# A Nanomesoporous Catalyst from Modified Red Mud and Its Application for Methane Decomposition to Hydrogen Production

Authors: Xiaoke Fang; Quanrun Liu; Peng Li; Haipeng Li; Fenghai Li; Guangxu Huang
Journal: Journal of Nanomaterials
 (2016)

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## Abstract

A type of nanomesoporous modified red mud (MRM) catalyst was prepared and utilized for catalytic methane decomposition (CMD) to produce hydrogen. The modification process significantly simplified the mineral composition of the red mud (RM); in the meantime, the physical and chemical structure of RM was changed. TEM images suggested that MRM was a kind of nanomesoporous material assembled by a number of uniformly nanoscale particles, BET results showed that the pore size distributions of MRM were ranged from 3 to 12 nm, and the specific surface area and total pore volumes of red mud improved from 8.00 m2/g and 0.08 cm3/g to 190.61 m2/g and 0.39 cm3/g, respectively. The catalytic performance of the catalysts has been tested at 800°C; the results showed that MRM exhibited much higher activity and stability than RM for CMD.


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## Body

## 1. Introduction

Hydrogen has been recognized as a clean and environmentally friendly energy and attracted widespread attention [1]. The conventional hydrogen production methods such as steam methane reformation [2, 3] and partial oxidation of methane [4, 5] will generate the by-products CO2, which needs further to be separated and significantly contributes to global warming. Since only hydrogen and carbon are formed in catalytic methane decomposition (CMD) process, CMD has been regarded [6] as one of the most promising methods to prepare hydrogen. Transition metals, such as Fe [7–9], Co [10], and Ni [11–13], have been widely used as catalyst for CMD due to their high activity and relatively low reaction temperature. The catalyst supports will also affect the dispersion of active metals and the catalytic performances of the metal catalysts, generally SiO2, Al2O3, MgO, and some carbon materials have been used as the supports [14–17] in these catalyst systems.Red mud (RM), a harmful by-product of the aluminum processing industry, has been classified as hazardous waste because of its caustic/alkaline nature [18]. Red mud mainly contains aluminum, iron, silicon, titanium oxides, and hydroxides, meanwhile, iron is one of the most well-known active components for CMD, the aluminum and silicon oxides are recognized as superior catalyst support, and these characteristics made red mud possess the potential value for catalytic application [19]. Due to its low cost, high poisoning, and sintering resistance, red mud has been studied as catalyst for a variety of reactions, such as hydrogenation [20], hydrodechlorination [21], exhaust gas clean-up [22], and catalytic combustion of methane [23]. However, few literatures reported red mud use as catalyst for CMD. Balakrishnan et al. [24] directly utilized three red mud samples for CMD, but not all of the samples showed fine performance and stability; the most effective sample showed the highest activity attributed to the highest proportion of iron, but the active time just lasted 140 minutes. Kim et al. [25] studied the performance of red mud-based catalysts for the complete oxidation of volatile organic compounds, which showed that the modified red mud exhibits much higher activity than RM. Therefore, we speculated that the poor textural properties may greatly limit the catalytic performance of red mud.In this work, we utilized red mud to prepare a type of catalyst that applies to methane decomposition for hydrogen production. Our purpose is restructuring the mineral composition and modifying the textural properties of red mud, so as to improve the activity and/or stability for CMD.


## 2. Experimental

### 2.1. Modification of Red Mud

The red mud sample was provided by Henan Zhongmei Aluminum Corporation, China. The sample was dried at 105°C for 2 h, then ground, and sieved to a size of <75μm.The modified red mud (MRM) was prepared by the typical sol-gel method. 10 g red mud was dissolved in 500 mL 1 M HCl solution under strring for 2 h at 60°C; then the resulting solution was precipitated by adding aqueous ammonia until pH reached 8. The obtained samples were filtered, washed by deionized water and anhydrous ethanol several times, dried at 105°C, then calcined at 600°C for 2 h (the main chemical composition of RM and MRM is showed in Table1), and finally sieved to a size of <75 μm.Table 1
The XRF analysis of dry RM and MRM.
Samples
Main compositions (%)
Al2O3
SiO2
Fe2O3
TiO2
CaO
MgO
Na2O
Dry RM
25.95
18.35
16.10
4.77
18.19
2.49
4.33
MRM
32.18
23.25
21.98
6.43
2.23
2.87
0.57


