# The Construct and Interpretation of Chelated Coordination Polymers and Their Use in Nanomaterials Research

Authors: Khalida Abbas Omran
Journal: Journal of Environmental and Public Health
 (2022)

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## Abstract

Presently, an important step from basic research to practical applications is synthesizing nanostructured materials. Metal-organic structures, as well as coordination polymers, are a diverse group of materials with a wide range of potential and properties applications. It has been difficult to get these materials into commercial use because of many drawbacks. Polymers containing chelated units are described and assessed for their advancements and problems in preparation, properties, and structure. Here, a proposed approach based on designing coordination polymeric materials with chelated units using the metal-ligand approach (CPM-CU-MA) has been introduced for a columnar-layered plan, supramolecular components, and building levels. Nanocomposite materials can be formed through the thermal transformation of coordination polymers based on donor atoms. The polymeric metal chelates (PMCs) are categorized according to luminescent coordination polymer (LCoP) development. It is classified as macrocyclic intracomplex, polynuclear, and molecular according to its macrostructure. Supramolecular networks (SMNs) can be transformed into a coordination polymer by introducing cyclo-dehydrogenation of natural building blocks on a surface. The structure-property connections of LCPs can influence a framework of liquid crystal display (LCP) that has been given based on LC phase modulators with a large modulation depth and has useful applications in LC lens. In the spatial organization of PMCs, the main focus is on the commonalities and contrasts between higher- and lower-molecular-weight chelates based on molecularly imprinted sensors (MISs) and nanomaterial sensors for a wide range of uses. New functional nanoparticles based on the molecular components have exciting potential, as demonstrated by these findings based on parameters risk factors for human health, hazards reduction in the environment, lack of cost-effectiveness, environmental sustainability, and bioavailability of polymers with an overall performance of 95.3%.


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## Body

## 1. Introduction to Coordination Polymers

Recently, coordination polymers have received much attention as new metal-organic hybrid materials. There are various ways in which the organic ligand is connected to the metal ions and other metal-containing cluster nodes that make up the extended network [1]. Metal-organic structures or porous organic polymers are used to refer to CPs with perpetual porous structure [2]. CPs, on the other hand, are outstanding precursors for the creation of a new class of highly tunable polymeric nanoparticles for pumped storage, sensing, catalyst supports, pollutant adsorbents, and electrochemistry applications [3]. In nanomaterials, as redox-active materials offer new insights into electrostatic interaction in the cooperation space and show characteristics that could support future apparatus development, progress in this area is critical for fundamental research and applied research [4]. For the hydrogen evolution reaction (HER), CPs and their composites have recently received much attention because of their numerous advantages, reflecting the manufacturing community’s urgent need to enhance chemical reliability and power storage advanced technologies performance [5].There are many applications for coordination polymers that use their luminous properties. Luminescence is produced after stimulating the particles, ions, or molecules [6]. The substances and hydrothermal stability of CPs are among the most important characteristics of nanomaterials. However, even with careful selection of metals and linkers, the coordination environment changes, and thus, the original structure is destroyed by redox reactions [7]. It is a well-known organic molecule with outstanding electro/photochromic and membrane processes relevant to electron appropriateness and oxidation activity [8]. The features of double-charged viologen derivatives are used as building blocks in the structure materials in these frameworks [9]. One of their strongest suits is the ability to form charge transfer (CT) systems species rich in electrons, such as substances, electronics, and photo-stimulated species [10].CP metal bipyridinium’s unique properties as a viologen compound inspire future functional studies [11]. In luminescence, CP metal bipyridinium is an excited state spontaneously consisting of photons from an excited state that can be generated in various ways, including photonic stimulation, mechanical stresses, and chemical/electrochemical responses [12]. To explain luminescence, a photon absorbs and then emits a photon, causing an electron to move from a ground state to an excited one and then back to a ground state again [13]. Nanomaterials and nanostructured polymers (NNPs) can be used to create electrochemical sensors that can be used in a variety of applications using SMN. Due to their high stability, short electro polymerization time, and high specificity toward the target molecule, MIPs-based electrochemical sensors have gained traction [14]. NNPs can be synthesized using various methods, and the most common are surplus and outer layer imprinting [15].This method is the most widely used for printing polymers because it involves embedding a template molecule entirely in the matrix material and then removing the imprinted material completely after polymer chains [13]. There are many commercial polymeric materials and nanomaterials on the market today that are inert, and as such, surface modification is essential to boost their adherence and to soak properties by adding polar as well as other structural features to their surfaces [16]. According to commercial polymeric materials, the number of publications on nanomaterials and polymers has increased exponentially since their inception [17]. An interesting aspect of nanoparticles is their magnitude, structure, and surface morphology [18]. It is important to remember that microparticles tend to aggregate into materials, especially when improperly stabilized during the manufacturing and application processes [19]. However, nanomaterials have some undesirable side effects, the most notable of which is a change in the assimilation rate used to administer medication, fight diseases, and identify diseases [20]. Because of this, composites now have a wider range of potential applications due to the convergence of nanoscience with polymer science and technology [20]. Nearly every field in which polymers can be used has found new uses for these materials. An overview of the most recent developments in electrochemical sensing using MIPs and nanomaterials is provided in the following review.The major contributions of this study involve the following points:(i)
Designing the nature of the donor atoms influences the classification of luminescent coordination polymers (LCoPs)(ii)
Supramolecular networks (SMNs) are introduced as a coordination polymer by cyclo-dehydrogenation of natural building blocks on a surface(iii)
The structure-property connections of LCPs based on LC phase modulators with a large modulation depth are implemented in the LCP frameworkThe remaining section of this study is given as follows: Section2 deals with the historical background of the coordination of polymers, followed by the implementation of our proposed CPM-CU-MA method in Section 3. Sections 4 and 5 give the experimental analysis and conclusion with the future scope.


