# Optical and Structural Properties of Thermally Evaporated Zinc Oxide Thin Films on Polyethylene Terephthalate Substrates

Authors: M. G. Faraj; K. Ibrahim
Journal: International Journal of Polymer Science
 (2011)

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## Abstract

Zinc oxide thin films of different thicknesses ranging from 100 to 300 nm were prepared on polyethylene terephthalate substrates with thermal evaporation in a vacuum of approximately3×10-5 Torr. X-ray diffraction patterns confirm the proper phase formation of the material. From atomic force microscopy (AFM) images, it was found that the root mean square roughness of the film surface increased as the film thickness increased. The optical properties of ZnO on PET substrates were determined through the optical transmission method using an ultraviolet-visible spectrophotometer. The optical band gap values of ZnO thin films slightly decreased as the film thickness increased.


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## Body

## 1. Introduction

Zinc oxide (ZnO) is an important wide band gap II–VI semiconductor material and a natural n-type electrical conductor. ZnO thin films are used in various applications, such as in transparent conductive film and window materials in solar cell applications, because of its high optical transmittance in the visible light region [1]. Recently, ZnO materials have attracted much more interest for the application of optoelectronic devices, such as light-emitting diodes, laser diodes, piezoelectric transducers, transistors, bulk acoustic wave devices, acoustic-optical devices, and phosphors [2].There are different methods available to prepare zinc oxide, such as radio-frequency magnetron sputtering [3], chemical vapor deposition [4], the sol-gel method [5], atomic layer deposition [6], spray pyrolysis [7], pulsed laser deposition [8], and thermal evaporation [9]. Of the various methods, the vacuum evaporation technique is known to be suitable for the preparation of ZnO films for a wide range of applications.This movement towards flexible polymer substrates is gaining a great amount of interest [10–12] because they can provide advantages such as light weight, high shock resistance and scalable roll-to-roll preparation procedures. Polyethylene terephthalate (PET) has been selected as a substrate in this study because PET is a low-cost, high-transmission material.In this present work, the structural and optical properties of ZnO thin films with different thicknesses ranging from 100 to 300 nm and grown by the thermal evaporation technique on PET substrates were studied. The effects of thickness on the optical properties of the prepared films were also studied.


## 2. Experimental Details

In this experiment, 250μm thick PET substrates obtained from Penfibre Sdn. Bhd. (Film Division) were used. The PET substrates were first cleaned by full immersion in Decon 90 at room temperature (25°C) for 10 minutes to remove contamination. After the cleaning process, all of the substrates were rinsed with deionized water (DIW) to remove the Decon 90 residue. The samples were then dipped in isopropyl alcohol (IPA) at room temperature (25°C) and agitated with moderate ultrasonic power for 10 minutes. The samples were again dipped in DIW and then dried off with nitrogen (N2) gas after the ultrasonic cleaning.ZnO thin films varying in thicknesses between 100 and 300 nm were prepared on PET substrates by the thermal evaporation technique in a vacuum of 3 × 10−5 Torr. The evaporator system, an Edwards Auto306, utilizes a common diffusion and rotary pump to evacuate the high vacuum chamber, which was made of an enclosed bell jar. Wafers were loaded at the top of the vacuum chamber while a tungsten boat was used to hold the molten ZnO for evaporation. The source of ZnO (99.9% pure) as a powder was loaded onto a tungsten crucible in the vacuum. Prior to deposition, the ZnO and tungsten boat were cleaned with alcohol to remove any contamination and dried using nitrogen gas. The vacuum chamber was evacuated to 3 × 10−5 Torr before the source was heated. The tungsten boat was heated using 3.0 A direct current for 10 seconds to melt the ZnO. The current was increased slowly to 8.0 A until all of the ZnO evaporated. The substrate was removed after waiting for a few minutes for the chamber to cool down. Films of different thicknesses were prepared through different individual evaporation sessions. The thicknesses of ZnO thin films are found using an optical reflectometer (model: Filmetrics F20). The crystallographic structure of ZnO thin films deposited on PET substrates was determined using a high-resolution X-ray diffractometer system (model: PANalytical X’Pert PRO MRD PW3040). The compositions of the ZnO thin films were estimated with energy dispersive X-ray analysis (EDX) (model: JSM–6460 LV).The surface morphology of ZnO thin films was studied using an atomic force microscope (AFM; model: ULTRA Objective). The optical properties of ZnO thin films deposited on PET substrates were characterized using a UV spectrophotometer (model: U-2000 HITACHI).


## 3. Results and Discussion

### 3.1. Structural Characterizations

Figure1 shows the XRD spectra for the vacuum-evaporated ZnO thin films on PET substrates. This spectrum was obtained at room temperature for a ZnO thin film with a thickness of 300 nm. The main peak corresponding to the PET substrate was observed at 2θ angle 26° [13–16]; it had a very high intensity. According to Figure 1, all peaks of the ZnO thin films can be well indexed to the hexagonal wurtzite structure of ZnO (JCPDS Card no. 01-089-0510, a=0.325 nm and c=0.521 nm).Figure 1
XRD patterns of ZnO thin films on PET substrates.Figure2 shows the EDX results for ZnO thin films deposited on PET substrates. EDX analysis confirms the composition of Zn and O in the ZnO film. The presence of the carbon peak in the spectrum is due to the PET substrate.Figure 2
EDX results for ZnO thin films deposited on PET substrates.AFM images of the surface morphologies of ZnO thin films deposited on PET substrates are shown in Figure3. The surfaces of the product ZnO thin films were obviously smooth. The root mean square (RMS) surface roughness of the films was 13.07 nm, 15.36 nm and 16.23 nm for films with thicknesses of 100 to 300 nm, respectively. These results indicate that the surface quality of ZnO thin films on PET substrate improved as the film thickness decreased. In all cases, the conical features clearly seen on the film surface were the cause of the surface roughness. It is important to note here that surface smoothness is a highly desired parameter for coatings that are used for optical applications because it reduces the reflection loss due to roughness-induced surface scattering [17].AFM analysis of ZnO films deposited on PET substrates with different thicknesses.
(a)(b)(c)


