# Structure, Mechanism, and Application of Vacuum Insulation Panels in Chinese Buildings

Authors: Changhai Peng; Jianqiang Yang
Journal: Advances in Materials Science and Engineering
 (2016)

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## Abstract

Thermal insulation is one of the most used approaches to reduce energy consumption in buildings. Vacuum insulation panels (VIPs) are new thermal insulation materials that have been used in the domestic and overseas market in the last 20 years. Due to the vacuum thermal insulation technology of these new materials, their thermal conductivity can be as low as 0.004 W/(m·K) at the center of panels. In addition, VIPs that are composites with inorganic core and an envelope out of commonly three metallized PET layers and a PE sealing layer can provide B class fire resistance (their core materials are not flammable and are classified as A1). Compared with other conventional thermal insulation materials, the thermal insulation and fire resistance performances form the foundation of VIP’s applications in the construction industry. The structure and thermal insulation mechanism of VIP and their application potential and problems in Chinese buildings are described in detail.


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## Body

## 1. Introduction

Currently, building energy consumption in China has remained extremely high, reaching 33% of the total social energy consumption. In particular, the energy consumption through enclosure structures accounts for over 50% of the building energy consumption. To reduce building energy consumption, thermal insulation materials have received widespread applications. Due to their low thermal conductivity, organic thermal insulation materials have enjoyed particularly wide adoption. However, in recent years, frequent fire accidents have occurred due to these organic thermal insulation materials, for example, the Beijing Television Cultural Center fire [1] and the 2010 Shanghai fire [2]. Therefore, a thermal insulation material that combines High-Performance Thermal Insulation with fire resistance is urgently needed in the current Chinese building market.VIPs (vacuum insulation panels) are inorganic composite thermal insulation panels with a thermal conductivity as low as 0.004 W/(m·K) at the center of panels [3]. The fire behavior of core materials is dependent on the types of fibers used for structural binding in the fumed silica core. Fumed silica core VIPs are class A, but the polymer barrier material is combustible [4]. However, additional layers added can reduce the behavior in the fire tests and one can imagine that it enables structural panels to reach one-hour fire rating. Thus, these materials can meet both requirements of high-efficiency thermal insulation and fire resistance performance. Silica core VIPs primarily consist of thermal insulation with a porous rigid core and membrane wall, as shown in Figure 1. However, glass fiber VIPs are commonly added with getters. The rigid core provides support for VIP against atmospheric pressure; the membrane wall maintains the vacuum inside VIP, and the getters collect gases either leaked through the membrane or off gassed from the membrane materials [5].Figure 1
VIP [13].In the 1980s, Brown, Boverie & Cie (BBC) in Heidelberg, Germany, investigated rectangular evacuated casings filled with powders and fiber mats to insulate sodium-sulfur high-temperature batteries [6]. Applications for VIP emerged in refrigerators, freezers, shipping, and aerospace and other industries. VIPs were first applied in the building sector in Germany and Switzerland in 2001 [7]. To date, the application of VIP in the building industry has lasted approximately 15 years. The preparation of materials, production of panels, characterization of performance, and application in buildings of VIP have been investigated by different countries around the world. For example, in Germany there have been a lot of test projects with constructions implementing VIPs, both refurbished and new constructions. Some were built as early as 2001 and have been monitored on a regular basis since then. Bayerisches Zentrum für Angewandte Energieforschung (ZAE Bayern) in collaboration with various VIP producers have many interesting projects which show how the implementation of VIPs into buildings has proceeded. ZAE Bayern conducted a research project called VIP Prove, where the aim was to see how VIPs behaved under practical conditions. To choose these projects, ZAE Bayern had certain criteria which the buildings had to fulfil, giving them a score of up to 85 points, where the higher the score was, the more suitable the construction was for monitoring [6, 8]. Mandilaras et al. investigated the actual in situ hygrothermal performance of a full scale envelope insulated initially with conventional ETICS using expanded polystyrene (EPS) as an insulation material [9]. Johansson et al. explored how VIP can be used when retrofitting listed buildings to improve the thermal transmittance and moisture performance of the walls and the thermal comfort for the occupants [10]. Examples of a number of different constructions where VIP has been used in retrofitted building envelopes have been reported in the literature. During 2002–2005, the international efforts in VIP research were assembled in the IEA/ECBCS Annex 39 High-Performance Thermal Insulation (HiPTI). The project included monitoring and evaluation of 20 buildings with VIP in floors, roofs, walls, dormer windows, and other constructions [11]. In China, the government had also published the “Building Industry Standard of China” for “vacuum insulation panels for buildings” (JG/T 438-2014) on June 30, 2014 [12].


