# Experimental Investigation of Mechanical Properties of PVC Polymer under Different Heating and Cooling Conditions

Authors: Sarkawt Rostam; Alan Kareem Ali; Firdaws Haidar AbdalMuhammad
Journal: Journal of Engineering
 (2016)

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## Abstract

Due to a widely increasing usage of polymers in various industrial applications, there should be a continuous need in doing research investigations for better understanding of their properties. These applications require the usage of the polymer in different working environments subjecting the material to various temperature ranges. In this paper, an experimental investigation of mechanical properties of polyvinyl chloride (PVC) polymer under heating and cooling conditions is presented. For this purpose standard samples are prepared and tested in laboratory using universal material testing apparatus. The samples are tested under different conditions including the room temperature environment, cooling in a refrigerator, and heating at different heating temperatures. It is observed that the strength of the tested samples decreases with the increasing of heating temperature and accordingly the material becomes softer. Meanwhile the cooling environments give a clear increasing to the strength of the material.


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## Body

## 1. Introduction

Among the plastic materials, polyvinyl chloride (PVC) is the one of the most used and produced [1]. For better understanding of the PVC properties and for the proper utilization of the working environment, a considerable number of works can be seen in this field. The range of these attempts covers different aspects of investigations on PVC from experimental investigations [2–7] to modelling and simulation approaches [8].In spite of poor mechanical properties and processing of PVC, a wide range of products are manufactured by utilization of PVC. In this aspect efforts have been made to improve its property [9]. Different techniques were used by Nowicki et al. [10] to determine the mechanical properties of polymers. The study included the effect of ultraviolet irradiation on the mechanical properties. Deshmukh and Joshi [11] observe an improvement of mechanical properties of PVC as a function of graphene oxide loading. Both tensile strength and Young’s modulus were increased as a result of this loading. Mechanical properties of PVC/multilayer graphene were investigated by Wang et al. [12]. The investigation aimed to improve the tensile modulus of PVC.The effects of both heat treatment and physical ageing on PVC’s mechanical properties were examined by Yarahmadi et al. [13]. The temperature below and above the glass transition range was used and the results showed a decrease in elongation at the break point. Bishay et al. [14] investigate the mechanical, electrical, and thermal properties of PVC filled with aluminium powder at temperature range from 30°C to 98°C. Merah et al. [15] address the effect of both temperature and weld line on chlorinated PVC. The effects of temperature range from −10°C to 70°C were taken. It is observed that the brittle fracture happened below room temperature while the ductile fracture happened above 23°C. In a study conducted by Colloca et al. [16], three types of load, namely, tensile, compression, and impact, have been applied to closed-cell PVC foams. It showed that there was a strong relationship between the mechanical properties of elastic modulus and strength with PVC foams’ density. Sarfraz et al. [17] used controlled uniaxial stretching to improve the tensile properties of PVC-montmorillonite nanocomposites at a temperature of 80°C. The improvement is shown by determining stress-strain curve and X-ray diffraction for both unstretched and stretched films. Accordingly the improvement imparted an increase in Young’s modulus and tensile strength of the films.As the polymers are now a good alternative to metals in today’s manufacturing world, the above efforts and the current work present in this paper aim to give a clear understanding of the ability of PVC to work safely within the designed loads in the applications where PVC is used.In this paper, experimental investigation of mechanical properties of PVC samples under different heating and cooling conditions is presented to determine the load and elongation limits and the strength of the tested samples. The remainder of the paper is organized as follows. The experimental work is detailed in Section2. The section includes two parts. The first part presents the materials used in the experiments and their preparation to standard samples for testing while the second part explains the experimental procedure. Results and discussions are presented in Section 3 followed by conclusion and future works in Section 4.


## 2. Experimental Work

### 2.1. Materials

Commercial round bars of PVC were provided with dimensions of 15 mm diameter and 60 mm length. The round PVC samples are prepared according to DIN 50125 standards. The samples were machined to M10 threaded heads on both sides with a measuring length of 30 mm and a diameter of 6 mm. The PVC samples, shown in Figure1, were machined to the standard dimensions by lathe machine. Eleven samples were prepared for testing.Figure 1
PVC samples.


### 2.2. Experimental Procedure

The standard PVC samples are divided into three groups for the next step of experimentation. The first group of the samples remain as it is without any heating or cooling. The second group were heated for a period of time to approximately 90°С in boiling water. The third group of the samples were cooled in a refrigerator to −18°С.In this work, universal material testing apparatus, Figure2, was used to demonstrate the basic principles of tensile strength testing. The maximum test force on this apparatus is 20 kN.Figure 2
Universal material testing apparatus.The apparatus is provided with PC-aided measurement data acquisition system to record and evaluate the measuring data. The load is applied gradually to the clamped specimen until rapture as shown in Figure3.Figure 3
Ruptured specimen.


## 2.1. Materials

Commercial round bars of PVC were provided with dimensions of 15 mm diameter and 60 mm length. The round PVC samples are prepared according to DIN 50125 standards. The samples were machined to M10 threaded heads on both sides with a measuring length of 30 mm and a diameter of 6 mm. The PVC samples, shown in Figure1, were machined to the standard dimensions by lathe machine. Eleven samples were prepared for testing.Figure 1
PVC samples.