## 2. Related Works on Coordination Polymers

Because organic ligands can vary in their versatility, duration, and symmetry, the building elements of desirable frameworks can be greatly enhanced using chelates. An infinite array of metal ions is linked together in a coordination polymer by coordinated ligands. Given the significance of coordination polymers as an essential group of organic-inorganic hybrid materials for functionalizing inorganic substances such as micro or nanofillers with organic and/or inorganic molecules able to interact with organic matrixes to provide enhanced properties.Capacitors based on cluster-based coordination polymers (C-CPs) have already shown commitment. Using thermal treatment reactions in laboratory settings, five additional new C-CPs based on organophosphates Strandberg-type clusters are synthesized at various ph levels to investigate the relationship between crystal lattice and capacitor achievement [21]. For our systematic analysis of the impacts of pH on CCP assembly, we isolated five compounds. For the first time, polyoxometalate groupings of organophosphates Strandberg type were explored as electrocatalysts.Polymeric chains containing cubane-like CoII4L4 components and dicarboxylates (CoL-2CB) were synthesized and characterized using monocrystalline diffraction and total X-ray dispersion [22]. To produce cubane-like compounds with a moderate interfacial area of 17–49 m2/g−1, heavy rainfall is a quick and flexible method that allows surface chemical reactions, even though the powders are nonporous. Oxygen evolution reactions can be carried out using an amorphous cubane-like polymer.A relatively new class of polyoxometalate-based coordination polymers (POMCPs) has already made significant strides in recent decades due to their remarkable structural characteristics and useful characteristics in photonics, electrodynamics, and organic photocatalyst [23]. Keggin-type POM derivatives such as these coordination polymers add structural variety. They often offer a way to design functional materials with exceptional properties guided by a structure-property correlation. Catalysis-related applications, as well as synthetic strategies, are indeed discussed.The numerous antitumor activities induced by nitric oxide (NO) include induction and hypersensitivity to chemo- and radiotherapy (CDT). As a result, it has received much attention in cancer intervention [24]. This symbiotic NO-CDT effect has been shown to slow tumorigenesis. The effect of NO-CDT therapy and the simple and efficient strategy to build a cooperative polymer nanoparticle were both demonstrated in this study to enhance the precision of NO targeting and treatment efficacy. This is accomplished through simple precipitation and partial ion exchange.Inorganic CPs (i-CPs) and organic CPs (o-CPs) are the two types of coordination polymers (CPs) proposed based on polycrystalline states and features as a recent research direction for CPs based on their successful crystal engineering by (i-o-CPs). Materials must be controlled in their liquid or translucent states [25], and this is to fine-tune the material’s properties such as conductivity, transparency, and porosity. Liquid/glass o-CPs have a unique landscape that allows for characteristics and features to be developed that complement those found in the crystalline phase.The problems risk factors for human health, hazards reduction in the environment, lack of cost-effectiveness, and environmental sustainability from the above research of C-CPs, CoL-2CB, POMCPs, NO-CDT, and i-o-CPs are compared and improved in our proposed method CPM-CU-MA which is implemented and analyzed in the following sections.


## 3. Proposed Coordination of Polymeric Materials with Chelated Units Using the Metal-Ligand Approach

When doing research with this kind of cutting-edge material, the interphase between the components becomes a crucial factor to take into consideration and will be centred in a coordination polymer, an inorganic or organometallic polymer structure. Here, in this study, a coordination polymer is extended based on a dimensional compound with repetitive coordination entities that are compared and analyzed. Chelated unit polymers are described and evaluated for advancements and problems in preparation, properties, and structure. Coordination polymeric materials are used in this approach.


### 3.1. Analysis 1: Designing the Nature of the Donor Atoms Influences the Classification of Luminescent Coordination Polymers (LCoP)

Photonic stimulation, mechanical stresses, redox processes, and other mechanisms contribute to the complex phenomenon of luminescence, which involves the photoluminescence of radiation from an excited state. Various radiative and nonradiative relaxation processes are involved in the strategic luminescence mechanism, which involves an electron moving from the ground to an excited state by absorbing a photon and then returning to the ground state with concurrent state photons emitted shown in Figure1.Figure 1
Mechanism and key transition in LCoPs.Short excited state lifetimes (1–100 ns) are a result of fluorescence transitions, which occur from the excited state (es) to the resting state (rs). Because of this, the excited singlet (es) undergoes an intersystem crossing (ISC) to the energized triplet state (ts), followed by a forbidden photon-emitting transition back to the ground state (rs), which is equal to 1 longer. The molecular framework of CPs can explain the CPs’ luminescence in the first place. Indeed, this method is often unable to account for all of the identified luminescence effects in their entirety, however, as shown in Figure1.(1)ρdtσCPe−ρdtcphtn∗es/rsmi∗ol∗ca=n,htn∗es/rs,wheren≥0.Most often, CPs exhibit emission linesCPe due to the presence of chelates cp that are coordinated to metal complexes or clusters by differentiation ρ/dt denoted in equation (1). A number of host molecules htn like solvent molecules can get intertwined in these structures ρ/dtσCPe, which can lead to emissions in CP in some cases ρ/dtcphtn∗es/rs/mi∗ol∗ca. In this way, CPs with configurable luminescence can be synthesized through a careful selection of metallic ions mi, organic linkers ol, and cleaning agents ca that are entangled in one another htn∗es/rs/mi∗ol∗ca, among other things by n value.This group comprises lanthanide and actinide metals, commonly found in metal-centered luminescence (MCL). These compounds can reduce the risk factors for human beings, which can be compared in the following section. However, CPs with transformation and p-block metal cations have shown key transitions in luminescence in some cases, as illustrated in Figure2. Metal-centered (MCT) emissions, based on d-d or f-f transitions, ligand-centered (LCT) emitters originating from organic ligands, and numerous charge transport emissions, such as ligand-to-metal charge transfer (LMCT), metal-to-ligand charge transfer (MLCT), ligand-to-ligand charge transfer (LLCT), and metal-to-metal charge transfer (MMCT) are among the most common mechanisms used in LCoPs.(2)htn∗esrs=ρdtmi+ρdtol+ρdtca∗n1−htn.Figure 2
LCoP’s general mechanism of detection.Based on their properties ones/rs, the nanoparticles will either be in oil or water. In the organic phase, hydrophobic nanoparticles are found, while hydrophilic nanoparticles htn are found in the liquid phase, identified using equation (2). It is possible to synthesize CPs with customizable luminescence by carefully selecting metallic ions ρ/dtmi, organic likers ρ/dtol , and cleaning agentsρ/dtca. As shown in equation (1), the presence of chelates, which are coordinated to metal complexes or clusters n/1−htn, causes emission lines to appear in CP materials through htn∗es/rs.CP syntheses, luminescence detection, and common luminescence sensing pathways are shown in Figure2. Energy transfer occurs between donor and acceptor molecular entity without the use of radiation. The fluorescence intensity and exciton lifetime of the donor decreased due to LCoP. In contrast, the acceptor’s excitation state lifetime and emission frequency increased due to reduction and recombination. This method can study Coulombic interactions between molecules because it is distance-dependent. Electron transfer is a process in which excitons from donor particles are transferred to acceptor molecules via a nonradiative pathway, hydrating the luminescence of the donor particles. Thus, this mechanism can be used in situations where the donor and acceptor are in close proximity. It is possible to transfer electrons in a single or two-step process.(3)nf=∑∑m∗mi∗ol∗ci,dcρdt∗dnpi−lri,pr−npi−lri.To better understand the movement of nanofluidsnf in coordination found by Brownian, we used Brownian diffusion, as shown in equation (3), to reduce human hazards to environments and humans, compared with other methods as follows. The nanoparticle dispersion coefficient np is the density of nanoparticles dnp in interval I; the net loss ratelr is the intensity of nanoparticles in an interval npi−lri and through in phase dcρ/dt. The pores pr absorb nanoparticles as they move through m∗mi∗ol∗ci for hazard reduction. The massive loss rate of nanomaterials after modification must therefore be taken into account using the summation process dcρ/dt∗dnpi−lri.(4)dcρdt=rd∗mi∗1−gmmax−gm+es,limax−gm∗ρdtli+lt,caρdt1−ht∗gmmax−gm−er.From equations (2) and (4), radiation rd is needed to transfer energy from one molecule to another. During LCoP, the donor’s absorption spectrum gm and exciton lifetime are maximized and given as gm/max−gm while the acceptor’s excitation state es, longevity lt, and emission recurrence er continued to increase from equation (4). The presence of various metallic ions mi and groupings, ligand compounds li, and different configurations a formed by altering the synthetic circumstancesmax−gm∗ρ/dtli conversations between cross-linking frameworks caρ/dt1−ht∗gm/max−gm constrained rotation in structures, guest molecules, and the method in which server and guest communication led to a complicated luminescence mechanism in CPs.