## 2. Structure of VIP

### 2.1. Core

The materials of the VIP core should possess certain characteristics. First, the materials should be porous, and the pore sizes should be small such that the contact points can be small; as a result, the thermal conduction will be reduced. Figure2 shows the cylindrical glass fibers, and Figure 3 shows the spherical gas-phase silica. Second, the materials should not fracture under high external loading. Because a pressure of 1 mbar must be maintained inside the core, the prestress of the VIP should be approximately 100 kN/m2.Figure 2
Scanning electron image (a) [13] and real image (b) (taken by authors) of glass fibers. Left image is a SEM picture of glass fiber insulation. The shape of the glass fibers is cylindrical which lead to small areas of contacts and thus small conductive heat transfer even if the material is compressed [13].
(a)
(b)Figure 3
Scanning electron image (a) [13] and real image (b) of silica powders (taken by authors).
(a)
(b)Currently, the primary types of VIP cores include foams, fibers, powders, and fiber-powder composites.Foam polymers are a type of porous foam that are lightweight, thermal insulating, sound absorbing, shockproof, and corrosion resistant [14]. Polyurethane foam has received widespread application as VIP core material. It exhibits low thermal conductivity (thermal conductivity 20–30 mW/m·K under nonvacuum) and is lightweight, easily produced, and inexpensive [15].Fiber is a high-performance inorganic material that exhibits multiple qualities, for example, noncombustibility, nontoxicity, corrosion resistance, low density, low thermal conductivity, high insulation performance, and excellent chemical stability. Fiber is produced by two main processes: centrifugal spinning and jet firing. Panels made from fibers can be used as thermal insulation materials with thermal conductivity of 32–40 mW/m·K [16]. As the material of a VIP core, the primary parameters of the fibers are type and diameter. VIP cores currently use mineral fibers and glass fibers, as shown in Figure 2. However, there are some safety and health concerns on glass fibers if they are less than 3 micrometers in diameter and greater than 20 micrometers in length [17].The powders used in VIP cores are all inorganic, nonmetallic materials, including expanded perlite, lightweight pumice, and silica. Expanded perlite is an insulation material with low thermal conductivity. At atmospheric pressure and a temperature of 77–293 K, its mean thermal conductivity is 18.5–29 mW/m·K [18]. As a VIP core material, expanded perlite exhibits advantages such as low cost. However, as a powder itself, it is extremely difficult to process and form shapes. In addition, the core is brittle and easily fractures even after forming shapes. As a VIP core material, silica includes fumed silica (also known as pyrogenic silica), precipitated silica, and silica aerogel. The first is prepared by the combustion method, whereas the latter two types are prepared by solution-phase synthesis. They all exhibit nanopore structures and therefore can reduce the thermal conductivity of gases. Figure 3 shows the fumed silica [13]. In Europe, fumed silica core VIPs have been professionalized and they have been better adapted to the needs of building applications because their aging and durability statements had been done [4].To reduce the cost of VIP cores, a low-cost composite core material was investigated in 2009 by the National Research Council Institute for Research in Construction (NRC-IRC) [19]. This core material consisted of multilayer structures of pumice and glass fiber panels (Figure 4). Two products with densities of 340 kg/m3 and 320 kg/m3 for the core materials were manufactured.Figure 4
Structure of the composite core investigated by NRC-IRC [19].Fiber-powder composites are a type of core material. Because this core material contains fiber layers, certain undesired situations, such as the restoration of the core to its original shape, can result, most commonly due to gas leakage through the membrane. If VIP made from these core materials is applied to the walls of buildings, the leakage through the membranes can lead to the surface being peeled off from the walls. Therefore, the application of these products requires further investigations.In summary, the stringent requirement for high vacuum, the negative environmental impact, and the flammability of the foam-type cores restrict their application in the thermal insulation of building walls. Although fibers possess low thermal conductivity, this VIP core material requires high vacuum. Additionally, when the vacuum disappears, the fibers will cause undesired effects, such as bulging walls. Although the conductivities of powders are higher than those of other types of core materials, powders receive more attention due to their related long expected durability. The advantages and disadvantages of different core materials are shown in Table1.Table 1
Characteristics of different core materials.
Type
Representative material
Advantages
Disadvantages
Fiber
Glass fiber
Low thermal conductivity, easy processing of ultrathin fibers, stable size, allowable contraction and expansion, being nonhygroscopic, and recoverability after contact with water
Caution during packaging, requirement of high vacuum
Foam
Foam polymer
Low thermal conductivity, lightweight, waterproofing
Requirement of instruction from technical staff, large contraction and expansion, service temperature below 350 K (77°C), flammable
Powder
Gas-phase silica, expanded perlite
Low thermal conductivity, low density, low cost, fire retardant, nontoxicity, easy to achieve vacuum
Nonelasticity under pressure, difficulty to mold


### 2.2. Membrane

The primary function of membranes is to prevent air in the external environment from entering the core and thus to maintain a high vacuum inside. Once gases enter the inner core, the inner pressure increases, which raises the thermal conductivity of the inner core. When the thermal conductivity reaches certain values, if the transient working life is used, the material reaches the end of its working life. The thickness of the VIP membrane is normally 100–200μm. VIP membranes are often divided into the sealing layer, the barrier layer, and a protective layer as seen in Figure 5 [20]. These layers are described by Alam et al. [21] and Brunner et al. [22]. The inner layer is the sealing layer. This layer seals the core material in the envelope and traditionally consists of low- or high-density polyethylene (PE). The laminate surfaces are heat-sealed by two hot bars under pressure to bond together. The middle layer is the barrier layer in the case of the aluminum foil laminate (AF) type (Figure 5) [20]. Furthermore, metallized polymer film multilayer laminates (MF) are in common usage, where the metallized coating is typically deposited on a polyethylene terephthalate (PET) film (Figure 5) [20]. The purpose of the barrier layer is to prevent water vapor and air transmission through the envelope and into the VIP core. An outer protective layer may be added, for example, for improving the fire resistance properties, and may consist of glass fiber fabric or transparent lacquer. Environmental and handling stresses may damage the panel, so sometimes an additional protective layer aims to make the panel more robust, for example, applying expanded polystyrene (EPS), extruded polystyrene (XPS), or rubber granule layers or hard polymeric plates. The material chosen for the envelope should also be able to withstand general handling through transportation and installation without tearing. The common PET layer also works as a substrate for the barrier layer due to its superior flatness for the metallization process (coating) [20].Figure 5
Illustration of an aluminum foil laminate (AF) and metallized polymer film MF [20].The membrane is the most important parameter in maintaining a long working life for the VIP. The evaluation of VIP membrane materials includes the penetration rates of gases, including those of oxygen and water vapors. The structure of the membrane material greatly affects the transmission of gases; different structures give rise to different transmission speeds. Multilayered foil coated membranes exhibit low thermal conductivity, but the penetration speed of gases is relatively high; by contrast, the penetration speed of gases is relatively low for foil layers, but the thermal conductivity is high. In summary, the application of VIP membranes requires the evaluation of synergistic effects of the foil layer and polymer layer.The penetration rate of the air barrier should be small; thus, the pyrogenic silica core VIP can last 30 to 50 years and even up to 100 years in top quality building envelopes. The International Energy Agency (IEA) has noted in its 2005 report that the penetration rate of oxygen should be controlled within the range of 0–2 cm3/(m2·day·bar) [7]. The valve depends on the size of the VIP and can only be used as an empirical value. If the inner core loses vacuum, the inner pressure will equalize with the outside atmospheric pressure, and the thermal conductivity will increase to 0.020 W/(m·K) for pyrogenic silica type of VIP cores.


