A method of printing a three-dimensional article comprising: selectively depositing layers of an ink in a fluid state onto a substrate to form the three-dimensional article; partially curing the ink prior to completion of deposition of all layers of the ink; and post-curing the ink following completion of deposition of all layers of the ink; wherein the ink comprises 10-70 wt. % cyclopolymerizable monomer, based on the total weight of the ink; wherein the cyclopolymerizable monomer comprises an acrylate moiety and an ethenyl or ethynyl moiety, and wherein the cyclopolymerizable monomer has the structure of Formula: wherein X is O, S, NH, NR 5, or CR 5 R 6; R 1 is H or a hydrocarbon group having 1-10 carbon atoms; R 2 is a hydrocarbon group having 1-4 carbon atoms; R 3 is a hydrocarbon group having 1-4 carbon atoms; R 4 is HC=CH 2 or C≡CH; R 5 is a hydrocarbon group having 1-4 carbon atoms; R 6 is a hydrocarbon group having 1-4 carbon atoms; and the total number of carbon atoms of R 2 and R 3 does not exceed 5, wherein the ink further comprises: 10-80 wt. % oligomeric curable material, based on the total weight of the ink; up to 80 wt. % additional monomeric curable material, based on the total weight of the ink; and optionally, at least one photoinitiator, at least one colorant, or one or more additives selected from the group consisting of inhibitors and stabilizing agents. selectively depositing layers of an ink in a fluid state onto a substrate to form the three-dimensional article; partially curing the ink prior to completion of deposition of all layers of the ink; and post-curing the ink following completion of deposition of all layers of the ink; wherein the ink comprises 10-70 wt. % cyclopolymerizable monomer, based on the total weight of the ink; wherein the cyclopolymerizable monomer comprises an acrylate moiety and an ethenyl or ethynyl moiety, and wherein the cyclopolymerizable monomer has the structure of Formula: wherein X is O, S, NH, NR 5, or CR 5 R 6; R 1 is H or a hydrocarbon group having 1-10 carbon atoms; R 2 is a hydrocarbon group having 1-4 carbon atoms; R 3 is a hydrocarbon group having 1-4 carbon atoms; R 4 is HC=CH 2 or C≡CH; R 5 is a hydrocarbon group having 1-4 carbon atoms; R 6 is a hydrocarbon group having 1-4 carbon atoms; and the total number of carbon atoms of R 2 and R 3 does not exceed 5, wherein the ink further comprises: 10-80 wt. % oligomeric curable material, based on the total weight of the ink; up to 80 wt. % additional monomeric curable material, based on the total weight of the ink; and optionally, at least one photoinitiator, at least one colorant, or one or more additives selected from the group consisting of inhibitors and stabilizing agents. wherein X is O, S, NH, NR 5, or CR 5 R 6; R 1 is H or a hydrocarbon group having 1-10 carbon atoms; R 2 is a hydrocarbon group having 1-4 carbon atoms; R 3 is a hydrocarbon group having 1-4 carbon atoms; R 4 is HC=CH 2 or C≡CH; R 5 is a hydrocarbon group having 1-4 carbon atoms; R 6 is a hydrocarbon group having 1-4 carbon atoms; and the total number of carbon atoms of R 2 and R 3 does not exceed 5, wherein the ink further comprises: 10-80 wt. % oligomeric curable material, based on the total weight of the ink; up to 80 wt. % additional monomeric curable material, based on the total weight of the ink; and optionally, at least one photoinitiator, at least one colorant, or one or more additives selected from the group consisting of inhibitors and stabilizing agents. 10-80 wt. % oligomeric curable material, based on the total weight of the ink; up to 80 wt. % additional monomeric curable material, based on the total weight of the ink; and optionally, at least one photoinitiator, at least one colorant, or one or more additives selected from the group consisting of inhibitors and stabilizing agents.