# Size Effect on the Structural and Magnetic Properties of Nanosized PerovskiteLaFeO3 Prepared by Different Methods

Authors: Nguyen Thi Thuy; Dang Le Minh
Journal: Advances in Materials Science and Engineering
 (2012)

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## Abstract

Nanosized LaFeO3 material was prepared by 3 methods: high energy milling, citrate gel, and coprecipitation. The X-ray diffraction (XRD), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA) show that the orthorhombic LaFeO3 phase was well formed at a low sintering temperature of 500°C in the citrate-gel and co-precipitation methods. Scanning electron microscope (SEM) and transmission electron microscope (TEM) observations indicate that the particle size of the LaFeO3 powder varies from 10 nm to 50 nm depending on the preparation method. The magnetic properties through magnetization versus temperature M(T) and magnetization verses magnetic field M(H) characteristics show that the nano-LaFeO3 exhibits a weak ferromagnetic behavior in the room temperature, and the M(H) curves are well fitted by Langevin functions.


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## Body

## 1. Introduction

The perovskite-type oxides (general, formula ABO3, A, and B are the metallic ions) have been attracting much attention for more than two decades due to their potential commercial applications as catalysts for various reactions. Moreover, the modified perovskite compounds such as La1−xSrxMnO3, La1−xPrxMnO3, La0.7Sr0.3Mn1−xNixO3, Ca1−xNdxMnO3, CaMn1−xFexO3, and so forth [1–7] have received much attention because of their interesting physical effects: colossal magnetoresistance (CMR), giant magnetocaloric effect (GMCE), and high thermoelectric performance (TEP) at high temperature. In recent years, many laboratories in the world have studied LaFeO3 as a thermoelectric material with high Seebeck coefficient and high power factor and it can be used as catalyst for methane combustion, the thin film gas sensors, and so forth. The LaFeO3 thin film can be used as sensitive O2 gas sensors [8] and nano-sized LaFeO3 powder can be used as catalyst for the autoreforming of sulfur-containing fuels or for partial oxidation of methane (POM) to (H2/CO) [9–12]. For preparation of those nano-materials, various technological methods are used such as co-precipitation, sol-gel, hydrothermal reactions, mechanical alloying, pulsed wire discharge, shock wave, spray drying, and so forth.In the present study, the nano-sized LaFeO3 has been prepared by 3 methods: high energy milling, citrate gel, and co-precipitation. Beside determination of the particle size, crystalline, and microstructures, the magnetic properties were also investigated. The particle size of the samples prepared by different methods influenced strongly on the structural and magnetic properties of the material.


## 2. Experimental Procedure

The nano-LaFeO3 was prepared using sol-gel, co-precipitation, and high-energy milling methods. These methods were performed as the following.In the sol-gel method, the analytical grade La(NO)3·6H2O, Fe(NO3)3·9H2O, and citric acid (CA) C6H8O7·H2O were used as starting materials. The same mole equivalent amounts of metal nitrates were weighed according to the nominal composition LaFeO3 and then dissolved in distilled water. The citric acid with the ratios (CA)/Σ(Metal ions) = (1.2–1.5) was then proportionally added to the metal nitrates solution. In the above ratio, (CA) and Σ(Metal ions) are concentration of (CA) and sum of concentration of metallic ions, respectively. The solution was concentrated by evaporation at 60–70°C with continuous stirring and pH controlled by NH3 solution. The nanocrystals of perovskite LaFeO3 were obtained by decomposition of the dried gel complex at selected temperatures: 300, 500, and 700°C in air.In the co-precipitation method, La(NO3)·6H2O, Fe(NO3)3·4H2O were raw materials. NH3 solution was added to the metal nitrates solution. The La(OH)3 and Fe(OH)3 were co-precipitated as hydroxide gel [13] at 80°C under continuous stirring and pH≈10 to ensure the completely precipitation. Then, the hydroxide gel was filtered and dried. The dried powders were calcined at different temperatures ranging from 100 to 700°C for 3 h in air.In the high-energy milling method, firstly, the bulk sample was prepared by ceramic method and then it was milled into the nanopowder using the high-energy milling equipment SPEX 8000D for 5 h.Various techniques such as thermal analysis (DSC and TGA with SDT-2960-TA Instrument-USA.), XRD (Diffractometer D5005-Bruker), SEM (S-4800-Hitachi-Japan), and TEM (JEM1011-Jeol-Japan) were employed to characterize the nano-sized LaFeO3 powder. The magnetic properties of the samples were examined by a vibrating sample magnetometer (VSM) DDS-880 (USA).


