# Comprehensive Characterization ofFurcraea selloa K. Koch Peduncle Fiber-Reinforced Polyester Composites—Effect of Fiber Length and Weight Ratio

Authors: D. Divya; I. Jenish; S. Raja
Journal: Advances in Materials Science and Engineering
 (2022)

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## Abstract

Nowadays, scientists and researchers working on polymer composites are paying much attention to the discovery of prospective plant fibers in order to build a promising fiber-reinforced polymer composite. The present study investigated the efficacy of using a novelFurcraea selloa K. Koch peduncle fiber in reinforced composites, and the specific composite characterization was done to explore the absolute fiber length and weight ratio to accomplish superior composite properties. For that, peduncle fibers with different length-to-weight ratios were reinforced with unsaturated polyester and the corresponding composites were tested to decide the optimum fiber length-to-weight ratio for obtaining the utmost composite properties. The results indicated that the highest mechanical properties were allied with a composite reinforced with 30 mm fiber length and 30 wt.% with the tensile strength of 103.51 MPa and flexural strength of 144.65 MPa. While the remaining tested volumes showed decreased properties as compared to optimal, which might be due to debonding effects or less interfacial bonding as examined clearly in SEM images of fractured samples. Enhanced thermal stability with 390°C and relatively reduced water absorption rate was observed in the case of optimal range when compared to other testing dimensions. Moreover, the current study confirmed that FSPF composites possess promising comparable properties which would be a good alternative to existing synthetic composites.


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## Body

## 1. Introduction

Polymer composites have become more popular in the twenty-first century because of the increasing depletion of conventional reserves and the excellent specific features of such polymeric composites. A variety of industrial sectors, including automotive, sports, aircraft, marine, oil, and construction, now use polymer composite materials extensively. Despite the lightweight nature, such materials have been gaining much attraction in the global market to replace traditional materials such as aluminum, steel, etc. A reinforcing phase and a matrix are often blended together to form composite materials, which are not soluble in each other, that offer incorporated properties of two or more classes of materials while using together, thereby making them more versatile. The natural plant fibers can be cast-off in the reinforcement phase to frame biopolymeric composites; which has more attention today. Such plant fiber reinforced-polymer composites showed good strength, stiffness, thermal stability, and other mechanical properties since that can be used as an alternative to conventional materials [1, 2].There is a great deal of interest in fiber-yielding plants since they may be easily accessed and renewed for sustainable composite fabrication without creating any environmental issues. As compared to conventional sources, their processing and handling are easy and need little investment only. Natural plant fiber composites need an overall manufacturing cost of 20 to 40% in contrast to synthetic fibers, which makes them a cost-effective alternative to traditional materials. Additionally, biodegradability, recyclability, and favorable environmental impacts of plant fibers compete with the properties of conventional nonrenewable materials. Hence, the identification of novel plant fibers with significant specific properties is a need of the hour [3]. Matrixes or polymers are long-chain molecules made up of atoms linked together by strong bonds in a repeating pattern. Polyesters are one of the thermoset polymers, which contain strong covalent bonds and can offer good interfacial bonding with fibers, as reported in earlier [4, 5]. Thus, the current study tried to explore a potential novel fiber reinforced unsaturated polyester composites.The performance of composite is usually affected by a variety of variables. Interfacial adhesion between the reinforcement and matrix is heavily influenced by the type of constituent materials, its dimensions, and distribution. Although, the interface area, texture, and strength of the whole composite material are governed by the reinforcement's size and orientation [6, 7]. Mainly, the age of the plant and position of the fiber in plants determines the mechanical characteristics of fibers. Since, the determination of appropriate fiber loading rate is having paramount importance in fiber research. A few investigations were done on the same aspect to explore the critical fiber length and weight percentage earlier, which disclosed that the fiber lengths ranging from 30 mm to 40 mm and fiber content ranging from 30 wt.% to 40 wt.% provided better mechanical properties. However, these properties vary with natural plant fibers obtained from different sources. Hence, the identification of suitable length or size and volume (weight fraction) of reinforcement is an adequate step in composite research studies to assure maximum strength of the material [8]. Diverse studies carried out earlier for the investigation of natural fibers by varying weight and loading on polymer composites are summarized in Table 1.Table 1
Listing the properties ofFurcraea selloa K. Koch peduncle fiber/polyester composite in comparison with other natural fiber reinforced composites.
FiberMatrixMethodOptimum fiberTensile strength MPaTensile modulus GPaFlexural strength MPaFlexural modulus GPaImpact strength J/cm2Hardness (HRRW)ReferenceLength mmLoading %Furcraea selloa K. Koch peduncle fiberPolyesterCompression molding3030103.52.35144.652.9310.0892Present workCymbopogon flexuosus stemPolyesterHand layup403084.7731.31093.531.8710.190[9]Tamarind fruit fiberPolyesterCompression molding50–1004077.41.488.51.57.390[10]Sansevieria cylindrica fiberPolyesterCompression molding304075.751.1028439.5—[11]Cissus quadrangularis stemPolyesterHand layup403090.2001.400103.0402.25010.792[12]Red banana peduncle fiberPolyesterCompression molding300–400—11.61—2—4.6—[13]Sisal fiberEpoxyHand layup103040.250.187104.7811.8961.366—[14]Calotropis procera fiberEpoxyHand layup303011.43 ± 0.06—26.38 ± 0.47—0.167—[15]Jute fiberEpoxyHand layup302075.150.638124.012.613.25—[16]Coconut coir fiberEpoxyHand layup303013.052.06435.42—1.7516.9 (hv)[17]Calotropis giganteaEpoxyHand layup0.149–0.1001048.73195.196.3467[18]In this study, a peduncle fiber extracted fromFurcraea selloa K. Koch (FSPF) was employed for the first time in composite manufacturing. The main aim of this study was to explore the potentiality of FSPF as a reinforcement in polyester composites and to optimize a standard length to weight ratio of fiber for effective composite fabrication. Composites with varied fiber lengths to weight ratio were experienced to optimize the ﬂexural, impact, hardness, and tensile properties of the composite. Fractography analysis was conducted to examine the interfacial adhesion property of the fractured surface. The water absorption analysis and thermal characterization of the composites were performed to establish the processability of specific composite in diverse environmental conditions.


