# Multiwalled Carbon Nanotubes Reinforced Polypropylene Composite Material

Authors: Juan Li
Journal: Journal of Nanomaterials
 (2017)

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## Abstract

Polypropylene (PP) composites reinforced with multiwalled carbon nanotubes (MWNTs) were prepared by using twin screw extruder. The experimental results showed that with the increasing amount of MWNTs the elongation at break decreased whereas the tensile strength, bending strength, and impact strength increased. By using scanning electron microscope (SEM), we find that the hydroxyl-modified carbon nanotube has better dispersion performance in PP and better mechanical properties.


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## Body

## 1. Introduction

PP is one of the fastest growing varieties in the world plastics industry. PP is mainly used as packaging materials, including film and plate which occupies a large proportion of PP market. In recent years, with the increasing of PP production, PP begins to enter the field of engineering plastic. Because its strength is not strong enough, pristine PP can not be used directly as engineering plastics.In order to obtain high performance of PP materials, the pristine PP should be modified. With strong mechanical strength and ultralow density as well as larger aspect ratio, a small amount of carbon nanotubes (CNTs) can improve the mechanical strength of the polymer [1–4]. In recent years, an enormous research interest has been focused on CNTs/polymer composites [5–11]. As a kind of nanomaterial, CNT is very easy to agglomerate, which is bound to affect the mechanical strength of nanocomposites.High strength properties of CNTs/polymer composites are achieved only in the case of an existing interaction between components and the dispersion of CNTs within the matrix. Grady found that functionalized or grafted CNTs could promote CNTs dispersion [12]. Araujo et al. used the methods of in situ polymerization of monomers on the nanotubes to producing nanocomposite material with evenly dispersed CNTs [13]. Ritter et al. found that electron irradiation could improve the mechanisms of microhardness of the CNTs/PP [14]. Ghoshal et al. used the approaches of combination of solution processing and melt blending and they found that dispersion quality was notably improved in the solution processed master batch based samples [15, 16].However, it should be noted that the melt mixing is the most convenient and environmentally friendly method for preparing CNTs/polymer nanocomposites and is being used more and more in industry [17]. In this work, the PP/MWNTs nanocomposites are prepared by melt extrusion. The mechanical strength of PP/MWNTs nanocomposites is tested. And then the PP nanocomposites with hydroxyl-modified multiwalled carbon nanotubes (HO-MWNTs) are prepared. The morphology of PP nanocomposites is observed by SEM.


## 2. Experimental

### 2.1. Materials

PP resin (trade mark BJ550, Samsung Total) is used as basal material. MWNTs and HO-MWNTs are offered by Xian Feng Nano Company.


### 2.2. Preparation of PP/CNTs Nanocomposites

First, MWNTs, HO-MWNTs, and PP were dried in a vacuum oven for 12 h at 80°C to reduce volatiles. According to the formula as shown in Table1, the composites were premixed for 5 minutes at stirring speed of 2000 rpm using high speed mixer (SHR-10). Then, the mixture of nanocomposite was manufactured by twin screw extruder (CTE35). The temperature range of the extruder was from 155°C to 195°C and the shear rate was 40 rpm. Finally, put the mixture of the nanocomposite into the injection molding machine (FT-110) and mold it into standard spline.Table 1
Formulations of the nanocomposites.
Sample number
PP (wt.%)
MWNTs (wt.%)
HO-MWNTs (wt.%)
1
100
0
0
2
99.6
0.4
0
3
99.4
0.6
0
4
99.2
0.8
0
5
99
1
0
6
99
0
1


### 2.3. Testing

Tensile tests were carried out using universal testing machine (WDT-W) at the speed of 50 mm/min according to the national standard of China GB/T 1040-1992. The dimension of the dumbbell shaped samples is 10 mm × 4 mm in the narrow part. And the impact strength tests were carried out using simple beam impact tester (JC-5) according to the national standard of China GB/T 1843-2008. The dimension of the sample is 10 mm × 4 mm. For all the mechanical tests, five samples were tested and the standard deviations were calculated.Impact-fractured surfaces of the PP/MWNT nanocomposite containing 1 wt.% MWNT and HO-MWNTs were investigated by SEM using Zeiss evo18 model.


