# Double Compressions of Atmospheric Depth by Geopotential Tendency, Vorticity, and Atmospheric Boundary Layer Affected Abrupt High Particulate Matter Concentrations at a Coastal City for a Yellow Dust Period in October

Authors: Hyo Choi; Mi Sook Lee
Journal: Advances in Meteorology
 (2014)

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## Abstract

Using GRIMM-aerosol sampler, NOAA-HYSPLIT model, and 3D-WRF-3.3 model, the transportation of dusts from Gobi Desert toward Gangneung city, Korea was investigated from 09:00 LST October 27 to 04:00 LST October 28, 2003. Maximum PM10 (PM2.5, PM1) concentration was detected with 3.8 (3.4, 14.1) times higher magnitude than one in non-Yellow Dust period. The combination of dusts transported from the desert under westerly wind with particulate matters and gases from vehicles on the road of the city caused high PM concentrations near the ground surface at 09:00 LST and their maxima at 17:00 LST near sunset with further pollutants from heating boilers in the resident area. Positive geopotential tendency at the 500 hPa level of the city (∂Φ/∂
t; m day−1) corresponding to negative vorticity of -
4
×
10
-
5 sec−1 (-
2.5
×
10
-
5 sec−1) at 0900 LST (21:00 LST; at night) was +83 m day−1 (+30 m day−1) and it caused atmospheric depth between 500 hPa level and the ground surface to be vertically expanded. However, its net reduction to −53 m/12 hrs until 21:00 LST indicated synoptic-scale atmospheric layer to be vertical shrunken, resulting in the increase of PM concentrations at 17:00 LST. Simultaneously, much shallower microscale stable nocturnal surface inversion layer (NSIL) than daytime thermal internal boundary layer induced particulate matters to be merged inside the NSIL, resulting in maximum PM concentrations at 17:00 LST.


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## Body

## 1. Introduction

In dry spring, air quality in the Korean eastern coastal region was greatly affected by huge amounts of dusts transported from the elevated ground of 1500 m above sea level of Taklamakan, Gobi, and Ordos Deserts and Loess plateau in Nei-Mongo in the northern China. In recent years, Yellow Dust Storm with various names of Yellow Sand Storm, Asian Dust Storm, and KOSA has been detected in even autumn and winter, showing a relatively lower concentration of particulate matters than one in spring [1–6]. The most concentrated region of Yellow Dust Storm has been known as northwest China, which included five provinces of Xinjiang, Inner-Mongolia (Nei-Mongo), Ningxi, Shanxi, and Gansu [7].Zhang and Zhong [8] and Choi and Zhang [9] indicated that the regions of dust storm occurring more than 30 days per year coincide with those regions with both relative humidity of air less than 40% as the representation of the surface water content of the soil layer and surface wind speed greater than 10 m s−1. Tegen and Fung [10] explained that, among the total quantity of dust particulates generated from the deserts, its 30% is deposited near the source area and the 20% is redistributed on a local scale and the other half of them are expected to be subject to their long-range transports. The estimation of dust loading controlled by wind velocity has mainly been used, considering size distribution of soil particles and surface roughness in terms of friction velocity. Thus, the dust generated in Gobi Desert and Nei-Mongo in the northern China is to serve as one of the major particulate matter sources all across the Asia and Pacific and it makes a great contribution to low visibility and air quality in spring in northern Asian countries and even USA [11–15].Kim et al. [16] showed that, during a Yellow Dust period in China, dusts generated from Gobi Desert were transported toward Seoul in the central region of Korea. Lee and Chung [17] also explained that a great amount of dusts from Gobi Desert were transported toward the Korean eastern mountainous coast, and the transported dusts from the desert usually included great amounts of particulate matters of not only coarse PM mode, but also fine one with various gases. Then, the transported dusts were combined with particulate matter and gases emitted from the downwind Korean cities, resulting in very high PM and gases concentrations with apparent temporal variations.In the Yellow Dust researches, meteorological approach was usually focused on the beginning stage of the generation of dust storm and weather conditions for the formation of the dust storm, considering synoptic weather situation1 [18]. When most of modelers perform the transport model, they have usually treated atmospheric boundary layer to be constant, even actually not constant, assuming 1.5 km or 2 km height above the ground surface. However, Choi and Zhang [9] insisted that the transportation of dusts from Gobi Desert toward the far downwind area like Korean peninsula is initially greatly affected by synoptic- and mesoscale wind fields. Choi and Speer [19], Choi and Choi [20], and Choi et al. [21, 22] further insisted the effects of variability of atmospheric boundary layer depth during the day and night on high concentrations of locally emitted particulate matters combined with dusts from the north China. Owing to no much considering those subjects in the transport model of dusts, the occurrence of abrupt high concentrations of dust particles in the downwind local area have been still obscured so far.In recent, Choi [23] showed the trapping effect of a calm zone by lee side-internal gravity waves and cyclonic winds on sudden high concentrations of particulate matters combined with the Yellow Dusts from Gobi Desert in the Korean eastern coast. Differently, Uzan and Alpert [24] explained that the highest air pollution events such as SO2 and NOx concentrations (not particulate matter) from Israel’s largest coal-fired power plant occurred during summer at 12:00~15:00 h through the average coincident drop of the boundary layer height down to 450 m above the ground. Even though they did not consider the transportation of gases from other city into the research area, the research result indicated that pollutant concentration should be directly affected by the depth of atmospheric boundary layer.Precisely understanding the evolution of atmospheric boundary layer is also one of the most important aspects for the horizontal transportation of the dust and its sudden high concentration in the far downwind area like Korea, considering synoptic and mesoscale motions of atmosphere. Choi and Lee [25] made primary research on abrupt high PM concentration during the dust period in October, 2003, considering shrunken atmospheric boundary layer, but they did not explain dynamically any relation of synoptic-scale atmospheric shrunken process with diurnal variations of atmospheric boundary layer. The purpose of this study is to explain the effects of double compression of not only synoptic-scale atmospheric layer varied by geopotential tendency and vorticity at 500 hPa level, but also microscale atmospheric boundary layer on the occurrence of abrupt high particulate matter concentration in the mountainous coastal region of Korea, during a Fall Yellow Dust period.


## 2. Study Area

Figure1 indicates Northeastern Asia including the study area near Gangneung city (37°45′N, 128°54′E; 20 m height above Mean Sea Level) in the Korean eastern coastal region. Gangneung city consists of high mountains in the west of the city, coastal basin in its center, and sea in its east and its population is about 230,000 with no special industries.Figure 1
Topography of the northeastern Asia including Gangneung city (37°45′N, 128°54′E) with the establishment of a GRIMM aerosol sampler. Large and small squares in the center indicate the first domain with a 27 km grid interval on 91 × 91 horizontal grids and the third domain with a 3 km by three-nesting techniques in the WRF model simulation. A square in the left and a circle in the center denote Gobi Desert and Gangneung city equipped with an aerosol sampler, respectively.The city has the characteristics of continental and marine climates due to its location between mountains and sea. Particularly, fall season is short, and weather in winter is mild due to the passage of the East Korea Warm Current (EKWC; branch currents of Kuroshio Warm Current) bounding for north along the eastern coast of Korean peninsula. As it is a clean coastal city without special industries, air pollution sources are mainly vehicles of about 50,000 on the road, flying dusts from the road, and heating boilers in the resident area and the city has typical urban characteristics. In Spring, air quality is greatly affected by the dust particles transported from the northern China, especially Gobi Desert and Nei-mongo (Inner Mongolia) such as arid area in China and Mongolia.