## 2. Experimental Details

### 2.1. Materials

Furcraea selloa K. Koch peduncle was collected from the village Asarivilai of Kanyakumari district, Tamil Nadu, India, and used for the extraction of respective fibers through the water retting process. The plant material, fiber extraction process, and extracted fibers and its polyester based composites are presented in Figure 1. The average diameter of the fiber was identified as 94.40 ± 2.12 μm. The extracted fibers were cut into appropriate lengths (10 mm, 20 mm, 30 mm, 40 mm, and 250 mm) and employed for composite manufacturing. An unsaturated polyester resin (98 vol.%) was used as a matrix for fiber reinforcement. Methyl ethyl ketone peroxide (MEKP) (1 vol.%) was used as the setting catalyst and cobalt naphthenate (1 vol.%) was cast-off for accelerating curing process, for composite structuring.Figure 1
Photographs of (a)Furcraea selloa K Koch plant with peduncle; (b) Peduncle under microbial degradation process; (c) Extracted fibers; and (d) FSPF reinforced composite at different weight percentages.
(a)(b)(c)(d)


### 2.2. Composite Fabrication

For composite preparation, the unsaturated polyester resin (98 vol.%) was mixed with the curing catalyst MEKP and the accelerator cobalt naphthenate. The physical and chemical properties of the resin was tested in its both solid and liquid forms (Table2). The composite specimens were made using a mild steel mold that possess dimensions of 300 mm × 125 mm × 3 mm. The hand layup-cum-compression molding technique was used for the fabrication of FSPF fiber reinforced polyester composites. For that, the chopped fibers with desired lengths and weights were evenly dispersed within the mold with utmost care. The resin was then poured over the pre-pressed fibers and then allowed it to infuse into the fiber layers. A grooved roller was used to physically integrate the matrix through the fibers manually without trapping air, and the mixture was then allowed to cure at room temperature under a 400 kN load. There were 26 sets of composite sheets were constructed for composite testing with different fiber lengths (10 mm, 20 mm, 30 mm, 40 mm, and 50 mm) and weight percentage (10%, 20%, 30%, 40%, and 50%) (Figure 1(d)) [19].Table 2
Properties of liquid and cured polyester resin utilized to prepare composites.
Liquid resinAcid value25 mg KOH/g ± 3 mg KOH/gAppearanceYellow coloured viscous liquidDensity1.25 ± 0.10 gm/ccSpecific gravity at 25°C1.20 ± 0.02Viscosity at 25°C200–300 cPVolatile content37 wt.% ± 2 wt.%Cured resinElongation at break1.20% ± 0.24%Flexural modulus1.73 GPa ± 0.38 GPaFlexural strength42.70 MPa ± 2.15 MPaImpact strength0.65 J/cm2 ± 0.05 J/cm2Melting point280°CRockwell hardness64 HRRW ± 3 HRRWShear strength4.10 MPa ± 1.34 MPaTensile modulus1.0 GPa ± 0.2 GPaTensile strength35.0 MPa ± 1.5 MPa


