# Short Time and Low Temperature Reaction between Metal Oxides through Microwave-Assisted Hydrothermal Method

Authors: S. M. V. Novais; P. C. R. Silva; Z. S. Macedo; L. B. Barbosa
Journal: Advances in Condensed Matter Physics
 (2016)

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## Abstract

This work demonstrates the possibility of synthesis of cadmium tungstate at low temperatures using oxide precursors. Cadmium tungstate (CdWO4) scintillator was produced via microwave-assisted hydrothermal reaction using the precursors CdO and WO3. The methodology was based on microwave radiation for heating, which is remarkably faster than the solid-state route or conventional hydrothermal procedure. CdWO4 monoclinic (wolframite) structure was successfully obtained at 120°C for synthesis times as short as 20 min. This route does not require the use of templates or surfactants and yields self-assembled nanorods with size of around 24 ± 9 nm width and 260 ± 47 nm length. The growth mechanism for the formation of CdWO4 involves microwave-induced dissociation of the reagents and solvation of Cd2+ and WO42- ions, which are free to move and start the nucleation process. The luminescence properties of the produced nanoparticles were investigated, presenting a broad emission band at around 500 nm, which is comparable to that observed for samples produced using other chemical routes. This result highlights the great potential of the proposed method as a low-cost and time saving process to fabricate luminescent oxide nanoparticles.


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## Body

## 1. Introduction

Recent advances in synthesis technologies demonstrate that the use of microwave radiation is convenient as heating method to obtain nanomaterials in a short reaction time. Further advantages of microwave-based methodology are low cost and low environmental damage [1, 2]. The fundamental requirement is that solvent and/or reagents employed have the ability to absorb microwave energy in order to convert it into heat [3]. The thermal effects provided by microwaves are consequence of the particle interactions with the electromagnetic field, involving processes of dipolar polarization and ionic conduction [3, 4]. Such unique feature cannot be achieved using conventional heating, and it provides uniform heating that improves the yield and reproducibility of the route [3, 5].Microwave-assisted hydrothermal method combines the advantages of fast heating and high-pressure reaction. Hydrothermal processes can promote the formation of crystalline products at temperatures much lower than those required in conventional synthesis [6–8]. The combination of microwave heating and hydrothermal environment typically enhances the kinetics of reactions by 1-2 orders of magnitude, saving time and energy [9–11].Tungstate materials are studied due to their potential application in different areas including catalysis, magnetic devices, humidity sensors, photonics, and scintillators [12, 13]. Conventional solid-state synthesis of CdWO4 departs from metal oxides, which are grinded and heated up to 1000°C for several hours [5, 14]. Alternatively, sol-gel, sonochemical, solvothermal, and conventional hydrothermal syntheses are reported to produce CdWO4 nanoparticles [15–22] but it is important to say that in all these works the precursors were either alcoxides or metal salts. Few reports can be found in literature about the microwave-assisted hydrothermal synthesis of CdWO4 [23–25], but they make use of metal salts and organic solvents or surfactants such as toluene and PEG-1000. To our knowledge, microwave-hydrothermal method using precursor oxides in aqueous solution was not reported up to the moment to produce nanostructured CdWO4. In the present work, this route was successfully used, satisfying the demand for simplification and improvement of the methodology. The proposed method is also advantageous since it does not require the use of surfactants or pH modifiers, consequently avoiding waste generation. In this work, the mechanism of nucleation and crystal growth, as well as the structural and optical characterization of the produced samples, is presented and discussed.


