# Investigation on Hot Corrosion Behaviour of Inconel 625 and Incoloy 800H Superalloys with YSZ-Thermal Barrier Coating Under High-Temperature Environment for Bioreactor Applications

Authors: M. Kamatchi Hariharan; A. Anderson; T. R. Praveenkumar; Endalkachew Mosisa
Journal: Journal of Nanomaterials
 (2022)

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## Abstract

Thermal energy storage is one of the promising technologies in the modern era for balancing the peak power demand without emitting much emission. Molten-salt technology plays a dominant role among the varieties of thermal energy storage systems. The difficulty in storing the molten-salt technology requires a storage material with high temperature, corrosion, and oxidation resistance properties. The nickel-based superalloys such as Inconel 625 and Incoloy 800H possess the desired properties to be used as a storage material for the molten salts. In this present work, the Incoloy 800H and Inconel 625 superalloy specimens were taken up for investigation. The specimens were coated with yttria-stabilized zirconia as a thermal barrier coating using a plasma spray process. The sodium chloride and potassium chloride molten salts with a weight fraction of 7 : 3 have been taken with both uncoated and YSZ-coated specimens, and specimens were heated up to 1000°C approximately. The specimens were heated for different hours such as 8, 12, and 16 hours, respectively. The increase in heating time also results in the increase in the tensile property of the specimens. The mechanical testing, such as tensile test and hardness test, was performed to comprehend the mechanical properties. Scanning electron microscope images and X-ray diffraction analysis were made to study the microstructural properties and the corrosion resistance property. From the test results, YSZ-coated specimens possess high corrosion resistance and high mechanical strength compared to the uncoated specimens.


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## Body

## 1. Introduction

Superalloys are an alloy with a high-melting point capability. It includes the outstanding mechanical strength, thermal deformation resistance, good surface stability, and corrosion or oxidation resistance. Super alloys are mostly formed as one single crystal, which increases creep resistance while the grain boundaries may provide strength at low temperatures. Inconel 625 is used for its high strength, excellent fabricability (including joining), and outstanding corrosion resistance. Its service temperatures range from cryogenic to 1800°F (982°C) [1–3].Similarly, Incoloy 800H possesses chemical properties for high-temperature strength and resistance to oxidation, carburization, and other high-temperature corrosion. Incoloy 800H has high nickel and chromium content, and this helps in resisting oxidation. A protective surface oxide is formed due to the presence of chromium, and nickel will provide the additional protection during continuous exposure to high temperature [4, 5]. Thermal barrier coatings which are usually coated in metal surfaces find their application in high-temperature environment such as gas turbines and aero engine parts [18,20]. The ceramic coatings like aluminum oxide, silicon oxide, and zirconia are the commonly used coatings, whereas zirconia possesses high-melting point and low coefficient of thermal expansion. Yttria-stabilized zirconia is one of the kinds of TBC applied in Inconel 625 and Incoloy 800H with the aid of bond coat material of NiCoAlY. All these TBC can be coated with the bond coat with the different substrates using the plasma spray coating process [6–8]. The molten salts are available in solid form in general, and their solid form changes to liquid phase when exposed to high temperature. Among the wide spread of molten salts, with frequently used eutectic mixture of 7 : 3, sodium chloride and potassium chloride molten salts were taken for analysis. Both salts are available in solid phase, and solid salts change to liquid phase when exposed to high temperature more than 770°C. Due to this enhanced property, the molten-salt technology is rising the efficiency and storage capacity of concentrated solar power plants while falling solar thermal energy costs. The molten salt is used as a heat-transfer fluid (HTF) and thermal energy storage (TES) in solar power plants [9–12]. Several other methods may be employed to improve the properties of any composite materials [13, 14].In this present work, Inconel 625 and Incoloy 800H have been taken up for the investigation. The base materials were coated with YSZ as a TBC coating using the plasma spray process. Both coated and uncoated substrates were heated with sodium and potassium chloride up to 1000°C in a muffle furnace for 8, 12, and 16 hours, respectively. The tensile test and hardness test were conducted on the heated specimens, and the mechanical properties were compared. The SEM images were taken, and XRD analysis was done for performing the microstructural analysis [15–17].


