A hydrogel composition comprising an alpha, beta-unsaturated amido-containing organosilicon compounds having the structure of Formula: wherein: R 1, R 2, and R 3 are independently chosen from hydrogen, an alkyl group containing from 1 to 3 carbon atoms, a phenyl group, or R 7 C(=O)OR 8, wherein R 7 is a chemical bond or an alkylene group containing from 1 to 6 carbon atoms, and R 8 is hydrogen or an alkyl group of from 1 to 3 carbon atoms; R 4 is hydrogen, an alkyl group containing from 1 to 6 carbon atoms, or a phenyl group; R 5 is an alkylene, containing from 1 to 16 carbon atoms and optionally a heteroatom of oxygen, sulfur, nitrogen, or a combination of two or more thereof; A is oxygen or sulfur; G is a hydroxyl-substituted cycloalkylene group; R 6 is a chemical bond or an alkylene group containing from 1 to 16 carbon atoms and optionally a heteroatom of oxygen, sulfur, nitrogen, or a combination of two or more thereof; X 1 is a methyl, trimethylsiloxy, or -O[Si(CH 3) 2 O-] n, wherein n is an integer of from 1 to 9; X 2 is methyl, trimethylsiloxy or -[OSi(CH 3) 2] m G 1, wherein G 1 is (CH 3) 3 SiOO- or H(CH 3) 2 SiO-, or an alpha, beta- unsaturated amidocontaining group with the general formula: and m is an integer from 0 to 200, with the proviso that when X 2 is -[OSi(CH 3) 2] m G 1, then X 1 and X 3 is methyl; X 3 is methyl, trimethylsiloxy, (CH 3) 3 SiCH 2 CH 2 -, (CH 3) 3 SiCH 2 CH 2 Si(CH 3) 2 O-, or -OSi(CH 3) 2, with the provisos that (i) when X 1 is -O[Si(CH 3) 2 O-] n, then X 3 is -OSi(CH 3) 2 and X 1 forms a chemical bond with the X 3 to form a divalent -X 1 -X 3 - group, which is bonded to the silicon atom to form a cyclic polysiloxane ring, (ii) when X 3 is -OSi(CH 3) 2, then X 1 is -O[Si(CH 3) 2 O-] n and X 1 forms a chemical bond with the X 3 to form a divalent -X 1 -X 3 - group, which is bonded to the silicon atom to form a cyclic polysiloxane ring. R 1, R 2, and R 3 are independently chosen from hydrogen, an alkyl group containing from 1 to 3 carbon atoms, a phenyl group, or R 7 C(=O)OR 8, wherein R 7 is a chemical bond or an alkylene group containing from 1 to 6 carbon atoms, and R 8 is hydrogen or an alkyl group of from 1 to 3 carbon atoms; R 4 is hydrogen, an alkyl group containing from 1 to 6 carbon atoms, or a phenyl group; R 5 is an alkylene, containing from 1 to 16 carbon atoms and optionally a heteroatom of oxygen, sulfur, nitrogen, or a combination of two or more thereof; A is oxygen or sulfur; G is a hydroxyl-substituted cycloalkylene group; R 6 is a chemical bond or an alkylene group containing from 1 to 16 carbon atoms and optionally a heteroatom of oxygen, sulfur, nitrogen, or a combination of two or more thereof; X 1 is a methyl, trimethylsiloxy, or -O[Si(CH 3) 2 O-] n, wherein n is an integer of from 1 to 9; X 2 is methyl, trimethylsiloxy or -[OSi(CH 3) 2] m G 1, wherein G 1 is (CH 3) 3 SiOO- or H(CH 3) 2 SiO-, or an alpha, beta- unsaturated amidocontaining group with the general formula: and m is an integer from 0 to 200, with the proviso that when X 2 is -[OSi(CH 3) 2] m G 1, then X 1 and X 3 is methyl; X 3 is methyl, trimethylsiloxy, (CH 3) 3 SiCH 2 CH 2 -, (CH 3) 3 SiCH 2 CH 2 Si(CH 3) 2 O-, or -OSi(CH 3) 2, with the provisos that (i) when X 1 is -O[Si(CH 3) 2 O-] n, then X 3 is -OSi(CH 3) 2 and X 1 forms a chemical bond with the X 3 to form a divalent -X 1 -X 3 - group, which is bonded to the silicon atom to form a cyclic polysiloxane ring, (ii) when X 3 is -OSi(CH 3) 2, then X 1 is -O[Si(CH 3) 2 O-] n and X 1 forms a chemical bond with the X 3 to form a divalent -X 1 -X 3 - group, which is bonded to the silicon atom to form a cyclic polysiloxane ring.