A multilayer cast film having a cling layer and a release layer, wherein: the cling layer comprises: (i) a first polyethylene composition which comprises the reaction product of ethylene and, optionally, one or more alpha olefin comonomers, wherein the first polyethylene composition is characterized by the following properties: (a) a melt index, I 2, of greater than 5.0 to 12.0 g/10 min; (b) a density of 0.905 to 0.920 g/cc; (c) a melt flow ratio, I 10 /I 2, of 6.0 to 7.6; and (d) a molecular weight distribution, (Mw/Mn) of from 2.6 to 3.5 and (ii) a polymer selected from ethylene/alpha-olefin elastomer, propylene-based elastomer, or combinations thereof; and the release layer comprises a second polyethylene composition which comprises the reaction product of ethylene and, optionally, one or more alpha olefin comonomers, wherein the second polyethylene composition is characterized by the following properties: (a) a melt index, I 2, of greater than 5.0 to 12.0 g/10 min; (b) a density of 0.905 to 0.920 g/cc; (c) a melt flow ratio, I 10 /I 2, of 6.0 to 7.6; and (d) a molecular weight distribution, (Mw/Mn) of from 2.6 to 4.0; wherein the multilayer cast film comprises one or more core layers positioned between the cling layer and the release layer; wherein the first and second polyethylene compositions are formed in the presence of a catalyst composition comprising a multi-metallic procatalyst via solution polymerization; wherein melt index is measured in accordance with ASTM D1238-13; and wherein density is measured in accordance with ASTM D792. the cling layer comprises: (i) a first polyethylene composition which comprises the reaction product of ethylene and, optionally, one or more alpha olefin comonomers, wherein the first polyethylene composition is characterized by the following properties: (a) a melt index, I 2, of greater than 5.0 to 12.0 g/10 min; (b) a density of 0.905 to 0.920 g/cc; (c) a melt flow ratio, I 10 /I 2, of 6.0 to 7.6; and (d) a molecular weight distribution, (Mw/Mn) of from 2.6 to 3.5 and (ii) a polymer selected from ethylene/alpha-olefin elastomer, propylene-based elastomer, or combinations thereof; and (i) a first polyethylene composition which comprises the reaction product of ethylene and, optionally, one or more alpha olefin comonomers, wherein the first polyethylene composition is characterized by the following properties: (a) a melt index, I 2, of greater than 5.0 to 12.0 g/10 min; (b) a density of 0.905 to 0.920 g/cc; (c) a melt flow ratio, I 10 /I 2, of 6.0 to 7.6; and (d) a molecular weight distribution, (Mw/Mn) of from 2.6 to 3.5 and (a) a melt index, I 2, of greater than 5.0 to 12.0 g/10 min; (b) a density of 0.905 to 0.920 g/cc; (c) a melt flow ratio, I 10 /I 2, of 6.0 to 7.6; and (d) a molecular weight distribution, (Mw/Mn) of from 2.6 to 3.5 and (ii) a polymer selected from ethylene/alpha-olefin elastomer, propylene-based elastomer, or combinations thereof; and the release layer comprises a second polyethylene composition which comprises the reaction product of ethylene and, optionally, one or more alpha olefin comonomers, wherein the second polyethylene composition is characterized by the following properties: (a) a melt index, I 2, of greater than 5.0 to 12.0 g/10 min; (b) a density of 0.905 to 0.920 g/cc; (c) a melt flow ratio, I 10 /I 2, of 6.0 to 7.6; and (d) a molecular weight distribution, (Mw/Mn) of from 2.6 to 4.0; (a) a melt index, I 2, of greater than 5.0 to 12.0 g/10 min; (b) a density of 0.905 to 0.920 g/cc; (c) a melt flow ratio, I 10 /I 2, of 6.0 to 7.6; and (d) a molecular weight distribution, (Mw/Mn) of from 2.6 to 4.0; wherein the multilayer cast film comprises one or more core layers positioned between the cling layer and the release layer; wherein the first and second polyethylene compositions are formed in the presence of a catalyst composition comprising a multi-metallic procatalyst via solution polymerization; wherein melt index is measured in accordance with ASTM D1238-13; and wherein density is measured in accordance with ASTM D792.