A temporary bonding method comprising: providing a stack comprising: a first substrate having a back surface and a device surface, said device surface having a peripheral region and a central region; a second substrate having a carrier surface; and an edge bond bonded to said peripheral region and to said carrier surface, said edge bond being absent from said central region so as to form a fill zone, said edge bond being formed from a material comprising monomers, oligomers, or polymers selected from the group consisting of epoxies, acrylics, silicones, styrenics, vinyl halides, vinyl esters, polyamides, polyimides, polysulfones, polyether-sulfones, cyclic olefins, polyolefin rubbers, and polyurethanes; and a fill material in said fill zone, said fill material being a polymeric material and having an adhesion strength with respect to at least one of said device or carrier surfaces of less than 4.45 x 10 5 Pa (50 psig), as determined by ASTM D4541/D7234, wherein said edge bond has an adhesion strength that is at least 4.45 x 10 3 Pa (0.5 psig) greater than said fill material adhesion strength; separating said first and second substrates (12, 32), wherein prior to said separating, said edge bond is exposed to solvent to dissolve said edge bond, or said edge bond is mechanically disrupted using laser ablation, plasma etching, or water jetting. providing a stack comprising: a first substrate having a back surface and a device surface, said device surface having a peripheral region and a central region; a second substrate having a carrier surface; and an edge bond bonded to said peripheral region and to said carrier surface, said edge bond being absent from said central region so as to form a fill zone, said edge bond being formed from a material comprising monomers, oligomers, or polymers selected from the group consisting of epoxies, acrylics, silicones, styrenics, vinyl halides, vinyl esters, polyamides, polyimides, polysulfones, polyether-sulfones, cyclic olefins, polyolefin rubbers, and polyurethanes; and a fill material in said fill zone, said fill material being a polymeric material and having an adhesion strength with respect to at least one of said device or carrier surfaces of less than 4.45 x 10 5 Pa (50 psig), as determined by ASTM D4541/D7234, wherein said edge bond has an adhesion strength that is at least 4.45 x 10 3 Pa (0.5 psig) greater than said fill material adhesion strength; separating said first and second substrates (12, 32), wherein prior to said separating, said edge bond is exposed to solvent to dissolve said edge bond, or said edge bond is mechanically disrupted using laser ablation, plasma etching, or water jetting. a first substrate having a back surface and a device surface, said device surface having a peripheral region and a central region; a second substrate having a carrier surface; and an edge bond bonded to said peripheral region and to said carrier surface, said edge bond being absent from said central region so as to form a fill zone, said edge bond being formed from a material comprising monomers, oligomers, or polymers selected from the group consisting of epoxies, acrylics, silicones, styrenics, vinyl halides, vinyl esters, polyamides, polyimides, polysulfones, polyether-sulfones, cyclic olefins, polyolefin rubbers, and polyurethanes; and a fill material in said fill zone, said fill material being a polymeric material and having an adhesion strength with respect to at least one of said device or carrier surfaces of less than 4.45 x 10 5 Pa (50 psig), as determined by ASTM D4541/D7234, wherein said edge bond has an adhesion strength that is at least 4.45 x 10 3 Pa (0.5 psig) greater than said fill material adhesion strength; separating said first and second substrates (12, 32), wherein prior to said separating, said edge bond is exposed to solvent to dissolve said edge bond, or said edge bond is mechanically disrupted using laser ablation, plasma etching, or water jetting.