# Investigation of Wear Behaviour and Mechanical Properties of Titanium Diboride Reinforced AMMC Composites

Authors: Madhan Prabhu Deva; A. Parthiban; B. Radha Krishnan; Adisu Haile; Wubishet Degife
Journal: Advances in Materials Science and Engineering
 (2022)

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## Abstract

The aluminium metal matrix composites (AMMCs) are preferred in automotive and aerospace industries for higher strength, weight ratio, good corrosion resistance, and also better tribological properties. This study proposed that the AA7075 alloy methodology was enhanced by stir casting with titanium diboride (TiB2) particles at different percentages (5, 10, and 15 wt. %). The preheated titanium diboride powder is spread to the molten state AA7075 at 870°C to provide good weight resistance and delivery. The prepared composites are evaluated by wear analysis, tensile properties, hardness range, and microstructural behavior studies. Pin-on-disk and Rockwell hardness tester were used to analyze the wear behaviour and hardness level. The tensile strength and hardness have defined the strength of the proposed composite while the addition of TiB2 particles improves the hardness and tensile stress. The findings showed that adding TiB2 particles in the Al7075 matrix strengthened all properties compared to the Al7075 matrix. The scanning electron microscope and EDS were used to analyze the eroded surface and chemical composition of composites.


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## Body

## 1. Introduction

The AMMCs have higher usage in the automotive and aerospace industries due to their enhanced strength and low wear. Enhanced mechanical and tribological characteristics of AMMCs are provided by adding reinforcements such as Al2O3, SiC, TiC, TiB2, ZrO2, and B4C [1]. The AMMCs were made by the infiltration, powder metallurgy process, compocasting, and stir-casting method [2]. Many researchers used a stir-casting method to make AMMCs because of the maximum metal yield range, lower particle damage, and cost-efficiency. TiB2 particles are highly stiff and hard and had better thermal stability range among the different ceramic strengthening particles.The exothermic nature of the process, as well as the reduced oxidation, makes it a good candidate for wear-resistant composites [3]. Normally, the composites are made with oxide particles, carbide particles, boride particles, and nitride particles. While added, the ceramic particulate matter in different aluminium matrices significantly increased the matrix wear performance [4]. Matrix reinforcement fraction is the factor that influences the composite mechanical properties. The wear has been observed to be oxidative wear to a maximum of 800°C, and the oxidative wear has been found to dominate the wearing rate at higher temperatures. Certain scientists have found that the inhomogeneous distribution of reinforcement particles on a molten matrix results in low weight and low surface tension [5]. Preheating treatment is used to absorb gas and remove humidity and utilize any sort of surface protection, and inert gas-atmospheric alloying elements will improve the properties of the composites [6]. The particulate injection avoided or minimised agglomeration and particulate clusters and enhanced the homogeneous atmosphere and distribution. A few researchers have prepared AA7075-TiB2 composite and evaluated the mechanical properties. The AA7075-TiB2 composites were synthesized by the stir-casting method with different percentages of TiB2 (5%, 10%, and 15% wt.%), and then the quality of the composites was inspected by tribological characteristics. This paper investigated the tribological properties such as wear and microstructural characteristics of compounds AA7075-TiB2 and investigated mechanical properties such as hardness.


## 2. Experimental Analysis

AA7075 alloy has been preferred as a matrix material in this study, and the chemical composition is illustrated in Table1. An in situ reaction supported various amounts of TiB2 (5, 10, and 15 wt.%).Table 1
Chemical constitutions of Al7075 alloy.
ConstituentsContributionAl90.60Si0.05Fe0.1Cu1.6Mn0.05Mg2.31Cr0.11Zn5.12Ti0.05Ti + Zn0.01The small pieces of Al7075 alloy are used for the composite's synthesis process. The quantity of matrix to be melted is measured with an additional 25% of slag. The induction crucible furnace was used to melt the aluminium alloy 7075 for 20 min with a temperature range of 850°C.Meanwhile, TiB2 was preheated up to 500 °C, and then, it was added uniformly into the furnace for avoiding agglomeration and clustering. The stirring process was carried out with the four-blade stirrer for 10 minutes at 500 rpm. Due to the stirring process, a vortex is formed [7].The preheated TiB2 particles have been fed into the furnace at proper timing intervals through a hopper which is shown in Figure 1. Approximately 750°C was regulated with continuous stirring to produce a uniform mixture. The molding mixture is formed by refreshing the mold at room temperature into rods and plates as shown in Figure 2 [8].Figure 1
Titanium diboride.Figure 2
Bottom pouring stir casting.Figure3 shows the processing methodology for AMMC and evaluation methods. The hardness and tensile tests were carried out for prepared specimens based on the ASTM E384-11 and ASTM E08 standards [9]. In this paper, the ASTM G99 standard was used as shown in Table 2 followed by wear test analysis of Al7075-TiB2 composite. The surface morphological characteristics and microstructural views are analyzed to investigate how reinforced particles are mixing with matrix materials by using the scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS) [10].Figure 3
Processing methodology.Table 2
Sample preparation.
Sample no.ContributionAluminium (g)TiB2 (g)1Al7075 95% and TiB2 5%120.7310.222Al7075 90% and TiB2 10%114.3820.443Al7075 85% and TiB2 15%108.0230.66The components’ weight was determined by density, and the theoretical densities have been obtained by the rule of mixture (ROM).