### 2.3. Characterization of FSPF Reinforced Composites

The obtained composite plates were used to prepare test specimens as per ASTM standards for further characterization. Then, the specimens were subjected for evaluation of its mechanical properties such as tensile strength, flexural strength, impact strength, and hardness features. For analyzing degradation behavior, the water uptake test was opted. The thermal behavior and fractography analysis were performed to recognize the thermal stability and fracture mechanics of specific composites. Conversely, the fractured surface of the composites was also examined [9].


### 2.4. Mechanical Characterization

For tensile testing, samples with 100 mm gauge length were prepared according to the ASTMD 3039 M-95 standard and the tests were executed in an Instron S-series H25K–S UTM (H25 K–S, S-Series, USA). Conversely, a three-point flexural test was performed in the same machine for the samples with 30 mm gauge length, where the samples are prepared as per ASTM D 790–10 standard to analyze flexural strength of composites. A transverse speed of 1 mm/min was admirable for conducting both the tests. The energy absorption capacity of the material was evaluated by conducting an Izod impact test (ASTM D 256–10) and the hardness property was determined by using a Digital Rockwell hardness testing machine by means of the ASTM D785-98 standard [20].


### 2.5. Thermal Analysis

The thermal stability of the selected optimal composite was evaluated by thermogravimetric analysis (TGA/DTG) to find out the suitability of composite for higher temperature required functioning. This test was executed in a thermal analyzer model Jupiter STA 449 F3 under nitrogen (20 ml/min) having an environment with a frequent increase in temperature by 10°C/minute, from 28 to 1000°C [1]. The mass changes in the material were recorded with respect to the time and used to assess the thermal stability of composites.


### 2.6. Water Uptake Test

Water absorption characteristics of the square composite specimens with 30 mm size with different weight percentage (10–50%) (ASTMD 570–98) were studied by immersing composite specimens in water along with a polyester sample, for varied time intervals from 0–24 hours [13]. The percentage of water absorption was calculated by weighing the specimens before and after conducting test by employing a 10−4g accuracy electronic mass balancer (model AUX220; Shimadzu, Japan) as per the following (1). In this relation, w0 denotes the specimen's weight before immersion (mg) and ‘wt’ symbolizes the specimen's weight after a specified duration of immersion in water (mg) [21].(1)%of water absorption,W=wt−w0w0×100.


### 2.7. Fractography Analysis

The fractured surface of optimum composite was examined under a scanning electron microscope model S-1500, Hitachi, Japan, to explore the surface features of the composites. For analysis, the specimen was coated with a thin gold layer to avoid the electron beam charging effects during the examination and thereby to assure good image quality. The examination was conducted with an electron beam charging of 10 kV [4].


## 2.1. Materials

Furcraea selloa K. Koch peduncle was collected from the village Asarivilai of Kanyakumari district, Tamil Nadu, India, and used for the extraction of respective fibers through the water retting process. The plant material, fiber extraction process, and extracted fibers and its polyester based composites are presented in Figure 1. The average diameter of the fiber was identified as 94.40 ± 2.12 μm. The extracted fibers were cut into appropriate lengths (10 mm, 20 mm, 30 mm, 40 mm, and 250 mm) and employed for composite manufacturing. An unsaturated polyester resin (98 vol.%) was used as a matrix for fiber reinforcement. Methyl ethyl ketone peroxide (MEKP) (1 vol.%) was used as the setting catalyst and cobalt naphthenate (1 vol.%) was cast-off for accelerating curing process, for composite structuring.Figure 1
Photographs of (a)Furcraea selloa K Koch plant with peduncle; (b) Peduncle under microbial degradation process; (c) Extracted fibers; and (d) FSPF reinforced composite at different weight percentages.
(a)(b)(c)(d)


