# Synthesis and Properties of Polysilsesquioxanes Having Ethoxysulfonyl Group as a Side Chain

Authors: Takahiro Gunji; Kazuki Yamamoto; Akira Tomobe; Noritaka Abe; Yoshimoto Abe
Journal: International Journal of Polymer Science
 (2012)

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## Abstract

Polysilsesquioxane having an ethoxysulfonyl group as a side chain was synthesized to prepare a proton-conductive film composed of a main chain of siloxane. At first, sodium 4-(2-methylallyloxy)benzenesulfonate was chlorinated with thionyl chloride. Next, hydrosilylation with trichlorosilane was carried out in the presence of platinum catalyst followed by treatment with ethanol. Finally, the hydrolytic polycondensation was carried out to provide poly(3-(4-ethoxysulfonylphenoxy)-2-methylpropyl)silsesquioxane. This polysilsesquioxane was heated to form a free-standing film that was brittle and brown in color.


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## Body

## 1. Introduction

Fuel cells, which generate power using hydrogen and oxygen gases, have been a focus of recent interest due to their potential for resolving both energy and environmental problems, as they produce very little pollution and have a high power generation efficiency. In particular, polymer electrolyte fuel cells (PEFCs), which are fuel cells that utilize a proton conductive membrane as an electrolyte, are expected to have a high potential, as PEFCs can generate power at low temperature with high energy density. PEFCs are therefore suitable for miniaturization to make them suitable for home use, for portable devices, or for car batteries. The proton-conducting membrane most commonly used is a fluorine-containing polyelectrolyte film that works under moderate moisture to improve proton conductivity. PEFCs are, however, difficult to operate at high temperatures, which can lower the power-generation efficiency due to the low heat resistance of the electrolyte film.In the previous works, a proton-conducting membrane utilizing a siloxane bond as a main chain with high heat resistance was utilized: polysilsesquioxanes having an acid group in the side chain were prepared by a sol-gel method [1–5] and then mixed with polyketone [6, 7], fluorine-containing polymer [8], or phosphor-containing polymer [9]. The film prepared showed high proton conductivity of approximately 10−2 S/cm [1–3, 5, 7, 9], which is higher than the perfluoro-type polymer electrolyte [10]. The degradation or phase separation of organic and inorganic components is a demerit in the use of these membranes over the long term.In our previous report, film formation was carried out by hydrolytic polycondensation and subsequent oxidation of a silane-coupling agent, which resulted in the degradation of polysiloxanes by a sulfonic acid group to give a broken film [11]. In contrast, copolymerization of a silane coupling agent having a mercapto group with 1,2-trimethoxysilylethane provided a proton-conducting film with a heat resistivity to 150°C.Polysilsesquioxane is useful as a framework in organic-inorganic polymer hybrid material because of its high heat-resistivity, high mechanical properties, and easy introduction of functional groups in the side chain. The application of polysilsesquioxanes as a PEFC membrane is limited by the degradation of the siloxane chain and gel formation by the acid groups. In order to improve this problem, a polysilsesquioxane having an arylsulfonic acid as a side chain was examined. The side chain is expected to form a stacking structure by the steric hindrance and interaction of pi electrons of an aryl group to depress the degradation of siloxane bonding by sulfonic acid. In this work, therefore, the synthesis of polysilsesquioxane having a sulfonic acid group from an arylsulfonic ester derivative as well as formation of the membrane was investigated according to the Scheme1.Scheme 1
Schematic figure for the synthesis of SPES.


## 2. Experimental

### 2.1. Reagents

Thionyl chloride, toluene, pyridine, acetone, sodium hydroxide, and 6 mol/L hydrochloric acid (Wako Pure Chemical Industries Ltd., reagent grade) were used as received.Trichlorosilane (Shin-Etsu Chemical Industry, Co., Ltd.) was used as received.Ethanol and hexane (Kanto Chemical, Co., Ltd.) were dried over calcium oxide and distilled before use.Sodium 4-hydroxybenzenesulfonate dihydrate, 3-chloro-2-methyl-1-propene, and chloroplatinic (IV) acid (Tokyo Chemical Industry Co., Ltd.) were used as received.