### 2.2. Catalytic Methane Decomposition

The reaction of catalytic methane decomposition took place in a vertical stainless steel fixed-bed reactor (8 mm i.d.). About 0.5 g catalyst was placed into the center of the reactor, heated to the reaction temperature under the N2 atmosphere; N2 flow rate was 30 mL/min. Then the pure CH4 (99.99 vol.%) instead of N2 was fed into the reactor with a total volumetric hourly space velocity (VHSV) of 4.8 L/(h·gcat). The gas products were analyzed by gas analyzers, adopting the advanced nondispersive infrared (NDIR) technology and thermal conductivity detector (TED) technology to measure the volume percentage of products (CO, CO2, O2, CH4, H2, and C
n
H
m). The conversion of methane was calculated from the following expression [26]:(1)
x
C
H
4
=
%
H
2
200
-
%
H
2
.


### 2.3. Characterization

X-ray diffraction (XRD) analysis was performed on a Bruker-AXS D8 Advance diffractometer, with Cu Kα radiation at 40 kV and 25 mA in a scanning range of 10–90° (2θ), with a step size of 0.2° and a counting rate of 2 s per step. Energy dispersive X-ray fluorescence (EDXRF) analysis was conducted on Magix-PW2403 energy dispersive X-ray fluorescence analyzer. N2 adsorption/desorption isotherms were obtained on the Quantachrome AsiQM0000-3 sorption analyzer; before carrying out the measurement, each sample was outgassed at 180°C for 6 h. Thermogravimetry-differential thermal gravity (TG-DTG) analysis was done on a NETZSCH STA449C Simultaneous Thermal Analyzer, the temperature range from room temperature to 800°C. Scanning electron microscopy (SEM) was conducted on FEI Quanta-250 PEG, applied to record the morphology of the samples before and after CMD reaction. Transmission electron microscopy (TEM) analysis was performed on a JEOL JEM-2100 microscope, operating at 200 kV. The samples were dispersed in ethanol and treated with ultrasound for 5 min and then deposited on a copper grid coated with preformed holey carbon film.


## 2.1. Modification of Red Mud

The red mud sample was provided by Henan Zhongmei Aluminum Corporation, China. The sample was dried at 105°C for 2 h, then ground, and sieved to a size of <75μm.The modified red mud (MRM) was prepared by the typical sol-gel method. 10 g red mud was dissolved in 500 mL 1 M HCl solution under strring for 2 h at 60°C; then the resulting solution was precipitated by adding aqueous ammonia until pH reached 8. The obtained samples were filtered, washed by deionized water and anhydrous ethanol several times, dried at 105°C, then calcined at 600°C for 2 h (the main chemical composition of RM and MRM is showed in Table1), and finally sieved to a size of <75 μm.Table 1
The XRF analysis of dry RM and MRM.
Samples
Main compositions (%)
Al2O3
SiO2
Fe2O3
TiO2
CaO
MgO
Na2O
Dry RM
25.95
18.35
16.10
4.77
18.19
2.49
4.33
MRM
32.18
23.25
21.98
6.43
2.23
2.87
0.57


## 2.2. Catalytic Methane Decomposition

The reaction of catalytic methane decomposition took place in a vertical stainless steel fixed-bed reactor (8 mm i.d.). About 0.5 g catalyst was placed into the center of the reactor, heated to the reaction temperature under the N2 atmosphere; N2 flow rate was 30 mL/min. Then the pure CH4 (99.99 vol.%) instead of N2 was fed into the reactor with a total volumetric hourly space velocity (VHSV) of 4.8 L/(h·gcat). The gas products were analyzed by gas analyzers, adopting the advanced nondispersive infrared (NDIR) technology and thermal conductivity detector (TED) technology to measure the volume percentage of products (CO, CO2, O2, CH4, H2, and C
n
H
m). The conversion of methane was calculated from the following expression [26]:(1)
x
C
H
4
=
%
H
2
200
-
%
H
2
.


