Abstract:
A process that uses targeted in-furnace Injection to feed a fluxing agent of the chemical family of compositions containing boron and/or alkali hydrates to either decrease heat transfer on waterwalls of utility furnaces burning solid fuels to improve steam generation, maintain steam temperature, and/or allow a protective layer of slag to form inside the barrels of cyclones on cyclone boilers burning fuels high in calcium so that the boiler can operate at a wider variety of power settings while allowing proper flow and drainage of slag from the cyclone barrels.

Description:
CROSS REFERENCE TO RELATED APPLICATIONS 
       [0001]    This application claims priority to pending US Provisional Patent Application Ser. No. 61/307,228, filed Feb. 23, 2010, which is hereby incorporated by reference in its entirety. 
     
    
     FIELD OF THE INVENTION 
       [0002]    The invention relates generally to improving the operation of cyclone burners and the combustors or boilers they fire by assuring adequate slag properties to modulate slag plasticity to a new effective level, enabling formation and maintenance of a protective layer of slag on inside wall of a cyclone barrel while assuring a viscosity that permits the constantly forming slag to flow to drains. 
         [0003]    In particular, the invention provides a system, apparatus and method for improving the operation of cyclone boilers by increasing operating flexibility and efficiency of a cyclone furnace while burning Powder River Basin (PRB) or similar coal by using a specifically effective fluxing composition in a highly efficient and effective manner. 
       BACKGROUND OF THE INVENTION 
       [0004]    As originally developed, cyclone burners were characterized as including a horizontally disposed cylindrical barrel attached through the side of a boiler furnace. The original design achieved a commercial following in part because they could take advantage of a variety of coal grades, including some not suitable for pulverized coal combustion. Cyclone furnaces will typically spirally feed coal into a combustion chamber to achieve maximum combustion efficiency.  FIG. 1  is a schematic drawing of a prior art cyclone burner. In addition to providing flexibility of coal type, they also reduced fuel preparation time and costs, were smaller and more compact than other furnaces and produced less fly ash and convective pass slagging. 
         [0005]    These furnaces require a protective layer of slag to be formed and maintained on the inside of the cyclone barrel wall ( 12  in  FIG. 1 ) to provide a degree of insulation for the wall materials. This slag layer is constantly renewed and drained, and it is essential that the slag viscosity always permits the slag to flow to drains. The slag must have a consistency sufficient to maintain the insulating layer, but not be so thick that it can cool and stop flow to or through drains. The slag further functions to hold larger coal particles as they continue to burn as the slag empties from the combustor. 
         [0006]    In these furnaces, the cyclone barrel is typically constructed with water-cooled, tangential-oriented, tube construction and the burners include a water-cooled horizontal cylinder in which fuel (coal, gas, or oil) is fired and heat is released at extremely high rates. When firing coal, the crushed coal is introduced tangentially into the burner, usually with primary air. The cyclone barrel extends into the furnace where it opens to supply burning hot gases and slag to the furnace interior. Typically during combustion of coal, volatile components are released from the coal and burn well. However, the fuel carbon results in “char” particles, which are less volatile and heavier. The char requires higher temperatures and benefit from the swirling supply of oxygen in a cyclone furnace, which provides thorough mixing of coal particles and air with sufficient turbulence to constantly renew fresh air to coal particle surfaces. The cyclonic fuel swirling in these burners is increased and maintained by tangentially-introduced, high-velocity secondary air. 
         [0007]    The cyclone barrel is water cooled and cools the slag while the slag insulates the barrel material as it cools. The cyclone is designed to operate at high temperatures to maintain the slag in a molten state and allow removal through the trap. A layer of molten slag coats the burner and flows through traps at the bottom of the burners. Because the slag is formed largely within the burners, the amount of slag that would otherwise form on the boiler tubes in the boiler or other combustor is reduced. While low volatile bituminous coals, lignite coal, mineral rich anthracitic coal, wood chips, petroleum coke, and old tires can and have all been used in cyclones, certain subbituminous coals high in alkaline earth metals, especially calcium, like Powder River Basin (PRB) coals, tend to produce slags that suffer from inconsistent properties. 
         [0008]    PRB and like subbituminous coals tend to produce slags that exhibit a surprisingly sharp drop in viscosity over short temperature spans. Drops of over 10,000 centipoises can occur in the temperature range of from 2250° to 2350° F., to a value below the normal operating temperature of the cyclone boiler. Because it is generally agreed that stable operation of a slagging cyclone combustor requires the ash layer to remain molten. The slag viscosity must be low enough to permit continuous drainage as is illustrated in  FIG. 1 . A typical viscosity for steady drainage has been shown to be about 250 centipoises, and the art refers to the temperature corresponding to this viscosity level as T250. Stable operation mandates a slag temperature of greater than or equal to T250. Unless the PRB coal is burned to achieve slag with the correct viscosity-temperature relationship, the furnace cannot operate efficiently at any temperature or will be restricted to only higher loads. The slag can freeze and cause shut down at the low end of a narrow temperature range or it might run too freely and not provide the optimum temperature differential at the surface of the water cooled-cyclone barrel at the high end of the temperature range. If it is desired to reduce the load, a secondary fuel may be required to just keep the slag hot enough. 
         [0009]    PRB coals are desired because of their low sulfur contents and economy, but have proved a challenge to cyclone burner operators, and efforts have been made to correct the difficulties experienced. Current remediating technology typically involves feeding iron oxides, e.g., as made from scale that came from steel plant hot strip rolling plants, into the furnace on a weight basis with the amount of coal used. This material will typically arrive dry in rail car quantities and is fed to the fuel using front end loaders to the fuel hopper. Large quantities of the iron oxide will be mixed the PRB coal. This method seems to provide poor mixing, uses excessive quantities of material and is very imprecise. Furthermore, too much material use also allows the fluxing agent to escape the cyclone barrels into the greater furnace, causing unwanted and undesired slagging of heat exchangers. 