## 2.2. Composite Fabrication

For composite preparation, the unsaturated polyester resin (98 vol.%) was mixed with the curing catalyst MEKP and the accelerator cobalt naphthenate. The physical and chemical properties of the resin was tested in its both solid and liquid forms (Table2). The composite specimens were made using a mild steel mold that possess dimensions of 300 mm × 125 mm × 3 mm. The hand layup-cum-compression molding technique was used for the fabrication of FSPF fiber reinforced polyester composites. For that, the chopped fibers with desired lengths and weights were evenly dispersed within the mold with utmost care. The resin was then poured over the pre-pressed fibers and then allowed it to infuse into the fiber layers. A grooved roller was used to physically integrate the matrix through the fibers manually without trapping air, and the mixture was then allowed to cure at room temperature under a 400 kN load. There were 26 sets of composite sheets were constructed for composite testing with different fiber lengths (10 mm, 20 mm, 30 mm, 40 mm, and 50 mm) and weight percentage (10%, 20%, 30%, 40%, and 50%) (Figure 1(d)) [19].Table 2
Properties of liquid and cured polyester resin utilized to prepare composites.
Liquid resinAcid value25 mg KOH/g ± 3 mg KOH/gAppearanceYellow coloured viscous liquidDensity1.25 ± 0.10 gm/ccSpecific gravity at 25°C1.20 ± 0.02Viscosity at 25°C200–300 cPVolatile content37 wt.% ± 2 wt.%Cured resinElongation at break1.20% ± 0.24%Flexural modulus1.73 GPa ± 0.38 GPaFlexural strength42.70 MPa ± 2.15 MPaImpact strength0.65 J/cm2 ± 0.05 J/cm2Melting point280°CRockwell hardness64 HRRW ± 3 HRRWShear strength4.10 MPa ± 1.34 MPaTensile modulus1.0 GPa ± 0.2 GPaTensile strength35.0 MPa ± 1.5 MPa


## 2.3. Characterization of FSPF Reinforced Composites

The obtained composite plates were used to prepare test specimens as per ASTM standards for further characterization. Then, the specimens were subjected for evaluation of its mechanical properties such as tensile strength, flexural strength, impact strength, and hardness features. For analyzing degradation behavior, the water uptake test was opted. The thermal behavior and fractography analysis were performed to recognize the thermal stability and fracture mechanics of specific composites. Conversely, the fractured surface of the composites was also examined [9].


## 2.4. Mechanical Characterization

For tensile testing, samples with 100 mm gauge length were prepared according to the ASTMD 3039 M-95 standard and the tests were executed in an Instron S-series H25K–S UTM (H25 K–S, S-Series, USA). Conversely, a three-point flexural test was performed in the same machine for the samples with 30 mm gauge length, where the samples are prepared as per ASTM D 790–10 standard to analyze flexural strength of composites. A transverse speed of 1 mm/min was admirable for conducting both the tests. The energy absorption capacity of the material was evaluated by conducting an Izod impact test (ASTM D 256–10) and the hardness property was determined by using a Digital Rockwell hardness testing machine by means of the ASTM D785-98 standard [20].


## 2.5. Thermal Analysis

The thermal stability of the selected optimal composite was evaluated by thermogravimetric analysis (TGA/DTG) to find out the suitability of composite for higher temperature required functioning. This test was executed in a thermal analyzer model Jupiter STA 449 F3 under nitrogen (20 ml/min) having an environment with a frequent increase in temperature by 10°C/minute, from 28 to 1000°C [1]. The mass changes in the material were recorded with respect to the time and used to assess the thermal stability of composites.


## 2.6. Water Uptake Test

Water absorption characteristics of the square composite specimens with 30 mm size with different weight percentage (10–50%) (ASTMD 570–98) were studied by immersing composite specimens in water along with a polyester sample, for varied time intervals from 0–24 hours [13]. The percentage of water absorption was calculated by weighing the specimens before and after conducting test by employing a 10−4g accuracy electronic mass balancer (model AUX220; Shimadzu, Japan) as per the following (1). In this relation, w0 denotes the specimen's weight before immersion (mg) and ‘wt’ symbolizes the specimen's weight after a specified duration of immersion in water (mg) [21].(1)%of water absorption,W=wt−w0w0×100.


## 2.7. Fractography Analysis

The fractured surface of optimum composite was examined under a scanning electron microscope model S-1500, Hitachi, Japan, to explore the surface features of the composites. For analysis, the specimen was coated with a thin gold layer to avoid the electron beam charging effects during the examination and thereby to assure good image quality. The examination was conducted with an electron beam charging of 10 kV [4].