## 2. Materials and Methods

The Inconel 625 and Incoloy 800H sheets of 1.6 mm thickness have been used, and the following test specimens were prepared as per ASTM standard dimensions. The materials used for this investigation can be seen from Figures1(a) and 1(b). The sheets were cut into required size and dimensions with a laser beam machining technique with reference to Figure 1(c). The material composition was tested using “OES Foundry Spectro-Analyzer”. The tensile test specimens as given in Figures 2(a) and 2(c) were prepared to know the yield strength, ultimate tensile strength, and % of elongation. All the dimensions shown in the figures are in millimeters. The SEM and XRD characterization study specimens are shown in Figures 2(b) and 2(d) in the dimension of 10×10 mm, respectively. All specimens, such as tensile test and SEM and XRD, were coated with yttria-stabilized zirconia as the thermal barrier coating to enhance the temperature resistance and corrosion resistance properties of the base substrate. 150 microns of YSZ coating thickness was used with the bond coat material of NiCoAlY. The coated specimens of both YSZ and Inconel 625 can be seen in Figure 3(a), whereas YSZ and Incoloy 800H specimens can be seen in Figure 3(b).Figure 1
(a) The Incoloy 800H sheet, (b) Inconel 625 sheet, and (c) laser beam machining.
(a)(b)(c)Figure 2
(a) Top view of the tensile specimen. (b) Top view of the SEM and XRD specimen. (c) Front view of the tensile specimen. (d) Front view of the SEM and XRD specimen.Figure 3
(a) YSZ-Inconel 625-coated specimens. (b) YSZ-Incoloy 800H-coated specimens. (c) Specimens before heating. (d) Specimens after heating.
(a)(b)(c)(d)The specimens coated with YSZ and uncoated specimens were heated up to 1000°C in a muffle furnace for 8, 16, and 24 hours with the sodium and potassium chloride molten salts with a weight fraction of 70 : 30 grams, respectively. Before heating, the specimens were cleaned with acetone solution to remove the any impurities on the surface material. The heated specimens were taken, and salt crystals were removed. The polished specimens after the heating process were used for mechanical testing and characterization study. The specimens before the heating process can be seen from Figure3(c), and those after heating can be seen from Figure 3(d).


## 3. Results and Discussion

After the heating process of specimens with different hours, the specimens were tested with the tensile test and hardness test. The results have been discussed for the comparative analysis of the yield strength, ultimate tensile strength, and % of elongation.