## 3. Aerosol Measurement and Numerical Model

### 3.1. Measurement of Aerosol

GRIMM-1107 aerosol sampler was equipped at Gangwon Regional Meteorological Administration (20 m height above Mean Sea Level) in the downtown of Gangneung city adjacent to the East Sea of Korea on October 26~29, 2003, under air quality at Gangneung city to be greatly affected by dusts transported from Gobi Desert. GRIMM-1107 aerosol sampler is characterized as a portable particle analyzer measuring particulates of 0.3~20μm by way of laser-light scattering, with a monitor on particulate matter concentrations (PM—PM10, PM2.5, and PM1) to offer dual technology consisting of both optical and gravimetrical analysis.After air of various particle sizes passes through a flat laser beam produced by a precisely focused laser and several collimator lenses, the scattered light is detected by a 15-channel, pulse-height analyzer for size classification at every 5 seconds and then the counts from each size classification are directly converted to mass by an established equation to be specifically designed for PM10, PM2.5, and PM1 ambient air analysis [22]. PM10, PM2.5, and PM1 are presented on the monitor and stored in a data log with every 10-minute averaged PM concentrations and total counts of different sizes.


### 3.2. Numerical Model and Input Data

For the numerical simulation of the generation of meteorological phenomena, Weather Research & Forecasting Model (WRF) version 3.3—a three-dimensional, nonhydrostatical grid point model with a terrain following coordinate system—was adopted on the route of dust transportation from China to Gangneung city in the eastern coast of Korea from 00:00 UTC (Local Standard Time (LST) = 9 h + UTC (Coordinated Universal Time); 09:00 LST in Korea), October 27 through 00:00 UTC, October 29, 2003. In the numerical simulation, one way-triple nesting process from a coarse-mesh domain to a fine-mesh domain was performed using a horizontal grid spacing of 27 km covering a 91 × 91 grid square in the largest domain. The second and third domains also consist of the same grid square of 91 × 91 with 9 km and 3 km horizontal grid intervals, respectively [20].National Centers for Environmental Prediction/National Center for Atmospheric Research (NCEP/NCAR) reanalysis-Final Analyses (FNL) 1.0°  ×  1.0° resolution data were used as meteorological input data of WRF model and the data were vertically interpolated onto 36 levels with sequentially larger intervals increasing with height from the surface to the upper boundary level of 100 hPa [20]. Among various parameterization schemes of WRF model, WSM 6 scheme was used for microphysical processes for the heat and moist budgets in the atmospheric boundary layer, and the YSU PBL scheme for the planetary boundary layer. Furthermore, the Kain-Fritsch (new Eta) for cumulus parameterization, the five thermal diffusion model for land surface, and the RRTM long wave radiation scheme and Dudhia short wave radiation schemes were also used. Input terrain data with a horizontal resolution of 1° (about 110 km) were used for the first-largest domain, and 1 km horizontal resolution data were for the second and third domains [23].Horizontal wind, air temperature, and 500 hPa height change for 24 hours (i.e., geopotential tendency (∂Φ/∂
t); m/day), relative vorticity (×10−1 sec−1) were evaluated in northeastern Asia and further both horizontal and vertical profiles of wind, air temperature, potential temperature, and potential vorticity for investigating the development of atmospheric boundary layer near Gangneung city of the Korea, sequentially in the three-mesh domains in the WRF model. For the verification of numerical results of the meteorological elements, wind, air temperature, and relative humidity by Gangwon Regional Meteorological Administration were used.


## 3.1. Measurement of Aerosol

GRIMM-1107 aerosol sampler was equipped at Gangwon Regional Meteorological Administration (20 m height above Mean Sea Level) in the downtown of Gangneung city adjacent to the East Sea of Korea on October 26~29, 2003, under air quality at Gangneung city to be greatly affected by dusts transported from Gobi Desert. GRIMM-1107 aerosol sampler is characterized as a portable particle analyzer measuring particulates of 0.3~20μm by way of laser-light scattering, with a monitor on particulate matter concentrations (PM—PM10, PM2.5, and PM1) to offer dual technology consisting of both optical and gravimetrical analysis.After air of various particle sizes passes through a flat laser beam produced by a precisely focused laser and several collimator lenses, the scattered light is detected by a 15-channel, pulse-height analyzer for size classification at every 5 seconds and then the counts from each size classification are directly converted to mass by an established equation to be specifically designed for PM10, PM2.5, and PM1 ambient air analysis [22]. PM10, PM2.5, and PM1 are presented on the monitor and stored in a data log with every 10-minute averaged PM concentrations and total counts of different sizes.


## 3.2. Numerical Model and Input Data

For the numerical simulation of the generation of meteorological phenomena, Weather Research & Forecasting Model (WRF) version 3.3—a three-dimensional, nonhydrostatical grid point model with a terrain following coordinate system—was adopted on the route of dust transportation from China to Gangneung city in the eastern coast of Korea from 00:00 UTC (Local Standard Time (LST) = 9 h + UTC (Coordinated Universal Time); 09:00 LST in Korea), October 27 through 00:00 UTC, October 29, 2003. In the numerical simulation, one way-triple nesting process from a coarse-mesh domain to a fine-mesh domain was performed using a horizontal grid spacing of 27 km covering a 91 × 91 grid square in the largest domain. The second and third domains also consist of the same grid square of 91 × 91 with 9 km and 3 km horizontal grid intervals, respectively [20].National Centers for Environmental Prediction/National Center for Atmospheric Research (NCEP/NCAR) reanalysis-Final Analyses (FNL) 1.0°  ×  1.0° resolution data were used as meteorological input data of WRF model and the data were vertically interpolated onto 36 levels with sequentially larger intervals increasing with height from the surface to the upper boundary level of 100 hPa [20]. Among various parameterization schemes of WRF model, WSM 6 scheme was used for microphysical processes for the heat and moist budgets in the atmospheric boundary layer, and the YSU PBL scheme for the planetary boundary layer. Furthermore, the Kain-Fritsch (new Eta) for cumulus parameterization, the five thermal diffusion model for land surface, and the RRTM long wave radiation scheme and Dudhia short wave radiation schemes were also used. Input terrain data with a horizontal resolution of 1° (about 110 km) were used for the first-largest domain, and 1 km horizontal resolution data were for the second and third domains [23].Horizontal wind, air temperature, and 500 hPa height change for 24 hours (i.e., geopotential tendency (∂Φ/∂
t); m/day), relative vorticity (×10−1 sec−1) were evaluated in northeastern Asia and further both horizontal and vertical profiles of wind, air temperature, potential temperature, and potential vorticity for investigating the development of atmospheric boundary layer near Gangneung city of the Korea, sequentially in the three-mesh domains in the WRF model. For the verification of numerical results of the meteorological elements, wind, air temperature, and relative humidity by Gangwon Regional Meteorological Administration were used.


