A high-strength steel sheet comprising: a component composition including: by mass%, C: 0.030% to 0.250%; Si: 0.01% to 3.00%; Mn: 3.10% to 4.20%; P: 0.001% to 0.100%; S: 0.0001% to 0.0200%; N: 0.0005% to 0.0100%; Al: 0.010% to 1.200%; optionally at least one element selected from Ti: 0.005% to 0.200%; Nb: 0.005% to 0.200%; V: 0.005% to 0.500%; W:0.005% to 0.500%; B: 0.0003% to 0.0050%; Ni: 0.005% to 1.000%; Cr: 0.005% to 1.000%; Mo: 0.005% to 1.000%; Cu: 0.005% to 1.000%; Sn: 0.002% to 0.200%; Sb: 0.002% to 0.200%; Ta: 0.001% to 0.100%; Ca: 0.0005% to 0.0050%; Mg: 0.0005% to 0.0050%; Zr: 0.0005% to 0.0050%; and REM: 0.0005% to 0.0050%; and balance Fe and inevitable impurities; and a steel structure with: ferrite being 35% to 80% and tempered martensite being greater than 5% and 20% or less in terms of area fraction; retained austenite being 8% or more in terms of volume fraction; an average grain size of the ferrite being 6 μm or less; an average grain size of the retained austenite being 3 μm or less; a value obtained by dividing an area fraction of blocky austenite by a sum of area fractions of lath-like austenite and the blocky austenite being 0.6 or more; a value obtained by dividing an average Mn content, by mass%, in the retained austenite by an average Mn content, by mass%, in the ferrite being 1.5 or more; and a value obtained by dividing an average C content, by mass%, in the retained austenite by an average C content, by mass%, in the ferrite being 3.0 or more; all measured according to the methods as of description, wherein the high-strength steel sheet includes a diffusible hydrogen amount in steel of 0.3 ppm by mass or less, measured with the method as of description. a component composition including: by mass%, C: 0.030% to 0.250%; Si: 0.01% to 3.00%; Mn: 3.10% to 4.20%; P: 0.001% to 0.100%; S: 0.0001% to 0.0200%; N: 0.0005% to 0.0100%; Al: 0.010% to 1.200%; optionally at least one element selected from Ti: 0.005% to 0.200%; Nb: 0.005% to 0.200%; V: 0.005% to 0.500%; W:0.005% to 0.500%; B: 0.0003% to 0.0050%; Ni: 0.005% to 1.000%; Cr: 0.005% to 1.000%; Mo: 0.005% to 1.000%; Cu: 0.005% to 1.000%; Sn: 0.002% to 0.200%; Sb: 0.002% to 0.200%; Ta: 0.001% to 0.100%; Ca: 0.0005% to 0.0050%; Mg: 0.0005% to 0.0050%; Zr: 0.0005% to 0.0050%; and REM: 0.0005% to 0.0050%; and balance Fe and inevitable impurities; and a steel structure with: ferrite being 35% to 80% and tempered martensite being greater than 5% and 20% or less in terms of area fraction; retained austenite being 8% or more in terms of volume fraction; an average grain size of the ferrite being 6 μm or less; an average grain size of the retained austenite being 3 μm or less; a value obtained by dividing an area fraction of blocky austenite by a sum of area fractions of lath-like austenite and the blocky austenite being 0.6 or more; a value obtained by dividing an average Mn content, by mass%, in the retained austenite by an average Mn content, by mass%, in the ferrite being 1.5 or more; and a value obtained by dividing an average C content, by mass%, in the retained austenite by an average C content, by mass%, in the ferrite being 3.0 or more; all measured according to the methods as of description, wherein the high-strength steel sheet includes a diffusible hydrogen amount in steel of 0.3 ppm by mass or less, measured with the method as of description. ferrite being 35% to 80% and tempered martensite being greater than 5% and 20% or less in terms of area fraction; retained austenite being 8% or more in terms of volume fraction; an average grain size of the ferrite being 6 μm or less; an average grain size of the retained austenite being 3 μm or less; a value obtained by dividing an area fraction of blocky austenite by a sum of area fractions of lath-like austenite and the blocky austenite being 0.6 or more; a value obtained by dividing an average Mn content, by mass%, in the retained austenite by an average Mn content, by mass%, in the ferrite being 1.5 or more; and a value obtained by dividing an average C content, by mass%, in the retained austenite by an average C content, by mass%, in the ferrite being 3.0 or more; all measured according to the methods as of description, wherein the high-strength steel sheet includes a diffusible hydrogen amount in steel of 0.3 ppm by mass or less, measured with the method as of description.