         [0010]    As exemplary of iron oxide treatment, Johnson in U.S. Pat. Nos. 6,729,248, 6,773,471 and 7,332,002 describes introduction of iron containing compounds to act as fluxing agents. The disclosures are directed to additives for coal-fired furnaces, particularly furnaces using a layer of slag to capture coal particles for combustion. The additives include iron, mineralizers, handling aids, flow aids, and/or abrasive materials. The iron and mineralizers are said to lower the melting temperature of ash in low-iron, high-alkali coals, leading to improved furnace performance; but control is difficult. We have assessed the problems and believe they are caused adding the treatment chemical to the furnace as a whole, either as part of the fuel or with the combustion air. 
         [0011]    A different example of using iron agents is found in U.S. Pat. No. 6,613,110, wherein Sanyal employs them to improve heat transfer on the water-walls of highly-reflective ash-containing boiler furnaces, and does not mention cyclone furnaces. The disclosed method is said to inhibit accumulation of light-colored ash on the walls of a furnace in which coal containing high levels of (coal-bound) calcium is burned. The light color on the ash surface reflects heat that is then not efficiently utilized and exits the boiler stack. To correct this, an iron compound is added to the coal prior to burning the coal, which when burned produces a dark calcium ferrite that darkens the ash. Other chemicals besides iron compounds have also been suggested for ash color control in such a context, and Sanyal cites U.S. Pat. No. 5,819,672 to Radway, which asserts that boron and metal oxides can act as darkening agents on furnace water-walls. The disclosed method involves exposing the walls to a darkening agent, or a combination of a darkening agent and a fluxing agent. A preferred embodiment involves direct application of the darkening agent to the water wall. Again, cyclone boilers are not described, and slag flow from them is not addressed. 
         [0012]    Representative of early efforts for controlling slag in slag tap furnaces burning higher grade coals, is U.S. Pat. No. 4,057,398 to Bennett. The patent asserts that boron additives can be introduced into the furnace box of the boiler as an intimate mixture of pulverized or crushed coal. Also, U.S. Pat. No. 4,377,118 to Sadowski and U.S. Pat. No. 5,207,164 to Breen suggest the addition of any of a number of fluxing agents for slag benefit. Sadowski is concerned with decreasing slag viscosity at the walls of a furnace and employs various slag viscosity adjuvants formed as particles of significant size and density, noting that pellets would be sufficiently large whereas a dust would not be. Bennett is concerned with decreasing the fusion point of coal ash. Breen utilizes iron, rust or slag for high calcium ash, which is recycled to the furnace to soften it so that it collects via gravity in a bottom ash pit. None of these enable increasing operating flexibility and efficiency of a cyclone furnace while burning Powder River Basin or similar coal by using a specifically effective fluxing compound in an efficient and effective manner to increase the flow temperature of the slag with a minimal use of additive. 
         [0013]    The problem of slag control in cyclone furnaces remains serious but has not been effectively resolved by the prior art despite years of effort directed at the problem even with a good understanding of slag properties, such as might be seen from the text “Influence of Coal Quality and Boiler Operating Conditions on Slagging of Utility Boilers”, Rod Hatt, Coal Combustion, Inc., Versailles, Ky. This work contains a wealth of reference material and a discussion on the types of slags produced by various coals, causes of deposits and procedures for reducing and removing deposits caused by coal ash. There is, however, no clear direction on chemical addition control for cyclone furnaces burning PRB coal that would be absolutely essential for economic and furnace maintenance reasons. 
         [0014]    There is a present need for a system, apparatus and method for improving the operation of cyclone boilers by increasing operating flexibility and efficiency of a cyclone furnace while burning Powder River Basin or similar coal by using a specifically effective fluxing compound in an efficient and effective manner. 
       SUMMARY OF THE INVENTION 
       [0015]    It is an object of the present invention to provide a system, apparatus and method for improving the operation of cyclone boilers by increasing operating flexibility and efficiency of a cyclone furnace while burning Powder River Basin or similar coal by using a specifically effective fluxing compound in an efficient and effective manner. 
         [0016]    In one aspect, the invention achieves uniform contact of the burning coal with a precise amount of a boron composition fluxing agent to improve the flow properties of the slag to assure proper cyclone furnace operation with coals having low iron and high calcium contents. 
         [0017]    In one aspect, the invention allows dosing of the slag layer formed on cyclone barrel walls with the precise amount of a boron composition fluxing agent required to achieve the goal, complete coverage of trouble spots and no more. The dosing will be guided by problems as observed and/or calculated and can be prophylactic or remedial. The net effect is that furnace downtime due to slagging problems will be held to a minimum while chemical usage will also be greatly reduced from conventional applications. 
         [0018]    In another aspect, the present invention provides precise dosing as to location and amount of a boron composition in a suitable vehicle, e.g., slurry, particulate solid or solution form, by controlled feeding through injection ports on each cyclone barrel such that the boron composition, e.g., comprising borate, borax, boric acid or a blend of two or more of these, lowers the melt point of the slag while making slag thicker (more plastic), causing a protective layer of slag to form on the cyclone barrel inside wall, but still able to flow to drains. 
         [0019]    In addition to treating the slag in the cyclone barrel at the cyclone barrel walls, the boron composition material can be advantageously applied in a targeted fashion to the water-walls of the boiler furnace to react with slag thereon to either insulate heat transfer and allow steam temperature to be maintained in the superheaters of boilers where superheat temperature is too low due to high furnace water-wall area, or in a blend with other metal oxides, to improve heat transfer on the water-walls by decreasing reflectivity of high alkali earth oxide containing boiler ash. 
     