## 3. Result and Discussion

The tensile, flexural, impact, hardness, water absorption, thermal, and fractography studies of FSPF-polyester composites (FSPFC) were done and the experimental outcomes of the characterization of composites are discussed in detail in this section.


### 3.1. Tensile Properties of FSPFC

The mechanical characteristics of the composites are largely influenced by the length and weight fraction of the fibers, and the optimum length to weight ratio is necessary to obtain composites with good quality (Indran et al., 2016). Since various lengths (from 10 to 50 mm) and weight percentages (from 10% to 50%) of reinforcing fibers were tested to recognize the maximum composite properties in this study. The impact of altering fiber length and weight % on tensile strength and tensile modulus are disclosed in Figures2(a) and 2(b). The critical fiber length and critical weight percentage of FSPF-reinforced composites were determined as 30 mm, 30 wt.%, respectively. The optimum tensile strength was found to be 103.51 MPa, which is promising than that of most of the fibers experienced in earlier as Sansevieria cyclindrica (75.75 MPa, 30 mm/40 wt.%), Tamarind fruit fiber (77.4 MPa, 50 mm/40 wt.%), red banana peduncle fiber (11.61 MPa, 300–400 mm), Cissus quadrangularis stem (90.20 MPa, 40 mm/30 wt.%), Cymbopogon flexuosus stem (84.77 MPa, 40 mm/30 wt.%), Coconut coir fiber (13.05 MPa, 30 mm/30 wt.%), Calotropis procera (11.43 MPa, 30 mm/30 wt.%), and jute fibers (75.15 MPa, 30 mm/40 wt.%) (Table 1). Moreover, it is noted that tensile strength increased as fiber length and weight % increases up to 30 mm/30 wt.%, since the polyester matrix transmits and distributes the maximum applied stress to the fibers. Beyond the optimum range, the fiber curls are inadequate to disseminate the polyester resin within the fiber [22]. Thus, 30 mm fiber length with a 30% fiber weight percentage gives the optimum bonding between the FSPF and polyester matrix. The same trend is reflected in case of tensile modulus, where the optimum modulus of 2.35 Gpa was attained at 30 mm fiber length and 30 wt.% fiber loading rate. The FSPF polymer composite was significant that that of Sansevieria cyclindrica (1.10 GPa), Tamarind fruit fiber (1.4 GPa), Cymbopogon flexuosus stem (1.31 GPa), Coconut coir fiber (2.06 GPa), and jute fiber (0.638 GPa) in terms of their tensile modulus. Whereas, beyond this level, a decreasing trend was observed due to matrix/fiber incompatibility and inadequate interfacial bonding in fact of improper fiber length and loading ratio [9].Figure 2
Effect of fiber length and weight percentage on (a) tensile strength and (b) tensile modulus.
(a)(b)


### 3.2. Flexural Properties of FSPFC

Flexural strength and modulus of FSPFC obtained with different fiber contents are demonstrated in Figures3(a) and 3(b). Flexural strength has a similar drift as like tensile strength and beyond the optimum content the properties dropped. With 30 wt. % and 40 mm fiber length, the maximum flexural strength of 144.62 MPa and flexural modulus of 2.93 GPa were obtained. This might be due to the homogeneous distribution of the FSPF/polyester matrix and improved fiber matrix interaction developed during bending by the optimum fiber content of the composite. A reduced trend is found with other fiber concentrations that might be due to curling of the fiber beyond 30 mm/30 wt.%, which reduces flexural properties. The obtained flexural strength and was promising than that of Acacia concinna fiber (112.31 ± 4.1 MPa. 40 mm/30 wt.%), Sansevieria cyclindrica (84 MPa), Tamarind fruit fiber (88.5 MPa), red banana peduncle fiber (2 MPa), Cissus quadrangularis stem (103.04 MPa), Cymbopogon flexuosus stem (93.53 MPa), Coconut coir fiber (35.45 MPa), Calotropis procera (26.38 MPa), and jute fiber (124.01 MPa) [9, 20]. The flexural modulus of the respective composite was higher than the earlier reported fibers as Cymbopogon flexuosus stem, Tamarind fruit fiber, Cissus quadrangularis stem, and jute fiber. The obtained flexural properties can be corelated with the results of tensile properties in terms of fiber dimensions, which shows the necessity of optimization for absolute composite formulation.Figure 3
Effect of fiber length and weight percentage on (a) flexural strength and (b) flexural modulus.
(a)(b)


