Abstract:
A photosensitive polymer having a cyclic backbone and containing an alicyclic compound and a resist composition obtained therefrom are provided. The photosensitive polymer has a weight-average molecular weight of between about 3,000-100,000 and represented by the following formula:                            
     wherein R 1  is tert-butyl, tetrahydropyranyl, 1-alkoxyethyl or 1-alkoxymethyl, R 2  is hydrogen, cyano, hydroxy, hydroxymethyl, carboxylic acid, 2-hydroxyethyloxycarbonyl or tert-butoxycarbonyl, or alicyclic compound, R 3  is hydrogen or methyl, R 4  is hydrogen, 2-hydroxyethyl, isobornyl, tert-butyl, adamantyl, norbornyl or menthyl, 1/(l+m+n+p) is between about 0.1-0.5, m/(l+m+n+p) is between about 0.3-0.5, n/(l+m+n+p) is between about 0.0-0.3, and p/(l+m+n+p) is between about 0.0-0.3.

Description:
BACKGROUND OF THE INVENTION 
     1. Field of the Invention 
     The present invention relates to a chemically amplified resist composition, and more particularly, to a photosensitive polymer having a cyclic backbone, and a resist composition for an ArF excimer laser obtained therefrom. 
     2. Description of the Related Art 
     As semiconductor devices become highly integrated and complicated to fabricate, fine pattern formation is required. 
     Further, as the capacity of a semiconductor device increases to exceed 1 giga bit, a pattern size having a design rule of less than 0.2, μm is required. Accordingly, there are limitations in using a conventional resist material with a KrF excimer laser (248 nm). Thus, a new resist material capable of being developed using an ArF excimer laser (193 nm) has been developed in a lithography process. 
     The resist material used in the lithography process using the ArF excimer laser has several problems in being commercially used, compared to the conventional resist materials. The most typical problems are transmittance of a polymer and resistance to dry etching. As the widely known ArF resist materials, (meth)acrylate polymers are generally used. In particular, the most typical resist material is a poly(methyl methacrylate-tert-butyl methacrylate-methacrylic acid) terpolymer system manufactured by IBM, Inc. However, such polymers have very weak resistance to dry etching. 
     Accordingly, to increase the resistance to dry etching, a polymer having a backbone composed of an alicyclic compound such as an isobornyl group, an adamantyl group or a tricyclodecanyl group, is used. However, the resulting resist still exhibits weak resistance to dry etching. 
     SUMMARY OF THE INVENTION 
     To solve the above problems, it is an objective of the present invention to provide a photosensitive polymer whose backbone has a cyclic structure and contains an alicyclic compound, for obtaining sufficiently strong resistance to dry etching. 
     It is another objective of the present invention to provide a resist composition containing the photosensitive polymer suitable for use in a lithography process using an ArF excimer laser. 
     To achieve the first objective, a photosensitive polymer is provided having a weight-average molecular weight of between about 3,000-100,000 and represented by the following formula:                           
     wherein R 1  is tert-butyl, tetrahydropyranyl, 1-alkoxyethyl or 1-alkoxymethyl group, R 2  is hydrogen, cyano (-CN), hydroxy, hydroxymethyl, carboxylic acid, 2-hydroxyethyloxycarbonyl or tert-butoxycarbonyl, or alicyclic compound, R 3  is hydrogen or methyl, R 4  is hydrogen, 2-hydroxyethyl, isobornyl, tert-butyl, adamantyl, norbornyl or menthyl, 1/(l+m+n+p) is between about 0.1-0.5, m/(l+m+n+p) is between about 0.3-0.5, n/(l+m+n+p) is between about 0.0-0.3, and p/(l+m+n+p) is between about 0.0-0.3. 
     Preferably, R 1  is selected from the group consisting of 1-ethoxyethyl, 1-ethoxypropyl, ethoxymethyl and methoxymethyl. 
     Also, R 2  is preferably isobornyloxycarbonyl group. 
     According to another aspect of the present invention, there is provided a resist composition including (a) a photosensitive polymer having a weight-average molecular weight of between about 3,000-100,000 and represented by the following formula:                           
     wherein R 1  is tert-butyl, tetrahydropyranyl, 1-alkoxyethyl or 1-alkoxymethyl, R 2  is hydrogen, cyano, hydroxy, hydroxymethyl, carboxylic acid, 2-hydroxyethyloxycarbonyl or tert-butoxycarbonyl, or alicyclic compound, R 3  is hydrogen or methyl, R 4  is hydrogen, 2-hydroxyethyl, isobornyl, tert-butyl, adamantyl, norbornyl or menthyl, l/(l+m+n+p) is between about 0.1-0.5, m/(l+m+n+p) is between about 0.3-0.5, n/(l+m+n+p) is between about 0.0-0.3, and p/(l+m+n+p) is between about 0.0-0.3, and (b) a photoacid generator (PAG). 
     Preferably, the PAG is selected from the group consisting of tiarylsulfonium salts, diaryliodonium salts, sulfonates, and mixtures thereof. 
     The resist composition may further include an organic base. The organic base is preferably contained in the composition in an amount of between about 0.01-2.0 weight percent based on the weight of the polymer. 
     The organic base may be selected from the group consisting of triethylamine, triisobutylamine, triisooctylamine, diethanol amine, triethanol amine, and mixtures thereof may be used. 
     According to the present invention, a photosensitive polymer is provided whose backbone has a cyclic structure and contains an alicyclic compound, thereby attaining resistance to dry etching. Also, since the polymer is prepared by using a monomer having two protective groups, a change in solubilities of the resist composition obtained from the polymer before and after exposure is made large, thereby increasing the contrast of the resist composition. 
     DESCRIPTION OF THE PREFERRED EMBODIMENTS 
    