### 2.3. Getter

A getter is a material that exhibits specific activity towards certain gases under certain conditions. To obtain a vacuum for the inner part of the VIP, the inner core is encapsulated by membrane materials. In a glass fiber core VIP with high vacuum requirement, getters are required to collect and remove gases because fiber core pore size is bigger than that of the fumed silica core type. The gases that penetrate to the core of the VIP primarily include N2, O, H2, CO2, and H2O. Water vapor can be removed by low-cost CaSO4 and CaO; gases such as O2, H2, CO2, and N2 can be removed by active metals, such as barium, zirconium, and the alloys of these metals. Notably, these precious metals can complex or react with water, which decreases their capacity for gas absorption. Therefore, the getter apparatus is designed to remove water vapor first and then other gases.


## 2.1. Core

The materials of the VIP core should possess certain characteristics. First, the materials should be porous, and the pore sizes should be small such that the contact points can be small; as a result, the thermal conduction will be reduced. Figure2 shows the cylindrical glass fibers, and Figure 3 shows the spherical gas-phase silica. Second, the materials should not fracture under high external loading. Because a pressure of 1 mbar must be maintained inside the core, the prestress of the VIP should be approximately 100 kN/m2.Figure 2
Scanning electron image (a) [13] and real image (b) (taken by authors) of glass fibers. Left image is a SEM picture of glass fiber insulation. The shape of the glass fibers is cylindrical which lead to small areas of contacts and thus small conductive heat transfer even if the material is compressed [13].
(a)
(b)Figure 3
Scanning electron image (a) [13] and real image (b) of silica powders (taken by authors).
(a)
(b)Currently, the primary types of VIP cores include foams, fibers, powders, and fiber-powder composites.Foam polymers are a type of porous foam that are lightweight, thermal insulating, sound absorbing, shockproof, and corrosion resistant [14]. Polyurethane foam has received widespread application as VIP core material. It exhibits low thermal conductivity (thermal conductivity 20–30 mW/m·K under nonvacuum) and is lightweight, easily produced, and inexpensive [15].Fiber is a high-performance inorganic material that exhibits multiple qualities, for example, noncombustibility, nontoxicity, corrosion resistance, low density, low thermal conductivity, high insulation performance, and excellent chemical stability. Fiber is produced by two main processes: centrifugal spinning and jet firing. Panels made from fibers can be used as thermal insulation materials with thermal conductivity of 32–40 mW/m·K [16]. As the material of a VIP core, the primary parameters of the fibers are type and diameter. VIP cores currently use mineral fibers and glass fibers, as shown in Figure 2. However, there are some safety and health concerns on glass fibers if they are less than 3 micrometers in diameter and greater than 20 micrometers in length [17].The powders used in VIP cores are all inorganic, nonmetallic materials, including expanded perlite, lightweight pumice, and silica. Expanded perlite is an insulation material with low thermal conductivity. At atmospheric pressure and a temperature of 77–293 K, its mean thermal conductivity is 18.5–29 mW/m·K [18]. As a VIP core material, expanded perlite exhibits advantages such as low cost. However, as a powder itself, it is extremely difficult to process and form shapes. In addition, the core is brittle and easily fractures even after forming shapes. As a VIP core material, silica includes fumed silica (also known as pyrogenic silica), precipitated silica, and silica aerogel. The first is prepared by the combustion method, whereas the latter two types are prepared by solution-phase synthesis. They all exhibit nanopore structures and therefore can reduce the thermal conductivity of gases. Figure 3 shows the fumed silica [13]. In Europe, fumed silica core VIPs have been professionalized and they have been better adapted to the needs of building applications because their aging and durability statements had been done [4].To reduce the cost of VIP cores, a low-cost composite core material was investigated in 2009 by the National Research Council Institute for Research in Construction (NRC-IRC) [19]. This core material consisted of multilayer structures of pumice and glass fiber panels (Figure 4). Two products with densities of 340 kg/m3 and 320 kg/m3 for the core materials were manufactured.Figure 4
Structure of the composite core investigated by NRC-IRC [19].Fiber-powder composites are a type of core material. Because this core material contains fiber layers, certain undesired situations, such as the restoration of the core to its original shape, can result, most commonly due to gas leakage through the membrane. If VIP made from these core materials is applied to the walls of buildings, the leakage through the membranes can lead to the surface being peeled off from the walls. Therefore, the application of these products requires further investigations.In summary, the stringent requirement for high vacuum, the negative environmental impact, and the flammability of the foam-type cores restrict their application in the thermal insulation of building walls. Although fibers possess low thermal conductivity, this VIP core material requires high vacuum. Additionally, when the vacuum disappears, the fibers will cause undesired effects, such as bulging walls. Although the conductivities of powders are higher than those of other types of core materials, powders receive more attention due to their related long expected durability. The advantages and disadvantages of different core materials are shown in Table1.Table 1
Characteristics of different core materials.
Type
Representative material
Advantages
Disadvantages
Fiber
Glass fiber
Low thermal conductivity, easy processing of ultrathin fibers, stable size, allowable contraction and expansion, being nonhygroscopic, and recoverability after contact with water
Caution during packaging, requirement of high vacuum
Foam
Foam polymer
Low thermal conductivity, lightweight, waterproofing
Requirement of instruction from technical staff, large contraction and expansion, service temperature below 350 K (77°C), flammable
Powder
Gas-phase silica, expanded perlite
Low thermal conductivity, low density, low cost, fire retardant, nontoxicity, easy to achieve vacuum
Nonelasticity under pressure, difficulty to mold


