# Synthesis of Thermally Spherical CuO Nanoparticles

Authors: Nittaya Tamaekong; Chaikarn Liewhiran; Sukon Phanichphant
Journal: Journal of Nanomaterials
 (2014)

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## Abstract

Copper oxide (CuO) nanoparticles were successfully synthesized by a thermal method. The CuO nanoparticles were further characterized by thermogravimetric analysis (TGA), differential thermal analysis (DTA), X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDS), and high resolution transmission electron microscopy (HRTEM), respectively. The specific surface area (S
S
A
BET) of CuO nanoparticles was determined by nitrogen adsorption. The S
S
A
BET was found to be 99.67 m2/g (d
BET of 9.5 nm). The average diameter of the spherical CuO nanoparticles was approximately 6–9 nm.


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## Body

## 1. Introduction

Metal oxides play a very important role in many areas of chemistry, physics, and materials science [1–6]. The metal elements can form a large diversity of oxide compounds [7]. These elements can adopt much structural geometry with an electronic structure that can exhibit metallic, semiconductor, or insulator character. In technological applications, oxides are used in the fabrication of microelectronic circuits, sensors, piezoelectric devices, fuel cells, and coatings for the passivation of surfaces against corrosion and as catalysts. For example, almost all catalysts used in industrial applications involve an oxide as active phase, promoter, or “support.” In the chemical and petrochemical industries, products worth billions of dollars are generated every year through processes that use oxide and metal/oxide catalysts [8]. For the control of environmental pollution, catalysts or sorbents that contain oxides are employed to remove the CO, NOx, and SOx species formed during the combustion of fossil-derived fuels [9, 10]. Furthermore, the most active areas of the semiconductor industry involve the use of oxides [11]. Thus, most of the chips used in computers contain an oxide component.Oxide nanoparticles can exhibit unique physical and chemical properties due to their limited size and high density of corner or edge surface sites. Particle size is expected to influence three important groups of basic properties in any material. The first one comprises the structural characteristics, namely, the lattice symmetry and cell parameters [12]. Bulk oxides are usually robust and stable systems with well-defined crystallographic structures. However, the growing importance of surface-free energy and stress with decreasing particle size must be considered: changes in thermodynamic stability associated with size can induce modification of cell parameters and/or structural transformations [13], and in extreme cases the nanoparticle can disappear due to interactions with its surrounding environment and the high surface-free energy [14]. Nanomaterials have become important owing to their small size and large surface area. They exhibit unique properties which are not seen in bulk materials [15].CuO has been studied as ap-type semiconductor material with narrow band gap of 1.2 eV, because of the natural abundance of its starting material, low-cost production processing, nontoxic nature, and reasonably good electrical and optical properties. CuO nanoparticles were of great interest due to their potential applications in a wide variety of areas including electronic and optoelectronic devices, such as microelectromechanical systems, field effect transistors, electrochemical cells, gas sensors, magnetic storage media, solar cells, field emitters, and nanodevices for catalysis. It has also been recently emphasized that, apart from the size, the shape of the nanostructure is equally important for controlling different properties [16].However copper is an essential trace element for the normal function of many tissues, including the nervous system, immune system, heart, and skin, and for the formation of capillaries [17, 18], and copper is well metabolized by humans [19]. Copper(II) oxide has extremely low bioavailability (practically zero) and should not be taken in conditions of copper deficiency, especially as part of a multivitamin which also includes zinc or molybdenum [19]. Excessive zinc or molybdenum intake eliminates copper from the body. Copper oxide is used in vitamin supplements as a safe source of copper and over-the-counter treatments. Copper oxide is also used in consumer products such as pillowcases and socks, due to its cosmetic and antimicrobial properties [20–23]. The risk of dermal sensitivity to copper is considered extremely minimal [24].In this study, CuO was synthesized using ethanediolthermal method. Because of its low cost CuO is applied as gas sensing material to detect combustible, toxic, and pollution gases. Usually gas sensing properties of oxide semiconductors strongly depend on the surface of these materials. Thus, this research has been concentrating on improving high specific surface area of CuO nanoparticles.


