# Modification of Ceramic Membranes by Silica Nanoparticles with Thiourea Functions

Authors: Veronika V. Tomina; Galyna I. Nazarchuk; Inna V. Melnyk
Journal: Journal of Nanomaterials
 (2019)

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## Abstract

Sol-gel approach based on hydrolytic copolycondensation of tetraethoxysilane (TEOS) with ethylthiocarbamidepropyl triethoxysilane (ETUS) was used to deposit functional layers with thiourea functions on the surface of macroporous ceramic alumina membrane supports. According to SEM images, such layers are composed of nanoparticles of about 60-70 nm in diameter, while IR spectroscopy data confirmed the presence of functional groups introduced during the synthesis. Such functionalization technique allows combining sorption and membrane technology and could be successfully used to remove trace quantities of copper, cadmium, and silver metal ions from aqueous solutions.


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## Body

## 1. Introduction

Methods of membrane separation used in water purification technology are conventionally divided into dialysis, electrodialysis, microfiltration, ultrafiltration, and reverse osmosis. In the process of ultrafiltration, the macromolecular substances exceeding the membrane pore sizes are retained, while the solvent freely permeates through the membrane. From ordinary filtration, ultrafiltration is distinguished by the smaller size of particles undergoing separation, while the pore size of the membrane should not exceed the size of the particles. In addition, this process results in the concentration of initial solution or suspension, not the precipitate formation as in conventional filtration. The mechanism of ultrafiltration is close to ordinary filtering [1].Membranes including thiourea groupings on the basis of different supports were synthesized and studied by many scientists due to their selectivity [2–5]. Thiourea derivatives were shown to have a strong complexation with different metals. For this reason, they were used to produce selective electrodes for silver(I) [6] and rubidium(I) [7] ions, mercury(II) membrane sensors [8], microporous cellulose membranes [9], and porous membranes with high selectivity and efficiency for the recovery of trace amounts of aurum(III) [10, 11].Various adsorbents with thiourea groups were synthesized using the sol-gel technique and analyzed in terms of their adsorption properties. Porous materials with thiourea groups in the surface layer are proved to be perspective for the sorption of heavy metal ions from aqueous solutions. Earlier, the scientists from our research team developed a one-step technique for the synthesis of the xerogels [12], the bridged xerogels [12, 13], mesoporous MCM-41 [12, 14], and SBA-15 [15, 16] type materials with thiourea functional groups and showed their ability to remove mercury(II) and silver(I) ions from aqueous solutions [12, 16, 17].Therefore, in the current research, we considered the possibility to deposit active layers containing thiourea functions [≡Si(CH2)3NHC(S)NНC2H5] on the surface of planar and tubular ceramic membrane supports.


## 2. Materials and Methods

### 2.1. Materials

Planar ceramic Al2O3 membrane supports are purchased from Anodisc, Whatman, with a diameter of 25 mm and an average pore size of 0.2 μm. Tubular ceramic Al2O3 membrane supports are purchased from Khust Ceramic Plant, Ukraine, which are cylindrical tubes with inner and outer diameters of 6 and 12 mm, respectively, and 25 cm in length. The average pore size is about 5 μm of the outer layer and 0.3 μm of the inner working layer. The following reagents are used for functionalization: tetraethoxysilane, Si(OC2H5)4 (ТEOS, Aldrich, 99%), ethylthiocarbamidepropyl triethoxysilane, (C2H5O)3Si(CH2)3NHC(S)NНC2H5 (ЕТUS, synthesized as in [15, 18]), ethanol (96%), and 0.0024 N HCl.


