An article, comprising: a substrate selected from a (co)polymeric film or an electronic device, the electronic device further comprising an organic light emitting device (OLED), an electrophoretic light emitting device, a liquid crystal display, a thin film transistor, a photovoltaic device, or a combination thereof; a base (co)polymer layer on a major surface of the substrate; an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, wherein the protective (co)polymer layer comprises the reaction product of at least one urethane (multi)-(meth)acrylate (multi)-silane precursor compound of the formula: R S -N -C -O-R A or R S -O-C -N -R A, wherein: R S is a silane containing group of the formula -R 1 -[Si(Y p)(R 2) 3-p] q, further wherein: R 1 is a multivalent alkylene, arylene, alkarylene, or aralkylene group, said alkylene, arylene, alkarylene, or aralkylene groups optionally containing one or more catenary oxygen atoms, each Y is a hydrolysable group, wherein each hydrolysable group Y is individually selected from an alkoxy group, an acetate group, an aryloxy group, and a halogen, R 2 is a monovalent alkyl or aryl group; p is 1, 2, or 3, and q is 1-5; and R A is a (meth)acryl group containing group of the formula R 11 - n, wherein: R 11 is a polyvalent alkylene, arylene, alkarylene, or aralkylene group, said alkylene, arylene, alkarylene, or aralkylene groups optionally containing one or more catenary oxygen atoms, A is a (meth)acryl group comprising the formula X 2 -C -C(R 3)=CH 2, further wherein: X 2 is -O, -S, or -NR 3, R 3 is H, or C 1, and n=1 to 5. a substrate selected from a (co)polymeric film or an electronic device, the electronic device further comprising an organic light emitting device (OLED), an electrophoretic light emitting device, a liquid crystal display, a thin film transistor, a photovoltaic device, or a combination thereof; a base (co)polymer layer on a major surface of the substrate; an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, wherein the protective (co)polymer layer comprises the reaction product of at least one urethane (multi)-(meth)acrylate (multi)-silane precursor compound of the formula: R S -N -C -O-R A or R S -O-C -N -R A, wherein: R S is a silane containing group of the formula -R 1 -[Si(Y p)(R 2) 3-p] q, further wherein: R 1 is a multivalent alkylene, arylene, alkarylene, or aralkylene group, said alkylene, arylene, alkarylene, or aralkylene groups optionally containing one or more catenary oxygen atoms, each Y is a hydrolysable group, wherein each hydrolysable group Y is individually selected from an alkoxy group, an acetate group, an aryloxy group, and a halogen, R 2 is a monovalent alkyl or aryl group; p is 1, 2, or 3, and q is 1-5; and R A is a (meth)acryl group containing group of the formula R 11 - n, wherein: R 11 is a polyvalent alkylene, arylene, alkarylene, or aralkylene group, said alkylene, arylene, alkarylene, or aralkylene groups optionally containing one or more catenary oxygen atoms, A is a (meth)acryl group comprising the formula X 2 -C -C(R 3)=CH 2, further wherein: X 2 is -O, -S, or -NR 3, R 3 is H, or C 1, and n=1 to 5. R S is a silane containing group of the formula -R 1 -[Si(Y p)(R 2) 3-p] q, further wherein: R 1 is a multivalent alkylene, arylene, alkarylene, or aralkylene group, said alkylene, arylene, alkarylene, or aralkylene groups optionally containing one or more catenary oxygen atoms, each Y is a hydrolysable group, wherein each hydrolysable group Y is individually selected from an alkoxy group, an acetate group, an aryloxy group, and a halogen, R 2 is a monovalent alkyl or aryl group; p is 1, 2, or 3, and q is 1-5; and R 1 is a multivalent alkylene, arylene, alkarylene, or aralkylene group, said alkylene, arylene, alkarylene, or aralkylene groups optionally containing one or more catenary oxygen atoms, each Y is a hydrolysable group, wherein each hydrolysable group Y is individually selected from an alkoxy group, an acetate group, an aryloxy group, and a halogen, R 2 is a monovalent alkyl or aryl group; p is 1, 2, or 3, and q is 1-5; and R A is a (meth)acryl group containing group of the formula R 11 - n, wherein: R 11 is a polyvalent alkylene, arylene, alkarylene, or aralkylene group, said alkylene, arylene, alkarylene, or aralkylene groups optionally containing one or more catenary oxygen atoms, A is a (meth)acryl group comprising the formula X 2 -C -C(R 3)=CH 2, further wherein: X 2 is -O, -S, or -NR 3, R 3 is H, or C 1, and n=1 to 5. R 11 is a polyvalent alkylene, arylene, alkarylene, or aralkylene group, said alkylene, arylene, alkarylene, or aralkylene groups optionally containing one or more catenary oxygen atoms, A is a (meth)acryl group comprising the formula X 2 -C -C(R 3)=CH 2, further wherein: X 2 is -O, -S, or -NR 3, R 3 is H, or C 1, and n=1 to 5. X 2 is -O, -S, or -NR 3, R 3 is H, or C 1, and n=1 to 5.