## 2.3. Characterization

X-ray diffraction (XRD) analysis was performed on a Bruker-AXS D8 Advance diffractometer, with Cu Kα radiation at 40 kV and 25 mA in a scanning range of 10–90° (2θ), with a step size of 0.2° and a counting rate of 2 s per step. Energy dispersive X-ray fluorescence (EDXRF) analysis was conducted on Magix-PW2403 energy dispersive X-ray fluorescence analyzer. N2 adsorption/desorption isotherms were obtained on the Quantachrome AsiQM0000-3 sorption analyzer; before carrying out the measurement, each sample was outgassed at 180°C for 6 h. Thermogravimetry-differential thermal gravity (TG-DTG) analysis was done on a NETZSCH STA449C Simultaneous Thermal Analyzer, the temperature range from room temperature to 800°C. Scanning electron microscopy (SEM) was conducted on FEI Quanta-250 PEG, applied to record the morphology of the samples before and after CMD reaction. Transmission electron microscopy (TEM) analysis was performed on a JEOL JEM-2100 microscope, operating at 200 kV. The samples were dispersed in ethanol and treated with ultrasound for 5 min and then deposited on a copper grid coated with preformed holey carbon film.


## 3. Results and Discussion

### 3.1. XRD and XRF Analysis

Figure1 shows the XRD patterns of catalysts (dry RM and MRM) before and after catalytic methane decomposition (CMD); Table 1 shows the main chemical composition (detected by EDXRF) of dry RM and MRM. From the pattern of dry RM, the characteristic diffraction peaks due to hydrogarnet, cancrinite, calcite, and calcium titanium oxide can be observed obviously; after modification process, those peaks can not be detected in the pattern of MRM, indicating that these species were decomposed into another species (such as Al2O3, SiO2, and TiO2) during modification process. The other contents in dry RM such as iron oxide hydroxide (FeOOH) and bayerite (Al(OH)3) were transformed into Fe2O3 and Al2O3 during modification, respectively. As Table 1 shows, the contents of CaO and Na2O in MRM are much lower than those in dry RM, suggesting that most of Na and Ca have been removed during modification process, and the contents of other compositions except CaO and Na2O are higher than that of dry RM.Figure 1
The XRD patterns of fresh and used catalysts. 1, hydrogarnet (3CaO·Al2O3·SiO2·4H2O); 2, cancrinite (Na6CaAl6Si6(CO3)O24·2H2O); 3, calcite (CaCO3); 4, iron oxide hydroxide (FeOOH); 5, bayerite (Al(OH)3); 6, hematite (Fe2O3); 7, aluminum oxide (Al2O3); 8, calcium titanium oxide (CaTiO3); 9, titanium oxide (TiO2); 10, silicon oxide (SiO2); 11, cementite (Fe3C); 12, graphitic carbon (C); and 13, iron (Fe).From the XRD patterns of MRM after CMD, we can observe that the characteristic peaks are attributed to the species of cementite [27] (Fe3C) with 2θ being 26.413°, 37.633°, 42.893°, 43.763°, 44.575°, 45.884°, and 49.131°, iron (44.669°), and graphitic carbon (26.381°, 54.542°), and the peak ascribed to Fe2O3 species disappeared, which suggests that almost all the Fe2O3 species in MRM have been reduced into Fe during CMD; at the same time, the CMD reaction accompanied the carbon deposition and formation of cementite. An interesting phenomenon that one should pay attention to is that the diffraction peaks due to Fe2O3 species (33.152°, 43.518°) still can be detected in the pattern of dry RM after CMD, which indicates that part of the Fe2O3 species in dry RM probably has been covered by the other compositions, resulting in the fact that this part of Fe species has no activity for CMD. Moreover, the peak intensities with 2θ being 43.763° (Fe3C) and 44.669° (Fe) in the XRD patterns of MRM after CMD are much higher than those of dry RM after CMD; this behavior indicates that far more Fe and Fe3C species were generated in MRM after CMD than those of dry RM after CMD. Therefore, much larger amount of active Fe species was generated in MRM compared to that of dry RM during CMD; this behavior should lead to higher activity of MRM than that of dry RM for CMD.