    
     EXAMPLE 1 
     Synthesis of 2,3-di-tert-butoxycarbonyl 5-norbornene 
     
       
                 
         
             
             
         
      
     
     34 g of potassium tert-butoxide (0.3 mol) was dissolved in 200 ml of dichloromethane (CH 2 Cl 2 ) in a round-bottom flask, 22 g of 5-norbornene-2,3-dicarbonyl chloride (0.1 mol) was slowly added thereto, and the reactant was reacted at a temperature of 45° C. for about 12 hours. 
     After the reaction was completed, excess solvent was evaporated, the product was poured into excess water and neutralized using HCl. Thereafter, the product was extracted using diethyl ether dried using MgSO 4 , to then separate a desired product (yield: 65%). 
     EXAMPLE 2 
     Synthesis of 2,3-di-tetrahydropyranyloxycarbonyl 5-norbornene 
     18.2 g of 5-norbornene-2,3-dicarboxylic acid (0.1 mol) and 34 g of 2,3-dihydropyran (0.4 mol) were dissolved in 150 ml of methylene chloride in a round-bottom flask, and a small amount of p-toluene sulfonic acid was added thereto. Thereafter, the reactant was reacted in a reflux condition for about 12 hours. 
     After the reaction was completed, the obtained product was poured into excess water and neutralized using potassium carbonate. Thereafter, the product was extracted using methylene chloride and a desired product was separated using column chromatography (ethyl acetate:n-hexane=1:3) (yield: 80%). 
     EXAMPLE 3 
     Synthesis of 2,3-di-ethoxy-1-ethyloxycarbonyl 5-norbornene 
     The reaction was carried out in the same manner as in Example 2 using ethyl vinyl ether (0.4 mol) and then the product was separated by vacuum distillation (yield: 75%). 
     EXAMPLE 4 
     Synthesis of Copolymer 
     
       
                 
         
             
             
         
      
     
     4-1. Synthesis of Copolymer wherein R is tert-butyl 
     15 g of monomer synthesized in Example 1 (50 mmol), 4.9 g of maleic anhydride (50 mmol) and 0.17 g of azobis(isobutyronitrile) (AIBN) were dissolved in 10 g of anhydrous dioxane, and degassed using ampule by a freezing method. Thereafter, the reactant was polymerized at 70° C. for about 24 hours. 
     After the polymerization was completed, the reactant was slowly dropped into excess n-hexane to be precipitated, dissolved again in Tetrahydrofuran (THF) and reprecipitated in a co-solvent (n-hexane:isopropylalcohol=8:2) to obtain the polymer (yield: 40%). 
     The weight-average molecular weight and polydispersity of the obtained product were 12,600 and 1.8, respectively. 
     4-2. Synthesis of Copolymer wherein R is tetrahydropyranyl 
     Polymerization was carried out using the monomer synthesized in Example 2 (50 mmol) and 4.9 g of maleic anhydride (50 mmol) in the same manner as in Example 4-1 to then obtain the polymer in the same precipitation method as in Example 4-1. 
     The weight-average molecular weight and polydispersity of the obtained product were 13,100 and 1.9, respectively. 
     4-3. Synthesis of Copolymer wherein R is 1-ethoxyethyl 
     Polymerization was carried out using the monomer synthesized in Example 3 (50 mmol) and 4.9 g of maleic anhydride (50 mmol) in the same manner as in Example 4-1 to then obtain the polymer in the same precipitation method as in Example 4-1. 
     The weight-average molecular weight and polydispersity of the obtained product were 13,100 and 1.9, respectively. 
     EXAMPLE 5 
     Synthesis of terpolymer 
     
