# Keggin-Type Heteropolyacid for Ring-Opening Polymerization of Cyclohexene Oxide: Molecular Weight Control

Authors: Ahmed Aouissi; Zeid Abdullah Al-Othman; Abdurrahman Salhabi
Journal: International Journal of Polymer Science
 (2015)

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## Abstract

Polymerization of 1,2-cyclohexene oxide (CHO) in
dichloromethane was catalyzed by 12-tungstophosphoric
acid
(H3PW12O40·13H2O)
as a super solid acid. The effect of polymerization
parameters such as reaction time, temperature, and
catalyst amount was investigated. The effect of acetic
anhydride as a ring-opening agent was also
investigated. The resulting poly(1,2-cyclohexene oxide) (PCHO) was characterized by Fourier transform
infrared (FTIR), nuclear magnetic resonance
spectroscopy (1HNMR), gel-permeation
chromatography (GPC), and differential scanning
calorimetry (DSC). It has been found that the PCHO
prepared over
H3PW12O40·13H2O
has a stereoregularity higher than that prepared over
clay and Aluminium alkoxide catalysts. The T
g value obtained is due to the
microstructure but not to molecular weight. The
yield and the molecular weight of the polymer
depend strongly on the reaction conditions.
Molecular weights can be readily controlled by
changing reaction temperature, reaction time, and
catalyst amount. Contrary to most polymerization
reactions, the molecular weight increases with the
temperature increase. Addition of acetic anhydride
to the reaction medium increased the yield
threefold.


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## Body

## 1. Introduction

Due to their high polarizability and flexibility, polyethers constitute a very important soft segment for producing thermoplastic elastomers. Many of these polymers have been synthesized by ring-opening polymerization (ROP) of cyclic ether monomers [1]. Among cyclic monomers’ ring-opening polymerization that of cyclohexene oxide (epoxide) into polycyclohexene oxide (polyether) has been the subject of a large number of papers [2–5]. This is due to the fact that cyclohexene oxide (CHO) polymers are useful materials. In fact, they are used in the synthesis of various alicyclic target materials including pesticides, pharmaceuticals, perfumery, and dyestuffs. ROP of cyclic ethers could be initiated by electrophilic agents such as Brønsted acids (HCl, H2SO4, HClO4, etc.) and Lewis acids (AlCl3, BF3OEt2, TiCl4, etc.). However, the protonic acid catalysts used are corrosive and not recoverable, and the Lewis acids required great amount to achieve acceptable polymer yields. Because of increasing environmental concerns in recent years, a more effective catalytic process has been sought. In this respect, researchers have conducted studies on the development of solid acids so that aggressive and dangerous homogeneous acids can be replaced to overcome the problem of separating the catalysts from the products and from the disposal of solid/liquid waste. Solid Brønsted acids with super acidic character, such as the Keggin-type heteropolyacids, are known as highly active catalysts [6–8]. Due to their strong acidity, these “super acids” catalyze various reactions much more effectively than the conventional protonic acids [9, 10]. In recent years, heteropolyacids have been used as catalysts to induce the polymerization of various monomers such as cyclic ethers, styrene, acetals, polyalcohols, and lactones [11–13]. In a previous paper [14] we have reported the polymerization of tetrahydrofuran catalyzed by a series of heteropolyacids. It has been found that H3PW12O40 was the efficient catalyst of the series of heteropolyacids tested. This fact prompted us to investigate the cationic ring-opening polymerization of CHO by this catalyst. The effect of reaction temperature, reaction time, catalyst amount, and acetic anhydride proportion on the polymerization was investigated.


