# ITO-Free Semitransparent Organic Solar Cells Based on Silver Thin Film Electrodes

Authors: Zhizhe Wang; Chunfu Zhang; Dazheng Chen; Shi Tang; Jincheng Zhang; Li Sun; Ting Heng; Yue Hao
Journal: International Journal of Photoenergy
 (2014)

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## Abstract

ITO-free semitransparent organic solar cells (OSCs) based on MoO3/Ag anodes with poly(3-hexylthiophene) and [6,6]-phenyl-C61-butyric acid methyl ester films as the active layer are investigated in this work. To obtain the optimal transparent (MoO3)/Ag anode, ITO-free reference OSCs are firstly fabricated. The power conversion efficiency (PCE) of 2.71% is obtained for OSCs based on the optimal MoO3 (2 nm)/Ag (9 nm) anode, comparable to that of ITO-based reference OSCs (PCE of 2.85%). Then based on MoO3 (2 nm)/Ag (9 nm) anode, ITO-free semitransparent OSCs with different thickness combination of Ca and Ag as the cathodes are investigated. It is observed from our results that OSCs with Ca (15 nm)/Ag (15 nm) cathode have the optimal transparency. Meanwhile, the PCE of 1.79% and 0.67% is obtained for illumination from the anode and cathode side, respectively, comparable to that of similar ITO-based semitransparent OSCs (PCE of 1.59% and 0.75% for illumination from the anode and cathode side, resp.) (Sol. Energy Mater. Sol. Cells, 95, pp. 877–880, 2011). The transparency and PCE of ITO-free semitransparent OSCs can be further improved by introducing a light couple layer. The developed method is compatible with various substrates, which is instructive for further research of ITO-free semitransparent OSCs.


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## Body

## 1. Introduction

Due to the advantage of low cost, light weight, simple process, flexibility, and possibility of roll-to-roll mass production [1–5], organic solar cells (OSCs) have become a highly attractive research topic over the past decade. With the development of the research, obvious progress has been made. Recently, even OSCs with certified power conversion efficiency (PCE) above 10% have been reported [6], which has approached the requirement of commercialization.However, there are still some bottlenecks for commercialization of OSCs. One awkward drawback is that most organic materials can cover only a fraction of the solar spectrum, and inefficient light harvest results in the low photocurrent [7]. One efficient way to enhance broad spectral absorption of OSCs is the realization of organic tandem solar cells based on complementary thin absorber materials. As we all know, the semitransparent electrode [8, 9] or recombination contact used to connect two subcells is of vital importance in the fabrication of tandem solar cells. Meanwhile, semitransparent OSCs make sense from the aspect of application. For example, these semitransparent OSCs can be employed as the windows of our houses and cars, providing electric power without occupying living space. Thus, various semitransparent electrodes for OSCs have been developed in recent years [10–12]. It should be noted that good transparency and high PCE are required simultaneously for the application of semitransparent OSCs.Another bottleneck for commercialization of OSCs stems from the commonly used transparent anode in the fabrication of OSCs—indium tin oxide (ITO) sputtered on glass. Although ITO has excellent properties in optical transparency and electrical conductivity, it is unsuitable for cheap roll-to-roll fabrication of OSCs, which relies on the flexible electrodes with low cost. For example, the scarce indium source and stringent process conditions (usually sputter) result in high cost for ITO electrode [13]. Meanwhile, both the brittleness of ITO electrode and high temperature condition in the fabrication of ITO make it unsuitable for the roll-to-roll mass production of OSCs [14]. Thus, more and more attention has been focused on alternative transparent conductive electrodes. Indium-free transparent conducting oxides (such as Ga-doped ZnO (GZO) and Al-doped ZnO (AZO)) [15–17], poly(3,4-ethylenedioxythiophene):poly-(styrenesulfonate) (PEDOT:PSS) [18, 19], Ag nanowires [14, 20], graphene [13], and carbon nanotubes [21] are used as the alternative of ITO electrode. However, although GZO or AZO has a lower cost than ITO, the fabrication of these electrodes still needs sputter. Although the PEDOT:PSS electrode can be easily fabricated by solution method, the resistivity of this electrode is still a little too high [22, 23]. Since the surfaces of Ag nanowire, graphene, and carbon nanotube electrodes are usually rough, charge injection into or extraction from active layer has been restricted [13, 14, 24]. In addition, complex film processing of these electrodes also makes them inappropriate for application in large-scale OSCs [13, 14, 24].On the contrary, a smooth metal thin film (e.g., Ag) can be easily fabricated by thermal evaporation, compatible with the mass production process. Moreover, due to their intrinsic flexibility and high conductivity [24], metal thin film electrodes are suitable for the flexible substrates in roll-to-roll mass production of OSCs. Thus, more and more attention is attracted to this topic. Various transparent metal thin film electrodes (such as Au [25], Ag [26], Cu [27], Cu/Ni [28], and MoO3/Au/MoO3 [24]) are reported and employed in the fabrication of OSCs.However, in the previous work, semitransparent OSCs are usually fabricated on ITO electrodes. Here, we have reported ITO-free semitransparent OSCs based on Ag thin film anodes. The ITO-free semitransparent OSC has combined the advantages of ITO-free OSCs and semitransparent OSCs, solving two bottlenecks discussed above for commercialization of OSCs simultaneously. At first, ITO-free reference OSCs based on (MoO3)/Ag anodes are fabricated, with poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) films as the active layer. The optimal anode, MoO3 (2 nm)/Ag (9 nm) anode, is obtained. The PCE of 2.71% is achieved for corresponding OSCs (also the highest PCE among all the ITO-free reference OSCs), comparable to that of ITO-based reference OSCs (PCE of 2.85%). Then based on this MoO3 (2 nm)/Ag (9 nm) anode, ITO-free semitransparent OSCs with different thickness combination of Ca and Ag as the cathodes are fabricated. It is observed from our results that OSCs with Ca (15 nm)/Ag (15 nm) cathode have the optimal transparency. Meanwhile, the PCE of 1.79% (illuminated from the anode side) and 0.67% (illuminated from the cathode side) is obtained for the corresponding device, comparable to that of similar ITO-based semitransparent OSCs (PCE of 1.59% and 0.75% for illumination from the anode and cathode side, resp.) [10, 11]. The result is instructive for further research of ITO-free semitransparent OSCs.


