A sample extraction device comprising: a cavity containing a sorbent, the cavity having a first opening at an extraction end of the sample extraction device and a second opening fluidly coupled to a valve end of the sample extraction device; a valve located at the valve end of the sample extraction device; an internal seal configured to selectively restrict fluid flow through the cavity, the internal seal disposed at the valve end of the sample extraction device; a plurality of external seals including a first external seal and a second external seal, the plurality of external seals disposed around an outside of the sample extraction device between the extraction end of the sample extraction device and the valve end of the sample extraction device; a port that is fluidly coupled to the cavity and open to an environment external to the sample extraction device, wherein an opening of the port is located between the first external seal and the second external seal on the outside of the sample extraction device, wherein: the plurality of external seals are configured to form a seal between the sample extraction device and a sample vial, thereby sealing the port from the environment external to the sample extraction device, the valve at the valve end of the sample extraction device is configured to couple to a vacuum source, wherein a sealing plunger of the valve is configured to be opened and the sorbent of the sample extraction device is configured to collect a sample, and the sample extraction device is configured to be coupled to a desorption device, the port is configured to accept a carrier fluid. a cavity containing a sorbent, the cavity having a first opening at an extraction end of the sample extraction device and a second opening fluidly coupled to a valve end of the sample extraction device; a valve located at the valve end of the sample extraction device; an internal seal configured to selectively restrict fluid flow through the cavity, the internal seal disposed at the valve end of the sample extraction device; a plurality of external seals including a first external seal and a second external seal, the plurality of external seals disposed around an outside of the sample extraction device between the extraction end of the sample extraction device and the valve end of the sample extraction device; a port that is fluidly coupled to the cavity and open to an environment external to the sample extraction device, wherein an opening of the port is located between the first external seal and the second external seal on the outside of the sample extraction device, wherein: the plurality of external seals are configured to form a seal between the sample extraction device and a sample vial, thereby sealing the port from the environment external to the sample extraction device, the valve at the valve end of the sample extraction device is configured to couple to a vacuum source, wherein a sealing plunger of the valve is configured to be opened and the sorbent of the sample extraction device is configured to collect a sample, and the sample extraction device is configured to be coupled to a desorption device, the port is configured to accept a carrier fluid. the plurality of external seals are configured to form a seal between the sample extraction device and a sample vial, thereby sealing the port from the environment external to the sample extraction device, the valve at the valve end of the sample extraction device is configured to couple to a vacuum source, wherein a sealing plunger of the valve is configured to be opened and the sorbent of the sample extraction device is configured to collect a sample, and the sample extraction device is configured to be coupled to a desorption device, the port is configured to accept a carrier fluid.