       
                 
         
             
             
         
      
     
     5-1. Synthesis of terpolymer wherein R 1  is tert-butyl and R 2  is hydroxymethyl 
     The monomer synthesized in Example 1 (40 mmol), 5-norbornene-2-methanol (10 mmol), 4.9 g of maleic anhydride (50 mmol) and 0.17 g of azobis(isobutyronitrile) (AIBN) were dissolved in anhydrous dioxane (half fold), and degassed using ampule by a freezing method. Thereafter, the reactant was polymerized at 70° C. for about 24 hours. 
     After the polymerization was completed, the reactant was slowly dropped into excess n-hexane to be precipitated, dissolved again in THF and reprecipitated in a co-solvent (n-hexane:isopropylalcohol=9:1) to obtain the polymer (yield: 40%). 
     The weight-average molecular weight and polydispersity of the obtained product were 12,600 and 1.8, respectively. 
     5-2. Synthesis of terpolymer wherein R 1  is tert-butyl and R 2  is carboxylic acid 
     Polymerization was carried out using the monomer synthesized in Example 1 (45 mmol), 5-norbornene-2-carboxylic acid (5 mmol) and maleic anhydride (50 mmol) in the same manner as in Example 5-1, and then the polymer was obtained using the same precipitation method as in Example 5-1. 
     The weight-average molecular weight and polydispersity of the obtained product were 13,700 and 1.9, respectively. 
     5-3. Synthesis of terpolymer wherein R 1  is tetrahydropyranyl and R 2  is 2-hydroxyethyloxycarbonyl 
     Polymerization was carried out using the monomer synthesized in Example 2 (40 mmol), 2-hydroxyethyl 5-norbornene-2-carboxylate (10 mmol) and maleic anhydride (50 mmol) in the same manner as in Example 5-1, and then the polymer was obtained using the same precipitation method as in Example 5-1. 
     The weight-average molecular weight and polydispersity of the obtained product were 13,300 and 2.0, respectively. 
     5-4. Synthesis of terpolymer wherein R 1  is 1-ethoxyethyl and R 2  is hydrogen 
     Polymerization was carried out using the monomer synthesized in Example 3 (40 mmol), norbornene (10 mmol) and maleic anhydride (50 mmol) in the same manner as in Example 5-1, and then the polymer was obtained using the same precipitation method as in Example 5-1. 
     The weight-average molecular weight and polydispersity of the obtained product were 12,300 and 2.2, respectively. 
     EXAMPLE 6 
     Synthesis of terpolymer 
     
       
                 
         
             
             
         
      
     