### 3.3. Impact Properties of FSPFC

Impact resistance refers to the ability of a material to resist under sudden stress conditions [23]. The toughness behavior of the composite was assessed using varied fiber lengths and loading rates and the results indicated that the impact strength rises linearly up to 30 wt.%/30 mm (10.8 ± 0.31 J/cm2) reinforcement owing to efficient stress transmission between the fiber and matrix with good fiber distribution (Figure 4). Beyond this concentration, there is a decline in impact strength that might be due to the increased fiber-to-fiber contact owing to increased loading or fiber breaking happens inside the composite. Moreover, the proposed plant fiber-polymer composite showed the maximum impact strength in course of all other fibers as presented in Table 1. Although, the composite possess better interfacial bonding as the composite absorbs a higher energy during the impact fracture.Figure 4
Effect of fiber length and weight percentage on the impact strength.


### 3.4. Hardness

The hardness qualities of the composite were examined to determine its resistance to scratches and abrasion. Figure5 depicts the influence of hardness on altering fiber weight and length ratio. A relatively good hardness value of 92 HRRW was allied with 30 wt.% and 40 mm length, while the cured resin's hardness is 90 HRRW. The hardness of a material is mainly influenced by the characteristics of the matrix and intermolecular bonding of the material with the matrix [8]. The enhanced hardness value obtained in this study was attributed to the matrix's homogeneous distribution [24].Figure 5
Effect of fiber length and weight percentage on Rockwell hardness.


### 3.5. Thermal Properties

The TG-DTG test was used to assess the thermal stability of the prepared fiber and the resultant deterioration patterns are evident in Figure6. The degradation of polyester was started at 360°C and for FSPF optimal composite degradation, it starts around 340°C; whilst, the complete decomposition for polyester has occurred at 495°C but for novel composite, it occurs around 390°C due to the natural fiber reinforcement, which is denoted by a sudden dip in the TG curve. This degradation temperature is reasonably higher than the thermal stability of most of the raw fibers and sufficient for composite manufacturing. Moreover, the thermal stability established for raw and treated composites were significant to withstand high temperature required applications [24, 25].Figure 6
TG and DTG curves of the polyester and FSPF/polyester (30 mm length and 30wt.% fiber) composite.


### 3.6. Water Absorption Property

Water absorption analysis was sufficient to examine the degradability of composites in aquatic environment. Figure7 signifies the effects of water on the polyester resin sample and FSPFC with five distinct fiber concentrations. This analysis revealed that there was an increase in water absorption observed from 10–50 wt.% except 30 wt.%, which might be due to the increased fiber weight fractions of the composites since polyester resin showed relatively lesser water absorption rate (7.25%). However, the optimal sample with 30 wt.% showed reduced water absorption (7.48%) than other weight percentages (7.6–8.5%). In fact, proper matrix-fiber adhesion and less microvoids are present in the optimal sample in contrast to other samples, which allows good interfacial bonding with the matrix by penetrating to lumen and reduces water absorption capacity [26, 27].Figure 7
Effect of fiber length and weight percentage on water absorption.


### 3.7. Fractography of FSPFC

Fractography of the FSPFC built-in with 30 mm/30 wt.% fiber content is presented in Figures8(a) and 8(b). This study was ideal to examine the morphological features of the composite’s fractured surface. It is clearly observed from the figures that the finest interlocking between fiber and matrix by the fact that the matrix is thoroughly infiltrated into fiber voids. The optimal composite fractography observed minimal fiber pull-out. More rough and uneven surface morphology of the fiber owing to the high interfacial strength leads to poor stress transfer, since a crack is initiated from the matrix followed by the fiber breakage occurred. Moreover, few voids remain unfilled in the matrix due to the limitation of the interface between the fibers and the matrix during manufacturing [12].Figure 8
SEM micrograph of tensile fractured specimen with 30 mm fiber length and 30 wt.% fiber content composites.


