A system comprising: (a) a container, of which at least a portion of an interior wall surface is to be coated, comprising an open end, a second end opposite the open end, and a wall extending there between, the wall having an exterior wall surface and an interior wall surface, the container having a chamber within an area defined by the interior wall surface between the open end and the second end of the container, wherein the chamber is sealed from an exterior of the container and the container acts as its own vacuum chamber; (b) a monomer gas supply source containing at least one monomer gas; (c) a gas inlet duct positioned at the open end of the container and having a portion extending into a portion of the chamber for supplying at least one monomer gas received from the monomer gas supply source into the chamber; (d) a pyrolyzing surface for pyrolyzing at least a portion of the monomer gas supplied to the chamber of the container to form a reactive gas comprising at least one reactive moiety from the monomer gas; (e) a temperature controller proximate to the exterior wall surface of the container to promote cooling of the exterior wall surface for maintaining the interior wall surface of the container at a desired temperature to facilitate deposition and polymerization of the reactive moiety on at least a portion of the interior wall surface of the container; and (f) an outlet duct positioned at the open end of the container or the second end of the container for removing excess reactive gas from the chamber, wherein the monomer gas comprises at least one monomer selected from the group consisting of organosilicon monomers, halocarbon monomers, azurine monomers, thiirane monomers, unsaturated olefinic monomers and mixtures thereof. (a) a container, of which at least a portion of an interior wall surface is to be coated, comprising an open end, a second end opposite the open end, and a wall extending there between, the wall having an exterior wall surface and an interior wall surface, the container having a chamber within an area defined by the interior wall surface between the open end and the second end of the container, wherein the chamber is sealed from an exterior of the container and the container acts as its own vacuum chamber; (b) a monomer gas supply source containing at least one monomer gas; (c) a gas inlet duct positioned at the open end of the container and having a portion extending into a portion of the chamber for supplying at least one monomer gas received from the monomer gas supply source into the chamber; (d) a pyrolyzing surface for pyrolyzing at least a portion of the monomer gas supplied to the chamber of the container to form a reactive gas comprising at least one reactive moiety from the monomer gas; (e) a temperature controller proximate to the exterior wall surface of the container to promote cooling of the exterior wall surface for maintaining the interior wall surface of the container at a desired temperature to facilitate deposition and polymerization of the reactive moiety on at least a portion of the interior wall surface of the container; and (f) an outlet duct positioned at the open end of the container or the second end of the container for removing excess reactive gas from the chamber,