A shampoo composition comprising: a) from 5 to 50% by weight of the composition of an anionic surfactant; b) from 0.05% to 10% by weight of a dispersed, water insoluble, solid, temperature stable particle that is not a liquid or gas at any temperature below 95°C; c) from 0.025% to 5% by weight of an organic, non crosslinked, cationic homopolymer or copolymer having a cationic charge density of from 3 meq/gm to 8 meq/gm and an average molecular weight of from 1,000 to 2,000,000; d) from 0.1% to 5%, by weight, of a phase separation initiator selected from the group consisting of electrolytes, amphiphiles and mixtures thereof; and e) from 50% to 95%, by weight, of water, and wherein said cationic homopolymer or copolymer promotes the formation of a microscopic-phase separation of lyotropic liquid crystals in said composition, and further wherein said cationic homopolymer or copolymer has the following structure: in which: • A is one or more of the following cationic moieties: Where @ = amido, alkylamido, ester, ether, alkyl or alkylaryl; Where Y = C1-C22 alkyl, alkoxy, alkylidene, alkyl or aryloxy; Where ψ = C1-C22 alkyl, alkyloxy, alkyl aryl or alkyl aryloxy; Where Z = C1-C22 alkyl, alkyloxy, aryl or aryloxy; Where R1 = H, C1-C4 linear or branched alkyl; Where s = 0 or 1, n = 0 or ≥ 1; Where T and R7 = C1-C22 alkyl; and Where X- = halogen, hydroxide, alkoxide, sulfate or alkylsulfate • The monomer bearing a negative charge is defined by R2' = H, C1-C4 linear or branched alkyl and R3 as: Where D = electronegative element chosen between oxygen, nitrogen, sulfur; Where Q = NH 2 or O; Where u =1-6; Where t = 0-1; and Where J = oxygenated functional group containing the following elements P, S, C • The nonionic monomer is defined by R2" = H, C1-C4 linear or branched alkyl, R6 = linear or branched alkyl, alkyl aryl, aryl oxy, alkyloxy, alkylaryl oxy and β is defined as Where G' and G" are, independently of one another, O, S or N-H; and Where L =0 or 1. a) from 5 to 50% by weight of the composition of an anionic surfactant; b) from 0.05% to 10% by weight of a dispersed, water insoluble, solid, temperature stable particle that is not a liquid or gas at any temperature below 95°C; c) from 0.025% to 5% by weight of an organic, non crosslinked, cationic homopolymer or copolymer having a cationic charge density of from 3 meq/gm to 8 meq/gm and an average molecular weight of from 1,000 to 2,000,000; d) from 0.1% to 5%, by weight, of a phase separation initiator selected from the group consisting of electrolytes, amphiphiles and mixtures thereof; and e) from 50% to 95%, by weight, of water, and wherein said cationic homopolymer or copolymer promotes the formation of a microscopic-phase separation of lyotropic liquid crystals in said composition, and further wherein said cationic homopolymer or copolymer has the following structure: in which: • A is one or more of the following cationic moieties: Where @ = amido, alkylamido, ester, ether, alkyl or alkylaryl; Where Y = C1-C22 alkyl, alkoxy, alkylidene, alkyl or aryloxy; Where ψ = C1-C22 alkyl, alkyloxy, alkyl aryl or alkyl aryloxy; Where Z = C1-C22 alkyl, alkyloxy, aryl or aryloxy; Where R1 = H, C1-C4 linear or branched alkyl; Where s = 0 or 1, n = 0 or ≥ 1; Where T and R7 = C1-C22 alkyl; and Where X- = halogen, hydroxide, alkoxide, sulfate or alkylsulfate • The monomer bearing a negative charge is defined by R2' = H, C1-C4 linear or branched alkyl and R3 as: Where D = electronegative element chosen between oxygen, nitrogen, sulfur; Where Q = NH 2 or O; Where u =1-6; Where t = 0-1; and Where J = oxygenated functional group containing the following elements P, S, C • The nonionic monomer is defined by R2" = H, C1-C4 linear or branched alkyl, R6 = linear or branched alkyl, alkyl aryl, aryl oxy, alkyloxy, alkylaryl oxy and β is defined as Where G' and G" are, independently of one another, O, S or N-H; and Where L =0 or 1. • A is one or more of the following cationic moieties: Where @ = amido, alkylamido, ester, ether, alkyl or alkylaryl; Where Y = C1-C22 alkyl, alkoxy, alkylidene, alkyl or aryloxy; Where ψ = C1-C22 alkyl, alkyloxy, alkyl aryl or alkyl aryloxy; Where Z = C1-C22 alkyl, alkyloxy, aryl or aryloxy; Where R1 = H, C1-C4 linear or branched alkyl; Where s = 0 or 1, n = 0 or ≥ 1; Where T and R7 = C1-C22 alkyl; and Where X- = halogen, hydroxide, alkoxide, sulfate or alkylsulfate Where @ = amido, alkylamido, ester, ether, alkyl or alkylaryl; Where Y = C1-C22 alkyl, alkoxy, alkylidene, alkyl or aryloxy; Where ψ = C1-C22 alkyl, alkyloxy, alkyl aryl or alkyl aryloxy; Where Z = C1-C22 alkyl, alkyloxy, aryl or aryloxy; Where R1 = H, C1-C4 linear or branched alkyl; Where s = 0 or 1, n = 0 or ≥ 1; Where T and R7 = C1-C22 alkyl; and Where X- = halogen, hydroxide, alkoxide, sulfate or alkylsulfate • The monomer bearing a negative charge is defined by R2' = H, C1-C4 linear or branched alkyl and R3 as: Where D = electronegative element chosen between oxygen, nitrogen, sulfur; Where Q = NH 2 or O; Where u =1-6; Where t = 0-1; and Where J = oxygenated functional group containing the following elements P, S, C Where D = electronegative element chosen between oxygen, nitrogen, sulfur; Where Q = NH 2 or O; Where u =1-6; Where t = 0-1; and Where J = oxygenated functional group containing the following elements P, S, C • The nonionic monomer is defined by R2" = H, C1-C4 linear or branched alkyl, R6 = linear or branched alkyl, alkyl aryl, aryl oxy, alkyloxy, alkylaryl oxy and β is defined as Where G' and G" are, independently of one another, O, S or N-H; and Where L =0 or 1. Where G' and G" are, independently of one another, O, S or N-H; and Where L =0 or 1.