## 4. Result and Discussion

### 4.1. Aerosol Concentration during a Non-Yellow Sand Period

Figure2 indicates hourly distribution of PM1, PM2.5, and PM10 concentrations at Gangneung city with no special industry in the eastern mountainous coast of Korea from 00:00 LST (09:00 LST), October 26 to 18:00 LST, October 29, 2003. Its main air pollution sources to affect local PM concentrations are vehicles on the road and heating boilers in the resident area. As air temperature of Gangneung city is in the range of 10~15°C for daytime hours in the late October and is lower than about 10°C at night, heating boilers in the resident area are put into operation for a few hours around sunset and sunrise. This operation can partially affect the increase of particulate matter and gases such as CO and NOx concentrations.Figure 2
Hourly distributions of PM10, PM2.5, and PM1 concentrations at Gangwon Meteorological Administration in the downtown of Gangneung city, Korea from October 26~29, 2003.A low pressure system of 999 hPa was located in the northern border of Mongolia and a high pressure system of 1021 hPa in the East Sea of Korea on weather map supplied by Korea Meteorological Administration (KMA) at 09:00 LST, October 26 (Figure3(a)). The pressure patterns produced northwesterly wind near Gobi Desert and the wind could blow dusts generated by Gobi Desert toward Manchuria in the north-eastern China. Under this situation, the dusts could not be transported toward Gangneung city in the eastern coast of the Korean peninsula (triangle).Surface weather maps at (a) 09:00 LST (00:00 UTC), October 26, 2003, and (b) 21:00 LST (12:00 UTC), supplied by KMA [26]. Square and thick line in (a) and (b) indicate Gobi Desert extending from the southern Mongolia to the northern China and cold front. Northwesterly wind in the left of cold front and southwesterly wind in the right of the front produced a main stream of dust particles originated from Gobi Desert toward Liaoning province in the northeastern China, which is far away from Gangneung city.
(a)
(b)As weather map or wind fields generated by a meteorological numerical model just show flow patterns of air particles at a certain height and at a given time of a special day. Thus, if we want to know the flow patterns of air particles continuously at different heights, we use many numbers of weather maps or simulated wind fields by a model at every 3 or 6 hours intervals for several days. On the other hand, particle trajectory using NOAA-HYSPIT model, which consists of meteorological model for wind field and Lagrangian random walk model on particle diffusion and dispersion, can supply the moving paths of air particles and their positions with different flowing heights at every 6 hours for several days, continuously. Thus, the position of air particle at a certain time on the moving trajectory of air for several days should be exactly the same as flow pattern of air at a given time weather map of a special day or wind field by a numerical model at a certain height. However, it is very difficult to chase the track of air particle on the weather map. Thus, we commonly use backward trajectory of air particle by NOAA-HYSPLIT model, which focuses only main stream of the majority of particles, not showing diffusion and dispersion of whole particles. Choi and Speer [19] described that the trajectories of whole particles in the wide area of different height such as in Seoul city and Korean eastern coast could be shown using Lagrangian Random Walk Model combined with meteorological model, but if we want to know the main stream of particles, not considering whole particles, HYSPLIT model is strongly recommended. In general, to investigate flow pattern of air in the wide area, it is necessary to review weather maps and horizontal wind fields generated by a meteorological numerical model.For depicting backward trajectories of dust particles with time, NOAA HYSPLIT model (hybrid single particle Lagrangian integrated trajectory) from the Air Resources Laboratory (ARL) using FNL meteorological data was adopted and the heights of dust particle trajectories were set up at 2000 m, 1000 m, and 500 m, respectively (Figure4). This model showed very detailed information on temporal transportation routes of dust particles for several days and their flowing height and spreading area. Weather map or wind fields generated by a meteorological model just show flow patterns of air at a given time, but particle trajectory using NOAA HYSPIT model supplies the moving path of particle and its position at every 6 hours for several days, continuously. Thus, this moving trajectory for several days is different from a given time weather map or wind field given by a numerical model. Unfortunately some environmental scientists misunderstand their differences. Thus, back trajectories with a time step of 6 hours over a period of 72 or 96 hours using the HYSPLIT model were depicted at 500 m, 1000 m, and 2000 m above ground level in order to detect possible links between diurnal variation of PM concentrations and pathway of dust particles transported from Gobi Desert and Nei-Mongo (Inner Mongo) in the northern China toward a Korean eastern coastal city.Backward trajectories of air masses at 2000 m, 1000 m, and 500 m heights by NOAA HYSPLIT model ending at (a) 09:00 LST (00:00 UTC), October 26, 2003 and (b) 21:00 LST (12:00 UTC). Clean air masses from above 2 km height of the north-eastern Mongolia flew toward Gangneung city at each level in (a) and ones from above 3 km height outside Gobi Desert (Nei-Mongo in the northeastern China) reached 1000 m and 2000 m heights of the city, without dust transportation to the city in (b). As weather map or wind fields generated by a meteorological numerical model just show flow patterns of air at a certain height and at a given time of a special day, but particle trajectory using NOAA-HYSPIT model supplies the moving path (main stream) of majority of air particle and its position at every 6 hours for several days, continuously.
(a)
(b)At 09:00 LST (00:00 UTC), October 26, clean air masses originated from over 2 km height in the north-eastern Mongolia far away from Gobi Desert reached Gangneung city at 500 m, 1000 m, and 2000 m heights and the city was under no influence of dusts in Gobi Desert (Figure4(a)). At 21:00 LST, the previous low pressure system moved toward the east and stretched toward the south-eastern China with pressure centers of 1000 hPa, 1002 hPa, and 1007 hPa, respectively (Figure 3(b)). A high pressure system of 1026 hPa was located in the northern Mongolia, but Gobi Desert was still under the influence of the low pressure system.The pressure patterns over Mongolia, China, and Korea caused northwesterly wind near Gobi Desert in the left of cold front and southwesterly in the right. Dusts driven by those winds should pass by Manchuria of the north-eastern China in the north of the Korean peninsula, resulting in no influence of dust transportation from China to Gangneung city of Korea (triangle). Figure4(b) showed that, on backward trajectory, relatively clean air particles from above 3 km height of Gobi Desert reached 1000 m and 200 m heights of the Korean city at 21:00 LST, October 26, but it was very difficult to expect dust transportation from Gobi Desert to the city. Nontransportation of dust from Gobi Desert and the northern China toward the city continued to be until 08:00 LST, October 27 in Figure 2.In Figure2, on October 26, especially before 09:00 LST October 27, under no intrusion of dust from Gobi Desert or Nei-Mongo (Inner Mongolia) in the northern China toward the city (non-Yellow Dust period), PM1, PM2.5, and PM10 concentrations near the ground surface of Gangneung city were generally very low, more or less than 20 μg m−3, 10 μg m−3, and 5 μg m−3, except for PM10 of 69.87 μg m−3 at 18:00 LST, October 26, respectively. High PM10, PM2.5, and PM1 concentrations were detected at 09:00 LST at the beginning time of office and 18:00 LST at the ending time of office hour, due to high density of traffic vehicles on the road at both times. Particularly maximum PM concentrations at 18:00 LST rather than 09:00 LST were shown due to additionally nighttime more operating of heating boilers in the resident area of the city, shortly after sunset. This hourly PM concentration showed a typical urban type-high PM concentrations around 09:00 LST in the morning and 18:00 LST near the sunset.


### 4.2. Aerosol Concentration during a Yellow Sand Event Period

During the intrusion of dust transported from Gobi Desert of the northern China toward the city from 09:00 LST October 27~04:00 LST, October 28 (Yellow Dust period), PM10 concentration was in the range of 48.20~154.57 μg m−3 and its maximum concentration was 3.8 times higher than the maximum concentration of nondust period.Similarly, PM2.5 (PM1) concentration was in the range of 26.92~93.19 μg m−3 (19.63~76.05 μg m−3) with a maximum concentration of 3.4 (14.1) times higher than one of nondust period and their hourly variations of PM concentrations were similar each other (Figure 2). High PM10 (PM2.5 and PM1) concentration was detected with 60.59 μg m−3 (26.92 μg m−3, 19.63 μg m−3) at 09:00 LST, October 27 (the beginning time of office hour), when a high traffic density on the road took place. PM concentration after 09:00 LST had a rapid increasing trend until 17:00 LST.As shown in surface weather maps of Figure5(a), one can expect that dusts generated in Gobi Desert in the northern China could be transported following isobaric lines of a high pressure, showing arrow movement of air masses in the figure. As shown in surface winds simulated by WRF-3.3 model, strong northerly surface wind in the north of China and southwesterly in the south prevailed (Figures 6(a) and 6(c)). In general, dusts generated from dried soil of the desert ground could be uplift to about 3 km height over the ground surface due to strong surface wind and daytime thermal convection [7], and then they moved eastward below the lower level than 3 km height.As shown in Figure3, except for (a) 09:00 LST (00:00 UTC), (b) 15:00 LST (06:00 UTC), (c) 21:00 LST (12:00 UTC), October 27, 2003, and (d) 03:00 LST (18:00 UTC), October 28. Dust particles originated from Gobi Desert move toward eastern Nei-Mongo, Manchuria, and northern Korea with their flowing southwestward in the left of cold front and northeastward in the right of the front, as the front moves toward the Korean peninsula, sequentially with time.
(a)
(b)
(c)
(d)(a) Moisture flux (m/s) at 850 hPa level (about 1.5 km height) supplied by KMA [26] and (b) surface wind (m/s) simulated by WRF model at 09:00 LST, October 27, 2003, and (c) and (d) are at 17:00LST (a maximum PM concentration), respectively. Small square and triangle in (a) and (c) denote Gobi Desert and Gangneung city (Korea). Small square in (b) and (d) denotes the vicinity of Gangneung (the 3rd domain of WRF model) at 09:00 LST, October 27, 2003 and 17:00 LST (occurrence time of maximum PM concentration). D and big arrow denote the eastern part of Gobi Desert in the northwest of Nei-Mongo and a dust transportation route. In (a), (b), (c), and (d), dust particles originated from Gobi Desert moved toward Nei-Mongo under westerly wind at both the surface and 1.5 km height and then, followed northerly and northwesterly toward the Chinese eastern coast and the Yellow Sea, further moving toward the northern Korea and Gangneung city.
(a)
(b)
(c)
(d)Figure6(a) at 09:00 LST, October 27, and Figure 6(c) at 17:00 LST of the occurrence time of a maximum PM concentration indicate transportation routes of moisture fluxes at about 1.5 km height (850 hPa level) in Mongolia, China, Korea, and Japan, which well show the movement of air parcel with water vapor. From these figures, it is very easy to find the transportation route of dust particles combining with air, water vapor, and dust. In Figures 6(a), 6(b), 6(c), and 6(d), dust particles originated from Gobi Desert moved toward Nei-Mongo under westerly wind at both the surface and 1.5 km height and then followed northerly and northwesterly toward the Chinese eastern coast and the Yellow Sea, further moving toward the northern Korea and Gangeung city.In Figure7(a), backward trajectories of dust particles generated in Gobi Desert at 09:00 LST (00:00 UTC) on October 25 flew from about 3 km height of the desert toward Gangneung city in the Korean east coast and reached 1000 m and 2000 m levels of the city at 09:00 LST (00:00 UTC), October 27 after three days. The dusts passed by about 2~3 km heights of Nei-Mongo in the northern China could reach the city at 1000 m and 500 m heights. Thus, dusts transported from Nei-Mongo could directly make a contribution to the increase of PM concentrations in the city as shown in Figure 2. At 21:00 LST (4 hours after the occurrence of maximum PM concentration), a high pressure system of 1025 hPa was located in the eastern Mongolia and a low pressure system of 1006 hPa was in the northeastern China (Figure 5(b)).Backward trajectories of air masses by NOAA HYSPLIT model ending at (a) 09:00 LST (00:00 UTC), October 27, 2003, (b) 17:00 LST (08:00 UTC; a maximum PM concentration), (c) 03:00 LST (18:00 UTC), October 28, and (d) 09:00 LST (00:00 UTC), respectively.
(a)
(b)
(c)
(d)As the previous high and low pressure systems moved toward the east, cold front passed by the northern part of Korean peninsula and stretched toward Manchuria in the north-eastern China. This kind of pressure pattern over Mongolia, China, and Korea caused northerly wind near Gobi Desert and southwesterly wind in the southern China (Figures6(b) and 6(d)). Southwesterly wind still prevailed through the Korean peninsula including the study area. Thus, dusts generated from Gobi Desert might pass by the eastern Mongolia-Nei-Mongo-southeastern China and finally reached the Korean eastern coastal city, sequentially. As a result, dusts transported from both Gobi Desert and Nei-Mongo could make a great contribution to the increase of local PM concentration in the city.In Figure7(b), as dust particles passed by 3 km height of Gobi Desert and 2000 m height of Nei-Mongo flew toward the Korean east coast and reached 2000~500 m heights in the city at 17:00 LST, October 27, when a maximum PM concentration took place. Thus, huge amounts of dusts generated from both Gobi Desert and Nei-Mongo could be transported to the city and made a great contribution to the increases of PM10, PM2.5, and PM1 concentration near the ground surface of the city. Similar patterns of backward particle trajectories could continuously exist until 03:00 LST, October 28 (Figure 7(c)). After 03:00 LST until 09:00 LST, October 28, dust transportation from Gobi Desert toward the Korean coastal city was very difficult as shown in Figure 7(d). Even though some amounts of dusts from not Gobi Desert, but Nei-Mongo (outside a box in the figure), passed by the southern China and the Yellow Sea and finally reached the Korean eastern coast, the transported dusts should be not much and local PM concentrations could be under little influence of the dusts.


### 4.3. Effect of Synoptic-Scale Geopotential Tendency Corresponding to Vorticity on High PM Concentration

Vorticity equation can be derived using horizontal momentum equations. It can be obtained by differentiating thex component equation of momentum with respect to y and the y component equation with respect to x and then subtraction of former differential equation from later differential equation ζ
=
∂
v
/
∂
x
-
∂
u
/
∂
y [27].Vorticity equation has a great advantage in order to investigate upward or downward of motion of air. Downward motion of air occurs in positive vorticity area at 500 hPa level (approximately 5.5 km height) and oppositely upward motion in negative vorticity area. Opposite to the 500 hPa level, downward motion of air near the ground surface (approximately 1,000 hPa level) occurs in negative vorticity area and vice versa. Holton [27], Sanders and Gyakum [29], and Reed and Albright [30] explained that the region of positive relative vorticity (ζ; ×10−5 sec−1) at the 500 hPa level causing convergence of air parcel and sequentially its downward motion toward the ground surface matches the region of the negative geopotential tendency (−∂Φ/∂
t; m day−1) at the 500 hPa level. Atmospheric depth in the negative geopotential tendency area should be reduced and vertically shrunken (Figure 8). On the other hand, the region of negative relative vorticity (-
ζ) inducing divergence of air parcel at the 500 hPa level and its upward motion from the ground surface toward the 500 hPa level matches the region of the positive geopotential tendency, (+∂Φ/∂
t; m day−1) with vertical expansion of atmospheric depth of 500 hPa level.Figure 8
Schematic profile of geopotential height change with time (geopotential tendency (∂Φ/∂
t); m day−1) at 500 hPa level (approximately 5.5 km height) and atmospheric boundary layer (ABL), modified from Choi et al. [28]. Negative geopotential tendency (∂Φ/∂
t) means the decrease of geopotential height for 24 hours (i.e., shrunken atmospheric layer) and vice versa. Positive vorticity (+
ζ
=
∂
v
/
∂
x
-
∂
u
/
∂
y) at the 500 hPa level, which implies the downward motion of air toward the ground corresponds to negative geopotential tendency area and vice versa.For applying geopotential tendency theory, we used every 6-hour weather maps of geopotential height at 500 hPa level supplied by Korea Meteorological Administration (KMA). At 09:00 LST, October 27, when huge amounts of dusts from Gobi Desert and Nei-Mongo began to make a contribution to the increase of PM concentrations at Gangneung city, geopotential tendency at 500 hPa level for a day in the city was +80 m day−1 (Figure 9(a)). The positive value of +83 m day−1 implies that atmospheric depth of 500 hPa level to the ground surface should be vertically expanded to more 83 m day−1 than one day before. On the other hand, the tendency at 21:00 LST was changed into +30 m day−1, which implied still the expansion of 500 hPa level to be up to 30 m day−1 for 24 hours (Figure 9(b)). Thus, the net variation of geopotential tendency between 09:00 LST and 21:00 LST for 12 hours could be reduced to −53 m, resulting in atmospheric depth to be shrunken. Similarly to the case of 21:00 LST, synoptic-scale shrunken atmospheric layer of 100 m could force nocturnal surface inversion layer in the city to be further more shrunken at night. Thus, resultantly much more shrunken nocturnal surface inversion layer might cause a maximum PM10 concentration as well as PM2.5 and PM1 in the coastal city at 17:00 LST.Geopotential tendency (∂Φ/∂
t; m day−1) at 500 hPa level at (a) 09:00 LST October 27, 2003, and (b) 21:00 LST. Triangle indicates Gangneung city. Shadow (white) area indicates negative (positive) geopotential tendency, which implies the shrunken (expansion) rate of geopotential height change at 500 hPa level for a day. As a positive tendency at 09:00 LST (21:00 LST) in Gangneung city was +83 m day−1 (+30 m day−1), the net one of −53 m for 12 hours implies a 53 m-shrunken atmospheric depth at 21:00 LST, causing a maximum PM10 at 17:00 LST.
(a)
(b)Figures10(a) and 10(b) indicate vorticity (×10−5 sec−1) at 500 hPa level at 09:00 LST October 27, 2003, and 21:00 LST, respectively. At 0900 LST October 27, Gangneung city was in negative vorticity area at the 500 hPa level, which caused upward motion of air with a magnitude of −4 × 10−5 sec−1 from the ground surface toward the 500 hPa height. At 21:00 LST, the city was still in negative vorticity area at the 500 hPa level, but upward motion of air with negative vorticity of −4 × 10−5 sec−1 became weaker than one by its reduction to negative vorticity of −2.5 × 10−5 sec−1, resulting in the shrunken of atmospheric depth between the 500 hPa level to the ground surface.Variations of vorticities (ζ
=
∂
v
/
∂
x
-
∂
u
/
∂
y; ×10−5 sec−1) at 500 hPa level at (a) 09:00 LST October 27, 2003, and (b) 21:00 LST. Triangle in the center indicates Gangneung city. Colorful (white) area indicates positive (negative) vorticity, which implies the downward (upward) motion of air at the 500 hPa level and corresponds to negative (positive) geopotential tendency area. Upward motion of air at the 500 hPa level with negative vorticity of −2.5 × 10−5 sec−1 at 21:00 LST became weaker than one with negative vorticity of −4 × 10−5 sec−1 at 09:00 LST, resulting in shrunken atmospheric depth.
(a)
(b)


### 4.4. Effects of Atmospheric Boundary Layer on High PM Concentration

As shown in Figure2, under the intensive intrusion of dusts from Gobi Desert toward the city during the dust period, high PM10, PM2.5, and PM1 concentrations were detected at 09:00 LST at the beginning time of office hour and 17:00 LST at the ending time of office hour, due to emission of gases and particulate matters from high density-traffic vehicles on the road, similarly to ones in the nondust period. As daytime went on after sunrise, convective boundary layer (CBL) due to thermal convection in the inland basin of the mountain top in the west of the city was much more developed than one at 09:00 LST, up to about 500 m in Figure 11(a), similarly to ones on October 26 (non-Yellow Dust Event period). Under the similar driving mechanism, thermal internal boundary layer (TIBL) during the day was also developed along the eastern slope of the mountain from the coast of the study area to the top of the mountain with about 300 m thickness.(a) Vertical profiles of potential temperature (k), wind speed (m/s), and potential vorticity (PVU = 10−6 m2 s−1 k kg−1) on a horizontal cutting line in the third domain of WRF model simulation in Figure 6 at (a) 09:00 LST and (b) 17:00 LST, October 27, 2003. Thick line, CBL, TIBL, G, and MABL on the bottom in (a) and (b) denote the top of convective boundary layer, thermal internal boundary layer, Gangneung city, and marine atmospheric boundary layer, respectively. Shade area near the surface in (b) is nocturnal surface inversion layer (NSIL) much shallower than TIBL in (a), where the dusts transported from the northern China combining with the dust particles floated from Gangneung city were merged into the ground surface, resulting in high PM concentrations at 17:00 LST at the city, similar to [9, 20, 31, 32].
(a)
(b)The maximum developments of CBL and TIBL occur around 12:00~15:00 LST, when maximum thermal convection takes place [31, 32]. Thus, although particulate matters emitted from vehicles on the road of the coastal city could increase for daytime hours, the particulates emitted from the ground surface of the city were uplifted to the top of the vertically developed TIBL and PM concentrations near the ground surface were generally very low on October 26 in the Gangneung coast. However, as the PM concentrations at Gangneung city continuously increased on October 27, due to huge amounts of dusts transported from Gobi Desert and Nei-Mongo toward the city, their concentrations with their still increasing trends were slightly lower at both 12:00 LST and 15:00 LST than 09:00 LST (Figures 2 and 11(a)).On the other hand, from 16:00 LST, October 27 until 04:00 LST, October 28, as huge amounts of dusts transported from Gobi Desert and Nei-Mongo toward Gangneung city under northerly wind (China), southwesterly wind (Yellow Sea) and southwesterly wind (Korean peninsula) increased rapidly and also combined with the dust and gases emitted from the ground surface of Gangneung city, local PM10 concentration continuously increased to a maximum value of 154.57 μg m−3 at 17:00 LST, October 27, which was 84.7 μg m−3 larger than a maximum one of 69.87 μg m−3 at 18:00 LST, October 26 (non-Yellow Sand Event period). Similarly, maximum value of PM2.5 (PM1) also reached 93.19 μg m−3 (76.05 μg m−3), which was much larger than ones of 27.19 μg m−3 (20.21 μg m−3), respectively.Particularly, shortly after sunset around 17:00 LST in Korea, nocturnal cooling of the ground surface causes cooling of air masses near ground surface and produces nocturnal surface inversion layer (NSIL), which is much more shrunken than the daytime thermal internal boundary layer (Figure11(b)). Both dusts transported from Gobi Desert toward Gangneung city should combine with ones from vehicles on the road and heating boilers from resident area of Gangneung city. The combined dusts were trapped under much shallower and shrunken NSIL of about 50~100 m depth, resulting in the increase of PM concentrations with their maximum values around 17:00 LST.In the previous research by Choi and Choi [20], nocturnal surface inversion layer in the coastal basin of Gangneung city was developed to 200~250 m height over the ground surface in March. Differently from their researches, in our case, synoptic-scale shrunken atmospheric depth from 500 hPa level to the ground surface due to the reduction of geopotential tendency for 12 hours (−53 m) could directly cause the decrease of nocturnal surface inversion layer depth. Thus, nocturnal surface inversion layer at 17:00 LST, October 27, could be about 150~200 m shallower than usual daytime thermal internal boundary layer. Thus, the shallower NSIL might make more contribution to the occurrence of a maximum PM concentration at 17:00 LST.Reed and Sanders [33] explained theoretically that potential vorticity can be used as a tracer like air parcel or dust. Haynes and McIntrye [34] showed that potential vorticity can be diluted or concentrated only by flow across isentropes and it cannot be created or destroyed within a layer bounded by isentropic surfaces. Thus, Choi and Zhang [9] described in detail the dust transportation route, using relative vorticity and depicting shade area in Figure 11(b) with the big magnitudes of potential vorticity near the ground surface of downwind side area and the shade area implied the accumulation of air masses inside a strong stable atmospheric layer. Thus, in Figures 11(a) and 11(b), the shade area with dense isotherm near the ground surface of the mountain and coast at 17:00 LST, October 27, denotes the merge of dust particles inside the NSIL, showing a maximum PM concentration in Figure 2.


## 4.1. Aerosol Concentration during a Non-Yellow Sand Period

Figure2 indicates hourly distribution of PM1, PM2.5, and PM10 concentrations at Gangneung city with no special industry in the eastern mountainous coast of Korea from 00:00 LST (09:00 LST), October 26 to 18:00 LST, October 29, 2003. Its main air pollution sources to affect local PM concentrations are vehicles on the road and heating boilers in the resident area. As air temperature of Gangneung city is in the range of 10~15°C for daytime hours in the late October and is lower than about 10°C at night, heating boilers in the resident area are put into operation for a few hours around sunset and sunrise. This operation can partially affect the increase of particulate matter and gases such as CO and NOx concentrations.Figure 2
Hourly distributions of PM10, PM2.5, and PM1 concentrations at Gangwon Meteorological Administration in the downtown of Gangneung city, Korea from October 26~29, 2003.A low pressure system of 999 hPa was located in the northern border of Mongolia and a high pressure system of 1021 hPa in the East Sea of Korea on weather map supplied by Korea Meteorological Administration (KMA) at 09:00 LST, October 26 (Figure3(a)). The pressure patterns produced northwesterly wind near Gobi Desert and the wind could blow dusts generated by Gobi Desert toward Manchuria in the north-eastern China. Under this situation, the dusts could not be transported toward Gangneung city in the eastern coast of the Korean peninsula (triangle).Surface weather maps at (a) 09:00 LST (00:00 UTC), October 26, 2003, and (b) 21:00 LST (12:00 UTC), supplied by KMA [26]. Square and thick line in (a) and (b) indicate Gobi Desert extending from the southern Mongolia to the northern China and cold front. Northwesterly wind in the left of cold front and southwesterly wind in the right of the front produced a main stream of dust particles originated from Gobi Desert toward Liaoning province in the northeastern China, which is far away from Gangneung city.
(a)
(b)As weather map or wind fields generated by a meteorological numerical model just show flow patterns of air particles at a certain height and at a given time of a special day. Thus, if we want to know the flow patterns of air particles continuously at different heights, we use many numbers of weather maps or simulated wind fields by a model at every 3 or 6 hours intervals for several days. On the other hand, particle trajectory using NOAA-HYSPIT model, which consists of meteorological model for wind field and Lagrangian random walk model on particle diffusion and dispersion, can supply the moving paths of air particles and their positions with different flowing heights at every 6 hours for several days, continuously. Thus, the position of air particle at a certain time on the moving trajectory of air for several days should be exactly the same as flow pattern of air at a given time weather map of a special day or wind field by a numerical model at a certain height. However, it is very difficult to chase the track of air particle on the weather map. Thus, we commonly use backward trajectory of air particle by NOAA-HYSPLIT model, which focuses only main stream of the majority of particles, not showing diffusion and dispersion of whole particles. Choi and Speer [19] described that the trajectories of whole particles in the wide area of different height such as in Seoul city and Korean eastern coast could be shown using Lagrangian Random Walk Model combined with meteorological model, but if we want to know the main stream of particles, not considering whole particles, HYSPLIT model is strongly recommended. In general, to investigate flow pattern of air in the wide area, it is necessary to review weather maps and horizontal wind fields generated by a meteorological numerical model.For depicting backward trajectories of dust particles with time, NOAA HYSPLIT model (hybrid single particle Lagrangian integrated trajectory) from the Air Resources Laboratory (ARL) using FNL meteorological data was adopted and the heights of dust particle trajectories were set up at 2000 m, 1000 m, and 500 m, respectively (Figure4). This model showed very detailed information on temporal transportation routes of dust particles for several days and their flowing height and spreading area. Weather map or wind fields generated by a meteorological model just show flow patterns of air at a given time, but particle trajectory using NOAA HYSPIT model supplies the moving path of particle and its position at every 6 hours for several days, continuously. Thus, this moving trajectory for several days is different from a given time weather map or wind field given by a numerical model. Unfortunately some environmental scientists misunderstand their differences. Thus, back trajectories with a time step of 6 hours over a period of 72 or 96 hours using the HYSPLIT model were depicted at 500 m, 1000 m, and 2000 m above ground level in order to detect possible links between diurnal variation of PM concentrations and pathway of dust particles transported from Gobi Desert and Nei-Mongo (Inner Mongo) in the northern China toward a Korean eastern coastal city.Backward trajectories of air masses at 2000 m, 1000 m, and 500 m heights by NOAA HYSPLIT model ending at (a) 09:00 LST (00:00 UTC), October 26, 2003 and (b) 21:00 LST (12:00 UTC). Clean air masses from above 2 km height of the north-eastern Mongolia flew toward Gangneung city at each level in (a) and ones from above 3 km height outside Gobi Desert (Nei-Mongo in the northeastern China) reached 1000 m and 2000 m heights of the city, without dust transportation to the city in (b). As weather map or wind fields generated by a meteorological numerical model just show flow patterns of air at a certain height and at a given time of a special day, but particle trajectory using NOAA-HYSPIT model supplies the moving path (main stream) of majority of air particle and its position at every 6 hours for several days, continuously.
(a)
(b)At 09:00 LST (00:00 UTC), October 26, clean air masses originated from over 2 km height in the north-eastern Mongolia far away from Gobi Desert reached Gangneung city at 500 m, 1000 m, and 2000 m heights and the city was under no influence of dusts in Gobi Desert (Figure4(a)). At 21:00 LST, the previous low pressure system moved toward the east and stretched toward the south-eastern China with pressure centers of 1000 hPa, 1002 hPa, and 1007 hPa, respectively (Figure 3(b)). A high pressure system of 1026 hPa was located in the northern Mongolia, but Gobi Desert was still under the influence of the low pressure system.The pressure patterns over Mongolia, China, and Korea caused northwesterly wind near Gobi Desert in the left of cold front and southwesterly in the right. Dusts driven by those winds should pass by Manchuria of the north-eastern China in the north of the Korean peninsula, resulting in no influence of dust transportation from China to Gangneung city of Korea (triangle). Figure4(b) showed that, on backward trajectory, relatively clean air particles from above 3 km height of Gobi Desert reached 1000 m and 200 m heights of the Korean city at 21:00 LST, October 26, but it was very difficult to expect dust transportation from Gobi Desert to the city. Nontransportation of dust from Gobi Desert and the northern China toward the city continued to be until 08:00 LST, October 27 in Figure 2.In Figure2, on October 26, especially before 09:00 LST October 27, under no intrusion of dust from Gobi Desert or Nei-Mongo (Inner Mongolia) in the northern China toward the city (non-Yellow Dust period), PM1, PM2.5, and PM10 concentrations near the ground surface of Gangneung city were generally very low, more or less than 20 μg m−3, 10 μg m−3, and 5 μg m−3, except for PM10 of 69.87 μg m−3 at 18:00 LST, October 26, respectively. High PM10, PM2.5, and PM1 concentrations were detected at 09:00 LST at the beginning time of office and 18:00 LST at the ending time of office hour, due to high density of traffic vehicles on the road at both times. Particularly maximum PM concentrations at 18:00 LST rather than 09:00 LST were shown due to additionally nighttime more operating of heating boilers in the resident area of the city, shortly after sunset. This hourly PM concentration showed a typical urban type-high PM concentrations around 09:00 LST in the morning and 18:00 LST near the sunset.


## 4.2. Aerosol Concentration during a Yellow Sand Event Period

During the intrusion of dust transported from Gobi Desert of the northern China toward the city from 09:00 LST October 27~04:00 LST, October 28 (Yellow Dust period), PM10 concentration was in the range of 48.20~154.57 μg m−3 and its maximum concentration was 3.8 times higher than the maximum concentration of nondust period.Similarly, PM2.5 (PM1) concentration was in the range of 26.92~93.19 μg m−3 (19.63~76.05 μg m−3) with a maximum concentration of 3.4 (14.1) times higher than one of nondust period and their hourly variations of PM concentrations were similar each other (Figure 2). High PM10 (PM2.5 and PM1) concentration was detected with 60.59 μg m−3 (26.92 μg m−3, 19.63 μg m−3) at 09:00 LST, October 27 (the beginning time of office hour), when a high traffic density on the road took place. PM concentration after 09:00 LST had a rapid increasing trend until 17:00 LST.As shown in surface weather maps of Figure5(a), one can expect that dusts generated in Gobi Desert in the northern China could be transported following isobaric lines of a high pressure, showing arrow movement of air masses in the figure. As shown in surface winds simulated by WRF-3.3 model, strong northerly surface wind in the north of China and southwesterly in the south prevailed (Figures 6(a) and 6(c)). In general, dusts generated from dried soil of the desert ground could be uplift to about 3 km height over the ground surface due to strong surface wind and daytime thermal convection [7], and then they moved eastward below the lower level than 3 km height.As shown in Figure3, except for (a) 09:00 LST (00:00 UTC), (b) 15:00 LST (06:00 UTC), (c) 21:00 LST (12:00 UTC), October 27, 2003, and (d) 03:00 LST (18:00 UTC), October 28. Dust particles originated from Gobi Desert move toward eastern Nei-Mongo, Manchuria, and northern Korea with their flowing southwestward in the left of cold front and northeastward in the right of the front, as the front moves toward the Korean peninsula, sequentially with time.
(a)
(b)
(c)
(d)(a) Moisture flux (m/s) at 850 hPa level (about 1.5 km height) supplied by KMA [26] and (b) surface wind (m/s) simulated by WRF model at 09:00 LST, October 27, 2003, and (c) and (d) are at 17:00LST (a maximum PM concentration), respectively. Small square and triangle in (a) and (c) denote Gobi Desert and Gangneung city (Korea). Small square in (b) and (d) denotes the vicinity of Gangneung (the 3rd domain of WRF model) at 09:00 LST, October 27, 2003 and 17:00 LST (occurrence time of maximum PM concentration). D and big arrow denote the eastern part of Gobi Desert in the northwest of Nei-Mongo and a dust transportation route. In (a), (b), (c), and (d), dust particles originated from Gobi Desert moved toward Nei-Mongo under westerly wind at both the surface and 1.5 km height and then, followed northerly and northwesterly toward the Chinese eastern coast and the Yellow Sea, further moving toward the northern Korea and Gangneung city.
(a)
(b)
(c)
(d)Figure6(a) at 09:00 LST, October 27, and Figure 6(c) at 17:00 LST of the occurrence time of a maximum PM concentration indicate transportation routes of moisture fluxes at about 1.5 km height (850 hPa level) in Mongolia, China, Korea, and Japan, which well show the movement of air parcel with water vapor. From these figures, it is very easy to find the transportation route of dust particles combining with air, water vapor, and dust. In Figures 6(a), 6(b), 6(c), and 6(d), dust particles originated from Gobi Desert moved toward Nei-Mongo under westerly wind at both the surface and 1.5 km height and then followed northerly and northwesterly toward the Chinese eastern coast and the Yellow Sea, further moving toward the northern Korea and Gangeung city.In Figure7(a), backward trajectories of dust particles generated in Gobi Desert at 09:00 LST (00:00 UTC) on October 25 flew from about 3 km height of the desert toward Gangneung city in the Korean east coast and reached 1000 m and 2000 m levels of the city at 09:00 LST (00:00 UTC), October 27 after three days. The dusts passed by about 2~3 km heights of Nei-Mongo in the northern China could reach the city at 1000 m and 500 m heights. Thus, dusts transported from Nei-Mongo could directly make a contribution to the increase of PM concentrations in the city as shown in Figure 2. At 21:00 LST (4 hours after the occurrence of maximum PM concentration), a high pressure system of 1025 hPa was located in the eastern Mongolia and a low pressure system of 1006 hPa was in the northeastern China (Figure 5(b)).Backward trajectories of air masses by NOAA HYSPLIT model ending at (a) 09:00 LST (00:00 UTC), October 27, 2003, (b) 17:00 LST (08:00 UTC; a maximum PM concentration), (c) 03:00 LST (18:00 UTC), October 28, and (d) 09:00 LST (00:00 UTC), respectively.
(a)
(b)
(c)
(d)As the previous high and low pressure systems moved toward the east, cold front passed by the northern part of Korean peninsula and stretched toward Manchuria in the north-eastern China. This kind of pressure pattern over Mongolia, China, and Korea caused northerly wind near Gobi Desert and southwesterly wind in the southern China (Figures6(b) and 6(d)). Southwesterly wind still prevailed through the Korean peninsula including the study area. Thus, dusts generated from Gobi Desert might pass by the eastern Mongolia-Nei-Mongo-southeastern China and finally reached the Korean eastern coastal city, sequentially. As a result, dusts transported from both Gobi Desert and Nei-Mongo could make a great contribution to the increase of local PM concentration in the city.In Figure7(b), as dust particles passed by 3 km height of Gobi Desert and 2000 m height of Nei-Mongo flew toward the Korean east coast and reached 2000~500 m heights in the city at 17:00 LST, October 27, when a maximum PM concentration took place. Thus, huge amounts of dusts generated from both Gobi Desert and Nei-Mongo could be transported to the city and made a great contribution to the increases of PM10, PM2.5, and PM1 concentration near the ground surface of the city. Similar patterns of backward particle trajectories could continuously exist until 03:00 LST, October 28 (Figure 7(c)). After 03:00 LST until 09:00 LST, October 28, dust transportation from Gobi Desert toward the Korean coastal city was very difficult as shown in Figure 7(d). Even though some amounts of dusts from not Gobi Desert, but Nei-Mongo (outside a box in the figure), passed by the southern China and the Yellow Sea and finally reached the Korean eastern coast, the transported dusts should be not much and local PM concentrations could be under little influence of the dusts.


## 4.3. Effect of Synoptic-Scale Geopotential Tendency Corresponding to Vorticity on High PM Concentration

Vorticity equation can be derived using horizontal momentum equations. It can be obtained by differentiating thex component equation of momentum with respect to y and the y component equation with respect to x and then subtraction of former differential equation from later differential equation ζ
=
∂
v
/
∂
x
-
∂
u
/
∂
y [27].Vorticity equation has a great advantage in order to investigate upward or downward of motion of air. Downward motion of air occurs in positive vorticity area at 500 hPa level (approximately 5.5 km height) and oppositely upward motion in negative vorticity area. Opposite to the 500 hPa level, downward motion of air near the ground surface (approximately 1,000 hPa level) occurs in negative vorticity area and vice versa. Holton [27], Sanders and Gyakum [29], and Reed and Albright [30] explained that the region of positive relative vorticity (ζ; ×10−5 sec−1) at the 500 hPa level causing convergence of air parcel and sequentially its downward motion toward the ground surface matches the region of the negative geopotential tendency (−∂Φ/∂
t; m day−1) at the 500 hPa level. Atmospheric depth in the negative geopotential tendency area should be reduced and vertically shrunken (Figure 8). On the other hand, the region of negative relative vorticity (-
ζ) inducing divergence of air parcel at the 500 hPa level and its upward motion from the ground surface toward the 500 hPa level matches the region of the positive geopotential tendency, (+∂Φ/∂
t; m day−1) with vertical expansion of atmospheric depth of 500 hPa level.Figure 8
Schematic profile of geopotential height change with time (geopotential tendency (∂Φ/∂
t); m day−1) at 500 hPa level (approximately 5.5 km height) and atmospheric boundary layer (ABL), modified from Choi et al. [28]. Negative geopotential tendency (∂Φ/∂
t) means the decrease of geopotential height for 24 hours (i.e., shrunken atmospheric layer) and vice versa. Positive vorticity (+
ζ
=
∂
v
/
∂
x
-
∂
u
/
∂
y) at the 500 hPa level, which implies the downward motion of air toward the ground corresponds to negative geopotential tendency area and vice versa.For applying geopotential tendency theory, we used every 6-hour weather maps of geopotential height at 500 hPa level supplied by Korea Meteorological Administration (KMA). At 09:00 LST, October 27, when huge amounts of dusts from Gobi Desert and Nei-Mongo began to make a contribution to the increase of PM concentrations at Gangneung city, geopotential tendency at 500 hPa level for a day in the city was +80 m day−1 (Figure 9(a)). The positive value of +83 m day−1 implies that atmospheric depth of 500 hPa level to the ground surface should be vertically expanded to more 83 m day−1 than one day before. On the other hand, the tendency at 21:00 LST was changed into +30 m day−1, which implied still the expansion of 500 hPa level to be up to 30 m day−1 for 24 hours (Figure 9(b)). Thus, the net variation of geopotential tendency between 09:00 LST and 21:00 LST for 12 hours could be reduced to −53 m, resulting in atmospheric depth to be shrunken. Similarly to the case of 21:00 LST, synoptic-scale shrunken atmospheric layer of 100 m could force nocturnal surface inversion layer in the city to be further more shrunken at night. Thus, resultantly much more shrunken nocturnal surface inversion layer might cause a maximum PM10 concentration as well as PM2.5 and PM1 in the coastal city at 17:00 LST.Geopotential tendency (∂Φ/∂
t; m day−1) at 500 hPa level at (a) 09:00 LST October 27, 2003, and (b) 21:00 LST. Triangle indicates Gangneung city. Shadow (white) area indicates negative (positive) geopotential tendency, which implies the shrunken (expansion) rate of geopotential height change at 500 hPa level for a day. As a positive tendency at 09:00 LST (21:00 LST) in Gangneung city was +83 m day−1 (+30 m day−1), the net one of −53 m for 12 hours implies a 53 m-shrunken atmospheric depth at 21:00 LST, causing a maximum PM10 at 17:00 LST.
(a)
(b)Figures10(a) and 10(b) indicate vorticity (×10−5 sec−1) at 500 hPa level at 09:00 LST October 27, 2003, and 21:00 LST, respectively. At 0900 LST October 27, Gangneung city was in negative vorticity area at the 500 hPa level, which caused upward motion of air with a magnitude of −4 × 10−5 sec−1 from the ground surface toward the 500 hPa height. At 21:00 LST, the city was still in negative vorticity area at the 500 hPa level, but upward motion of air with negative vorticity of −4 × 10−5 sec−1 became weaker than one by its reduction to negative vorticity of −2.5 × 10−5 sec−1, resulting in the shrunken of atmospheric depth between the 500 hPa level to the ground surface.Variations of vorticities (ζ
=
∂
v
/
∂
x
-
∂
u
/
∂
y; ×10−5 sec−1) at 500 hPa level at (a) 09:00 LST October 27, 2003, and (b) 21:00 LST. Triangle in the center indicates Gangneung city. Colorful (white) area indicates positive (negative) vorticity, which implies the downward (upward) motion of air at the 500 hPa level and corresponds to negative (positive) geopotential tendency area. Upward motion of air at the 500 hPa level with negative vorticity of −2.5 × 10−5 sec−1 at 21:00 LST became weaker than one with negative vorticity of −4 × 10−5 sec−1 at 09:00 LST, resulting in shrunken atmospheric depth.
(a)
(b)