### 3.2. Analysis 2: Supramolecular Networks (SMNs) in Coordination Polymer by Cyclo-Dehydrogenation

Chemically bonded polymers linked by transitory, noncovalent bonds in supramolecular polymer networks exhibit properties such as stimuli attentiveness, identity, and structure, making them an intriguing class of soft materials. The major advantages of supramolecular polymer networks are based on the versatility of coordination polymer networks and the flexibility of physical bonding with chelates.Polymer science has recently introduced a new nanomaterial that combines the flexibility of manufacturer synthetic connections with the redox potential. The versatility of physical bonding in a supramolecular network of polymers is given in Figure3, with bonding and nonbonding structures based on low and high temperatures. To construct the network chains from noncovalently associating polymeric materials or to tie covalently joined and yet noncovalently associated polymer chains together, these supramolecular bonds such as hydrogen coordination polymers, p–p polymers, or metal chelates are used.(5)OL,mi=htncnn+1ps∗∑i=0nhtncnn∗ra11ra12⋯ra1nra12ra22⋯ra2n⋮⋮⋯⋮ran1ran2⋯rann.Figure 3
Diagrammatic representation of SMN.It is possible to connect the organicO ligand to the metal ions L,mi and other cluster nodes cnn+1 in the extended network htn from equation (1) in various ways from equation (5). Perpetual porous structures ps are referred to as metal-organic formations ∑i=0nhtncnn or highly permeable organic polymers by n+1, respectively. Advances in redox-active ra materials in nanomaterials in matrices formra11ra12⋯ra1nra12ra22⋯ra2n⋮⋮⋯⋮ran1ran2⋯rann are essential for both fundamental and applied research because they provide new insights into an iconic attraction in the cooperation storage cn and pressure coefficient htncnn+1 that may support future apparatus development.(6)ps=−1logn∑i=0nstnm×logstnm+OL,mi.Some of these carbon-based rigorous aromatic binding sitesstnm may be detrimental to humans and the environment by ∑i=0nstnm×logstnm being useful in the preparation of rigid connections with internal surface area.(7)ESR=1loght∑i=1nsphsni,hpi+1lognhsni,hpi−sp.To create electrochemical sensorsESR that can be used in a wide range of applications, nanomaterials can be used as 1/loght. This sustainability of electrochemical sensors has become popular because of their high stability hsni, short polymers time sp, and high precision hpi as sphsni,hpi for the target molecule may be stated as 1/loglognhsni,hpi and can be calculated from the above equation by the combination sphsni,hpi+1/loglognhsni,hpi (7).As shown in Figure4, the degree of supramolecular polymers is directly proportional to the chelating constant. Supramolecular polymers based on bifunctional cyclo-dehydrogenation can improve their carbon atoms and macromolecular lifeforms by increasing the polymeric coordination concentration. Due to this combined effect, the supramolecular chain molecules become entangled at a certain concentration. A true chelation transition is observed at critical concentrations in systems that can form implicit nodes with a feature greater than two.(8)lgscm=tsexpmc∗m2c1−rm∫mAb∗∑i=1nma.Figure 4
Comparison of SMN with chelates.For example, those formed by polymeric materials modified to be dehydrogenation or basic components constituted of transition metals to remove the risk factors for human health, reduce environmental dangers and lack of cost-effectiveness as shown in Figure5. Metal-chelating polymers (MCPs) play a critical role in mass cytometric mc based on multimode chemiluminescence m2c and the ligands lg in CPs are made up of both synthetic compound’s modules scm. Each metal atom ma in the polymer is carried by the polymer mentioned in equation (8) in the form of noble metals ∑i=1nma, and the polymer’s reactionary functionality expmc∗m2c is used to attach the radioactive metal materials rm to the monoclonal antibody mAb using integration as 1−rm∫mAb. It is possible to have two or even more donor atoms form covalent bonds with two or more different parts of the ligand to create a chelating ligand, given as the combination expmc∗m2c/1−rm∫mAb. It could be said that these are multivalent ligands or ligands with multiple donor sites, depending on the context.Figure 5
Path flow process of MPC in CPs.


### 3.3. Analysis 3: The Structure-Property Connections of LCPs Based on CPs Phase Modulators with a Large Modulation Framework

