Patent ID: 12189297

DETAILED DESCRIPTION

Improved process flows and methods are provided herein for patterning extreme ultraviolet (EUV) (or lower wavelength) photoresists. More specifically, improved process flows and methods are provided herein for patterning metal-oxide photoresists, which may be used in EUV or lower wavelength lithography to transfer patterns onto one or more underlying layers formed on a substrate. The process flows and methods disclosed herein may utilize a wide variety of metal-oxide materials including, but not limited to, metal-oxides comprising tin (Sn), hafnium (Hf) and zirconium (Zr). Although metal-oxide materials containing Sn, Hf or Zr are disclosed herein as examples, the process flows and methods disclosed herein are extendible to other metal-oxide materials and metal-containing photoresists. As described herein, an example embodiment utilizing EUV wavelength light is discussed. However, the techniques utilized herein are not limited to EUV wavelengths. Further, the techniques may be particularly advantageous for EUV or lower wavelengths of light. Thus, though described in some examples herein with regard to EUV wavelengths, the techniques provided may also be applicable to EUV or lower wavelengths of light.

In the disclosed process flows and methods, a patterning layer comprising a metal-oxide photoresist is formed on one or more underlying layers provided on a substrate, and portions of the patterning layer not protected by a mask between the light source and the patterning layer are exposed to EUV light. EUV exposure separates organic ligands from metal-oxide structures (e.g., cages or chains) within the exposed portions of the metal-oxide photoresist, while leaving unexposed portions of the metal-oxide photoresist unchanged. After EUV exposure, a bake process is performed to release the organic ligands freed from the exposed portions of the metal-oxide photoresist, and a plasma process is used to remove (e.g., etch) the exposed portions to develop the metal-oxide photoresist pattern. In this manner a dry plasma develop of a metal-oxide photoresist is provided.

The plasma process described herein may use a plurality of deposition and etch steps to develop the metal-oxide photoresist pattern. In some embodiments, a hydrocarbon or fluorocarbon based plasma may be used in the deposition step to selectively deposit a protective layer (or film) onto the unexposed portions of the metal-oxide photoresist. During the etch step, a hydrogen or halogen based plasma may be used to selectively convert a surface of the exposed portions of the metal-oxide photoresist into a volatile material (e.g., a metal hydride, halide or chloride), which can be removed for example via ion bombardment. The protective layer selectively deposited onto the unexposed portions of the metal-oxide photoresist protects the unexposed portions from erosion, while the exposed portions of the metal-oxide photoresist are selectively etched during the etch step. In some embodiments, the plasma development process described herein may continue in a cyclical manner, repeating the selective deposition and selective etch steps, until the exposed portions of the metal-oxide photoresist are completely removed.

Accordingly, a novel plasma development process for a metal-oxide photoresist is disclosed herein for advanced EUV patterning. The plasma development process allows selective deposition and selective etch at molecular/atomic level through precise plasma process control. In addition to other plasma process parameters, plasma precursors are chosen to selectively convert a surface of the EUV activated areas (i.e., the exposed portions of the metal-oxide photoresist) into a more volatile material (e.g., a metal hydride, halogen, or chloride) in the selective etch step, and to selectively deposit a protective layer on the un-activated areas (i.e., the unexposed portions of the metal-oxide photoresist) in the selective deposition step. In some embodiments, the plasma processing steps disclosed herein may be performed simultaneously within the plasma process chamber using the same plasma precursors for both deposition and etch steps. In other embodiments, the plasma processing steps may be segregated within the plasma process chamber, so that different plasma precursors can be used to perform the deposition and etch steps.

FIG.1A-1Fillustrate one embodiment of an improved process flow for patterning EUV metal-oxide photoresists according to the techniques disclosed herein. It will be recognized that the embodiment shown inFIGS.1A-1Fis merely exemplary and the techniques described herein may be applied to other process flows.

As shown inFIG.1A, substrate100includes a patterning layer108formed over one or more underlying layers, such as for example, a hard mask layer106, a sacrificial carbon layer104and a base substrate102. Base substrate102may be any substrate for which the use of patterned features is desirable. For example, base substrate102may be a semiconductor substrate having one or more semiconductor processing layers formed thereon. In one embodiment, base substrate102may be a substrate that has been subject to multiple semiconductor processing steps which yield a wide variety of structures and layers, all of which are known in the substrate processing art.