## 2. Materials and Methods

### 2.1. Catalyst Preparation

H3PW12O40 was prepared according to a now well-known method [15]; that is, 100 g of Na2WO4·2H2O was dissolved in 100 mL of warm distilled water and then successively 85% H3PO4 (5 mL) and 37.5% HCl (22 mL) were added slowly to the solution. The mixture was concentrated to three quarters of its initial volume by heating and then after that it was cooled to room temperature. The cooled mixture was extracted with diethyl ether in hydrochloric acid medium. The product formed with ether, which settled down at the bottom, was separated from the aqueous phase. The white crystals of H3PW12O40·13H2O were dried at room temperature.


### 2.2. Polymerization Procedure

Polymerization reactions of CHO were carried out in dichloromethane in a glass reactor fitted with a condenser. The temperature of the reactor was adjusted by a heating jacket. Typically, a fixed amount of H3PW12O40 as catalyst was added to CHO (10 mL) and dichloromethane (4 mL) mixture under stirring at a desired temperature. Polymerization was terminated with addition of a saturated NaOH aqueous solution and still stirred for 5 min. At the end of the reaction, the resulting PCHO polymer was precipitated in methanol and then filtrated off for characterization and molecular weight measurements.


### 2.3. Catalyst and Polymer Characterization

The Keggin structure of the catalyst (H3PW12O40) was checked by means of FTIR. IR spectrum was recorded with an infrared spectrometer GENESIS II FTIR (4000–400 cm−1) as KBr pellets.The polymer was characterized by using FTIR spectroscopy, NMR spectroscopy, differential scanning calorimeter (DSC), and molecular weight measurements.1H NMR spectra were recorded on a Bruker Avance 400 MHz spectrophotometer using 5 mm NMR tubes using deuterated acetone-D6 as solvent. DSC model DSC-60 made by Shimadzu was utilized here. The specimens weigh about 12 mg each. Each specimen was placed in aluminum pan. The pan was placed in the DSC’s oven in air at atmospheric pressure. Specimens were heated at a constant heating rate of 5°C/min to 300°C. Molecular weight measurements were determined by means of a HT-GPC, Model 430, Viscotek, Houston, TX, USA, gel-permeation chromatograph (GPC) with CLM6210 column.


## 2.1. Catalyst Preparation

H3PW12O40 was prepared according to a now well-known method [15]; that is, 100 g of Na2WO4·2H2O was dissolved in 100 mL of warm distilled water and then successively 85% H3PO4 (5 mL) and 37.5% HCl (22 mL) were added slowly to the solution. The mixture was concentrated to three quarters of its initial volume by heating and then after that it was cooled to room temperature. The cooled mixture was extracted with diethyl ether in hydrochloric acid medium. The product formed with ether, which settled down at the bottom, was separated from the aqueous phase. The white crystals of H3PW12O40·13H2O were dried at room temperature.


## 2.2. Polymerization Procedure

Polymerization reactions of CHO were carried out in dichloromethane in a glass reactor fitted with a condenser. The temperature of the reactor was adjusted by a heating jacket. Typically, a fixed amount of H3PW12O40 as catalyst was added to CHO (10 mL) and dichloromethane (4 mL) mixture under stirring at a desired temperature. Polymerization was terminated with addition of a saturated NaOH aqueous solution and still stirred for 5 min. At the end of the reaction, the resulting PCHO polymer was precipitated in methanol and then filtrated off for characterization and molecular weight measurements.


## 2.3. Catalyst and Polymer Characterization

The Keggin structure of the catalyst (H3PW12O40) was checked by means of FTIR. IR spectrum was recorded with an infrared spectrometer GENESIS II FTIR (4000–400 cm−1) as KBr pellets.The polymer was characterized by using FTIR spectroscopy, NMR spectroscopy, differential scanning calorimeter (DSC), and molecular weight measurements.1H NMR spectra were recorded on a Bruker Avance 400 MHz spectrophotometer using 5 mm NMR tubes using deuterated acetone-D6 as solvent. DSC model DSC-60 made by Shimadzu was utilized here. The specimens weigh about 12 mg each. Each specimen was placed in aluminum pan. The pan was placed in the DSC’s oven in air at atmospheric pressure. Specimens were heated at a constant heating rate of 5°C/min to 300°C. Molecular weight measurements were determined by means of a HT-GPC, Model 430, Viscotek, Houston, TX, USA, gel-permeation chromatograph (GPC) with CLM6210 column.