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         [0020]    The invention will be better understood and its advantages will become more apparent from the following detailed description, especially when taken with the accompanying drawings, wherein 
           [0021]      FIG. 1  is a schematic view of a cyclone furnace combustor of the prior art, showing air and slag flow to help explain material movements in a burner of this type; 
           [0022]      FIG. 2  is a schematic view of a cyclone furnace combustor, as viewed from the portion that would extend into the furnace, and showing one embodiment of flux addition according to the invention; 
           [0023]      FIG. 3  is a schematic perspective view of an exemplary equipment layout for cyclone burner equipped furnace according to the invention; 
           [0024]      FIG. 4  is a schematic perspective view showing some of the detail of ductwork for the embodiment shown in  FIG. 3 ; and 
           [0025]      FIG. 5  is a schematic view of an embodiment of the invention with representative control and material feed arrangements. 
       
    
    
     DETAILED DESCRIPTION 
       [0026]    Since the invention provides strong advantages in the context of cyclone furnaces, the following description will refer to such for clarity and consistency. It will be understood by those skilled in the art, however, that the principals that make the invention so effective in that setting will also make it effective in others.  FIG. 1 , is a schematic view of a prior art cyclone burner  10 , showing air and slag flow to help explain material movements in a burner of this type.  FIG. 2  shows one embodiment of the invention wherein a boron composition is added directly to the cyclone burner  10  separate from the coal feed. Reference to  FIG. 3  will help understand the arrangement of the of individual cyclone furnace burners as part of the larger combustor or boiler, and  FIG. 4  will help to better understand the role and importance of computational fluid dynamics to assure efficient distribution of boron composition into the cyclone burner. 
         [0027]    The invention will also be described with specific reference to certain subbituminous coals, like Powder River Basin (PRB) coals, which tend to produce slags that have a short transition in viscosity as the temperature varies and otherwise suffer from inconsistent properties. The burning of these coals in a furnace requiring slag flow, might result in the slag freezing and causing shut down of the furnace if the operator wants to operate at less than full load. In other cases, the slag might run too freely and not provide the optimum temperature differential at the surface of the water cooled-cyclone barrel. The PRB coals can produce slags that have a surprisingly sharp drop in viscosity over short temperature spans. Drops of over 10,000 centipoises can occur in the temperature range of from 2250° to 2350° F., to a value below the normal operating temperature of the cyclone boiler. 
         [0028]    It is generally agreed that stable operation of a slagging cyclone combustor requires the ash layer to be molten, but not too low in viscosity and not too high. It needs to have a viscosity low enough to permit continuous drainage as is illustrated in  FIG. 1 , but not so low that it runs out of the cyclone burner without retaining the necessary protective layer of slag. PRB coals often tend to run too quickly at desirable operating conditions. A critical viscosity for steady drainage is has been shown to be about 250 centipoises. The temperature corresponding to this viscosity level is referred to in the art as T250, and stable operation mandates a slag temperature of greater than or equal to T250. The invention enables achieving the correct viscosity-temperature relationship with very low additive levels by appreciation of the unique operating aspects of cyclone burners and tailoring a treatment regimen to them, preferably through the use of computational fluid dynamic modeling. 
         [0029]    While not limited to PRB coals, and generally useful for all operations with coal-fired cyclone burners, the following provides an idea of approximate values (dry, weight basis) for coal compositions that can be successfully burned in a cyclone burner utilizing the present invention. The coal is preferably fed, crushed as particulates wherein about 95% passes through a 4 mesh screen. Using crushed coal as opposed to coal pulverized to a greater degree, mitigates the escape of fines from the barrel. Other high-calcium and/or low iron fuels can also be effectively treated according to the invention. 
         [0000]    
       
         
               
               
               
             
           
               
                   
                   
               
             
             
               
                   
                 Total Ash 
                  2-15% of the coal 
               
               
                   
                 Si02 
                 20-35% of the ash 
               
               
                   
                 Al203 
                 13-20% of the ash 
               
               
                   
                 Fe203 
                  3-10% of the ash 
               
               
                   
                 CaO 
                 18-35% of the ash 
               
               
                   
                 MgO 
                  3-10% of the ash 
               
               
                   
                 Na20 
                  0-3% of the ash 
               
               
                   
                 K20 
                  0-1% of the ash 
               
               
                   
                 S03/other 
                  6-20% of the ash 
               
               
                   
                   
               
             
          
         
       