## 2. Materials and Methods

CdWO4 polycrystalline samples were produced via microwave-assisted hydrothermal method using cadmium oxide and tungsten oxide as precursors. In a typical experiment, 2 mmol of CdO (Vetec, 99.5%) and 2 mmol of WO3 (Fluka, 99.9%) were homogenized in an agate mortar and placed into a Teflon autoclave filled with 50 ml of distilled water. Then, the autoclave was sealed and placed in the microwave system (Brazilian patent 2008-PI0801233-4) with frequency of 2.45 GHz and maximum power of 800 W. Reactions were conducted at 120°C under autogenous pressure (~1.5 kgf/cm2) for 20 min and 60 min. After cooling down to room temperature, the resulting product was collected by centrifugation and dried at 60°C in air. Due to CdO losses during heating, synthesis was also performed varying the amount of this reagent to 2.2 mmol, 2.4 mmol, and 2.6 mmol, keeping the amount of 2 mmol WO3.Crystalline phases obtained were characterized by X-ray diffraction (XRD) in a Rigaku Ultima+ 2000/PC using Kα radiation from Co. The data were acquired in step-scan mode, in the 2θ range from 10° to 80° with steps of 0.02° and acquisition time of 10 s. The composition of the samples was determined from energy dispersive X-ray (EDX) spectroscopy measured with Shimadzu EDX-7000 equipment, in semiquantitative mode. Transmission electron microscopy (TEM) images were acquired with Jeol JEM-1400Plus microscope (accelerating voltage of 120 kV) to evaluate the size and morphology of the powders. Photoluminescence (PL) measurements were performed in an ISS PC1TM spectrofluorimeter that uses a 300 W Xenon lamp as excitation source, with fixed excitation wavelength at 292 nm. X-ray excited optical luminescence (XEOL) was measured while the samples were under excitation of X-rays emitted by a Co target tube operating at 40 kV/40 mA. Both PL and XEOL were collected using an Ocean Optics HR2000 spectrometer (resolution of 0.5 nm) and all measurements were performed at room temperature.


