A process for preparing a compound of Formula (III), the process comprising: a) contacting a compound of Formula (I) with a compound of Formula (IV) in the presence of a transition metal catalyst, an amine, and a chiral ligand to form a compound of Formula (II); and b) contacting the compound of Formula (II) with a secondary amine having Formula (V) to form the compound of Formula (III) according to the following reaction scheme: wherein: Z is R is hydrogen, alkenyl, substituted alkenyl, aryl, substituted aryl, or aryl(C 1 -C 10 )alkyl; R 1 is hydrogen, OR 20 , NR 20 R 21 , SR 20 R 21 , hydrocarbyl, or substituted hydrocarbyl; R 2 is hydrocarbyl or substituted hydrocarbyl; R 3 , R 4 , R 5 , and R 7 are independently hydrogen, OR 20 , NR 20 R 21 , SR 20 R 21 , halo, hydrocarbyl, or substituted hydrocarbyl; R 10 and R 11 are independently hydrocarbyl, substituted hydrocarbyl, or R 10 and R 11 together may form a ring or ring system selected from carbocyclic, heterocyclic, aryl, heteroaryl, or combinations thereof; R 12 is hydrocarbyl or substituted hydrocarbyl; R 13 and R 14 are independently hydrogen, hydrocarbyl, or substituted hydrocarbyl; R 20 and R 21 are independently hydrogen, hydrocarbyl, or substituted hydrocarbyl; n is an integer of 1 or greater; and X is halo. a) contacting a compound of Formula (I) with a compound of Formula (IV) in the presence of a transition metal catalyst, an amine, and a chiral ligand to form a compound of Formula (II); and b) contacting the compound of Formula (II) with a secondary amine having Formula (V) to form the compound of Formula (III) according to the following reaction scheme: wherein: Z is R is hydrogen, alkenyl, substituted alkenyl, aryl, substituted aryl, or aryl(C 1 -C 10 )alkyl; R 1 is hydrogen, OR 20 , NR 20 R 21 , SR 20 R 21 , hydrocarbyl, or substituted hydrocarbyl; R 2 is hydrocarbyl or substituted hydrocarbyl; R 3 , R 4 , R 5 , and R 7 are independently hydrogen, OR 20 , NR 20 R 21 , SR 20 R 21 , halo, hydrocarbyl, or substituted hydrocarbyl; R 10 and R 11 are independently hydrocarbyl, substituted hydrocarbyl, or R 10 and R 11 together may form a ring or ring system selected from carbocyclic, heterocyclic, aryl, heteroaryl, or combinations thereof; R 12 is hydrocarbyl or substituted hydrocarbyl; R 13 and R 14 are independently hydrogen, hydrocarbyl, or substituted hydrocarbyl; R 20 and R 21 are independently hydrogen, hydrocarbyl, or substituted hydrocarbyl; n is an integer of 1 or greater; and X is halo. Z is R is hydrogen, alkenyl, substituted alkenyl, aryl, substituted aryl, or aryl(C 1 -C 10 )alkyl; R 1 is hydrogen, OR 20 , NR 20 R 21 , SR 20 R 21 , hydrocarbyl, or substituted hydrocarbyl; R 2 is hydrocarbyl or substituted hydrocarbyl; R 3 , R 4 , R 5 , and R 7 are independently hydrogen, OR 20 , NR 20 R 21 , SR 20 R 21 , halo, hydrocarbyl, or substituted hydrocarbyl; R 10 and R 11 are independently hydrocarbyl, substituted hydrocarbyl, or R 10 and R 11 together may form a ring or ring system selected from carbocyclic, heterocyclic, aryl, heteroaryl, or combinations thereof; R 12 is hydrocarbyl or substituted hydrocarbyl; R 13 and R 14 are independently hydrogen, hydrocarbyl, or substituted hydrocarbyl; R 20 and R 21 are independently hydrogen, hydrocarbyl, or substituted hydrocarbyl; n is an integer of 1 or greater; and X is halo. <EOS>