A multilayer film for making pouches containing flowable materials, said multi-layer film comprising the following layers in order, from an at least one inner sealant-layer to at least one core layer and to an at least one outer sealant-layer for: packaging liquids comprising: at least one outer sealant layer and at least one inner sealant layer, each layer comprising an α-interpolymer composition comprises from 50-75% by weight of a first ethylene/α-olefin copolymer fraction having a density in the range of 0.894 to 0.908 g/cc; a melt index in the range of 0.2 to 1 g/10 min.; and from 25 to 50 percent by weight of a second ethylene/α-olefin copolymer fraction and wherein the interpolymer has a density in the range of 0.910 to 0.924 g/cc and a melt index in the range from 0.5 to 2 g/10 min; a zero shear viscosity ratio (ZSVR) in the range of from 1.15 to 2.5; a molecular weight distribution, expressed as the ratio of the weight average molecular weight (Mw/Mn), in the range of 2.0 to 4.0; at least one core layer selected from the group consisting of: a core layer comprising linear low density polyethylene, ethylene/octene-1 copolymer having a melt index of 1.0 g/10 min. and a density of 0.916 g/cc; a core layer comprising 30-100% by weight of linear low density polyethylene, ethylene/octene -1 copolymer having a melt index of 1.0 g/10 min. and a density of 0.916 g/cc and 70-0% of ethylene butane copolymer having a melt index of 1.0 g/10 min and a density of 0.918 g/cc; and a core layer comprising 30-100% by weight of linear low density polyethylene, ethylene/hexene -1 copolymer having a melt index of 1.0 g/10 min. and density of 0.916 g/cc and 70-0% by weight of a linear low density ethylene/hexene copolymer having a melt index of 1.0 g/10 min. and a density of 0.918 g/cc (density is measured according to ASTM D 792 and melt index according to ASTM D 1238). at least one outer sealant layer and at least one inner sealant layer, each layer comprising an α-interpolymer composition comprises from 50-75% by weight of a first ethylene/α-olefin copolymer fraction having a density in the range of 0.894 to 0.908 g/cc; a melt index in the range of 0.2 to 1 g/10 min.; and from 25 to 50 percent by weight of a second ethylene/α-olefin copolymer fraction and wherein the interpolymer has a density in the range of 0.910 to 0.924 g/cc and a melt index in the range from 0.5 to 2 g/10 min; a zero shear viscosity ratio (ZSVR) in the range of from 1.15 to 2.5; a molecular weight distribution, expressed as the ratio of the weight average molecular weight (Mw/Mn), in the range of 2.0 to 4.0; at least one core layer selected from the group consisting of: a core layer comprising linear low density polyethylene, ethylene/octene-1 copolymer having a melt index of 1.0 g/10 min. and a density of 0.916 g/cc; a core layer comprising 30-100% by weight of linear low density polyethylene, ethylene/octene -1 copolymer having a melt index of 1.0 g/10 min. and a density of 0.916 g/cc and 70-0% of ethylene butane copolymer having a melt index of 1.0 g/10 min and a density of 0.918 g/cc; and a core layer comprising 30-100% by weight of linear low density polyethylene, ethylene/hexene -1 copolymer having a melt index of 1.0 g/10 min. and density of 0.916 g/cc and 70-0% by weight of a linear low density ethylene/hexene copolymer having a melt index of 1.0 g/10 min. and a density of 0.918 g/cc (density is measured according to ASTM D 792 and melt index according to ASTM D 1238). a core layer comprising linear low density polyethylene, ethylene/octene-1 copolymer having a melt index of 1.0 g/10 min. and a density of 0.916 g/cc; a core layer comprising 30-100% by weight of linear low density polyethylene, ethylene/octene -1 copolymer having a melt index of 1.0 g/10 min. and a density of 0.916 g/cc and 70-0% of ethylene butane copolymer having a melt index of 1.0 g/10 min and a density of 0.918 g/cc; and a core layer comprising 30-100% by weight of linear low density polyethylene, ethylene/hexene -1 copolymer having a melt index of 1.0 g/10 min. and density of 0.916 g/cc and 70-0% by weight of a linear low density ethylene/hexene copolymer having a melt index of 1.0 g/10 min. and a density of 0.918 g/cc (density is measured according to ASTM D 792 and melt index according to ASTM D 1238).