## 3. Results and Discussion

Figure1 shows the DSC and TGA curves for the sample prepared by sol-gel method. It can be seen from Figure 1 that TGA curve exhibits a weight loss of about 65% corresponding to an exothermic peak in DSC curve at 240.55°C, those are the removal of the water from crystallization and decomposition process of the organic substances. Heating at higher temperature led to a small weight loss (~8.3%) at 250°C and finishing at 500°C associated with a peak at 457.01°C in the DSC curve. The weight loss (~65%) is due to the chemical changes as shown in the following equation [14]:
(1)La(NO3)3·6H2O+Fe(NO3)·9H2O+C6H8O7·H2O→LaFeO3+6CO2+2N2+2NO2+20H2O
During the evaporation of the solvent, a reddish-brown gas corresponding to NO2 comes out of the solution. The above chemical formula only shows the result of chemical reaction but the nature of the sol-gel method is not pointed out. In the used sol-gel method, before creating the solid solution of LaFeO3, the La and Fe ions have been presented in a gel complex. The Fourier transform infrared (FTIR) spectra of the citric acid, gel, and LaFeO3 have been measured for demonstration of the process mentioned above [15].Figure 1
The DSC-TGA curves of the gel complex.The FTIR spectra of the citric acid, gel complex, and LaFeO3 nanoparticles are shown in Figure 2. In Figure 2(b) (black line), two vibrational bands can be observed at 1572 cm−1 and 1385 cm−1 that are assigned to the stretching of C–O bonds. The bands occurred at 551 cm−1 and 646 cm−1 are corresponding to Fe–O and La–O bonds, respectively, and the wide band around 3137 cm−1 in Figure 2(b) (black-line) and 3364 cm−1  in Figure 2(a) correspond to the hydroxyl group. From the above spectroscopic observations it was suggested that the as-prepared gel consists of an intermediate/complex of citric acid, water, and metal ions. On the basis of the above FTIR results, the expected molecular structure of the complex of metal ions and citric acid is shown in Figure 3.(a) FTIR spectra of citric acid; (b) FTIR spectra of gel complex (black line) and LaFeO3 (red line).
(a)
(b)Molecular structure for the citric acid (a) and for a possible complex of metal ions and citric acid (b) in gel precursor of LaFeO3 nanoparticles.
(a)
(b)Figure4 shows the XRD patterns of the nano-sized LaFeO3 powders obtained after heating at different temperatures of 300°C (line 1), 500°C (line 2), and 700°C (line 3) for 3 hours. At 700°C the XRD pattern shows that the major phase is LaFeO3 with orthorhombic crystalline structure. The lattice parameters are a=5.546 Å; b=5.5497 Å; c=7.8573 Å. The gel complex which was heated at 500°C for 3 hours has not yet changed to the LaFeO3 phase, as shown in Figure 4 (line 2) and Figure 5 (red line). It seems to be amorphous, but with further heating at 500°C for 7 hours, the LaFeO3 phase was completely formed (Figure 5—black line). Figure 6 shows the XRD pattern of LaFeO3 prepared by the co-precipitation method. The complex precipitate was heated at different temperatures for 3 hours. The phase states are similar to the case of the sol-gel method (Figure 5). The XRD patterns of hydroxide gel show that the LaFeO3 phase does not appear at 300°C or 500°C; however, at 700°C a major phase as LaFeO3 is formed (Figure 6).Figure 4
The powder X-ray diffraction patterns ofgel complex heated at 300°C (line 1); 500°C (line 2); 700°C (line 3) for 3 hours.Figure 5
The powder X-ray diffraction patterns ofgel complex heated at 500°C for 3 hours (red line) and for 10 hours (black line).Figure 6
The powder X-ray diffraction patterns ofhydroxide gel heated at 300°C (line 1); 500°C (line 2); 700°C (line 3) for 3 hours.The average crystalline particle size calculated from Scherrer’s formulaD=kλ/Bcosθ is about 30 nm, where D is the average size of crystalline particle, assuming that particles are spherical, k=0.9 [14], λ is the wavelength of X-ray radiation, B is full width at half maximum of the diffracted peak, and θ is angle of diffraction.The particle size and morphology of the calcined powders examined by TEM and SEM are shown in Figures7(a), 7(b), and 8, respectively. It can be estimated from these figures that the particle size is varying from about 10 to 30 nm.TEM (a) and SEM (b) micrographs of LaFeO3 prepared by sol-gel method, followed by calcining process at 700°C.
(a)
(b)Figure 8
SEM micrograph of nano-LaFeO3 prepared by high-energy milling method.The magnetic properties of the samples were examined by Vibrating Sample Magnetometer (VSM) in the field of 13.5 kOe from room temperature to 800 K. The Curie temperature determined by theM(T) curve (Figure 9) is around 730 K, which is corresponding to the peak in the DSC curve at about 457°C (Figure 1). The M(H) curve of nano-LaFeO3 prepared by sol-gel method is shown in Figure 10.Figure 9
TheM(T) curve of nano-LaFeO3 prepared by sol-gel method.Figure 10