### 3.2. TG-DTG Analysis

Figure2 shows the thermogravimetry (TG) and derivative thermogravimetry (DTG) curves of dry RM and uncalcined MRM precursor. The total weight loss of RM was 15.55% of the total weight from 35 to 800°C, and the TG curve showed three weight loss steps. The first weight loss (5.21%) step occurred in the temperature range from 35 to 129°C, attributed to the evaporation of physically adsorbed water; the second step showed a rapid weight loss (6.82%) between 129 and 281°C which was ascribed to the removal of crystal water, partial decomposition of hydroxides, such as gibbsite decomposed into boehmite [28], and transformation of goethite to hematite [29]; the third weight loss (3.52%) step occurred in the temperature range from 281 to 800°C, which may be due to the decomposition of carbonate [30] and remaining hydroxides. The TG curve of the uncalcined MRM catalyst precursor showed three weight loss steps that were similar to those of RM, exhibiting that continuous weight loss was approximately 26.92% of the total weight from 22 to 800°C. The first weight loss of 8.52% from 22 to 130°C was mainly ascribed to the physically adsorbed water; the second weight loss of 12.29% from 130 to 364°C may be due to gibbsite and Fe hydroxide (formed in the homogeneous precipitation process during catalyst preparation) decomposed into γ-Al2O3 [31] and hematite, respectively; the third weight loss of 6.11% in the temperature range from 364 to 800°C was attributed to decomposition of the remaining hydroxides. The uncalcined MRM catalyst precursor exhibited a greater total weight loss than RM, which indicated that much higher hydroxide content in uncalcined MRM precursor than in RM, which should be attributed to the hydrogarnet and cancrinite in RM that have been dissolved by HCl, and then the aluminum ion transformed into aluminum hydroxide during the precipitation process. The purpose of the calcining process in catalyst pretreatment is to transform the hydroxides into metal-oxides and improve the pore structure of the catalyst; however, high temperature will cause the pore structure sintering and lead to the surface areas decreasing [32]. Therefore, based on the above analysis, the calcining temperature chosen in this study was 600°C. To investigate the morphology and textual properties of the two samples (dry RM and MRM), transmission electron microscopy (TEM) and nitrogen-adsorption-desorption were carried out in our following work.Figure 2
The TG-DTG curves of dry RM and MRM.


### 3.3. Morphology and Textural Properties of Catalysts

Figures3(a) and 3(b) show the TEM images of dry RM and MRM, respectively. From Figure 3(a), we can observe a number of particles with different sizes and forms; the sizes of some large particles are larger than 100 nm. After modification, in Figure 3(b), the particles of MRM change into a number of uniformly nanoscale particles that are much smaller than the original particles in RM; meanwhile, MRM shows an abundant wormhole-like pore structure. This behavior should indicate that the modification process greatly affects the pore structure of MRM, which may be in favor of improving the catalytic performance of MRM for CMD. Figures 3(c) and 3(d) show the SEM images of dry RM and MRM, respectively. It can be observed that the large particles of dry RM with the wrapped and embedded status were transformed into small particles of MRM; this phenomenon is consistent with the results that TEM images showed above. Figures 3(e) and 3(f) show the EDX-map (Fe distribution) of dry RM and MRM, respectively. By comparing Figures 3(e) and 3(f), it is obviously found that the content of Fe distributed on the external structure of MRM is much higher than that of dry RM. This interesting phenomenon may indicate that part of the Fe species in dry RM (which have been covered by other compositions) turned exposed; attributes to the modified process changed the structure of dry RM.Figure 3
The TEM images of dry RM (a) and MRM (b); SEM images of dry RM (c) and MRM (d); EDX-map (Fe distribution) of RM (e) and MRM (f).
(a)
(b)
(c)
(d)
(e)
(f)Figure4 shows the N2-adsorption-desorption isotherms (a) and the corresponding pore size distribution curves (b) of the two samples. The isotherm of dry RM can be classified as classical type I (according to the IUPAC), and there is no apparent peak in the pore size distribution curve (see Figure 4(b)); this characteristic seriously limits the active metal contacting with methane during CMD. The isotherm of MRM can be categorized as classical type IV; the hysteresis loops belong to the H2 type with steep adsorption and desorption branches, suggesting that MRM possesses a typical mesoporous structure [32]. The pore size of MRM (see Figure 4(b)) was mainly distributed from 3 to 12 nm, which confirms that MRM is a kind of nanomesoporous material. As presented in Table 2, after modification, the specific surface area and total pore volumes of dry RM improve from 8.00 m2/g and 0.08 cm3/g to 190.61 m2/g and 0.39 cm3/g, respectively, signifying that the textural properties of dry RM have been greatly improved after modification, which is corresponding with the results that Figures 3(a) and 3(b) showed above. We inferred that the enhancement of surface area and pore volumes may be helpful in improving the activity and/or stability of MRM for CMD; therefore, the catalytic performance of catalysts has been tested to confirm this inference.Table 2
The textural properties of dry RM and MRM.
Samples
Surface areaa (m2/g)
V
t
o
t (cm3/g)
D
DFT-ads
b (nm)
Dry RM
8.00
0.08
14.60
MRM
190.61
0.39
4.80
aMultipoint BET surface area.
bMaximum of DFT pore diameter as determined from the adsorption branch.Figure 4
The BET analysis of dry RM and MRM.
(a)
(b)