## 3. Results and Discussion

### 3.1. Characterization of the Catalyst

Infrared spectrum of 12-tungstophosphoric acid, H3PW12O40·13H2O (abbreviated as H3PW12O40), is shown in Figure 1. According to [16], the main characteristic features of the Keggin structure observed at 1080–1060 cm−1 (ν
a
s P-O
a), at 990–960 cm−1 (ν
a
s Mo-O
d), at 900–870 cm−1 (ν
a Mo-O
d-Mo), and at 810–760 cm−1 (ν
a
s Mo-O
c-Mo) were obtained.Figure 1
IR spectrum of H3PW12O40.


### 3.2. Polymer Characterization

The cationic ring-opening polymerization of cyclohexene oxide was catalyzed by H3PW12O40 solid super acid catalyst in dichloromethane at 40°C (Scheme 1).Scheme 1
Reaction scheme for the synthesis of PCHO by ring-opening polymerization of CHO over H3PW12O40 catalyst.The IR spectrum of PCHO is shown in Figure2. The bands present at 2932 (γ
a
s CH2), 2859 (γ
s CH2, γ CH), 1449 (δ CH2), 1366 (δ CH2), 1158, 1090 (C-O-C antisymmetric stretching), 895, 850, and 756 (δ CH out-of-plane). These assignments for PCHO agree well with those of Yahiaoui et al. [2] and Suga and Aoyama [17] for the PCHO prepared with an acid-exchanged montmorillonite clay catalyst.Figure 2
IR spectrum of poly(CHO). Polymerization catalyzed by 0.2 g of H3PW12O40 at 40°C during 3 hours in CH2Cl2.Figure3 shows different peaks, the methylene groups (cyclohexane CH2-) at 1.0–2.0 ppm, and methine groups (CH2-CHO) at 3.2–3.6 ppm. The signal of the methine protons appears in the form of two peaks (3.28 and 3.33 ppm), which we attribute, respectively, to triads isotactic (mm) and heterotactic (mr and rm). These assignments for PCHO agree well with those of Ling et al. [5] for the PCHO prepared over recyclable scandium triflate in room temperature ionic liquid catalyst.Figure 3
1HNMR spectrum of PCHO. Polymerization catalyzed by 0.2 g of H3PW12O40·13H2O at 40°C during 3 hours in CH2Cl2.