## 2.1. Materials

PP resin (trade mark BJ550, Samsung Total) is used as basal material. MWNTs and HO-MWNTs are offered by Xian Feng Nano Company.


## 2.2. Preparation of PP/CNTs Nanocomposites

First, MWNTs, HO-MWNTs, and PP were dried in a vacuum oven for 12 h at 80°C to reduce volatiles. According to the formula as shown in Table1, the composites were premixed for 5 minutes at stirring speed of 2000 rpm using high speed mixer (SHR-10). Then, the mixture of nanocomposite was manufactured by twin screw extruder (CTE35). The temperature range of the extruder was from 155°C to 195°C and the shear rate was 40 rpm. Finally, put the mixture of the nanocomposite into the injection molding machine (FT-110) and mold it into standard spline.Table 1
Formulations of the nanocomposites.
Sample number
PP (wt.%)
MWNTs (wt.%)
HO-MWNTs (wt.%)
1
100
0
0
2
99.6
0.4
0
3
99.4
0.6
0
4
99.2
0.8
0
5
99
1
0
6
99
0
1


## 2.3. Testing

Tensile tests were carried out using universal testing machine (WDT-W) at the speed of 50 mm/min according to the national standard of China GB/T 1040-1992. The dimension of the dumbbell shaped samples is 10 mm × 4 mm in the narrow part. And the impact strength tests were carried out using simple beam impact tester (JC-5) according to the national standard of China GB/T 1843-2008. The dimension of the sample is 10 mm × 4 mm. For all the mechanical tests, five samples were tested and the standard deviations were calculated.Impact-fractured surfaces of the PP/MWNT nanocomposite containing 1 wt.% MWNT and HO-MWNTs were investigated by SEM using Zeiss evo18 model.


## 3. Results and Discussion

### 3.1. Mechanical Property of PP/MWNTs Nanocomposites

The tensile strength of nanocomposites with various MWNTs contents is shown in Figure1. It can be seen that, with the increase of concentration of MWNTs, the tensile strength of the nanocomposite appears to increase as compared to the pristine PP. Tensile strength for the blends increases with increasing of MWNTs, on the one hand due to the relatively high strength of carbon tube and on the other hand due to ultra high aspect ratio of carbon tube. When subjected to an external force, the load of external force can be dispersed along the length direction of the carbon tube.Figure 1
Tensile strength of PP/MWNTs nanocomposites.In the case of elongation at break, it is decreased gradually with the increase amount of MWNTs as shown in Figure2. Elongation at break is depending on the flexibility of the molecular chain. The conformation change of polymer chain is restricted by the MWNTs, which leads to the decrease of the elongation at break.Figure 2
Elongation at break of PP/MWNTs nanocomposites.Bending strength and impact strength are an important index of engineering materials. As shown in Figure3, the bending strength of the nanocomposites increases gradually with the increase amount of MWNTs.Figure 3
Bending strength of PP/MWNTs nanocomposites.The impact strength is characterized by the destruction of the material’s ability to resist damage. One of the most important characteristics of engineering plastics is high performance of impact strength. The performance of impact strength with the increase of MWNTs content is shown in Figure4. With the increase of MWNTs content, the impact strength of the composite increased gradually. It is hypothesized that MWNTs could effectively dissipate the impact energy from the polymer matrix to the MWNTs.Figure 4
Impact strength of PP/MWNTs nanocomposites.


