Abstract:
A gas generating composition containing glycidyl azide polymer and a high trogen content additive selected from the group consisting of guanylaminotetrazole nitrate, bis(triaminoguanidinium)5,5&#39;azotetrazole, ammonium 5-nitraminotetrazole and high bulk density nitro guanidine generates large quantities of nitrogen gas upon burning and can be used to extinguish fires.

Description:
BACKGROUND OF THE INVENTION 
     Field of the Invention: 
     This invention relates to gas generating systems. More particularly, this invention relates to gas generating compositions which release large amounts of nitrogen gas to suppress fires. 
     Description of the Prior Art: 
     A common fire extinguisher for small localized fires is bottled carbon dioxide gas. This carbon dioxide system has several disadvantages. The storage bottles must withstand high pressures and the possibility of leakage requires periodic checking of the pressure and weight to insure that adequate amounts of carbon dioxide remain in the bottles. A system is desired that does not require constant monitoring or checking. 
     SUMMARY OF THE INVENTION 
     Accordingly, the present invention provides gas generating compositions comprising glycidyl azide polymer (GAP and a high nitrogen content solid additive selected from the group consisting of guanylaminotetrazole nitrate, bis(triaminoguanidium) 5,5&#39;-azotetrazole, ammonium 5-nitraminotetrazole and high bulk density nitroguanidine. 
     OBJECTS OF THE INVENTION 
     It is an object of this invention to provide solid gas generating compositions which generate large amounts of nitrogen gas when the compositions are burned. 
     Another object of this invention is to provide a method of extinguishing a fire by providing gas generating compositions which generate large amounts of nitrogen gas to extinguish a fire. 
     Still another object of this invention is to provide gas generating compositions that generate large amounts of nitrogen gas when brought in contact with a fire to extinguish the fire. 
     Yet another object of this invention is to provide gas generating compositions which can be cast cured into small shapes and stored in a conveniently located container as a fire extinguisher. 
     These and other objects and novel features of the invention will become apparent from the following detailed description. 
     DETAILED DESCRIPTION OF THE INVENTION 
     It has been found that compositions containing glycidyl azide polymer (GAP) and a high nitrogen content solid additive or compound will generate substantially large amounts of nitrogen gas when brought into contact with a fire. This production of nitrogen gas can be used to smother or extinguish the fire. The high nitrogen content solid additives used include guanylaminotetrazole nitrate (GATN), bis(triaminoguanidinium) 5,5&#39;-azotetrazole (BTAGAZT), ammonium 5-nitraminotetrazole (ANT) and high bulk density nitroguanidine (HNBQ). 
    
    
     The following examples will serve to illustrate this invention without restricting it to what is specifically described. 
     EXAMPLE I 
     A preferred nitrogen gas generating composition was prepared including the following ingredients: 
     
         ______________________________________glycidyl azide polymer (GAP)              4.26   weight percent;the biuret trimer of hexa-              0.74   weight percent;methylene diisocyanate (N-100)(BTAGAZT)          95.0   weight percent; anddibutyltin dilaurate              0.005  weight percent.______________________________________ 
    
     The ingredients were thoroughly mixed and warmed to 130° F., then pressed into various sized granules and tablets and cooled. A uniform mixture is obtained by using a solvent such as methylene chloride during mixing and then removing the solvent. The tablets when heated, decomposed and evolved 80 g of nitrogen gas per 100 g of tablets. 
     EXAMPLE II 
     Another nitrogen gas generating composition was prepared in a similar fashion including the following ingredients: 
     
         ______________________________________GAP              42.6   weight percent;N-100            7.4    weight percent;BTAGAZT          50.0   weight percent; anddibutyltin dilaurate            0.005  weight percent.______________________________________ 
    
     The tablets prepared from this composition evolved 62 g of nitrogen gas per 100 g of tablets when heated. 
     EXAMPLE III 
     Another gas generating composition contained the following ingredients: 
     
         ______________________________________GAP              17.0   weight percent;N-100            3.0    weight percent;BTAGAZT          80.0   weight percent; anddibutyltin dilaurate            0.005  weight percent.______________________________________ 
    
     These ingredients were mixed together, poured into a gas generator cannister and cured at 130° F. for about 1 to 5 days. This composition has been calculated to generate 73 g of nitrogen per 100 g of composition. 
     The burn rates of compositions containing 50 weight percent GAP and 50 weight percent of the different high nitrogen content solid additives have been determined. The burn rates were measured at 70° F. and at 500 psi. The burn rate determines the amount of gas to be generated in a specific time period. In the case of a fire the time period may be limited and a fast burn rate is needed. 
     
         ______________________________________ADDITIVE            BURN RATE______________________________________HBNQ                0.193   in./sec.GATN                0.29    in./sec.ANT                 0.73    in./sec.BTAGAZT             0.87    in./sec.______________________________________ 
    
     The compositions of the invention are useful in extinguishing fires which are confined in an area not easily accessable and in operations where the occurance of fires is predictable. The occurance of such potential fires could be avoided by providing the smothering gas before the fire has a chance to ignite. Examples of operations with potential but predictable fires are plane crashes and oil refineries. 
     A method of combatting fires or preventing potential fires from occuring includes a fire extinguishing reservoir containing a gas generating composition. The gas generating composition can consist of pellets or tablets or the composition can be cast cured into a suitable reservoir or container in a similar fashion as a rocket motor is cast. The reservoir or container includes a device to ignite the composition. After the ignition of the gas generating composition, the evolved gas can be conveyed to the fire or potential fire site. The gas is expelled from appropriate pipes or ducts with fins to additionally cool the gas. The use of fins to cause cooling is well understood to those skilled in the art. 
     Obviously many modifications and variations of the present invention are possible in light of the above teachings. It should be understood that within the scope of the appended claims the invention may be practiced otherwise than as specifically described.