# Effective Utilization of Synthesized FeS2 for Improving Output Performance of Polycrystalline Silicon Solar Cell

Authors: Moganapriya Chinnasamy; Rajasekar Rathanasamy; Santhosh Sivaraj; Gobinath Velu Kaliyannan; Manivasakan Palanisamy; Samir Kumar Pal; Md. Elias Uddin
Journal: Advances in Materials Science and Engineering
 (2022)

---

## Abstract

Solar cells are capable of converting light energy into electrical energy and can completely replace the utilization of fossil fuel energy resources. The current research work majorly concentrates on the development and coating of antireflection materials over the front contact of silicon solar cells. Ferrous disulphide was one of the wide band gap semiconductors employed as a catalytic electrode (in DSSCs), counter electrode (in QDSSs), and solar energy harvester. FeS2 was synthesized through the hydrothermal method. The antireflective coating was performed over solar cells through the electrospraying technique. It was found that the antireflective material was distributed evenly over the coating substrate at 2 ml/h for 30 (F1), 60 (F2), 90 (F3), and 120 (F4) min. The coated solar cells were examined under neodymium light illumination mimicking sunlight. The effect of electrosprayed FeS2 films adhered over the front contact of solar cells was evaluated using various characterization techniques. The maximum efficiency attained by coated solar cells under indirect light was 19.6%. With the aid of electrospraying, hydrothermally synthesized FeS2 assists incoming photons with energy greater than the bandgap of a procured Si solar cell to take part in the photogeneration process. The maximum Isc and Voc of 38.08 mA/cm2 and 0.655 V were achieved for the F3 solar cell under neodymium irradiation.


---

## Body

## 1. Introduction

In the present situation, the global population and energy consumption are increasing rapidly. This leads to excessive consumption of limited fossil fuel resources, which delivers toxic gases and pollutes the global atmosphere. Researchers were on the verge of identifying and adopting an alternate energy resource with long-term sustainability, the absence of toxic gas emissions during photocurrent generation, and eco-friendly energy generation [1–3]. Solar energy was one of the promising candidates because it is copious, consistent, and delivers sustainable energy to the present and future world. It can be effectively converted and utilized as heat and electrical energy. With the adaption of solar photovoltaic technology, global electrical energy needs can be easily achieved and do not impose a greenhouse effect on the global atmosphere as compared to conventional energy sources. According to the NREL efficiency chart, a polycrystalline silicon solar cell delivers a higher power output of 23.2%. In India, polycrystalline Si solar cells were preferred mostly for both industrial and domestic purposes because of their low cost, higher power conversion efficiency, and longer working life [4].Even though polycrystalline Si solar cells deliver higher power output, some of the notable performance inhibitors were reflection loss, thermal loss, recombination loss, and resistive loss. Among the mentioned losses, reflection loss hinders the electron-hole generation process to a greater extent. Antireflective surface coatings over front contact surfaces have the ability to increase short-circuit current along with a sequential decrease in reflectivity of incident light [5]. Antireflective materials should be transparent, have wide bandgap semiconductors, and have a low cost [6–8]. The optimal refractive index of the anti-reflective material was essential to trap the reflected photons. Materials with similar anti-reflective properties utilized for improving light transmittance were MoSe2, ZnAl2O4, MnFe2O4, CaTiO3, MoS2, SiO2, TiO2, SiO2/TiO2, ZnAl2S4, MoS2, Ta2O5, etc. [9–12]. The transmittance of incident light increases with multilayered coatings, until it achieves optimal thickness. Further coating of material leads to incremental scattering of incident light. The major reason for the drop in cell performance was the cluster formation of coating material [2, 9].Transition metal sulfides hold a wider energy band gap and better electrical and optical properties. They are semiconducting materials that possess explicit stability and find application in the photovoltaic sector, such as lithium-ion batteries, photo sensible capacitors, and photodetectors [13]. As a performance promoter, fewer sulphur-based materials are involved in the collection of reflected photons such as, Al2S3, MoS2, and ZnS [14–16]. Some of the coating techniques for achieving thin surface films were screen printing, dip coating, sputter deposition, doctor blading, spin coating, laser beam epitaxy, spray pyrolysis, and spray coating [17]. The electrospraying method with optimal running conditions was taken into account for coating the synthesized antireflective FeS2 particles [18, 19]. Due to the abundant nature of FeS2, it is utilized as an effective photoabsorber material in place of silicon. The energy band gap of FeS2 was equivalent to 0.95 eV, which was quite nearer to the Shockley-Queisser limit for photoenergy conversion. It also holds higher carrier diffusion lengths and an elevated coefficient of absorption owing to the thickness of the films. This material was also available at a low cost [20]. FeS2 was extensively resistant to a corrosive environment, and hence was used as an alternative for the Pt counter electrode in DSSCs [21, 22].This research work majorly concentrates on the development and coating of ferrous disulphide thin films as a perfect light harvesting material for minimizing the light reflection at front contact of crystalline silicon solar cell. However, the synthesized material was confirmed through the X-ray diffraction method and compared with standard JCPDS files. Initially, an adequate quantity of synthesized FeS2 was dispersed with ethanol. Then, the dispersed liquid was electrosprayed over the front contact surface of the solar cell. The cross-sectional thickness and material distribution were identified using the FESEM analysis. The coated samples were evaluated using electrical, structural, optical, and thermal studies. The photocurrent generation was measured using a Keithley IV source meter.