### 2.2. Sol Preparation and Membrane Functionalization Techniques

To prepare the functionalizing sol, both TEOS and ETUS were subjected to preliminary acidic hydrolysis. For TEOS hydrolysis, it was mixed with an equal volume of ethanol (1.12 mL) at constant stirring (500 rpm) followed by the addition of 1 mL of hydrochloric acid (0.0024 М) as a catalyst. The hydrolysis was carried out at 70–80°С for 30 min until the formation of transparent solution. Separately, the hydrolysis of trifunctional silane (ЕТUS) was carried. Similarly, equal volumes of ЕТUS and ethanol (4 mL each) were mixed in a glass with the addition of 0.9 mL of hydrochloric acid (0.0024 M) as a catalyst at room temperature (20-25°C). The mixture was stirred until the formation of transparent sol (3 min). The sols of TEOS and ЕТUS were mixed at TEOS/ЕТUS molar ratio 3/1 and constant stirring at 500 rpm. Afterwards, the resulting TEOS/ЕТUS sol was diluted with ethanol and deposited onto the membranes.Before functionalization, the tubular membrane supports were activated as described in [19]. They were boiled in 0.1 N HCl for 5 h, washed with water (about 2 L) until neutral pH values, and dried in a muffle furnace at 320°C for 6 h. In order to functionalize tubular membrane supports, an excess of sol (about 15 mL) was put in contact with the inner surface of the ceramic membrane for the period of 5 min. The excess sol was removed from the sample surface by purging with air.Thereafter, the functionalized membranes were dried for 2 h in air (at ambient temperature), for 2 h at 30°C and 50°C, and 20 h at 80°C. The samples were named asTU (planar) and TUt (tubular). The modification degree (MD), in μg of functionalizing coating per 1 cm2 of the membrane surface, was calculated from the difference between the weights of a membrane sample before and after functionalization.


### 2.3. Methods

Scanning electron microscopy (SEM) was used to investigate the porous structure of the membranes. The images were obtained with an electron microscope (JSM 6060 LA, Jeol, Japan) using secondary electrons at an accelerating voltage of 30 kV. The surface of the samples was covered with a thin continuous layer of gold by cathodic sputtering in vacuum.FT-IR spectra were recorded on a Thermo Nicolet Nexus FTIR spectrometer using diffuse reflection mode “SMART Collector” in the 4000–400 cm-1 range, with a resolution of 4 cm-1. The samples were ground with KBr (Fluka, spectranal) at the ratios of sample/KBr=1/20. The spectra were processed with the software of firm-supplier “OMNIC.”For contact angle measurements, a membrane was mounted on a horizontal stage and a water drop (10μL) was placed on its surface with a micrometer syringe. Then, a camera was used to take photographs of the drop profile. The contact angle was measured almost immediately after drop deposition (within 3-5 sec).


### 2.4. Membrane Filtration Techniques

The filtration of water and aqueous solutions of heavy metal ions (Cu(II), Ag(I), and Cd(II)) through the planar membranes was carried out using an Amicon stirred ultrafiltration cell (Millipore Corporation, USA) in the dead-end mode (Figure1(a)). To analyze the transport properties of tubular membranes, experimental filtration unit with recirculation mode was used (Figure 1(b)). The membrane flux, Jv (L/m2h), was calculated by measuring the time needed to collect some volume of the permeate:
(1)Jv=VA⋅t,where V is the volume of the permeate (L), A is the effective membrane area (m2), and t is the time taken to collect the permeate (h).Figure 1
Amicon stirred ultrafiltration cell (Millipore Corporation, USA) (a) and experimental setup for studying transport characteristics of tubular membranes in the circulation mode (b): 1—feed solution, 2—retentate, 3—membrane cell, 4—pump, 5—container with purified permeate, and 6—container with feed solution.
(a)
(b)Working aqueous heavy metal ion solutions were prepared from the batches of the corresponding nitrate salts of these metals: Cu(NO3)2·3H2O solution (pH ~5.8), AgNO3 solution (pH ~2), and Cd(NO3)2·4H2O solution (pH ~5.7). The samples of the permeate and concentrate were tested for the content of Cu(II), Ag(I), and Cd(II) ions.Membrane regeneration for copper(II) ion desorption was carried out in the filtration unit in the dynamic mode by pumping 0.1 N HCl solution through the membranes for 30 min, followed by washing with distilled water (still in the filtration unit) till neutral pH values [20]. After that, the regenerated membranes were dried in an oven at 50°C and used for the next adsorption cycle.Heavy metal ion concentrations in the probes were determined by atomic absorption spectrophotometer C-115-M1 in depleted (oxidative) flame (acetylene/air mixture) using the resonance signals at 328.1 nm (Ag), 324.7 nm (Cu), and 228.3 nm (Cd). The source of resonance radiation was a spectral lamp LS-2 with a detection limit of 0.01μg/сm3.The retention (R) of metal ions by the membranes was calculated as
(2)R=1−CpCf∗100%,where Cp and Cf are the concentrations of heavy metal ions in the permeate and in the feed solutions, respectively.