### 2.2. Synthesis of Sodium 4-(2-Methyl-2-propenoxy)benzenesulfonate

Sodium 4-(2-methyl-2-propenoxy)benzenesulfonate was synthesized according to the procedure shown in the literature [12]. Sodium 4-hydroxybenzenesulfonate dihydrate 174 g (0.75 mol) was mixed with water 375 mL, acetone 375 mL, and sodium hydroxide 30.8 g (0.77 mol) and heated to reflux for 10 min. 3-Chloro-2-methyl-1-propene was added slowly and subjected to reflux for 24 h, followed by recrystallization.Yield: 104 g (80%). White crystal.1H NMR [δ/ppm] (300 MHz, CDCl3) 1.84 (s, 3H), 4.55 (s, 2H), 5.07 (d, 1H), 5.09 (d, 1H), 7.06 (d, 2H, J = 9.0 Hz), 7.99 (d, 2H, J = 9.0 Hz). MS (ESI) m/z = 246[M+], 211[M-Cl]+.


### 2.3. Synthesis of 4-(2-Methyl-2-propenoxy)benzenesulfonyl Chloride

4-(2-methyl-2-propenoxy)benzenesulfonyl chloride was synthesized according to a previously reported procedure [12]. First, 25 g (0.1 mol) of sodium 4-(2-methyl-2-propenoxy)benzenesulfonate was mixed with thionyl chloride 11 mL (0.15 mol), dimethylformamide 0.1 mL, and toluene 100 mL and heated to 100°C for 12 h. The reaction mixture was washed with water three times, followed by drying and condensation.Yield: 23 g (80%). Colorless liquid.1H NMR [δ/ppm] (300 MHz, CDCl3) 1.84 (s, 3H), 4.55 (s, 2H), 5.07 (d, 1H), 5.09 (d, 1H), 7.06 (d, 2H, J= 9.0 Hz), 7.99 (d, 2H, J= 9.0 Hz). MS (ESI) m/z = 246[M+], 211[M-Cl]+.


### 2.4. Synthesis of 4-(2-Methyl-3-trichlorosilylpropoxy)benzenesulfonyl Chloride

3.0 g (13 mmol) of 7 was mixed with trichlorosilane 12 mL (0.15 mol) and 5% 2-propanol solution of chloroplatinic acid dihydrate 0.1 mL and heated at 50°C for 12 h to complete the hydrosilylation. Product was recovered by condensation under reduced pressure.Yield: 3.2 g (69%). Yellow liquid.1H NMR [δ/ppm] (300 MHz, CDCl3) 1.26 (d, 3H), 1.50 (dd, 1H), 1.77 (dd, 1H), 2.49 (m, 1H), 3.80 (d, 2H), 7.50 (d, 2H), 7.80 (d, 2H). 13C NMR [δ/ppm] (75 MHz, CDCl3) 19.1, 28.9, 29.2, 73.9, 115.2, 129.5, 136.2, 163.9. 29Si NMR [δ/ppm] (100 MHz, CDCl3) −14.24.


### 2.5. Synthesis of Ethyl 4-(2-Methyl-3-triethoxysilylpropoxy)benzenesulfonate (STES)

3.2 g (6 mmol) of 4-(2-methyl-3-trichlorosilylpropoxy)benzenesulfonyl chloride, ethanol 1.6 g (0.35 mmol), and pyridine 2.0 g (0.25 mol) were added to hexane 50 mL and heated at 50°C for 6 h. Hydrogen chloride pyridine salt was filtered, and the filtrate was subjected to condensation. Ethyl 4-(2-methyl-3-triethoxysilylpropoxy)benzenesulfonate (STES) was isolated by short silica gel column chromatography using chloroform as an eluent.Yield: 2.5 g (61%). Slightly yellow liquid.1H NMR [δ/ppm] (300 MHz, CDCl3) 0.75 (m, 2H), 1.12 (d, 3H, J= 6.9 Hz), 1.22 (t, 9H, J= 6.9 Hz), 1.29 (t, 3H, J= 7.2 Hz), 2.22 (m, 1H), 3.86 (q, 6H), 3.92 (d, 2H), 4.08 (q, 2H), 7.00 (d, 2H, J= 9.0 Hz), 7.82 (d, 2H, J= 9.0 Hz). 13C NMR [δ/ppm] (75 MHz, CDCl3). 29Si NMR [δ/ppm] (100 MHz, CDCl3) −46.37. MS (ESI) m/z = 420[M]+, 375[(M-C2H5O]+.


### 2.6. Synthesis of Poly(3-(4-ethoxysulfonylphenoxy)-2-methylpropyl)silsesquioxane (SPES)

Into a 100 mL four-necked flask, STES 2.10 g (5 mmol) and ethanol 0.46 g were charged. After cooling for 10 min using an ice bath, water and 6 mol/L hydrochloric acid were added in the molar ratio of HCl/SPES = 0.1 and stirred for 10 min. After removing the ice bath, the solution was stirred for 10 min at room temperature. The flask was then heated at 80°C for 4 h with stirring to provide poly(3-(4-ethoxysulfonylphenoxy)-2-methylpropyl)silsesquioxane (SPES) as a highly viscous liquid.


### 2.7. Formation of Films

A 33% THF solution of SPES was poured into a scale made from polytetrafluoroethylene and heated at 80°C for 3 days.


### 2.8. Measurement

1H, 13C, and 29Si nuclear magnetic resonance (NMR) spectra were recorded by JEOL NM ECP-300 or JNM ECP-500. Chloroform-d was used as a solvent, and tetramethylsilane was used as an internal standard of chemical shift.Fourier transformation infrared (FT-IR) spectra were acquired by JASCO FT/IR410. The KBr disk method and CCl4 solution method were utilized for solid and liquid samples, respectively.Gas chromatography (GC) was performed by Shimadzu GC-14B. Injection temperature: 250°C. Column temperature: 50–250°C (+20°C/min). TCD temperature: 250°C. Carrier gas: helium.Gas chromatograph/mass spectroscopy (GC/MS) was performed by JEOL GCMate.High-performance liquid chromatography (HPLC) was performed with a Shimadzu LC-6AD attached to a YMC guard column ODS-A (50×20 mm) and two YMC ODS-A5 μm. Acetonitrile (7 mL/min) was used as an eluent. Detector: RID-10A.Gel-permeation chromatography (GPC) was performed with a Shimadzu LC-6AD attached to a Polymer Laboratory PL gel 5μ Mixed-D column. Tetrahydrofuran was used as an eluent. Detector: RID-10A.


## 2.1. Reagents

Thionyl chloride, toluene, pyridine, acetone, sodium hydroxide, and 6 mol/L hydrochloric acid (Wako Pure Chemical Industries Ltd., reagent grade) were used as received.Trichlorosilane (Shin-Etsu Chemical Industry, Co., Ltd.) was used as received.Ethanol and hexane (Kanto Chemical, Co., Ltd.) were dried over calcium oxide and distilled before use.Sodium 4-hydroxybenzenesulfonate dihydrate, 3-chloro-2-methyl-1-propene, and chloroplatinic (IV) acid (Tokyo Chemical Industry Co., Ltd.) were used as received.


## 2.2. Synthesis of Sodium 4-(2-Methyl-2-propenoxy)benzenesulfonate

Sodium 4-(2-methyl-2-propenoxy)benzenesulfonate was synthesized according to the procedure shown in the literature [12]. Sodium 4-hydroxybenzenesulfonate dihydrate 174 g (0.75 mol) was mixed with water 375 mL, acetone 375 mL, and sodium hydroxide 30.8 g (0.77 mol) and heated to reflux for 10 min. 3-Chloro-2-methyl-1-propene was added slowly and subjected to reflux for 24 h, followed by recrystallization.Yield: 104 g (80%). White crystal.1H NMR [δ/ppm] (300 MHz, CDCl3) 1.84 (s, 3H), 4.55 (s, 2H), 5.07 (d, 1H), 5.09 (d, 1H), 7.06 (d, 2H, J = 9.0 Hz), 7.99 (d, 2H, J = 9.0 Hz). MS (ESI) m/z = 246[M+], 211[M-Cl]+.


## 2.3. Synthesis of 4-(2-Methyl-2-propenoxy)benzenesulfonyl Chloride

4-(2-methyl-2-propenoxy)benzenesulfonyl chloride was synthesized according to a previously reported procedure [12]. First, 25 g (0.1 mol) of sodium 4-(2-methyl-2-propenoxy)benzenesulfonate was mixed with thionyl chloride 11 mL (0.15 mol), dimethylformamide 0.1 mL, and toluene 100 mL and heated to 100°C for 12 h. The reaction mixture was washed with water three times, followed by drying and condensation.Yield: 23 g (80%). Colorless liquid.1H NMR [δ/ppm] (300 MHz, CDCl3) 1.84 (s, 3H), 4.55 (s, 2H), 5.07 (d, 1H), 5.09 (d, 1H), 7.06 (d, 2H, J= 9.0 Hz), 7.99 (d, 2H, J= 9.0 Hz). MS (ESI) m/z = 246[M+], 211[M-Cl]+.


## 2.4. Synthesis of 4-(2-Methyl-3-trichlorosilylpropoxy)benzenesulfonyl Chloride

3.0 g (13 mmol) of 7 was mixed with trichlorosilane 12 mL (0.15 mol) and 5% 2-propanol solution of chloroplatinic acid dihydrate 0.1 mL and heated at 50°C for 12 h to complete the hydrosilylation. Product was recovered by condensation under reduced pressure.Yield: 3.2 g (69%). Yellow liquid.1H NMR [δ/ppm] (300 MHz, CDCl3) 1.26 (d, 3H), 1.50 (dd, 1H), 1.77 (dd, 1H), 2.49 (m, 1H), 3.80 (d, 2H), 7.50 (d, 2H), 7.80 (d, 2H). 13C NMR [δ/ppm] (75 MHz, CDCl3) 19.1, 28.9, 29.2, 73.9, 115.2, 129.5, 136.2, 163.9. 29Si NMR [δ/ppm] (100 MHz, CDCl3) −14.24.


## 2.5. Synthesis of Ethyl 4-(2-Methyl-3-triethoxysilylpropoxy)benzenesulfonate (STES)

3.2 g (6 mmol) of 4-(2-methyl-3-trichlorosilylpropoxy)benzenesulfonyl chloride, ethanol 1.6 g (0.35 mmol), and pyridine 2.0 g (0.25 mol) were added to hexane 50 mL and heated at 50°C for 6 h. Hydrogen chloride pyridine salt was filtered, and the filtrate was subjected to condensation. Ethyl 4-(2-methyl-3-triethoxysilylpropoxy)benzenesulfonate (STES) was isolated by short silica gel column chromatography using chloroform as an eluent.Yield: 2.5 g (61%). Slightly yellow liquid.1H NMR [δ/ppm] (300 MHz, CDCl3) 0.75 (m, 2H), 1.12 (d, 3H, J= 6.9 Hz), 1.22 (t, 9H, J= 6.9 Hz), 1.29 (t, 3H, J= 7.2 Hz), 2.22 (m, 1H), 3.86 (q, 6H), 3.92 (d, 2H), 4.08 (q, 2H), 7.00 (d, 2H, J= 9.0 Hz), 7.82 (d, 2H, J= 9.0 Hz). 13C NMR [δ/ppm] (75 MHz, CDCl3). 29Si NMR [δ/ppm] (100 MHz, CDCl3) −46.37. MS (ESI) m/z = 420[M]+, 375[(M-C2H5O]+.


## 2.6. Synthesis of Poly(3-(4-ethoxysulfonylphenoxy)-2-methylpropyl)silsesquioxane (SPES)

Into a 100 mL four-necked flask, STES 2.10 g (5 mmol) and ethanol 0.46 g were charged. After cooling for 10 min using an ice bath, water and 6 mol/L hydrochloric acid were added in the molar ratio of HCl/SPES = 0.1 and stirred for 10 min. After removing the ice bath, the solution was stirred for 10 min at room temperature. The flask was then heated at 80°C for 4 h with stirring to provide poly(3-(4-ethoxysulfonylphenoxy)-2-methylpropyl)silsesquioxane (SPES) as a highly viscous liquid.


## 2.7. Formation of Films

A 33% THF solution of SPES was poured into a scale made from polytetrafluoroethylene and heated at 80°C for 3 days.


## 2.8. Measurement

1H, 13C, and 29Si nuclear magnetic resonance (NMR) spectra were recorded by JEOL NM ECP-300 or JNM ECP-500. Chloroform-d was used as a solvent, and tetramethylsilane was used as an internal standard of chemical shift.Fourier transformation infrared (FT-IR) spectra were acquired by JASCO FT/IR410. The KBr disk method and CCl4 solution method were utilized for solid and liquid samples, respectively.Gas chromatography (GC) was performed by Shimadzu GC-14B. Injection temperature: 250°C. Column temperature: 50–250°C (+20°C/min). TCD temperature: 250°C. Carrier gas: helium.Gas chromatograph/mass spectroscopy (GC/MS) was performed by JEOL GCMate.High-performance liquid chromatography (HPLC) was performed with a Shimadzu LC-6AD attached to a YMC guard column ODS-A (50×20 mm) and two YMC ODS-A5 μm. Acetonitrile (7 mL/min) was used as an eluent. Detector: RID-10A.Gel-permeation chromatography (GPC) was performed with a Shimadzu LC-6AD attached to a Polymer Laboratory PL gel 5μ Mixed-D column. Tetrahydrofuran was used as an eluent. Detector: RID-10A.