## 2. Materials Used

High-performance polycrystalline silicon solar cells were purchased from Pearlescent Green, Noida. The dimensions of the procured solar cell considered for the performance analysis were 70 mm × 70 mm. Powdered polyvinylpyrrolidone was purchased from Sigma Aldrich and with thiocarbamide and FeSO4. 7H2O was obtained from Lakshita Chemicals, Mumbai. Thiourea, C2H5OH, and sodium hydroxide were brought from Mahadev Chemicals in Chennai. The pure form of sulphur was purchased from Labogens, India.


### 2.1. Preferred Methodology

The layer-by-layer assembly of ethanol-dispersed FeS2 over the front contact surface of solar cells was performed using the electrospray technique. Initially, the surface of solar cells sensible to solar light was precleaned using ethanol. At preset parameters, the coating of synthesized FeS2 was performed. After each coating, the photovoltaic cell was heat treated at 70°C using a hot air oven. This process was repeated in cyclic manner for attaining a multilayer antireflective coating.


### 2.2. Synthesis of Metalsulphide-FeS2

One of the abundant transition metal sulfides with explicit optical and electrical properties was FeS2, and it was synthesized using the hydrothermal technique (as indicated in Figure 1). Initiator materials such as iron sulphate heptahydrate and polyvinylpyrrolidone were taken in adequate quantity and then mixed with 0.02 L of distilled water. The mixture was heat treated at 95°C for 0.5 h. Following this, 0.01 mol of thiourea was poured into the mixture and heated at 100°C for 0.5 h. The final mixture was taken into an autoclave. Further, the addition of 0.02 mol of sulphur (in powder form) into the mixture was performed. The autoclave was subjected to a constant heating process for 1 day at 210°C, then allowed to cool at room temperature. Now, 0.01 L of sodium hydroxide solution was added to the final solution. The end product was obtained as a result of centrifugation together with multiple washings of ethyl alcohol and CS2. The resultant powder was dried in an oven at 70°C. The obtained FeS2 powder was dispersed with ethanol and then loaded into the 5 ml surgical syringe. The loaded syringe was placed in the spinneret holder. The surface of the solar cell was wiped thoroughly using ethanol and then placed over the flat plate collector. A high supply voltage of 17 kV was given to the syringe. Under the influence of high electrostatic force, the fine droplets of dispersed liquid get ejected from the syringe and deposited over the silicon solar cell surface. The operating parameters for electrospray deposition are specified in Table 1.Figure 1
Synthesis and coating of FeS2 over silicon solar cell.Table 1
Coating parameters of an electrospray deposition technique.
Solar cellElectrospraying time (min)Coating thickness (μm)Plate translational speed (m/s)Spinneret translational speed (m/s)Flow rate (ml/h)Drying temperature (° C)Bare000.150.1270F1300.95F2601.46F3901.78F41202.31The cross-sectional thickness and distribution of coating materials were observed through FESEM analysis (MIRA 3). By matching the standard JCPDS file, the synthesized FeS2 was confirmed through the XRD technique (XPertPro analyzer). The analysis was performed between the diffraction angles of 20 and 80 , along with the step size and scanning rate, which seemed to be 0.5⁰ and 0.02⁰/min. Through standard software, the roughness of the coated surface was determined using the atomic force microscopy technique (Tosca 400). In this method, the coated solar cells were scanned at 1 × 10−10 m2 area for evaluating the surface topography over the front contact surface. The photogenerated energy was calculated with the help of a Keithley I-V source meter at each instant for different solar cells under a neodymium lamp. The input AC regulator and solar power meter help us to tune the neodymium radiation equivalent to solar radiation. The transmittance of various glass samples which are coated under the same operating conditions of different solar cells through UV-Vis-NiR spectroscopy (Cary 5000). The variation in surface temperature of different coated solar cell samples was encountered using an IR fluke thermal imager. The solar simulator setup for determining the power conversion efficiency of solar cells is represented in Figure 2.Figure 2
I-V measurement under a simulated light source.