## 3. Results and Discussion

XRD patterns of polycrystalline samples prepared using metal oxides in stoichiometric proportion are presented in Figure1. One can observe that the products obtained by the proposed route are predominantly CdWO4 with monoclinic structure (PDF #00-088-0181). The temperature of 120°C is significantly lower than that used for solid-state synthesis of this scintillator [14, 27]. Furthermore, Figure 1(a) shows that CdWO4 is successfully formed for reaction times as short as 20 min, due to the efficiency of microwave radiation in promoting rapid reactions. Small amount of WO3 (PDF #00-083-0950) was detected as secondary phase, indicating that Cd losses can occur during synthesis, possibly by volatilization or by dispersion into the water as Cd(OH)2 [28, 29]. Figure 1(b) corresponds to the nominally stoichiometric sample synthesized during 60 min, indicating that no noticeable change in crystalline structure was detected for longer synthesis times. From the full width at half maximum (FWHM) of the (100) diffraction peak and using Scherrer formula [30], it was possible to estimate the crystallite size D:(1)D=K·λβ·cos⁡θB,where K is the shape coefficient (in this work, K=0.9), λ is the X-ray wavelength (0.179 nm for Co target), β is the line broadening, and θB is the Bragg angle, in radians. The average crystalline sizes were about 23 ± 1 nm and 24 ± 1 nm for the sample produced with reaction time of 20 and 60 min, respectively.Figure 1
XRD patterns of the samples prepared with reagents in stoichiometric proportion, varying the time of synthesis: (a) 20 min and (b) 60 min. Bars represent the wolframite structure of CdWO4 (some crystalline planes are indexed according to [26]) and symbols correspond to WO3.In order to compensate the Cd loss, samples were produced departing from precursors homogenized with excess CdO. Figure2 presents XRD patterns for the samples synthesized during 60 min using 10% (2.2 mmol), 20% (2.4 mmol), and 30% (2.6 mmol) of CdO excess. The results point to the presence of monoclinic CdWO4 and lower proportions of WO3 phase. The amount of WO3 was 8% for the sample prepared with reagents in stoichiometric proportion, as estimated from the XRD data using Match! software [31]. When CdO excess of 10, 20, or 30% was used, the amount of WO3 phase decreased to 7%, 6.5%, and 6%, respectively. Nevertheless, one must notice that the diffraction peaks of CdWO4 become broader with increasing the amount of cadmium precursor (see Figure 2) and such behavior can be related to modifications in the microstructure of these samples, as it will be discussed later in this paper. From the evaluation using (1), a slight decrease was found of the crystalline sizes in relation to that of samples produced without excess of CdO. The results were 21 ± 1 nm, 19 ± 1 nm, and 19 ± 1 nm when the excess amount of this precursor was 10, 20, and 30%, respectively.Figure 2
XRD patterns of the samples prepared with reagents out of stoichiometric proportion: (a) 10% excess of CdO, (b) 20% excess of CdO, and (c) 30% excess of CdO. Bars represent the wolframite structure of CdWO4 (some crystalline planes are indexed according to [26]) and symbols correspond to WO3.Further investigations about composition of these products were performed through EDX. Results are presented in Table1. Only Cd and W elements were found in the composition of the samples. Therefore, the level of impurities can be considered negligible. The percentage of O atoms could not be measured due to experimental limitations of the equipment. This means that, considering only Cd and W, CdWO4 stoichiometric samples should contain 50% of each of these elements. However, for all samples synthesized using CdO and WO3 precursors in stoichiometric proportion, a deficiency of Cd atoms was found. The composition of 60% W and 40% Cd is the same for synthesis times of 20 and 60 min, indicating a nondependence of the reaction time on stoichiometry, at least for the time intervals used in the present work. One can notice that the amount of Cd deficiency (10%) is in agreement with the XRD results, which pointed out approximately 8% of secondary phase WO3. Accordingly, for the samples prepared using CdO excess, the deviation from stoichiometry decreased to 8%, 6%, and 4% (see Table 1). These values are also consistent with those obtained from XRD and corroborate that secondary phase of WO3 formed during the hydrothermal reaction can be controlled.Table 1
EDX results for atomic composition of the samples.
Samples Amount of CdO Time of synthesis Cd W Without using excess of Cd 2 mmol 20 min 40% 60% 2 mmol 60 min 40% 60%  Using excess of Cd 2.2 mmol 60 min 42% 58% 2.4 mmol 60 min 44% 56% 2.6 mmol 60 min 46% 54%Particle morphology was investigated using TEM, and some of the images obtained are presented in Figure3. The micrographs show that CdWO4 powders prepared with reagents in stoichiometric proportion at 120°C for 20 min exhibit nanorods with widths of 24 ± 9 nm and lengths of 260 ± 47 nm, whereas, for reaction time of 60 min, particles with widths of 11 ± 3 nm and lengths of 98 ± 33 nm were observed. Therefore, Figures 3(a) and 3(b) indicate that the aspect ratio (or length-to-diameter ratio) is very similar despite increasing the time of synthesis. The nanorod formation is attributed to a preferred growth along the (100) direction at the expense of individual crystallites [32, 33], and it is an interesting result of this work, considering that no template or surface passivation was used in the production, as related in previous reports. The morphology obtained in this work is consistent with those reported for the synthesis of CdWO4 departing from metal salts combined to PEG-1000 surfactant [24], indicating that CdWO4 preferably grows into the nanorod morphology, regardless of the nature of the chemical reagents. Also, from Figures 3(a) and 3(b), it can be observed that samples prepared with reaction