Abstract:
A process is described for treating waste plastics material to provide at least one on-specification fuel product. Plastics material is melted and then pyrolysed in an oxygen-free atmosphere to provide pyrolysis gases. The pyrolysis gases are brought into contact with plates in a contactor vessel so that some long chain gas components condense and return to be further pyrolysed to achieve thermal degradation. Short chain gas components exit the contactor in gaseous form and proceed to distillation to provide one or more on-specification fuel products. A pipe directly links the pyrolysis chamber to the contactor, suitable for conveying upwardly-moving pyrolysis gases and downwardly-flowing long-chain liquid for thermal degradation.

Description:
FIELD OF THE INVENTION 
       [0001]    The invention relates to conversion of waste hydrocarbon material such as plastics into fuel. 
       PRIOR ART DISCUSSION 
       [0002]    GB2158089 (Suzy-Jen) describes a treatment process in which plastics is melted and heated to produce gas, the gas is condensed to provide an oily liquid, and this is fractionally distilled. WO2005/087897 (Ozmotech Pty) describes a process in which there may be multiple pyrolysis chambers. Pyrolysis gases are transferred into a catalytic converter where the molecular structure of the gaseous material is altered in structure and form WO01/05908 (Xing) describes a process in which there are first and second cracking stages with first and second catalysts. US2003/0199718 (Miller) describes an approach in which there is pyrolysis and the reactor is maintained at a temperature in the range of 450° C. and 700° C. The effluent from the pyrolysis reactor is passed to a catalytic summarization de-waxing unit. 
         [0003]    The invention is directed towards providing a process which more consistently produces particular grades of “on-spec” fuel, and/or with an improved yield. 
       SUMMARY OF THE INVENTION 
       [0004]    According to the invention, there is provided a process for treating waste plastics material to provide at least one fuel product, the process comprising the steps of:
       melting the waste plastics material,   pyrolysing the molten material in an oxygen-free atmosphere to provide pyrolysis gases;   bringing the pyrolysis gases into a contactor having a bank of condenser elements so that some long chain gas components condense on said elements,   returning said condensed long-chain material to be further pyrolysed to achieve thermal degradation, and allowing short chain gas components to exit from the contactor in gaseous form; and   distilling said pyrolysis gases from the contactor in a distillation column to provide one or more fuel products.       
 
         [0010]    In one embodiment, the contactor elements comprise a plurality of plates forming an arduous path for the pyrolysis gases in the contactor. Preferably, the plates are sloped downwardly for run-off of the condensed long-chain hydrocarbon, and include apertures to allow upward progression of pyrolysis gases. In one embodiment, the contactor elements comprise arrays of plates on both sides of a gas path. In one embodiment, the contactor element plates are of stainless steel. 
         [0011]    In one embodiment, the contactor is actively cooled by a cooling means. In one embodiment, the cooling is by a heat exchanger for at least one contactor element. 
         [0012]    In one embodiment, there is a pipe directly linking the pyrolysis chamber to the contactor, the pipe being arranged for conveying upwardly-moving pyrolysis gases and downwardly-flowing long-chain liquid for thermal degradation. 
         [0013]    In one embodiment, the cooling means comprises a contactor jacket and cooling fluid is directed into the jacket. 
         [0014]    In one embodiment, the cooling means controls a valve linking the jacket with a flue, opening of the valve causing cooling by down-draught and closing of the valve causing heating. 
         [0015]    In one embodiment, the valve provides access to a flue for exhaust gases of a combustion unit of the pyrolysis chamber. 
         [0016]    In one embodiment, infeed to the pyrolysis chamber is controlled according to monitoring of level of molten plastics in the chamber, as detected by a gamma radiation detector arranged to emit gamma radiation through the chamber and detect the radiation on an opposed side, intensity of received radiation indicating the density of contents of the chamber. 
         [0017]    In one embodiment, the pyrolysis chamber is agitated by rotation of at least two helical blades arranged to rotate close to an internal surface of the pyrolysis chamber. Preferably, the pyrolysis chamber is further agitated by a central auger. In one embodiment, the auger is located so that reverse operation of it causes output of char via a char outlet. 