TheM(H) curve at room temperature of nano-LaFeO3 prepared by sol-gel method.As for the sample prepared by high-energy milling the powders after milling were heated at 500°C in 3 hours to eliminate inner stress in the samples. Figure8 shows the SEM image for the LaFeO3 powder after milling and heat treatment. The average size of particle is about 50 nm. The M(H) curve of nano-sized LaFeO3 prepared by milling method is shown in Figure 11.Figure 11
TheM(H) curve at room temperature of nano-LaFeO3 prepared by high-energy milling method.It is well known that the perovskite LaFeO3 displays antiferromagnetic and insulator behavior in room temperature [16]. However, the M(T) and M(H) curves of the prepared LaFeO3 show that LaFeO3 exhibits weak ferromagnetism. It may be caused by the antiferromagnetic order with canted spins [17]. In addition, during heating at high temperature some couples of Fe3+-Fe2+ may be appeared in LaFeO3 due to the losing of oxygen. The difference between magnetic moment of Fe3+ ions (5 μB) and Fe2+ (4 μB) has contributed to magnetic behaviors of the samples and they became an electrical conducting materials as semiconductor.The parameters of hysteresis loop of the samples prepared by sol-gel and milling methods are listed in Table1.Table 1
The parameters of hysteresis loop of the samples prepared by sol-gel and milling methods.
Parameters
Sol-gel method(Particle size of 30 nm)
Milling method(Particle size of 50 nm)
M
m (emu/g) at H=13.5 kOe
1.464
0.443
M
r (emu/g)
0.078
0.063
H
c (Oe)
92.6
198.9
S
=
M
r
/
M
m
0.05
0.14The results listed in the above table show that the preparation method and particle size influence on the magnetic properties. Although after milling the samples have been annealed, it seems that the inner press could not be eliminated completely; thus the magnetizationMm of the sample prepared by milling method is less than that of the samples prepared by sol-gel method. The particle size of the powders prepared by the milling method is larger than the one obtained by the sol-gel method. The bigger particles give a higher coercivity Hc. This is in good agreement with the law (Hc~D6) of the nanomagnetic particles [18, 19]. It is noted that the nanosized, and single-domain ferromagnetic powder could be superparamagnetic with Hc=0 and Mr=0; S=(Mr/Ms)=0 [20]. If the prepared nano-sized powder has some of particles with multiple domain sizes, Hc, Mr, and S will differ from zero. The larger particle size gives higher S and the ferromagnetic behavior is more clear. That is why we suggested that the ratio S=Mr/Ms could be used as a functionally parameter for evaluating the homogeneity on dimension of nanoparticles and the limit of single domain size of the magnetic nano-sized powder materials.As mentioned above, the prepared nano-sized LaFeO3 powder is weakly ferromagnetic (Mr≠0). It is a multi-disperse system consisting of the single-domain and multiple-domain particles. The magnetization of the sample is considered as the sum of two terms:
(2)M(H)=Msp(H)+Mf(H),
where Msp(H) is the contribution from the superparamagnetic (sp) nanoparticles (single domain), Mf(H) is the contribution of ferromagnetic (f) nanoparticles (multiple domains):
(3)Mf(H)=2Msfπtan-1[H±HcHctan(πS2)],Msf: saturation magnetization of ferromagnetic phase (Msf=Mr/0.866). S: rectangular coefficence of ferromagetic hysteresis loop.The noninteraction magnetization process of the superparamagnetic monodisperse nanoparticles can be shown by the expression:(4)M(H)=M(∞)L[mHkBT],
where m is magnetic moment and L(x)=coth(x)-1/x is the Langevin function, x=mH/kBT, [21]. To take into account the effects of size dispersion that are always presented in any real system, the magnetization of superparamagnetic particles, in this case, it is better to use the expression:
(5)Msp(H)=Msp(∞)∑jf(mj)L[mjHkBT].mj is magnetic moment of the particle, f(mj) is weighted terms in Langevin functions [22].It is suggested that the particles are spherical shape, the distribution of particle sizef(D) is shown by the expression [23]:
(6)f(D)=12πσDexp(-ln(D/D¯)22σ2),
where σ is standard deviation and D¯ is the average particle size. f(mj) can be calculated from D. Figure 12 shows the Langevin function fitting result for the magnetization curve of the nano-sized LaFeO3.Figure 12
The result of the fitting of theM(H) curve of the nano-LaFeO3 prepared by sol-gel method based on the Langevin function.


## 4. Conclusion

The nano-sized LaFeO3 has been successfully prepared by different methods. The particle size of nano-LaFeO3 is varying from about 10 to 50 nm depending on the preparation method. The prepared nano-LaFeO3 exhibited a ferromagnetic behavior and the particle size influences the magnetic properties of nano-LaFeO3. The M(H) curve was well fitted by Langevin function. We have proposed that by using parameter S=Mr/Ms one could evaluate the homogeneity of the dimensions of nanoparticles and the critical size of single domain of the nano-magnetic materials.



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*Source: 380306-2012-08-29.xml*