Hard mask layer106and sacrificial carbon layer104may be formed from any of a wide variety of materials, as is known in the art. In one embodiment, the hard mask layer106may be a spin on glass (SOG) layer and the sacrificial carbon layer104may be a spin on carbon (SOC) layer. It is recognized, however, that the underlying layers described and shown in the figures are merely exemplary, and more, less or other underlying layers may be utilized.

The patterning layer108shown inFIG.1Amay be formed from any of a wide variety of materials commonly used in EUV lithography. For example, the patterning layer108may be a metal-oxide photoresist. In some embodiments, the patterning layer108may comprise a metal-oxide material containing tin (Sn), hafnium (Hf) or zirconium (Zr). Other metal-oxide materials may also be used to implement the patterning layer108. In some embodiments, a metal-containing, non-oxide photoresist material may be used to implement the patterning layer108. The patterning layer108may generally be formed using any of a wide variety of deposition processes. In some embodiments, for example, a spin coating process may be utilized to form the patterning layer108. However, the techniques described herein are not limited to the method of forming the patterning layer108.

In the example embodiment shown inFIG.1A, the patterning layer108comprises a metal-oxide material, which includes clusters of metal-oxide structures (M-O) having chemically bound organic ligands (L). As described in more detail below, the process flow shown inFIGS.1B-1Cexposes portions of the patterning layer108to extreme ultraviolet (EUV) light to separate or free the organic ligands (L) from the metal-oxide structures (M-O), and performs a bake process to release the freed ligands from the EUV exposed portions of the patterning layer108. Once the organic ligands are freed, a cyclical dry process is used to remove the EUV exposed portions of the patterning layer108and develop the metal-oxide photoresist pattern, as shown inFIGS.1D-1F.

After patterning layer108is formed inFIG.1A, a mask110is provided above the patterning layer108and an EUV lithography step is performed inFIG.1B. During the EUV lithography step shown inFIG.1B, the exposed portions114of the patterning layer108(i.e., the portions of the patterning layer108not protected by the mask110) are exposed to EUV light112. As shown inFIG.1B, EUV exposure separates the organic ligands (L) from the metal-oxide structures (M-O) within only the exposed portions114of the patterning layer108, while leaving the unexposed portions116of the patterning layer108unchanged.

After the EUV lithography step is performed inFIG.1B, a post exposure bake (PEB) process is performed to release the freed ligands from the exposed portions114of the patterning layer108, leaving only dense metal-oxide structures (M-O) in the exposed portions114, as shown inFIG.1C. After the PEB process is performed, a dry process (e.g., a plasma development process) is used to remove the exposed portions114of the patterning layer108to develop the metal-oxide photoresist pattern.

FIGS.1D-1Fillustrate one embodiment of a plasma development process that may be used to develop a metal-oxide photoresist pattern in accordance with the techniques described herein. As described in more detail below, the disclosed plasma development process may generally include a plurality of deposition and etch steps. In some embodiments, the plasma development process may begin by exposing the substrate100to a first plasma118to selectively deposit a protective layer120onto the unexposed portions116of the patterning layer108, as shown inFIG.1D. After the protective layer120is formed on the unexposed portions116, the substrate100is exposed to a second plasma122to selectively etch or remove the exposed portions114of the patterning layer108, as shown inFIG.1E. The protective layer120protects the unexposed portions116of the patterning layer108from erosion, while the exposed portions114of the patterning layer108are selectively etched or removed during the selective etch step. In some embodiments, the plasma development process shown inFIGS.1D and1Emay continue in a cyclical manner, by repeating the selective deposition and selective etch steps a number of cycles and/or until the exposed portions114of the patterning layer108are completely removed, as shown inFIG.1F.

Various plasma chemistries may be used in the selective deposition step shown inFIG.1D. In some embodiments, the first plasma118may use a hydrocarbon or fluorocarbon based precursor gas chemistry to selectively deposit the protective layer120onto the unexposed portions116of the patterning layer108. Examples of hydrocarbon and fluorocarbon based chemistries that may be used within the first plasma118include, but are not limited to, CH4, C4F8, C4F6or CH3F. Other hydrocarbon or fluorocarbon based chemistries may also be used in the selective deposition step shown inFIG.1D.

