A process to produce a quick-drying print and environmental-friendly biaxially orientated polypropylene synthetic paper, including: 1) a polypropylene resin composition comprising 90 to 40% by weight of a high crystallinity, isotacticity above 97% polypropylene resin, 10 to 40% by weight of calcium carbonate composite particles, 0.1 to 15 % by weight of titanium dioxide composite particles, 0.1 to 5% by weight of antistatic agent, 0.1 to 2% by weight of UV absorbers and a resin composition comprising 50 to 99% by weight of polypropylene and 5 to 0.1 % by weight of anti-blocking agent are fed into one twin-screw primary extruder and two twin-screw secondary extruders respectively at temperature set at 200 to 280 °C and convergently flow through the same T-die and co-extrude into a three-layer structure coated material sheet; 2) after this three-layer structure coated substrate film is cooled and shaped on a 15 to 80°C cooling roll, it is biaxially orientated, i.e. preheated, longitudinally stretched 4 to 6 times at 100 to 160°C, annealed, then preheated again, laterally stretched 5 to 10 times at temperature set at 150 to 190 °C and annealed; 3) then the biaxially orientated sheet is treated with a 20 to 150KW power high-frequency corona discharge to become a coated substrate film having a thickness below 250μm, characterized in that: 4) the resulted coated sheet is treated via a 100 to 400 mesh, 60μm to 10μm engraving depth gravure coating roll with a paper-like surface processing agent composed of 8 to 20% by weight of acrylic resin, 20 to 60% by weight of calcium carbonate, 0.1 to 5% by weight of clay, 0.1 to 2% by weight of titanium dioxide, 30 to 90% by weight of water, 0.1 to 2% by weight of anti-static agent, then passed through a 10 to 25M, temperature 80 to 120°C oven equipment to procure the synthetic paper having a thickness below 250μm. 1) a polypropylene resin composition comprising 90 to 40% by weight of a high crystallinity, isotacticity above 97% polypropylene resin, 10 to 40% by weight of calcium carbonate composite particles, 0.1 to 15 % by weight of titanium dioxide composite particles, 0.1 to 5% by weight of antistatic agent, 0.1 to 2% by weight of UV absorbers and a resin composition comprising 50 to 99% by weight of polypropylene and 5 to 0.1 % by weight of anti-blocking agent are fed into one twin-screw primary extruder and two twin-screw secondary extruders respectively at temperature set at 200 to 280 °C and convergently flow through the same T-die and co-extrude into a three-layer structure coated material sheet; 2) after this three-layer structure coated substrate film is cooled and shaped on a 15 to 80°C cooling roll, it is biaxially orientated, i.e. preheated, longitudinally stretched 4 to 6 times at 100 to 160°C, annealed, then preheated again, laterally stretched 5 to 10 times at temperature set at 150 to 190 °C and annealed; 3) then the biaxially orientated sheet is treated with a 20 to 150KW power high-frequency corona discharge to become a coated substrate film having a thickness below 250μm, characterized in that: 4) the resulted coated sheet is treated via a 100 to 400 mesh, 60μm to 10μm engraving depth gravure coating roll with a paper-like surface processing agent composed of 8 to 20% by weight of acrylic resin, 20 to 60% by weight of calcium carbonate, 0.1 to 5% by weight of clay, 0.1 to 2% by weight of titanium dioxide, 30 to 90% by weight of water, 0.1 to 2% by weight of anti-static agent, then passed through a 10 to 25M, temperature 80 to 120°C oven equipment to procure the synthetic paper having a thickness below 250μm.