Process for preparing polysulfane silanes of the formula I (R 1 O) 3-m R 2 m Si-R 3 -S x -R 3 -SiR 2 m (OR 1) 3-m I, wherein R 1 are identical or different and are C1-C10 alkyl groups, phenyl groups or alkyl polyether groups -(R'-O) r -R", where R' are identical or different and are a branched or unbranched, saturated or unsaturated, aliphatic, aromatic or mixed aliphatic/aromatic divalent C1-C30 hydrocarbon group, r is an integer from 1 to 30, and R" are unsubstituted or substituted, branched or unbranched monovalent alkyl, alkenyl, aryl or aralkyl group, R 2 are identical or different and are C6-C20 aryl groups, C1-C10 alkyl groups, C2-C20 alkenyl groups, C7-C20 aralkyl groups or halogens, R 3 are identical or different and are a branched or unbranched, saturated or unsaturated, aliphatic, aromatic or mixed aliphatic/aromatic divalent C1-C30 hydrocarbon groups, and m are identical or different and are 0, 1, 2 or 3, x is 1-10, by reaction of silane of the formula II (R 1 O) 3-m R 2 m Si-R 3 -Hal II where R 1, R 2, R 3 and m are as defined above and Hal is a halogen, with one or more metal sulfides of the formula III Me f and/or Me 3-f S x-y III where Me is an element of main group 1 or 2, f = 1 for Me of main group 1 and f = 2 for Me of main group 2 and y has a value from 0 to x-1, optionally in the presence of one or more salts of monohydric or polyhydric acids, with the optional addition of y mol of sulfur, in aqueous R 1 -OH solvent, wherein R 1 is as defined above, the water content of the aqueous R 1 -OH solution is 5% to 40% by weight, characterized in that a. the process stream from the reaction of silane of the formula II with one or more metal sulfides of the formula III, optionally in the presence of one or more salts and optionally with the addition of sulfur, in aqueous R 1 -OH solution, comprising polysulfane silanes of the formula I, solvent R 1 -OH, water and process salts, is combined with the wash solution from step d, comprising solvent R 1 -OH, water and polysulfane silanes of the formula I, b. the solvent R 1 -OH and water are removed by distillation, c. the remaining suspension comprising polysulfane silane of the formula I and process salt is subjected to a filtration or a sedimentation and d. the process salt from step c is washed with solvent R 1 -OH and then dried, the wash solution comprising solvent R 1 -OH, water and polysulfane silane of the formula I is recycled to process step a. wherein R 1 are identical or different and are C1-C10 alkyl groups, phenyl groups or alkyl polyether groups -(R'-O) r -R", where R' are identical or different and are a branched or unbranched, saturated or unsaturated, aliphatic, aromatic or mixed aliphatic/aromatic divalent C1-C30 hydrocarbon group, r is an integer from 1 to 30, and R" are unsubstituted or substituted, branched or unbranched monovalent alkyl, alkenyl, aryl or aralkyl group, R 2 are identical or different and are C6-C20 aryl groups, C1-C10 alkyl groups, C2-C20 alkenyl groups, C7-C20 aralkyl groups or halogens, R 3 are identical or different and are a branched or unbranched, saturated or unsaturated, aliphatic, aromatic or mixed aliphatic/aromatic divalent C1-C30 hydrocarbon groups, and m are identical or different and are 0, 1, 2 or 3, x is 1-10, by reaction of silane of the formula II (R 1 O) 3-m R 2 m Si-R 3 -Hal II where R 1, R 2, R 3 and m are as defined above and Hal is a halogen, with one or more metal sulfides of the formula III Me f and/or Me 3-f S x-y III where Me is an element of main group 1 or 2, f = 1 for Me of main group 1 and f = 2 for Me of main group 2 and y has a value from 0 to x-1, optionally in the presence of one or more salts of monohydric or polyhydric acids, with the optional addition of y mol of sulfur, in aqueous R 1 -OH solvent, wherein R 1 is as defined above, the water content of the aqueous R 1 -OH solution is 5% to 40% by weight, characterized in that a. the process stream from the reaction of silane of the formula II with one or more metal sulfides of the formula III, optionally in the presence of one or more salts and optionally with the addition of sulfur, in aqueous R 1 -OH solution, comprising polysulfane silanes of the formula I, solvent R 1 -OH, water and process salts, is combined with the wash solution from step d, comprising solvent R 1 -OH, water and polysulfane silanes of the formula I, b. the solvent R 1 -OH and water are removed by distillation, c. the remaining suspension comprising polysulfane silane of the formula I and process salt is subjected to a filtration or a sedimentation and d. the process salt from step c is washed with solvent R 1 -OH and then dried, a. the process stream from the reaction of silane of the formula II with one or more metal sulfides of the formula III, optionally in the presence of one or more salts and optionally with the addition of sulfur, in aqueous R 1 -OH solution, comprising polysulfane silanes of the formula I, solvent R 1 -OH, water and process salts, is combined with the wash solution from step d, comprising solvent R 1 -OH, water and polysulfane silanes of the formula I, b. the solvent R 1 -OH and water are removed by distillation, c. the remaining suspension comprising polysulfane silane of the formula I and process salt is subjected to a filtration or a sedimentation and d. the process salt from step c is washed with solvent R 1 -OH and then dried, the wash solution comprising solvent R 1 -OH, water and polysulfane silane of the formula I is recycled to process step a.