Various plasma chemistries may also be used in the selective etch step shown inFIG.1E. In some embodiments, the second plasma122may use a hydrogen or halogen containing precursor gas chemistry to convert a surface of the exposed portions114into a volatile material (e.g., a metal hydride, halide or chloride), and may use an inert gas (such as, e.g., argon) to selectively etch or remove the volatized surface via ion bombardment. Examples of hydrogen or halogen containing precursor gas chemistries that may be used within the second plasma122include, but are not limited to, hydrocarbons (e.g., CH4), halocarbons (e.g., CF4, CHF3) and other halogen based chemistries (e.g., BCl3) commonly used in plasma etching. In some embodiments, a combination of a hydrocarbon precursor gas and an inert gas may be used to generate the second plasma122. In other embodiments, the second plasma122may include a halocarbon, hydrogen and inert gas combination.

The hydrogen (or halogen) components included within the second plasma122facilitate etching by converting the surface of the metal oxide material within the exposed portions114into volatized metal hydrides, halides or chlorides, which are removed in one embodiment via ion bombardment. In some embodiments, the selective etch step shown inFIG.1Emay be performed as a single step by exposing the substrate100to a plasma containing a hydrogen (or halogen) containing precursor gas and an inert gas (such as argon). In other embodiments, the selective etch step may be a cyclic process that exposes the substrate100to a hydrogen (or halogen) based plasma before exposing the substrate100to an argon plasma.

Although one example embodiment is described herein with regard to argon (Ar), other inert gas ions may also be used to bombard the surface of the exposed portions114in the selective etch step shown inFIG.1D. Exemplary inert gases include, but are not limited to He, Ne, Kr, and other noble gases. Further, other gases may be utilized in combination with the argon and/or noble gases. For example, other gases may be added to the plasma, as the plasma is not limited to only having argon or noble gases. For example, other inert gases or other gases that are not inert gases may be added to the process.

In some embodiments, the selective deposition and selective etch steps shown inFIGS.1D and1Emay be performed simultaneously within the plasma processing chamber, or alternatively, may be segregated into two plasma processing steps and separated for example by one or more purge steps. In one embodiment, the selective deposition and etch steps may be performed simultaneously within the plasma process chamber using the same plasma precursors (e.g., CH4) for both deposition and etch steps. In other embodiments, the selective deposition and etch steps may be segregated within the plasma process chamber, so that different plasma precursors can be used in the deposition and etch steps. For example, the selective deposition and etch steps may be segregated within the plasma process chamber, so that a hydrocarbon precursor (e.g., CH4) can be used in the deposition step, while a hydrogen (H2), halocarbon (e.g., CF4or CHF3) and halogen based chemistry (e.g., BCl3) is used in the etch step.

The selective deposition and etch steps shown inFIGS.1D and1Emay be performed as a cyclic process, which is repeated a number of cycles until the exposed portions114of the patterning layer108are completely removed as shown inFIG.1F. Each time an etch step is performed, some or all of the protective layer120formed on the unexposed portions116may be removed along with the volatized surface of the exposed portions114. In one embodiment, a very thin protective layer may remain after each cycle. At each subsequent deposition step, a new protective layer120is formed on the top and sides of the unexposed portions116as shown inFIG.1F. In order to avoid etching the hard mask layer106underlying the patterning layer108, the plasma chemistries used in the selective deposition and etch steps described herein may generally be selective to the hard mask layer106.

Compared to conventional pattern development processes, which use a wet process to develop negative tone, metal-oxide photoresists, the plasma development process shown inFIGS.1D-1Fuses a cyclic, dry process for pattern development of positive tone photoresists. Unlike negative tone photoresists, positive tone photoresists can be used for hole, block and line/space patterning in narrow geometry processes. By utilizing a cyclic, dry process for pattern development, the plasma development process described herein provides atomic layer control of surface reactions and improves line edge roughness (LER) and critical dimension (CD) control compared to conventional wet process pattern development. The plasma development process described herein is also cleaner and more cost effective than conventional wet process pattern development.

FIGS.2-3illustrate exemplary methods for patterning a substrate, which use the plasma development process described herein. It will be recognized that the embodiments ofFIGS.2-3are merely exemplary and additional methods may utilize the techniques described herein. Further, additional processing steps may be added to the methods shown in theFIGS.2-3as the steps described are not intended to be exclusive. Moreover, the order of the steps is not limited to the order shown in the figures as different orders may occur and/or various steps may be performed in combination or at the same time. Further, though described with relation to EUV light, it will be recognized that the methods ofFIGS.2-3may be advantageous for EUV or lower wavelengths of light.