### 3.2. Influence of HO-MWNTs on the Performance of PP

As shown in Figures5–8, we find that adding the same amount of HO-MWNTs can improve the mechanical strength of nanocomposite compared with MWNTs. To elucidate the dispersion of MWNTs and HO-MWNTs, an analysis of nanocomposites microphotographs has been investigated in detail. Figures 9-10 show the SEM image of PP/MWNTs and PP/HO-MWNTs. AS shown in Figure 9, most of MWNTs are likely to get together. The gathering of MWNTs is very easy to form defects, which is the stress concentration point in the case of external forces. After sodium hydroxide being modified, there are a lot of hydroxyl groups on the HO-MWNTs. These hydroxyl groups could prevent the carbon tube from poly and increase the dispersion of carbon nanotubes in the composite material.Figure 5
Tensile strength of nanocomposites.Figure 6
Elongation at break of nanocomposites.Figure 7
Bending strength of nanocomposites.Figure 8
Impact strength of nanocomposites.Figure 9
SEM microphotograph of the PP/MWNTs nanocomposites.Figure 10
SEM microphotograph of the PP/HO-MWNTs nanocomposites.


## 3.1. Mechanical Property of PP/MWNTs Nanocomposites

The tensile strength of nanocomposites with various MWNTs contents is shown in Figure1. It can be seen that, with the increase of concentration of MWNTs, the tensile strength of the nanocomposite appears to increase as compared to the pristine PP. Tensile strength for the blends increases with increasing of MWNTs, on the one hand due to the relatively high strength of carbon tube and on the other hand due to ultra high aspect ratio of carbon tube. When subjected to an external force, the load of external force can be dispersed along the length direction of the carbon tube.Figure 1
Tensile strength of PP/MWNTs nanocomposites.In the case of elongation at break, it is decreased gradually with the increase amount of MWNTs as shown in Figure2. Elongation at break is depending on the flexibility of the molecular chain. The conformation change of polymer chain is restricted by the MWNTs, which leads to the decrease of the elongation at break.Figure 2
Elongation at break of PP/MWNTs nanocomposites.Bending strength and impact strength are an important index of engineering materials. As shown in Figure3, the bending strength of the nanocomposites increases gradually with the increase amount of MWNTs.Figure 3
Bending strength of PP/MWNTs nanocomposites.The impact strength is characterized by the destruction of the material’s ability to resist damage. One of the most important characteristics of engineering plastics is high performance of impact strength. The performance of impact strength with the increase of MWNTs content is shown in Figure4. With the increase of MWNTs content, the impact strength of the composite increased gradually. It is hypothesized that MWNTs could effectively dissipate the impact energy from the polymer matrix to the MWNTs.Figure 4
Impact strength of PP/MWNTs nanocomposites.


## 3.2. Influence of HO-MWNTs on the Performance of PP

As shown in Figures5–8, we find that adding the same amount of HO-MWNTs can improve the mechanical strength of nanocomposite compared with MWNTs. To elucidate the dispersion of MWNTs and HO-MWNTs, an analysis of nanocomposites microphotographs has been investigated in detail. Figures 9-10 show the SEM image of PP/MWNTs and PP/HO-MWNTs. AS shown in Figure 9, most of MWNTs are likely to get together. The gathering of MWNTs is very easy to form defects, which is the stress concentration point in the case of external forces. After sodium hydroxide being modified, there are a lot of hydroxyl groups on the HO-MWNTs. These hydroxyl groups could prevent the carbon tube from poly and increase the dispersion of carbon nanotubes in the composite material.Figure 5
Tensile strength of nanocomposites.Figure 6
Elongation at break of nanocomposites.Figure 7
Bending strength of nanocomposites.Figure 8
Impact strength of nanocomposites.Figure 9
SEM microphotograph of the PP/MWNTs nanocomposites.Figure 10
SEM microphotograph of the PP/HO-MWNTs nanocomposites.


## 4. Conclusion

Nanocomposites based on PP/MWNTs and PP/HO-MWNTs were prepared with a twin screw extruder. The nanocomposites exhibited not only improved tensile strength but also increased bending strength and impact strength. However, the elongation at break decreased with the increasing content of MWNTs. The results showed that the HO-MWNTs can further improve the tensile strength, bending strength, and impact strength of the material compared with MWNTs. The structure and morphology of the prepared samples were examined through SEM. Compared with MWNTs, HO-MWNTs could get better dispersion in nanocomposites.



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*Source: 2171356-2017-05-21.xml*