         [0018]    In one embodiment, the temperature of pyrolysis gases at an outlet of the contactor is maintained in the range of 240° C. to 280° C. Preferably, the contactor outlet temperature is maintained by a heat exchanger at a contactor outlet. 
         [0019]    In one embodiment, a bottom section of the distillation column is maintained at a temperature in the range of 200° C. to 240° C., preferably 210° C. to 230° C. Preferably, the top of the distillation column is maintained at a temperature in the range of 90° C. to 110° C., preferably approximately 100° C. 
         [0020]    In one embodiment, diesel is drawn from the distillation column and is further distilled to provide on-specification fuels. 
         [0021]    In one embodiment, material is drawn from the top of the distillation column to a knock-out pot which separates water, oil, and non-condensable gases, in turn feeding a gas scrubber to prepare synthetic gases for use in furnaces. 
         [0022]    In one embodiment, there is further distillation of some material is in a vacuum distillation column. Preferably, heavy or waxy oil fractions are drawn from the bottom of the vacuum distillation column. In one embodiment, said heavy or waxy oil is recycled back to the pyrolysis chamber. In one embodiment, desired grade on-specification diesel is drawn from a middle section of the vacuum distillation column. In one embodiment, light fractions are drawn from a top section of the vacuum distillation column and are condensed. 
         [0023]    In one embodiment, the pyrolysis chamber and the contactor are purged in isolation from downstream components of the system. In one embodiment, a purging gas such as nitrogen is pumped through the pyrolysis chamber and the contactor and directly from the contactor to a thermal oxidizer where purging gas is burned. Preferably, any pyrolysis gases remaining at the end of a batch process are delivered from the contactor and are burned off together with the purging gas. 
         [0024]    In one embodiment, load on a pyrolysis chamber agitator is monitored to provide an indication of when char drying is taking place. 
         [0025]    In another aspect, the invention provides an apparatus for treating waste plastics material to provide at least one fuel product, the apparatus comprising:
       means for melting the waste plastics material,   a pyrolysis chamber for pyrolysing the molten material in an oxygen-free atmosphere to provide pyrolysis gases;   a conduit for bringing the pyrolysis gases into a contactor having a bank of condenser elements so that some long chain gas components condense on said elements,   a conduit for returning said condensed long-chain material to be further pyrolysed to achieve thermal degradation,   a conduit for allowing short chain gas components to exit from the contactor in gaseous form; and   a distillation column for distilling said pyrolysis gases from the contactor to provide one or more fuel products.       
 
         [0032]    In one embodiment, the contactor elements comprise a plurality of plates forming an arduous path for the pyrolysis gases in the contactor. 
         [0033]    In one embodiment, the plates are sloped downwardly for run-off of the condensed long-chain hydrocarbon, and include apertures to allow upward progression of pyrolysis gases. 
         [0034]    In one embodiment, there is a pipe directly linking the pyrolysis chamber to the contactor, the pipe being arranged for conveying upwardly-moving pyrolysis gases and downwardly-flowing long-chain liquid for thermal degradation. 
         [0035]    In one embodiment, the apparatus comprises a cooling means adapted to control a valve linking the jacket with a flue, opening of the valve causing cooling by down-draught and closing of the valve causing heating. 
         [0036]    In one embodiment, the valve provides access to a flue for exhaust gases of a combustion unit of the pyrolysis chamber. 
         [0037]    In one embodiment, the apparatus further comprises a purging means adapted to purge the pyrolysis chamber and the contactor in isolation from downstream components of the system, and to pump a purging gas through the pyrolysis chamber and the contactor and directly from the contactor to a thermal oxidizer where purging gas is burned. 
     
    
     
       DETAILED DESCRIPTION OF THE INVENTION 
         [0038]    The invention will be more clearly understood from the following description of some embodiments thereof, given by way of example only with reference to the accompanying drawings in which: 
           [0039]      FIG. 1  is a diagram showing a system of the invention for treatment of waste plastics; and 
           [0040]      FIG. 2  is a set of plots showing various key parameters monitored during operation of the system. 