FIG.2illustrates one embodiment of a method200that may be used to pattern a substrate using the techniques disclosed herein. In some embodiments, the method200may begin by forming a patterning layer and one or more underlying layers on the substrate, wherein the patterning layer comprises a metal-oxide photoresist (in step210). After the patterning layer is formed, the method200performs an extreme ultraviolet (EUV) lithography step, in which portions of the patterning layer not covered by an overlying mask are exposed to EUV light (in step220). In step230, the method200performs a cyclic, dry process to remove the portions of the patterning layer exposed to the EUV light and develop the metal-oxide photoresist pattern.

FIG.3illustrates another embodiment of a method300that may be used to pattern a substrate using the techniques disclosed herein. In some embodiments, the method300may begin by forming a patterning layer and one or more underlying layers on the substrate, wherein the patterning layer comprises a metal-oxide photoresist (in step310). After the patterning layer is formed, the method300exposes portions of the patterning layer, which are not covered by a mask overlying the patterning layer, to extreme ultraviolet (EUV) light (in step320). In step330, the method300selectively deposits a protective layer onto unexposed portions of the patterning layer by exposing the substrate to a first plasma. The unexposed portions of the patterning layer are covered by the mask and not exposed to the EUV light. In step340, the method300selectively etches the exposed portions of the patterning layer by exposing the substrate to a second plasma. In step350, the method300repeats the selectively depositing and the selectively etching until the exposed portions of the patterning layer are completely removed.

FIG.4provides one example embodiment for a plasma processing system400that can be used with respect to the disclosed techniques and is provided only for illustrative purposes. Although the plasma processing system400shown inFIG.4is a capacitively coupled plasma (CCP) processing apparatus, one skilled in the art would recognize the techniques described herein could be performed in inductively coupled plasma (ICP) processing apparatus, microwave plasma processing apparatus, Radial Line Slot Antenna (RLSA™) microwave plasma processing apparatus, electron cyclotron resonance (ECR) plasma processing apparatus, or other type of processing system or combination of systems. Thus, it will be recognized by those skilled in the art that the techniques described herein may be utilized with any of a wide variety of plasma processing systems.

The plasma processing system400can be used for a wide variety of operations including, but not limited to, etching, deposition, cleaning, plasma polymerization, plasma enhanced chemical vapor deposition (PECVD), atomic layer deposition (ALD), atomic layer etch (ALE), and so forth. The structure of a plasma processing system400is well known, and the particular structure provided herein is merely of illustrative purposes. It will be recognized that different and/or additional plasma process systems may be implemented while still taking advantage of the techniques described herein.

Looking in more detail toFIG.4, the plasma processing system400may include a process chamber405. As is known in the art, process chamber405may be a pressure controlled chamber. A substrate410(in one example a semiconductor wafer) may be held on a stage or chuck415. An upper electrode420and a lower electrode425may be provided as shown. The upper electrode420may be electrically coupled to a first radio frequency (RF) source430through a first matching network455. The first RF source430may provide a source voltage435at an upper frequency (fU). The lower electrode425may be electrically coupled to a second RF source440through a second matching network457. The second RF source440may provide a bias voltage445at a lower frequency (fL). Though not shown, it will be known by those skilled in the art that a voltage may also be applied to the chuck415.

Components of the plasma processing system400can be connected to, and controlled by, a control unit470that in turn can be connected to a corresponding memory storage unit and user interface (all not shown). Various plasma processing operations can be executed via the user interface, and various plasma processing recipes and operations can be stored in a storage unit. Accordingly, a given substrate can be processed within the plasma processing chamber with various microfabrication techniques. It will be recognized that control unit470may be coupled to various components of the plasma processing system400to receive inputs from and provide outputs to the components.

The control unit470can be implemented in a wide variety of manners. For example, the control unit470may be a computer. In another example, the control unit may include one or more programmable integrated circuits that are programmed to provide the functionality described herein. For example, one or more processors (e.g., microprocessor, microcontroller, central processing unit, etc.), programmable logic devices (e.g., complex programmable logic device (CPLD)), field programmable gate array (FPGA), etc.), and/or other programmable integrated circuits can be programmed with software or other programming instructions to implement the functionality of a prescribed plasma process recipe. It is further noted that the software or other programming instructions can be stored in one or more non-transitory computer-readable mediums (e.g., memory storage devices, FLASH memory, dynamic random access (DRAM) memory, reprogrammable storage devices, hard drives, floppy disks, DVDs, CD-ROMs, etc.), and the software or other programming instructions when executed by the programmable integrated circuits cause the programmable integrated circuits to perform the processes, functions, and/or capabilities described herein. Other variations could also be implemented.

