A multilayer volume hologram stacked on an application member, wherein the multilayer volume hologram comprises: an adhesive layer; a volume hologram layer comprising a matrix polymer, a photopolymerized compound, a photopolymerization initiator and a sensitizing dye; a surface-protective coating film; and a substrate; all being stacked in the above order on the application member, wherein said surface-protective coating film is formed by using an ink having a binder methacrylate-based resin and an additive of at least one component selected from polyacrylic acid ester resins, polyvinyl chloride resins, cellulose resins, silicone resins, chlorinated rubber and casein dissolved in an organic solvent; wherein the substrate is releasable from the surface-protective coating film and is made of polyethylene films, polypropylene films, polyethylene fluoride films, polyvinylidene fluoride films, polyvinyl chloride films, polyvinylidene chloride films, ethylene-vinyl alcohol films, polyvinyl alcohol films, polymethyl methacrylate films, polyether sulfone films, polyether ether ketone films, polyamide films, tetrafluoroethylene-perfluoroalkyvinyl ether copolymer films, polyester films, and polyimide films, which have a thickness of 2 μm to 200 μm; and wherein the breaking strength of a multilayer structure consisting of said volume hologram layer and said surface-protective coating film is in the range of 0,005 kgf/mm 2 to 0,05 kgf/mm 2 measured according to JIS K7127-1989, and the peeling strength with which said multilayer structure consisting of said volume hologram layer and said surface-protective coating film is peeled off said application member is in the range of 0,5 kgf/25 mm to 3 kgf/25 mm mesured according to JIS Z0237. an adhesive layer; a volume hologram layer comprising a matrix polymer, a photopolymerized compound, a photopolymerization initiator and a sensitizing dye; a surface-protective coating film; and a substrate; all being stacked in the above order on the application member, wherein said surface-protective coating film is formed by using an ink having a binder methacrylate-based resin and an additive of at least one component selected from polyacrylic acid ester resins, polyvinyl chloride resins, cellulose resins, silicone resins, chlorinated rubber and casein dissolved in an organic solvent; wherein the substrate is releasable from the surface-protective coating film and is made of polyethylene films, polypropylene films, polyethylene fluoride films, polyvinylidene fluoride films, polyvinyl chloride films, polyvinylidene chloride films, ethylene-vinyl alcohol films, polyvinyl alcohol films, polymethyl methacrylate films, polyether sulfone films, polyether ether ketone films, polyamide films, tetrafluoroethylene-perfluoroalkyvinyl ether copolymer films, polyester films, and polyimide films, which have a thickness of 2 μm to 200 μm; and wherein the breaking strength of a multilayer structure consisting of said volume hologram layer and said surface-protective coating film is in the range of 0,005 kgf/mm 2 to 0,05 kgf/mm 2 measured according to JIS K7127-1989, and the peeling strength with which said multilayer structure consisting of said volume hologram layer and said surface-protective coating film is peeled off said application member is in the range of 0,5 kgf/25 mm to 3 kgf/25 mm mesured according to JIS Z0237.