## 2.2. Membrane

The primary function of membranes is to prevent air in the external environment from entering the core and thus to maintain a high vacuum inside. Once gases enter the inner core, the inner pressure increases, which raises the thermal conductivity of the inner core. When the thermal conductivity reaches certain values, if the transient working life is used, the material reaches the end of its working life. The thickness of the VIP membrane is normally 100–200μm. VIP membranes are often divided into the sealing layer, the barrier layer, and a protective layer as seen in Figure 5 [20]. These layers are described by Alam et al. [21] and Brunner et al. [22]. The inner layer is the sealing layer. This layer seals the core material in the envelope and traditionally consists of low- or high-density polyethylene (PE). The laminate surfaces are heat-sealed by two hot bars under pressure to bond together. The middle layer is the barrier layer in the case of the aluminum foil laminate (AF) type (Figure 5) [20]. Furthermore, metallized polymer film multilayer laminates (MF) are in common usage, where the metallized coating is typically deposited on a polyethylene terephthalate (PET) film (Figure 5) [20]. The purpose of the barrier layer is to prevent water vapor and air transmission through the envelope and into the VIP core. An outer protective layer may be added, for example, for improving the fire resistance properties, and may consist of glass fiber fabric or transparent lacquer. Environmental and handling stresses may damage the panel, so sometimes an additional protective layer aims to make the panel more robust, for example, applying expanded polystyrene (EPS), extruded polystyrene (XPS), or rubber granule layers or hard polymeric plates. The material chosen for the envelope should also be able to withstand general handling through transportation and installation without tearing. The common PET layer also works as a substrate for the barrier layer due to its superior flatness for the metallization process (coating) [20].Figure 5
Illustration of an aluminum foil laminate (AF) and metallized polymer film MF [20].The membrane is the most important parameter in maintaining a long working life for the VIP. The evaluation of VIP membrane materials includes the penetration rates of gases, including those of oxygen and water vapors. The structure of the membrane material greatly affects the transmission of gases; different structures give rise to different transmission speeds. Multilayered foil coated membranes exhibit low thermal conductivity, but the penetration speed of gases is relatively high; by contrast, the penetration speed of gases is relatively low for foil layers, but the thermal conductivity is high. In summary, the application of VIP membranes requires the evaluation of synergistic effects of the foil layer and polymer layer.The penetration rate of the air barrier should be small; thus, the pyrogenic silica core VIP can last 30 to 50 years and even up to 100 years in top quality building envelopes. The International Energy Agency (IEA) has noted in its 2005 report that the penetration rate of oxygen should be controlled within the range of 0–2 cm3/(m2·day·bar) [7]. The valve depends on the size of the VIP and can only be used as an empirical value. If the inner core loses vacuum, the inner pressure will equalize with the outside atmospheric pressure, and the thermal conductivity will increase to 0.020 W/(m·K) for pyrogenic silica type of VIP cores.


## 2.3. Getter

A getter is a material that exhibits specific activity towards certain gases under certain conditions. To obtain a vacuum for the inner part of the VIP, the inner core is encapsulated by membrane materials. In a glass fiber core VIP with high vacuum requirement, getters are required to collect and remove gases because fiber core pore size is bigger than that of the fumed silica core type. The gases that penetrate to the core of the VIP primarily include N2, O, H2, CO2, and H2O. Water vapor can be removed by low-cost CaSO4 and CaO; gases such as O2, H2, CO2, and N2 can be removed by active metals, such as barium, zirconium, and the alloys of these metals. Notably, these precious metals can complex or react with water, which decreases their capacity for gas absorption. Therefore, the getter apparatus is designed to remove water vapor first and then other gases.


## 3. Thermal Insulation Mechanism of VIP

In conventional thermal insulation materials, the contributions of the three heat transfer mechanisms to the thermal conductivity vary. As shown in Figure6, solid heat transfer increases linearly with an increase in the bulk density. In contrast, radiation transfer decreases with an increase in the bulk density; for example, when the density is approximately 200 kg/m3, the increase in the thermal conductivity due to radiation transfer is approximately 1–3 mW/m·K. Finally, gas heat transfer is responsible for the majority of the total heat transfer, with values between 20 and 30 mW/m·K. Therefore, if the gas heat transfer is decreased, the thermal conductivity of the materials will decrease dramatically. This relationship explains why special vacuum processing is used in VIP.Figure 6
Comparison of the three heat transfer mechanisms in conventional thermal insulation materials [7].The total thermal conductivity of the VIP inner core can be described as(1)
λ
C
=
λ
S
+
λ
R
+
λ
G
+
λ
C
ν
+
λ
c
o
u
p
, where λ
S is the solid heat transfer (W/(m·K)), λ
R is the radiation heat transfer (W/(m·K)), λ
G is the gas heat transfer (W/(m·K)), λ
C
ν is the gas convection inside the openings (W/(m·K)), and λ
c
o
u
p is the heat transfer from the coupled effect (W/(m·K)).


### 3.1. Solid Heat Transfer

Solid heat transfer in the core materials occurs on the necks through the physical contact between particles. The magnitude of this transfer is determined by the structure, density, and external pressure of the materials. The following equation expresses the relationship between the thermal conductivity of solids and the density of materials [23]:(2)
λ
S
=
ρ
α
,where ρ is the density (kg/m3) and index α is a constant for foam materials and 1.5–2 nm class materials.It can be seen from (2) that the smaller the density, the smaller the thermal conductivity of the solids.Gas-phase silica will be used as an example of a VIP core material; the powder is assumed to consist of spherical particles. The decrease inλ
S can be explained in two ways. First, for the close-packed spherical particles, the orientation of contact between two spherical particles is different from the normal direction of the boundary spherical particles, which results in the tortuosity of heat transfer and the increase in the number of heat transfer pathways. Second, each contact between the spherical particles is a point contact, which increases the thermal resistance [14]. Brodt [24] and Kwon et al. [14] reported that the porosity of core materials also has a large effect on the thermal conductivity of solids, as shown in Figure 7. The figure shows that maintaining high porosity (i.e., low density) can further decrease the thermal conductivity of solids for the core materials.Figure 7
Relationship between the porosity and thermal conductivity of solids for VIP core materials.


### 3.2. Gas Heat Transfer

The gas heat transfer is referred to as the sum of gas conduction transfer and convection transfer. Its magnitude is determined by the mean free path of gas and the ratio of the path to the material pore size. Kaganer [25] proposed the following equation to calculate the gas thermal conductivity λ
G:(3)
λ
G
=
λ
0
1
+
2
β
K
n
, where λ
0 denotes the thermal conductivity of air under atmospheric pressure [W/(m·K)], β is an index that combines the activity coefficient and the inert coefficient of gases, and K
n denotes the Knudsen coefficient, where its value is the ratio of the mean free path of the gas to the diameter of the pores and can be represented by(4)
K
n
=
1
Φ
=
k
B
T
2
ϕ
d
2
p
Φ
,where k
B is the Boltzmann constant (1.38  × 10−23 JK−1), T is the thermodynamic temperature (K), d is the diameter of molecules (m), and P is the gas pressure (Pa).Kwon et al. [14] proposed the following equation to calculate the gas thermal conductivity of air at 25°C (β
=
0.0016
/
P):(5)
λ
G
=
λ
0
1
+
0.0032
/
P
Φ
,where P denotes the gas pressure (Pa) and Φ is the pore size of the porous thermal insulation material (m).From (5), the relationship between the gas thermal conductivity of different porosity and pressure can be calculated, as shown in Figure 8. It can be seen from Figure 8 that, for the materials whose pore size is in the nanometer range, their thermal conductivity under atmospheric pressure can be neglected. However, it cannot be ignored under large pressure such as 105 Pa. Additionally, as the pore size increases, smaller pressure is required to maintain the small gas thermal conductivity.Figure 8
Relationship between the gas thermal conductivity and the atmospheric pressure and pore diameter [14].


### 3.3. Radiation Heat Transfer

The following heat equation expresses radiation heat transfer in VIP [26]:(6)
q
R
=
-
16
n
2
k
B
T
3
3
K
d
T
d
x
=
-
16
n
2
k
B
T
3
3
e
T
ρ
d
T
d
x
,where K denotes the extinction coefficient of materials (m−1), K
=
e
T
·
ρ, e
(
T
) denotes the specific extinction coefficient (m2/kg), ρ denotes the material density (kg/m3), and n denotes the refractive index.From the relationship between the heat flux and temperature gradient in (6), the thermal conductivity due to radiation heat transfer can be obtained [26]: (7)
λ
R
=
16
n
2
k
B
T
3
3
K
=
16
n
2
k
B
T
3
3
e
T
ρ
.Using gas-phase silica, Brodt [24] summarized the relationship between the radiation thermal conductivity and temperature, as shown in Figure 9. It can be seen from Figure 9 that when the temperature is below 150 K, the radiation thermal conductivity is extremely small and can be neglected.Figure 9
Relationship between the radiation thermal conductivity and temperature for gas-phase silica.The addition of opacifiers to the core material can weaken the radiation heat transfer. Fricke noted that, at room temperature, the total thermal conductivity of pure silicon is 0.002–0.003 W/(m·K) higher than that of silicon with added opacifiers [7].


### 3.4. Convection

Once gases flow, heat will be transferred through convection. Convection is the transfer of heat from one place to another by the movement of gases or liquids. The most common convection medium in buildings is moist air. The penetration of moist air to enclosure structures is often accompanied by heat transfer. In addition, the heat transfer between the materials themselves and the surrounding air is normally conducted through convection.Therefore, weakening of the gas thermal conductivity is the most effective way to reduce the total thermal conductivity. In VIP structure, by using membrane materials, the gas can be excluded from the main inner vacuum. This approach eliminates gas thermal conductivity.


## 3.1. Solid Heat Transfer

Solid heat transfer in the core materials occurs on the necks through the physical contact between particles. The magnitude of this transfer is determined by the structure, density, and external pressure of the materials. The following equation expresses the relationship between the thermal conductivity of solids and the density of materials [23]:(2)
λ
S
=
ρ
α
,where ρ is the density (kg/m3) and index α is a constant for foam materials and 1.5–2 nm class materials.It can be seen from (2) that the smaller the density, the smaller the thermal conductivity of the solids.Gas-phase silica will be used as an example of a VIP core material; the powder is assumed to consist of spherical particles. The decrease inλ
S can be explained in two ways. First, for the close-packed spherical particles, the orientation of contact between two spherical particles is different from the normal direction of the boundary spherical particles, which results in the tortuosity of heat transfer and the increase in the number of heat transfer pathways. Second, each contact between the spherical particles is a point contact, which increases the thermal resistance [14]. Brodt [24] and Kwon et al. [14] reported that the porosity of core materials also has a large effect on the thermal conductivity of solids, as shown in Figure 7. The figure shows that maintaining high porosity (i.e., low density) can further decrease the thermal conductivity of solids for the core materials.Figure 7
Relationship between the porosity and thermal conductivity of solids for VIP core materials.


## 3.2. Gas Heat Transfer

The gas heat transfer is referred to as the sum of gas conduction transfer and convection transfer. Its magnitude is determined by the mean free path of gas and the ratio of the path to the material pore size. Kaganer [25] proposed the following equation to calculate the gas thermal conductivity λ
G:(3)
λ
G
=
λ
0
1
+
2
β
K
n
, where λ
0 denotes the thermal conductivity of air under atmospheric pressure [W/(m·K)], β is an index that combines the activity coefficient and the inert coefficient of gases, and K
n denotes the Knudsen coefficient, where its value is the ratio of the mean free path of the gas to the diameter of the pores and can be represented by(4)
K
n
=
1
Φ
=
k
B
T
2
ϕ
d
2
p
Φ
,where k
B is the Boltzmann constant (1.38  × 10−23 JK−1), T is the thermodynamic temperature (K), d is the diameter of molecules (m), and P is the gas pressure (Pa).Kwon et al. [14] proposed the following equation to calculate the gas thermal conductivity of air at 25°C (β
=
0.0016
/
P):(5)
λ
G
=
λ
0
1
+
0.0032
/
P
Φ
,where P denotes the gas pressure (Pa) and Φ is the pore size of the porous thermal insulation material (m).From (5), the relationship between the gas thermal conductivity of different porosity and pressure can be calculated, as shown in Figure 8. It can be seen from Figure 8 that, for the materials whose pore size is in the nanometer range, their thermal conductivity under atmospheric pressure can be neglected. However, it cannot be ignored under large pressure such as 105 Pa. Additionally, as the pore size increases, smaller pressure is required to maintain the small gas thermal conductivity.Figure 8
Relationship between the gas thermal conductivity and the atmospheric pressure and pore diameter [14].