## 2.1. Materials

Planar ceramic Al2O3 membrane supports are purchased from Anodisc, Whatman, with a diameter of 25 mm and an average pore size of 0.2 μm. Tubular ceramic Al2O3 membrane supports are purchased from Khust Ceramic Plant, Ukraine, which are cylindrical tubes with inner and outer diameters of 6 and 12 mm, respectively, and 25 cm in length. The average pore size is about 5 μm of the outer layer and 0.3 μm of the inner working layer. The following reagents are used for functionalization: tetraethoxysilane, Si(OC2H5)4 (ТEOS, Aldrich, 99%), ethylthiocarbamidepropyl triethoxysilane, (C2H5O)3Si(CH2)3NHC(S)NНC2H5 (ЕТUS, synthesized as in [15, 18]), ethanol (96%), and 0.0024 N HCl.


## 2.2. Sol Preparation and Membrane Functionalization Techniques

To prepare the functionalizing sol, both TEOS and ETUS were subjected to preliminary acidic hydrolysis. For TEOS hydrolysis, it was mixed with an equal volume of ethanol (1.12 mL) at constant stirring (500 rpm) followed by the addition of 1 mL of hydrochloric acid (0.0024 М) as a catalyst. The hydrolysis was carried out at 70–80°С for 30 min until the formation of transparent solution. Separately, the hydrolysis of trifunctional silane (ЕТUS) was carried. Similarly, equal volumes of ЕТUS and ethanol (4 mL each) were mixed in a glass with the addition of 0.9 mL of hydrochloric acid (0.0024 M) as a catalyst at room temperature (20-25°C). The mixture was stirred until the formation of transparent sol (3 min). The sols of TEOS and ЕТUS were mixed at TEOS/ЕТUS molar ratio 3/1 and constant stirring at 500 rpm. Afterwards, the resulting TEOS/ЕТUS sol was diluted with ethanol and deposited onto the membranes.Before functionalization, the tubular membrane supports were activated as described in [19]. They were boiled in 0.1 N HCl for 5 h, washed with water (about 2 L) until neutral pH values, and dried in a muffle furnace at 320°C for 6 h. In order to functionalize tubular membrane supports, an excess of sol (about 15 mL) was put in contact with the inner surface of the ceramic membrane for the period of 5 min. The excess sol was removed from the sample surface by purging with air.Thereafter, the functionalized membranes were dried for 2 h in air (at ambient temperature), for 2 h at 30°C and 50°C, and 20 h at 80°C. The samples were named asTU (planar) and TUt (tubular). The modification degree (MD), in μg of functionalizing coating per 1 cm2 of the membrane surface, was calculated from the difference between the weights of a membrane sample before and after functionalization.


## 2.3. Methods

Scanning electron microscopy (SEM) was used to investigate the porous structure of the membranes. The images were obtained with an electron microscope (JSM 6060 LA, Jeol, Japan) using secondary electrons at an accelerating voltage of 30 kV. The surface of the samples was covered with a thin continuous layer of gold by cathodic sputtering in vacuum.FT-IR spectra were recorded on a Thermo Nicolet Nexus FTIR spectrometer using diffuse reflection mode “SMART Collector” in the 4000–400 cm-1 range, with a resolution of 4 cm-1. The samples were ground with KBr (Fluka, spectranal) at the ratios of sample/KBr=1/20. The spectra were processed with the software of firm-supplier “OMNIC.”For contact angle measurements, a membrane was mounted on a horizontal stage and a water drop (10μL) was placed on its surface with a micrometer syringe. Then, a camera was used to take photographs of the drop profile. The contact angle was measured almost immediately after drop deposition (within 3-5 sec).


## 2.4. Membrane Filtration Techniques

The filtration of water and aqueous solutions of heavy metal ions (Cu(II), Ag(I), and Cd(II)) through the planar membranes was carried out using an Amicon stirred ultrafiltration cell (Millipore Corporation, USA) in the dead-end mode (Figure1(a)). To analyze the transport properties of tubular membranes, experimental filtration unit with recirculation mode was used (Figure 1(b)). The membrane flux, Jv (L/m2h), was calculated by measuring the time needed to collect some volume of the permeate:
(1)Jv=VA⋅t,where V is the volume of the permeate (L), A is the effective membrane area (m2), and t is the time taken to collect the permeate (h).Figure 1
Amicon stirred ultrafiltration cell (Millipore Corporation, USA) (a) and experimental setup for studying transport characteristics of tubular membranes in the circulation mode (b): 1—feed solution, 2—retentate, 3—membrane cell, 4—pump, 5—container with purified permeate, and 6—container with feed solution.
(a)
(b)Working aqueous heavy metal ion solutions were prepared from the batches of the corresponding nitrate salts of these metals: Cu(NO3)2·3H2O solution (pH ~5.8), AgNO3 solution (pH ~2), and Cd(NO3)2·4H2O solution (pH ~5.7). The samples of the permeate and concentrate were tested for the content of Cu(II), Ag(I), and Cd(II) ions.Membrane regeneration for copper(II) ion desorption was carried out in the filtration unit in the dynamic mode by pumping 0.1 N HCl solution through the membranes for 30 min, followed by washing with distilled water (still in the filtration unit) till neutral pH values [20]. After that, the regenerated membranes were dried in an oven at 50°C and used for the next adsorption cycle.Heavy metal ion concentrations in the probes were determined by atomic absorption spectrophotometer C-115-M1 in depleted (oxidative) flame (acetylene/air mixture) using the resonance signals at 328.1 nm (Ag), 324.7 nm (Cu), and 228.3 nm (Cd). The source of resonance radiation was a spectral lamp LS-2 with a detection limit of 0.01μg/сm3.The retention (R) of metal ions by the membranes was calculated as
(2)R=1−CpCf∗100%,where Cp and Cf are the concentrations of heavy metal ions in the permeate and in the feed solutions, respectively.