## 3.1. Tensile Properties of FSPFC

The mechanical characteristics of the composites are largely influenced by the length and weight fraction of the fibers, and the optimum length to weight ratio is necessary to obtain composites with good quality (Indran et al., 2016). Since various lengths (from 10 to 50 mm) and weight percentages (from 10% to 50%) of reinforcing fibers were tested to recognize the maximum composite properties in this study. The impact of altering fiber length and weight % on tensile strength and tensile modulus are disclosed in Figures2(a) and 2(b). The critical fiber length and critical weight percentage of FSPF-reinforced composites were determined as 30 mm, 30 wt.%, respectively. The optimum tensile strength was found to be 103.51 MPa, which is promising than that of most of the fibers experienced in earlier as Sansevieria cyclindrica (75.75 MPa, 30 mm/40 wt.%), Tamarind fruit fiber (77.4 MPa, 50 mm/40 wt.%), red banana peduncle fiber (11.61 MPa, 300–400 mm), Cissus quadrangularis stem (90.20 MPa, 40 mm/30 wt.%), Cymbopogon flexuosus stem (84.77 MPa, 40 mm/30 wt.%), Coconut coir fiber (13.05 MPa, 30 mm/30 wt.%), Calotropis procera (11.43 MPa, 30 mm/30 wt.%), and jute fibers (75.15 MPa, 30 mm/40 wt.%) (Table 1). Moreover, it is noted that tensile strength increased as fiber length and weight % increases up to 30 mm/30 wt.%, since the polyester matrix transmits and distributes the maximum applied stress to the fibers. Beyond the optimum range, the fiber curls are inadequate to disseminate the polyester resin within the fiber [22]. Thus, 30 mm fiber length with a 30% fiber weight percentage gives the optimum bonding between the FSPF and polyester matrix. The same trend is reflected in case of tensile modulus, where the optimum modulus of 2.35 Gpa was attained at 30 mm fiber length and 30 wt.% fiber loading rate. The FSPF polymer composite was significant that that of Sansevieria cyclindrica (1.10 GPa), Tamarind fruit fiber (1.4 GPa), Cymbopogon flexuosus stem (1.31 GPa), Coconut coir fiber (2.06 GPa), and jute fiber (0.638 GPa) in terms of their tensile modulus. Whereas, beyond this level, a decreasing trend was observed due to matrix/fiber incompatibility and inadequate interfacial bonding in fact of improper fiber length and loading ratio [9].Figure 2
Effect of fiber length and weight percentage on (a) tensile strength and (b) tensile modulus.
(a)(b)


## 3.2. Flexural Properties of FSPFC

Flexural strength and modulus of FSPFC obtained with different fiber contents are demonstrated in Figures3(a) and 3(b). Flexural strength has a similar drift as like tensile strength and beyond the optimum content the properties dropped. With 30 wt. % and 40 mm fiber length, the maximum flexural strength of 144.62 MPa and flexural modulus of 2.93 GPa were obtained. This might be due to the homogeneous distribution of the FSPF/polyester matrix and improved fiber matrix interaction developed during bending by the optimum fiber content of the composite. A reduced trend is found with other fiber concentrations that might be due to curling of the fiber beyond 30 mm/30 wt.%, which reduces flexural properties. The obtained flexural strength and was promising than that of Acacia concinna fiber (112.31 ± 4.1 MPa. 40 mm/30 wt.%), Sansevieria cyclindrica (84 MPa), Tamarind fruit fiber (88.5 MPa), red banana peduncle fiber (2 MPa), Cissus quadrangularis stem (103.04 MPa), Cymbopogon flexuosus stem (93.53 MPa), Coconut coir fiber (35.45 MPa), Calotropis procera (26.38 MPa), and jute fiber (124.01 MPa) [9, 20]. The flexural modulus of the respective composite was higher than the earlier reported fibers as Cymbopogon flexuosus stem, Tamarind fruit fiber, Cissus quadrangularis stem, and jute fiber. The obtained flexural properties can be corelated with the results of tensile properties in terms of fiber dimensions, which shows the necessity of optimization for absolute composite formulation.Figure 3
Effect of fiber length and weight percentage on (a) flexural strength and (b) flexural modulus.
(a)(b)


## 3.3. Impact Properties of FSPFC

Impact resistance refers to the ability of a material to resist under sudden stress conditions [23]. The toughness behavior of the composite was assessed using varied fiber lengths and loading rates and the results indicated that the impact strength rises linearly up to 30 wt.%/30 mm (10.8 ± 0.31 J/cm2) reinforcement owing to efficient stress transmission between the fiber and matrix with good fiber distribution (Figure 4). Beyond this concentration, there is a decline in impact strength that might be due to the increased fiber-to-fiber contact owing to increased loading or fiber breaking happens inside the composite. Moreover, the proposed plant fiber-polymer composite showed the maximum impact strength in course of all other fibers as presented in Table 1. Although, the composite possess better interfacial bonding as the composite absorbs a higher energy during the impact fracture.Figure 4
Effect of fiber length and weight percentage on the impact strength.