### 3.4. Activity of Catalysts in Methane Decomposition

The activity and stability of catalysts (dry RM and MRM) for CMD at 800°C were compared, and the results were showed in Figure5. Figure 5(a) shows the gas production (H2 and CO) volume fraction curves, and Figure 5(b) shows the methane conversion kinetic curves.Figure 5
The gas volume fraction curves (a) and methane conversion curves (b) of the catalysts for CMD at 800°C.
(a)
(b)In Figure5(a), we can observe that the initial stage of the reaction will accompany the production of CO and H2, and CO is derived from the reduction of Fe2O3 species in the temperature of 800°C. The CO volume fraction curve of dry RM shows quick declining in the initial reaction; then CO disappeared after 70 minutes; it can be inferred that, after 70 minutes of the reaction, the exposed Fe2O3 species have been reduced into metal Fe by methane. The CO volume fraction curve of MRM shows two peaks and CO disappeared after 110 minutes of reaction. Because the modification process enhanced the specific surface area and total pore volume of MRM, almost all the Fe2O3 species in MRM were exposed, so that much higher content of exposed Fe2O3 species led to much longer reducing time under the same conditions; the first peak of CO volume fraction curve may be due to the reduction of the Fe2O3 species in external structure of MRM, while the second peak was probably ascribed to the reduction of the Fe2O3 species in internal structure of MRM. The H2 volume fraction curve of dry RM rises quickly until attaining its maximum (21.21%) at 70 minutes of the reaction, and then it gradually declines as the reaction continues. An interesting phenomenon that should be paid attention to is that the H2 volume fraction curve of MRM exhibits two peaks; the first peak (25.04%) appears at 110 minutes of the reaction, which is much later than when dry RM attains its maximum activity. However, 110 minutes later, MRM does not attain its maximum activity; the H2 volume fraction curve shows a decreasing-increasing variation tendency from 110 to 340 minutes. As mentioned above, MRM is assembled by a number of uniformly nanoscale particles and shows abundant wormhole-like pore structure (see Figure 3(b)), even though all the exposed Fe2O3 species in MRM have been reduced into Fe after 110 minutes’ reaction, but the adsorption of methane molecules on the new generated active center is not yet saturated; meanwhile, the active center in external structure of the catalyst was partly covered by the carbon deposits and deactivated [33]. Therefore, 110 minutes later, the H2 volume fraction curve shows a short time decrease variation tendency; after the following 40 minutes, the methane molecules are continually diffusing into the internal pore structure of MRM and occupying the active center; the H2 volume fraction curve of MRM then shows an increase variation tendency and attains its maximum (41.22%) at 340 minutes, which may suggest that the adsorption of methane molecules on the active center is saturated at that time; then the H2 volume fraction curve is gradually declining as the reaction continues. The methane conversion curves (see Figure 5(b)) show similar tendency as H2 volume fraction curves; the peak methane conversion of MRM obtained was 25.99%, much higher than those of dry RM (11.88%); meanwhile, MRM exhibits much higher activity and much longer lifetime than those of dry RM; this behavior suggests that modification process significantly improved the activity and stability of dry RM for CMD.In order to study the effect of CMD process influencing the morphology and structure of MRM, we utilized SEM to investigate the morphologies of MRM after CMD in our following work.


### 3.5. The Morphologies of MRM after CMD

The SEM image of MRM after CMD is shown in Figure6. Compared with Figure 3(d), Figure 6 shows many differences that the carbon deposits covered the surface and embedded into the pore structure of the catalyst, which should result in the deactivation of the catalyst [34]. These carbons can be classified into two types based on their morphologies: spheric-like carbons and filamentous carbons; the amount of spheric-like carbons is far more than that of filamentous carbons. The formation of the spheric-like carbons is ascribed to the iron species covered by graphite layers [9], and this part of iron species that have been covered should be deactivated for methane decomposition, because the iron species can not contact with methane molecules; the filamentous carbons formed on metal catalysts could help the metal remaining exposed and active [6]. Therefore, the deactivation of the catalyst should be attributed to the formation of large amount of spheric-like carbons.Figure 6
The SEM images of MRM after CMD.