## 2.2. Experimental Procedure

The standard PVC samples are divided into three groups for the next step of experimentation. The first group of the samples remain as it is without any heating or cooling. The second group were heated for a period of time to approximately 90°С in boiling water. The third group of the samples were cooled in a refrigerator to −18°С.In this work, universal material testing apparatus, Figure2, was used to demonstrate the basic principles of tensile strength testing. The maximum test force on this apparatus is 20 kN.Figure 2
Universal material testing apparatus.The apparatus is provided with PC-aided measurement data acquisition system to record and evaluate the measuring data. The load is applied gradually to the clamped specimen until rapture as shown in Figure3.Figure 3
Ruptured specimen.


## 3. Results and Discussion

The aim of this research work is to monitor and find the tensile strength of PVC bars under a load at various working environments as well as the load-elongation limits for each condition. Table1 shows the range of the applied load during experiments for different working environments.Table 1
Range of the applied loads.
Load range (kN)
Working environment
1.8–1.88
Room temperature
1.92–2.07
Cooled samples (to −18°С)
0.6–1.5
Heated samples (to approximately 90°С)Figure4 shows the relationship between force and elongation for PVC specimen tested without heating or cooling conditions. It can be seen from the figure that the recorded maximum applied load was 1.8 kN and the sample has been ruptured (failure of the sample) at 1.3 kN with 11 mm elongation.Figure 4
Force-elongation diagram.The tensile strength of the tested PVC samples can be calculated from the following formula:(1)Tensile  strength=Maximum  test  forceCross-section  area  of  the  sample.For the sample under investigation the tensile strength is equal to 63.67 N/mm2 as shown in Figure 5. The figure also shows the stress at the failure point which is recorded as 46.33 N/mm2.Figure 5
Stress-strain diagram.In Figure6 the force-elongation diagram is shown, where the PVC specimen is heated to approximately 90°С. The figure shows the diagrams for two different temperatures 64°С and 90°С, respectively. For the sample heated to 64°С, the maximum testing force and failure force are 1.5 kN and 1.32 kN, respectively, corresponding to 18.39 mm elongation at fracture point. Increasing the heating temperature, for instance, to 90°C, of the PVC samples causes a decreasing of the amount of the testing forces at both the maximum point and the failure point as shown in the figure.Figure 6
Force-elongation diagrams at different heating temperatures.Corresponding to the results above, Figure7 shows the stress-strain diagram for PVC samples at different heating temperatures.Figure 7
Stress-strain diagram for heated samples.Interesting remarks regarding the force and elongation can be seen in Figure8. The figure shows that the maximum testing force has been recorded for the cooled sample while the least force has been recorded for the heated sample to 90°С.Figure 8
Force-elongation diagrams at different working environments.From the series experiments conducted on the prepared PVC samples tested at different working environments, Table2 has been drawn. It can be concluded from the table that the cooled sample has the maximum testing force (2.1 kN) while the minimum failure force (0.6 kN) has been recorded for the heated sample to 90°С.Table 2
Force and elongation data for different working environments.
Working environment
Max. test force, kN
Elongation, mm
Failure force, kN
Elongation, mm
Free condition
1.8
5.81
1.3
11
Heated to 64°С
1.5
10.57
1.32
18.39
Heated to 90°С
0.58
6.77
0.6
21
Cooled samples
2.1
5.85
1.69
8.8To get a clear view of the strength for the tested samples, the stress-strain diagram is drawn as shown in Figure9. The exact numerical values of the tensile strength for each tested specimen are given in Table 3. It can be noted from the table that the maximum strength is for the cooled specimen and the minimum strength is for the heated sample to 90°С.Table 3
Tensile strength data for different working environment.
Working environment
Strength, N/mm2
Corresponding strain (%)
Cooled sample
74.27
19.5
Free condition
63.67
18.3
Heated to 64°С
53.05
35.9
Heated to 90°С
20.51
20.5Figure 9
Stress-strain diagrams at different working environment.


## 4. Conclusions

In this research, an experimental investigation for the effect of various heating and cooling environments on the mechanical behavior of PVC polymers was presented. For this purpose, three groups of standard PVC samples were prepared using lathe machine and tested using universal material tester. The apparatus was used to apply load until the fracture of the specimen. Different load ranges have been used depending on the working environment during the experiments. The samples were heated and cooled to different conditions as follows:(i)
Heating temperature from 64°С to 90°С.(ii)
Cooling temperature to −18°С.From the results, it can be concluded that(i)
the heating conditions for PVC samples make both the force and the strength smaller than the normal temperature condition;(ii)
the heating conditions make the samples softer;(iii)
the cooled condition showed the need of larger load to rupture the specimen; that is to say, the PVC samples became brittle behavior polymer.The current work can be expanded in several directions. One direction is to expand the experiments by conducting other tests such as fatigue and impact tests. Another direction is to demonstrate the scanning electron microscope (SEM) photographs for the tested specimens and the thermal transition analysis for different working environments.



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