## 3.4. Hardness

The hardness qualities of the composite were examined to determine its resistance to scratches and abrasion. Figure5 depicts the influence of hardness on altering fiber weight and length ratio. A relatively good hardness value of 92 HRRW was allied with 30 wt.% and 40 mm length, while the cured resin's hardness is 90 HRRW. The hardness of a material is mainly influenced by the characteristics of the matrix and intermolecular bonding of the material with the matrix [8]. The enhanced hardness value obtained in this study was attributed to the matrix's homogeneous distribution [24].Figure 5
Effect of fiber length and weight percentage on Rockwell hardness.


## 3.5. Thermal Properties

The TG-DTG test was used to assess the thermal stability of the prepared fiber and the resultant deterioration patterns are evident in Figure6. The degradation of polyester was started at 360°C and for FSPF optimal composite degradation, it starts around 340°C; whilst, the complete decomposition for polyester has occurred at 495°C but for novel composite, it occurs around 390°C due to the natural fiber reinforcement, which is denoted by a sudden dip in the TG curve. This degradation temperature is reasonably higher than the thermal stability of most of the raw fibers and sufficient for composite manufacturing. Moreover, the thermal stability established for raw and treated composites were significant to withstand high temperature required applications [24, 25].Figure 6
TG and DTG curves of the polyester and FSPF/polyester (30 mm length and 30wt.% fiber) composite.


## 3.6. Water Absorption Property

Water absorption analysis was sufficient to examine the degradability of composites in aquatic environment. Figure7 signifies the effects of water on the polyester resin sample and FSPFC with five distinct fiber concentrations. This analysis revealed that there was an increase in water absorption observed from 10–50 wt.% except 30 wt.%, which might be due to the increased fiber weight fractions of the composites since polyester resin showed relatively lesser water absorption rate (7.25%). However, the optimal sample with 30 wt.% showed reduced water absorption (7.48%) than other weight percentages (7.6–8.5%). In fact, proper matrix-fiber adhesion and less microvoids are present in the optimal sample in contrast to other samples, which allows good interfacial bonding with the matrix by penetrating to lumen and reduces water absorption capacity [26, 27].Figure 7
Effect of fiber length and weight percentage on water absorption.


## 3.7. Fractography of FSPFC

Fractography of the FSPFC built-in with 30 mm/30 wt.% fiber content is presented in Figures8(a) and 8(b). This study was ideal to examine the morphological features of the composite’s fractured surface. It is clearly observed from the figures that the finest interlocking between fiber and matrix by the fact that the matrix is thoroughly infiltrated into fiber voids. The optimal composite fractography observed minimal fiber pull-out. More rough and uneven surface morphology of the fiber owing to the high interfacial strength leads to poor stress transfer, since a crack is initiated from the matrix followed by the fiber breakage occurred. Moreover, few voids remain unfilled in the matrix due to the limitation of the interface between the fibers and the matrix during manufacturing [12].Figure 8
SEM micrograph of tensile fractured specimen with 30 mm fiber length and 30 wt.% fiber content composites.


## 4. Conclusion

Fiber content has an important impact on the overall performance of a composite system; hence, the effect of different fiber content on the performance of specific FSPF reinforced polyester composites was tested. The optimum composite properties were analyzed by studying tensile strength, flexural strength, impact strength, hardness, and water uptake properties. Among the varied fiber length (10 mm, 20 mm, 30 mm, 40 mm, and 50 mm) and weight percentage (10%, 20%, 30%, 40%, and 50%) tested, the specific composite had its maximum stability with an ideal length of 30 mm and 30% weight percentage. The thermal analysis indicated that the composite material possesses good thermal stability and reduced water absorption property validated its usage in aquatic environments. The matrix and fibers in the optimal reinforcement were found to be well-bonded microstructurally, as evidenced by SEM analysis. Therefore, the present study suggested that the optimal FSPF reinforced polyester composite would be a promising alternative to conventional materials for the production of value-added products for the time being.



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*Source: 8099500-2022-05-10.xml*