## 3. Results and Discussions

### 3.1. EDAX Testing

In Figures4 to 6, the EDAX graph showed the aluminium and titanium peak values showing the particulate content of the composites made [11, 12]. The EDAX graph of Al7075/5% TiB2, Al7075/10% TiB2, and Al7075/15% TiB2 composites shown in figures indicates the presence of aluminium and titanium particles.Figure 4
EDAX graph of Al 7075 95% and TiB2 5%.Figure 5
EDAX graph of Al7075 90% and TiB2 10%.Figure 6
EDAX graph of Al7075 85% and TiB2 15%.


### 3.2. Impact of Reinforcement on Tensile Strength

The tensile load is applied to create large internal tensions that can cause the material to break if they exceed its strength [13]. Reinforcement particle bonding will be the major focus of the internal stress distribution. The tensile strength of Al7075 composites is enhanced when the percentage of TiB2 is increased, as shown in Figure 7.Figure 7
Tensile test report.Figure7 shows that while adding TiB2 particles, the tensile strength increases proportionally, increasing 242 MPa with 5% TiB2. Therefore, it reached up to 250 MPa for 10% TiB2. The tensile strength increases by 260 MPa at 15% TiB2. The percentage is due to the improved linkage between the matrix TiB2 and Al7075. The results show the TiB2 particles can increase the tensile stress level, but it may affect the ductile-brittle nature of the composite. Based on the problem mentioned above in this research, the TiB2 was added at the range of 5% to 15%.


### 3.3. Impact of Reinforcement on Hardness

In general, hardness is defined as the resistance to indentation. Figure8 depicts the Al7075 and TiB2 composites. Figure 8 indicates a major change in the prepared sample's microhardness values was an increase in 5% TiB2, 10% TiB2, and 15% TiB2. Table 3 shows the comparison of the pure Al7075 series and the hardness values such as Rockwell hardness number (RHN) enhanced with prepared samples.Figure 8
Hardness value report.Table 3
Hardness value for prepared samples.
S. noSpecimenIntenderLoad (kgf)Rockwell hardness (HR)MeanABCDE1Al7075 100%Ball100B64B64B65B63B64B642Al7075 95% and TiB2 5%Ball100B65B66B70B68B66B673Al7075 90% and TiB2 10%Ball100B69B68B72B73B70B70.44Al7075 85% and TiB2 15%Ball100B70B70B73B71B75B72TiB2 particles are more resistant to plastic deformation due to the Al7075 matrix; when integrated into the molten matrix, the TiB2 type preferred heterogeneous grain nucleation sites. Similarly, many researchers reported improving the value of Vickers hardness when TiB2 particles were added to a metallic matrix in situ process [14].