## 2.1. Preferred Methodology

The layer-by-layer assembly of ethanol-dispersed FeS2 over the front contact surface of solar cells was performed using the electrospray technique. Initially, the surface of solar cells sensible to solar light was precleaned using ethanol. At preset parameters, the coating of synthesized FeS2 was performed. After each coating, the photovoltaic cell was heat treated at 70°C using a hot air oven. This process was repeated in cyclic manner for attaining a multilayer antireflective coating.


## 2.2. Synthesis of Metalsulphide-FeS2

One of the abundant transition metal sulfides with explicit optical and electrical properties was FeS2, and it was synthesized using the hydrothermal technique (as indicated in Figure 1). Initiator materials such as iron sulphate heptahydrate and polyvinylpyrrolidone were taken in adequate quantity and then mixed with 0.02 L of distilled water. The mixture was heat treated at 95°C for 0.5 h. Following this, 0.01 mol of thiourea was poured into the mixture and heated at 100°C for 0.5 h. The final mixture was taken into an autoclave. Further, the addition of 0.02 mol of sulphur (in powder form) into the mixture was performed. The autoclave was subjected to a constant heating process for 1 day at 210°C, then allowed to cool at room temperature. Now, 0.01 L of sodium hydroxide solution was added to the final solution. The end product was obtained as a result of centrifugation together with multiple washings of ethyl alcohol and CS2. The resultant powder was dried in an oven at 70°C. The obtained FeS2 powder was dispersed with ethanol and then loaded into the 5 ml surgical syringe. The loaded syringe was placed in the spinneret holder. The surface of the solar cell was wiped thoroughly using ethanol and then placed over the flat plate collector. A high supply voltage of 17 kV was given to the syringe. Under the influence of high electrostatic force, the fine droplets of dispersed liquid get ejected from the syringe and deposited over the silicon solar cell surface. The operating parameters for electrospray deposition are specified in Table 1.Figure 1
Synthesis and coating of FeS2 over silicon solar cell.Table 1
Coating parameters of an electrospray deposition technique.
Solar cellElectrospraying time (min)Coating thickness (μm)Plate translational speed (m/s)Spinneret translational speed (m/s)Flow rate (ml/h)Drying temperature (° C)Bare000.150.1270F1300.95F2601.46F3901.78F41202.31The cross-sectional thickness and distribution of coating materials were observed through FESEM analysis (MIRA 3). By matching the standard JCPDS file, the synthesized FeS2 was confirmed through the XRD technique (XPertPro analyzer). The analysis was performed between the diffraction angles of 20 and 80 , along with the step size and scanning rate, which seemed to be 0.5⁰ and 0.02⁰/min. Through standard software, the roughness of the coated surface was determined using the atomic force microscopy technique (Tosca 400). In this method, the coated solar cells were scanned at 1 × 10−10 m2 area for evaluating the surface topography over the front contact surface. The photogenerated energy was calculated with the help of a Keithley I-V source meter at each instant for different solar cells under a neodymium lamp. The input AC regulator and solar power meter help us to tune the neodymium radiation equivalent to solar radiation. The transmittance of various glass samples which are coated under the same operating conditions of different solar cells through UV-Vis-NiR spectroscopy (Cary 5000). The variation in surface temperature of different coated solar cell samples was encountered using an IR fluke thermal imager. The solar simulator setup for determining the power conversion efficiency of solar cells is represented in Figure 2.Figure 2
I-V measurement under a simulated light source.