## 2. Experimental Details

### 2.1. Material and Substrate Preparation

P3HT was purchased from Rieke Metals Inc., PCBM was purchased from Nano-C Inc., and 1,2-dichlorobenzene and MoO3 were provided from Aldrich Inc. All the materials were used without any further purification. P3HT and PCBM were dissolved in 1,2-dichlorobenzene with a concentration of 20 mg/mL, respectively. They were mixed in a weight ratio of 1 : 0.8 and stirred at room temperature for 2 h before use. Glass substrates were cleaned sequentially with detergent (Decon 90, UK), deionized water, acetone, and ethanol in an ultrasonic bath for about 15 min.


### 2.2. Electrode Deposition and Characterization

Cleaned glass substrates were dried with a nitrogen (N2) flow and then transferred into a custom-made multichamber ultrahigh vacuum evaporation system. The (MoO3)/Ag electrodes were deposited on glass by thermal evaporation at a vacuum pressure <5 × 10−4 Pa, with a evaporation rate of 0.02 and 0.1 nm/s for MoO3 and Ag, respectively. The substrates during deposition were at room temperature. The thicknesses and evaporation rates of MoO3, Ag, Al, and Ca were estimated in situ with a calibrated quartz crystal monitor.The spectral transmission and reflectance were recorded by using an UV-VIS-NIR spectrophotometer (Lambda 950, Perkin Elmer). Since transmission was measured relative to air, the reflection of the glass substrate was included. The sheet resistances of the samples were measured by using a four-point probe setup. The transmission electron microscope (TEM) cross-sectional image was taken by a FEI Tecnai G2 F20 S-Twin transmission electron microscope.