### 3.1. Inconel 625: Tensile Test Results

The tensile test has been carried out for the different specimens with the aid of universal testing machine. The unheated/raw specimens of uncoated Inconel 625 specimen result in yield strength of 614 MPa, ultimate tensile strength of 970 MPa, and % of elongation of 42.50 in 25 mm gauge length. The unheated YSZ-coated specimens result in yield strength of 624 MPa, ultimate tensile strength of 1015 MPa, and % of elongation of 47.0 in 25 mm gauge length. The influence of YSZ coating on the Inconel 625 specimens increases by 1.60% in yield strength and 4.43% in ultimate tensile strength as shown in Figure4. The tensile test conducted on 8-hour-heated specimens result in yield strength of 243 MPa, ultimate tensile strength of 551 MPa, and % of elongation of 38.00 in 25 mm gauge length. The 8-hour-heated YSZ-coated specimens result in yield strength of 334 MPa, ultimate tensile strength of 568 MPa, and % of elongation of 32.0 in 25 mm gauge length. The effect of YSZ coating on the 8-hour-heated Inconel 625 specimens increases by 27.24% in yield strength and 2.99% in ultimate tensile strength as shown in Figure 5.Figure 4
Inconel 625 (unheated specimen) mechanical test result.Figure 5
Inconel 625 (8-hour-heated specimen) mechanical test result.The tensile test conducted on 12-hour-heated specimens results in yield strength of 223 MPa, ultimate tensile strength of 472 MPa, and % of elongation of 29.50 in 25 mm gauge length. The 12-hour-heated YSZ-coated specimens result in yield strength of 310 MPa, ultimate tensile strength of 577 MPa, and % of elongation of 27.50 in 25 mm gauge length. The result of YSZ coating on the 12-hour-heated Inconel 625 specimens increases by 28.06% in yield strength and 18.19% in ultimate tensile strength as shown in Figure6. With reference to Figure 7, the tensile test conducted on 16-hour-heated specimens results in yield strength of 166 MPa, ultimate tensile strength of 403 MPa, and % of elongation of 21.50 in 25 mm gauge length. The 16-hour-heated YSZ-coated specimens result in yield strength of 306 MPa, ultimate tensile strength of 572 MPa, and % of elongation of 31.50 in 25 mm gauge length. The result of YSZ coating on the 16-hour-heated Inconel 625 specimens increases by 45.75% in yield strength and 29.54% in ultimate tensile strength. Thus, the influence of YSZ coating results in increase in the yield strength and ultimate tensile strength for all Inconel 625 specimens. The increase in heating time also results in increase in the tensile property of the specimens [19].Figure 6
Inconel 625 (12-hour-heated specimens) mechanical test resultFigure 7
Inconel 625 (16-hour-heated specimens) mechanical test results.


### 3.2. Incoloy 800H: Tensile Test Results

Similar to the Inconel 625, the tensile test for Incoloy 800H has been carried out for the different specimens. The unheated/raw specimens of uncoated Incoloy 800H specimens result in yield strength of 291 MPa, ultimate tensile strength of 593 MPa, and % of elongation of in 25 mm gauge length. The unheated YSZ-coated specimens result in yield strength of 312 MPa, ultimate tensile strength of 606 MPa, and % of elongation of 41.50 in 25 mm gauge length. The influence of YSZ coating on the Incoloy 800H specimens increases by 6.73% in yield strength and 2.14% in ultimate tensile strength as shown in Figure8. With reference to Figure 9, the tensile test conducted on 8-hour-heated Incoloy 800H specimens results in yield strength of 263 MPa, ultimate tensile strength of 552 MPa, and % of elongation of 30.50 in 25 mm gauge length. The 8-hour-heated YSZ-coated specimens result in yield strength of 292 MPa, ultimate tensile strength of 566 MPa, and % of elongation of 38.0 in 25 mm gauge length. The effect of YSZ coating on the 8-hour-heated Incoloy 800H specimens increases by 9.93% in yield strength and 2.47% in ultimate tensile strength. The tensile test conducted on 12-hour-heated specimens results in yield strength of 247 MPa, ultimate tensile strength of 486 MPa, and % of elongation of 29.00 in 25 mm gauge length. The 12-hour-heated YSZ-coated specimens result in yield strength of 267 MPa, ultimate tensile strength of 499 MPa, and % of elongation of 36.50 in 25 mm gauge length. The result of YSZ coating on the 12-hour-heated Incoloy 800H specimens increases by 7.49% in yield strength and 2.60% in ultimate tensile strength as shown in Figure 10.Figure 8
Incoloy 800H (unheated specimens) mechanical test results.Figure 9
Incoloy 800H (8-hour-heated specimens) mechanical test results.Figure 10
Incoloy 800H (12-hour-heated specimens) mechanical test results.Tensile test conducted on 16-hour-heated specimens result in yield strength of 229 MPa, ultimate tensile strength of 301 MPa and a % of 28.50 elongation in 25 mm gauge length. The 12-hour-heated YSZ-coated specimens result in yield strength of 253 MPa, ultimate tensile strength of 340 MPa, and % of 38.50 elongation in 25 mm gauge length. The result of YSZ coating on the 8-hour-heated Incoloy 800H specimens increases by 9.48% in yield strength and 11.47% in ultimate tensile strength as shown in Figure11.Figure 11
Incoloy 800H (16-hour-heated specimens) mechanical test results.The influence of YSZ coating on the Incoloy 800H superalloy increases the tensile property of the specimen and influence of heating also resulted in increase in yield strength and ultimate tensile strength. Based on the results obtained, it can be suggested that, influence of YSZ thermal barrier coating increases the yield strength and ultimate tensile strength for both Inconel 625 and Incoloy 800H specimens.


