A silicone release coating composition of condensation reaction curing type comprising: component in an amount of 100 parts by weight which is an organopolysiloxane having at least two silanol groups in one molecule; component which is composed of component (B-1) in an amount of 0.1 to 20 parts by weight which is an organohydrogenpolysiloxane having at least three SiH groups in one molecule, and/or component (B-2) in an amount of 0.1 to 20 parts by weight which is an organopolysiloxane having at least three hydrolyzable groups directly bonded to a silicon atom in one molecule, with component being in such an amount that the number of moles of SiH groups and hydrolyzable groups as active groups therein is 1 to 200 times the number of moles of silanol amount in component; component in a catalyst quantity which is a compound of metal selected from magnesium, aluminum, titanium, chromium, iron, cobalt, nickel, copper, zinc, zirconium, tungsten, and bismuth, which functions as a condensation reaction catalyst; and component in an amount of 1 to 20 parts by weight which is either component (D-1), which is a cocatalyst of an organic compound having a bond between a nitrogen atom and an oxygen atom and/or a bond between a nitrogen atom and a sulfur atom through 1 to 3 carbon atoms, or component (D-2), which is a cocatalyst of an organic compound functioning as an oxygen multidentate ligand, wherein component (D-1) is one selected from the following organic compounds (i) to (iv) and an organic compound formed by reaction between at least two of the organic compounds (i) to (iv): (i) an isocyanate group-containing compound and a condensate thereof; (ii) a reaction product of the isocyanate group-containing compound and a hydroxyl group-containing and/or amino group-containing compound; (iii) a ring opening reaction product of the amino group-containing compound and an epoxy compound; and (iv) a ring opening reaction product of the amino group-containing compound and an oxetane compound. component in an amount of 100 parts by weight which is an organopolysiloxane having at least two silanol groups in one molecule; component which is composed of component (B-1) in an amount of 0.1 to 20 parts by weight which is an organohydrogenpolysiloxane having at least three SiH groups in one molecule, and/or component (B-2) in an amount of 0.1 to 20 parts by weight which is an organopolysiloxane having at least three hydrolyzable groups directly bonded to a silicon atom in one molecule, with component being in such an amount that the number of moles of SiH groups and hydrolyzable groups as active groups therein is 1 to 200 times the number of moles of silanol amount in component; component in a catalyst quantity which is a compound of metal selected from magnesium, aluminum, titanium, chromium, iron, cobalt, nickel, copper, zinc, zirconium, tungsten, and bismuth, which functions as a condensation reaction catalyst; and component in an amount of 1 to 20 parts by weight which is either component (D-1), which is a cocatalyst of an organic compound having a bond between a nitrogen atom and an oxygen atom and/or a bond between a nitrogen atom and a sulfur atom through 1 to 3 carbon atoms, or component (D-2), which is a cocatalyst of an organic compound functioning as an oxygen multidentate ligand, wherein component (D-1) is one selected from the following organic compounds (i) to (iv) and an organic compound formed by reaction between at least two of the organic compounds (i) to (iv): (i) an isocyanate group-containing compound and a condensate thereof; (ii) a reaction product of the isocyanate group-containing compound and a hydroxyl group-containing and/or amino group-containing compound; (iii) a ring opening reaction product of the amino group-containing compound and an epoxy compound; and (iv) a ring opening reaction product of the amino group-containing compound and an oxetane compound. (i) an isocyanate group-containing compound and a condensate thereof; (ii) a reaction product of the isocyanate group-containing compound and a hydroxyl group-containing and/or amino group-containing compound; (iii) a ring opening reaction product of the amino group-containing compound and an epoxy compound; and (iv) a ring opening reaction product of the amino group-containing compound and an oxetane compound.