In operation, the plasma processing system400uses the upper and lower electrodes to generate a plasma460in the process chamber405when applying power to the system from the first RF source430and the second RF source440. The application of power results in a high-frequency electric field being generated between the upper electrode420and the lower electrode425. Processing gas(es) delivered to process chamber405can then be dissociated and converted into a plasma460. The generated plasma460can be used for processing a target substrate (such as substrate410or any material to be processed) in various types of treatments such as, but not limited to, plasma deposition, etching and/or ion bombardment/sputtering.

In some embodiments, the selective deposition and etch steps disclosed herein may be performed simultaneously using the same plasma460. For example, a hydrocarbon (such as CH4) based plasma460may be utilized to selectively deposit a protective layer on the unexposed portions116and selectively etch the exposed portions114of the patterning layer108. In other embodiments, the selective deposition and etch steps disclosed herein may use different plasmas460, which are segregated within the process chamber405for example by one or more purge steps.

As shown inFIG.4, the exemplary plasma processing system400described herein utilizes two RF sources. In an exemplary embodiment, the first RF source430provides source power at relatively high frequencies to convert the processing gas(es) delivered into the process chamber405into plasma and to control the plasma density, while the second RF source440provides a bias power at lower frequencies to control ion bombardment energy.

In one example plasma processing system, the first RF source430may provide about 0 to 1400 W of source power in a high-frequency (HF) range from about 3 MHz to 150 MHz (or above) to the upper electrode420, and the second RF source440may provide about 0 to 1400 W of bias power in a low-frequency (LF) range from about 0.2 MHz to 60 MHz to the lower electrode425. Different operational ranges can also be used depending on type of plasma processing system and the type of treatments (e.g., etching, deposition, sputtering, etc.) performed therein.

In one exemplary embodiment, the first plasma118used in the deposition step shown inFIG.1Dmay be performed with process conditions of 50 W to 1000 W source power, 0 W to 200 W bias power, 10 mT to 200 mT pressure, 0° C. to 150° C. electrostatic chuck temperature, and 50 standard cubic centimeters (SCCM) of CH4gas flow. Other gases, such as for example, CH3F, CH2F2, etc. may also be used in the gas flow.

In one exemplary embodiment, the second plasma122used in the etch step shown inFIG.1Emay be performed with process conditions of 50 W to 1000 W source power, 0 W to 200 W bias power, 10 mT to 200 mT pressure, 10° C. to 150° C. electrostatic chuck temperature, and 20 to 100 standard cubic centimeters (SCCM) of CH4gas flow. Other gases, such as for example, Cl2. BCl3, inert gases, etc. may also be used in the gas flow. In some embodiments, the bias power may be adjusted or controlled to control the ion bombardment energy during the etch step. In some embodiments a separate surface activation/ion bombardment step may be performed with process conditions of 100 W to 500 W source power, 0 W to 200 W bias power, 10 mT to 200 mT pressure, 10° C. to 200° C. electrostatic chuck temperature, and 800 standard cubic centimeters (SCCM) of Ar gas flow. Other gases, such as for example, He, Ne, Kr, etc. may also be used in the gas flow.

It is noted that the techniques described herein may be utilized within a wide range of plasma processing systems. Although a particular plasma processing system400is shown inFIG.4, it will be recognized that the techniques described herein may be utilized within other plasma processing systems. In one example system, the RF sources shown inFIG.4may be switched (e.g., higher frequencies may be supplied to the lower electrode425and lower frequencies may be supplied to the upper electrode420). Further, a dual source system is shown inFIG.4merely as an example system. It will be recognized that the techniques described herein may be utilized with other plasma processing systems in which a modulated RF power source is provided to one or more electrodes, direct current (DC) bias sources are utilized, or other system components are utilized.