     6-1. Synthesis of terpolymer wherein R 1  is tert-butyl, R 2  hydrogen and R 3  is hydroxyethyl 
     The monomer synthesized in Example 1 (40 mmol), 2-hydroxyethyl acrylate (10 mmol), maleic anhydride (50 mmol) and 0.17 g of azobis(isobutyronitrile) (AIBN) were dissolved in 10 g of anhydrous dioxane (one fold), and degassed using ampule by a freezing method. Thereafter, the reactant was polymerized at 70° C. for about 24 hours. 
     After the polymerization was completed, the reactant was slowly dropped into excess n-hexane to be precipitated, dissolved again in THF and reprecipitated in a co-solvent (n-hexane:isopropylalcohol=9:1) to obtain the polymer (yield: 45%). 
     The weight-average molecular weight and polydispersity of the obtained product were 12,600 and 2.0, respectively. 
     6-2. Synthesis of terpolymer wherein R 1  is tert-butyl, R 2  is methyl and R 3  is hydrogen 
     Polymerization was carried out using the monomer synthesized in Example 1 (45 mmol), methyl methacrylate (5 mmol) and maleic anhydride (50 mmol) in the same manner as in Example 6-1, and then the polymer was obtained using the same precipitation method as in Example 6-1. 
     The weight-average molecular weight and polydispersity of the obtained product were 13,700 and 2.2 respectively. 
     6-3. Synthesis of terpolymer wherein R 1  is tetrahydropyranyl, R 2  is methyl and R 3  is 2-hydroxyethyl 
     Polymerization was carried out using the monomer synthesized in Example 2 (40 mmol), 2-hydroxyethyl methacrylate (10 mmol) and maleic anhydride (50 mmol) in the same manner as in Example 6-1, and then the polymer was obtained using the same precipitation method as in Example 6-1. 
     The weight-average molecular weight and polydispersity of the obtained product were 13,300 and 2.1, respectively. 
     6-4. Synthesis of terpolymer wherein R 1  is 1-ethoxyethyl, R 2  is methyl and R 3  is 2-hyroxyethyl 
     Polymerization was carried out using the monomer synthesized in Example 3 (40 mmol), 2-hydroxyethyl methacrylate (5 mmol) and maleic anhydride (50 mmol) in the same manner as in Example 6-1, and then the polymer was obtained using the same precipitation method as in Example 6-1. 
     The weight-average molecular weight and polydispersity of the obtained product were 12,300 and 2.2, respectively. 
     EXAMPLE 7 
     Synthesis of tetrapolymer 
     The monomer synthesized in Example 1 (40 mmol), 5-norbornene-2-methanol (10 mmol), maleic anhydride (50 mmol), isobornyl acrylate (5 mmol) and 1 mole % of azobis(isobutyronitrile) (AIBN) were dissolved in anhydrous dioxane (one fold), and degassed using ampule by a freezing method. Thereafter, the reactant was polymerized at 70° C. for about 24 hours. 
     After the polymerization was completed, the reactant was slowly dropped into excess n-hexane to be precipitated, dissolved again in THF and reprecipitated in a co-solvent (n-hexane:isopropylalcohol=9:1) to obtain the polymer (yield: 45%). 
     The weight-average molecular weight and polydispersity of the obtained product were 12,600 and 2.2, respectively. 
     EXAMPLE 8 
     Synthesis of tetrapolymer 
     Polymerization was carried out using the monomer synthesized in Example 1 (40 mmol), 5-norbornene-2 carboxylic acid (10 mmol), isobornyl acrylate (10 mmol) and maleic anhydride (50 mmol) in the same manner as in Example 7, and then the polymer was obtained using the same precipitation method as in Example 7. 
     The weight-average molecular weight and polydispersity of the obtained product were 13,100 and 2.1, respectively. 
     EXAMPLE 9 
     Synthesis of tetrapolymer 
     Polymerization was carried out using the monomer synthesized in Example 1 (30 mmol), acrylic acid (10 mmol), 2-isobornyl 5-norbornene-2 carboxylate (10 mmol) and maleic anhydride (50 mmol) in the same manner as in Example 7, and then the polymer was obtained using the same precipitation method as in Example 7. 
     The weight-average molecular weight and polydispersity of the obtained product were 14,100 and 2.3, respectively. 
     EXAMPLE 10 
     Synthesis of tetrapolymer 
     Polymerization was carried out using the monomer synthesized in Example 1 (30 mmol), norbornene (20 mmol), 2-hydroxyethyl methacrylate (20 mmol) and maleic anhydride (50 mmol) in the same manner as in Example 7, and then the polymer was obtained using the same precipitation method as in Example 7. 
     The weight-average molecular weight and polydispersity of the obtained product were 12,100 and 2.1, respectively. 
     EXAMPLE 11 
     Patterning Process Using Resist Composition 
     Hereinbelow, the following processes were used for preparing the resist compositions used in a patterning process. 
     1.0 g of polymer selected from polymers synthesized in Examples 4 through 10, 20 mg of triphenyl sulfonium triflate as a photoacid generator and 2 mg of triisobutylamine as an organic base were completely dissolved in 6.0 g of propylene glycol monomethyl ether acetate (PGMEA). Thereafter, the solution was filtered using a 0.2 μm membrane filter to obtain a resist composition. Then, for a patterning process using the resist composition obtained by the above method, the following processes were used. 