Polymer fibers, waveguides, supercapacitors, contour memory, surface functionalization, storage systems, electric motors, and more use LCPs because of their superior properties and wide range of applications. CPs can combine the major area of LCP in the chelating process, and the relation between them is illustrated in Figure6.Figure 6
Representation of shearing LPC in CPs.Fast response and massive phase modulation intensity can be achieved using coordination polymer network liquid crystals; however, these cells are highly scattered in the visible spectrum. Indium-tin-oxide is being used to coat both substrates’ inside surfaces, and there is no need for an alignment layer depicted in Figure6. In this two-step procedure, 365 nm ultraviolet radiation light highlights the cell in the electrode with a voltage (v). A mismatch in the refractive index between the randomly distributed LC and the CP caused the cell to be transparent immediately following the curing process. As a final step, the upper substrate is sheared with precision, and the length between the shears is 350 m. Since the LC molecules are all aligned in the same direction, the cell became transparent.(9)prnms=∑i=−∞∞ncm−Sms+∑i=−∞∞mc∗m2c2mc/2∗ncm−Sms,(10)∑i=−∞∞mc∗m2c=1−2mc/2∗ncm−Sms∗mc1−rm∫mAb.As precursorspr for the development of nanocomposite materials nms, CPs are increasingly in demand because they serve as a starting material Sms and stabilizers ncm−Sms for the nanoparticles that are formed using multimode chemiluminescent from equation (8) mc∗m2c. When it comes to designing new materials like 2mc/2, the use of solid-state thermolysis with infinity limits through summation ∑i=−∞∞mc∗m2c to create new nanostructures is a straightforward and logical method using equation (9). Numerous studies for the analysis of the cost-effectiveness of thermal decomposition 2mc/2∗ncm−Sms of CPs have been carried out to produce different types of nanomaterials with the desired sizes, and morphological characteristics are denoted by ∑i=−∞∞mc∗m2c2mc/2∗ncm−Sms to the monoclonal antibody mAb for the analysis of the bioavailability of polymers in equation (10).The comparison of LPC switching time in two phases is shown in Table1. There are five levels of phase retardation, and 100–10% phase shift is used to describe the system performance. For various applications, the operating temperature of LC devices can vary greatly. However, many of the CP’s characteristics of LC content are strongly influenced by the temperature at which they are used. This necessitates further investigation into the LPC’s temperature effects. The rise from the first phase to the second phase takes the longest (745 s). As a result, the rise time is directly related to the voltage switching, for a reduced voltage switch is usually associated with a small phase transition.Table 1
Comparison of switching time of LPC in two phases.
Response timeSecond phase01234First phase07454003302061289531349210231038639421533593794304894408370442267Carbon-based nanostructured polymers and their diverse biochemical applications, from inorganic to organic molecules, are the subject of various research. Aside from a host of advantages, including specificity and sensitivity, MIPs have a few drawbacks, including loss of permeability, catalytic performance, and a price that limits their use in various fields, which are overcome in our proposed technique with the implementation of CPs.MIP scan recognizes molecules because of the presence of a pattern in the synthesis process that involves polymerization. During MIP self-assembly, specific binding occurs between the MIP and the template molecules through linking agents with monomers, as illustrated in Figure7. Antibodies and proteases can be imitated using these synthetic receptors by removing templates. MIPs had many advantages, including their ability to be robust, stable, and low cost to prepare, as well as their ability to recognize specific analytes by rebinding the template with a high degree of sensitivity to those analytes. Bioanalytical methods and sensors both rely on MIPs because of their excellent selectivity and selectivity for sample processing. Because of their low cost and ease of preparation, MIPs can be used as chemically synthesized receptors for recognition in electrochemical sensors.(11)ECs=NM+MP+1wl,Tr=NM+MPπ=ECsmc1−rm∫mAb.Figure 7
The process involved in MIPs.It is normalizedNM to the same value measured in a monoclinic phase MP here. For the sample’s transmittance Tr to decrease, the wavelength 1/wl must be reduced by NM+MP+1/wl. The operating temperature of LC devices is analyzed by the squared value of ECs and can vary widely depending on the application of phase difference as NM+MP/π. Many of the EO characteristics of LC material ECsmc/1−rm∫mAb, on the other hand, are highly dependent on temperature through equation (11) as Tr=NM+MP/π.Analytical chemistry’s field of nanotechnology has recently risen to prominence. Comprehension, control, and influence of matter at the nanoscale level in creating nanomaterials, devices, and structures are known as nanoscale design. It is transparent that the proposed MIPs have several advantages over traditional MIPs, including their ability to bind quickly and effectively to specific analytes, their ability to be magnetically attracted, and their shorter pretreatment time. Electrochemical sensing uses magnetic nanoparticles because of their separation and preconcentration characteristics, poor bioavailability, ease of preparation, and low cost for support fundamental decorated nanostructured polymers. MIPS-based electrochemical sensors employ nanomaterials in two primary ways. As shown in Figure8, they can be used as core materials in the synthesis of MIPs, or electrode surface modifiers, to enhance and enlarge the electrochemical notification due to their high reflectivity and large surface area. Nanomaterials combined with MIPs for electrochemical sensing are the focus of this review.(12)MP=ecihti−1psECsht2psi−1∗pSi−2.Figure 8
Schematic representation of template in MIPs.By now, many approaches to MOF synthesis have been developed, which are usually conventionally divided into two big groups: conventional synthesis and alternative synthesis methods. These are compared using equation (12) based on the overall performance of polymers. Traditional electric combustion eci without parallel processingECs is referred to as conventional synthesis, a term used to describe reactions that do not require heating ∑nhti−1ps. When a reaction contains strong water 2psi−1 and a ligand mixture ∗pSi−2, the solution is added to dissolve the salt and ligand mixture by ECsht2psi−1∗pSi−2, which is the most common method for making MIPs.Although many others have been reported, the most widely used methods for synthesizing MIPs are plentiful and outer layer imprinting. When it comes to imprinting polymer composites, the most common method relies on the principle of completely imprinting the template molecule into the polymer matrices and then removing it completely after polymerization.From the above implementation, our proposed method CPM-CU-MA has a result enhanced by overcoming all the issues in the other traditional methods, C-CPs, CoL-2CB, POMCPs, NO-CDT, and i-o-CPs, to optimize the result with improved parameters risk factors for human health, hazards reduction in the environment, lack of cost-effectiveness, and environmental sustainability.


## 3.1. Analysis 1: Designing the Nature of the Donor Atoms Influences the Classification of Luminescent Coordination Polymers (LCoP)

