# Stored Coulomb Self-Energy of a Uniformly Charged Rectangular Plate

Authors: Orion Ciftja
Journal: Advances in Mathematical Physics
 (2016)

---

## Abstract

A large number of electronic devices contain charged, flat plates (electrodes) as their components. The approximation of considering such components as infinitely large plates is not satisfactory for the current status of consumer electronics where size is now extremely small. In particular, the nanotechnology revolution has made the fabrication of truly finite systems with arbitrary shape and characteristic lengths that measure in nanometers possible. As a result the only accurate approach for such situations is to consider the system realistically as one with a finite size extent. In this work we calculate the amount of electrostatic energy that is stored in a charged finite size electrode that is modelled as a uniformly charged rectangular plate with arbitrary length and width. Nontrivial mathematical transformations allow us to derive a closed form exact expression for the Coulomb self-energy of such a system as a function of its length and width (therefore, shape, too). The exact result derived can be useful to understand the storage process of electrostatic energy as a function of size/shape in uniformly charged plate systems. The result also applies to calculations that deal with the properties of a finite two-dimensional electron gas within the jellium model where the finite jellium domain can have an arbitrary rectangular shape.


---

## Body

## 1. Introduction

Many electronic devices have charged, flat plates (squares, rectangles, disks, etc.) as their components. These charged plates (often called electrodes) serve the purpose of steering the current along the proper paths in a device. Although any real electrode is finite in extent, one can often get a good understanding of the system by modelling it as an infinite uniformly charged plate. This simple treatment is very reasonable as long as the distance of interest to the electrode is small in comparison to the characteristic length of the electrode itself. For such a situation it is legitimate to treat the edges as if they were infinitely far away from the point of interest.However, great advances in nanotechnology have now made the fabrication of very small trulyfinite systems with arbitrary shape, size, and dimensionality possible [1–8] where treatments that discard the finite size are not accurate. In particular, charged nanoplates are key components of any given nanoelectronic device. Often, their properties are size/shape-dependent and dominated mainly by electrostatic interactions [9–15]. For instance, LiMnPO4 nanoplates have been recently grown experimentally for battery cathode applications [16]. Transmission electron microscope measurements have indicated that such nanoplates are very thin rectangles measuring about 50 nanometers (which is approximately a thousand times thinner than a human hair) and up to 2000 nanometers on a side [16]. For these values, they can be safely approximated as almost ideal two-dimensional (2D) rectangular plates. When charged, such nanoplates can theoretically store some of the highest amounts of electrostatic energy of the rechargeable batteries. The amount of electricity that the material can store can be measured by charging and discharging the nanoplate fast or slowly. In this particular case it was found that when the nanoplates were charged slowly over a day and then discharged just as slowly, the amount of electricity held was extremely large [16]. Improvements on the material (charging and discharging in an hour without substantial reductions of the best performance observed for slow charging and discharging) may lead to important advances in consumer electronics.Developments in the field of nanotechnology have also made the fabrication of finite systems of electrons confined in a finite 2D domain possible [17–22]. The simplest model for a finite two-dimensional electron gas (2DEG) involves the “jellium” approximation where one assumes that a neutralizing positive charge is uniformly spread over a finite 2D region. While the shape of the jellium background is irrelevant when it comes to bulk properties of a 2DEG in the thermodynamic limit [23–25], this is not the case for finite systems of few electrons confined in a finite region. Finite systems of electrons are sensitive to the geometry of the finite jellium domain (the electron-depleted region) where electrons are trapped. As a result, the properties of a finite 2DEG reflect the shape of the chosen positive finite jellium background [26, 27]. Even though the assumption of a finite square domain is perfectly legitimate, a rectangular shape of the finite jellium background is a more general choice that applies to a finite 2DEG model.In this work, we consider a uniformly charged finite rectangular domain (which would represent either a uniformly charged nanoplate or a finite rectangular jellium background for a 2DEG) and calculate exactly the amount of Coulomb electrostatic self-energy stored in that system. We obtain an exact analytic expression for such a quantity as a function of length/width and, thus, shape of the rectangular plate. This way one can show precisely how size and shape influence the electrostatic energy stored in a finite plate with rectangular geometry.The article is organized as follows. In Section2 we explain the theory and show the main results. In Section 3 we discuss the key findings and present some concluding remarks. Details of some challenging calculations that are deemed of mathematical interest are provided in Appendices A, B, C, D, E, and F.