     
         [0030]    The invention provides a method for controlling slag properties in a cyclone combustor, which comprises: determining the need, location, dosage amount and targeting information of a boron composition necessary for slag modification for proper viscosity; and providing precise dosing as to location and amount of a boron composition in a suitable vehicle, e.g., slurry, particulate solid or solution form, by controlled feeding through injection ports on each cyclone barrel such that the boron composition, e.g., borate, borax or blend, lowers the melt point of the slag while making slag thicker (more plastic), causing a protective layer of slag to form on the cyclone barrel inside wall, but still able to flow to drains. 
         [0031]    In one aspect, the invention achieves uniform contact of the burning coal with a precise amount of a boron composition fluxing agent to improve the flow properties of the slag to assure proper cyclone furnace operation with coals having low iron and high calcium contents. 
         [0032]    Preferably, as will be explained in greater detail below with specific regard to  FIGS. 3 to 5 , direct observation or computational fluid dynamics (CFD) or other computer or cold flow modeling will be employed to determine the location of injection ports on each cyclone barrel such that the boron composition modifies the melt point of the slag while making slag suitably viscous (e.g., plastic), causing a protective layer of slag to form on the cyclone barrel inside wall, but still able to flow to drains. By virtue of the correct calculation and the correct selection of boron compositions, the present invention can provide precise dosing as to location and amount of a boron composition. The disclosures of U.S. Pat. No. 5,740,745, U.S. Pat. No. 5,894,806 and U.S. Pat. No. 7,162,960, all to the inventor herein with others, are incorporated by reference herein for their descriptions of suitable computational fluid dynamics and other modeling techniques. 
         [0033]    The boron composition used according to the invention can be a member selected from the group consisting of borax, borates, boric and blends of two or more of these. In particular, borax or boric acid, and sodium borate can be employed. They can be effective alone or with a carbonate or sulfate boron salt, or the like, e.g., as a stabilized boric acid blend, and will be employed in a suitable physical form, e.g., particulate solid or solution, in a suitable, preferably liquid, vehicle such as water as a slurry, dispersed solid or solution, or in air, controlled feeding through injection ports on each cyclone barrel such that the boron composition, e.g., borate, borax or blend, lowers the melt point of the slag while making slag thicker (more plastic), causing a protective layer of slag to form on the cyclone barrel inside wall, but still able to flow to drains. The composition can be a boron composition and may also include alkali hydrates. In some cases, the boron composition can be stopped and the alkali hydrates can be started or continued. Exemplary of the alkali hydrates are soda ash, coal ash, sodium salts with alkalinity, phosphorous compounds, and the like, which like the boron composition will be employed in a suitable physical form. The boron composition mixes with the swirling gas in the cyclone burner. The swirling air flow in the burner  10  can be best seen from the flow lines in  FIG. 1 . The boron composition is exposed to sodium in the flux and is believed to convert to sodium borate that does the fluxing in the cyclone barrel. 
         [0034]    The technology of the invention allows precise targeting of the cyclone barrel walls with the precise amount of boron composition required to achieve the goal, 100% coverage and no more. While mixing at the slag surface will be problematical when a fluxing agent is simply added with the fuel or air fed to a combustor, the ability of the invention to provide precise targeting enhances the mixing. An advantage of this approach is that the invention is highly effective as a remedial measure when slagging anomalies are identified. Doses may be increased for a time period as necessary to achieve mixing and slag modification. 
