A superficially porous particle based chiral stationary phase comprising: a chiral selector linked to a superficially porous particle; where the chiral selector is selected from the group consisting of a native or derivatized cyclodextrin; a native or derivatized cyclofructan; teicoplanin; vancomycin; teicoplanin aglycone; ristocetin A; dalbavancin; boromycin; dinitrobenzoyl-phenylglycine; dinitrobenzoyl-diphenylethylenediamine; dinitrobenzoyl-N-(1,2,3,4-tetrahydrophenanthren-4-yl)benzamide; dinitrobenzoyl-1,2-diaminocyclohexane; 3,3'-diphenyl-binaphthyl functionalized 18-crown-6; proline; penicillamine; hydroxyproline; quinine; derivatized quinine; or quinidine; wherein, when the chiral selector is selected from the group consisting of a native or derivatized cyclodextrin; a native or derivatized cyclofructan; teicoplanin; vancomycin; teicoplanin aglycone; ristocetin A; dalbavancin; boromycin; dinitrobenzoyl-diphenylethylenediamine; dinitrobenzoyl-1,2-diaminocyclohexane; 3,3'-diphenyl-binaphthyl functionalized 18-crown-6; proline; penicillamine; or hydroxyproline, the chiral selector linked to the superficially porous particle is covalently bonded to the superficially porous particle via ether, carbamate, or urea linkage; and when the chiral selector is selected from the group dinitrobenzoyl-phenylglycine; dinitrobenzoyl-N-(1,2,3,4-tetrahydrophenanthren-4-yl)benzamide; quinine; derivatized quinine; or quinidine, the chiral selector linked to the superficially porous particle is covalently bonded to the superficially porous particle via ether, carbamate, urea or olefin hydrosilylation linkage; wherein derivatizing groups of the derivatized cyclodextrin and the derivatized cyclofructan are alkanes or aromatic compounds; wherein the alkanes of the derivatizing groups are selected from the group consisting of linear alkane C 1 -C 30, branched alkane C 1 -C 30, cyclic alkane C 1 -C 30, linear and/or cyclic alkane containing heteroatoms, wherein the heteroatoms are selected from the group consisting of N, S and 0, wherein the aromatic compounds are selected from the group consisting of benzyl; derivatized benzyl, wherein derivatized benzyl is NO 2, Cl, F, Br, or CH 3 functionalized benzyl; phenyl; derivatized phenyl, wherein derivatized phenyl is NO 2, Cl, F, Br or CH 3 functionalized phenyl; naphthyl; derivatized naphthyl, wherein derivatized naphtyl is NO 2, Cl, F, Br, CH 3 functionalized naphtyl; or biaryl; wherein the derivatized quinine is selected from t-butyl carbamoylated quinine or isopropylated quinine; and wherein the superficially porous particle linked to the chiral selectors form brush type chiral superficially porous particles thereto. a chiral selector linked to a superficially porous particle; where the chiral selector is selected from the group consisting of a native or derivatized cyclodextrin; a native or derivatized cyclofructan; teicoplanin; vancomycin; teicoplanin aglycone; ristocetin A; dalbavancin; boromycin; dinitrobenzoyl-phenylglycine; dinitrobenzoyl-diphenylethylenediamine; dinitrobenzoyl-N-(1,2,3,4-tetrahydrophenanthren-4-yl)benzamide; dinitrobenzoyl-1,2-diaminocyclohexane; 3,3'-diphenyl-binaphthyl functionalized 18-crown-6; proline; penicillamine; hydroxyproline; quinine; derivatized quinine; or quinidine; wherein, when the chiral selector is selected from the group consisting of a native or derivatized cyclodextrin; a native or derivatized cyclofructan; teicoplanin; vancomycin; teicoplanin aglycone; ristocetin A; dalbavancin; boromycin; dinitrobenzoyl-diphenylethylenediamine; dinitrobenzoyl-1,2-diaminocyclohexane; 3,3'-diphenyl-binaphthyl functionalized 18-crown-6; proline; penicillamine; or hydroxyproline, the chiral selector linked to the superficially porous particle is covalently bonded to the superficially porous particle via ether, carbamate, or urea linkage; and when the chiral selector is selected from the group dinitrobenzoyl-phenylglycine; dinitrobenzoyl-N-(1,2,3,4-tetrahydrophenanthren-4-yl)benzamide; quinine; derivatized quinine; or quinidine, the chiral selector linked to the superficially porous particle is covalently bonded to the superficially porous particle via ether, carbamate, urea or olefin hydrosilylation linkage; wherein derivatizing groups of the derivatized cyclodextrin and the derivatized cyclofructan are alkanes or aromatic compounds; wherein the alkanes of the derivatizing groups are selected from the group consisting of linear alkane C 1 -C 30, branched alkane C 1 -C 30, cyclic alkane C 1 -C 30, linear and/or cyclic alkane containing heteroatoms, wherein the heteroatoms are selected from the group consisting of N, S and 0, wherein the aromatic compounds are selected from the group consisting of benzyl; derivatized benzyl, wherein derivatized benzyl is NO 2, Cl, F, Br, or CH 3 functionalized benzyl; phenyl; derivatized phenyl, wherein derivatized phenyl is NO 2, Cl, F, Br or CH 3 functionalized phenyl; naphthyl; derivatized naphthyl, wherein derivatized naphtyl is NO 2, Cl, F, Br, CH 3 functionalized naphtyl; or biaryl; wherein the derivatized quinine is selected from t-butyl carbamoylated quinine or isopropylated quinine; and wherein the superficially porous particle linked to the chiral selectors form brush type chiral superficially porous particles thereto.