### 3.4. Impact of Reinforcement on Wear Properties

As a function of the TiB2 weight percentage, load, and speed, Figure 9 indicates Al7075 composite wear. Table 4 shows the wear rate at a constant sliding speed of different percentages of TiB2 refurbishments in the Al7075 matrix; therefore, the wear rate generally increases with the rising load. The wear loss of pure Al 7075 alloy is greater than that of other composites. When the amount of TiB2 reinforcements in the Al7075 matrix was increased, the wear rate values began to drop. For all sliding speeds, the same trend was observed as shown in Table 4. As seen on the base alloy diagram, the wear rate gap is 30–35%, and the inclusion of both loads is 15% TiB2.Figure 9
Wear rate load.Table 4
Wear rate for prepared samples.
Speed (rpm)Load (kg)Wear rate (mm3/min)5%10%15%20022.612.422.433.283.122.8643.433.273.1730023.272.932.8733.723.383.1943.923.553.3340023.423.193.1333.843.493.3143.973.723.59The graph of wear rates is not aligned with the increase in TiB2 strengthening due to the diverse wearing processes as shown in Figure 9. The wear rate at various loads at 200 rpm shows lower wear than that at the higher load. The wear rate is influenced by the reinforcement between the counterfeit and matrix. The adhesive phenomena are produced by contact asperity between the hard face (disk) and the soft surface (pin). Such touch is deformed by the effects of cold welding and is called adherence. This process leads to a loss of metal as sliding removes asperities from the surface, called adhesive wear. This is based on the applied load function, and TiB2 particles have a constant sliding speed for 20 minutes.Figure9 indicates that the effect of TiB2 on wear resistance at lower loads is high, and the wear resistance decreases as the load applied increases to 4 kg. The resulting graph is not linear, as improvements in adhesion and processing characteristics affect composite wear resistance.As specified in the Archard wear equation act, “hardness is directly proportionate to the composite’s volumetric wear resistance” [15]. The TiB2% was similar, with a substantial increase in the applied load of 2 kg, but the resistance fell to 3 kg. Due to their major changes in intensity, the proportion of particulate strengthening TiB2 is important to wear study. An analysis of the worn surface and surface morphology is important to better understand the nonlinear graphs found in these specimens.Figure10 to 12 show the SEM image of the TiB2 strengthened alliance Al7075 worn base, the specimen samples. The samples are fed on the different 2, 3, and 4 kg loads at room temperature. At first, chemical acetone was used to clean up the specimens and remove loose particles and dirt [16, 17]. The wear mechanism demonstrates the plastic surface's deformation due to relative contact motion, tension, asperities, and floor projections.Figure 10
SEM image of Al7075 95% and TiB2 5%.Figure 11
SEM image of Al7075 90% and TiB2 10%.Figure 12
SEM image of Al7075 85% and TiB2 15%.The wear rate inspection indicates that the grooves, scales, asperities, and ridges run in the sliding direction on the surface in parallel, as shown in Figure12. The aggression of the grooves grows as the functional factor increases, becoming higher and lower than the regular arming grooves created on the low TiB2 strengthening matrix, which are greater than the 15% TiB2 adding grooves. The vicinity of wear paths of a thin oxide film indicates the oxide waste surface layers [18]. The large craters were formed in the specimen, and the TiB2 reinforcement particles adhered to the greater scrap due to the sliding conditions of larger scrap.


## 3.1. EDAX Testing

In Figures4 to 6, the EDAX graph showed the aluminium and titanium peak values showing the particulate content of the composites made [11, 12]. The EDAX graph of Al7075/5% TiB2, Al7075/10% TiB2, and Al7075/15% TiB2 composites shown in figures indicates the presence of aluminium and titanium particles.Figure 4
EDAX graph of Al 7075 95% and TiB2 5%.Figure 5
EDAX graph of Al7075 90% and TiB2 10%.Figure 6
EDAX graph of Al7075 85% and TiB2 15%.


## 3.2. Impact of Reinforcement on Tensile Strength

The tensile load is applied to create large internal tensions that can cause the material to break if they exceed its strength [13]. Reinforcement particle bonding will be the major focus of the internal stress distribution. The tensile strength of Al7075 composites is enhanced when the percentage of TiB2 is increased, as shown in Figure 7.Figure 7
Tensile test report.Figure7 shows that while adding TiB2 particles, the tensile strength increases proportionally, increasing 242 MPa with 5% TiB2. Therefore, it reached up to 250 MPa for 10% TiB2. The tensile strength increases by 260 MPa at 15% TiB2. The percentage is due to the improved linkage between the matrix TiB2 and Al7075. The results show the TiB2 particles can increase the tensile stress level, but it may affect the ductile-brittle nature of the composite. Based on the problem mentioned above in this research, the TiB2 was added at the range of 5% to 15%.


## 3.3. Impact of Reinforcement on Hardness

In general, hardness is defined as the resistance to indentation. Figure8 depicts the Al7075 and TiB2 composites. Figure 8 indicates a major change in the prepared sample's microhardness values was an increase in 5% TiB2, 10% TiB2, and 15% TiB2. Table 3 shows the comparison of the pure Al7075 series and the hardness values such as Rockwell hardness number (RHN) enhanced with prepared samples.Figure 8
Hardness value report.Table 3
Hardness value for prepared samples.
S. noSpecimenIntenderLoad (kgf)Rockwell hardness (HR)MeanABCDE1Al7075 100%Ball100B64B64B65B63B64B642Al7075 95% and TiB2 5%Ball100B65B66B70B68B66B673Al7075 90% and TiB2 10%Ball100B69B68B72B73B70B70.44Al7075 85% and TiB2 15%Ball100B70B70B73B71B75B72TiB2 particles are more resistant to plastic deformation due to the Al7075 matrix; when integrated into the molten matrix, the TiB2 type preferred heterogeneous grain nucleation sites. Similarly, many researchers reported improving the value of Vickers hardness when TiB2 particles were added to a metallic matrix in situ process [14].


