# Influence of Intercalation-Exfoliation-Reduction Technique towards the Physico-Chemical of VPO Catalysts

Authors: Y. C. Wong; Y. H. Taufiq-Yap
Journal: Journal of Chemistry
 (2013)

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## Abstract

Four VPO catalysts were synthesized through intercalation and exfoliation in various alcohols and subsequent reduction of the exfoliated VOPO4 sheets with various alcohols to produce VOHPO4·0.5H2O. The resulting VOHPO4·0.5H2O that undergoes the intercalation-exfoliation-reduction (IER) process will be further activated into VPO catalysts, and addition of 1 mole % Bi(NO3)3·5H2O in the first stage of this experiment has also being investigated. The synthesized materials were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), and temperature-programmed reduction (TPR) in H2. Catalytic evaluation of the IER-treated and Bi-doped VPO catalysts was also studied on microreactor. The VPO catalyst produced through IER using 2-butanol and ethanol with addition of Bi, IERC(2Bu-Et)RBi1, gave the highest MA selectivity due to reactive O2− species released from the additional crystalline V5+ phase formed by doping 1% bismuth as promoter (O2−-V5+ pair) at relative lower temperature. Nevertheless, the VPO catalyst produced through IER using isobutanol, IERC(isoBu), gave the highest activity due to high amount of reactive O− species released from V4+ phase (O−-V4+ pair) whereby the IERC(isoBu) catalyst synthesized consists of high percentage of V4+ (93 %).


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## Body

## 1. Introduction

Although the selective oxidation ofn-butane to maleic anhydride (MA) has been commercialised using vanadyl pyrophosphate (VO)2P2O7 as a catalyst [1–3], low selectivity toward MA remains a serious problem. Therefore, it is keenly desirable to develop new and functional forms of (VO)2P2O7 that can offer improvements to this oxidation process [4] by using different approach of synthesis method such as intercalation-exfoliation-reduction (IER) technique.The MA selectivity in this reaction is sensitive to the chemical and physical properties of (VO)2P2O7 crystallites, including microstructure, defect sites, composition, oxidation state, and the presence of VOPO4 phases [5–7]. Among these factors, the microstructure (shape and dimension) of the (VO)2P2O7 crystallites is considered to have a critical effect on selectivity in n-butane oxidation [5]. Thus, control of the shape and dimension of (VO)2P2O7 crystallites should result in improved catalytic performance.In this study, the VOPO4·2H2O which is a starting material for the dihydrate route will be intercalated and exfoliated in various alcohols and subsequent reduction of the exfoliated VOPO4 sheets with alcohol to produce VOHPO4·0.5H2O. The resulting VOHPO4·0.5H2O that undergoes the intercalation-exfoliation-reduction (IER) process will be further activated into (VO)2P2O7 catalysts, and the physic chemical characteristic of this VPO catalysts obtained via this method was examined.


## 2. Experimental

### 2.1. Preparation of Intercalation-Exfoliation-Reduction (IER) VPO Catalysts

Vanadyl phosphate dihydrate, VOPO4·2H2O was synthesized by reacting V2O5 (12.0 g from Fluka) with ortho-H3PO4 (57.4 cm3, 85% from Merck) in distilled water (288 cm3) and under reflux at 393 K with continuous stirring for 24 h. The colour of the solid solution changed slowly from brownish to yellow. The resultant yellow solid (VOPO4·2H2O phase) was then recovered by using centrifuge technique and subsequently washed sparingly with distilled water and acetone and oven dried at 373 K for 24 h.The well synthesized of VOPO4·2H2O (2.0 g) was suspended by rapid stirring into 2-butyl alcohol (50 cm3 from BDH) and was refluxed stepwise at 303, 323, 343, and 363 K for 1 h at each temperature, yielding a homogeneous, yellow solution as the result of the intercalation, and exfoliation of VOPO4·2H2O.Ethyl alcohol (14.4 cm3 from Sigma-Aldrich) was then added at room temperature to the homogeneous 2-butyl alcohol solution, and the solution was refluxed for 24 h at 393 K to give a blue precipitate. The precipitate was separated using centrifugation, washed with acetone and oven dried at 353 K for 24 h, and this catalyst precursor was denoted as IERP(2Bu-Et).Addition of 1 mole % Bi(NO3)3·5H2O in the first stage of this experiment has also being investigated, and the precursor produced was denoted as IERP(2Bu-Et)RBi1.For another section of experiment, the precursor was also prepared by replacing 2-butyl alcohol with isobutyl alcohol, and the precursor produced was denoted as IERP(isoBu-Et).A precursor was also prepared using similar method in first section of this experiment by replacing 2-butyl alcohol with isobutyl alcohol, and followed by the thermal treatment without adding ethyl alcohol and the precursor produced was denoted as IERP(isoBu).The entire precursor obtained was calcined in reaction flow of 0.75%n-butane/air mixture for 18 h at 733 K to generate the active catalyst denoted as IERC(2Bu-Et), IERC(2Bu-Et)RBi1, IERC(isoBu-Et), and IERC(isoBu).