## 2. Methods and Procedures

### 2.1. Synthesis of Nanoparticles

CuO nanoparticles were synthesized by the thermal method method. Copper (II) acetate (Cu(CH3COO)2·xH2O, Aldrich, 98%) and sodium hydroxide (NaOH, Merck, 99%) were used as the precursors, and ethanediol (C2H6O2, Ajex Finechem, 99.5%) was used as the solvent. In a typical procedure to synthesize the CuO nanoparticles, 25 mM of  Cu (CH3COO)2·xH2O and 100 mM of NaOH were dissolved in ethanediol at 80°C by stirring for 2 h on the basis of the following reaction:
(1)
Cu
(
C
H
3
COO
)
2
·
x
H
2
O
+
C
2
H
6
O
2
+
2NaOH
⟶
Cu
(
OH
)
2
+
2Na(
C
2
H
5
COO)
+
x
H
2
O
(2)
Cu
(
OH
)
2
+
2Na
(
C
2
H
5
COO
)
+
x
H
2
O
⟶
CuO
+
2Na(
C
2
H
5
COO)
+
x
H
2
OThe pH of the solution under continuous stirring was 9. Then, the final products were washed with DI water and ethanol several times by centrifugation. The obtained brown powder was subsequently dried at 80°C in air. The resultant powder was then characterized using TG/DTA for calcination temperatures.


### 2.2. Powder Characterizations

The thermogravimetric analysis (TGA) and differential thermal analysis (DTA) were carried on TGA7 and DTA7 (Perkin Elmer). The X-ray diffraction (XRD) patterns were correspondingly recorded with JEOL JDX-3530 operating with Cu Kα (λ
=
1.5405 Å). The elemental compositions of nanoparticles were analyzed by EDS quantitative analysis (Oxford Instrument). The specific surface area (SSABET) of the nanoparticles was measured by nitrogen adsorption at 77 K (Micromeritics Tristar) after degassing the sample for 1 h at 150°C under nitrogen fluctuation. The equivalent average primary particle diameter d
BET was calculated by d
BET
=
6
/
(
ρ
CuO
×
SSA
BET
) [25], where ρ
CuO is the density of CuO = 6.5 g/cm3 [26]. Finally, the accurate morphologies of nanoparticles were observed using HRTEM (JEOL JEM-2010).


## 2.1. Synthesis of Nanoparticles

CuO nanoparticles were synthesized by the thermal method method. Copper (II) acetate (Cu(CH3COO)2·xH2O, Aldrich, 98%) and sodium hydroxide (NaOH, Merck, 99%) were used as the precursors, and ethanediol (C2H6O2, Ajex Finechem, 99.5%) was used as the solvent. In a typical procedure to synthesize the CuO nanoparticles, 25 mM of  Cu (CH3COO)2·xH2O and 100 mM of NaOH were dissolved in ethanediol at 80°C by stirring for 2 h on the basis of the following reaction:
(1)
Cu
(
C
H
3
COO
)
2
·
x
H
2
O
+
C
2
H
6
O
2
+
2NaOH
⟶
Cu
(
OH
)
2
+
2Na(
C
2
H
5
COO)
+
x
H
2
O
(2)
Cu
(
OH
)
2
+
2Na
(
C
2
H
5
COO
)
+
x
H
2
O
⟶
CuO
+
2Na(
C
2
H
5
COO)
+
x
H
2
OThe pH of the solution under continuous stirring was 9. Then, the final products were washed with DI water and ethanol several times by centrifugation. The obtained brown powder was subsequently dried at 80°C in air. The resultant powder was then characterized using TG/DTA for calcination temperatures.


## 2.2. Powder Characterizations

The thermogravimetric analysis (TGA) and differential thermal analysis (DTA) were carried on TGA7 and DTA7 (Perkin Elmer). The X-ray diffraction (XRD) patterns were correspondingly recorded with JEOL JDX-3530 operating with Cu Kα (λ
=
1.5405 Å). The elemental compositions of nanoparticles were analyzed by EDS quantitative analysis (Oxford Instrument). The specific surface area (SSABET) of the nanoparticles was measured by nitrogen adsorption at 77 K (Micromeritics Tristar) after degassing the sample for 1 h at 150°C under nitrogen fluctuation. The equivalent average primary particle diameter d
BET was calculated by d
BET
=
6
/
(
ρ
CuO
×
SSA
BET
) [25], where ρ
CuO is the density of CuO = 6.5 g/cm3 [26]. Finally, the accurate morphologies of nanoparticles were observed using HRTEM (JEOL JEM-2010).