time of 60 min present smoother particle surface. This effect is probably due to Ostwald ripening or better crystallization of the particles hydrothermalized for longer times, although negligible influence of reaction time on the phase formation was detected from XRD data. Figures 3(c) and 3(d) correspond to samples produced with Cd excess of 20% and 30%, respectively (synthesis times of 60 min in both cases). In these micrographs, the formation of thinner particles, which tend to agglomerate into bundles, can be noticed. Respectively, their sizes were found to be of 10 ± 2 nm width and 161 ± 27 nm length or 10 ± 2 nm width and 146 ± 50 nm length, which point to higher aspect ratios in comparison to that of samples produced without excess of Cd. Such microstructure is less common but can be related to small changes in the experimental procedure that originally produced nanorods [20, 34].Figure 3
TEM images of CdWO4 nanorods produced with varied conditions: using reagents in stoichiometric proportion, soaking time of (a) 20 min and (b) 60 min, or using Cd excess of (c) 20% and (d) 30%. Some nanofiber bundles are indicated by red arrows.
(a) (b) (c) (d)About the growth mechanism of CdWO4 using oxide precursors under microwave-hydrothermal conditions, some assumptions can be made. Initially, the microwave radiation promotes a superheating of the water as well as of the CdO and WO3 particles. These reagents undergo a dissociation so that Cd2+ and WO42- are produced and solvated by H2O molecules. This means that the partial negative charges of H2O electrostatically attract Cd2+ ions whereas the positive charges attract WO42-. Then, free ions are able to move by the action of the radiation, and collisions occur. In such conditions, nucleation takes place in a very short time and thus leads to the production of particles in nanoscale regime [35, 36]. In the present case, CdWO4 crystals are crystallographic oriented and self-assembled into nanorod or nanofiber morphologies.PL and XEOL emission spectra are presented in Figures4 and 5, respectively. Upon excitation of either UV or X-ray, the samples presented a broad band emission with maximum at 500 nm, characteristic of CdWO4 and attributed to charge transfer transitions between W6+ and O2− ions within the tungstate molecular units WO6 [37, 38]. The luminescence profile was basically the same for reaction times of 60 min (presented in Figures 4 and 5) or 20 min (not presented). The total light output was obtained from the area under each curve, with the highest light output set as 100. These results are presented in the inset of Figures 4 and 5, as function of Cd/W ratio (as determined by EDX) and reaction times. For both excitation sources, it was observed that the light yield increases for longer reaction times, for all stoichiometric proportions used. This is probably due to the higher crystallinity achieved with longer hydrothermal treatments. Similar results were reported for CdWO4 samples produced by conventional hydrothermal synthesis at different conditions [39, 40]. On the other hand, works in [23, 24], about the microwave-assisted method, point to an opposite dependence of PL intensity with the reaction time, demonstrating that in these cases other factors such as particles size and the surface modification by surfactants can influence the luminescence emission.Figure 4
PL emission spectra of samples prepared with different cadmium precursor (CdO) amounts and reaction time of 60 min. The inset shows the total light output, for reaction times of 20 min and 60 min, obtained from the area under the luminescence curves, as function of Cd/W atomic ratio, as determined by EDX.Figure 5
XEOL emission spectra of samples prepared with different cadmium precursor (CdO) amounts and reaction time of 60 min. The inset shows the total light output, for reaction times of 20 min and 60 min, obtained from the area under the luminescence curves, as function of Cd/W atomic ratio, as determined by EDX.Figures4 and 5 show that the most intense emission corresponds to that of nominally stoichiometric samples, where the actual proportion of Cd/W is 40/60. This result suggests that the different morphologic features of the samples produced with or without Cd excess have a strong influence on the light output of the samples. This is probably due to the different effective areas of the particles with rod or fiber morphologies. Despite the fact that WO3 as secondary phase tends to influence negatively the recombination rate of photogenerated charge carriers [41], the role played by microstructure seems to be more crucial for the light output efficiency in this case. In future works, an in-depth study of surface area and light output should be carried on to establish a quantitative relationship between these two parameters.


## 4. Conclusions

The results presented in this work show the feasibility of using oxide precursors for synthesizing CdWO4 under microwave-assisted hydrothermal conditions. Methodology is conducted at short times and low temperature, being environmentally safe and also saving time and energy. Monoclinic structure and nanorod or bundle morphologies of CdWO4 were obtained, depending on Cd excess used in the synthesis. From the luminescence measurements, it was observed that the microstructure plays an important role in the light output of these scintillators. Samples prepared with excess of CdO precursor in relation to the stoichiometric proportion provided some reduction of the WO3 content in the final product, but they have presented lower luminescence. Nevertheless, increasing the reaction time from 20 to 60 min favored the crystallization process and such samples have an overall higher efficiency. Different methods to avoid the loss of cadmium and formation of single crystalline phase are under investigation and will be presented in future works.



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