### 2.3. Device Fabrication and Measurement

After the electrode deposition, a 10 nm thick MoO3 layer was first thermally evaporated onto the substrates as the hole transport layer with high work function. Then P3HT:PCBM solution was spin-coated onto the samples at 1000 rpm for 60 s in a N2 glove box attached to the vacuum system, followed by annealing at 150°C for 10 min. Finally, Ca and Ag with different thicknesses were further deposited on top of the active layer as the cathode through a metal shadow mask to finish the ITO-free semitransparent OSCs, resulting in an active solar cell area of 6 mm2. ITO-free and ITO-based reference OSCs were fabricated in nearly the same procedure except that they were postannealed after the deposition of the 70 nm thick Al cathode. Device geometry of ITO-free reference or ITO-free semitransparent OSCs is illustrated in Figure 1(a). TEM cross-sectional image of corresponding ITO-free semitransparent OSCs is shown in Figure 1(b). The current density-voltage (J-V) characteristics were measured with a source measurement unit 2400 SMU (Keithley, USA) and simulated AM 1.5 G sun light (San-Ei Electric) in air without any device encapsulation. The illumination intensity was kept at 100 mW/cm2 through using a Si standard solar cell calibrated by the National Renewable Energy Laboratory (NREL).(a) Device geometry of ITO-free reference or ITO-free semitransparent OSCs based on (MoO3)/Ag anodes and (b) TEM cross-sectional image of ITO-free semitransparent OSCs.
(a)
(b)


## 2.1. Material and Substrate Preparation

P3HT was purchased from Rieke Metals Inc., PCBM was purchased from Nano-C Inc., and 1,2-dichlorobenzene and MoO3 were provided from Aldrich Inc. All the materials were used without any further purification. P3HT and PCBM were dissolved in 1,2-dichlorobenzene with a concentration of 20 mg/mL, respectively. They were mixed in a weight ratio of 1 : 0.8 and stirred at room temperature for 2 h before use. Glass substrates were cleaned sequentially with detergent (Decon 90, UK), deionized water, acetone, and ethanol in an ultrasonic bath for about 15 min.


## 2.2. Electrode Deposition and Characterization

Cleaned glass substrates were dried with a nitrogen (N2) flow and then transferred into a custom-made multichamber ultrahigh vacuum evaporation system. The (MoO3)/Ag electrodes were deposited on glass by thermal evaporation at a vacuum pressure <5 × 10−4 Pa, with a evaporation rate of 0.02 and 0.1 nm/s for MoO3 and Ag, respectively. The substrates during deposition were at room temperature. The thicknesses and evaporation rates of MoO3, Ag, Al, and Ca were estimated in situ with a calibrated quartz crystal monitor.The spectral transmission and reflectance were recorded by using an UV-VIS-NIR spectrophotometer (Lambda 950, Perkin Elmer). Since transmission was measured relative to air, the reflection of the glass substrate was included. The sheet resistances of the samples were measured by using a four-point probe setup. The transmission electron microscope (TEM) cross-sectional image was taken by a FEI Tecnai G2 F20 S-Twin transmission electron microscope.


## 2.3. Device Fabrication and Measurement

After the electrode deposition, a 10 nm thick MoO3 layer was first thermally evaporated onto the substrates as the hole transport layer with high work function. Then P3HT:PCBM solution was spin-coated onto the samples at 1000 rpm for 60 s in a N2 glove box attached to the vacuum system, followed by annealing at 150°C for 10 min. Finally, Ca and Ag with different thicknesses were further deposited on top of the active layer as the cathode through a metal shadow mask to finish the ITO-free semitransparent OSCs, resulting in an active solar cell area of 6 mm2. ITO-free and ITO-based reference OSCs were fabricated in nearly the same procedure except that they were postannealed after the deposition of the 70 nm thick Al cathode. Device geometry of ITO-free reference or ITO-free semitransparent OSCs is illustrated in Figure 1(a). TEM cross-sectional image of corresponding ITO-free semitransparent OSCs is shown in Figure 1(b). The current density-voltage (J-V) characteristics were measured with a source measurement unit 2400 SMU (Keithley, USA) and simulated AM 1.5 G sun light (San-Ei Electric) in air without any device encapsulation. The illumination intensity was kept at 100 mW/cm2 through using a Si standard solar cell calibrated by the National Renewable Energy Laboratory (NREL).(a) Device geometry of ITO-free reference or ITO-free semitransparent OSCs based on (MoO3)/Ag anodes and (b) TEM cross-sectional image of ITO-free semitransparent OSCs.
(a)
(b)


