A hollow fiber membrane comprising: a gas permeable nonporous layer; and a porous supporting layer to support the nonporous layer, wherein the nonporous layer is formed of a thermoplastic elastomer, wherein the thermoplastic elastomer has a DSC melting peak temperature of 130°C or higher and a rupture elongation prescribed in ISO 37 of 300% or more, and the nonporous layer is formed of a composition containing a styrene-based thermoplastic elastomer containing at least either of an ABA type styrene-based thermoplastic elastomer (α) having a polystyrene portion and a poly-conjugated diene portion or a hydrogenated product (αh) of the ABA type styrene-based thermoplastic elastomer (α) and a polyolefin, wherein the poly-conjugated diene portion contains butadiene and isoprene as a component and at least either of a 1,2-bonding unit or a 3,4-bonding unit, and the total amount of the 1,2-bonding unit and the 3,4-bonding unit is 50% by mole or more with respect to a total amount of the entire units constituting the poly-conjugated diene portion, the polyolefin is at least one kind of polypropylene having a melting point of 145-165°C as measured by DSC or unsaturated carboxylic acid-modified polypropylene having a melting point of 120-170°C as measured by DSC, the composition contains the styrene-based thermoplastic elastomer at 60% by mass or more and 90% by mass or less with respect to a total amount of the styrene-based thermoplastic elastomer and the polyolefin, wherein the porous supporting layer is formed of polyethylene, the polyethylene being a high-density polyethylene having a density of 0.942 g/cm 3 or more as determined according to JIS K 6748: 1995, and in which the poly-conjugated diene portion is composed of constituent units derived from butadiene and isoprene, wherein there are a 1, 4-bonding unit or a 1,2-bonding unit which are derived from butadiene or a 1,4-bonding unit, a 3,4-bonding unit, and a 1,2-bonding unit which are derived from isoprene as a unit constituting the poly-conjugated diene portion, the 1,4-bonding unit derived from butadiene being [-CH 2 -CH=CH-CH 2 -], the 1,2-bonding unit derived from butadiene being [-CH 2 -CH(CH=CH 2)-], the 1,4-bonding unit derived from isoprene being [-CH 2 -C(CH 3)=CH-CH 2 -], the 3,4-bonding unit derived from isoprene being [-CH 2 -CH(C(CH 3)=CH 2)-], and the 1,2-bonding unit derived from isoprene being [-CH 2 -C(CH 3)(CH=CH 2)-]. a gas permeable nonporous layer; and a porous supporting layer to support the nonporous layer, wherein the nonporous layer is formed of a thermoplastic elastomer, wherein the thermoplastic elastomer has a DSC melting peak temperature of 130°C or higher and a rupture elongation prescribed in ISO 37 of 300% or more, and the nonporous layer is formed of a composition containing a styrene-based thermoplastic elastomer containing at least either of an ABA type styrene-based thermoplastic elastomer (α) having a polystyrene portion and a poly-conjugated diene portion or a hydrogenated product (αh) of the ABA type styrene-based thermoplastic elastomer (α) and a polyolefin, wherein the poly-conjugated diene portion contains butadiene and isoprene as a component and at least either of a 1,2-bonding unit or a 3,4-bonding unit, and the total amount of the 1,2-bonding unit and the 3,4-bonding unit is 50% by mole or more with respect to a total amount of the entire units constituting the poly-conjugated diene portion, the polyolefin is at least one kind of polypropylene having a melting point of 145-165°C as measured by DSC or unsaturated carboxylic acid-modified polypropylene having a melting point of 120-170°C as measured by DSC, the composition contains the styrene-based thermoplastic elastomer at 60% by mass or more and 90% by mass or less with respect to a total amount of the styrene-based thermoplastic elastomer and the polyolefin, wherein the porous supporting layer is formed of polyethylene, the polyethylene being a high-density polyethylene having a density of 0.942 g/cm 3 or more as determined according to JIS K 6748: 1995, and in which the poly-conjugated diene portion is composed of constituent units derived from butadiene and isoprene, wherein there are a 1, 4-bonding unit or a 1,2-bonding unit which are derived from butadiene or a 1,4-bonding unit, a 3,4-bonding unit, and a 1,2-bonding unit which are derived from isoprene as a unit constituting the poly-conjugated diene portion, the 1,4-bonding unit derived from butadiene being [-CH 2 -CH=CH-CH 2 -], the 1,2-bonding unit derived from butadiene being [-CH 2 -CH(CH=CH 2)-], the 1,4-bonding unit derived from isoprene being [-CH 2 -C(CH 3)=CH-CH 2 -], the 3,4-bonding unit derived from isoprene being [-CH 2 -CH(C(CH 3)=CH 2)-], and the 1,2-bonding unit derived from isoprene being [-CH 2 -C(CH 3)(CH=CH 2)-].