An organic optoelectric device comprising an anode and a cathode facing each other, an emission layer between the anode and the cathode, a hole transport layer between the anode and the emission layer, a hole transport auxiliary layer between the hole transport layer and the emission layer, an electron transport layer between the cathode and the emission layer, and an electron transport auxiliary layer between the electron transport layer and the emission layer, wherein the electron transport auxiliary layer comprises at least one of a first compound represented by Chemical Formula 1, and the hole transport auxiliary layer comprises at least one of a second compound represented by Chemical Formula 2: wherein, in Chemical Formula 1, Z is each independently N or CR a, at least one of Z is N, R 1 to R 10 and R a are each independently hydrogen, deuterium, a substituted or unsubstituted C1 to C10 alkyl group, a substituted or unsubstituted C6 to C12 aryl group, or a combination thereof, L 1 is a substituted or unsubstituted phenylene group, a substituted or unsubstituted biphenylene group or a substituted or unsubstituted terphenylene group, n1 to n3 are each independently 0 or 1, n1+n2+n3 ≥ 1, wherein, in Chemical Formula 2, L 2 is a substituted or unsubstituted C6 to C30 arylene group or a substituted or unsubstituted C6 to C30 heteroarylene group, n4 is an integer of 1 to 5, R 11 to R 22 are independently, hydrogen, deuterium, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C6 to C50 aryl group, a substituted or unsubstituted C2 to C50 heteroaryl group, or a combination thereof, R 11 to R 20 are independently present or are fused with each other to form a ring, wherein "substituted" of Chemical Formulae 1 and 2 refers to that at least one hydrogen is replaced by deuterium, a halogen, a hydroxy group, an amino group, a substituted or unsubstituted C1 to C30 amine group, a nitro group, a substituted or unsubstituted C1 to C40 silyl group, a C1 to C30 alkyl group, a C3 to C30 cycloalkyl group, a C2 to C30 heterocycloalkyl group, a C6 to C30 aryl group, a C2 to C30 heteroaryl group, a C1 to C20 alkoxy group, a fluoro group, a C1 to C10 trifluoroalkyl group, or a cyano group. Z is each independently N or CR a, at least one of Z is N, R 1 to R 10 and R a are each independently hydrogen, deuterium, a substituted or unsubstituted C1 to C10 alkyl group, a substituted or unsubstituted C6 to C12 aryl group, or a combination thereof, L 1 is a substituted or unsubstituted phenylene group, a substituted or unsubstituted biphenylene group or a substituted or unsubstituted terphenylene group, n1 to n3 are each independently 0 or 1, n1+n2+n3 ≥ 1, L 2 is a substituted or unsubstituted C6 to C30 arylene group or a substituted or unsubstituted C6 to C30 heteroarylene group, n4 is an integer of 1 to 5, R 11 to R 22 are independently, hydrogen, deuterium, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C6 to C50 aryl group, a substituted or unsubstituted C2 to C50 heteroaryl group, or a combination thereof, R 11 to R 20 are independently present or are fused with each other to form a ring, wherein "substituted" of Chemical Formulae 1 and 2 refers to that at least one hydrogen is replaced by deuterium, a halogen, a hydroxy group, an amino group, a substituted or unsubstituted C1 to C30 amine group, a nitro group, a substituted or unsubstituted C1 to C40 silyl group, a C1 to C30 alkyl group, a C3 to C30 cycloalkyl group, a C2 to C30 heterocycloalkyl group, a C6 to C30 aryl group, a C2 to C30 heteroaryl group, a C1 to C20 alkoxy group, a fluoro group, a C1 to C10 trifluoroalkyl group, or a cyano group.