## 3.1. XRD and XRF Analysis

Figure1 shows the XRD patterns of catalysts (dry RM and MRM) before and after catalytic methane decomposition (CMD); Table 1 shows the main chemical composition (detected by EDXRF) of dry RM and MRM. From the pattern of dry RM, the characteristic diffraction peaks due to hydrogarnet, cancrinite, calcite, and calcium titanium oxide can be observed obviously; after modification process, those peaks can not be detected in the pattern of MRM, indicating that these species were decomposed into another species (such as Al2O3, SiO2, and TiO2) during modification process. The other contents in dry RM such as iron oxide hydroxide (FeOOH) and bayerite (Al(OH)3) were transformed into Fe2O3 and Al2O3 during modification, respectively. As Table 1 shows, the contents of CaO and Na2O in MRM are much lower than those in dry RM, suggesting that most of Na and Ca have been removed during modification process, and the contents of other compositions except CaO and Na2O are higher than that of dry RM.Figure 1
The XRD patterns of fresh and used catalysts. 1, hydrogarnet (3CaO·Al2O3·SiO2·4H2O); 2, cancrinite (Na6CaAl6Si6(CO3)O24·2H2O); 3, calcite (CaCO3); 4, iron oxide hydroxide (FeOOH); 5, bayerite (Al(OH)3); 6, hematite (Fe2O3); 7, aluminum oxide (Al2O3); 8, calcium titanium oxide (CaTiO3); 9, titanium oxide (TiO2); 10, silicon oxide (SiO2); 11, cementite (Fe3C); 12, graphitic carbon (C); and 13, iron (Fe).From the XRD patterns of MRM after CMD, we can observe that the characteristic peaks are attributed to the species of cementite [27] (Fe3C) with 2θ being 26.413°, 37.633°, 42.893°, 43.763°, 44.575°, 45.884°, and 49.131°, iron (44.669°), and graphitic carbon (26.381°, 54.542°), and the peak ascribed to Fe2O3 species disappeared, which suggests that almost all the Fe2O3 species in MRM have been reduced into Fe during CMD; at the same time, the CMD reaction accompanied the carbon deposition and formation of cementite. An interesting phenomenon that one should pay attention to is that the diffraction peaks due to Fe2O3 species (33.152°, 43.518°) still can be detected in the pattern of dry RM after CMD, which indicates that part of the Fe2O3 species in dry RM probably has been covered by the other compositions, resulting in the fact that this part of Fe species has no activity for CMD. Moreover, the peak intensities with 2θ being 43.763° (Fe3C) and 44.669° (Fe) in the XRD patterns of MRM after CMD are much higher than those of dry RM after CMD; this behavior indicates that far more Fe and Fe3C species were generated in MRM after CMD than those of dry RM after CMD. Therefore, much larger amount of active Fe species was generated in MRM compared to that of dry RM during CMD; this behavior should lead to higher activity of MRM than that of dry RM for CMD.


## 3.2. TG-DTG Analysis

Figure2 shows the thermogravimetry (TG) and derivative thermogravimetry (DTG) curves of dry RM and uncalcined MRM precursor. The total weight loss of RM was 15.55% of the total weight from 35 to 800°C, and the TG curve showed three weight loss steps. The first weight loss (5.21%) step occurred in the temperature range from 35 to 129°C, attributed to the evaporation of physically adsorbed water; the second step showed a rapid weight loss (6.82%) between 129 and 281°C which was ascribed to the removal of crystal water, partial decomposition of hydroxides, such as gibbsite decomposed into boehmite [28], and transformation of goethite to hematite [29]; the third weight loss (3.52%) step occurred in the temperature range from 281 to 800°C, which may be due to the decomposition of carbonate [30] and remaining hydroxides. The TG curve of the uncalcined MRM catalyst precursor showed three weight loss steps that were similar to those of RM, exhibiting that continuous weight loss was approximately 26.92% of the total weight from 22 to 800°C. The first weight loss of 8.52% from 22 to 130°C was mainly ascribed to the physically adsorbed water; the second weight loss of 12.29% from 130 to 364°C may be due to gibbsite and Fe hydroxide (formed in the homogeneous precipitation process during catalyst preparation) decomposed into γ-Al2O3 [31] and hematite, respectively; the third weight loss of 6.11% in the temperature range from 364 to 800°C was attributed to decomposition of the remaining hydroxides. The uncalcined MRM catalyst precursor exhibited a greater total weight loss than RM, which indicated that much higher hydroxide content in uncalcined MRM precursor than in RM, which should be attributed to the hydrogarnet and cancrinite in RM that have been dissolved by HCl, and then the aluminum ion transformed into aluminum hydroxide during the precipitation process. The purpose of the calcining process in catalyst pretreatment is to transform the hydroxides into metal-oxides and improve the pore structure of the catalyst; however, high temperature will cause the pore structure sintering and lead to the surface areas decreasing [32]. Therefore, based on the above analysis, the calcining temperature chosen in this study was 600°C. To investigate the morphology and textual properties of the two samples (dry RM and MRM), transmission electron microscopy (TEM) and nitrogen-adsorption-desorption were carried out in our following work.Figure 2
The TG-DTG curves of dry RM and MRM.