### 2.2. Catalysts Characterization

The total surface area of the catalysts was measured by the Brunauer-Emmett-Teller (BET) method using nitrogen adsorption at 77 K. This was done by a Sorptomatic 1990 Series, Thermo-Fischer-Scientific instrument.The bulk chemical composition was determined by using a sequential scanning inductively coupled plasma-atomic emission spectrometer (ICP-AES) (Perkin Elmer Emission Spectrometer model plasma 1000).The average oxidation numbers of vanadium in the sample bulk were determined by redox titration following the method of Niwa and Murakami [8].X-ray diffraction (XRD) analysis was carried out by using a Shimadzu diffractometer model XRD 6000.The electron microscopy techniques were used to obtain the information on the morphology and size of the samples by LEO 1455 Variable Pressure scanning electron microscope (SEM). The morphology was studied at an accelerating voltage of 30 kV. The particles were attached on an aluminium stub by using double-sided tape. The preparation was covered by using a thin layer of gold coating by using BIO-RAD Sputter Coater. The SEM micrographs were recorded by using a digital camera at various magnifications.The particle size of the samples was examined using LEO 912AB energy filter transmission electron microscope (TEM) with an acceleration voltage of 120 keV.H2-TPR analysis was performed using ThermoFisher Scientific TPDRO 1100 apparatus equipped with a thermal conductivity detector (TCD). The experiment was done by following the thermal conductivity of the outlet stream with TCD when raising the temperature of the fresh catalysts was raised from ambient to 1223 K at 10 K/min in a H2/Ar stream.The oxidation ofn-butane was carried out at 673 K with GHSV = 2400 h−1 in a fixed-bed microreactor with a standard mass of catalyst (250 mg). n-Butane and air were fed to the reactor via calibrated mass flow controllers to give a feedstock composition of 1.0% n-butane in air. The products were then fed via heated lines to an online gas chromatograph for analysis. The reactor comprised a stainless steel tube with the catalyst held in place by plugs of quartz wool. A thermocouple was located in the centre of the catalyst bed.


## 2.1. Preparation of Intercalation-Exfoliation-Reduction (IER) VPO Catalysts

Vanadyl phosphate dihydrate, VOPO4·2H2O was synthesized by reacting V2O5 (12.0 g from Fluka) with ortho-H3PO4 (57.4 cm3, 85% from Merck) in distilled water (288 cm3) and under reflux at 393 K with continuous stirring for 24 h. The colour of the solid solution changed slowly from brownish to yellow. The resultant yellow solid (VOPO4·2H2O phase) was then recovered by using centrifuge technique and subsequently washed sparingly with distilled water and acetone and oven dried at 373 K for 24 h.The well synthesized of VOPO4·2H2O (2.0 g) was suspended by rapid stirring into 2-butyl alcohol (50 cm3 from BDH) and was refluxed stepwise at 303, 323, 343, and 363 K for 1 h at each temperature, yielding a homogeneous, yellow solution as the result of the intercalation, and exfoliation of VOPO4·2H2O.Ethyl alcohol (14.4 cm3 from Sigma-Aldrich) was then added at room temperature to the homogeneous 2-butyl alcohol solution, and the solution was refluxed for 24 h at 393 K to give a blue precipitate. The precipitate was separated using centrifugation, washed with acetone and oven dried at 353 K for 24 h, and this catalyst precursor was denoted as IERP(2Bu-Et).Addition of 1 mole % Bi(NO3)3·5H2O in the first stage of this experiment has also being investigated, and the precursor produced was denoted as IERP(2Bu-Et)RBi1.For another section of experiment, the precursor was also prepared by replacing 2-butyl alcohol with isobutyl alcohol, and the precursor produced was denoted as IERP(isoBu-Et).A precursor was also prepared using similar method in first section of this experiment by replacing 2-butyl alcohol with isobutyl alcohol, and followed by the thermal treatment without adding ethyl alcohol and the precursor produced was denoted as IERP(isoBu).The entire precursor obtained was calcined in reaction flow of 0.75%n-butane/air mixture for 18 h at 733 K to generate the active catalyst denoted as IERC(2Bu-Et), IERC(2Bu-Et)RBi1, IERC(isoBu-Et), and IERC(isoBu).


## 2.2. Catalysts Characterization

The total surface area of the catalysts was measured by the Brunauer-Emmett-Teller (BET) method using nitrogen adsorption at 77 K. This was done by a Sorptomatic 1990 Series, Thermo-Fischer-Scientific instrument.The bulk chemical composition was determined by using a sequential scanning inductively coupled plasma-atomic emission spectrometer (ICP-AES) (Perkin Elmer Emission Spectrometer model plasma 1000).The average oxidation numbers of vanadium in the sample bulk were determined by redox titration following the method of Niwa and Murakami [8].X-ray diffraction (XRD) analysis was carried out by using a Shimadzu diffractometer model XRD 6000.The electron microscopy techniques were used to obtain the information on the morphology and size of the samples by LEO 1455 Variable Pressure scanning electron microscope (SEM). The morphology was studied at an accelerating voltage of 30 kV. The particles were attached on an aluminium stub by using double-sided tape. The preparation was covered by using a thin layer of gold coating by using BIO-RAD Sputter Coater. The SEM micrographs were recorded by using a digital camera at various magnifications.The particle size of the samples was examined using LEO 912AB energy filter transmission electron microscope (TEM) with an acceleration voltage of 120 keV.H2-TPR analysis was performed using ThermoFisher Scientific TPDRO 1100 apparatus equipped with a thermal conductivity detector (TCD). The experiment was done by following the thermal conductivity of the outlet stream with TCD when raising the temperature of the fresh catalysts was raised from ambient to 1223 K at 10 K/min in a H2/Ar stream.The oxidation ofn-butane was carried out at 673 K with GHSV = 2400 h−1 in a fixed-bed microreactor with a standard mass of catalyst (250 mg). n-Butane and air were fed to the reactor via calibrated mass flow controllers to give a feedstock composition of 1.0% n-butane in air. The products were then fed via heated lines to an online gas chromatograph for analysis. The reactor comprised a stainless steel tube with the catalyst held in place by plugs of quartz wool. A thermocouple was located in the centre of the catalyst bed.