### 3.2. Optical Characterization

The effect of thickness on the optical properties of ZnO films has been studied. The optical transmittance spectra of ZnO thin films deposited on PET substrates of different thicknesses are shown in Figure4. All these films demonstrate good optical transmittance (over 80%) in the visible and near-infrared range. Their high transmission in the visible range makes these films excellent candidates for transparent window materials in solar cells. The transmission of ZnO thin films decreased as the thickness increased; similar behavior involving a decrease in the transmission of the films as the film thickness increases has been reported in the literature [18, 19].Figure 4
Transmission spectra of ZnO thin films of varying thicknesses.It is well known that ZnO is a direct gap semiconductor. The optical band gapEg was determined by analyzing the optical data with the expression for the optical absorbance α and the photon energy hν [20]: (1)αhν=k(hν-Eg)1/2,
where h is the Planck constant, ν is the radiation frequency, and k is a constant. The optical band gap value (Eg) can be obtained by plotting (αhν)2; hν is the photon energy, as shown in Figure 5. As the film thickness increased from 100 to 300 nm, the value of the optical band gap gradually decreased from 3.45 to 3.375 eV, similar to other reports [21].Figure 5
A plot of (αhν)2 as a function of photon energy for ZnO thin films deposited on PET substrates with different thicknesses.


## 3.1. Structural Characterizations

Figure1 shows the XRD spectra for the vacuum-evaporated ZnO thin films on PET substrates. This spectrum was obtained at room temperature for a ZnO thin film with a thickness of 300 nm. The main peak corresponding to the PET substrate was observed at 2θ angle 26° [13–16]; it had a very high intensity. According to Figure 1, all peaks of the ZnO thin films can be well indexed to the hexagonal wurtzite structure of ZnO (JCPDS Card no. 01-089-0510, a=0.325 nm and c=0.521 nm).Figure 1
XRD patterns of ZnO thin films on PET substrates.Figure2 shows the EDX results for ZnO thin films deposited on PET substrates. EDX analysis confirms the composition of Zn and O in the ZnO film. The presence of the carbon peak in the spectrum is due to the PET substrate.Figure 2
EDX results for ZnO thin films deposited on PET substrates.AFM images of the surface morphologies of ZnO thin films deposited on PET substrates are shown in Figure3. The surfaces of the product ZnO thin films were obviously smooth. The root mean square (RMS) surface roughness of the films was 13.07 nm, 15.36 nm and 16.23 nm for films with thicknesses of 100 to 300 nm, respectively. These results indicate that the surface quality of ZnO thin films on PET substrate improved as the film thickness decreased. In all cases, the conical features clearly seen on the film surface were the cause of the surface roughness. It is important to note here that surface smoothness is a highly desired parameter for coatings that are used for optical applications because it reduces the reflection loss due to roughness-induced surface scattering [17].AFM analysis of ZnO films deposited on PET substrates with different thicknesses.
(a)(b)(c)


## 3.2. Optical Characterization

The effect of thickness on the optical properties of ZnO films has been studied. The optical transmittance spectra of ZnO thin films deposited on PET substrates of different thicknesses are shown in Figure4. All these films demonstrate good optical transmittance (over 80%) in the visible and near-infrared range. Their high transmission in the visible range makes these films excellent candidates for transparent window materials in solar cells. The transmission of ZnO thin films decreased as the thickness increased; similar behavior involving a decrease in the transmission of the films as the film thickness increases has been reported in the literature [18, 19].Figure 4
Transmission spectra of ZnO thin films of varying thicknesses.It is well known that ZnO is a direct gap semiconductor. The optical band gapEg was determined by analyzing the optical data with the expression for the optical absorbance α and the photon energy hν [20]: (1)αhν=k(hν-Eg)1/2,
where h is the Planck constant, ν is the radiation frequency, and k is a constant. The optical band gap value (Eg) can be obtained by plotting (αhν)2; hν is the photon energy, as shown in Figure 5. As the film thickness increased from 100 to 300 nm, the value of the optical band gap gradually decreased from 3.45 to 3.375 eV, similar to other reports [21].Figure 5
A plot of (αhν)2 as a function of photon energy for ZnO thin films deposited on PET substrates with different thicknesses.


## 4. Conclusion

ZnO thin films with various thicknesses were prepared on PET substrates by the thermal evaporation technique. The characteristics of ZnO thin films were investigated by various tools. The XRD patterns of the films deposited on PET substrates showed the proper formation of hexagonal ZnO. From AFM images, it was found that the root mean square roughness of the film surface increased as the film thickness increased. The optical band gap values of ZnO thin films decreased as the film thickness increased. The optical properties that were observed for uniform films of ZnO on PET substrates indicate that they may be used as window layers in solar cells.



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*Source: 302843-2011-12-01.xml*