An organic electrolytic cell of a multi-layer type comprising: a positive electrode, a current collector of the positive electrode, a negative electrode, a current collector of the negative electrode, a lithium metal foil arranged to face a surface of the positive or negative electrode; and a solution of lithium salt in an aprotic organic solvent as an electrolytic solution; wherein the current collector of the positive electrode and the current collector of the negative electrode are respectively provided with pores piercing from the front surface to the back surface, and a porosity of each current collector (1'; 2') is not less than 1% and not more than 30%, an active material of the positive electrode and an active material of the negative electrode are capable of reversibly carrying lithium ions, wherein lithium ions originating in the positive electrode are carried on the positive electrode by electrochemical contact with the lithium metal foil, thereby passing all or a portion of the lithium ions through at least one layer of the negative electrode, or lithium ions originating in the negative electrode are carried on the negative electrode by electrochemical contact with a lithium metal foil, thereby passing all or a portion of the lithium ions through at least one layer of the positive electrode, wherein the lithium ions to be carried on one layer of the positive electrode disposed between two layers of the negative electrode are carried on said one layer of the positive electrode by passing through at least one of said two layers of the negative electrode from said lithium metal foil, and the lithium ions to be carried on one layer of the negative electrode disposed between two layers of the positive electrode are carried on said one layer of the negative electrode by passing through at least one of said two layers of the positive electrode from said lithium metal foil. a positive electrode, a current collector of the positive electrode, a negative electrode, a current collector of the negative electrode, a lithium metal foil arranged to face a surface of the positive or negative electrode; and a solution of lithium salt in an aprotic organic solvent as an electrolytic solution; wherein the current collector of the positive electrode and the current collector of the negative electrode are respectively provided with pores piercing from the front surface to the back surface, and a porosity of each current collector (1'; 2') is not less than 1% and not more than 30%, an active material of the positive electrode and an active material of the negative electrode are capable of reversibly carrying lithium ions, wherein lithium ions originating in the positive electrode are carried on the positive electrode by electrochemical contact with the lithium metal foil, thereby passing all or a portion of the lithium ions through at least one layer of the negative electrode, or lithium ions originating in the negative electrode are carried on the negative electrode by electrochemical contact with a lithium metal foil, thereby passing all or a portion of the lithium ions through at least one layer of the positive electrode, wherein the lithium ions to be carried on one layer of the positive electrode disposed between two layers of the negative electrode are carried on said one layer of the positive electrode by passing through at least one of said two layers of the negative electrode from said lithium metal foil, and the lithium ions to be carried on one layer of the negative electrode disposed between two layers of the positive electrode are carried on said one layer of the negative electrode by passing through at least one of said two layers of the positive electrode from said lithium metal foil.