### 3.3. Hardness Test Results

The hardness value for all the heated specimens of both Inconel 625 and Incoloy 800H were measured using a Vickers hardness tester.The hardness values for uncoated Inconel 625 specimens were gradually decreased for different hours of heating process. The hardness value for uncoated and unheated specimen decreased from 171.9 HV to 146.3 HV after 16 hours of heating as shown in Figure12. With reference to Figure 13, for YSZ–Inconel 625-coated specimens the hardness value decreased from 179.3 HV to 163.3 HV after 16 hours of heating. The overall reduction of hardness value was found to be 14.89% for uncoated Inconel 625 specimens and 8.92% for YSZ-coated specimens. The hardness value for uncoated Incoloy 800H specimens were gradually decreased for different hours of heating process. The hardness value for Incoloy 800H uncoated and unheated specimen decreased from 143.8 HV to 124.3 HV after 16 hours of heating as shown in Figure 14. With reference to Figure 15, for YSZ-coated specimens the hardness value decreased from 151.2 HV to 132.2 HV after 16 hours of heating. The overall reduction of hardness value was found to be 13.56% for uncoated Incoloy 800H specimens and 12.56% for YSZ-coated specimens. The obtained values indicating that, influence of YSZ coating results in the increase in hardness in both Inconel 625 and Incoloy 800H specimens, whereas the influence of high aggressive environment resulted in decrease in the hardness value for both Inconel 625 and Incoloy 800H specimens.Figure 12
Inconel 625 (uncoated coated specimens) hardness test results.Figure 13
Inconel 625 (YSZ-coated specimens) hardness test results.Figure 14
Incoloy 800H (uncoated specimens) hardness test results.Figure 15
Incoloy 800H (YSZ-coated specimens) hardness test results.


### 3.4. Microstructural Analysis

The scanning electron microscope images were taken for both uncoated and YSZ-coated specimens which is heated for different hours. The images were taken under different magnification for to have clear analysis. With reference to Figures16 and 17, the SEM images of the Inconel 625 specimens support the statement of YSZ-coated specimens are resisting the hot corrosion in a better manner comparing to the uncoated specimens. In the YSZ-coated specimens the formation of protective layer against the molten salt corrosion is evident on all 8-, 12-, and 16-hour-heated specimens. With reference to Figures 18 and 19, the SEM images of all heated Incoloy 800H uncoated and YSZ-coated specimens were taken in different magnification. The high-temperature corrosion is minimal in the YSZ-coated specimens on comparing with the uncoated specimens. The YSZ thermal barrier coating forms a protective layer and resists the corrosion formation on base substrate material.Figure 16
SEM images of Inconel 625 specimens. (a) Uncoated 8-hour-heated 300x magnification. (b) Uncoated 12-hour-heated 300x magnification. (c) Uncoated 16-hour-heated 300x magnification. (d) Uncoated 8-hour-heated 300x magnification. (e) Uncoated 12-hour-heated 300x magnification. (f) Uncoated 16-hour-heated 300x magnification.
(a)(b)(c)(d)(e)(f)Figure 17
SEM images of Inconel 625 specimens. (a) YSZ-coated 8-hour-heated 300x magnification. (b) YSZ-coated 12-hour-heated 300x magnification. (c) YSZ-coated 16-hour-heated 300x magnification. (d) YSZ-coated 8-hour-heated 300x magnification. (e) YSZ-coated 12-hour-heated 300x magnification. (f) YSZ-coated 16-hour-heated 300x magnification.
(a)(b)(c)(d)(e)(f)Figure 18
SEM images of Incoloy 800H specimens. (a) Uncoated 8-hour-heated 300x magnification. (b) Uncoated 12-hour-heated 300x magnification. (c) Uncoated 16-hour-heated 300x magnification. (d) Uncoated 8-hour-heated 300x magnification. (e) Uncoated 12-hour-heated 300x magnification. (f) Uncoated 16-hour heated 300x magnification.
(a)(b)(c)(d)(e)(f)Figure 19
SEM images of Incoloy 800H specimens. (a) YSZ-coated 8-hour-heated 300x magnification. (b) YSZ-coated 12-hour-heated 300x magnification. (c) YSZ-coated 16-hour-heated 300x magnification. (d) YSZ-coated 8-hour-heated 300x magnification. (e) YSZ-coated 12-hour-heated 300x magnification. (f) YSZ-coated 16-hour-heated 300x magnification.
(a)(b)(c)(d)(e)(f)


### 3.5. XRD Analysis

The X-ray diffraction analysis is performed to study the microstructural properties of nickel-based superalloy specimens subjected to the high-temperature environment with chloride-based molten salts. The graph exhibits some XRD peaks of short- and long-range order and noise like pattern. But there are some very sharp peak points especially at 44.280(2-theta deg) indicating the presence of crystalline structures. In YSZ-coated specimens, corrosion is not significant, and the crystal structures are present indicating that the atoms are placed in their lattice without getting disturbed from corrosion. In similar to the XRD graphs of Inconel 625 as shown in Figure20, Incoloy 800H XRD graph as shown in Figure 21 also exhibits some all range of peaks. Here also are some very sharp peak points especially at 30.625(2-thetadeg) indicating the occurrence of crystalline structures. In coated specimens, corrosion is not substantial as the crystal structures are present without the atoms are rearranged.Figure 20
XRD results of Inconel 625 specimens. (a) Uncoated 8-hour-heated. (b) YSZ-coated 8-hour-heated. (c) Uncoated 12-hour-heated. (d) YSZ-coated 12-hour-heated. (e) Uncoated 16-hour-heated. (f) YSZ-coated 16-hour-heated.
(a)(b)(c)(d)(e)(f)Figure 21
XRD results of Incoloy 800H specimens. (a) Uncoated 8-hour-heated. (b) YSZ-coated 8-hour-heated. (c) Uncoated 12-hour-heated. (d) YSZ-coated 12-hour-heated. (e) Uncoated 16-hour-heated. (f) YSZ-coated 16-hour-heated.
(a)(b)(c)(d)(e)(f)