### 3.3. Effect of Reaction Temperature

The effect of the reaction temperature on the yield, molecular weight, andT
g of the PCHO was investigated. The reactions were carried out in a temperature ranging from 15°C to 70°C in dichloromethane solvent. Figure 4 shows the effect of the temperature on the yield and on the molecular weight. It can be seen that both the yield and the molecular weight increased with the increase of the temperature. This result is in agreement with that reported in the literature [2]. The increase of the yield with temperature is an expected result but the increase of the molecular weight is unexpected. In fact, in most polymerization reactions, the molecular weight decreases with the increase of the temperature owing to the fact that the temperature accelerates the rate of chain transfer reactions which in turn decreases the molecular weight [18]. In the case of CHO polymerization, the increase of the molecular weight can be explained by the fact that the HO- group bound to a rigid cyclohexene ring cannot approach sufficiently close to the oxygen atom to allow for the interchange reaction [19].Figure 4
Yield and Mw of PCHO as a function of reaction temperature. Polymerization catalyzed by 0.2 g of H3PW12O40 during 3 hours in CH2Cl2.The effect of the temperature reaction on the PCHOT
g is shown in Figure 5. It can be seen that the T
g values are ranging between 23 and 37°C. These T
g values are different from that observed by Yahiaoui et al. (T
g = 75.23°C) over a clay catalyst [2]. As for the PCHO prepared by Zevaco et al. over Aluminium alkoxides catalyst [20], the authors reported that they have not observed a clear glass transition temperature but a broad endotherm between 66 and 100°C (max at 70°C) which they have attributed to a melting point of their resulting polymer. The difference in the T
g value between our polymer and that of Yahiaoui et al. and Zevaco et al. might be due to the difference in the microstructure of the prepared polymer. Indeed, our PCHO which was prepared by a super acid (Keggin heteropolyacid) has a different stereoregularity than that prepared by these authors. In fact, the 1H NMR spectrum of our PCHO showed only two peaks (3.28 and 3.33 ppm) for the signals of the methine protons which we have attributed, respectively, to triads isotactic (mm) and heterotactic (mr and rm) whereas the NMR of the PCHO prepared by Yahiaoui et al. [2] and Zevaco et al. [20] showed three peaks (3.3, 3.4, and 3.5 ppm) and (3.66, 3.78, and 3.88 ppm), respectively, which they attribute, respectively, to triads isotactic (mm), heterotactic (mr and rm), and syndiotactic (rr).Figure 5
Typical DSC thermograms of the prepared PCHO obtained at a heating rate of 20°C/min. Polymerization catalyzed by 0.2 g of H3PW12O40 during 3 hours in CH2Cl2.


### 3.4. Effect of Catalyst Amount

To investigate the effect of the amount of catalyst on the polymerization yield and molecular weight, we carried out the polymerization reaction of CHO (10 mL) in dichloromethane (4 mL) at 40°C during 3 hours. The results obtained are reported in Figure6. It can be seen that the polymer yield increases as the mass of the catalyst increases, whereas the molecular weight decreases. The highest molecular weight (9100 g mol−1) was obtained for the lowest amount used of catalyst (10 mg). The inverse proportionality between the molecular weight and the amount of catalyst can be explained by the fact that when the amount of the catalyst increased, the number of initiating active responsible sites (H+) for inducing polymerization increased and consequently the number of chains increased which is obviously at the expense of the length of the chains. The decrease in molecular weight might be due also to the increase in water which increased with the increase of catalyst amount.Figure 6
Effect of catalyst amount on the molecular weight and yield for the polymerization of CHO in CH2Cl2 at 40°C over H3PW12O40.


### 3.5. The Effect of Reaction Time

Effect of reaction time on the yield and the molecular weight of the polymer were examined. The polymerization reactions were catalyzed by 0.02 g of catalyst at 40°C in dichloromethane solvent. The results (Figure 7) show that both the yield and molecular weight of the polymer increase with increasing reaction time. The increase of the yield and the molecular weight was rapid for short reaction times whereas for long time reactions a slight variation is observed. A yield of 64% and a molecular weight of 8300 g mol−1 are reached after 21 hours of reaction. The stagnation of the molecular mass may be due to the fact that, at higher yields and higher molecular weights, the viscosity of the medium increased and therefore the reaction became kinetically slow. So there was a stagnation of the molecular weight and yield.Figure 7
Effect of reaction time on the conversion and molecular weight of PCHO in CH2Cl2 at 40°C over H3PW12O40.


### 3.6. Effect of Acetic Anhydride Proportion

Acetic anhydride has been used for the ring-opening of many heterocyclic compounds and it has been found that the yield of the polymer depends on its used proportion [21–23]. That is why we have tried to study its effect on the ring-opening of CHO. To achieve this, different volumes are added to the solution CHO/CH2Cl2. The reactions were carried out at 40°C for three hours. The results obtained (Figure 8) showed that the yield of the polymer depends strongly on the acetic anhydride proportion. In fact, when the volume ratio varies from 0 to 0.30, the yield increased by 20% to 60%. This shows that the initial value has tripled. When the volume ratio of the acetic anhydride added is beyond 0.3, the yield decreased. The decrease of the yield at high acetic anhydride volume ratio might be due to consumption of heteropolyacid protons by the acetic anhydride leading to acetic acid (a weak acid) or to an increase in the number of methyl groups at the extremities of the chains that block the growth of polymer chains. In fact, large addition of acetic anhydride to the mixture creates chain ends unable to take part in polymerization.Figure 8
Effect of acetic anhydride proportion on PCHO yield. Reaction conditions:T = 40°C; reaction time = 3 h.