       
    
    
     SYSTEM 
       [0041]    Referring to  FIG. 1 , a system for treatment of waste plastics comprises the following main components:
         1 , two waste plastics infeed hoppers, each receiving pelletized or flaked plastics material including all polythene variants, polystyrene, and polyproplene;     2 , plastics infeed conveyor;     3 , weigh belt;     4 , extruder having four heating stages to melt the plastics material to a final temperature of about 300° C.,     5 , feed lines from the extruder  4  to two pyrolysis chambers  6 ;     6 , pyrolysis chambers or reactors, of which there are four, each for oxygen-free pyrolysis of the hydrocarbons and delivering pyrolysis gases to a contactor  7 , and each chamber  6  has a combustion unit  8  and a char outlet  9 ;     7 , contactor having a cooling jacket  7 ( a ),     10 , purge lines for the pyrolysis chambers  6  and the contactors  7 ,     11 , flue valves for the contactors  7 , linking an exhaust flue to a jacket around the contactor vessel;     12 , pipe linking each pyrolysis chamber  6  with its associated contactor  7 , to allow hydrocarbon vapour (pyrolysis gases) to flow up and condensed heavy long-chain hydrocarbon material to flow back into the pyrolysis chamber  6  for thermal degradation treatment;     13 , stainless steel plates of the contactor, arranged with holes so pyrolysis gases can pass upwardly, and being sloped so that condensed long-chain hydrocarbon material runs down and back to the relevant pyrolysis chamber  6  via the pipe  12 ;     15 , pyrolysis gas outlet manifold for routing to distillation;     20 , first (atmospheric) distillation column;     21 , pump for diesel output of bottom of the first distillation column  20 , feeding a cooler  22 , in turn feeding a diesel holding tank  23  and a re-circulation link back to the distillation column  20 ;     24 , pump for pumping diesel fuel from the tank  23  to a heater  25 , which feeds a vacuum distillation column  26 ;     27 , pump for pumping waxy residues to a heater  28  for re-circulation, or as a recycled feedback to the pyrolysis chambers  6  according to control by valves, not shown;     35 , pump for pumping diesel via a cooler  36  from the vacuum distillation column  26  to a diesel holding tank  37 ;     38 , feedback link from the diesel product tank  37  to the holding tank  23 , for use if the final product diesel is determined after testing to not be at the required standard;     40 , outlet from the top of the first distillation column  20  to a light oil product tank  41 ;     42 , cooler for feed from the top of the vacuum distillation column  26  to a light oil tank  45 ;     45 , light oil tank having a link to a thermal oxidizer;     46 , pump for delivering light oil from the tank  45  to the light oil product tank  41 ;     55 , pump for pumping kerosene from the vacuum distillation column  26  to a kerosene product tank  60 ;     70 , cooler arranged to draw from the top of the first distillation column  20  to a knock-out pot  71  which separates water, oil, and non-condensable gases, in turn feeding a gas scrubber  72  to prepare synthetic gases for use in furnaces.       
 
       Process 
       [0066]    Waste plastics material is processed to granular or flake form. It is heated in the extruder  4  and molten plastics is fed into the pyrolysis chambers  6 . This is done while ensuring that no oxygen enters the system and molten plastics is maintained as close as possible to a pyrolysis temperature, preferably 300° C. to 320° C. 
         [0067]    In each pyrolysis chamber  6  the plastics material is heated to 390° C. to 410° C. in a nitrogen-purged system while agitating. Agitation is performed by a double helical agitator with a central screw, and the helical blades sweep at a separation of about 5 mm from the chamber internal surface. This maximizes heat transfer at walls of the vessel  6 , which is very advantageous due to the poor heat transfer properties of the infeed plastics material. 
         [0068]    Pyrolysis gases rise through the direct pipe link  12  to the contactor  7 . In the contactor  7  there is contact between the vapour and the metal plates  13  in a staggered baffle-like arrangement. This causes some condensation of the vapour long C chains. The proportion of gases which are condensed in this manner is approximately 15% to 20%. The level of condensation can be controlled by control of the temperature of the jacket  7 ( a ), which is cooled by chilled water and also by control of flue down-draught. 