     A silicon wafer having a silicon oxide film formed thereon was prepared and treated with hexamethyldisilazane (HMDS). Then, the resist composition was coated on the silicon oxide film to a thickness of about 0.4 μm. 
     The wafer having the resist composition coated thereon was pre-baked at a temperature of 100 to 130° C. for 60 to 120 seconds and exposed to light using a KrF excimer laser having a numerical aperture of 0.45 or an ArF excimer laser having a numerical aperture of 0.6. Then, post exposure baking (PEB) was performed at a temperature of 100 to 140° C. for 60 to 120 seconds. 
     Thereafter, the resultant was developed using 2.38 wt % of tetramethylammonium hydroxide (TMAH) solution for about 20 to 60 seconds. As a result, the silicon oxide film was etched with a predetermined etching gas using the obtained resist pattern as a mask. Subsequently, the resist pattern remaining on the silicon wafer was removed using a stripper to form a desired silicon oxide pattern. 
     Next, detailed examples of forming patterns using the resist composition prepared in the same method as in Example 11 will be described. 
     EXAMPLE 11-1 
     A resist composition was prepared using 1.0 g of the polymer synthesized in Example 4-2 in the same method as in Example 11 and the obtained resist composition was coated on a wafer. 
     Thereafter, the wafer having the resist composition coated thereon was pre-baked at a temperature of 100° C. for 90 seconds and exposed to light using a KrF excimer laser having a numerical aperture of 0.45. Then, post exposure baking (PEB) was performed at a temperature of 100° C. for 90 seconds. 
     The resultant was developed using 2.38 wt % of TMAH solution for about 60 seconds to form a resist pattern. As a result, when an exposure dose was about 23 mJ/cm 2 , it was observed that a 0.5 μm line and space pattern was obtained. 
     EXAMPLE 11-2 
     A resist composition was prepared using 1.0 g of the polymer synthesized in Example 5-1, 30 mg of triphenylsulfonirum triflate as a PAG and 3 mg of triethanolamine as an organic base in the same method as in Example 11 and the obtained resist composition was coated on a wafer. 
     Thereafter, the wafer having the resist composition coated thereon was pre-baked at a temperature of 140° C. for 90 seconds and exposed to light using a KrF excimer laser having a numerical aperture of 0.45. Then, post exposure baking (PEB) was performed at a temperature of 120° C. for 90 seconds. 
     The resultant was developed using 2.38 wt % of TMAH solution for about 60 seconds to form a resist pattern. 
     As a result, when an exposure dose was about 21 mJ/cm 2 , it was observed that a 0.4 μm line and space pattern was obtained. 
     EXAMPLE 11-3 
     A resist composition was prepared using 1.0 g of the polymer synthesized in Example 5-2 in the same method as in Example 11 and the obtained resist composition was coated on a wafer. 
     Thereafter, the wafer having the resist composition coated thereon was pre-baked at a temperature of 140° C. for 90 seconds and exposed to light using an ArF excimer laser having a numerical aperture of 0.6. Then, post exposure baking (PEB) was performed at a temperature of 110° C. for 90 seconds. 
     The resultant was developed using 2.38 wt % of TMAH solution for about 60 seconds to form a resist pattern. As a result, when an exposure dose was about 11 mJ/cm 2 , it was observed that a 0.3 μm line and space pattern was obtained. 
     EXAMPLE 11-4 
     A resist composition was prepared using 1.0 g of the polymer synthesized in Example 6-1 in the same method as in Example 11 and the obtained resist composition was coated on a wafer. 
     Thereafter, the wafer having the resist composition coated thereon was pre-baked at a temperature of 140° C. for 90 seconds and exposed to light using an ArF excimer laser having a numerical aperture of 0.6. Then, post exposure baking (PEB) was performed at a temperature of 120° C. for 90 seconds. 
     The resultant was developed using 2.38 wt % of TMAH solution for about 45 seconds to form a resist pattern. 
     As a result, when an exposure dose was about 14 mJ/cm 2 , it was observed that a 0.3 μm line and space pattern was obtained. 
     EXAMPLE 11-5 
     A resist composition was prepared using 1.0 g of the polymer synthesized in Example 6-3 in the same method as in Example 11 and the obtained resist composition was coated on a wafer. 
     Thereafter, the wafer having the resist composition coated thereon was pre-baked at a temperature of 110° C. for 90 seconds and exposed to light using an ArF excimer laser having a numerical aperture of 0.6. Then, post exposure baking (PEB) was performed at a temperature of 110° C. for 90 seconds. 