## 3. Results and Discussions

### 3.1. X-Ray Diffraction (XRD)

The XRD patterns (Figure1) of the VPD precursors obtained via intercalation-exfoliation-reduction technique are perfectly matched with the standard VOHPO4·0.5H2O (JCPDS File no. 37-0269). The main characteristic peaks at 2θ = 15.6°, 19.6°, 24.3°, 27.1°, and 30.4° are corresponding to (001), (101), (021), (121), and (130) planes, respectively.Figure 1
XRD patterns for IER-VPD precursors.The intercalation-exfoliation-reduction method basically does not cause any changes, in terms of the basic matrix of the vanadyl hydrogen phosphate hemihydrate precursor (VOHPO4·0.5H2O), which could be evidenced from the standard VOHPO4·0.5H2O of the JCPDS. Peak at 30.4° appeared to be the most prominent peak for IERP(2Bu-Et), IERP(isoBu-Et), and IERP(isoBu). This was the main identity of the VPD precursor via the reduction of VOPO4·2H2O, which could also be observed in other open literatures [9, 10]. However, the (001) diffraction plane for catalyst precursor IERP(2Bu-Et)RBi1 appeared to be more intense and narrower as compared to the others. Therefore, this had indicated that by doping 1% of bismuth had somehow induced the formation of more crystalline VPD precursor than the other precursor.Another interesting point to note is that, by changing the solvent from 2-butanol to isobutanol in the intercalation and exfoliation stage, the (001), (101), (021), and (121) appeared to be less intense and broader as compared to those catalysts precursor that using 2-butanol as solvent in the mentioned stage above. Therefore, this also indicated that using isobutanol instead of 2-butanol as solvent in the intercalation and exfoliation stage somehow promotes the formation of more amorphous VPD precursor compared to the VPD precursor that used 2-butanol as solvent in the intercalation and exfoliation stage which has been well studied by Kamiya and coworkers [11].Figure2 exhibited the XRD patterns of intercalation-exfoliation-reduction VPD catalysts, after being activated at 733 K in reaction environment (0.75% n-butane/air mixture) for 18 h. All the catalysts produced are very similar and show the characteristic of (VO)2P2O7 phase with (020), (204), and (221) lines at 22.9°, 28.4°, and 29.9°, respectively. This particular phase has been accepted to be responsible for the partial oxidation of n-butane to maleic anhydride [2, 3]. However, IERC(2Bu-Et) catalyst whereby its precursor prepared through the intercalation-exfoliation-reduction technique using 2-butanol and ethanol shows lower-intensity characteristic peaks of (VO)2P2O7 phase, which further suggest that this catalyst may consist of lower crystallinity and the formation of more amorphous phase.Figure 2
XRD patterns for IER-VPD catalysts.Two additional weak peaks emerged at 2θ = 21.5° and 29.1° after addition of bismuth as dopant into the precursor of the catalyst, which corresponds to β-VOPO4 (JCPDS File no. 37-0948) and αII-VOPO4 (JCPDS File no. 34-1247) phases, respectively. This had indicated that the addition of 1% bismuth as dopant into the precursor catalyst has promoted the formation of V5+ phase component in the catalyst during the calcination stage whereby the precursor of the catalyst topotactically transformed into the active VPO catalyst which is well-agreed with the findings by Taufiq-Yap and coworkers [12]. Coulston and co-workers [13] reported that the formation of MA is proportional to the rate of V5+ species decay. So, it is believe that the additional formation of V5+ phases in 1% bismuth-doped IER-VPD catalyst will increase the selectivity towards MA compared to other catalysts.