## 2. Calculation of the Coulomb Self-Energy of a Uniformly Charged Rectangular Plate

We consider an arbitrarily shaped rectangular plate with length,Lx, and width, Ly. We assume that the rectangular plate is uniformly charged and contains a total amount of charge, Q. Thus, the uniform surface charge density of the rectangular plate is(1)σ=QLxLy.The Cartesian system of coordinates is chosen so that the rectangular plate is assumed to lie in x-y plane. The origin of the system of coordinates is at the center of the rectangular plate. The x- and y-axes are chosen to be parallel to plate’s edges as shown in Figure 1. For this choice of the coordinative system, the rectangular domain uniformly filled with charge is(2)D:-Lx2≤x≤+Lx2,-Ly2≤y≤+Ly2.We assume Coulomb interaction between elementary charges dq1=σd2r1 and dq2=σd2r2, where ri→=(xi,yi) (i=1,2) are 2D position vectors and d2ri=dxidyi (i=1,2) are elementary surface areas. It is expected that the Coulomb self-energy of the uniformly charged rectangular plate will be shape-dependent. For this reason we denote it as U(Lx,Ly) since it will depend on both Lx and Ly. The quantity to calculate is(3)ULx,Ly=keσ22∫Dd2r1∫Dd2r21r1→-r2→,where ke is Coulomb’s electric constant and D is the domain of integration as specified in (2). The exact calculation of U(Lx,Ly) is very challenging since it involves a nontrivial four-dimensional integral.Figure 1
Schematic view of a uniformly charged rectangular plate with arbitrary length,Lx, and width, Ly. The rectangular plate has a uniform surface charge density, σ=Q/(LxLy), where Q represents the total amount of charge uniformly spread over the area, LxLy.In order to simplify the calculation of the integral expression in (3), we transform the quantity 1/r1→-r2→ the following way:(4)1r1→-r2→=2π∫0∞due-u2r1→-r2→2=2π∫0∞due-u2x1-x22e-u2y1-y22.Substitution of the result from (4) into (3) leads to(5)ULx,Ly=keσ2π∫0∞du∫-Lx/2+Lx/2dx1∫-Lx/2+Lx/2dx2e-u2x1-x22∫-Ly/2+Ly/2dy1∫-Ly/2+Ly/2dy2e-u2y1-y22.One can write the expression in (5) as(6)ULx,Ly=keσ2π∫0∞du∫-Lx/2+Lx/2dx2fu,x2,Lx∫-Ly/2+Ly/2dy2fu,y2,Ly,where the two functions, f(u,x2,Lx) and f(u,y2,Ly), are defined and calculated in Appendix A. Two of the resulting integrals in (6) are calculated in Appendix B. With help from (B.8) and (B.9) and after simple manipulations one rewrites the expression in (6) as(7)ULx,Ly=keQ2π∫0∞duguLxguLy,where the auxiliary function, g(t), has the following form [see (B.7)]:(8)gt=πerf⁡tt+e-t2-1t2.It can be easily verified from (7) that U(Lx,Ly) diverges if Lx=0 (or Ly=0) or both Lx=Ly=0. Note that g(t=0)=1 and ∫0∞dtg(t)=∞ for such a situation.By using the expression forg(t) given in (8) one can write the quantity in (7) more explicitly as(9)ULx,Ly=keQ2π∫0∞duπLxLyerf⁡uLxerf⁡uLyu2+πLxLy2erf⁡uLxu3e-uLy2-1+πLx2Lyerf⁡uLyu3e-uLx2-1+1Lx2Ly21u4e-uLx2-1e-uLy2-1.Calculation of the quantity in (9) involves three different types of integrals as listed below:(10)∫0∞dxerf⁡axerf⁡bxx2=2πasinh-1⁡ba2+bsinh-1⁡ab2,∫0∞dxx3erf⁡axe-b2x2-1=aa2-a2+b2-b2sinh-1⁡ab2,∫0∞dxx4e-a2x2-1e-b2x2-1=23πa2+b23/2-a23/2-b23/2,where a, b are real constants and sinh-1⁡(x)=ln⁡x+x2+1 is the inverse sine hyperbolic function. At this juncture, we point out that the integrals shown in (10) are not ordinary table integrals. Thus, for the benefit of the reader, all the details of the calculations of such integrals are provided in Appendices C, D, and E, respectively. The key point made is that all the one-dimensional integrals appearing in (9) can be calculated exactly. After some careful algebraic manipulations we were able to write the final result for the Coulomb self-energy of a uniformly charged rectangular plate as(11)ULx,Ly=keQ21Lxsinh-1⁡LxLy+1Lysinh-1⁡LyLx+13LxLy2+LyLx2-1Lx2+1Ly2Lx2+Ly2.Note that the expression in (11) allows one to immediately see the expected result:(12)ULx,Ly=ULy,Lx.The expression in (11) can be cast in a different form to show how the energy varies with size. In such a scenario, one must assume that at least one of the lengths (Lx or Ly) is nonzero. For instance, let us assume that Lx≠0 which means that we can use keQ2/Lx as unit of energy. Let us now introduce a dimensionless parameter:(13)α=LyLx≥0.For such a choice one has(14)ULx,Ly=αLx=keQ2LxFα,where(15)Fα=sinh-1⁡1α+1αsinh-1⁡α+131α2+α-1+1α21+α2.A plot of F(α) as a function of α is shown in Figure 2. Note that F(α→0)→∞ which is consistent with the well-known fact that the Coulomb self-energy of a uniformly charged line diverges if charges interact with a standard (inverse distance) Coulomb interaction potential.Figure 2
The Coulomb self-energy of a uniformly charged rectangular plate,U(Lx,Ly), can be expressed in units of keQ2/Lx for Lx≠0 in terms of a function, F(α), where α=Ly/Lx≥0 is a nonnegative dimensionless parameter. The value α=1 represents a uniformly charged square. The value α=0 represents a uniformly charged line with length, Lx, in which a total charge, Q, is uniformly spread over its length. The values of parameter α in the plot vary from α=0.01 to α=2 in steps of Δα=0.01.For the special case of a uniformly charged square plate we have(16)Lx=Ly=L.The expression for the Coulomb self-energy of a uniformly charged square plate becomes(17)UL,L=keQ2L2sinh-1⁡1+21-23=keQ2L2ln⁡1+2+21-23,where we used the fact that sinh-1⁡1=ln⁡(1+2). This result can also be proven directly starting from (7) after noting that(18)UL,L=keQ2L1π∫0∞dtgt2.The resulting integral, ∫0∞dtg(t)2, is calculated in Appendix F. Substitution of the result from (F.6) to (18) leads to the expression in (17) which represents the exact value of the Coulomb self-energy of a uniformly charged square plate [28] with length L containing a total amount of charge Q.


