Metal-clad laminates comprising crosslinkable, organopolysiloxane compounds of the formula [O 3-a/2 R a Si-Y(SiR a O 3-a/2) b] c (R 1 SiO 3/2) d (R 2 2 SiO 2/2) e (R 3 3 SiO 1/2) f (SiO 4/2) g where R may be identical or different and is either a hydrogen radical or a monovalent SiC-bonded organic hydrocarbon radical having 1 to 18 carbon atoms and optionally substituted with heteroatoms, Y is a divalent to dodecavalent organic radical having 1 to 24 carbon atoms and optionally substituted with heteroatoms, where the radical Y is always attached by an Si-C bond to the silicon atoms connected to each other by the radical Y, R 1 is independently of one another a hydrogen radical or an SiC-bonded unsaturated C1-C18 hydrocarbon radical that may optionally be substituted with heteroatoms and that optionally may also be attached to the silicon atom via an oxygen atom, where the radicals R 1 may each assume their meaning independently of one another, such that a plurality of radicals R 1 in the organopolysiloxane according to formula may be different radicals from the defined group, the radicals R 2 and R 3 are independently of one another a hydrogen radical or an optionally unsaturated SiC-bonded C1-C18 hydrocarbon radical that may optionally be substituted with heteroatoms, or a C1-C12 hydrocarbon radical that optionally contains heteroatoms and is attached via an oxygen atom, where the radicals R 2 and the radicals R 3 may each assume their meaning independently of one another, such that a plurality of radicals R 2 or a plurality of radicals R 3 attached to the same silicon atom may be different radicals from the defined group, where, based on all SiC-bonded radicals Y, R, R 1, R 2 and R 3 as 100 mol%, at least 0.1 mol% must be aliphatically unsaturated radicals, a is 0, 1 or 2, where the indices a on either side of the group Y may assume their meaning independently of one another, such that different a may independently of one another be different values within the range of values specified, b is a number having a value from 1 to 11, c is a value from 0.1 to 0.99, d is a value from 0 to 0.8, e is a value from 0 to 0.5, f is a value from 0.01 to 0.6 and g is a value from 0 to 0.2, where c+d+e+f+g is 1. where R may be identical or different and is either a hydrogen radical or a monovalent SiC-bonded organic hydrocarbon radical having 1 to 18 carbon atoms and optionally substituted with heteroatoms, Y is a divalent to dodecavalent organic radical having 1 to 24 carbon atoms and optionally substituted with heteroatoms, where the radical Y is always attached by an Si-C bond to the silicon atoms connected to each other by the radical Y, R 1 is independently of one another a hydrogen radical or an SiC-bonded unsaturated C1-C18 hydrocarbon radical that may optionally be substituted with heteroatoms and that optionally may also be attached to the silicon atom via an oxygen atom, where the radicals R 1 may each assume their meaning independently of one another, such that a plurality of radicals R 1 in the organopolysiloxane according to formula may be different radicals from the defined group, the radicals R 2 and R 3 are independently of one another a hydrogen radical or an optionally unsaturated SiC-bonded C1-C18 hydrocarbon radical that may optionally be substituted with heteroatoms, or a C1-C12 hydrocarbon radical that optionally contains heteroatoms and is attached via an oxygen atom, where the radicals R 2 and the radicals R 3 may each assume their meaning independently of one another, such that a plurality of radicals R 2 or a plurality of radicals R 3 attached to the same silicon atom may be different radicals from the defined group, where, based on all SiC-bonded radicals Y, R, R 1, R 2 and R 3 as 100 mol%, at least 0.1 mol% must be aliphatically unsaturated radicals, a is 0, 1 or 2, where the indices a on either side of the group Y may assume their meaning independently of one another, such that different a may independently of one another be different values within the range of values specified, b is a number having a value from 1 to 11, c is a value from 0.1 to 0.99, d is a value from 0 to 0.8, e is a value from 0 to 0.5, f is a value from 0.01 to 0.6 and g is a value from 0 to 0.2, where c+d+e+f+g is 1.