## 3. Result and Discussion

Solar cells coated with the FeS2 powder were assessed through FESEM analysis. From the I-V characteristic curve, the F3 sample holds denser and more uniform coatings of materials. The coating thickness and material distribution were clearly identified using the FESEM technique [23–25]. The cross-sectional thickness of F1, F2, F3, and F4 cells was 0.95, 1.46, 1.78, and 2.31 μm,a respectively. From the results, the coating thickness goes on increasing with a gradual increment in coating time. Figure 3(a) indicates the cross-sectional thickness of the F3 sample, while Figure 3(b) represents the distribution of coated materials over the solar cell surface.Figure 3
(a) FESEM Cross-sectional image—F3 solar cell sample. (b) FESEM surface morphology—F3 sample.
(a)(b)From Figure4, the synthesized FeS2 was confirmed by matching the obtained XRD results with the predefined JCPDS card: 01–1295. The appearance of steep peaks points out the crystalline nature of FeS2 powdered material. FeS2 crystalline material gets oriented predominantly in planes as follows: (1 1 1), (2 0 0), (2 10), (2 1 1), (2 2 0), (3 1 1), (2 2 2), (0 2 3), and (3 2 1). The corresponding diffraction angles were noted as 27.75°, 31.63°, 54.72°, 57.08°, 66.18°, and 74.99°.Figure 4
XRD examination-synthesized FeS2 powder.The crystallite size of synthesized material is found to vary from one particle to another. By means of Debye Scherer equation (1), the average crystallite size of hydrothermally synthesized FeS2 particles was determined and is tabulated in Table 2. The average crystallite size of FeS2 particles was about 17.5590 nm. The number of crystallites is addedtogether to form a particle. Hence, the measured particle size is found to be less than the crystallite size of synthesized FeS2 [26].Table 2
Determination of average crystallite size of synthesized FeS2 particles.
2θ (degrees)FWHM (radians)Crystallite size (nm)Average crystallite sizeD (nm)28.550.61313.3725883317.5590322135.470.69212.0529981839.110.48117.5271483341.480.3226.5461740658.050.4221.6317462662.060.6314.4211641764.240.53417.36140617Debye Scherer equation,(1)D=K×λβ×cosθ,where K = Scherer constant (0.9). λ = 0.15406 nm (wavelength of incident X-ray source). β = Line broadening at the FWHM (radians). θ = Position of peaks (radians). D = Average crystallite size (nm).The synthesized powder was examined through HRTEM to obtain the size of the particles [27]. FeS2 powdered particles were added with ethyl alcohol. A small amount of the dispersed mixture was taken with the help of a glass dropper. Then, the glass dropper was pressed against the thin carbon film, which was placed over a copper grid arrangement. An accelerating voltage of 0.2 MV was supplied to the copper grid. The examined particles were of different sizes, varying from 67.43 nm to 310.75 nm. From Figure 5, HRTEM studies of particles appeared to have irregular shapes.Figure 5
TEM image of synthesized FeS2 particles.The surface topography at near atomic resolution for coated solar cells was analyzed using the AFM technique [28]. Figure 6 represents the 3D morphology of coated samples evaluated through AFM studies. The RMS values of surface roughness for coated solar cells were found to be 55, 89, 103, and 133 nm, respectively. Various FeS2 electrosprayed samples were examined under a fixed scanning area in a tapping mode. The coating material firmly gets adhered to the front contact surface, with slight variations in the magnitude of surface roughness for different solar cells. It was found that an increase in coating time increases the surface roughness and thickness of the coated film. The roughened surface of coated cells facilitates the incoming photons to impregnate into the junction of the p-n region. This should enhance the power conversion efficiency of coated solar cells.Figure 6
AFM studies of FeS2-coated solar cells (a) F1, (b) F2, (c) F3, and (d) F4.
(a)(b)(c)(d)The transmittance of coated samples at varying coating times was analyzed through UV-Vis spectroscopy [17, 29]. The obtained transmittance studies were graphically represented in Figure 7. The coated samples were analyzed with respect to reference glass slides. Among all coated glass slides, the triple-layer electrosprayed specimen exhibits maximum transmittance than other samples. The size of the glass sample for optical analysis was 2.54 cm × 7.62 cm. The maximum transmittances obtained for one, two, three, and four-layered glass slides were 84.6, 86.2, 92.7, and 82.5%, respectively. The refractive index of the sample was found to be varying and was measured at different wavelengths. As the refractive index decreases, light transmittance tends to rise for coated samples. The refractive indexes of FeS2-coated samples were determined as 4.5, 4.1, 3.7, and 3.5 using Eq. (2). Here, n2 and n0 represent the refractive index of thermally evaporated ZnSe and atmospheric air. The antireflective material should be selected by considering its refractive index and transparent nature. For the coated thin films with enhanced light transmittance, hall mobility reaches a maximum of 14.97 cm2 V−1 s−1 (F3). This indicates the traption of the maximum possible photons reflected from the solar cell surface to achieve the maximum photocurrent generation.(2)n1=n0×n2.Figure 7