## 3. Results and Discussion

Since porous materials with thiourea groups in the surface layer are proved to be perspective for the sorption of heavy metal ions from aqueous solutions, we made an attempt of introduction these groups in the structure of the functionalizing layer of planar ceramic membranes. However, the procedure for the surface layer deposition was similar to the functionalization of membranes with mercapto groups, as described in [21] for planar ceramic membranes and in [19, 22] for tubular ones. We used the reaction of hydrolytic copolycondensation of TEOS (as a structure-forming agent) and ETUS (as a source of functional thiourea groups) to form polysiloxane active membrane layers. Preliminary acidic hydrolysis was used for both silanes, as was described earlier in the text, in order to avoid nonhomogenous gelation. The scheme of the reaction is presented in Figure 2.Figure 2
Scheme of the reaction of hydrolytic polycondensation of alkoxysilanes.Because of sufficient viscosity of the original sol, it was diluted with ethanol to facilitate the formation of a homogeneous polysiloxane layer on the membrane surface (Table1). Such procedure of sol dilution with ethanol earlier are proved effective for the formation of uniform active layers with SH groups [19, 21]. However, due to the hydrophobicity of the resulting samples with thiourea groups and their poor permeability to water, optimal for the functionalization of planar supports appeared to be nine times the dilution of the original TEOS/ETUS sol. We also used a syringe to blow air through the membrane sample after sol deposition and previous to drying, but it resulted in the decrease of MD (sample TU3∗ from Table 1).Table 1
Functionalizing membrane supports with thiourea groups.
Sample
Sol/EtOH ratio
Volume of deposited sol (mL)
∆m (g)
MD (μg/cm2)
Thiourea groups content (theor.) (mmol/g)
TU1
1/4
0.025
0.0014
335
2.65
TU2
1/8
0.025
0.0017
410
2.65
TU3∗
1/8
0.025
0.0006
145
2.65
TU4
1/8
0.025
0.0099
2385
2.65
TU5
1/8
0.010
0.0013
315
2.65
TU6
1/8
0.025
0.0022
530
2.65
TUt
1/2
15
0.4529
8876
2.65
∗Millipore Swinnex filter holder was used for sol deposition.Figure3 presents typical SEM images of the active layer of planar membrane supports functionalized with thiourea groups, samples TU1 and TU6. According to it, the functionalizing polysiloxane layer with thiourea groups is composed of nanoparticles. The average size of such particles is about 60-70 nm for all the samples. These particles are similar to those with 3-mercaptopropyl groups obtained in the same acidic conditions [21]. However, they are smaller than those with 3-aminopropyl groups [23] due to the alkaline properties of 3-aminopropyltriethoxysilane autocatalizing the reaction at an early stage. Therefore, we can conclude that the type of catalyst influences the size of functionalized particles. Also, we can add that the morphology of the membrane does not change during the two cycles of adsorption-desorption (Figure 3(c)) and such modification technique is effective to produce stable membranes for water remediation.Figure 3
SEM images of the membranes with thiourea functional groups:TU1 (a), TU6 (b), and TU6 regenerated (c).
(a)
(b)
(c)The method of FTIR spectroscopy was used to verify the functionalization, namely, the formation of polysiloxane network, and the incorporation of thiourea groups. For this reason, there were recorded FTIR spectra of thiourea-functionalized silica particles (Figure4, spectrum 1) and membranes, illustrations of which are plotted in Figure 4. The positions of absorption bands are similar in these three spectra, except for a low-frequency region containing an intensive broad absorption band from an Al-O-Al network of the membrane support. It accords with the composition of functionalized membrane samples witnessed by SEM, namely, consisting of alumina membrane support and active layer formed by functionalized silica particles. FTIR spectroscopy data confirm the presence of thiourea-containing Si(CH2)3NHC(S)NHC2H5 groups in the surface layer of the functionalized membranes. Thiourea ligands are characterized by thione-thiol tautomerism. They have two tautomeric forms: thione (>C=S) and thiol (≥C-SH). In our research [17], we showed that during the interaction with silver or mercury ions, the thion form is transformed into thiol, which is evidenced by the decrease in the pH value of the adsorption solution and FTIR spectra. Thus, the FTIR spectra of the samples have a narrow absorption band of medium intensity at 1549 cm-1, which refers to νas(NCN) stretches of thiourea fragment –NH–C(S)–NH– and the absorption bands at 1500 сm–1 which can be attributed to the ν(C=S) of the thione form [24]. After 2 cycles of adsorption-desorption, we can observe the appearance of the adsorption band at 1637 cm-1, corresponding ν(N=CS) of the azomethine group in the thiol form of the thiourea group and this fact confirms our conclusion that during adsorption, the thione form of thiourea grouping transforms to thiol one [25]. It should be mentioned that in the infrared spectrum of the initial membrane, there are no bands in this spectral region. Thus, the emerging complexes may have the following composition: [(HN)2>C(–S–Ag)], [(HN)2>C(–S–Cd–S–)C<(NH)2], and [(HN)2>C(–S–Cu–S–)C<(NH)2]. There are several absorption bands in the region of 2875–2973 cm-1, which can be attributed to the valence vibrations of C–H bonds from the methyl and methylene fragments. Also, there is a group of low-intensity bands in the region of 1337–1445 сm–1 related to the bending vibrations of the latter. This indicates the presence of propyl and ethyl chains in the surface layer of functionalized membranes.Figure 4
FTIR spectra of polysiloxane spheres with thiourea groups (1), membrane functionalized with thiourea groupsTU6 (2), and regenerated membrane TU6 after two cycles of Cu(II) ion adsorption-desorption (3).Finally, it should be mentioned that the IR spectra of functionalized membranes contain the most intense absorption band in the range of 1059–1200 cm-1 with a high-frequency shoulder. Its presence is associated with the formation of a three-dimensional polysiloxane network [26]. There are wide bands at ~3300 cm-1 and ~3700 cm-1 assigned to ν(NH) of thiourea fragment and ν(ОН) stretches of sorbed water in all DRIFT spectra [12, 17]. The overlapping of these bands occurs because all the samples contain the water on the surface.To evaluate the changes in surface hydrophilicity, we conducted the measurement of water contact angles of the membrane supports after functionalization. The water contact angle of the initial membrane support was measured and described earlier [23] and is about 8°, indicating strong hydrophilicity of the sample. However, all the samples with thiourea groups appear to be hydrophobic, independent from the ratio of the sol dilution used for functionalization and MD, as it can be seen in Figure 5 for TU1 and TU6 samples. It also should be mentioned that the contact angle does not change essentially within 2 min and after copper(II) ion adsorption-desorption (Figure 5(c)). Hydrophobicity of membranes explains the low water flux through such functionalized membranes (Figure 6(b)) compared to 2200 L/m2h through the original membrane, as can be seen in Figure 6(a).Figure 5
