A composition comprising an emulsion, the emulsion comprising at least one polymeric surfactant, water and at least one hydrophobic organophosphorous compound selected from the group consisting of: wherein each R1 is independently a monovalent aryl, arylalkyl, or alkyl substituent containing up to 20 carbon atoms, each R3 is independently a monovalent aryl, arylalkyl, alkyl, hydrogen, phosphate ester, silyl, or phosphonate ester substituent containing up to 20 carbon atoms; each R2 is independently a divalent aryl, arylalkyl, or alkyl substituent containing up to 20 carbon atoms; R1, R3 and R2 each optionally include one or more heteroatoms in the substituents; and n is from 1 to 100; wherein each R1 is independently a monovalent aryl, arylalkyl, or alkyl substituent containing up to 20 carbon atoms, each R3 is independently a monovalent aryl, arylalkyl, alkyl, hydrogen, phosphate ester, silyl, or phosphonate ester substituent containing up to 20 carbon atoms; each R2 is independently a divalent aryl, arylalkyl, or alkyl substituent containing up to 20 carbon atoms; R1, R3 and R2 each optionally include one or more heteroatoms in the substituents; and n is from 1 to 100; and wherein R1 and R2 are independently monovalent aryl, arylalkyl, alkyl, hydrogen, phosphate ester, silyl, or phosphonate ester substituents containing up to 20 carbon atoms; each R3 and R4 are independently monovalent aryl, arylalkyl, or alkyl substituents containing up to 20 carbon atoms; R5 is a divalent aryl, arylalkyl, or alkyl substituent containing up to 20 carbon atoms; each R6 and R7 are independently divalent aryl, arylalkyl, or alkyl substituents containing up to 20 carbon atoms; R1, R2, R3, R4, R5, R6, and R7 each optionally include one or more heteroatoms in the substituents; m is from 1 to 100; and n is from 1 to 100, wherein the emulsion is an oil-in-water emulsion. each R1 is independently a monovalent aryl, arylalkyl, or alkyl substituent containing up to 20 carbon atoms, each R3 is independently a monovalent aryl, arylalkyl, alkyl, hydrogen, phosphate ester, silyl, or phosphonate ester substituent containing up to 20 carbon atoms; each R2 is independently a divalent aryl, arylalkyl, or alkyl substituent containing up to 20 carbon atoms; R1, R3 and R2 each optionally include one or more heteroatoms in the substituents; and n is from 1 to 100; wherein each R1 is independently a monovalent aryl, arylalkyl, or alkyl substituent containing up to 20 carbon atoms, each R3 is independently a monovalent aryl, arylalkyl, alkyl, hydrogen, phosphate ester, silyl, or phosphonate ester substituent containing up to 20 carbon atoms; each R2 is independently a divalent aryl, arylalkyl, or alkyl substituent containing up to 20 carbon atoms; R1, R3 and R2 each optionally include one or more heteroatoms in the substituents; and n is from 1 to 100; and wherein R1 and R2 are independently monovalent aryl, arylalkyl, alkyl, hydrogen, phosphate ester, silyl, or phosphonate ester substituents containing up to 20 carbon atoms; each R3 and R4 are independently monovalent aryl, arylalkyl, or alkyl substituents containing up to 20 carbon atoms; R5 is a divalent aryl, arylalkyl, or alkyl substituent containing up to 20 carbon atoms; each R6 and R7 are independently divalent aryl, arylalkyl, or alkyl substituents containing up to 20 carbon atoms; R1, R2, R3, R4, R5, R6, and R7 each optionally include one or more heteroatoms in the substituents; m is from 1 to 100; and n is from 1 to 100, wherein the emulsion is an oil-in-water emulsion. each R1 is independently a monovalent aryl, arylalkyl, or alkyl substituent containing up to 20 carbon atoms, each R3 is independently a monovalent aryl, arylalkyl, alkyl, hydrogen, phosphate ester, silyl, or phosphonate ester substituent containing up to 20 carbon atoms; each R2 is independently a divalent aryl, arylalkyl, or alkyl substituent containing up to 20 carbon atoms; R1, R3 and R2 each optionally include one or more heteroatoms in the substituents; and n is from 1 to 100; and wherein R1 and R2 are independently monovalent aryl, arylalkyl, alkyl, hydrogen, phosphate ester, silyl, or phosphonate ester substituents containing up to 20 carbon atoms; each R3 and R4 are independently monovalent aryl, arylalkyl, or alkyl substituents containing up to 20 carbon atoms; R5 is a divalent aryl, arylalkyl, or alkyl substituent containing up to 20 carbon atoms; each R6 and R7 are independently divalent aryl, arylalkyl, or alkyl substituents containing up to 20 carbon atoms; R1, R2, R3, R4, R5, R6, and R7 each optionally include one or more heteroatoms in the substituents; m is from 1 to 100; and n is from 1 to 100, R1 and R2 are independently monovalent aryl, arylalkyl, alkyl, hydrogen, phosphate ester, silyl, or phosphonate ester substituents containing up to 20 carbon atoms; each R3 and R4 are independently monovalent aryl, arylalkyl, or alkyl substituents containing up to 20 carbon atoms; R5 is a divalent aryl, arylalkyl, or alkyl substituent containing up to 20 carbon atoms; each R6 and R7 are independently divalent aryl, arylalkyl, or alkyl substituents containing up to 20 carbon atoms; R1, R2, R3, R4, R5, R6, and R7 each optionally include one or more heteroatoms in the substituents; m is from 1 to 100; and n is from 1 to 100,