## 3. Results and Discussion

The TGA/DTA profile for the CuO precursor was shown in Figure1. The TGA curve showed a three-step decomposition of the precursor to form the CuO. The weight losses were decomposed under excited temperatures ranging 35–166°C, 166–287°C, and 287–370°C. The initial weight loss below 166°C (~9%) was caused by the water evaporation (moisture) and organic solvent molecules according to two minor endotherms peaks on the DTA curves (56–160°C) in this region. The second decomposition step of TGA curve at 166–287°C can be attributed to the pyrolysis and combustion of organic compounds form precursor and solvent which leave the system in the form of CO
x (x
=
1
,
2) and organic gases. This observation was consistent with the well-resolved exothermic in the DTA curves at approximately 163–300°C [27]. According to the temperature that was approximately up to 500°C, here the CuO nanopowder was calcined at 500°C for 2 h.Figure 1
TG/DTA curve of copper acetate precursor.For XRD patterns of the CuO nanoparticles, all peaks can be confirmed to be the monoclinic phase of CuO (JCPDS no. 48–1548) as shown in Figure2. The smaller size of CuO nanoparticles can be predicted consistently with the broadening diffraction peaks of XRD patterns. Moreover, the crystallite size based on the broadening diffraction peaks was approximately estimated from the corresponding X-ray spectral peak employing the Debye-Scherrer’s formula (2) [28]. The calculated value was estimated to be 6.1 nm:
(3)
d
(
Å
)
=
k
λ
β
cos
θ
,
where k is an empirical constant equal to 0.9 as the spherical particles, λ is the wavelength of the X-ray source (1.5405 Å), β is the full width at half maximum of the diffraction peak, and θ is the angular position of the diffraction peak. According to the BET method, the specific surface area (SSABET) of CuO nanoparticles was measured to be 99.67 m2/g. It was found that the calculated particle size of sample was 9.3 nm [25]. The accurate particle size and morphologies of CuO nanoparticle were confirmed by SEM and TEM bright-field images. Figures 3(a) and 3(b) showed the morphology of highly crystalline CuO nanoparticles from SEM/EDS and TEM analyses. The SEM micrograph clearly showed rough agglomeration of nanostructural homogeneities with spherical morphologies of CuO nanoparticles. The SEM observation showed the presence of agglomerated nanospheres with an average diameter of 10–20 nm. Therefore, from this observation only the rough morphology was found. Nevertheless, the accurate sizes and morphology of the nanoparticles can be estimated from the TEM analysis. While the SEM images provide 3D morphology and estimated particle sizes, TEM images can reveal internal structure and a more accurate measurement of particle size and morphology. The corresponding EDS spectrum can also confirm the presence of Cu and O elements in sample. The spherical CuO nanoparticles are evaluated by EDS quantitative analysis software (Oxford Instrument) and found to have 59.33 at% of Cu and 40.67 at% of O. If it is in atomic %, theoretically the Cu will be 50% and O will be 50%. But in the experimental found 59.33 at% of Cu and 40.67 at% of O. Because of the EDS, analysis techniques can select only one area. Thus the amount of Cu and O in difference area may be difference values, so in the dispersion of CuO nanoparticles were found into a high and poor dispersion, respectively as shown in Figure 3(a). The HRTEM bright-field images of CuO nanoparticles presented in Figure 3(b) revealed spherical morphology of the synthesized nanoparticles with the crystallite size of 5–15 nm. The corresponding diffraction pattern of the nanoparticles was in an inset which clearly indicated the CuO lattice planes. Thus, the results from XRD, BET, and HRTEM also confirmed the morphological properties of CuO nanoparticles by controlling the condition of ethanediol route.Figure 2
XRD patterns of CuO nanoparticles.(a) SEM/EDS analyses and (b) HRTEM image of CuO morphologies. Insets show the corresponding diffraction patterns of the particles related to the CuO lattice planes.
(a)
(b)


## 4. Conclusion

The ethanediolthermal route was used to synthesize CuO nanoparticles by controlling the fictionalization of physical properties. The XRD spectrum can be observed to confirm the monoclinic phase of CuO, and the corresponding calculated size was 6.1 nm. The SSABET was found to be 99.67 m2/g (d
BET of 9.3 nm). The HRTEM revealed spherical morphology of CuO nanoparticles with the crystallite size ranging from 5 to 15 nm.



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*Source: 507978-2014-01-08.xml*