands around 560–720 nm assigned to the D
5
0→F
7
J  (
J
=
0
–
4
) transitions of Eu
3
+ [59–63], of which the red emission band at 617 nm is the most intense one due to the electric dipole transition 5D0→7F2.Figure 4
Emission spectrum of ELCB phosphor (λ
ex
=
391.0 nm). Inserted photo: fluorescence from ELCB phosphor under 365.0 nm excitation.Luminescence ofEu
3
+ is especially useful to probe the local symmetry and bonding characteristics of luminescent centers in a host lattice on account of its unsplit 7F0 ground state and relatively simple energy level scheme. The symmetry of the crystal site in which Eu
3
+ is located can be determined by the intensity ratio between 5D0→7F2 and 5D0→7F1 transition emissions in ELCB [64–67]. Here, the ratio is 1.9076 in ELCB phosphor from Figure 4, indicating that 5D0→7F2 electric dipole transition is dominated and Eu
3
+ is in an inversion asymmetrical site.Moreover, in order to further identify the asymmetry ofEu
3
+ in ELCB phosphor, the intensity parameters are calculated. Generally, J
-
O intensity parameters are derived from absorption spectra; however, in consideration of the special energy level structure of Eu
3
+, they should be calculated from the emission spectra because the recorded absorption peaks are not enough to get accurate results [68–70]. The transitions of Eu
3
+ from 5D0 to 7FJ  (J
=
2
,
4, and 6) are electronic dipole allowed ones and hypersensitive to the local environment around Eu
3
+. The spontaneous emission probability A
ed from |
ψ
J
〉 to |
ψ
′
J
′
〉 is given by the following expression:
(2)
A
ed
=
64
π
4
e
2
ν
3
3
h
(
2
J
+
1
)
n
(
n
2
+
2
)
2
9
×
∑
t
=
2,4
,
6
Ω
t
〈
ψ
J
∥
U
(
t
)
∥
ψ
′
J
′
〉
2
,
where e is the electron charge, v is the emission peak wavenumber, h is the Planck constant, n is the refractive index, 2
J
+
1 is the degeneracy of the excited state, and 〈
ψ
J
∥
U
(
t
)
∥
ψ
′
J
′
〉
2 is the square of the reduced matrix elements of the tensor operator, which connects the initial state |
ψ
J
〉 with the final state |
ψ
′
J
′
〉 and is considered to be independent of host matrix. The 5D0→7F1 transition of Eu
3
+ is magnetic-dipole allowed one and insensitive to the host matrix. The spontaneous emission probability of it (A
md) is given by
(3)
A
md
=
64
π
4
ν
3
3
h
(
2
J
+
1
)
n
3
S
md
,
where the magnetic dipole line strength S
md is constant and independent of the matrix, so the value of A
md can be estimated by the value of fluoride glass (A
md
′
=
60.3
s
-
1). The relationship is
(4)
A
md
=
(
n
n
′
)
3
A
md
′
,
where n  (
=
1.679
) and n
′  (
=
1.522
) are the refractive indices of ELCB crystal [71] and fluoride glass [72], respectively.Based on the calculatedA
rad, the selection rules, and the characteristic of transition intensities of Eu
3
+, each of the 〈
ψ
J
∥
U
(
t
)
∥
ψ
′
J
′
〉
2 parameters decides the intensities of transitions because the remaining two are zero. Thus, the Ω
t can be estimated from the intensity ratios of 5D0→7F2,4 transitions to 5D0→7F1 transition as
(5)
∫
I
(
v
)
d
v
∫
I
md
(
v
)
d
v
=
A
J
A
md
=
64
π
4
e
2
ν
3
3
h
(
2
J
+
1
)
n
(
n
2
+
2
)
2
9
A
md
Ω
t
〈
ψ
J
∥
U
(
t
)
∥
ψ
′
J
′
〉
2
.
The calculated Ω
t (t
=
2 and 4) values of Eu
3
+ in ELCB phosphor are 3.62 × 10−20 and 1.97 × 10−20 cm2, respectively. This result confirms a high inversion asymmetric and strong covalent environment of Eu
3
+ in the phosphor. The value of Ω
6 cannot be given since the 5D0
→
7F6 emission is unable to be experimentally detected in this work.Figure5 presents the SEM pictures of the as-prepared SLCB and ELCB phosphors. The two samples have similar morphology and particle size distribution. Also, they have good dispersion and relatively narrow size distribution with the average size of about 0.5~6 μm. However, the particles have no regular and uniform shape, and some of them are agglomerated. The main reasons are that the primary nanocrystals with high energy would assemble to minimize the surface energy and they would be sintered in the heat treatment process.SEM images of as-prepared SLCB (a) and ELCB (b).
(a)
(b)


## 4. Conclusion

A red emitting phosphor SLCB (SmxLa2−xCaB10O19) was prepared by solid-state reaction method in the air. XRD analysis indicates that the crystal belongs to a monoclinic system with unit cell parameters a
=
1.1028 nm, b
=
0.6556 nm, c
=
0.9114 nm, and β
=
91.431°. The excitation spectrum shows that the phosphor can be efficiently excited by the commercial near-UV and blue light emitting diodes. Under the excitation of 398.0 nm, the phosphor presented red luminescence with efficient emissions at 562.0, 598.0, 646.5, 706.0, and 735.0 nm, corresponding to 4G5/2→6
H
J (J
=
5
/
2
,
7
/
2
,
9
/
2
,
11
/
2, and 13/2) transitions, respectively. Eu
3
+ is used as a spectroscopic probe for the microstructure of ELCB (EuxLa2−xCaB10O19) phosphor and, thus, Judd-Ofelt parameters Ω
t
(
t
=
2
,
4
) of Eu
3
+ in ELCB phosphor are derived to be 3.62 × 10−20 and 1.97 × 10−20 cm2, indicating a high asymmetrical and covalent environment around rare earth luminescence centers in the host lattice. The red fluorescence suggests that the two phosphors are potential candidates for light emitting diode applications.



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*Source: 819057-2014-08-05.xml*