## 3. Results and Discussion

To fabricate ITO-free semitransparent OSCs, ITO-free reference OSCs with Al cathode were firstly investigated so that we can obtain the optimal transparent Ag thin film anode.As we all know, the thermally evaporated Ag layer prefers Volmer-Weber growth, which starts from isolated island [29]. Thus, Ag atoms agglomerate to form isolated clusters at first when Ag is thermally evaporated on glass substrates. It can cause surface plasmon resonances with light in the visible range which significantly reduces the film transparency [30]. With the increase of the Ag film thickness, the percolation threshold of Ag is reached, which is defined as equivalent thickness where isolated metal islands start to connect and form a continuous layer [31]. If the thickness of Ag layer is over this transition point, the transparency is decreased with an increased conductivity. Thus the best performance of OSCs based on Ag thin film anode is generally achieved close to the percolation threshold, indicating the best trade-off between increasing conductivity and decreasing transparency.The PCE of ITO-free reference OSCs fabricated on the Ag or MoO3/Ag anodes is illustrated in Figures 2(a) and 2(b), respectively. For comparison, the PCE of the ITO-based reference OSC is also shown in Figure 2(b). As shown in Figure 2(a), the PCE of 2.57% is obtained for OSCs based on Ag (11 nm) anode, the best performance among the devices fabricated on pure Ag anodes. It may suggest that the percolation threshold of Ag in our case is approximately 11 nm. Then a MoO3 interlayer between the Ag layer and glass substrate is introduced. Since a closed MoO3 layer is formed with the approximate thickness of 4 nm [32], two different thicknesses of MoO3 (2 nm or 10 nm) are chosen here. It can be observed from Figure 2 that the introduction of the MoO3 interlayer can improve the performance of OSCs effectively, particularly when the thickness of MoO3 is 2 nm. The PCE of OSCs based on MoO3 (2 nm)/Ag (9 nm) anode is even enhanced to 2.71% (also the highest PCE among all the ITO-free reference OSCs), comparable to that of ITO-based reference OSCs (PCE of 2.85%). Improvement in the performance of the Ag thin film electrode can be attributed to decreased percolation threshold of Ag by introducing a MoO3 interlayer (especially when the MoO3 layer is thin). MoO3 works as a surfactant here to modify the surface of Ag film. When the thickness of MoO3 is 2 nm, the unclosed layer may create preferred nucleation sites on the glass substrate to enhance the lateral growth of Ag film and decrease Ag threshold. The detailed discussion and analysis can be seen in our previous work [33].The PCE of ITO-free reference OSCs fabricated on the (a) Ag or (b) MoO3/Ag anodes. For comparison, the PCE of the ITO-based reference OSC is also shown in (b). The characters A, B, C, D, E, and F on the X axis of (b) indicate MoO3 (2 nm)/Ag (7 nm), MoO3 (2 nm)/Ag (9 nm), MoO3 (2 nm)/Ag (11 nm), MoO3 (10 nm)/Ag (9 nm), MoO3 (10 nm)/Ag (11 nm), and ITO anode, respectively.
(a)
(b)Based on this optimal MoO3 (2 nm)/Ag (9 nm) anode, ITO-free semitransparent OSCs are fabricated with different thickness combination of Ca and Ag as the cathodes. J-V characteristics of corresponding OSCs illuminated from the anode or cathode side are shown in Figures 3(a) and 3(b), respectively. Dark J-V curves are also shown in Figure 3(a) for comparison. The corresponding photovoltaic parameters have been summarized in Table 1. As shown in Figure 3(a) and Table 1, the best performance is obtained for OSCs with Ca (10 nm)/Ag (20 nm) cathode when illuminated from the anode side, with an open-circuit voltage (V
OC) of 0.64 V, a short-circuit current density (J
SC) of 5.03 mA/cm2, a fill factor (FF) of 62.4%, and a PCE of 2.01%. However, when illuminated from the cathode side, a higher J
SC of 1.90 mA/cm2 and a higher PCE of 0.67% are obtained for OSCs based on Ca (15 nm)/Ag (15 nm) cathode, compared with that of devices with Ca (10 nm)/Ag (20 nm) cathode. Moreover, a very low J
SC of 0.31 mA/cm2 is obtained for OSCs with Ca (20 nm)/Ag (10 nm) cathode when illuminated from the anode side.Table 1
Photovoltaic performance parameters of ITO-free semitransparent OSCs with different thickness combination of Ca and Ag as the cathodes illuminated from the anode (bottom) and cathode (top) side.
Ca (nm)
Ag (nm)
Illumination
V
OC (V)
J
SC (mA/cm2)
FF (%)
PCE (%)
R
S (Ω/cm2)
R
Sh (kΩ/cm2)
10
20
Bottom
0.64
5.03
62.4
2.01
1.2
1.08
10
20
Top
0.60
1.44
64.6
0.56
1.3
5.07
15
15
Bottom
0.64
4.70
59.5
1.79
2.1
1.12
15
15
Top
0.60
1.90
59.3
0.67
1.7
2.31
20
10
Bottom
0.62
0.31
10.1
0.02
/
/
20
10
Top
/
/
/
/
/
/J-V characteristics of devices MoO3 (2 nm)/Ag (9 nm)/MoO3 (10 nm)/P3HT:PCBM/Ca/Ag with different thickness combination of Ca and Ag as the cathodes when illuminated from the (a) anode side and (b) cathode side. Corresponding dark J-V curves are also shown in (a) for comparison.