         [0069]    The condensed liquid runs back through the same pipe  12  to the pyrolysis chamber  10  to be thermally degraded. The bottom of the contactor  6 , as shown in the expanded view of  FIG. 1 , is funnel-shaped to accommodate this flow. This process is referred to in this specification as thermal degradation. It avoids need for catalytic cracking as is performed in the prior art. The thermal degradation of the invention is achieved in a very simple manner, by simply allowing the pyrolysis gases to rise through the pipe  12  into the contactor  7  and for the longer/heavier chains to condense on the baffle plates  13  and from there to run back for further pyrolysis. It is our understanding that this mechanism avoids need for catalytic cracking because the contactors  7  ensure that the heavy/long carbon chains do not pass through the system but are broken down further in the contactors or fall back into the pyrolysis vessel for further degradation. Without them, very heavy material (half way between plastic and liquid fuel) will pass through the system, giving a large proportion of syngas. The baffle plates  13  provide an arduous path with a long residence time, and their apertures allow passage of the upwardly-flowing pyrolysis gases. 
         [0070]    It is envisaged that the plates may incorporate active cooling by being part of a heat exchanger. Such cooling could be controlled to fine-tune the grade of end-product diesel obtained. 
         [0071]    Importantly, the thermal degradation avoids need for catalysts, which would be expensive, require replacement, and may be consumed in the process. The prior art catalyst waste material is often hazardous, resulting in expensive disposal Also, the prior processes involving catalysts are much more complicated and have tighter operating conditions. 
         [0072]    An advantageous aspect of the contactor operation is that the valves  11  are used to cool down the contactors by allowing down-draught from the flue into the surrounding jacket. This is in contrast to the prior catalytic cracking approach, in which efforts are made to heat the catalysts as much as possible. We have found that by providing the valves  11  with access to the flue we have a very simple and effective mechanism for cooling the contactor. The temperature control of the contactors  7  is achieved by opening and closing the flue valves  11 , opening a contactor tower flue valve  11  cools the contactor due to the chimney down-draught effect. Also, cooling of the contactors takes place by controlling water flow through water pipes running through the contactor jackets  7 ( a ). 
         [0073]    The vapour at 250° C. to 300° C. and most preferably at 260° C. to 280° C. is fed into the first distillation column  20 . The sump at the bottom of the column  20  has re-circulation through the pump  21  and the cooler  22  and the temperature is maintained as close as possible to 220° C. in this part of the column  20 . 
         [0074]    By appropriate operation of valves, diesel is drawn from the sump of the column  20  into the tank  23  and from there to the vacuum distillation column  26 . On-spec diesel is provided from the vacuum distillation column  26  to the product tank  37 . 
         [0075]    The vacuum distillation column  26  allows operation at much lower temperatures and is smaller, while achieving equivalent results to an atmospheric distillation column. 
         [0076]    The top part of the first distillation column  20  is maintained as close as possible to 100° C. Light oil is drawn directly to the tank  41 . This is a by-product, but may be used to power a low-compression engine to power the plant or to generate electrical power for the grid. 
         [0077]    There is also a feed of light oil to the tank  41  from the top of the vacuum distillation column  26  via the tank  45  and the pump  46 . It has been found that the first distillation column  20  has about 20% light oil output and the vacuum column  26  has about 10% light oil output. 
         [0078]    The gas scrubber  72  washes and prepares the synthetic gases for use in the furnaces for the pyrolysis chamber (process is parasitic), and waste water is delivered for treatment. 
         [0079]    Diesel is drawn from the bottom section of the first distillation column  20  to the holding tank  23  from which it is fed via the heater  25  to the vacuum tower  26 . Heavy oil is drawn from the bottom section of the vacuum tower  26  and is used as a supply for the pyrolysis chambers, suitably heated by the wax heater  28 . The main product, diesel, is drawn from the middle section of the vacuum column  26  via the cooler  36  to the product tank  37 . 