## 3.3. Morphology and Textural Properties of Catalysts

Figures3(a) and 3(b) show the TEM images of dry RM and MRM, respectively. From Figure 3(a), we can observe a number of particles with different sizes and forms; the sizes of some large particles are larger than 100 nm. After modification, in Figure 3(b), the particles of MRM change into a number of uniformly nanoscale particles that are much smaller than the original particles in RM; meanwhile, MRM shows an abundant wormhole-like pore structure. This behavior should indicate that the modification process greatly affects the pore structure of MRM, which may be in favor of improving the catalytic performance of MRM for CMD. Figures 3(c) and 3(d) show the SEM images of dry RM and MRM, respectively. It can be observed that the large particles of dry RM with the wrapped and embedded status were transformed into small particles of MRM; this phenomenon is consistent with the results that TEM images showed above. Figures 3(e) and 3(f) show the EDX-map (Fe distribution) of dry RM and MRM, respectively. By comparing Figures 3(e) and 3(f), it is obviously found that the content of Fe distributed on the external structure of MRM is much higher than that of dry RM. This interesting phenomenon may indicate that part of the Fe species in dry RM (which have been covered by other compositions) turned exposed; attributes to the modified process changed the structure of dry RM.Figure 3
The TEM images of dry RM (a) and MRM (b); SEM images of dry RM (c) and MRM (d); EDX-map (Fe distribution) of RM (e) and MRM (f).
(a)
(b)
(c)
(d)
(e)
(f)Figure4 shows the N2-adsorption-desorption isotherms (a) and the corresponding pore size distribution curves (b) of the two samples. The isotherm of dry RM can be classified as classical type I (according to the IUPAC), and there is no apparent peak in the pore size distribution curve (see Figure 4(b)); this characteristic seriously limits the active metal contacting with methane during CMD. The isotherm of MRM can be categorized as classical type IV; the hysteresis loops belong to the H2 type with steep adsorption and desorption branches, suggesting that MRM possesses a typical mesoporous structure [32]. The pore size of MRM (see Figure 4(b)) was mainly distributed from 3 to 12 nm, which confirms that MRM is a kind of nanomesoporous material. As presented in Table 2, after modification, the specific surface area and total pore volumes of dry RM improve from 8.00 m2/g and 0.08 cm3/g to 190.61 m2/g and 0.39 cm3/g, respectively, signifying that the textural properties of dry RM have been greatly improved after modification, which is corresponding with the results that Figures 3(a) and 3(b) showed above. We inferred that the enhancement of surface area and pore volumes may be helpful in improving the activity and/or stability of MRM for CMD; therefore, the catalytic performance of catalysts has been tested to confirm this inference.Table 2
The textural properties of dry RM and MRM.
Samples
Surface areaa (m2/g)
V
t
o
t (cm3/g)
D
DFT-ads
b (nm)
Dry RM
8.00
0.08
14.60
MRM
190.61
0.39
4.80
aMultipoint BET surface area.
bMaximum of DFT pore diameter as determined from the adsorption branch.Figure 4
The BET analysis of dry RM and MRM.
(a)
(b)


## 3.4. Activity of Catalysts in Methane Decomposition

The activity and stability of catalysts (dry RM and MRM) for CMD at 800°C were compared, and the results were showed in Figure5. Figure 5(a) shows the gas production (H2 and CO) volume fraction curves, and Figure 5(b) shows the methane conversion kinetic curves.Figure 5
The gas volume fraction curves (a) and methane conversion curves (b) of the catalysts for CMD at 800°C.
(a)
(b)In Figure5(a), we can observe that the initial stage of the reaction will accompany the production of CO and H2, and CO is derived from the reduction of Fe2O3 species in the temperature of 800°C. The CO volume fraction curve of dry RM shows quick declining in the initial reaction; then CO disappeared after 70 minutes; it can be inferred that, after 70 minutes of the reaction, the exposed Fe2O3 species have been reduced into metal Fe by methane. The CO volume fraction curve of MRM shows two peaks and CO disappeared after 110 minutes of reaction. Because the modification process enhanced the specific surface area and total pore volume of MRM, almost all the Fe2O3 species in MRM were exposed, so that much higher content of exposed Fe2O3 species led to much longer reducing time under the same conditions; the first peak of CO volume fraction curve may be due to the reduction of the Fe2O3 species in external structure of MRM, while the second peak was probably ascribed to the reduction of the Fe2O3 species in internal structure of MRM. The H2 volume fraction curve of dry RM rises quickly until attaining its maximum (21.21%) at 70 minutes of the reaction, and then it gradually declines as the reaction continues. An interesting phenomenon that should be paid attention to is that the H2 volume fraction curve of MRM exhibits two peaks; the first peak (25.04%) appears at 110 minutes of the reaction, which is much later than when dry RM attains its maximum activity. However, 110 minutes later, MRM does not attain its maximum activity; the H2 volume fraction curve shows a decreasing-increasing variation tendency from 110 to 340 minutes. As mentioned above, MRM is assembled by a number of uniformly nanoscale particles and shows abundant wormhole-like pore structure (see Figure 3(b)), even though all the exposed Fe2O3 species in MRM have been reduced into Fe after 110 minutes’ reaction, but the adsorption of methane molecules on the new generated active center is not yet saturated; meanwhile, the active center in external structure of the catalyst was partly covered by the carbon deposits and deactivated [33]. Therefore, 110 minutes later, the H2 volume fraction curve shows a short time decrease variation tendency; after the following 40 minutes, the methane molecules are continually diffusing into the internal pore structure of MRM and occupying the active center; the H2 volume fraction curve of MRM then shows an increase variation tendency and attains its maximum (41.22%) at 340 minutes, which may suggest that the adsorption of methane molecules on the active center is saturated at that time; then the H2 volume fraction curve is gradually declining as the reaction continues. The methane conversion curves (see Figure 5(b)) show similar tendency as H2 volume fraction curves; the peak methane conversion of MRM obtained was 25.99%, much higher than those of dry RM (11.88%); meanwhile, MRM exhibits much higher activity and much longer lifetime than those of dry RM; this behavior suggests that modification process significantly improved the activity and stability of dry RM for CMD.In order to study the effect of CMD process influencing the morphology and structure of MRM, we utilized SEM to investigate the morphologies of MRM after CMD in our following work.


## 3.5. The Morphologies of MRM after CMD

The SEM image of MRM after CMD is shown in Figure6. Compared with Figure 3(d), Figure 6 shows many differences that the carbon deposits covered the surface and embedded into the pore structure of the catalyst, which should result in the deactivation of the catalyst [34]. These carbons can be classified into two types based on their morphologies: spheric-like carbons and filamentous carbons; the amount of spheric-like carbons is far more than that of filamentous carbons. The formation of the spheric-like carbons is ascribed to the iron species covered by graphite layers [9], and this part of iron species that have been covered should be deactivated for methane decomposition, because the iron species can not contact with methane molecules; the filamentous carbons formed on metal catalysts could help the metal remaining exposed and active [6]. Therefore, the deactivation of the catalyst should be attributed to the formation of large amount of spheric-like carbons.Figure 6
The SEM images of MRM after CMD.


## 4. Conclusions

Red mud (RM), as the industrial wastes, has been utilized to prepare a type of nanomesoporous catalyst through the modification method. After modification, the mineral composition of dry RM changed and almost all of Na and Ca have been removed; the textural properties of dry RM significantly improved that the specific surface area and total pore volumes improved from 8.00 m2/g and 0.08 cm3/g to 190.61 m2/g and 0.39 cm3/g, respectively; the structure of dry RM transformed into an abundant wormhole-like pore structure assembled by a number of uniformly nanoscale particles; the pore size distributions of modified red mud (MRM) were mainly ranged from 3 to 12 nm. The activity and stability of MRM were much better than those of dry RM for CMD; the peak methane conversion obtained by MRM was 25.99%, much higher than that of dry RM obtained (11.88%) in the same condition.



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*Source: 6947636-2016-04-17.xml*