Transmittance of various coated samples.The generated electrons flow into the closed circuit and were measured using an I-V source meter. The source meter was interfaced with the display device. The measured electrical characteristics of coated and uncoated samples were tabulated in Table3. With the experimental data, the characteristic curve was traced with open-circuit voltage against short-circuit current. The analysis of solar cells was performed under constant light irradiation (neodymium light illumination). From Figure 8, the obtained power conversion efficiencies of uncoated and F3 solar cell samples were found to be 14.88% and 19.6%, respectively. The triple-layer electrosprayed FeS2 sample showed almost a 5% increase in power conversion efficiency as compared to an uncoated solar cell. The solar cell performance gradually increases until reaching optimal coating thickness. At optimal coating thickness, this promoted electron mobility reduced photon reflection with the front contact surface and elevated the built-in voltage. After 1.78 μm of thickness, there is a drop in solar cell efficiency due to increased reflectivity at the coated surface for the F4 solar cell as compared to the F3 solar cell. Only a certain quantity of photons were involved in the photogeneration process, which was the major reason for the drop in cell performance. The remaining photons were dissipated as heat energy, which was responsible for increasing solar cell temperature. Thus, increased cell temperature reduces the electrical conductivity of a solar cell [8, 30, 31].Table 3
I-V assessment under a neodymium light source.
S.NoLayerIsc (mA/cm2)Voc (V)FF (%)Rsh (Ω m)Rs (Ω m)Efficiency (%)Thickness (μm)1F133.920.64175.914780.5116.502720.972F235.610.64776.817630.4817.694471.253F338.080.65578.619520.4519.604731.784F436.470.64877.718840.4218.36252.195Uncoated31.820.6327412750.5314.881580Figure 8
The outcome of photogeneration of various coated FeS2 electrosprayed solar cells under neodymium light.The resistivity of coated and uncoated solar cells was assessed through four-probe methods (as represented in Figure9). The best-performing solar cell (F3) experiences hall mobility and resistivity at 14.97 cm2 V−1 s−1 and 2.35 × 10−3 Ω m, respectively. The parameters related to the electrical properties such as hall mobility, carrier concentration, and electrical resistivity were evaluated and tabulated in Table 4. The presence of Fe was responsible for the increment in the overall electrical conductivity of coated solar cells. The spin-coated surface films experience decremented electrical resistivity until reaching the optimal coating thickness of 1.78 μm; beyond that, resistivity starts increasing. This is because clustered coated materials inhibit the penetration of photons into the front contact of the solar cell [12, 17]. The rate at which excitons were generated and recombined was dependent on hall mobility. Hall mobility is the measure of representing the generated electron mobility in photovoltaic cells. Certain noticeable changes occur in the size of the crystal without altering the orientation of the crystal, which was the major reason for incremental electrical resistivity (for the F4 sample).Figure 9
Electrical resistivity of coated samples.Table 4
Electrical resistivity and hall mobility of various coated samples.
S.NoLayerResistivity (Ω m)Closed temperature (° C)Hall mobility (cm2·V−1·s−1)1F14.95 × 10−355.811.432F23.89 × 10−353.213.163F32.35 × 10−349.714.974F43.19 × 10−352.313.095Uncoated6.71 × 10−359.48.76The thermal imaging technique was one of the nondestructive examination techniques employed in the fields of energy audit, ecology, foundry and manufacturing industries, etc. The coated and uncoated solar cells get heated under continual light irradiation. An increase in surface temperature reduces photoelectron generation [32]. This results in a drop in the power conversion efficiency of solar cells. Until now, temperature studies on coated solar cells were not well explored. The measured solar cell temperatures for uncoated and coated solar cells were 60.7, 55.1, 53.3, 49.9, and 52.1°C, which were clearly evident from Figure 10. In general, the performance of semiconductors decreases with an increase in operating temperature. For solar cells, the operating temperature directly affects the magnitude of Voc and Isc. Increasing cell temperature slightly increases the short circuit current but decreases the open circuit voltage. This phenomenon results in shifting the I-V curve toward the origin, leading to a decrease in the measured fill factor. Due to the decreased energy band gap, minimal energy was required for the electron to jump from the valence to the conduction band. This facilitates the mobility of generated electron and hole pairs. Hence, Isc increases in a very minimal quantity with reference to temperature [33].Figure 10
IR thermal imaging under a simulated light source (a) uncoated, (b) F1, (c) F2, (d) F3, and (e) F4.
(a)(b)(c)(d)(e)In most cases, the photogeneration ability decreases with an increase in cell temperatures, owing to enhanced electrical resistivity. Due to a higher number of excitons generation and recombination, maximum hall mobility was achieved for the F3 sample. The charge carrier mobility decreases with an increase in photon reflection at the solar cell surface, leading to an increase in the solar cell temperature. From the observed results, photon scattering at the solar cell surface promotes heat flux and hinders photocurrent generation.