Photonic stimulation, mechanical stresses, redox processes, and other mechanisms contribute to the complex phenomenon of luminescence, which involves the photoluminescence of radiation from an excited state. Various radiative and nonradiative relaxation processes are involved in the strategic luminescence mechanism, which involves an electron moving from the ground to an excited state by absorbing a photon and then returning to the ground state with concurrent state photons emitted shown in Figure1.Figure 1
Mechanism and key transition in LCoPs.Short excited state lifetimes (1–100 ns) are a result of fluorescence transitions, which occur from the excited state (es) to the resting state (rs). Because of this, the excited singlet (es) undergoes an intersystem crossing (ISC) to the energized triplet state (ts), followed by a forbidden photon-emitting transition back to the ground state (rs), which is equal to 1 longer. The molecular framework of CPs can explain the CPs’ luminescence in the first place. Indeed, this method is often unable to account for all of the identified luminescence effects in their entirety, however, as shown in Figure1.(1)ρdtσCPe−ρdtcphtn∗es/rsmi∗ol∗ca=n,htn∗es/rs,wheren≥0.Most often, CPs exhibit emission linesCPe due to the presence of chelates cp that are coordinated to metal complexes or clusters by differentiation ρ/dt denoted in equation (1). A number of host molecules htn like solvent molecules can get intertwined in these structures ρ/dtσCPe, which can lead to emissions in CP in some cases ρ/dtcphtn∗es/rs/mi∗ol∗ca. In this way, CPs with configurable luminescence can be synthesized through a careful selection of metallic ions mi, organic linkers ol, and cleaning agents ca that are entangled in one another htn∗es/rs/mi∗ol∗ca, among other things by n value.This group comprises lanthanide and actinide metals, commonly found in metal-centered luminescence (MCL). These compounds can reduce the risk factors for human beings, which can be compared in the following section. However, CPs with transformation and p-block metal cations have shown key transitions in luminescence in some cases, as illustrated in Figure2. Metal-centered (MCT) emissions, based on d-d or f-f transitions, ligand-centered (LCT) emitters originating from organic ligands, and numerous charge transport emissions, such as ligand-to-metal charge transfer (LMCT), metal-to-ligand charge transfer (MLCT), ligand-to-ligand charge transfer (LLCT), and metal-to-metal charge transfer (MMCT) are among the most common mechanisms used in LCoPs.(2)htn∗esrs=ρdtmi+ρdtol+ρdtca∗n1−htn.Figure 2
LCoP’s general mechanism of detection.Based on their properties ones/rs, the nanoparticles will either be in oil or water. In the organic phase, hydrophobic nanoparticles are found, while hydrophilic nanoparticles htn are found in the liquid phase, identified using equation (2). It is possible to synthesize CPs with customizable luminescence by carefully selecting metallic ions ρ/dtmi, organic likers ρ/dtol , and cleaning agentsρ/dtca. As shown in equation (1), the presence of chelates, which are coordinated to metal complexes or clusters n/1−htn, causes emission lines to appear in CP materials through htn∗es/rs.CP syntheses, luminescence detection, and common luminescence sensing pathways are shown in Figure2. Energy transfer occurs between donor and acceptor molecular entity without the use of radiation. The fluorescence intensity and exciton lifetime of the donor decreased due to LCoP. In contrast, the acceptor’s excitation state lifetime and emission frequency increased due to reduction and recombination. This method can study Coulombic interactions between molecules because it is distance-dependent. Electron transfer is a process in which excitons from donor particles are transferred to acceptor molecules via a nonradiative pathway, hydrating the luminescence of the donor particles. Thus, this mechanism can be used in situations where the donor and acceptor are in close proximity. It is possible to transfer electrons in a single or two-step process.(3)nf=∑∑m∗mi∗ol∗ci,dcρdt∗dnpi−lri,pr−npi−lri.To better understand the movement of nanofluidsnf in coordination found by Brownian, we used Brownian diffusion, as shown in equation (3), to reduce human hazards to environments and humans, compared with other methods as follows. The nanoparticle dispersion coefficient np is the density of nanoparticles dnp in interval I; the net loss ratelr is the intensity of nanoparticles in an interval npi−lri and through in phase dcρ/dt. The pores pr absorb nanoparticles as they move through m∗mi∗ol∗ci for hazard reduction. The massive loss rate of nanomaterials after modification must therefore be taken into account using the summation process dcρ/dt∗dnpi−lri.(4)dcρdt=rd∗mi∗1−gmmax−gm+es,limax−gm∗ρdtli+lt,caρdt1−ht∗gmmax−gm−er.From equations (2) and (4), radiation rd is needed to transfer energy from one molecule to another. During LCoP, the donor’s absorption spectrum gm and exciton lifetime are maximized and given as gm/max−gm while the acceptor’s excitation state es, longevity lt, and emission recurrence er continued to increase from equation (4). The presence of various metallic ions mi and groupings, ligand compounds li, and different configurations a formed by altering the synthetic circumstancesmax−gm∗ρ/dtli conversations between cross-linking frameworks caρ/dt1−ht∗gm/max−gm constrained rotation in structures, guest molecules, and the method in which server and guest communication led to a complicated luminescence mechanism in CPs.


## 3.2. Analysis 2: Supramolecular Networks (SMNs) in Coordination Polymer by Cyclo-Dehydrogenation

Chemically bonded polymers linked by transitory, noncovalent bonds in supramolecular polymer networks exhibit properties such as stimuli attentiveness, identity, and structure, making them an intriguing class of soft materials. The major advantages of supramolecular polymer networks are based on the versatility of coordination polymer networks and the flexibility of physical bonding with chelates.Polymer science has recently introduced a new nanomaterial that combines the flexibility of manufacturer synthetic connections with the redox potential. The versatility of physical bonding in a supramolecular network of polymers is given in Figure3, with bonding and nonbonding structures based on low and high temperatures. To construct the network chains from noncovalently associating polymeric materials or to tie covalently joined and yet noncovalently associated polymer chains together, these supramolecular bonds such as hydrogen coordination polymers, p–p polymers, or metal chelates are used.(5)OL,mi=htncnn+1ps∗∑i=0nhtncnn∗ra11ra12⋯ra1nra12ra22⋯ra2n⋮⋮⋯⋮ran1ran2⋯rann.Figure 3
Diagrammatic representation of SMN.It is possible to connect the organicO ligand to the metal ions L,mi and other cluster nodes cnn+1 in the extended network htn from equation (1) in various ways from equation (5). Perpetual porous structures ps are referred to as metal-organic formations ∑i=0nhtncnn or highly permeable organic polymers by n+1, respectively. Advances in redox-active ra materials in nanomaterials in matrices formra11ra12⋯ra1nra12ra22⋯ra2n⋮⋮⋯⋮ran1ran2⋯rann are essential for both fundamental and applied research because they provide new insights into an iconic attraction in the cooperation storage cn and pressure coefficient htncnn+1 that may support future apparatus development.(6)ps=−1logn∑i=0nstnm×logstnm+OL,mi.Some of these carbon-based rigorous aromatic binding sitesstnm may be detrimental to humans and the environment by ∑i=0nstnm×logstnm being useful in the preparation of rigid connections with internal surface area.(7)ESR=1loght∑i=1nsphsni,hpi+1lognhsni,hpi−sp.To create electrochemical sensorsESR that can be used in a wide range of applications, nanomaterials can be used as 1/loght. This sustainability of electrochemical sensors has become popular because of their high stability hsni, short polymers time sp, and high precision hpi as sphsni,hpi for the target molecule may be stated as 1/loglognhsni,hpi and can be calculated from the above equation by the combination sphsni,hpi+1/loglognhsni,hpi (7).As shown in Figure4, the degree of supramolecular polymers is directly proportional to the chelating constant. Supramolecular polymers based on bifunctional cyclo-dehydrogenation can improve their carbon atoms and macromolecular lifeforms by increasing the polymeric coordination concentration. Due to this combined effect, the supramolecular chain molecules become entangled at a certain concentration. A true chelation transition is observed at critical concentrations in systems that can form implicit nodes with a feature greater than two.(8)lgscm=tsexpmc∗m2c1−rm∫mAb∗∑i=1nma.Figure 4
Comparison of SMN with chelates.For example, those formed by polymeric materials modified to be dehydrogenation or basic components constituted of transition metals to remove the risk factors for human health, reduce environmental dangers and lack of cost-effectiveness as shown in Figure5. Metal-chelating polymers (MCPs) play a critical role in mass cytometric mc based on multimode chemiluminescence m2c and the ligands lg in CPs are made up of both synthetic compound’s modules scm. Each metal atom ma in the polymer is carried by the polymer mentioned in equation (8) in the form of noble metals ∑i=1nma, and the polymer’s reactionary functionality expmc∗m2c is used to attach the radioactive metal materials rm to the monoclonal antibody mAb using integration as 1−rm∫mAb. It is possible to have two or even more donor atoms form covalent bonds with two or more different parts of the ligand to create a chelating ligand, given as the combination expmc∗m2c/1−rm∫mAb. It could be said that these are multivalent ligands or ligands with multiple donor sites, depending on the context.Figure 5
Path flow process of MPC in CPs.