## 3. Conclusions

To conclude, we calculated in exact closed form the Coulomb self-energy (namely, the amount of stored electrostatic energy) of a uniformly charged rectangular plate with arbitrary length,Lx, and width, Ly. We introduced a suitable mathematical transformation of variables which enabled us to obtain the Coulomb self-energy in one-dimensional integral form as reported in (7). Such an integral expression was used as a starting point to verify that the Coulomb self-energy diverges in the limit when at least one of the lengths goes to zero (namely, Lx→0 or Ly→0 limit). From that point on, we focused our attention on the general case scenario of arbitrary length and width. The exact closed form solution of the problem for arbitrary Lx and Ly was obtained after calculating the tedious one-dimensional integrals appearing in (9).The exact expression of the Coulomb self-energy of a uniformly charged rectangular plate is written in (11) and depends on length and width (thus, shape) of the plate. The general result for a uniformly charged rectangular plate reduces to the expected value of a square plate when length and width are equal [see (17)]. Knowing the exact form of the Coulomb self-energy of a uniformly charged rectangular plate as a function of length/width and shape parameters may help one analyze how electrostatic energy is stored in various uniformly charged plates with rectangular shapes without resorting to approximations. This can be useful to understand the properties of various electronic nanosystems made up of charged nanoplates. Such situations are often encountered in studies of 2D nanoscale structures or metallic thin films where the dominant interactions are electrostatic. It is also important to remark that several integral formulae that were derived in the process do not appear to be standard and, thus, special care was required when dealing with them. Therefore, some mathematical derivations (typically, those appearing in the Appendices) are deemed of interest on their own from a mathematical point of view.



---

*Source: 7207536-2016-12-18.xml*