An ultra-high color rendering white light-emitting device, comprising: a semiconductor LED chip that emits a violet wavelength range of light with an emission peak at 405 nm and a half-width of 30 nm, and a phosphor layer distributed in a transparent resin layer that emits light when excited by an excitation wavelength of the violet LED chip, wherein the phosphor layer includes: a first phosphor having an emission peak at 450-470 nm, the first phosphor being (Sr,Br) 10 (PO 4) 6 Cl 2:Eu; a second phosphor having an emission peak at 510-550 nm, the second phosphor being SiAlON:EU; a third phosphor having an emission peak at 550-590 nm, the third phosphor being (Ba,Sr)Si 2 (O,Cl) 2 N 2:Eu; a fourth phosphor having an emission peak at 630-660 nm, the fourth phosphor being CaAlSi 2:Eu; and a fifth phosphor having an emission peak at 660-730 nm, the fifth phosphor being CaAlSiN 2:Eu, wherein a weight ratio of the first phosphor, the second phosphor, the third phosphor, the fourth phosphor and the fifth phosphor is 12.3: 1.0: 1.0: 5.0: 0.3, wherein the correlated color temperature is 4477K and the ultra-high color rendering white light-emitting device has a general color rendering index Ra that is 99, a special color rendering index Ri that is 94 for R9, 100 for R11, 98 for R12 and 100 for R15, and emission efficiency that is equal to or higher than 80 Im/W and up to 110 lm/W. a semiconductor LED chip that emits a violet wavelength range of light with an emission peak at 405 nm and a half-width of 30 nm, and a phosphor layer distributed in a transparent resin layer that emits light when excited by an excitation wavelength of the violet LED chip, wherein the phosphor layer includes: a first phosphor having an emission peak at 450-470 nm, the first phosphor being (Sr,Br) 10 (PO 4) 6 Cl 2:Eu; a second phosphor having an emission peak at 510-550 nm, the second phosphor being SiAlON:EU; a third phosphor having an emission peak at 550-590 nm, the third phosphor being (Ba,Sr)Si 2 (O,Cl) 2 N 2:Eu; a fourth phosphor having an emission peak at 630-660 nm, the fourth phosphor being CaAlSi 2:Eu; and a fifth phosphor having an emission peak at 660-730 nm, the fifth phosphor being CaAlSiN 2:Eu, wherein a weight ratio of the first phosphor, the second phosphor, the third phosphor, the fourth phosphor and the fifth phosphor is 12.3: 1.0: 1.0: 5.0: 0.3, wherein the correlated color temperature is 4477K and the ultra-high color rendering white light-emitting device has a general color rendering index Ra that is 99, a special color rendering index Ri that is 94 for R9, 100 for R11, 98 for R12 and 100 for R15, and emission efficiency that is equal to or higher than 80 Im/W and up to 110 lm/W. a first phosphor having an emission peak at 450-470 nm, the first phosphor being (Sr,Br) 10 (PO 4) 6 Cl 2:Eu; a second phosphor having an emission peak at 510-550 nm, the second phosphor being SiAlON:EU; a third phosphor having an emission peak at 550-590 nm, the third phosphor being (Ba,Sr)Si 2 (O,Cl) 2 N 2:Eu; a fourth phosphor having an emission peak at 630-660 nm, the fourth phosphor being CaAlSi 2:Eu; and a fifth phosphor having an emission peak at 660-730 nm, the fifth phosphor being CaAlSiN 2:Eu, wherein a weight ratio of the first phosphor, the second phosphor, the third phosphor, the fourth phosphor and the fifth phosphor is 12.3: 1.0: 1.0: 5.0: 0.3, wherein the correlated color temperature is 4477K and the ultra-high color rendering white light-emitting device has a general color rendering index Ra that is 99, a special color rendering index Ri that is 94 for R9, 100 for R11, 98 for R12 and 100 for R15, and emission efficiency that is equal to or higher than 80 Im/W and up to 110 lm/W.