(a)
(b)In order to better understand the effect of different cathodes on the device performance, the cathode-only samples of Ca (10 nm)/Ag (20 nm), Ca (15 nm)/Ag (15 nm), and Ca (20 nm)/Ag (10 nm) are fabricated on glass substrates through the same procedure as the device production and characterized. The wavelength-dependent transmittance and reflectance spectra of these samples are shown in Figure4. The sheet resistances of these three cathodes are also depicted in Figure 4(a). As shown in Figure 4(a), a large sheet resistance of 1.03 MΩ/□ is obtained for Ca (20 nm)/Ag (10 nm) cathode. This may be caused by that the Ag layer is still not continuous here, in accordance with the previous conclusion that the percolation threshold of Ag in our case is approximately 11 nm. Meanwhile, the discontinuous Ag layer cannot effectively protect the Ca layer from oxygen and moisture so that Ca is oxidized, which also increase the sheet resistance. The poor conductivity of this cathode leads to a very low J
SC of 0.31 mA/cm2 (shown in Table 1).(a) The wavelength-dependent transmittance spectra with corresponding sheet resistances and (b) the wavelength-dependent reflectance spectra of Ca (10 nm)/Ag (20 nm), Ca (15 nm)/Ag (15 nm), and Ca (20 nm)/Ag (10 nm) electrodes deposited on glass substrates.
(a)
(b)As shown in Figure4(a), although both Ca (10 nm)/Ag (20 nm) and Ca (15 nm)/Ag (15 nm) cathodes show good conductivity with a low sheet resistance, the transparency of Ca (15 nm)/Ag (15 nm) cathode is always better than that of Ca (10 nm)/Ag (20 nm) cathode in the visible and near infrared spectral range. Thus when illuminated from the cathode side, as shown in Table 1, a higher J
SC of 1.90 mA/cm2 and a higher PCE of 0.67% are obtained for OSCs with Ca (15 nm)/Ag (15 nm) cathode, compared with that of Ca (10 nm)/Ag (20 nm) cathode (J
SC of 1.44 mA/cm2 and PCE of 0.56%).However, the situation becomes different when illuminated from the anode side. As shown in Figure4(b), Ca (10 nm)/Ag (20 nm) cathode has a stronger reflectance than Ca (15 nm)/Ag (15 nm) cathode in the nearly entire spectral range discussed. Thus when illuminated from the anode side, more light is reflected from the Ca/Ag surface and arrives at the active layer a second time for OSCs based on Ca (10 nm)/Ag (20 nm) cathode. It leads to a higher J
SC of 5.03 mA/cm2 and a higher PCE of 2.01%, compared with that of Ca (15 nm)/Ag (15 nm) cathode (J
SC of 4.70 mA/cm2 and PCE of 1.79%).Since good transparency and high PCE should be achieved simultaneously in the application of semitransparent OSCs, samples with the same stack as our devices but a larger area are fabricated. The wavelength-dependent transmittance spectra of corresponding OSCs with different thickness combination of Ca and Ag as the cathodes are shown in Figure5. For comparison, the transmittance spectrum of the stack MoO3 (2 nm)/Ag (9 nm)/MoO3 (10 nm)/P3HT:PCBM (the device without the cathode) is also depicted in Figure 5. It is observed from Figure 5 that the spectral shapes of the transmittance curves are similar for four samples. Two minimums around 500 and 600 nm represent the absorption peak of P3HT:PCBM. The transparency of OSCs based on Ca (10 nm)/Ag (20 nm) cathode is the lowest nearly across the entire spectral range, with a small transparency peak of 16% at 365 nm. It is in agreement with the results shown in Figure 4. The best transparency is obtained for OSCs with Ca (15 nm)/Ag (15 nm) cathode, with a maximum of 32% at 690 nm. Meanwhile the performance of this device (PCE of 1.79% and 0.67% for illumination from the anode and cathode side, resp.) is comparable to that of similar ITO-based semitransparent OSCs (PCE of 1.59% and 0.75% for illumination from the anode and cathode side, resp.) [10, 11]. Thus ITO-free semitransparent OSCs based on Ca (15 nm)/Ag (15 nm) cathode are more preferred for the application.Figure 5
The wavelength-dependent transmittance spectra of ITO-free semitransparent OSCs with different thickness combination of Ca and Ag as the cathodes. For comparison, the transmittance spectrum of the stack MoO3 (2 nm)/Ag (9 nm)/MoO3 (10 nm)/P3HT:PCBM (the device without the cathode) is also depicted in Figure 5. Bottom illumination from the anode side is applied for measurement.Moreover, the stability has also been investigated for ITO-free semitransparent OSCs with Ca (15 nm)/Ag (15 nm) cathode. The unencapsulated OSCs were stored in the glove box and measured in air ambient conditions. The normalized PCE as a function of time is shown in Figure6. As shown in Figure 6, PCE of the device remains 70% of the original efficiency after 262 h no matter the OSC is illuminated from the anode or cathode side. It is expected that the better stability could be obtained for our encapsulated ITO-free semitransparent OSCs by avoiding oxidation and mechanical damage.Figure 6
The variation of the normalized PCE with time.