## 3.1. Inconel 625: Tensile Test Results

The tensile test has been carried out for the different specimens with the aid of universal testing machine. The unheated/raw specimens of uncoated Inconel 625 specimen result in yield strength of 614 MPa, ultimate tensile strength of 970 MPa, and % of elongation of 42.50 in 25 mm gauge length. The unheated YSZ-coated specimens result in yield strength of 624 MPa, ultimate tensile strength of 1015 MPa, and % of elongation of 47.0 in 25 mm gauge length. The influence of YSZ coating on the Inconel 625 specimens increases by 1.60% in yield strength and 4.43% in ultimate tensile strength as shown in Figure4. The tensile test conducted on 8-hour-heated specimens result in yield strength of 243 MPa, ultimate tensile strength of 551 MPa, and % of elongation of 38.00 in 25 mm gauge length. The 8-hour-heated YSZ-coated specimens result in yield strength of 334 MPa, ultimate tensile strength of 568 MPa, and % of elongation of 32.0 in 25 mm gauge length. The effect of YSZ coating on the 8-hour-heated Inconel 625 specimens increases by 27.24% in yield strength and 2.99% in ultimate tensile strength as shown in Figure 5.Figure 4
Inconel 625 (unheated specimen) mechanical test result.Figure 5
Inconel 625 (8-hour-heated specimen) mechanical test result.The tensile test conducted on 12-hour-heated specimens results in yield strength of 223 MPa, ultimate tensile strength of 472 MPa, and % of elongation of 29.50 in 25 mm gauge length. The 12-hour-heated YSZ-coated specimens result in yield strength of 310 MPa, ultimate tensile strength of 577 MPa, and % of elongation of 27.50 in 25 mm gauge length. The result of YSZ coating on the 12-hour-heated Inconel 625 specimens increases by 28.06% in yield strength and 18.19% in ultimate tensile strength as shown in Figure6. With reference to Figure 7, the tensile test conducted on 16-hour-heated specimens results in yield strength of 166 MPa, ultimate tensile strength of 403 MPa, and % of elongation of 21.50 in 25 mm gauge length. The 16-hour-heated YSZ-coated specimens result in yield strength of 306 MPa, ultimate tensile strength of 572 MPa, and % of elongation of 31.50 in 25 mm gauge length. The result of YSZ coating on the 16-hour-heated Inconel 625 specimens increases by 45.75% in yield strength and 29.54% in ultimate tensile strength. Thus, the influence of YSZ coating results in increase in the yield strength and ultimate tensile strength for all Inconel 625 specimens. The increase in heating time also results in increase in the tensile property of the specimens [19].Figure 6
Inconel 625 (12-hour-heated specimens) mechanical test resultFigure 7
Inconel 625 (16-hour-heated specimens) mechanical test results.


## 3.2. Incoloy 800H: Tensile Test Results

Similar to the Inconel 625, the tensile test for Incoloy 800H has been carried out for the different specimens. The unheated/raw specimens of uncoated Incoloy 800H specimens result in yield strength of 291 MPa, ultimate tensile strength of 593 MPa, and % of elongation of in 25 mm gauge length. The unheated YSZ-coated specimens result in yield strength of 312 MPa, ultimate tensile strength of 606 MPa, and % of elongation of 41.50 in 25 mm gauge length. The influence of YSZ coating on the Incoloy 800H specimens increases by 6.73% in yield strength and 2.14% in ultimate tensile strength as shown in Figure8. With reference to Figure 9, the tensile test conducted on 8-hour-heated Incoloy 800H specimens results in yield strength of 263 MPa, ultimate tensile strength of 552 MPa, and % of elongation of 30.50 in 25 mm gauge length. The 8-hour-heated YSZ-coated specimens result in yield strength of 292 MPa, ultimate tensile strength of 566 MPa, and % of elongation of 38.0 in 25 mm gauge length. The effect of YSZ coating on the 8-hour-heated Incoloy 800H specimens increases by 9.93% in yield strength and 2.47% in ultimate tensile strength. The tensile test conducted on 12-hour-heated specimens results in yield strength of 247 MPa, ultimate tensile strength of 486 MPa, and % of elongation of 29.00 in 25 mm gauge length. The 12-hour-heated YSZ-coated specimens result in yield strength of 267 MPa, ultimate tensile strength of 499 MPa, and % of elongation of 36.50 in 25 mm gauge length. The result of YSZ coating on the 12-hour-heated Incoloy 800H specimens increases by 7.49% in yield strength and 2.60% in ultimate tensile strength as shown in Figure 10.Figure 8
Incoloy 800H (unheated specimens) mechanical test results.Figure 9
Incoloy 800H (8-hour-heated specimens) mechanical test results.Figure 10
Incoloy 800H (12-hour-heated specimens) mechanical test results.Tensile test conducted on 16-hour-heated specimens result in yield strength of 229 MPa, ultimate tensile strength of 301 MPa and a % of 28.50 elongation in 25 mm gauge length. The 12-hour-heated YSZ-coated specimens result in yield strength of 253 MPa, ultimate tensile strength of 340 MPa, and % of 38.50 elongation in 25 mm gauge length. The result of YSZ coating on the 8-hour-heated Incoloy 800H specimens increases by 9.48% in yield strength and 11.47% in ultimate tensile strength as shown in Figure11.Figure 11
Incoloy 800H (16-hour-heated specimens) mechanical test results.The influence of YSZ coating on the Incoloy 800H superalloy increases the tensile property of the specimen and influence of heating also resulted in increase in yield strength and ultimate tensile strength. Based on the results obtained, it can be suggested that, influence of YSZ thermal barrier coating increases the yield strength and ultimate tensile strength for both Inconel 625 and Incoloy 800H specimens.