Contact angle measurements forTU1 (a), TU6 (b), and TU6 regenerated (c).
(a)
(b)
(c)Figure 6
Water flux through planar membranes, initial (a) and functionalized with thiourea groups (b).
(a)
(b)It appears that the flux through the membranes functionalized with sol nine times diluted with ethanol (TU2) is higher than that through the membrane functionalized with sol five times diluted with ethanol (TU1) (see Figure 6(b)). Such phenomenon may be explained by the formation of a more uniform surface layer in the case of more diluted sol (TU2), as it was observed for thiol-functionalized membranes in [19]. Therefore, nine times sol dilution was used in the further experiments.To evaluate the performance of functionalized membranes in retention of heavy metal ions, we conducted the experiments with the filtration of model solutions of Ag(I), Cd(II), and Cu(II) nitrate salts (Figure7). The retention of Ag(I) and Cd(II) ions decreases during filtration, with confirms that retention is due to the interaction of ions with the surface functional groups.Figure 7
Silver(I) (a) and cadmium(II) (b) ions retention by membranes with thiourea groups (CAg+=22mg/L, CCd2+=260mg/L, p=4bar).
(a)
(b)However, for the Cu(II) ions, there is observed increasing retention during the filtration which suggests the involvement of size-exclusion membrane mechanism. An attempt was made to reuse functionalized membranes with thiourea groups in the second cycle after the regeneration procedure. The regeneration was carried out with 0.1% HCl acid. Interestingly, that the membranes with thiourea groups showed improved retention of copper(II) ions in the second cycle, comparing with the first (see Figure8). There can be two possible explanations of increased retention of copper(II) ions in the second cycle. The pressure under which the filtration was performed may cause the compression of the active layer, resulting in lower water permeability and higher metal ion retention. It also can be the influence of hydrochloric acid used for the regeneration, causing the hydrolysis of residual ethoxy groups to silanol. This study was done only for copper(II) ions and may be the subject of further research, but it is known that thiourea groups have an affinity to Ag, Cd, and Pb metal ions, so they are expected to be adsorbed. As for Ag ions, in our previous article [17], we carried out adsorption and desorption of silver ions by similar functional groups, and one should expect the same mechanism for the membranes.Figure 8
Copper(II) ions retention by membranes with thiourea groups during first cycle of filtration (a) and second cycle (b) (CCu2+=18.6mg/L, p=4bar).
(a)
(b)When analyzing the performance of tubular ceramic membranes in the filtration of water, it was witnessed that water flux decreases strongly after functionalization with polysiloxane layers containing thiourea groups (see Figure9). Moreover, the water flow through TUt membranes does not vary with pressure and decreases during filtration from about 300 to about 150 L/m2h (Figure 9(b)). Such behavior may be connected with high hydrophobicity of the samples.Figure 9
Water flux through tubular membranes, initial (a) and functionalized with thiourea groups (b).
(a)
(b)Similar to planar membranes, there were conducted experiments on heavy metal ion retention by tubular alumina membranes with thiourea functions, using copper(II) nitrate model solutions (see Figure10). The regeneration was conducted with 0.1 N HCl. The retention of copper ions decreases with time during filtration both in the first and in the second cycles, which suggests that the retention is mainly due to the ion interaction with the surface thiourea groups.Figure 10
Retention (a) and water flux (b) for tubular membrane with thiourea groups (TUt) in the filtration of Сu(NO3)2, CCu2+=22mg/L, p=1bar, and regeneration: 0.1 N HCl.
(a)
(b)Moreover, the retention of copper(II) ions appeared to be the same before and after regeneration. However, a substantial decrease in water flow through the membrane after the regeneration was observed. This, similar to the functionalized planar membranes, may suggest some changes in the properties of the functionalizing layer during the regeneration procedure.


## 4. Conclusions

The Sol-gel method based on the reaction of hydrolytic polycondensation of alkoxysilanes was used for creating selective layers with amino and thiourea groups on the surfaces of planar and tubular ceramic membranes. It was shown that such approach allows influencing the degree of hydrophobicity of the created surface layer. Additionally, it allows controlling the porous structure of the surface layer at the stage of formation and ripening of silica sol and its transition to gel, by varying the ratio of reactants, the nature of the solvent, and the drying mode.The identification of functional coatings on the surface of planar ceramic membranes was carried out by means of IR spectroscopy, while their morphology was analyzed with SEM. It is necessary to use diluted sols for the formation of monolayer-like coating and better interaction of the particles with the surface of the support. It will ensure better fixation of the active layer and contribute to the membrane exploitation in several cycles. It was shown that the deposited layers adsorb heavy metal ions, such as copper(II), silver(I), and cadmium(II). There possibility of membrane regeneration with hydrochloric acid and reuse in several cycles of copper(II) ion sorption/desorption was also shown. An important feature of the proposed functionalization technique is the possibility of introducing other functional groups in the surface of ceramic membranes, i.e., depending on the practical task; there is the possibility of preparing sols with different silanes.



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