## 3.3. Radiation Heat Transfer

The following heat equation expresses radiation heat transfer in VIP [26]:(6)
q
R
=
-
16
n
2
k
B
T
3
3
K
d
T
d
x
=
-
16
n
2
k
B
T
3
3
e
T
ρ
d
T
d
x
,where K denotes the extinction coefficient of materials (m−1), K
=
e
T
·
ρ, e
(
T
) denotes the specific extinction coefficient (m2/kg), ρ denotes the material density (kg/m3), and n denotes the refractive index.From the relationship between the heat flux and temperature gradient in (6), the thermal conductivity due to radiation heat transfer can be obtained [26]: (7)
λ
R
=
16
n
2
k
B
T
3
3
K
=
16
n
2
k
B
T
3
3
e
T
ρ
.Using gas-phase silica, Brodt [24] summarized the relationship between the radiation thermal conductivity and temperature, as shown in Figure 9. It can be seen from Figure 9 that when the temperature is below 150 K, the radiation thermal conductivity is extremely small and can be neglected.Figure 9
Relationship between the radiation thermal conductivity and temperature for gas-phase silica.The addition of opacifiers to the core material can weaken the radiation heat transfer. Fricke noted that, at room temperature, the total thermal conductivity of pure silicon is 0.002–0.003 W/(m·K) higher than that of silicon with added opacifiers [7].


## 3.4. Convection

Once gases flow, heat will be transferred through convection. Convection is the transfer of heat from one place to another by the movement of gases or liquids. The most common convection medium in buildings is moist air. The penetration of moist air to enclosure structures is often accompanied by heat transfer. In addition, the heat transfer between the materials themselves and the surrounding air is normally conducted through convection.Therefore, weakening of the gas thermal conductivity is the most effective way to reduce the total thermal conductivity. In VIP structure, by using membrane materials, the gas can be excluded from the main inner vacuum. This approach eliminates gas thermal conductivity.


## 4. Application Potential of VIP in Chinese Buildings

Currently, two types of thermal insulation materials are used to building walls, that is, inorganic and organic thermal insulation materials. Inorganic insulation materials include Rockwool, glass fiber, calcium silicate, and foam concrete, and organic insulation materials include expanded polystyrene (EPS), extruded polystyrene (XPS), and polyurethane (PU) foams. The thermal conductivity of inorganic thermal insulation materials is normally larger than that of organic thermal insulation materials, resulting in poorer insulation performance. However, the fire resistance performance of organic insulation materials is poor. Figure10 and Table 2 list the thermal insulation materials on the market and their advantages and disadvantages. Therefore, compared with these materials, what is distinctive about VIP? The thermal performance, durability, physical properties, economy, and environmental impact of the materials are compared in Table 2.Table 2
Comparison of the thermal performance of VIP and other thermal insulation materials [4].
Materials
Thermal conductivitymW/(m·K)
Cuttable?
Fire resistance, waterproofing, and corrosion resistance
Prevention of physical injuries
Performance after penetration
Cost of unit heat resistance
Environmental impact
VIP
4–8
No
Low
Low
Weakened
High
Medium
Conventional thermal insulation materials
Stone wool
34–50
Yes
High
High
No change
Low
Low
Glass fiber
30–40
Yes
High
High
No change
Low
Medium
Foam concrete
70–80
Yes
High
High
No change
Low
Medium
EPS
30–40
Yes
Low
Medium
No change
Low
High
XPS
30–32
Yes
Medium
Medium
No change
High
High
Polyurethane
20–30
Yes
Medium
High
No change
High
High
State-of-the-art insulation materials
Gas panel
10–40
No
Low
Low
Weakened
High
Medium
Aerogel
13-14
Yes
Medium
Low
No change
High
MediumFigure 10
Classification of commonly used thermal insulation materials for buildings and their advantages and disadvantages.It can be seen from Table2 that the thermal conductivity of VIP is much lower than that of other conventional insulation materials. According to the Chinese “design standard for energy efficiency of residential buildings in hot summer and cold winter zone,” when the shape factor is >0.4, the total U-value of external walls is smaller than 0.8 W/(m2·K) [27].A Shanxi Datong residential building with a construction area of 100 m2 and a length and width of 10 m will be used as an example. In EnergyPlus, if the indoor electrical equipment and layout, people density, and timetable are same, a change in the wall insulation material from XPS to VIP of the same thickness will reduce the annual electricity consumption by 20.3%, or the indoor net residential area can be increased by 2% while maintaining the same annual electricity consumption. Therefore, there is a huge potential for VIP application in high-performance buildings.


## 5. Problems in the Application of VIP in Chinese Buildings

The introduction, development, and application of VIP products have only been performed for approximately twenty years, and VIP research in China just began a few years ago. There are many theoretical investigations into the production performance, heat transfer, and aging of VIP. However, investigating VIP application in buildings is rare, and there are extremely few examples of the application of VIP to buildings worldwide. Although there is a huge potential for VIP application in Chinese buildings, many problems exist.