## 3. Results and Discussion

### 3.1. Synthesis of SPES

The synthesis of polysilsesquioxane having an arylsulfonate group as a side chain was planned by the hydrolytic polycondensation of trialkoxysilane. First, we planned the synthesis of ethyl 4-(2-triethoxysilylethyl)benzenesulfonate by the hydrosilylation of ethyl 4-vinylbenzenesulfonate and triethoxysilane, which resulted in the formation of a mixture of ethyl 4-(2-triethoxysilylethyl)benzenesulfonate and ethyl 4-(1-triethoxysilylethyl)benzenesulfonate. We therefore designed the structure of ethyl 4-(2-methyl-3-triethoxysilylpropoxy)benzenesulfonate as a target compound.The synthesis of ethyl 4-(2-methyl-3-triethoxysilylpropoxy)benzenesulfonate was established by a four-step reaction from sodium 4-hydroxybenzenesulfonate dihydrate.4-(2-Methyl-3-trichlorosilylpropoxy)benzenesulfonyl chloride was synthesized by the hydrosilylation of 4-(2-methyl-2-propenoxy)benzenesulfonyl chloride with trichlorosilane in the presence of chloroplatinic acid. This reaction proceeded gently to provide a unique product, 4-(2-methyl-3-trichlorosilylpropoxy)benzenesulfonyl chloride. This product was isolated by distillation under reduced pressure as a colorless liquid of high hydrolyzability. The formation of this compound was confirmed by the disappearance of signals corresponding to a vinylidene group in the1H and 13C NMR spectra.STES was synthesized by the reaction of 4-(2-methyl-3-trichlorosilylpropoxy)benzenesulfonyl chloride with ethanol. This reaction is one of the general procedures for replacing a chloro group with an ethoxy group: both chloro groups on silicon and sulfur were replaced with an ethoxy group in a one-step reaction. The formation of STES was confirmed by NMR and MASS analyses.SPES was synthesized by the hydrolysis of STES in the presence of hydrochloric acid under a nitrogen stream. The results for the synthesis of SPES are summarized in Table1 including the molecular weight and the percentage of sulfonic acid which were calculated based on the GPC analysis and the integral ratio of signals in the 1H NMR spectrum of SPES, respectively. The progress of hydrolytic polycondensation of STES was confirmed by the increasing viscosity of the hydrolysis product. The yield of SPES decreased with an increase in the molar ratio of water to STES, which suggests the formation of SPES with high molecular weight. In addition, the molecular weight and the percentage of sulfonic acid of SPES increased with the increase of the molar ratio of water to STES. When the molar ratio of water to STES was set to be more than 6, the molecular weight of SPES decreased in accordance with the degradation of the siloxane linkage by the sulfonic acid. SPES (number 2) was soluble in acetone, tetrahydrofuran, diethyl ether, and chloroform, and the solubility was independent of the molecular weight of SPES.Table 1
Results for the synthesis of SPESa.
Number
r (molar ratio of H2O/Si)
Yield (g)
GPCb
Percentagec of sulfonic acid/%
M
w
M
w/Mn
1
1.0
1.77
2.000
1.2
—
2
2.0
1.64
3.200
1.1
—
3
3.0
1.51
4.500
1.1
7
4
5.0
1.50
5.200
1.2
18
5
6.0
1.54
5.800
1.5
32
6
8.0
1.54
4.800
1.5
55
7
10.0
1.50
4.400
1.3
61
8
12.0
1.50
4.600
1.1
79
aScale in operation: STES 2.10 g (5 mmol). EtOH 0.46 g (10 mmol). Molar ratio: HCl/Si = 0.10.
bCalculated based on standard polystyrene.
cCalculated based on the integral ratio of signals in 1H NMR spectrum.The1H NMR spectrum of SPES (number 2) is shown in Figure 1. The intensity of signals due to the ethoxy group in the ethoxysulfonyl group was decreased compared to that of the 2-methylpropyl group, which suggests the hydrolysis of the ethoxysulfonyl group to form sulfonic acid. Additionally, the appearance of new signals due to a phenylene group at the lower field suggests the formation of sulfuric acid. The 29Si NMR spectra of SPES (number 2) and SPTS are shown in Figure 2. The signal due to STES disappeared in the spectrum of SPES, and new signals appeared in the chemical shift areas ascribed to T1, T2, and T3 unit structures. (The symbol Tn denotes the unit structure as RSi(OSi)n(OEt)3-n (n=1, 2, 3; R: 3-(4-ethoxysulfonylphenoxy)-2-methylpropyl group).) The appearance of signals due to T1, T2, and T3 unit structures supports the formation of polysilsesquioxane. The degree of condensation was calculated based on the equation AT3/(AT1+AT2+AT3), with ATn denoting the peak area of the unit structure Tn, as 46%. Approximately half of the silicon atoms in SPES condensed to form the silsesquioxane structure.1H NMR spectra of STES and SPES (number 2).
(a)
(b)29Si NMR spectra of STES and SPES (number 2).
(a)
(b)