### 3.7. Polymerization Mechanism

The ring-opening polymerization of PCHO can be achieved by addition of acetic anhydride via a cationic pathway. According to the obtained results, we propose a cationic mechanism for the polymerization initiated by protons provided by H3PW12O40 (Scheme 2).Initiation. The first stage is the protonation of acetic anhydride by H3PW12O40, leading to the formation of acetyl polyoxometalate salt. Then there is a nucleophilic attack of the oxygen of cyclohexene oxide on the carbon atom of the acetyl species. The formed oxonium ion undergoes a nucleophilic attack on the carbon by the oxygen of the cyclohexene oxide of the chains in growth.Propagation. In this stage, the protonated oxonium ion undergoes a nucleophilic attack by a molecule of cyclohexene oxide.Termination. The last stage is a nucleophilic attack of the oxygen of the acetic acid formed in the first stage on the carbon in alpha of positively charged oxygen of the chains in growth.Scheme 2
Mechanism for the ring-opening polymerization of cyclohexene oxide in the presence of acetic anhydride over H3PW12O40 catalyst.


## 3.1. Characterization of the Catalyst

Infrared spectrum of 12-tungstophosphoric acid, H3PW12O40·13H2O (abbreviated as H3PW12O40), is shown in Figure 1. According to [16], the main characteristic features of the Keggin structure observed at 1080–1060 cm−1 (ν
a
s P-O
a), at 990–960 cm−1 (ν
a
s Mo-O
d), at 900–870 cm−1 (ν
a Mo-O
d-Mo), and at 810–760 cm−1 (ν
a
s Mo-O
c-Mo) were obtained.Figure 1
IR spectrum of H3PW12O40.


## 3.2. Polymer Characterization

The cationic ring-opening polymerization of cyclohexene oxide was catalyzed by H3PW12O40 solid super acid catalyst in dichloromethane at 40°C (Scheme 1).Scheme 1
Reaction scheme for the synthesis of PCHO by ring-opening polymerization of CHO over H3PW12O40 catalyst.The IR spectrum of PCHO is shown in Figure2. The bands present at 2932 (γ
a
s CH2), 2859 (γ
s CH2, γ CH), 1449 (δ CH2), 1366 (δ CH2), 1158, 1090 (C-O-C antisymmetric stretching), 895, 850, and 756 (δ CH out-of-plane). These assignments for PCHO agree well with those of Yahiaoui et al. [2] and Suga and Aoyama [17] for the PCHO prepared with an acid-exchanged montmorillonite clay catalyst.Figure 2
IR spectrum of poly(CHO). Polymerization catalyzed by 0.2 g of H3PW12O40 at 40°C during 3 hours in CH2Cl2.Figure3 shows different peaks, the methylene groups (cyclohexane CH2-) at 1.0–2.0 ppm, and methine groups (CH2-CHO) at 3.2–3.6 ppm. The signal of the methine protons appears in the form of two peaks (3.28 and 3.33 ppm), which we attribute, respectively, to triads isotactic (mm) and heterotactic (mr and rm). These assignments for PCHO agree well with those of Ling et al. [5] for the PCHO prepared over recyclable scandium triflate in room temperature ionic liquid catalyst.Figure 3
1HNMR spectrum of PCHO. Polymerization catalyzed by 0.2 g of H3PW12O40·13H2O at 40°C during 3 hours in CH2Cl2.