### 5.1. Failure by Puncturing

The VIP production process is complex, involving vacuum pumping and heat sealing. Therefore, once the products are molded, they cannot be cut. However, in the application process to real walls, it is difficult to manufacture a single-sized VIP for special positions, such as corners and surroundings of windows. Therefore, in the design stage, different VIP sizes are required. Compared with other cuttable materials, this aspect represents a major restriction on VIP applications. Additionally, during transportation, storage at a construction site, construction, and even delivery to use, the outer membranes of VIP can be easily punctured and thus cause the loss of the vacuum, which greatly increases the thermal conductivity of VIP. Binz et al. [11] reported in 2005 that, given that the surface of VIP can be easily punctured and lose its vacuum, the thermal conductivity of a punctured VIP is 5 times that of an intact VIP. However, most VIP constructions currently are mounted on the building sites. The storage at construction sites is random and chaotic; therefore, there exist many unpredictable factors that can easily puncture the VIP, leading to the loss of its function. Figure 11 shows the storage of VIP at a construction site, and Figure 12 shows the comparison of VIP before and after puncture.Figure 11
VIP at construction site.Figure 12
Comparison of VIP before and after puncture and loss of vacuum in China.
(a)
Before loss of vacuum
(b)
After loss of vacuum


### 5.2. Heat Bridge

When VIP performance is discussed, normally, only the thermal conductivity at the center of the panels has been taken into account. However, in real applications, it is more appropriate to consider the effective thermal conductivity by taking into account the heat bridge effects surrounding the VIP. In real applications, a heat bridge can be observed with three layers, that is,(
1
) VIP layer, (
2
) building component layer, and (
3
) building façade layer [28]. The heat bridge of a VIP layer is induced by the huge difference in thermal conductivity between the vacuumed core material and outer membrane, as shown in Figure 13.Figure 13
Heat bridge effect surrounding the VIP.The linear thermal conductivity of the VIP boundary is related to the thickness, circumference, and surface area of the panels. The effective thermal conductivity of a VIP can be calculated with the following equation [29]:(8)
λ
e
f
f
=
λ
c
o
p
+
Ψ
V
I
P
e
d
g
e
·
d
p
·
l
p
S
p
,where λ
c
o
p denotes the thermal conductivity of the VIP panel center (W/(m·K)), Ψ
V
I
P
e
d
g
e denotes the linear thermal conductivity (W/(m·K)), λ
e
f
f denotes the effective thermal conductivity, d
p denotes the thickness of the VIP (m), l
p denotes the circumference of boundaries, and  S
p denotes the surface area.It can be seen from Figure14 that because the VIP sizes cannot be large, many VIPs must be combined for the façade of the entire building, resulting in a large number of joints. The heat bridge effects at the joints on the entire walls cannot be ignored.Figure 14
VIP at the façade of building.


### 5.3. VIP Cannot Be Anchored and Perforated

Currently, the thermal insulation of the outer walls by VIP requires bonding or a combination of bonding and anchorage. For high-rise buildings, due to the large area, the combination of bonding and anchorage is commonly used, as shown in Figures15 and 16. Insulation nails are used to secure the joining areas of four adjacent VIPs.Figure 15
Anchorage of VIP.Figure 16
Actual images of VIP anchored by insulation nails.Because a VIP cannot be perforated, the anchorage position cannot be as flexible as the conventional insulation materials. Because the anchorage is implemented at the boundaries, it will result in larger gaps between adjacent VIPs and thus create more heat losses.In addition, there are many openings on the wall, for example, air louvers, entrance holes for electrical lines and water pipelines, and drainage holes. These positions will cause much difficulty in the application of VIP. Therefore, some parts of the building envelopes still need to be done with other cuttable insulation materials.When VIPs are used as insulation materials inside walls, the problems associated with nonanchorage and nonperforation become more pronounced. Once construction is complete, no nails can be applied to the surface of the entire wall for a suspended wall cupboard, household appliances, and hooks; these basic setups cannot be avoided in Chinese homes. Particularly, after a long period of time or a change of ownership, these problems will become more obvious for the second interior decoration.Boafo et al. proposed an improved solution which might be possible to address these problems. Figure17 described a sectional view of an insulated wall system showing the material layers [30].Figure 17
Assembly of vacuum insulation system: (a) cross section and (b) pictorial view of insulated wall [30].VA-Q-TEC [31] proposed a solution, as shown in Figure 18. During VIP production, circular, semicircular, or unusually shaped holes are reserved. In those special locations on the wall, these VIP products with optimized shapes for special needs can be used to complement the aforementioned regular VIP.Figure 18
VIP with holes or opening.However, due to the exceptionally low thermal conductivity, only extremely thin VIP will be able to meet requirements in real applications. Therefore, their thermal insulation capability is lost in those anchorage holes, resulting in severe heat bridges. As such, the usage of these VIPs with holes or opening requires compromise. These VIPs can only be used in the places that require them, such as air louvers and line and wire holes.


## 5.1. Failure by Puncturing

The VIP production process is complex, involving vacuum pumping and heat sealing. Therefore, once the products are molded, they cannot be cut. However, in the application process to real walls, it is difficult to manufacture a single-sized VIP for special positions, such as corners and surroundings of windows. Therefore, in the design stage, different VIP sizes are required. Compared with other cuttable materials, this aspect represents a major restriction on VIP applications. Additionally, during transportation, storage at a construction site, construction, and even delivery to use, the outer membranes of VIP can be easily punctured and thus cause the loss of the vacuum, which greatly increases the thermal conductivity of VIP. Binz et al. [11] reported in 2005 that, given that the surface of VIP can be easily punctured and lose its vacuum, the thermal conductivity of a punctured VIP is 5 times that of an intact VIP. However, most VIP constructions currently are mounted on the building sites. The storage at construction sites is random and chaotic; therefore, there exist many unpredictable factors that can easily puncture the VIP, leading to the loss of its function. Figure 11 shows the storage of VIP at a construction site, and Figure 12 shows the comparison of VIP before and after puncture.Figure 11
VIP at construction site.Figure 12
Comparison of VIP before and after puncture and loss of vacuum in China.
(a)
Before loss of vacuum
(b)
After loss of vacuum