### 3.2. BET Surface Area Measurements and Chemical Analysis

Table1 exhibited the total surface areas and chemical analysis results of intercalation-exfoliation-reduction catalysts by using different solvent. The total surface area of IERC(2Bu-Et) catalyst which undergoes the intercalation and exfoliation process using 2-butanol and ethanol as reducing agent is only 11.7 m2 g−1. However, the surface area obtained is differing from the findings by Kamiya and co-workers [11] using the same technique which has total surface area of 46.0 m2 g−1.Table 1
Specific BET surface area, chemical properties, average vanadium valence, and percentages of V4+ and V5+ oxidation states present in IER-VPD catalysts synthesized with different mixture of solvent.
CatalystsSpecific BET surface area (m2/g)Atomic ratio P/VOxidation of the vanadiumV4+ (%)V5+ (%)VavIERC(2Bu-Et)11.71.0874264.26IERC(2Bu-Et)RBi115.31.0577234.23IERC(isoBu-Et)35.61.0390104.10IERC(isoBu)21.81.059374.07The reduction of surface area may be due to the morphologies shown in the SEM micrograph (following section), indicated that the crystal plates formed in the IERC(2Bu-Et) catalyst are relatively small and unstable and have the tendency to agglomerate with each others to form larger platelet that caused lower surface to volume ratio being exposed to the environment.The surface area of 1% bismuth-doped IER-VPD catalyst using mixture of 2-butanol and ethanol shown to slightly increase to 15.3 m2 g−1. The addition of bismuth as dopant into the IER-VPD catalyst has somehow altered the development of the basal (100) (VO)2P2O7 face which is the interesting feature of the high total surface area of the catalyst produced [12].Interestingly, changing the reducing agent from 2-butanol to isobutanol with the present of ethanol, IERC(isoBu-Et) for intercalation-exfoliation-reduction of VOPO4·2H2O drastically increased the total surface area to 35.6 m2 g−1 approximately 3 times higher than IERC(2Bu-Et). However, for IERC(isoBu) catalyst produced in the same technique but without the presence of ethanol has caused slightly decrease in the total surface area to 21.8 m2 g−1. This may be due to the structures of isobutanol that somehow intercalated the layered VOPO4 sheets much larger compared to 2-butanol and followed by well exfoliated of VOPO4 sheets that formed smaller platelets that caused higher surface to volume ratio being exposed to the environment that directly increased the surface area of the catalysts produced.Chemical analysis using ICP in Table1 indicated that the ranges of P/V ratio for the intercalation-exfoliation-reduction catalysts synthesised using different mixture of solvent were in between 1.03 to 1.08. Even though the obtained values were slightly deviated from the nominal P/V atomic ratio value of 1 : 1, these values indicated that the V4+ species that is responsible for the activity of the respective catalyst could be stabilised by higher P/V atomic ratio [1].The average oxidation numbers of vanadium and percentage of V5+ and V4+ oxidation state are summarised in Table 1. Doping 1% of bismuth into the IER-VPD catalyst with the mixture of 2-butanol and ethanol has resulted in a slight decreased of the V5+ contribution from 26% to 23% for IERC(2Bu-Et) and IERC(2Bu-Et)RBi1, respectively.Moreover, changing the mixture solvent to isobutanol and ethanol also has caused remarkable lowering of V5+ phase to only 10% compared to IERC(2Bu-Et). Furthermore, the absence of ethanol with only the presence of isobutanol in the intercalation-exfoliation-reduction technique to synthesize the catalyst also caused a slight decrease in the formation of V5+ percentage to 7%. The average oxidation state of vanadium reduced from 4.26 for IERC(2Bu-Et) to 4.23, 4.10, and 4.07 for IERC(2Bu-Et)RBi1, IERC(isoBu-Et), and IERC(isoBu), respectively.


### 3.3. Scanning Electron Microscope (SEM)

The surface morphologies of intercalation-exfoliation-reduction catalysts synthesized using different mixture of solvent were examined by using scanning electron microscope as shown in Figure3. All the catalysts synthesised through intercalation-exfoliation-reduction technique had lost their secondary structure of rosette shape and only consist of plate-like and rather flat crystal structure that these smaller platelets are unstable and have high surface energy, tendency to agglomerate, and are stacking with each other; hence, this caused a decrease of the surface area of the catalyst which is in agreement with the results obtained from the BET surface area measurements (Table 1).SEM micrographs of (a) IERC(2Bu-Et), (b) IERC(2Bu-Et)RBi1, (c) IERC(isoBu-Et), and (d) IERC(isoBu) (with 15000x magnification).
(a)(b)(c)(d)


### 3.4. Transmission Electron Microscope (TEM)

Figure4 shows the particle size of the intercalation-exfoliation-reduction VPD catalysts synthesized using different mixture of solvent which were examined by using TEM. The TEM images show that the IER-VPD catalysts synthesized indeed consist of nano crystallites with average sizes of approximately 20 nm. These TEM images also further confirmed that these nanocrystallites are unstable, have high surface energy, tend to agglomerate, and stacking with each other to form larger platelets. This phenomenon will promote the decrease of the exposed surface to volume ratio to the surrounding environment that is causing the IER-VPD catalysts having a lower surface area which is also in agreement with the results obtained from the BET surface area measurements (Table 1).TEM micrographs of (a) IERC(2Bu-Et), (b) IERC(2Bu-Et)RBi1, (c) IERC(isoBu-Et), and (d) IERC(isoBu).
(a)
Approximate 100 nm(b)
Approximate 20 nm(c)
Approximate 25 nm(d)
Approximate 60 nm


### 3.5. Temperature-Programmed Reduction (TPR in H2/Ar)

Three distinct peak maxima exhibited by the IERC(2Bu-Et) catalyst were observed in the rate of hydrogen consumption at 802, 984 and 1060 K, respectively (Figure5). The amount of oxygen removed by the reaction with H2 for this IER-VPD catalyst is 0.13 × 1021, 0.64 × 1021, and 0.90 × 1021 atoms g−1, respectively, with an oxygen ratio removed from V5+/V4+ of 0.08 (Table 2).Table 2
Total amount of oxygen removed from the doped and undoped IER-VPD catalysts by reduction in H2/Ar.
Catalyst (Peak)Tmax (K)Oxygen atom removed (×10-3mol g−1)Oxygen atom removed (×1021  atoms g−1)Ratio for oxygen removal of V5+/V4+IERC(2Bu-Et)18020.220.1329841.060.640.08310601.500.90Total oxygen atoms removed2.781.67IERC(2Bu-Et)RBi118290.210.1329412.571.550.08Total oxygen atoms removed2.781.68IERC(isoBu-Et)18950.240.14210301.991.200.17Total oxygen atoms removed2.231.34IERC(isoBu)18900.280.17210592.421.460.12Total oxygen atoms removed2.701.63Figure 5
TPR profiles for the IER-VPD catalysts.However, IERC(2Bu-Et)RBi1, IERC(isoBu-Et), and IERC(isoBu) only show two distinct reduction peaks maxima in the rate of hydrogen consumption which is differ from IERC(2Bu-Et) catalyst produced. For the 1% bismuth-doped IER-VPD catalyst using mixture of 2-butanol and ethanol, IERC(2Bu-Et)RBi1 gave two reduction peaks whereby the first reduction peak occurred at slightly higher temperature compared to the undoped VPO catalyst using the same mixture of solvent which is 829 K with 0.13 × 1021 atoms g−1 of the amount of oxygen removed at that particular peak.Interestingly, the addition of 1% bismuth significantly lowered the second reduction peak to 941 K with higher amount of oxygen removed (1.55 × 1021 atoms g−1). The bismuth-doped VPO catalyst shows the same oxygen ratio removed from V5+/V4+ in undoped catalyst produced using the same mixture of solvent. The lowering of the reduction peak temperature and the increment of the oxygen atoms removed from the lattice by the reaction of H2 may suggest that the oxygen species in the bismuth which promoted VPO catalyst are more reactive and will give higher conversion for n-butane oxidation compared to the unpromoted VPO catalyst.Another noteworthy point is that, by changing the mixture solvent from 2-butanol and ethanol to isobutanol and ethanol in the same technique to produce the VPO catalyst, IERC(isoBu-Et) shows the first reduction peak occurred at relative higher temperature which is 895 K but with a slight increase in the amount of oxygen removed that is 0.14 × 1021 atoms g−1 compared to IERC(2Bu-Et). However, the second reduction peak of IERC(isoBu-Et) somehow occurred at lower temperature (1030 K) but with a lower amount of oxygen removed which is 1.20 × 1021 atoms g−1 with an oxygen ratio removed from V5+/V4+ of 0.17 as shown in Table 2.Nevertheless, with the absence of ethanol in the same preparation technique to produce IERC(isoBu) catalyst, the first reduction peak occurred at slightly lower temperature which is 890 K but with a slight increase in the amount of oxygen removed which is 0.17 × 1021  atoms g−1, and the second reduction peak occurred at higher temperature (1059 K) but with a higher amount of oxygen removed which is 1.46 × 1021 atoms g−1 compared to IERC(isoBu-Et).


### 3.6. Catalytic Oxidation of n-Butane

As depicted from Figure6, IERC(2Bu-Et)RBi1 is the most selective catalyst with 27.0% of MA selectivity, followed by IERC(2Bu-Et) (23.0%), IERC(isoBu-Et) (17.0%), and IERC(isoBu) (9.0%). Furthermore, IERC(isoBu) with 44.0% conversion was also found to be the most active catalyst, followed by IERC(isoBu-Et) (32.0%), IERC(2Bu-Et), and IERC(2Bu-Et)RBi1 both catalysts showing the same amount of conversion (19.2%) as summarised in Table 3.Table 3
The catalytic performance of doped and undoped intercalation-exfoliation-reduction catalysts using different mixture of solvent for oxidation ofn-butane.
Catalystsn-Butane conversion (%)Product selectivity (%)MA yield (%)MACOCO2IERC(2Bu-Et)30.023.03.074.06.9IERC(2Bu-Et)RBi130.027.08.065.08.1IERC(isoBu-Et)32.017.037.046.05.4IERC(isoBu)44.09.041.050.04.0Figure 6
The relation between conversion (%), MA selectivity (%), and MA yield (%) of catalysts produced inn-butane oxidation.The difference in catalytic activity and selectivity for the doped and undoped VPO catalysts which undergo intercalation-exfoliation-reduction technique using different mixture of solvent is attributed to the higher reactivity of the oxygen species in the lattice. It should be noted that IERC(2Bu-Et)RBi1 catalyst shows the additional formation of crystalline V5+ phase component in the XRD analysis. As reported earlier, selective oxidation of n-butane over VPO catalyst was shown to proceed via a redox mechanism [14]. Therefore, the reduction behaviour of the synthesised catalyst is a reliable method as an indicator for the catalytic performance.As expected earlier, IERC(2Bu-Et)RBi1 catalyst gave the highest MA selectivity due to reactive O2- species released from the additional crystalline V5+ phase formed (O2--V5+ pair) at relative lower temperature. Furthermore, IERC(2Bu-Et) catalyst also gave relatively high MA selectivity due to the additional reactive and mobile O2- species released at lower temperature. Moreover, IERC(isoBu) catalysts gave the highest activity due to high amount of reactive O- species released from V4+ phase (O--V4+ pair) whereby this catalyst consists of high percentage of V4+ (93%).


## 3.1. X-Ray Diffraction (XRD)

The XRD patterns (Figure1) of the VPD precursors obtained via intercalation-exfoliation-reduction technique are perfectly matched with the standard VOHPO4·0.5H2O (JCPDS File no. 37-0269). The main characteristic peaks at 2θ = 15.6°, 19.6°, 24.3°, 27.1°, and 30.4° are corresponding to (001), (101), (021), (121), and (130) planes, respectively.Figure 1
XRD patterns for IER-VPD precursors.The intercalation-exfoliation-reduction method basically does not cause any changes, in terms of the basic matrix of the vanadyl hydrogen phosphate hemihydrate precursor (VOHPO4·0.5H2O), which could be evidenced from the standard VOHPO4·0.5H2O of the JCPDS. Peak at 30.4° appeared to be the most prominent peak for IERP(2Bu-Et), IERP(isoBu-Et), and IERP(isoBu). This was the main identity of the VPD precursor via the reduction of VOPO4·2H2O, which could also be observed in other open literatures [9, 10]. However, the (001) diffraction plane for catalyst precursor IERP(2Bu-Et)RBi1 appeared to be more intense and narrower as compared to the others. Therefore, this had indicated that by doping 1% of bismuth had somehow induced the formation of more crystalline VPD precursor than the other precursor.Another interesting point to note is that, by changing the solvent from 2-butanol to isobutanol in the intercalation and exfoliation stage, the (001), (101), (021), and (121) appeared to be less intense and broader as compared to those catalysts precursor that using 2-butanol as solvent in the mentioned stage above. Therefore, this also indicated that using isobutanol instead of 2-butanol as solvent in the intercalation and exfoliation stage somehow promotes the formation of more amorphous VPD precursor compared to the VPD precursor that used 2-butanol as solvent in the intercalation and exfoliation stage which has been well studied by Kamiya and coworkers [11].Figure2 exhibited the XRD patterns of intercalation-exfoliation-reduction VPD catalysts, after being activated at 733 K in reaction environment (0.75% n-butane/air mixture) for 18 h. All the catalysts produced are very similar and show the characteristic of (VO)2P2O7 phase with (020), (204), and (221) lines at 22.9°, 28.4°, and 29.9°, respectively. This particular phase has been accepted to be responsible for the partial oxidation of n-butane to maleic anhydride [2, 3]. However, IERC(2Bu-Et) catalyst whereby its precursor prepared through the intercalation-exfoliation-reduction technique using 2-butanol and ethanol shows lower-intensity characteristic peaks of (VO)2P2O7 phase, which further suggest that this catalyst may consist of lower crystallinity and the formation of more amorphous phase.Figure 2
XRD patterns for IER-VPD catalysts.Two additional weak peaks emerged at 2θ = 21.5° and 29.1° after addition of bismuth as dopant into the precursor of the catalyst, which corresponds to β-VOPO4 (JCPDS File no. 37-0948) and αII-VOPO4 (JCPDS File no. 34-1247) phases, respectively. This had indicated that the addition of 1% bismuth as dopant into the precursor catalyst has promoted the formation of V5+ phase component in the catalyst during the calcination stage whereby the precursor of the catalyst topotactically transformed into the active VPO catalyst which is well-agreed with the findings by Taufiq-Yap and coworkers [12]. Coulston and co-workers [13] reported that the formation of MA is proportional to the rate of V5+ species decay. So, it is believe that the additional formation of V5+ phases in 1% bismuth-doped IER-VPD catalyst will increase the selectivity towards MA compared to other catalysts.


## 3.2. BET Surface Area Measurements and Chemical Analysis

Table1 exhibited the total surface areas and chemical analysis results of intercalation-exfoliation-reduction catalysts by using different solvent. The total surface area of IERC(2Bu-Et) catalyst which undergoes the intercalation and exfoliation process using 2-butanol and ethanol as reducing agent is only 11.7 m2 g−1. However, the surface area obtained is differing from the findings by Kamiya and co-workers [11] using the same technique which has total surface area of 46.0 m2 g−1.Table 1
Specific BET surface area, chemical properties, average vanadium valence, and percentages of V4+ and V5+ oxidation states present in IER-VPD catalysts synthesized with different mixture of solvent.
CatalystsSpecific BET surface area (m2/g)Atomic ratio P/VOxidation of the vanadiumV4+ (%)V5+ (%)VavIERC(2Bu-Et)11.71.0874264.26IERC(2Bu-Et)RBi115.31.0577234.23IERC(isoBu-Et)35.61.0390104.10IERC(isoBu)21.81.059374.07The reduction of surface area may be due to the morphologies shown in the SEM micrograph (following section), indicated that the crystal plates formed in the IERC(2Bu-Et) catalyst are relatively small and unstable and have the tendency to agglomerate with each others to form larger platelet that caused lower surface to volume ratio being exposed to the environment.The surface area of 1% bismuth-doped IER-VPD catalyst using mixture of 2-butanol and ethanol shown to slightly increase to 15.3 m2 g−1. The addition of bismuth as dopant into the IER-VPD catalyst has somehow altered the development of the basal (100) (VO)2P2O7 face which is the interesting feature of the high total surface area of the catalyst produced [12].Interestingly, changing the reducing agent from 2-butanol to isobutanol with the present of ethanol, IERC(isoBu-Et) for intercalation-exfoliation-reduction of VOPO4·2H2O drastically increased the total surface area to 35.6 m2 g−1 approximately 3 times higher than IERC(2Bu-Et). However, for IERC(isoBu) catalyst produced in the same technique but without the presence of ethanol has caused slightly decrease in the total surface area to 21.8 m2 g−1. This may be due to the structures of isobutanol that somehow intercalated the layered VOPO4 sheets much larger compared to 2-butanol and followed by well exfoliated of VOPO4 sheets that formed smaller platelets that caused higher surface to volume ratio being exposed to the environment that directly increased the surface area of the catalysts produced.Chemical analysis using ICP in Table1 indicated that the ranges of P/V ratio for the intercalation-exfoliation-reduction catalysts synthesised using different mixture of solvent were in between 1.03 to 1.08. Even though the obtained values were slightly deviated from the nominal P/V atomic ratio value of 1 : 1, these values indicated that the V4+ species that is responsible for the activity of the respective catalyst could be stabilised by higher P/V atomic ratio [1].The average oxidation numbers of vanadium and percentage of V5+ and V4+ oxidation state are summarised in Table 1. Doping 1% of bismuth into the IER-VPD catalyst with the mixture of 2-butanol and ethanol has resulted in a slight decreased of the V5+ contribution from 26% to 23% for IERC(2Bu-Et) and IERC(2Bu-Et)RBi1, respectively.Moreover, changing the mixture solvent to isobutanol and ethanol also has caused remarkable lowering of V5+ phase to only 10% compared to IERC(2Bu-Et). Furthermore, the absence of ethanol with only the presence of isobutanol in the intercalation-exfoliation-reduction technique to synthesize the catalyst also caused a slight decrease in the formation of V5+ percentage to 7%. The average oxidation state of vanadium reduced from 4.26 for IERC(2Bu-Et) to 4.23, 4.10, and 4.07 for IERC(2Bu-Et)RBi1, IERC(isoBu-Et), and IERC(isoBu), respectively.


## 3.3. Scanning Electron Microscope (SEM)

The surface morphologies of intercalation-exfoliation-reduction catalysts synthesized using different mixture of solvent were examined by using scanning electron microscope as shown in Figure3. All the catalysts synthesised through intercalation-exfoliation-reduction technique had lost their secondary structure of rosette shape and only consist of plate-like and rather flat crystal structure that these smaller platelets are unstable and have high surface energy, tendency to agglomerate, and are stacking with each other; hence, this caused a decrease of the surface area of the catalyst which is in agreement with the results obtained from the BET surface area measurements (Table 1).SEM micrographs of (a) IERC(2Bu-Et), (b) IERC(2Bu-Et)RBi1, (c) IERC(isoBu-Et), and (d) IERC(isoBu) (with 15000x magnification).
(a)(b)(c)(d)


## 3.4. Transmission Electron Microscope (TEM)

Figure4 shows the particle size of the intercalation-exfoliation-reduction VPD catalysts synthesized using different mixture of solvent which were examined by using TEM. The TEM images show that the IER-VPD catalysts synthesized indeed consist of nano crystallites with average sizes of approximately 20 nm. These TEM images also further confirmed that these nanocrystallites are unstable, have high surface energy, tend to agglomerate, and stacking with each other to form larger platelets. This phenomenon will promote the decrease of the exposed surface to volume ratio to the surrounding environment that is causing the IER-VPD catalysts having a lower surface area which is also in agreement with the results obtained from the BET surface area measurements (Table 1).TEM micrographs of (a) IERC(2Bu-Et), (b) IERC(2Bu-Et)RBi1, (c) IERC(isoBu-Et), and (d) IERC(isoBu).
(a)
Approximate 100 nm(b)
Approximate 20 nm(c)
Approximate 25 nm(d)
Approximate 60 nm