## 3.4. Impact of Reinforcement on Wear Properties

As a function of the TiB2 weight percentage, load, and speed, Figure 9 indicates Al7075 composite wear. Table 4 shows the wear rate at a constant sliding speed of different percentages of TiB2 refurbishments in the Al7075 matrix; therefore, the wear rate generally increases with the rising load. The wear loss of pure Al 7075 alloy is greater than that of other composites. When the amount of TiB2 reinforcements in the Al7075 matrix was increased, the wear rate values began to drop. For all sliding speeds, the same trend was observed as shown in Table 4. As seen on the base alloy diagram, the wear rate gap is 30–35%, and the inclusion of both loads is 15% TiB2.Figure 9
Wear rate load.Table 4
Wear rate for prepared samples.
Speed (rpm)Load (kg)Wear rate (mm3/min)5%10%15%20022.612.422.433.283.122.8643.433.273.1730023.272.932.8733.723.383.1943.923.553.3340023.423.193.1333.843.493.3143.973.723.59The graph of wear rates is not aligned with the increase in TiB2 strengthening due to the diverse wearing processes as shown in Figure 9. The wear rate at various loads at 200 rpm shows lower wear than that at the higher load. The wear rate is influenced by the reinforcement between the counterfeit and matrix. The adhesive phenomena are produced by contact asperity between the hard face (disk) and the soft surface (pin). Such touch is deformed by the effects of cold welding and is called adherence. This process leads to a loss of metal as sliding removes asperities from the surface, called adhesive wear. This is based on the applied load function, and TiB2 particles have a constant sliding speed for 20 minutes.Figure9 indicates that the effect of TiB2 on wear resistance at lower loads is high, and the wear resistance decreases as the load applied increases to 4 kg. The resulting graph is not linear, as improvements in adhesion and processing characteristics affect composite wear resistance.As specified in the Archard wear equation act, “hardness is directly proportionate to the composite’s volumetric wear resistance” [15]. The TiB2% was similar, with a substantial increase in the applied load of 2 kg, but the resistance fell to 3 kg. Due to their major changes in intensity, the proportion of particulate strengthening TiB2 is important to wear study. An analysis of the worn surface and surface morphology is important to better understand the nonlinear graphs found in these specimens.Figure10 to 12 show the SEM image of the TiB2 strengthened alliance Al7075 worn base, the specimen samples. The samples are fed on the different 2, 3, and 4 kg loads at room temperature. At first, chemical acetone was used to clean up the specimens and remove loose particles and dirt [16, 17]. The wear mechanism demonstrates the plastic surface's deformation due to relative contact motion, tension, asperities, and floor projections.Figure 10
SEM image of Al7075 95% and TiB2 5%.Figure 11
SEM image of Al7075 90% and TiB2 10%.Figure 12
SEM image of Al7075 85% and TiB2 15%.The wear rate inspection indicates that the grooves, scales, asperities, and ridges run in the sliding direction on the surface in parallel, as shown in Figure12. The aggression of the grooves grows as the functional factor increases, becoming higher and lower than the regular arming grooves created on the low TiB2 strengthening matrix, which are greater than the 15% TiB2 adding grooves. The vicinity of wear paths of a thin oxide film indicates the oxide waste surface layers [18]. The large craters were formed in the specimen, and the TiB2 reinforcement particles adhered to the greater scrap due to the sliding conditions of larger scrap.


## 4. Conclusion

The stirring process was carried out with different percentages of TiB2 enhancements applied to Al7075. The tensile stress, hardness range, and tribological characteristics were investigated in this research work; based on the investigation, the following findings have been reported:(1)
Upon melting, the preheating of the TiB2 particles has a significant effect. The porosity is that indicating that the bonding is much better.(2)
When the inclusion of TiB2 particles in the Al7075 matrix increases, microhardness values increase.(3)
The 2 kg load and 200 rpm sample processing with additional reinforcement of 15% at a rate of 200 rpm ensure optimum resistance to wear and minimum wear.(4)
Adding 15% of TiB2 with Al7075 leads to an increase in wear behavior.(5)
In the tribological view, the high load sliding distance and reinforcement percentage of TiB2 increase the wear rate.



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*Source: 5144010-2022-02-01.xml*