## 4. Conclusion

With the aid of certain precursor materials such as polyvinylpyrrolidone, thiocarbamide, iron sulphate heptahydrate, and NaOH, FeS2 was synthesized through the hydrothermal method. From the results of XRD, the miller indices approximately coincide with the standard JCPDS file. Also, the average crystallite size of hydrothermally synthesized samples was determined to be approximately 17.5590 nm. From FESEM, the coating thickness for the best operating solar cell (F3) was 0.97, 1.25, 1.78, and 2.19 μm. Various layers of FeS2 over silicon substrates were confirmed through a continual increase in coating thickness. The maximum number of photons get diffused in the F3 sample, with a corresponding transmittance of 92.7%. A pyrite-structured antireflective material with three coating layers experiences a maximum power conversion efficiency of 19.6%. Through IV studies, the F3 solar cell exhibits a higher Voc, which increases from 14.88% (bare cell) to 19.6%. With a further increase in coating thickness, the Isc tends to drop, resulting in minimal output photocurrent generation. From the observed results, solar cell performance decreases (for the F4 solar cell) with increases in surface temperature and electrical resistivity. As a result, synthesized FeS2 was found to be transparent, antireflective, and minimize photon scattering at the solar cell surface.



---

*Source: 1252105-2022-10-08.xml*