## 3.5. Temperature-Programmed Reduction (TPR in H2/Ar)

Three distinct peak maxima exhibited by the IERC(2Bu-Et) catalyst were observed in the rate of hydrogen consumption at 802, 984 and 1060 K, respectively (Figure5). The amount of oxygen removed by the reaction with H2 for this IER-VPD catalyst is 0.13 × 1021, 0.64 × 1021, and 0.90 × 1021 atoms g−1, respectively, with an oxygen ratio removed from V5+/V4+ of 0.08 (Table 2).Table 2
Total amount of oxygen removed from the doped and undoped IER-VPD catalysts by reduction in H2/Ar.
Catalyst (Peak)Tmax (K)Oxygen atom removed (×10-3mol g−1)Oxygen atom removed (×1021  atoms g−1)Ratio for oxygen removal of V5+/V4+IERC(2Bu-Et)18020.220.1329841.060.640.08310601.500.90Total oxygen atoms removed2.781.67IERC(2Bu-Et)RBi118290.210.1329412.571.550.08Total oxygen atoms removed2.781.68IERC(isoBu-Et)18950.240.14210301.991.200.17Total oxygen atoms removed2.231.34IERC(isoBu)18900.280.17210592.421.460.12Total oxygen atoms removed2.701.63Figure 5
TPR profiles for the IER-VPD catalysts.However, IERC(2Bu-Et)RBi1, IERC(isoBu-Et), and IERC(isoBu) only show two distinct reduction peaks maxima in the rate of hydrogen consumption which is differ from IERC(2Bu-Et) catalyst produced. For the 1% bismuth-doped IER-VPD catalyst using mixture of 2-butanol and ethanol, IERC(2Bu-Et)RBi1 gave two reduction peaks whereby the first reduction peak occurred at slightly higher temperature compared to the undoped VPO catalyst using the same mixture of solvent which is 829 K with 0.13 × 1021 atoms g−1 of the amount of oxygen removed at that particular peak.Interestingly, the addition of 1% bismuth significantly lowered the second reduction peak to 941 K with higher amount of oxygen removed (1.55 × 1021 atoms g−1). The bismuth-doped VPO catalyst shows the same oxygen ratio removed from V5+/V4+ in undoped catalyst produced using the same mixture of solvent. The lowering of the reduction peak temperature and the increment of the oxygen atoms removed from the lattice by the reaction of H2 may suggest that the oxygen species in the bismuth which promoted VPO catalyst are more reactive and will give higher conversion for n-butane oxidation compared to the unpromoted VPO catalyst.Another noteworthy point is that, by changing the mixture solvent from 2-butanol and ethanol to isobutanol and ethanol in the same technique to produce the VPO catalyst, IERC(isoBu-Et) shows the first reduction peak occurred at relative higher temperature which is 895 K but with a slight increase in the amount of oxygen removed that is 0.14 × 1021 atoms g−1 compared to IERC(2Bu-Et). However, the second reduction peak of IERC(isoBu-Et) somehow occurred at lower temperature (1030 K) but with a lower amount of oxygen removed which is 1.20 × 1021 atoms g−1 with an oxygen ratio removed from V5+/V4+ of 0.17 as shown in Table 2.Nevertheless, with the absence of ethanol in the same preparation technique to produce IERC(isoBu) catalyst, the first reduction peak occurred at slightly lower temperature which is 890 K but with a slight increase in the amount of oxygen removed which is 0.17 × 1021  atoms g−1, and the second reduction peak occurred at higher temperature (1059 K) but with a higher amount of oxygen removed which is 1.46 × 1021 atoms g−1 compared to IERC(isoBu-Et).


## 3.6. Catalytic Oxidation of n-Butane

As depicted from Figure6, IERC(2Bu-Et)RBi1 is the most selective catalyst with 27.0% of MA selectivity, followed by IERC(2Bu-Et) (23.0%), IERC(isoBu-Et) (17.0%), and IERC(isoBu) (9.0%). Furthermore, IERC(isoBu) with 44.0% conversion was also found to be the most active catalyst, followed by IERC(isoBu-Et) (32.0%), IERC(2Bu-Et), and IERC(2Bu-Et)RBi1 both catalysts showing the same amount of conversion (19.2%) as summarised in Table 3.Table 3
The catalytic performance of doped and undoped intercalation-exfoliation-reduction catalysts using different mixture of solvent for oxidation ofn-butane.
Catalystsn-Butane conversion (%)Product selectivity (%)MA yield (%)MACOCO2IERC(2Bu-Et)30.023.03.074.06.9IERC(2Bu-Et)RBi130.027.08.065.08.1IERC(isoBu-Et)32.017.037.046.05.4IERC(isoBu)44.09.041.050.04.0Figure 6
The relation between conversion (%), MA selectivity (%), and MA yield (%) of catalysts produced inn-butane oxidation.The difference in catalytic activity and selectivity for the doped and undoped VPO catalysts which undergo intercalation-exfoliation-reduction technique using different mixture of solvent is attributed to the higher reactivity of the oxygen species in the lattice. It should be noted that IERC(2Bu-Et)RBi1 catalyst shows the additional formation of crystalline V5+ phase component in the XRD analysis. As reported earlier, selective oxidation of n-butane over VPO catalyst was shown to proceed via a redox mechanism [14]. Therefore, the reduction behaviour of the synthesised catalyst is a reliable method as an indicator for the catalytic performance.As expected earlier, IERC(2Bu-Et)RBi1 catalyst gave the highest MA selectivity due to reactive O2- species released from the additional crystalline V5+ phase formed (O2--V5+ pair) at relative lower temperature. Furthermore, IERC(2Bu-Et) catalyst also gave relatively high MA selectivity due to the additional reactive and mobile O2- species released at lower temperature. Moreover, IERC(isoBu) catalysts gave the highest activity due to high amount of reactive O- species released from V4+ phase (O--V4+ pair) whereby this catalyst consists of high percentage of V4+ (93%).


## 4. Conclusions

All the catalysts synthesized through intercalation-exfoliation-reduction technique had lost their secondary structure of rosette-shape and only consist of plate-like and rather flat crystal structure that these smaller platelets are unstable, have high surface energy and tendency to agglomerate, and are stacking with each other which is in agreement with the TEM images. Moreover, IERC(2Bu-Et)RBi1 catalyst gave the highest MA selectivity due to reactive O2- species released from the additional crystalline V5+ phase formed by doping 1% bismuth as promoter (O2--V5+ pair) at relative lower temperature. Nevertheless, IERC(isoBu) catalysts gave the highest activity due to high amount of reactive O- species released from V4+ phase (O--V4+ pair) whereby the IERC(isoBu) catalyst synthesised consists of high percentage of V4+ (93%).



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*Source: 727539-2012-06-14.xml*