### 3.2. Film Formation of SPES

SPES film was prepared by aging SPES (number 2) at 80°C for several days. A photograph of the SPES film is shown in Figure3. SPES was a colorless liquid, and its film became brown with heating, which may have been due to the formation of a sulfonic acid group from the ethoxysulfonyl group. The thickness was approximately 0.1 mm, and the film was brittle, easily broken into pieces when bended. The relatively low molecular weight and degree of crosslinking of SPES would cause this decrease in the film strength.Figure 3
A photograph of the SPES film.The film was colored by using an acid-functional dye: methyl red. The film was uniformly colored in red, which supports the formation of a sulfonic acid group by heating.The thermogravimetric differential thermal analysis of thin film is shown in Figure4. Exothermic peaks were found at 200–240°C and 600–640°C with weight loss and were ascribed to the degradation of an ethoxysulfonyl group and organic component, respectively. The SPES film showed thermoresistivity up to 200°C.Figure 4
Thermogravimetric differential thermal analysis of SPES film.The film showed proton conductivity of2×10-2 S/cm at room temperature.


## 3.1. Synthesis of SPES

The synthesis of polysilsesquioxane having an arylsulfonate group as a side chain was planned by the hydrolytic polycondensation of trialkoxysilane. First, we planned the synthesis of ethyl 4-(2-triethoxysilylethyl)benzenesulfonate by the hydrosilylation of ethyl 4-vinylbenzenesulfonate and triethoxysilane, which resulted in the formation of a mixture of ethyl 4-(2-triethoxysilylethyl)benzenesulfonate and ethyl 4-(1-triethoxysilylethyl)benzenesulfonate. We therefore designed the structure of ethyl 4-(2-methyl-3-triethoxysilylpropoxy)benzenesulfonate as a target compound.The synthesis of ethyl 4-(2-methyl-3-triethoxysilylpropoxy)benzenesulfonate was established by a four-step reaction from sodium 4-hydroxybenzenesulfonate dihydrate.4-(2-Methyl-3-trichlorosilylpropoxy)benzenesulfonyl chloride was synthesized by the hydrosilylation of 4-(2-methyl-2-propenoxy)benzenesulfonyl chloride with trichlorosilane in the presence of chloroplatinic acid. This reaction proceeded gently to provide a unique product, 4-(2-methyl-3-trichlorosilylpropoxy)benzenesulfonyl chloride. This product was isolated by distillation under reduced pressure as a colorless liquid of high hydrolyzability. The formation of this compound was confirmed by the disappearance of signals corresponding to a vinylidene group in the1H and 13C NMR spectra.STES was synthesized by the reaction of 4-(2-methyl-3-trichlorosilylpropoxy)benzenesulfonyl chloride with ethanol. This reaction is one of the general procedures for replacing a chloro group with an ethoxy group: both chloro groups on silicon and sulfur were replaced with an ethoxy group in a one-step reaction. The formation of STES was confirmed by NMR and MASS analyses.SPES was synthesized by the hydrolysis of STES in the presence of hydrochloric acid under a nitrogen stream. The results for the synthesis of SPES are summarized in Table1 including the molecular weight and the percentage of sulfonic acid which were calculated based on the GPC analysis and the integral ratio of signals in the 1H NMR spectrum of SPES, respectively. The progress of hydrolytic polycondensation of STES was confirmed by the increasing viscosity of the hydrolysis product. The yield of SPES decreased with an increase in the molar ratio of water to STES, which suggests the formation of SPES with high molecular weight. In addition, the molecular weight and the percentage of sulfonic acid of SPES increased with the increase of the molar ratio of water to STES. When the molar ratio of water to STES was set to be more than 6, the molecular weight of SPES decreased in accordance with the degradation of the siloxane linkage by the sulfonic acid. SPES (number 2) was soluble in acetone, tetrahydrofuran, diethyl ether, and chloroform, and the solubility was independent of the molecular weight of SPES.Table 1
