A compound of the formula wherein the bond between carbon atoms 22 and 23 indicated with a broken line is a single or double bond, the symbols δ, ε, φ, η, κ, λ and γ represent that the configuration of the corresponding carbon atom can be or. n is 0, 1 or 2, R 1 represents a C 1 -C 12 alkyl, C 3 -C 8 cycloalkyl or C 2 -C 12 alkenyl group, R 2 represents R 15, R 15 O, R 16 OC(=O)O-; R 3 represents R 15 O or R 16 OC(=O)O-; R 4 represents R 16 R 17 N, R 16 N, R 16 (R 17 O)N, R 16 C(=O)R 17 N, R 16 C(=O)(OR 17)N, R 15 OC(=O)R 17 N, R 15 OC(=O)(OR 17)N, R 15 SO 2 R 17 N, R 16 R 17 NO, R 16 NO, (R 16 R 17 C=)NO, R 16 C(=O)R 17 NO, R 18 R 19 N-R 17 N, R 18 N-R 17 N, R 18 (R 19 O)N-R 17 N, R 18 R 19 N-C(=O)-O, R 18 R 19 N-C(=O)R 17 N, or a R 18 R 19 N-SO 2 R 17 N group; R 5 represents hydrogen, a hydrocarbyl or R 4 and R 5 together represent =O, =NR 9 or =CR 10 R 11, and R 6 represents R 16, R 16 OCH 2, R 16 C(=O)OCH 2, R 15 OC(=O)OCH 2, R 16 C(=S)OCH 2, R 16 SCH 2, R 16 C(=O)SCH 2, R 16 C(=S)SCH 2, R 16 R 17 NCH 2, R 16 NCH 2, R 16 (R 17 O)NCH 2, R 16 C(=O)NR 17 CH 2, R 16 C(=O)N(OR 17)CH 2, R 15 OC(=O)NR 17 CH 2, R 15 OC(=O)N(OR 17)CH 2, R 15 SO 2 NR 17 CH 2, R 16 R 17 NOCH 2, R 16 NOCH 2, R 16 (R 17 O)NOCH 2, R 16 C(=O)NR 17 OCH 2, R 18 R 19 N-NR 17 CH 2, R 18 N-NR 17 CH 2, R 18 (R 19 O)N-NR 17 CH 2, R 18 R 19 N-C(=O)-OCH 2, R 18 R 19 N-C(=O)NR 17 CH 2, or a R 18 R 19 N-SO 2 NR 17 CH 2 group; wherein R 7 and R 8 represent, independently of each other, hydrogen, or a C 1 -C 6 alkyl group, R 9 represents a hydrogen, or a R 2 group, R 10 and R 11 represent, independently of each other, hydrogen, halogen, cyano, formyl, C OR 12, C NR 13 R 14, C 1 -C 6 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 6 cycloalkyl, aryl, or heteroaryl group, R 15 represents C 1 -C 6 alkyl, and R 12, R 13, R 14, R 16, R 17, R 18 and R 19 represent, independently of each other, hydrogen or R 15, or R 16 and R 17, or R 18 and R 19, together represent, independently of each other, a three- to ten-membered ring, optionally containing heteroatoms; and if appropriate, an E/Z isomer and/or diastereoisomer and/or tautomer of the compound of formula, in each case in free form or in salt form. n is 0, 1 or 2, R 1 represents a C 1 -C 12 alkyl, C 3 -C 8 cycloalkyl or C 2 -C 12 alkenyl group, R 2 represents R 15, R 15 O, R 16 OC(=O)O-; R 3 represents R 15 O or R 16 OC(=O)O-; R 4 represents R 16 R 17 N, R 16 N, R 16 (R 17 O)N, R 16 C(=O)R 17 N, R 16 C(=O)(OR 17)N, R 15 OC(=O)R 17 N, R 15 OC(=O)(OR 17)N, R 15 SO 2 R 17 N, R 16 R 17 NO, R 16 NO, (R 16 R 17 C=)NO, R 16 C(=O)R 17 NO, R 18 R 19 N-R 17 N, R 18 N-R 17 N, R 18 (R 19 O)N-R 17 N, R 18 R 19 N-C(=O)-O, R 18 R 19 N-C(=O)R 17 N, or a R 18 R 19 N-SO 2 R 17 N group; R 5 represents hydrogen, a hydrocarbyl or R 4 and R 5 together represent =O, =NR 9 or =CR 10 R 11, and R 6 represents R 16, R 16 OCH 2, R 16 C(=O)OCH 2, R 15 OC(=O)OCH 2, R 16 C(=S)OCH 2, R 16 SCH 2, R 16 C(=O)SCH 2, R 16 C(=S)SCH 2, R 16 R 17 NCH 2, R 16 NCH 2, R 16 (R 17 O)NCH 2, R 16 C(=O)NR 17 CH 2, R 16 C(=O)N(OR 17)CH 2, R 15 OC(=O)NR 17 CH 2, R 15 OC(=O)N(OR 17)CH 2, R 15 SO 2 NR 17 CH 2, R 16 R 17 NOCH 2, R 16 NOCH 2, R 16 (R 17 O)NOCH 2, R 16 C(=O)NR 17 OCH 2, R 18 R 19 N-NR 17 CH 2, R 18 N-NR 17 CH 2, R 18 (R 19 O)N-NR 17 CH 2, R 18 R 19 N-C(=O)-OCH 2, R 18 R 19 N-C(=O)NR 17 CH 2, or a R 18 R 19 N-SO 2 NR 17 CH 2 group; R 7 and R 8 represent, independently of each other, hydrogen, or a C 1 -C 6 alkyl group, R 9 represents a hydrogen, or a R 2 group, R 10 and R 11 represent, independently of each other, hydrogen, halogen, cyano, formyl, C OR 12, C NR 13 R 14, C 1 -C 6 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 6 cycloalkyl, aryl, or heteroaryl group, R 15 represents C 1 -C 6 alkyl, and R 12, R 13, R 14, R 16, R 17, R 18 and R 19 represent, independently of each other, hydrogen or R 15, or R 16 and R 17, or R 18 and R 19, together represent, independently of each other, a three- to ten-membered ring, optionally containing heteroatoms;