A functionalized ionic silicone having formula: M 1 a M 2 b M 3 c D 1 d D 2 e D 3 f T 1 g T 2 h T 3 i Qj wherein: M 1 = R 1 R 2 R 3 SiO 1/2 M 2 = R 4 R 5 R 6 SiO 1/2 M 3 = R 7 R 8 R 9 SiO 1/2 D 1 = R 10 R 11 SiO 2/2 D 2 = R 12 R 13 SiO 2/2 D 3 = R 14 R 15 SiO 2/2 T 1 = R 16 SiO 3/2 T 2 = R 17 SiO 3/2 T 3 = R 18 SiO 3/2 Q = SiO 4/2 where R 1, R 2, R 3, R 5, R 6, R 8, R 9, R 10, R 11, R 13, R 15, R 16 are aliphatic, aromatic or fluoro containing monovalent hydrocarbon radicals containing from 1 to 60 carbon atoms; where R 4, R 12, R 17 are zwitterions having the formula: -R'-NR" 2 + -R′′′-I where R' is a divalent hydrocarbon radical containing from 1 to 20 carbon atoms, where R" is monovalent hydrocarbon radical containing from 1 to 20 carbon atoms and where R′′′ is divalent hydrocarbon radical containing from 2 to 20 carbon atoms; where I is an ionic group such as sulfonate (-SO 3 -), sulfate (-OSO 3 2-), carboxylate (-COO -), phosphonate (-PO 3 2-) and phosphate (-OPO 3 2-) group, and where R 7, R 18 are each independently monovalent hydrocarbon radicals selected from -OR 20, hydrogen, unsaturated monovalent radicals, monovalent epoxy group-containing radicals, monovalent sulfur atom-containing radicals, monovalent organosilane groups and monvalent hydroxyl group containing radicals, and a monovalent hydrocarbon containing one or more of a halogen moiety, a carboxylate moiety, an imine moiety, an isocyanate moiety, an amide moiety, a nitrile moiety, or a tertiary amine moiety containing other than alkyl groups moiety, where R 14 is each independently monovalent hydrocarbon radicals selected from -OR 20,unsaturated monovalent radicals, monovalent epoxy group-containing radicals, monovalent sulfur atom-containing radicals, monovalent organosilane groups and monvalent hydroxyl group containing radicals, and a monovalent hydrocarbon containing one or more of a halogen moiety, a carboxylate moiety, an imine moiety, an isocyanate moiety, an amide moiety, a nitrile moiety, or a tertiary amine moiety containing other than alkyl groups moiety, where R 20 is a monovalent hydrocarbon radical containing from1 to 60 carbon atoms or a heteroatom, where the subscripts a, b, c, d, e, f, g, h, i, j are zero or positive subject to the following limitations: the sum a+b+c+d+e+f+g+h+i+j is greater than or equal to 2 and less than or equal to 6000, b+e+h is greater than zero and c+f+i is greater than zero. M 1 = R 1 R 2 R 3 SiO 1/2 M 2 = R 4 R 5 R 6 SiO 1/2 M 3 = R 7 R 8 R 9 SiO 1/2 D 1 = R 10 R 11 SiO 2/2 D 2 = R 12 R 13 SiO 2/2 D 3 = R 14 R 15 SiO 2/2 T 1 = R 16 SiO 3/2 T 2 = R 17 SiO 3/2 T 3 = R 18 SiO 3/2 Q = SiO 4/2 where R 4, R 12, R 17 are zwitterions having the formula: -R'-NR" 2 + -R′′′-I where R' is a divalent hydrocarbon radical containing from 1 to 20 carbon atoms, where R" is monovalent hydrocarbon radical containing from 1 to 20 carbon atoms and where R′′′ is divalent hydrocarbon radical containing from 2 to 20 carbon atoms; where I is an ionic group such as sulfonate (-SO 3 -), sulfate (-OSO 3 2-), carboxylate (-COO -), phosphonate (-PO 3 2-) and phosphate (-OPO 3 2-) group, and where R 7, R 18 are each independently monovalent hydrocarbon radicals selected from -OR 20, hydrogen, unsaturated monovalent radicals, monovalent epoxy group-containing radicals, monovalent sulfur atom-containing radicals, monovalent organosilane groups and monvalent hydroxyl group containing radicals, and a monovalent hydrocarbon containing one or more of a halogen moiety, a carboxylate moiety, an imine moiety, an isocyanate moiety, an amide moiety, a nitrile moiety, or a tertiary amine moiety containing other than alkyl groups moiety, where R 14 is each independently monovalent hydrocarbon radicals selected from -OR 20,unsaturated monovalent radicals, monovalent epoxy group-containing radicals, monovalent sulfur atom-containing radicals, monovalent organosilane groups and monvalent hydroxyl group containing radicals, and a monovalent hydrocarbon containing one or more of a halogen moiety, a carboxylate moiety, an imine moiety, an isocyanate moiety, an amide moiety, a nitrile moiety, or a tertiary amine moiety containing other than alkyl groups moiety, where R 20 is a monovalent hydrocarbon radical containing from1 to 60 carbon atoms or a heteroatom, where the subscripts a, b, c, d, e, f, g, h, i, j are zero or positive subject to the following limitations: the sum a+b+c+d+e+f+g+h+i+j is greater than or equal to 2 and less than or equal to 6000, b+e+h is greater than zero and c+f+i is greater than zero.