## 4.4. Effects of Atmospheric Boundary Layer on High PM Concentration

As shown in Figure2, under the intensive intrusion of dusts from Gobi Desert toward the city during the dust period, high PM10, PM2.5, and PM1 concentrations were detected at 09:00 LST at the beginning time of office hour and 17:00 LST at the ending time of office hour, due to emission of gases and particulate matters from high density-traffic vehicles on the road, similarly to ones in the nondust period. As daytime went on after sunrise, convective boundary layer (CBL) due to thermal convection in the inland basin of the mountain top in the west of the city was much more developed than one at 09:00 LST, up to about 500 m in Figure 11(a), similarly to ones on October 26 (non-Yellow Dust Event period). Under the similar driving mechanism, thermal internal boundary layer (TIBL) during the day was also developed along the eastern slope of the mountain from the coast of the study area to the top of the mountain with about 300 m thickness.(a) Vertical profiles of potential temperature (k), wind speed (m/s), and potential vorticity (PVU = 10−6 m2 s−1 k kg−1) on a horizontal cutting line in the third domain of WRF model simulation in Figure 6 at (a) 09:00 LST and (b) 17:00 LST, October 27, 2003. Thick line, CBL, TIBL, G, and MABL on the bottom in (a) and (b) denote the top of convective boundary layer, thermal internal boundary layer, Gangneung city, and marine atmospheric boundary layer, respectively. Shade area near the surface in (b) is nocturnal surface inversion layer (NSIL) much shallower than TIBL in (a), where the dusts transported from the northern China combining with the dust particles floated from Gangneung city were merged into the ground surface, resulting in high PM concentrations at 17:00 LST at the city, similar to [9, 20, 31, 32].
(a)
(b)The maximum developments of CBL and TIBL occur around 12:00~15:00 LST, when maximum thermal convection takes place [31, 32]. Thus, although particulate matters emitted from vehicles on the road of the coastal city could increase for daytime hours, the particulates emitted from the ground surface of the city were uplifted to the top of the vertically developed TIBL and PM concentrations near the ground surface were generally very low on October 26 in the Gangneung coast. However, as the PM concentrations at Gangneung city continuously increased on October 27, due to huge amounts of dusts transported from Gobi Desert and Nei-Mongo toward the city, their concentrations with their still increasing trends were slightly lower at both 12:00 LST and 15:00 LST than 09:00 LST (Figures 2 and 11(a)).On the other hand, from 16:00 LST, October 27 until 04:00 LST, October 28, as huge amounts of dusts transported from Gobi Desert and Nei-Mongo toward Gangneung city under northerly wind (China), southwesterly wind (Yellow Sea) and southwesterly wind (Korean peninsula) increased rapidly and also combined with the dust and gases emitted from the ground surface of Gangneung city, local PM10 concentration continuously increased to a maximum value of 154.57 μg m−3 at 17:00 LST, October 27, which was 84.7 μg m−3 larger than a maximum one of 69.87 μg m−3 at 18:00 LST, October 26 (non-Yellow Sand Event period). Similarly, maximum value of PM2.5 (PM1) also reached 93.19 μg m−3 (76.05 μg m−3), which was much larger than ones of 27.19 μg m−3 (20.21 μg m−3), respectively.Particularly, shortly after sunset around 17:00 LST in Korea, nocturnal cooling of the ground surface causes cooling of air masses near ground surface and produces nocturnal surface inversion layer (NSIL), which is much more shrunken than the daytime thermal internal boundary layer (Figure11(b)). Both dusts transported from Gobi Desert toward Gangneung city should combine with ones from vehicles on the road and heating boilers from resident area of Gangneung city. The combined dusts were trapped under much shallower and shrunken NSIL of about 50~100 m depth, resulting in the increase of PM concentrations with their maximum values around 17:00 LST.In the previous research by Choi and Choi [20], nocturnal surface inversion layer in the coastal basin of Gangneung city was developed to 200~250 m height over the ground surface in March. Differently from their researches, in our case, synoptic-scale shrunken atmospheric depth from 500 hPa level to the ground surface due to the reduction of geopotential tendency for 12 hours (−53 m) could directly cause the decrease of nocturnal surface inversion layer depth. Thus, nocturnal surface inversion layer at 17:00 LST, October 27, could be about 150~200 m shallower than usual daytime thermal internal boundary layer. Thus, the shallower NSIL might make more contribution to the occurrence of a maximum PM concentration at 17:00 LST.Reed and Sanders [33] explained theoretically that potential vorticity can be used as a tracer like air parcel or dust. Haynes and McIntrye [34] showed that potential vorticity can be diluted or concentrated only by flow across isentropes and it cannot be created or destroyed within a layer bounded by isentropic surfaces. Thus, Choi and Zhang [9] described in detail the dust transportation route, using relative vorticity and depicting shade area in Figure 11(b) with the big magnitudes of potential vorticity near the ground surface of downwind side area and the shade area implied the accumulation of air masses inside a strong stable atmospheric layer. Thus, in Figures 11(a) and 11(b), the shade area with dense isotherm near the ground surface of the mountain and coast at 17:00 LST, October 27, denotes the merge of dust particles inside the NSIL, showing a maximum PM concentration in Figure 2.


## 5. Conclusions

Huge transportation of dusts was detected from Gobi Desert and Nei-Mongo in the northern China toward the Korean coastal city from 09:00 LST, October 27, to 05:00 LST, October 28, using the analysis of backward trajectories by HYSPLIT model and simulated surface wind by WRF model, and local concentrations of PM during Yellow Sand period were more than three times higher than ones before or after the event period. Under the combination of dusts transported from China, high PM concentrations occurred at 09:00 LST (beginning time of office) due to particulate and gases locally emitted from vehicles of a high traffic density on the road in the city, and maintaining their increasing trends with time for daytime hours, maximum ones were detected at 17:00 LST (ending time of office), additionally with the operation of heating boilers from the resident area near sunset, showing abrupt higher PM concentrations.The reduction of geopotential tendency of 500 hPa level for 12 hours corresponding to positive vorticity caused vertically shrunken synoptic-scale atmospheric depth, which could force nocturnal surface inversion layer to be further shrunken with at least 200 m shortly around sunset. The combined dusts from Gobi Desert with ones emitted from the Gangneung city should be merged into the ground surface and trapped within much shrunken stable surface inversion layer, resulting in a maximum PM10 concentration as well as PM2.5 and PM1 in the city at 17:00 LST.



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*Source: 756230-2014-01-23.xml*