## 3.3. Hardness Test Results

The hardness value for all the heated specimens of both Inconel 625 and Incoloy 800H were measured using a Vickers hardness tester.The hardness values for uncoated Inconel 625 specimens were gradually decreased for different hours of heating process. The hardness value for uncoated and unheated specimen decreased from 171.9 HV to 146.3 HV after 16 hours of heating as shown in Figure12. With reference to Figure 13, for YSZ–Inconel 625-coated specimens the hardness value decreased from 179.3 HV to 163.3 HV after 16 hours of heating. The overall reduction of hardness value was found to be 14.89% for uncoated Inconel 625 specimens and 8.92% for YSZ-coated specimens. The hardness value for uncoated Incoloy 800H specimens were gradually decreased for different hours of heating process. The hardness value for Incoloy 800H uncoated and unheated specimen decreased from 143.8 HV to 124.3 HV after 16 hours of heating as shown in Figure 14. With reference to Figure 15, for YSZ-coated specimens the hardness value decreased from 151.2 HV to 132.2 HV after 16 hours of heating. The overall reduction of hardness value was found to be 13.56% for uncoated Incoloy 800H specimens and 12.56% for YSZ-coated specimens. The obtained values indicating that, influence of YSZ coating results in the increase in hardness in both Inconel 625 and Incoloy 800H specimens, whereas the influence of high aggressive environment resulted in decrease in the hardness value for both Inconel 625 and Incoloy 800H specimens.Figure 12
Inconel 625 (uncoated coated specimens) hardness test results.Figure 13
Inconel 625 (YSZ-coated specimens) hardness test results.Figure 14
Incoloy 800H (uncoated specimens) hardness test results.Figure 15
Incoloy 800H (YSZ-coated specimens) hardness test results.


## 3.4. Microstructural Analysis

The scanning electron microscope images were taken for both uncoated and YSZ-coated specimens which is heated for different hours. The images were taken under different magnification for to have clear analysis. With reference to Figures16 and 17, the SEM images of the Inconel 625 specimens support the statement of YSZ-coated specimens are resisting the hot corrosion in a better manner comparing to the uncoated specimens. In the YSZ-coated specimens the formation of protective layer against the molten salt corrosion is evident on all 8-, 12-, and 16-hour-heated specimens. With reference to Figures 18 and 19, the SEM images of all heated Incoloy 800H uncoated and YSZ-coated specimens were taken in different magnification. The high-temperature corrosion is minimal in the YSZ-coated specimens on comparing with the uncoated specimens. The YSZ thermal barrier coating forms a protective layer and resists the corrosion formation on base substrate material.Figure 16
SEM images of Inconel 625 specimens. (a) Uncoated 8-hour-heated 300x magnification. (b) Uncoated 12-hour-heated 300x magnification. (c) Uncoated 16-hour-heated 300x magnification. (d) Uncoated 8-hour-heated 300x magnification. (e) Uncoated 12-hour-heated 300x magnification. (f) Uncoated 16-hour-heated 300x magnification.
(a)(b)(c)(d)(e)(f)Figure 17
SEM images of Inconel 625 specimens. (a) YSZ-coated 8-hour-heated 300x magnification. (b) YSZ-coated 12-hour-heated 300x magnification. (c) YSZ-coated 16-hour-heated 300x magnification. (d) YSZ-coated 8-hour-heated 300x magnification. (e) YSZ-coated 12-hour-heated 300x magnification. (f) YSZ-coated 16-hour-heated 300x magnification.
(a)(b)(c)(d)(e)(f)Figure 18
SEM images of Incoloy 800H specimens. (a) Uncoated 8-hour-heated 300x magnification. (b) Uncoated 12-hour-heated 300x magnification. (c) Uncoated 16-hour-heated 300x magnification. (d) Uncoated 8-hour-heated 300x magnification. (e) Uncoated 12-hour-heated 300x magnification. (f) Uncoated 16-hour heated 300x magnification.
(a)(b)(c)(d)(e)(f)Figure 19
SEM images of Incoloy 800H specimens. (a) YSZ-coated 8-hour-heated 300x magnification. (b) YSZ-coated 12-hour-heated 300x magnification. (c) YSZ-coated 16-hour-heated 300x magnification. (d) YSZ-coated 8-hour-heated 300x magnification. (e) YSZ-coated 12-hour-heated 300x magnification. (f) YSZ-coated 16-hour-heated 300x magnification.
(a)(b)(c)(d)(e)(f)