## 3.3. Effect of Reaction Temperature

The effect of the reaction temperature on the yield, molecular weight, andT
g of the PCHO was investigated. The reactions were carried out in a temperature ranging from 15°C to 70°C in dichloromethane solvent. Figure 4 shows the effect of the temperature on the yield and on the molecular weight. It can be seen that both the yield and the molecular weight increased with the increase of the temperature. This result is in agreement with that reported in the literature [2]. The increase of the yield with temperature is an expected result but the increase of the molecular weight is unexpected. In fact, in most polymerization reactions, the molecular weight decreases with the increase of the temperature owing to the fact that the temperature accelerates the rate of chain transfer reactions which in turn decreases the molecular weight [18]. In the case of CHO polymerization, the increase of the molecular weight can be explained by the fact that the HO- group bound to a rigid cyclohexene ring cannot approach sufficiently close to the oxygen atom to allow for the interchange reaction [19].Figure 4
Yield and Mw of PCHO as a function of reaction temperature. Polymerization catalyzed by 0.2 g of H3PW12O40 during 3 hours in CH2Cl2.The effect of the temperature reaction on the PCHOT
g is shown in Figure 5. It can be seen that the T
g values are ranging between 23 and 37°C. These T
g values are different from that observed by Yahiaoui et al. (T
g = 75.23°C) over a clay catalyst [2]. As for the PCHO prepared by Zevaco et al. over Aluminium alkoxides catalyst [20], the authors reported that they have not observed a clear glass transition temperature but a broad endotherm between 66 and 100°C (max at 70°C) which they have attributed to a melting point of their resulting polymer. The difference in the T
g value between our polymer and that of Yahiaoui et al. and Zevaco et al. might be due to the difference in the microstructure of the prepared polymer. Indeed, our PCHO which was prepared by a super acid (Keggin heteropolyacid) has a different stereoregularity than that prepared by these authors. In fact, the 1H NMR spectrum of our PCHO showed only two peaks (3.28 and 3.33 ppm) for the signals of the methine protons which we have attributed, respectively, to triads isotactic (mm) and heterotactic (mr and rm) whereas the NMR of the PCHO prepared by Yahiaoui et al. [2] and Zevaco et al. [20] showed three peaks (3.3, 3.4, and 3.5 ppm) and (3.66, 3.78, and 3.88 ppm), respectively, which they attribute, respectively, to triads isotactic (mm), heterotactic (mr and rm), and syndiotactic (rr).Figure 5
Typical DSC thermograms of the prepared PCHO obtained at a heating rate of 20°C/min. Polymerization catalyzed by 0.2 g of H3PW12O40 during 3 hours in CH2Cl2.


## 3.4. Effect of Catalyst Amount

To investigate the effect of the amount of catalyst on the polymerization yield and molecular weight, we carried out the polymerization reaction of CHO (10 mL) in dichloromethane (4 mL) at 40°C during 3 hours. The results obtained are reported in Figure6. It can be seen that the polymer yield increases as the mass of the catalyst increases, whereas the molecular weight decreases. The highest molecular weight (9100 g mol−1) was obtained for the lowest amount used of catalyst (10 mg). The inverse proportionality between the molecular weight and the amount of catalyst can be explained by the fact that when the amount of the catalyst increased, the number of initiating active responsible sites (H+) for inducing polymerization increased and consequently the number of chains increased which is obviously at the expense of the length of the chains. The decrease in molecular weight might be due also to the increase in water which increased with the increase of catalyst amount.Figure 6
Effect of catalyst amount on the molecular weight and yield for the polymerization of CHO in CH2Cl2 at 40°C over H3PW12O40.