It is noted that various deposition processes can be used to form one or more of the material layers shown and described herein. For example, one or more depositions can be implemented using chemical vapor deposition (CVD), plasma enhanced CVD (PECVD), physical vapor deposition (PVD), atomic layer deposition (ALD), and/or other deposition processes. In one example plasma deposition process, a precursor gas mixture can be used including but not limited to hydrocarbons and fluorocarbons, possibly in combination with one or more dilution gases (e.g., argon, nitrogen, etc.) at a variety of pressure, power, flow and temperature conditions.

It is further noted that various etch processes can be used to etch one or more of the material layers shown and described herein. For example, one or more etch processes can be implemented using plasma etch processes, discharge etch processes, and/or other desired etch processes. The plasma etch processes described herein can be implemented using plasma containing hydrogen, halocarbons and other halogen containing chemistries, argon and/or other gases. As noted above, one or more operational parameters (e.g., bias power) of the plasma etch processes described herein may be tuned to control the ion bombardment energy during the etch step.

Other operating variables for process steps can also be adjusted to control the various deposition and/or etch processes described herein. The operating variables may include, for example, the chamber temperature, chamber pressure, flowrates of gases, types of gases, and/or other operating variables for the processing steps. Variations can also be implemented while still taking advantage of the techniques described herein.

It is noted that reference throughout this specification to “one embodiment” or “an embodiment” means that a particular feature, structure, material, or characteristic described in connection with the embodiment is included in at least one embodiment of the invention, but do not denote that they are present in every embodiment. Thus, the appearances of the phrases “in one embodiment” or “in an embodiment” in various places throughout this specification are not necessarily referring to the same embodiment of the invention. Furthermore, the particular features, structures, materials, or characteristics may be combined in any suitable manner in one or more embodiments. Various additional layers and/or structures may be included and/or described features may be omitted in other embodiments.

The term “substrate” as used herein means and includes a base material or construction upon which materials are formed. It will be appreciated that the substrate may include a single material, a plurality of layers of different materials, a layer or layers having regions of different materials or different structures in them, etc. These materials may include semiconductors, insulators, conductors, or combinations thereof. For example, the substrate may be a semiconductor substrate, a base semiconductor layer on a supporting structure, a metal electrode or a semiconductor substrate having one or more layers, structures or regions formed thereon. The substrate may be a conventional silicon substrate or other bulk substrate comprising a layer of semi-conductive material. As used herein, the term “bulk substrate” means and includes not only silicon wafers, but also silicon-on-insulator (“SOI”) substrates, such as silicon-on-sapphire (“SOS”) substrates and silicon-on-glass (“SOG”) substrates, epitaxial layers of silicon on a base semiconductor foundation, and other semiconductor or optoelectronic materials, such as silicon-germanium, germanium, gallium arsenide, gallium nitride, and indium phosphide. The substrate may be doped or undoped.

Systems and methods for processing a substrate are described in various embodiments. The substrate may include any material portion or structure of a device, particularly a semiconductor or other electronics device, and may, for example, be a base substrate structure, such as a semiconductor substrate or a layer on or overlying a base substrate structure such as a thin film. Thus, substrate is not intended to be limited to any particular base structure, underlying layer or overlying layer, patterned or unpatterned, but rather, is contemplated to include any such layer or base structure, and any combination of layers and/or base structures.

One skilled in the relevant art will recognize that the various embodiments may be practiced without one or more of the specific details, or with other replacement and/or additional methods, materials, or components. In other instances, well-known structures, materials, or operations are not shown or described in detail to avoid obscuring aspects of various embodiments of the invention. Similarly, for purposes of explanation, specific numbers, materials, and configurations are set forth in order to provide a thorough understanding of the invention. Nevertheless, the invention may be practiced without specific details. Furthermore, it is understood that the various embodiments shown in the figures are illustrative representations and are not necessarily drawn to scale.

Further modifications and alternative embodiments of the described systems and methods will be apparent to those skilled in the art in view of this description. It will be recognized, therefore, that the described systems and methods are not limited by these example arrangements. It is to be understood that the forms of the systems and methods herein shown and described are to be taken as example embodiments. Various changes may be made in the implementations. Thus, although the inventions are described herein with reference to specific embodiments, various modifications and changes can be made without departing from the scope of the present inventions. Accordingly, the specification and figures are to be regarded in an illustrative rather than a restrictive sense, and such modifications are intended to be included within the scope of the present inventions. Further, any benefits, advantages, or solutions to problems that are described herein with regard to specific embodiments are not intended to be construed as a critical, required, or essential feature or element of any or all the claims.