## 5.2. Heat Bridge

When VIP performance is discussed, normally, only the thermal conductivity at the center of the panels has been taken into account. However, in real applications, it is more appropriate to consider the effective thermal conductivity by taking into account the heat bridge effects surrounding the VIP. In real applications, a heat bridge can be observed with three layers, that is,(
1
) VIP layer, (
2
) building component layer, and (
3
) building façade layer [28]. The heat bridge of a VIP layer is induced by the huge difference in thermal conductivity between the vacuumed core material and outer membrane, as shown in Figure 13.Figure 13
Heat bridge effect surrounding the VIP.The linear thermal conductivity of the VIP boundary is related to the thickness, circumference, and surface area of the panels. The effective thermal conductivity of a VIP can be calculated with the following equation [29]:(8)
λ
e
f
f
=
λ
c
o
p
+
Ψ
V
I
P
e
d
g
e
·
d
p
·
l
p
S
p
,where λ
c
o
p denotes the thermal conductivity of the VIP panel center (W/(m·K)), Ψ
V
I
P
e
d
g
e denotes the linear thermal conductivity (W/(m·K)), λ
e
f
f denotes the effective thermal conductivity, d
p denotes the thickness of the VIP (m), l
p denotes the circumference of boundaries, and  S
p denotes the surface area.It can be seen from Figure14 that because the VIP sizes cannot be large, many VIPs must be combined for the façade of the entire building, resulting in a large number of joints. The heat bridge effects at the joints on the entire walls cannot be ignored.Figure 14
VIP at the façade of building.


## 5.3. VIP Cannot Be Anchored and Perforated

Currently, the thermal insulation of the outer walls by VIP requires bonding or a combination of bonding and anchorage. For high-rise buildings, due to the large area, the combination of bonding and anchorage is commonly used, as shown in Figures15 and 16. Insulation nails are used to secure the joining areas of four adjacent VIPs.Figure 15
Anchorage of VIP.Figure 16
Actual images of VIP anchored by insulation nails.Because a VIP cannot be perforated, the anchorage position cannot be as flexible as the conventional insulation materials. Because the anchorage is implemented at the boundaries, it will result in larger gaps between adjacent VIPs and thus create more heat losses.In addition, there are many openings on the wall, for example, air louvers, entrance holes for electrical lines and water pipelines, and drainage holes. These positions will cause much difficulty in the application of VIP. Therefore, some parts of the building envelopes still need to be done with other cuttable insulation materials.When VIPs are used as insulation materials inside walls, the problems associated with nonanchorage and nonperforation become more pronounced. Once construction is complete, no nails can be applied to the surface of the entire wall for a suspended wall cupboard, household appliances, and hooks; these basic setups cannot be avoided in Chinese homes. Particularly, after a long period of time or a change of ownership, these problems will become more obvious for the second interior decoration.Boafo et al. proposed an improved solution which might be possible to address these problems. Figure17 described a sectional view of an insulated wall system showing the material layers [30].Figure 17
Assembly of vacuum insulation system: (a) cross section and (b) pictorial view of insulated wall [30].VA-Q-TEC [31] proposed a solution, as shown in Figure 18. During VIP production, circular, semicircular, or unusually shaped holes are reserved. In those special locations on the wall, these VIP products with optimized shapes for special needs can be used to complement the aforementioned regular VIP.Figure 18
VIP with holes or opening.However, due to the exceptionally low thermal conductivity, only extremely thin VIP will be able to meet requirements in real applications. Therefore, their thermal insulation capability is lost in those anchorage holes, resulting in severe heat bridges. As such, the usage of these VIPs with holes or opening requires compromise. These VIPs can only be used in the places that require them, such as air louvers and line and wire holes.


## 6. Conclusions

The selection of VIP core materials, membranes, and their construction is based on certain thermal insulation mechanism. Inner core materials with porosity, excellent frame geometrics, and lightweight, such as glass fiber and silica, can effectively reduce solid heat transfer. High porosity ensures that the inner part can be vacuumed, whereas the membrane will ensure the maintenance of the high vacuum inside, which essentially prevents gas convection from occurring inside the material. The metal foils and multilayered metallized polymer membranes can maximally reduce the gas penetration to the inside and the loss of vacuum; therefore, the reduction of gas thermal conductivity is further enhanced. The getters inside the VIP can collect and remove gases either leaked through the membrane or off gassed from the membrane materials over time. The low thermal conductivity of VIP is attributed to the reduction of thermal conductivity and radiation.In real buildings, due to the low thermal conductivity, extremely thin VIP will be able to meet the standard requirements. This capacity will drastically reduce the wall thickness and increase the indoor usage area. If the same thickness of VIP and conventional insulation materials are used, the usage of VIP will drastically reduce energy consumption from air conditioning in buildings.However, at present, several problems exist in the application of VIP in Chinese buildings.(1)
Failure: the membrane of a VIP can be easily damaged by puncturing, ripping, or squeezing, resulting in vacuum leakage and a drastic decrease in the thermal insulation performance.
(2)
Heat bridge: because the VIP membrane contains a foil layer, such as aluminum foil, heat is easily transferred at the boundaries of the VIP panels, which creates natural heat bridges.
(3)
Noncuttability: the size of the VIP panels cannot be changed once manufactured, and the panels cannot be cut on-site according to real applications. As a result, arranging VIP on walls becomes a complex and difficult task.
(4)
Nonanchorage and nonperforation: in the construction process, VIP cannot be perforated. As a result, the means to apply VIP to walls are extremely limited.Overall, VIPs are thermal insulation materials with distinct advantages and disadvantages. If not appropriately used, their advantages cannot be fully utilized, and their disadvantages will dominate. Problems exist for VIP. If the problems are addressed alone, other problems could result. Therefore, the VIP thermal insulation system should be considered as an integral part. The material, structure, system, and their relationship must be systematically considered. Based on the real conditions and different building types, the problem must be addressed systemically to provide solutions.



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*Source: 1358072-2016-05-19.xml*