## 3.5. The Effect of Reaction Time

Effect of reaction time on the yield and the molecular weight of the polymer were examined. The polymerization reactions were catalyzed by 0.02 g of catalyst at 40°C in dichloromethane solvent. The results (Figure 7) show that both the yield and molecular weight of the polymer increase with increasing reaction time. The increase of the yield and the molecular weight was rapid for short reaction times whereas for long time reactions a slight variation is observed. A yield of 64% and a molecular weight of 8300 g mol−1 are reached after 21 hours of reaction. The stagnation of the molecular mass may be due to the fact that, at higher yields and higher molecular weights, the viscosity of the medium increased and therefore the reaction became kinetically slow. So there was a stagnation of the molecular weight and yield.Figure 7
Effect of reaction time on the conversion and molecular weight of PCHO in CH2Cl2 at 40°C over H3PW12O40.


## 3.6. Effect of Acetic Anhydride Proportion

Acetic anhydride has been used for the ring-opening of many heterocyclic compounds and it has been found that the yield of the polymer depends on its used proportion [21–23]. That is why we have tried to study its effect on the ring-opening of CHO. To achieve this, different volumes are added to the solution CHO/CH2Cl2. The reactions were carried out at 40°C for three hours. The results obtained (Figure 8) showed that the yield of the polymer depends strongly on the acetic anhydride proportion. In fact, when the volume ratio varies from 0 to 0.30, the yield increased by 20% to 60%. This shows that the initial value has tripled. When the volume ratio of the acetic anhydride added is beyond 0.3, the yield decreased. The decrease of the yield at high acetic anhydride volume ratio might be due to consumption of heteropolyacid protons by the acetic anhydride leading to acetic acid (a weak acid) or to an increase in the number of methyl groups at the extremities of the chains that block the growth of polymer chains. In fact, large addition of acetic anhydride to the mixture creates chain ends unable to take part in polymerization.Figure 8
Effect of acetic anhydride proportion on PCHO yield. Reaction conditions:T = 40°C; reaction time = 3 h.


## 3.7. Polymerization Mechanism

The ring-opening polymerization of PCHO can be achieved by addition of acetic anhydride via a cationic pathway. According to the obtained results, we propose a cationic mechanism for the polymerization initiated by protons provided by H3PW12O40 (Scheme 2).Initiation. The first stage is the protonation of acetic anhydride by H3PW12O40, leading to the formation of acetyl polyoxometalate salt. Then there is a nucleophilic attack of the oxygen of cyclohexene oxide on the carbon atom of the acetyl species. The formed oxonium ion undergoes a nucleophilic attack on the carbon by the oxygen of the cyclohexene oxide of the chains in growth.Propagation. In this stage, the protonated oxonium ion undergoes a nucleophilic attack by a molecule of cyclohexene oxide.Termination. The last stage is a nucleophilic attack of the oxygen of the acetic acid formed in the first stage on the carbon in alpha of positively charged oxygen of the chains in growth.Scheme 2
Mechanism for the ring-opening polymerization of cyclohexene oxide in the presence of acetic anhydride over H3PW12O40 catalyst.


## 4. Conclusions

From the results it can be concluded that Keggin-type heteropolyacid (H3PW12O40) is an effective catalyst of the ring-opening polymerization of cyclohexene oxide owing to its strong Brønsted acidity.The microstructure of the resulting PCHO is different from that prepared over clay and alumina alkoxide catalysts. The lowT
g value of the PCHO is due to the microstructure but not to molecular weight. Contrary to most polymerization reactions, the molecular weight and the yield increase with the increase of the temperature.The decrease in the molecular weight with the increase of the amount of catalyst might be due to the increase of the amount of water which increased with the increase of catalyst amount or to the increase of the number of initiating active sites (H+) which increases the number of chains at the expense of the length of the chains.Controlled low molecular weight of the PCHO over H3PW12O40 can find various applications. It can be used for preparing soft segments for thermoplastic elastomers.The use of H3PW12O40 as a solid acid catalyst instead of the usual soluble inorganic acids is a contribution to a reduction of waste.



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*Source: 826512-2015-06-22.xml*