## 4. Conclusions

In this paper, we have firstly demonstrated efficient ITO-free reference OSCs based on (MoO3)/Ag anodes. The PCE of 2.71% is obtained for OSCs based on the optimal MoO3 (2 nm)/Ag (9 nm) anode (also the highest PCE among all the ITO-free reference OSCs), comparable to that of ITO-based reference OSCs (PCE of 2.85%). Then based on this MoO3 (2 nm)/Ag (9 nm) anode, ITO-free semitransparent OSCs with different thickness combination of Ca and Ag as the cathodes are fabricated. It combines the advantages of ITO-free OSCs and semitransparent OSCs simultaneously, providing a way for commercialization of OSCs. It is observed from our results that OSCs with Ca (15 nm)/Ag (15 nm) cathode have the optimal transparency. Meanwhile, the PCE of 1.79% (illuminated from the anode side) and 0.67% (illuminated from the cathode side) is obtained, comparable to that of similar ITO-based semitransparent OSCs (PCE of 1.59% and 0.75% for illumination from the anode and cathode side, resp.) [10, 11]. Although all the devices are only fabricated on glass substrates, our method and process can also be applied to flexible substrates. Meanwhile, the transparency and PCE of ITO-free semitransparent OSCs can be further improved by introducing a light couple layer. These results are instructive for further research of ITO-free semitransparent OSCs.



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