## 3.3. Analysis 3: The Structure-Property Connections of LCPs Based on CPs Phase Modulators with a Large Modulation Framework

Polymer fibers, waveguides, supercapacitors, contour memory, surface functionalization, storage systems, electric motors, and more use LCPs because of their superior properties and wide range of applications. CPs can combine the major area of LCP in the chelating process, and the relation between them is illustrated in Figure6.Figure 6
Representation of shearing LPC in CPs.Fast response and massive phase modulation intensity can be achieved using coordination polymer network liquid crystals; however, these cells are highly scattered in the visible spectrum. Indium-tin-oxide is being used to coat both substrates’ inside surfaces, and there is no need for an alignment layer depicted in Figure6. In this two-step procedure, 365 nm ultraviolet radiation light highlights the cell in the electrode with a voltage (v). A mismatch in the refractive index between the randomly distributed LC and the CP caused the cell to be transparent immediately following the curing process. As a final step, the upper substrate is sheared with precision, and the length between the shears is 350 m. Since the LC molecules are all aligned in the same direction, the cell became transparent.(9)prnms=∑i=−∞∞ncm−Sms+∑i=−∞∞mc∗m2c2mc/2∗ncm−Sms,(10)∑i=−∞∞mc∗m2c=1−2mc/2∗ncm−Sms∗mc1−rm∫mAb.As precursorspr for the development of nanocomposite materials nms, CPs are increasingly in demand because they serve as a starting material Sms and stabilizers ncm−Sms for the nanoparticles that are formed using multimode chemiluminescent from equation (8) mc∗m2c. When it comes to designing new materials like 2mc/2, the use of solid-state thermolysis with infinity limits through summation ∑i=−∞∞mc∗m2c to create new nanostructures is a straightforward and logical method using equation (9). Numerous studies for the analysis of the cost-effectiveness of thermal decomposition 2mc/2∗ncm−Sms of CPs have been carried out to produce different types of nanomaterials with the desired sizes, and morphological characteristics are denoted by ∑i=−∞∞mc∗m2c2mc/2∗ncm−Sms to the monoclonal antibody mAb for the analysis of the bioavailability of polymers in equation (10).The comparison of LPC switching time in two phases is shown in Table1. There are five levels of phase retardation, and 100–10% phase shift is used to describe the system performance. For various applications, the operating temperature of LC devices can vary greatly. However, many of the CP’s characteristics of LC content are strongly influenced by the temperature at which they are used. This necessitates further investigation into the LPC’s temperature effects. The rise from the first phase to the second phase takes the longest (745 s). As a result, the rise time is directly related to the voltage switching, for a reduced voltage switch is usually associated with a small phase transition.Table 1
Comparison of switching time of LPC in two phases.
Response timeSecond phase01234First phase07454003302061289531349210231038639421533593794304894408370442267Carbon-based nanostructured polymers and their diverse biochemical applications, from inorganic to organic molecules, are the subject of various research. Aside from a host of advantages, including specificity and sensitivity, MIPs have a few drawbacks, including loss of permeability, catalytic performance, and a price that limits their use in various fields, which are overcome in our proposed technique with the implementation of CPs.MIP scan recognizes molecules because of the presence of a pattern in the synthesis process that involves polymerization. During MIP self-assembly, specific binding occurs between the MIP and the template molecules through linking agents with monomers, as illustrated in Figure7. Antibodies and proteases can be imitated using these synthetic receptors by removing templates. MIPs had many advantages, including their ability to be robust, stable, and low cost to prepare, as well as their ability to recognize specific analytes by rebinding the template with a high degree of sensitivity to those analytes. Bioanalytical methods and sensors both rely on MIPs because of their excellent selectivity and selectivity for sample processing. Because of their low cost and ease of preparation, MIPs can be used as chemically synthesized receptors for recognition in electrochemical sensors.(11)ECs=NM+MP+1wl,Tr=NM+MPπ=ECsmc1−rm∫mAb.Figure 7
The process involved in MIPs.It is normalizedNM to the same value measured in a monoclinic phase MP here. For the sample’s transmittance Tr to decrease, the wavelength 1/wl must be reduced by NM+MP+1/wl. The operating temperature of LC devices is analyzed by the squared value of ECs and can vary widely depending on the application of phase difference as NM+MP/π. Many of the EO characteristics of LC material ECsmc/1−rm∫mAb, on the other hand, are highly dependent on temperature through equation (11) as Tr=NM+MP/π.Analytical chemistry’s field of nanotechnology has recently risen to prominence. Comprehension, control, and influence of matter at the nanoscale level in creating nanomaterials, devices, and structures are known as nanoscale design. It is transparent that the proposed MIPs have several advantages over traditional MIPs, including their ability to bind quickly and effectively to specific analytes, their ability to be magnetically attracted, and their shorter pretreatment time. Electrochemical sensing uses magnetic nanoparticles because of their separation and preconcentration characteristics, poor bioavailability, ease of preparation, and low cost for support fundamental decorated nanostructured polymers. MIPS-based electrochemical sensors employ nanomaterials in two primary ways. As shown in Figure8, they can be used as core materials in the synthesis of MIPs, or electrode surface modifiers, to enhance and enlarge the electrochemical notification due to their high reflectivity and large surface area. Nanomaterials combined with MIPs for electrochemical sensing are the focus of this review.(12)MP=ecihti−1psECsht2psi−1∗pSi−2.Figure 8
Schematic representation of template in MIPs.By now, many approaches to MOF synthesis have been developed, which are usually conventionally divided into two big groups: conventional synthesis and alternative synthesis methods. These are compared using equation (12) based on the overall performance of polymers. Traditional electric combustion eci without parallel processingECs is referred to as conventional synthesis, a term used to describe reactions that do not require heating ∑nhti−1ps. When a reaction contains strong water 2psi−1 and a ligand mixture ∗pSi−2, the solution is added to dissolve the salt and ligand mixture by ECsht2psi−1∗pSi−2, which is the most common method for making MIPs.Although many others have been reported, the most widely used methods for synthesizing MIPs are plentiful and outer layer imprinting. When it comes to imprinting polymer composites, the most common method relies on the principle of completely imprinting the template molecule into the polymer matrices and then removing it completely after polymerization.From the above implementation, our proposed method CPM-CU-MA has a result enhanced by overcoming all the issues in the other traditional methods, C-CPs, CoL-2CB, POMCPs, NO-CDT, and i-o-CPs, to optimize the result with improved parameters risk factors for human health, hazards reduction in the environment, lack of cost-effectiveness, and environmental sustainability.