         [0080]    Regarding the components  70 ,  71 , and  72  linked with the top of the first distillation column  20 , synthetic gases are taken off the top of the column  20 . The cooler  70  draws from the top of the column  20  to the knock-out pot  71 , which separates water, oil, and non-condensable gases, in turn feeding a gas scrubber  72  to prepare synthetic gases for use in furnaces. There is feedback from the knock-out pot  71  to the top of the column  20 . Levels are automatically controlled. 
         [0081]    As a batch ends, increased load on the pyrolysis chamber agitator indicates that char drying is taking place, and that the process is ending. Rather than purge the full system with N 2 , risking the N 2  carrying char through the full system, N 2  is purged via the conduits  10  through the contactors  7  and the pyrolysis chambers  6  only. Resulting vapour is drawn off from above the contactors  7  and is burned off in a thermal oxidizer. This allows the system to continue without being distorted and isolates mechanical removal of the char. The pyrolysis chambers  6  are purged with nitrogen which passes up through the contactor  6  and out the top directly to thermal oxidisers to flush any remaining hydrocarbons. This ensures a safe char removal sequence. During this phase the pyrolysis vessel  6  and contactor  7  have been isolated from the rest of the system. This reduces process time and prevents char from being carried through the system and fouling components such as the fuel lines and pumps. It has been found that this provides improved stability in the process by avoiding risk of contamination of downstream components with char particles. It also reduces the purging time. 
         [0082]    The double helical agitator blades are operated in reverse to remove char during purging. This char removal process can be performed continuously, if desired. 
         [0083]    The char leaves the pot by opening a large valve at the base of the pyrolysis vessel  6 . Under the pyrolysis vessel is a negatively charged pot which initially draws the char into it. The agitator is designed at the base such that when it operates in the reverse direction to that during processing it sweeps the char into the centre of the vessel and the agitator screw pushes the char down into a char pot. Once cooled, the char is vacuumed into a char vessel for removal from site. 
         [0084]    The pyrolysis chamber jacket is heated to c. 590° C. so that there is further drying of the char for about 4 hours. 
         [0085]    Although not illustrated, each pyrolysis chamber  6  has a detector for determining content of the chamber for control purposes. The detector comprises a gamma radiation source on one side and a receiver along the opposed side. The intensity of radiation detection on the receiving side provides an indication of level in the chamber  6 . A major advantage is that the emitter and the receiver are mounted on the outside of the chamber  6 , and so are totally non-invasive. The emitted gamma radiation is attenuated as it passes through the chamber  6 , the intensity detected at the receiver being an indication of the density of contents of the chamber  6 . 
         [0086]    Referring to  FIG. 2  various parameters for the system are monitored for effective system control. It shows that as the agitator load increases (in this example at about 14.30 hours) when char drying is taking place. It also shows that the bottom of the first distillation column  20  stays approximately constant, even between batches, due to operation of a heater. 
         [0087]    It will also be appreciated that the contactor  7  outlet temperature can rise above optimum towards the end of the batch. 
         [0088]    It has been found that the process as described above provides a high quality diesel product in the tank  37 , meeting the EN590 European standards. The other major on-spec fuel is BS2869 for kerosene. 
         [0089]    The invention is not limited to the embodiments described but may be varied in construction and detail. For example, there may be a cooler at the contactor  7  outlet to maintain a vapour outlet temperature in the desired range. Also, there may be additional active cooling of the contactors  7 , such as by chilled water circulation in a jacket around the contactor plates, or indeed by an arrangement in which the contactor has an active heat exchanger in direct contact with the pyrolysis gases. Such a heat exchanger may replace some or all of the baffle plates described above. This cooler may for example work with oil which is passed through the cooler at the target temperature. Chilled water may be used to control the oil temperature. The cooling system may also include a liquid knockout pot for return of heavier chains to the pyrolysis chambers  6  for further cracking. It has been found that maintenance of the vapour temperature at this level at the outlet of the contactor  7  is particularly advantageous for achieving the desired grade of fuel products.