     The resultant was developed using 2.38 wt % of TMAH solution for about 60 seconds to form a resist pattern. 
     As a result, when an exposure dose was about 13 mJ/cm 2 , it was observed that a 0.3 μm line and space pattern was obtained. 
     EXAMPLE 11-6 
     A resist composition was prepared using 1.0 g of the polymer synthesized in Example 7, 30 mg of triphenylsulfonirum triflate as a PAG and 3 mg of triethanolamine as an organic base in the same method as in Example 11 and the obtained resist composition was coated on a wafer. 
     Thereafter, the wafer having the resist composition coated thereon was pre-baked at a temperature of 140° C. for 90 seconds and exposed to light using a KrF excimer laser having a numerical aperture of 0.45. Then, post exposure baking (PEB) was performed at a temperature of 120° C. for 90 seconds. 
     The resultant was developed using 2.38 wt % of TMAH solution for about 60 seconds to form a resist pattern. 
     As a result, when an exposure dose was about 21 mJ/cm 2 , it was observed that a 0.5 μm line and space pattern was obtained. 
     EXAMPLE 11-7 
     A resist composition was prepared using 1.0 g of the polymer synthesized in Example 8, 20 mg of triphenylsulfonirum triflate as a PAG and 2 mg of triisobutylamine as an organic base in the same method as in Example 11 and the obtained resist composition was coated on a wafer. 
     Thereafter, the wafer having the resist composition coated thereon was pre-baked at a temperature of 140° C. for 90 seconds and exposed to light using an ArF excimer laser having a numerical aperture of 0.6. Then, post exposure baking (PEB) was performed at a temperature of 120° C. for 90 seconds. 
     The resultant was developed using 2.38 wt % of TMAH solution for about 60 seconds to form a resist pattern. 
     As a result, when an exposure dose was about 13 mJ/cm 2 , it was observed that a 0.3 μm line and space pattern was obtained. 
     EXAMPLE 11-8 
     A resist composition was prepared using 1.0 g of the polymer synthesized in Example 9, 20 mg of triphenylsulfonirum nonaflate as a PAG and 2 mg of diethanolamine as an organic base in the same method as in Example 11 and the obtained resist composition was coated on a wafer. 
     Thereafter, the wafer having the resist composition coated thereon was pre-baked at a temperature of 140° C. for 90 seconds and exposed to light using an ArF excimer laser having a numerical aperture of 0.6. Then, post exposure baking (PEB) was performed at a temperature of 110° C. for 90 seconds. 
     The resultant was developed using 2.38 wt % of TMAH solution for about 60 seconds to form a resist pattern. 
     As a result, when an exposure dose was about 15 mJ/cm 2 , it was observed that a 0.3 μm line and space pattern was obtained. 
     EXAMPLE 11-9 
     A resist composition was prepared using 1.0 g of the polymer synthesized in Example 10, 20 mg of 4-methoxy-diphenyliodonium triflate as a PAG and 2 mg of triisobutylamine as an organic base in the same method as in Example 11 and the obtained resist composition was coated on a wafer. 
     Thereafter, the wafer having the resist composition coated thereon was pre-baked at a temperature of 140° C. for 90 seconds and exposed to light using an ArF excimer laser having a numerical aperture of 0.6. Then, post exposure baking (PEB) was performed at a temperature of 120° C. for 90 seconds. 
     The resultant was developed using 2.38 wt % of TMAH solution for about 60 seconds to form a resist pattern. 
     As a result, when an exposure dose was about 13 mJ/cm 2 , it was observed that a 0.3 μm line and space pattern was obtained. 
     As described above, according to the present invention, by providing a polymer whose backbone has a cyclic structure and contains an alicyclic compound in its protecting group capable of strengthening dry etching resistance of the polymer, sufficiently increased dry etching resistance can be obtained. 
     Also, in the present invention, since a polymer is synthesized using a monomer having two protecting groups, the resist contrast can be increased by increasing difference in solubility between before and after the polymer is exposed to light. 
     Also, adhesiveness to an underlying film material can be increased by introducing various comonomers which increase adhesiveness of a resist composition to form a copolymer. Further, the resist can be patterned using a general developer solution, i.e., 2.38 wt % TMAH solution. 
     Therefore, the resist composition having a polymer according to the present invention can obtain sufficient dry etching resistance. Also, excellent lithographic performance can be obtained using the resist composition obtained from the polymer, and the resist composition according to the present invention can be useful in the manufacture of next generation semiconductor devices. 
     While this invention has been particularly shown and described with references to preferred embodiments thereof, it will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims.