# Influence of Stratospheric Intrusion on the Surface Ozone Levels in India

Authors: Nandita D. Ganguly
Journal: ISRN Meteorology
 (2012)

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## Abstract

The surface ozone levels in some Indian cities have increased significantly in the recent years. Ozone being toxic to the living system and an important contributor to anthropogenic global warming, enhanced surface ozone may have adverse effects on the air quality and climate. Transport of ozone from the stratosphere to the troposphere causes stratospheric ozone to decrease and tropospheric ozone to increase, which can in turn have serious consequences for life on earth. Since stratosphere-troposphere exchange (STE) is an important factor influencing the ozone concentration in the troposphere, this paper investigates probably for the first time the possible contribution of STE events to the observed enhanced surface ozone levels for cities covering from north to south of India. It is concluded that apart from transport processes and in situ photochemical production, STE also influences the observed high-surface ozone levels in Indian cities to a small extent (8%–16%). STE events producing high-surface ozone levels are found to be higher at high latitudes.


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## Body

## 1. Introduction

The amount of surface ozone at any location depends upon the amount of its supply from the stratosphere, rate of photochemical production, transport from other regions, and the rate of its destruction on the earth’s surface either due to dry deposition or photochemical loss mechanisms [1–3]. Downward transport of stratospheric ozone [4, 5], called stratosphere-troposphere exchange (STE) of ozone is an important and significant natural source of surface ozone. The mechanisms leading to STE are tropopause folds, cutoff lows, and quasiadiabatic transports along isentropic surfaces [5, 6]. Ozone being toxic to the living system, intense exposure to surface ozone may result in persistent decrease in lung function, pneumonia, influenza, asthma, and decrease in crop yield. Transport of ozone from the stratosphere to the troposphere may cause surface ozone levels to increase resulting in adverse consequences for life on earth. The ambient air quality standards for surface ozone in India are 180 μg/m3 (92 ppbv) for 1-hour average and 100 μg/m3 (51 ppbv) for 8-hour average [7].It has been observed in the recent years that the background surface ozone levels have increased significantly in some Indian cities [8, 9]. Several studies suggest that rapid and deep STE events may be associated with severe weather [10–12] and cause ozone peaks at the surface [13, 14]. When compared with high-surface ozone episodes induced photo chemically near the Earth's surface, relatively little study has been reported for high-surface ozone cases induced by STE in India. Although these episodes are relatively uncommon, they have been reported to produce transient peak ozone concentrations of around 100 ppbv at sea level and concentrations in excess of 250 ppbv in mountain regions [15] in other parts of the world. In view of the above observations, this paper is aimed to identify the Indian cities where the surface ozone is likely to be affected by STE by examining all the case studies in detail over a period of 11 years from 1998–2008.


## 2. Measurement Site and Data

The Indian subcontinent lies between 8°N–36°N latitude. The five surface ozone monitoring stations, namely, New Delhi (28.4°N, 77.13°E; 214.42 meters above sea level), Nagpur (21°N, 79°E; 310 meters above sea level), Pune (18.5°N, 73.5°E; 560 meters above sea level), Kodaikanal (10°N, 77.5°E; 2,133meters above sea level), and Thiruvananthapuram (8.28°N, 76.56°E; 60meters above sea level) extending from North to South India (Figure1), have entirely different geographical morphology and hence different local climatic conditions. The topographic map of India depicting the measurement sites was obtained from the website: http://www.mapsindia.com/. The daily maximum surface ozone at New Delhi, Pune, Kodaikanal, and Thiruvananthapuram over the period from 1998–2008 and at Nagpur during the period from 2005–2007 measured by electrochemical method have been obtained from India Meteorological Department (IMD). 5-day back-trajectory at different pressure levels and potential vorticity at the tropopause (100 hPa) has been retrieved from the European Centre for Medium-Range Weather Forecasts (ECMWF). The vertical pressure velocity, relative humidity, and geopotential height maps have been retrieved from NCEP/NCAR reanalysis [16]. Daily global 2.0°×4.0° gridded data of surface carbon monoxide (CO) and methane (CH4) were obtained from TES (Tropospheric Emission Spectrometer) on NASA’s EOS (Earth Observing System) spacecraft. Total Nitrogen dioxide (NO2) column data from Ozone monitoring instrument (OMI) was obtained from the website http://www.temis.nl/. Fire count data representing biomass burning from the ATSR World Fire Atlas has been taken from Ionia products of European Space Agency.Figure 1
Topographic map of India depicting the measurement sites (source:http://www.mapsindia.com/).


## 3. Analysis and Results

The day characterized by maximum surface ozone concentration in each month was identified and the linear trend of this monthly maximum surface ozone data was plotted for the entire period of available data set. The surface ozone levels at Pune and Thiruvananthapuram indicated a small decreasing trend, while that at New Delhi, Nagpur, and Kodaikanal indicated a small increasing trend (Figure2) over the period of study. Several studies in the recent years indicate that surface ozone, even at concentrations less than the ambient air quality standards, can flare harmful effects in human beings [17, 18]. Therefore instead of considering ozone episodes greater than the ambient air quality standard as critical, higher than normal ozone episodes were identified by employing the statistic mean control chart (MCC), and the causes leading to these episodes were investigated in detail.Time series of surface ozone at different Indian cities.
(a)
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(e)MCC is a time plot of observations with a statistically calculated control limit. If the variations in surface ozone follow a normal cyclic pattern throughout the year (due to seasonal changes), then all the points in the time plot should lie within the control limit. When an observation exceeds the upper control limit (UCL), some new and unanticipated source of variation (either natural or anthropogenic) is likely to be operating, and a search for the special cause should be initiated. The UCL for surface ozone at different Indian stations has been estimated statistically [19] from the MCC by using the monthly maximum surface ozone data for the entire period of available data set. The results are summarized in Table 1:
(1)X¯¯=∑XK¯11;R¯=∑RK11,(forNewDelhi,Pune,Kodaikanal,andThiruvananthapuram),(2)X¯¯=∑XK¯3;R¯=∑RK3,(forNagpur),
where XK¯ is the yearly mean surface ozone for n=12 months of the kth year. Range Rk = (Maximum ozone—Minimum ozone) observed for the kth year. k=1,2,3,…, 11 (years from 1998–2008 for New Delhi, Pune, Kodaikanal, and Thiruvananthapuram) and k=1,2,3 (years from 2005–2007 for Nagpur)
(3)UCL=X¯¯+A2R¯.Table 1
Upper control limit (UCL) for surface ozone at different Indian cities, estimated statistically (Gupta and Kapoor, 1993 [19]) from the mean control chart using the monthly maximum surface ozone data at New Delhi, Pune, Kodaikanal, and Thiruvananthapuram over the period from 1998–2008 and at Nagpur during the period from 2005–2007.
City
UCL for surface ozone
New Delhi (28.4°N, 77.13°E)
79.5 ppbv
Nagpur (21°N, 79°E)
57.6 ppbv
Pune (18.5°N, 73.5°E)
57.3 ppbv
Kodaikanal (10°N, 77.5°E)
43.4 ppbv
Thiruvananthapuram (8.28°N, 76.56°E)
47.3 ppbvThe value of constantA2 corresponding to n=12 is 0.266 and is obtained from standard statistical control table [19]. The days characterized by surface ozone concentration higher than UCL was identified from the monthly maximum surface ozone dataset for each station (Figure 3), and the possible association of this unusually high surface ozone concentration with STE was investigated. Potential vorticity (PV) is a measure of the spin of air. Stratospheric air is characterized by high PV and low relative humidity (RH). According to the WMO definition of dynamical tropopause [20], PV values exceeding 1.6 pvu (1 pvu = 10−6 m2 Kkg−1 s−1) at the tropopause indicate the presence of air masses having stratospheric origin. Therefore, the presence of air masses characterized by PV>1.6 and RH<60% has been considered as a signature of stratospheric air similar to that in the study by Cristofanelli et al. [21]. To identify and exclude air masses possibly influenced by polluted air or biomass burning plumes, the CO, CH4, and NO2 concentration and fire counts were taken into account. The 5-day back-trajectories at 1000, 925, and 850 hPa pressure levels were examined to determine the place from where the air parcels had originated. This information was in turn used to check the possibility of horizontal transport of ozone and its precursors from these areas. The vertical pressure velocity (Pa s−1) was examined to confirm the downward transport of ozone from the stratosphere. As pressure decreases with altitude, positive values of vertical pressure velocity indicate sinking motion and negative values indicate rising motion in the atmosphere. The days characterized by higher than normal concentration of CO, CH4, NO2, and fire counts, vertical pressure velocity indicating upward transport of ozone and back trajectories from high ozone or ozone precursor areas were excluded from this study. Further, the geopotential maps in the upper troposphere were examined to detect the formation of cutoff lows. The total ozone concentration was examined for ±10 days from the day of STE event to investigate if the increase in surface ozone was due to tropopause folding.Figure 3
Upper control limit (UCL) for surface ozone at Pune, estimated statistically (Gupta and Kapoor, 1993 [19]) from the mean control chart using the monthly maximum surface ozone data from 1998–2008.One such case study at Pune on 24 November, 2006 is presented as an illustration (Figure4). The geopotential height map at 850 hPa pressure level indicates the formation of a trough, which is typically preceded by stormy weather and colder air at the surface. The vertical pressure velocity at the tropopause indicated downward transport of ozone from the stratosphere. The PV value was >1.6 and RH at the tropopause were low (20%), indicating the presence of air masses having stratospheric origin. The fire counts representing biomass burning were absent at all places lying in and around the station under consideration and along the path of back trajectories. Similar results were observed on all high ozone days at all stations considered in the study. These characteristic features suggest that the enhanced surface ozone observed on these occasions may be a consequence of stratospheric intrusion.(a) Geopotential height (meter) map at 850 hPa, (b) vertical pressure velocity (Pa·s-1) at the tropopause, (c) relative humidity (%) at 300 hPa pressure level, (d) potential vorticity at the tropopause, (e) 5-day back trajectories at 1000 hPa (pink), 925 hPa (red), and 850 hPa (green) pressure levels, (f) tropospheric CO (10-1 ppmv), (g) CH4 (ppmv), (h) NO2 (1015  molecules·cm2), and (i) fire counts at Pune on 24 November 2006 (sources of data: NCEP Reanalysis, ECMWF, TES, OMI, and ASTR world fire atlas).
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(i)Multiple regression analysis (Figure5) was used to determine the amount of dependence of STE events producing high-surface ozone levels on the order of latitude. A regression equation indicates the nature of the relationship between the variables and, in particular, the extent to which the variables are associated with one another. The regression equation and the respective correlation coefficients are noted in the plot. The coefficient of determination “R2” was found to be 0.8216, indicating that STE events producing high-surface ozone levels depend by an amount of 82.16% on the order of the Latitude. This is because deep STE events of ozone occur more frequently at high latitudes [22] compared to low Indian latitudes. Between October and May, the intertropical convergence zone (ITCZ) is located to the south of Thiruvananthapuram [23]. The vertical velocity profiles exhibit a strong ascending motion over the mean position of the ITCZ, and a strong subsidence between 10°N–30°N latitudes [24, 25], thus affecting the STE processes over India. It appears from Figure 5 that STE events influencing the high surface ozone levels in India decrease exponentially with increase in altitude. However, this may be because all the measurement stations having high altitude, which have been considered in this study, lie at low latitudes where deep STE of ozone is not very prominent.Figure representing the percentage dependence of STE events producing high surface ozone levels on the order of latitude and altitude.
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## 4. Conclusions

This paper investigates the possible contribution of STE events to the observed higher than normal surface ozone levels for few Indian cities. It is concluded that apart from transport processes and in situ photochemical production, STE also influences the observed high-surface ozone levels in Indian cities to a small extent (8%–16%). STE events producing high-surface ozone levels are found to be higher at high latitudes.



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*Source: 625318-2012-08-01.xml*