## 4. Results and Discussion

As a means of enhancing, changing, or bestowing CPs with specific functions, postsynthetic reconfiguration can be an important option. LCoP modification can add new properties to CPs by modifying the functional groups, which can be classified as either organic or inorganic metal. Here, the comparison of the implemented result of CPM-CU-MA is made with other existing approaches using a dataset from the link [26] based on the parameters which are mentioned in Table 2.Table 2
Input parameters.
FactorsMetricsData provider250Frequency maximum18.276 (MHz)High surface areaPorous CPsCapacity250 MBSimulation timeT = 1,150,970 nsBandwidth512 mbps


### 4.1. Risk Factors in Human Health Analysis

Polymers are less toxic to humans than the subunits they contain, although they are still harmful to the environment. Polymeric materials and their decomposition products can discharge hazardous dust and fumes when cut, warmed, or otherwise manipulated using equation (1). CPs σCPe, which contain vinyl acetate, may have negative effects on the cardiovascular system, peripheral nerves, and liver. In addition to their role in everyday activities like food storage, public transit, communication, medicine, nutrition, and recording history, polymers—natural and synthetic—play a significant role in enhancing human well-being and enhancing the quality of everyday life (Figure 9). The nanoparticles are formed instantly because of the widespread introduction htn∗es/rs of the suitable solvent into the aqueous medium, which causes the water molecules to be avoided. A nanosphere-sized polymer induces the solution as it diffuses out of the nanoparticles.Figure 9
Risk factor analysis of CPs.


### 4.2. Hazards Reduction in the Environment

Based on Table3, the skin, lungs, and digestive system are the entry points for nanoparticles into the body. Free radicals, which can damage cells, may be generated as a result. There is concern that nanoparticles will cross barriers once they are in the bloodstream. Polymers must be made less flammable and their harmful thermal degradation products controlled using equation (3). Traditional flame retardants have proven to be effective, yet they have been shown to cause significant harm to health and the environment. It is possible to significantly improve the flame retardant properties of multifunctional polymers and composites by chemically or physically fusing carbon nanoparticles with other substances or samples containing phosphorus and nitrogen. Polymers can indeed improve the thermal and mechanical properties and result in multifunctionality such as electrical and thermal conductivity without compromising the mechanical characteristics of the polymers.Table 3
Hazards reduction comparison.
Number of datasetsC-CPsCoL-2CBPOMCPsNO-CDTi-o-CPsCPM-CU-MA1081.380.778.969.150.430.72079.677.971.067.455.630.13080.276.774.363.757.832.64074.474.379.559.959.029.25076.672.270.955.141.324.46077.969.569.153.548.625.87068.966.167.358.743.921.78064.063.063.552.045.219.19062.259.359.050.448.515.410060.157.255.956.145.712.9


### 4.3. Lack of Cost-Effectiveness Analysis

Researchers can estimate the long-term financial and health-related benefits and costs of multiple interventions by combining data from different sources, such as a patient’s natural history and clinical effectiveness, the health-related standard of living, and resource consumption. As shown in Figure10, researchers can compare two or more potential alternative systems in the context of their health and financial repercussions. The values are represented as an additional cost ratio of differences in expense between two invasive procedures compared to their respective variations in the health and economic consequences of each.Figure 10
Cost-effectiveness analysis.


### 4.4. Bioavailability of Polymers

Different novel delivery systems, such as lipid nanoparticles, macropinosomes, nanoemulsions, and lipid-based mechanisms, can improve bioavailability by accelerating the amount of release and the capacity to cross liposome biomembranes, such as those found in the body, as compared in Table4. There are a number of ways in which drugs can be administered, and this represents the percentage of the total intake that is absorbed into the bloodstream, representing the bioavailability of CPs from equation (10). The phrase oral bioavailability refers to the ability of a drug or other substance to be absorbed and utilized by the body when taken orally.Table 4
Comparison of availability of polymers.
Number of datasetsC-CPsCoL-2CBPOMCPsNO-CDTi-o-CPsCPM-CU-MA1044.247.557.665.359.371.22054.369.467.864.867.876.53054.579.470.578.265.288.94072.672.573.773.378.589.75044.753.976.575.779.385.16042.854.858.468.873.183.97049.445.757.357.670.279.28059.356.760.272.275.487.39067.276.677.184.786.792.310063.175.789.287.989.895.6


### 4.5. Environmental Sustainability

As an environmentally, health, and economic impact-neutral plastic, a sustainable polymer meets consumer demands without compromising our natural resources. This research activity has intensified environmental sustainability due to the volume of overspending it generates. Environmental issues are increasingly being addressed using biopolymers using equation (7). Both the processability and the end-use application are still inferior to their competitors. When it comes to increasing the biopolymer’s flexibility and impact resistance, mixing is currently a very cost-effective strategy as shown in Figure 11. Furthermore, conventional polymers are derived from fossil fuels. They have a long half-life in the environment, raising concerns about environmental sustainability and resource depletion.Figure 11
Environmental sustainability comparison.


### 4.6. Overall Performance Comparison of CPM-CU-MA

A wide range of nanomaterials that can be formed during thermal transformations of CP is the main component of LCoP. Constructions and coordination polymers with a wide array of synthetic methods, expandability, and appropriate premium ratios provide a methodological platform to build new promising materials, including metal nanoparticles, based on CP are compared and shown in Table5. Biopolymers made from renewable resources are a sustainable alternative to petroleum-derived polymers, and they can help in reducing the carbon footprint of a product, achieved using equation (12). All the existing approaches are compared with our proposed method CPM-CU-MA and achieve enhanced output.Table 5
Overall performance of CPM-CU-MA.
Number of datasetsC-CPsCoL-2CBPOMCPsNO-CDTCPM-CU-MA1053.763.775.785.491.72054.865.876.885.592.83055.767.777.786.792.74056.768.778.787.993.75057.969.979.988.393.96058.870.880.888.194.87060.671.681.689.394.68061.872.882.890.995.89062.573.083.990.595.110063.074.684.990.596.3From the tables and figures, our proposed method CPM-CU-MA is compared with other conventional methods, C-CPs, CoL-2CB, POMCPs, NO-CDT, and i-o-CPs to analyze the enhancement of parameters like risk factors for human health, hazards reduction in the environment, lack of cost-effectiveness, environmental sustainability, and overall performance of 95.3%.


## 4.1. Risk Factors in Human Health Analysis

Polymers are less toxic to humans than the subunits they contain, although they are still harmful to the environment. Polymeric materials and their decomposition products can discharge hazardous dust and fumes when cut, warmed, or otherwise manipulated using equation (1). CPs σCPe, which contain vinyl acetate, may have negative effects on the cardiovascular system, peripheral nerves, and liver. In addition to their role in everyday activities like food storage, public transit, communication, medicine, nutrition, and recording history, polymers—natural and synthetic—play a significant role in enhancing human well-being and enhancing the quality of everyday life (Figure 9). The nanoparticles are formed instantly because of the widespread introduction htn∗es/rs of the suitable solvent into the aqueous medium, which causes the water molecules to be avoided. A nanosphere-sized polymer induces the solution as it diffuses out of the nanoparticles.Figure 9
Risk factor analysis of CPs.


## 4.2. Hazards Reduction in the Environment

Based on Table3, the skin, lungs, and digestive system are the entry points for nanoparticles into the body. Free radicals, which can damage cells, may be generated as a result. There is concern that nanoparticles will cross barriers once they are in the bloodstream. Polymers must be made less flammable and their harmful thermal degradation products controlled using equation (3). Traditional flame retardants have proven to be effective, yet they have been shown to cause significant harm to health and the environment. It is possible to significantly improve the flame retardant properties of multifunctional polymers and composites by chemically or physically fusing carbon nanoparticles with other substances or samples containing phosphorus and nitrogen. Polymers can indeed improve the thermal and mechanical properties and result in multifunctionality such as electrical and thermal conductivity without compromising the mechanical characteristics of the polymers.Table 3
Hazards reduction comparison.
Number of datasetsC-CPsCoL-2CBPOMCPsNO-CDTi-o-CPsCPM-CU-MA1081.380.778.969.150.430.72079.677.971.067.455.630.13080.276.774.363.757.832.64074.474.379.559.959.029.25076.672.270.955.141.324.46077.969.569.153.548.625.87068.966.167.358.743.921.78064.063.063.552.045.219.19062.259.359.050.448.515.410060.157.255.956.145.712.9


## 4.3. Lack of Cost-Effectiveness Analysis

Researchers can estimate the long-term financial and health-related benefits and costs of multiple interventions by combining data from different sources, such as a patient’s natural history and clinical effectiveness, the health-related standard of living, and resource consumption. As shown in Figure10, researchers can compare two or more potential alternative systems in the context of their health and financial repercussions. The values are represented as an additional cost ratio of differences in expense between two invasive procedures compared to their respective variations in the health and economic consequences of each.Figure 10
Cost-effectiveness analysis.


## 4.4. Bioavailability of Polymers

Different novel delivery systems, such as lipid nanoparticles, macropinosomes, nanoemulsions, and lipid-based mechanisms, can improve bioavailability by accelerating the amount of release and the capacity to cross liposome biomembranes, such as those found in the body, as compared in Table4. There are a number of ways in which drugs can be administered, and this represents the percentage of the total intake that is absorbed into the bloodstream, representing the bioavailability of CPs from equation (10). The phrase oral bioavailability refers to the ability of a drug or other substance to be absorbed and utilized by the body when taken orally.Table 4
Comparison of availability of polymers.
Number of datasetsC-CPsCoL-2CBPOMCPsNO-CDTi-o-CPsCPM-CU-MA1044.247.557.665.359.371.22054.369.467.864.867.876.53054.579.470.578.265.288.94072.672.573.773.378.589.75044.753.976.575.779.385.16042.854.858.468.873.183.97049.445.757.357.670.279.28059.356.760.272.275.487.39067.276.677.184.786.792.310063.175.789.287.989.895.6


## 4.5. Environmental Sustainability

As an environmentally, health, and economic impact-neutral plastic, a sustainable polymer meets consumer demands without compromising our natural resources. This research activity has intensified environmental sustainability due to the volume of overspending it generates. Environmental issues are increasingly being addressed using biopolymers using equation (7). Both the processability and the end-use application are still inferior to their competitors. When it comes to increasing the biopolymer’s flexibility and impact resistance, mixing is currently a very cost-effective strategy as shown in Figure 11. Furthermore, conventional polymers are derived from fossil fuels. They have a long half-life in the environment, raising concerns about environmental sustainability and resource depletion.Figure 11
Environmental sustainability comparison.


## 4.6. Overall Performance Comparison of CPM-CU-MA

A wide range of nanomaterials that can be formed during thermal transformations of CP is the main component of LCoP. Constructions and coordination polymers with a wide array of synthetic methods, expandability, and appropriate premium ratios provide a methodological platform to build new promising materials, including metal nanoparticles, based on CP are compared and shown in Table5. Biopolymers made from renewable resources are a sustainable alternative to petroleum-derived polymers, and they can help in reducing the carbon footprint of a product, achieved using equation (12). All the existing approaches are compared with our proposed method CPM-CU-MA and achieve enhanced output.Table 5
Overall performance of CPM-CU-MA.
Number of datasetsC-CPsCoL-2CBPOMCPsNO-CDTCPM-CU-MA1053.763.775.785.491.72054.865.876.885.592.83055.767.777.786.792.74056.768.778.787.993.75057.969.979.988.393.96058.870.880.888.194.87060.671.681.689.394.68061.872.882.890.995.89062.573.083.990.595.110063.074.684.990.596.3From the tables and figures, our proposed method CPM-CU-MA is compared with other conventional methods, C-CPs, CoL-2CB, POMCPs, NO-CDT, and i-o-CPs to analyze the enhancement of parameters like risk factors for human health, hazards reduction in the environment, lack of cost-effectiveness, environmental sustainability, and overall performance of 95.3%.


## 5. Conclusion

Recent years have seen an increase in the implementation of environmental CP materials. An encouraging development is the appearance of novel compounds that combine bio-based metal ligands with abundant elements. MIPs and LCoPs series show that completely safe and sustainable CPs can be made. There is little concern for the long-term sustainability of new CP materials. However, many of these materials are intended for environmental, energy, and other sustainable applications and are implemented in our proposed method CPM-CU-MA. Greater focus on CPs built with sustainable materials and green synthetic processes has enormous potential and a powerful social imperative. CPs must therefore demonstrate that they can at least equal or, better yet, outcompete current alternatives. This is a significant obstacle. Thousands of CPs have been found, and many of them have still proven to be interesting as a source of curiosity differently. The enhancement of parameters like risk factors for human health, hazards reduction in the environment, lack of cost-effectiveness, environmental sustainability, and overall performance of 95.3% is implemented. CPs’ formability and responsiveness to luminaires, such as solar energy, could be useful in light-based applications and are considered a future scope of this study.



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*Source: 3937375-2022-08-10.xml*