A composition comprising: 0.001 wt.% to 99.999 wt.% of a mixture of C 10 -C 13 alkylphenyl sulfonates, based on the total weight of the composition, wherein the alkyl groups independently have a total of 10-13 carbon atoms, 0-3 C 1 -C 2 alkyl branches and wherein in the alkene mixture used to prepare the alkylphenyl sulfonates the linear alkene groups are present in an amount of at least 40 % based on the total weight of the mixture, and a bimodal alkyl chain distribution wherein the composition comprises C 10- C 13 alkylphenyl sulfonates having: (a) C 10 and C 13 alkyl groups to C 11 and C 12 alkyl groups; or (b) C 10, C 11, and C 13 alkyl groups to C 12 alkyl groups; or (c) C 10, C 12, and C 13 alkyl groups to C 11 alkyl groups (a) in a weight ratio of at least 60 to 40; and, wherein the mixture comprises: (i) less than 5 wt.% of alkylphenyl sulfonates with alkyl groups having 9 or fewer carbon atoms and alkyl groups having 14 or more carbon atoms, based on the total weight of the mixture; (ii) less than 10 wt.% of C 10- C 13 alkylphenyl sulfonates having two or more C 10- C 13 alkyl groups on the phenyl group, based on the total weight of the mixture; and, (iii) less than 10 wt% of C 10- C 13 alkylphenyl sulfonates having an alkyl group comprising a quaternary carbon atom, based on the total weight of the mixture, and, (b) 0.001 wt.% to 99.999 wt.% of (i) at least one additional cleaning component; or (ii) at least one personal care component. 0.001 wt.% to 99.999 wt.% of a mixture of C 10 -C 13 alkylphenyl sulfonates, based on the total weight of the composition, wherein the alkyl groups independently have a total of 10-13 carbon atoms, 0-3 C 1 -C 2 alkyl branches and wherein in the alkene mixture used to prepare the alkylphenyl sulfonates the linear alkene groups are present in an amount of at least 40 % based on the total weight of the mixture, and a bimodal alkyl chain distribution wherein the composition comprises C 10- C 13 alkylphenyl sulfonates having: (a) C 10 and C 13 alkyl groups to C 11 and C 12 alkyl groups; or (b) C 10, C 11, and C 13 alkyl groups to C 12 alkyl groups; or (c) C 10, C 12, and C 13 alkyl groups to C 11 alkyl groups (a) in a weight ratio of at least 60 to 40; and, wherein the mixture comprises: (i) less than 5 wt.% of alkylphenyl sulfonates with alkyl groups having 9 or fewer carbon atoms and alkyl groups having 14 or more carbon atoms, based on the total weight of the mixture; (ii) less than 10 wt.% of C 10- C 13 alkylphenyl sulfonates having two or more C 10- C 13 alkyl groups on the phenyl group, based on the total weight of the mixture; and, (iii) less than 10 wt% of C 10- C 13 alkylphenyl sulfonates having an alkyl group comprising a quaternary carbon atom, based on the total weight of the mixture, and, (b) 0.001 wt.% to 99.999 wt.% of (i) at least one additional cleaning component; or (ii) at least one personal care component. (a) C 10 and C 13 alkyl groups to C 11 and C 12 alkyl groups; or (b) C 10, C 11, and C 13 alkyl groups to C 12 alkyl groups; or (c) C 10, C 12, and C 13 alkyl groups to C 11 alkyl groups (a) in a weight ratio of at least 60 to 40; and, wherein the mixture comprises: (i) less than 5 wt.% of alkylphenyl sulfonates with alkyl groups having 9 or fewer carbon atoms and alkyl groups having 14 or more carbon atoms, based on the total weight of the mixture; (ii) less than 10 wt.% of C 10- C 13 alkylphenyl sulfonates having two or more C 10- C 13 alkyl groups on the phenyl group, based on the total weight of the mixture; and, (iii) less than 10 wt% of C 10- C 13 alkylphenyl sulfonates having an alkyl group comprising a quaternary carbon atom, based on the total weight of the mixture, and, (b) 0.001 wt.% to 99.999 wt.% of (i) at least one additional cleaning component; or (ii) at least one personal care component. (a) in a weight ratio of at least 60 to 40; and, wherein the mixture comprises: (i) less than 5 wt.% of alkylphenyl sulfonates with alkyl groups having 9 or fewer carbon atoms and alkyl groups having 14 or more carbon atoms, based on the total weight of the mixture; (ii) less than 10 wt.% of C 10- C 13 alkylphenyl sulfonates having two or more C 10- C 13 alkyl groups on the phenyl group, based on the total weight of the mixture; and, (iii) less than 10 wt% of C 10- C 13 alkylphenyl sulfonates having an alkyl group comprising a quaternary carbon atom, based on the total weight of the mixture, and, (i) less than 5 wt.% of alkylphenyl sulfonates with alkyl groups having 9 or fewer carbon atoms and alkyl groups having 14 or more carbon atoms, based on the total weight of the mixture; (ii) less than 10 wt.% of C 10- C 13 alkylphenyl sulfonates having two or more C 10- C 13 alkyl groups on the phenyl group, based on the total weight of the mixture; and, (iii) less than 10 wt% of C 10- C 13 alkylphenyl sulfonates having an alkyl group comprising a quaternary carbon atom, based on the total weight of the mixture, (b) 0.001 wt.% to 99.999 wt.% of (i) at least one additional cleaning component; or (ii) at least one personal care component. (i) at least one additional cleaning component; or (ii) at least one personal care component.