## 3.5. XRD Analysis

The X-ray diffraction analysis is performed to study the microstructural properties of nickel-based superalloy specimens subjected to the high-temperature environment with chloride-based molten salts. The graph exhibits some XRD peaks of short- and long-range order and noise like pattern. But there are some very sharp peak points especially at 44.280(2-theta deg) indicating the presence of crystalline structures. In YSZ-coated specimens, corrosion is not significant, and the crystal structures are present indicating that the atoms are placed in their lattice without getting disturbed from corrosion. In similar to the XRD graphs of Inconel 625 as shown in Figure20, Incoloy 800H XRD graph as shown in Figure 21 also exhibits some all range of peaks. Here also are some very sharp peak points especially at 30.625(2-thetadeg) indicating the occurrence of crystalline structures. In coated specimens, corrosion is not substantial as the crystal structures are present without the atoms are rearranged.Figure 20
XRD results of Inconel 625 specimens. (a) Uncoated 8-hour-heated. (b) YSZ-coated 8-hour-heated. (c) Uncoated 12-hour-heated. (d) YSZ-coated 12-hour-heated. (e) Uncoated 16-hour-heated. (f) YSZ-coated 16-hour-heated.
(a)(b)(c)(d)(e)(f)Figure 21
XRD results of Incoloy 800H specimens. (a) Uncoated 8-hour-heated. (b) YSZ-coated 8-hour-heated. (c) Uncoated 12-hour-heated. (d) YSZ-coated 12-hour-heated. (e) Uncoated 16-hour-heated. (f) YSZ-coated 16-hour-heated.
(a)(b)(c)(d)(e)(f)


## 4. Conclusion

The Inconel 625 and Incoloy 800H nickel-based superalloys were taken with molten salts such as sodium chloride and potassium chloride with a eutectic mixture of 7 : 3 for investigation. Yttria-stabilized zirconia-thermal barrier coating was coated on the alloy specimens to compare the mechanical and metallurgical properties of the raw specimen with the coated specimen.To find the hot corrosion behaviour of the molten salts with the coated and uncoated alloy, the specimens were heated up to 1000°C for different hours. Tensile test and hardness test were performed to find the yield strength, ultimate tensile strength, and the % of elongation and the hardness value.The SEM images and XRD analysis were performed to study the microstructural properties. Based on the experiments performed, the following recommendations were specified.(i)
Inconel 625 and Incoloy 800H are highly suited for to be used as storage material in the molten salts’ thermal energy storage devices(ii)
Yttria-stabilized zirconia-thermal barrier coated alloy materials exhibit high strength and hardness and makes the alloy material as more corrosion resistant and temperature resistant. The statement is supported with the assistance of mechanical testing and microstructural analysisFor the future work, other superalloys with different thermal barrier coating types can be taken with the wide varieties of molten salts, and the hot-corrosion behaviour can be investigated.



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