Results for the synthesis of SPESa.
Number
r (molar ratio of H2O/Si)
Yield (g)
GPCb
Percentagec of sulfonic acid/%
M
w
M
w/Mn
1
1.0
1.77
2.000
1.2
—
2
2.0
1.64
3.200
1.1
—
3
3.0
1.51
4.500
1.1
7
4
5.0
1.50
5.200
1.2
18
5
6.0
1.54
5.800
1.5
32
6
8.0
1.54
4.800
1.5
55
7
10.0
1.50
4.400
1.3
61
8
12.0
1.50
4.600
1.1
79
aScale in operation: STES 2.10 g (5 mmol). EtOH 0.46 g (10 mmol). Molar ratio: HCl/Si = 0.10.
bCalculated based on standard polystyrene.
cCalculated based on the integral ratio of signals in 1H NMR spectrum.The1H NMR spectrum of SPES (number 2) is shown in Figure 1. The intensity of signals due to the ethoxy group in the ethoxysulfonyl group was decreased compared to that of the 2-methylpropyl group, which suggests the hydrolysis of the ethoxysulfonyl group to form sulfonic acid. Additionally, the appearance of new signals due to a phenylene group at the lower field suggests the formation of sulfuric acid. The 29Si NMR spectra of SPES (number 2) and SPTS are shown in Figure 2. The signal due to STES disappeared in the spectrum of SPES, and new signals appeared in the chemical shift areas ascribed to T1, T2, and T3 unit structures. (The symbol Tn denotes the unit structure as RSi(OSi)n(OEt)3-n (n=1, 2, 3; R: 3-(4-ethoxysulfonylphenoxy)-2-methylpropyl group).) The appearance of signals due to T1, T2, and T3 unit structures supports the formation of polysilsesquioxane. The degree of condensation was calculated based on the equation AT3/(AT1+AT2+AT3), with ATn denoting the peak area of the unit structure Tn, as 46%. Approximately half of the silicon atoms in SPES condensed to form the silsesquioxane structure.1H NMR spectra of STES and SPES (number 2).
(a)
(b)29Si NMR spectra of STES and SPES (number 2).
(a)
(b)


## 3.2. Film Formation of SPES

SPES film was prepared by aging SPES (number 2) at 80°C for several days. A photograph of the SPES film is shown in Figure3. SPES was a colorless liquid, and its film became brown with heating, which may have been due to the formation of a sulfonic acid group from the ethoxysulfonyl group. The thickness was approximately 0.1 mm, and the film was brittle, easily broken into pieces when bended. The relatively low molecular weight and degree of crosslinking of SPES would cause this decrease in the film strength.Figure 3
A photograph of the SPES film.The film was colored by using an acid-functional dye: methyl red. The film was uniformly colored in red, which supports the formation of a sulfonic acid group by heating.The thermogravimetric differential thermal analysis of thin film is shown in Figure4. Exothermic peaks were found at 200–240°C and 600–640°C with weight loss and were ascribed to the degradation of an ethoxysulfonyl group and organic component, respectively. The SPES film showed thermoresistivity up to 200°C.Figure 4
Thermogravimetric differential thermal analysis of SPES film.The film showed proton conductivity of2×10-2 S/cm at room temperature.


## 4. Conclusion

Poly(3-(4-ethoxysulfonylphenoxy)-2-methylpropyl)silsesquioxane (SPES) was synthesized from sodium 4-(2-methyl-2-propenoxy)benzenesulfonate by a five-step reaction. The molecular weight of SPES was 2000–5200, reaching a maximum when the molar ratio of water was 6.0. The ethoxysulfonyl group was hydrolyzed when the molar ratio of water was greater than 3.0. The ratio of theT3 unit was 46% when the molecular weight of SPES was 3200. SPES film was prepared by heating SPES at 80°C for 3 days. The film was brown and brittle and showed thermal resistivity up to 200°C.



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*Source: 568301-2012-09-27.xml*