         [0035]    It will be seen that the doses of the boron compositions according to the present invention can be reduced from what might otherwise be necessary without precise dosing. Typically, the boron composition will be introduced in amounts as low as about 0.1 pounds per ton of PRB or like coal. Preferred dosings in many cases will be less than 1.0 pounds per ton of PRB coal, e.g., from 0.2 to about 0.5 pounds per ton of PRB coal. 
         [0036]    In addition to treating the slag in the cyclone barrel at the cyclone barrel walls, the boron composition material can be advantageously applied in a targeted fashion to the water-walls of the boiler furnace to react with slag thereon to either insulate heat transfer and allow steam temperature to be maintained in the superheaters of boilers where superheat temperature is too low due to high furnace water-wall area, or in a blend with other metal oxides, to improve heat transfer on the water-walls by decreasing reflectivity of high alkaline earth oxide containing boiler ash. 
         [0037]    To best understand the invention, we first refer to  FIGS. 1 and 2 , which are schematic representations of a cyclone furnace combustor  10 . The first,  FIG. 1  shows the prior art with material flows of air, coal and slag, while  FIG. 2  shows one embodiment of the invention wherein the boron composition is added to the cyclone burner through separate injectors  20 , and  FIG. 3  shows the introduction of the boron composition with secondary air  15 . This type of introduction is greatly benefited by the use of computational fluid dynamics that will enable complete coverage of exposed slag surfaces in the cyclone, as will be explained in greater detail below. 
         [0038]    The combustor includes a barrel  12 , a re-entrant throat  14 , secondary air inlet  15 , and slag tap opening  16  through which slag  17  flows out. In operation of the apparatus as shown, crushed coal is fed, preferably with the primary air, through feed opening  18 . Coal is desirably fed in particulate form and particles are thrown outward as the flow spins through the barrel as shown by the arrows (the flame  13 , generally shown in  FIG. 3 , will swirl like the arrows). This flow of air and fuel is caused by the tangential flow imparted by the manner of introducing the air and coal. This flow creates a region of high heat release adjacent the refractory lining of the barrel wall. The high temperature in this region causes the ash contained within the coal to melt. The molten slag  17  acts as a trap for the carbon-rich coal particles, retaining the particles for a period of time enabling a high degree of carbon burnout. The molten slag  17  eventually migrates forward along the wall of the barrel, exits at the slag spout opening  16 , and continuously drains through a slag tap opening  16  located below the re-entrant throat  14 . Tertiary air is shown to be fed to the burner at the tertiary air inlet  19 , and secondary air (the main combustion air) enters the cyclone combustor at the secondary air inlet  15 . Reference to  FIGS. 1 and 3  shows the slag emptying from the furnace  30  via a slag tap  32 . 
         [0039]    The flow of slag  17  from the cyclone burner at the proper rate with PRB coal is assured by the invention, which introduces the boron composition in a manner that it treats the upper surface of the flow of slag  17 . The boron composition is provided as a fine powder, preferably from drying a solution or suspension by hot air in an air duct such as  52  in  FIGS. 3 and 4 . While not wishing to be bound to any particular theory of operation, the treatment at the surface of the slag with the finely-divided boron composition as opposed to the whole mass of it helps explain how the invention can operate effectively with very low consumption of born composition. In the arrangement shown in  FIG. 2 , a borate or other boron composition is introduced via feed  20 . In preferred embodiments, such as illustrated in  FIGS. 3 to 5 , the borate or other boron composition will be fed as part of the secondary air  15 . 
         [0040]    Reference to  FIG. 3  will show the general orientation of the combustor  10  in the furnace  30 , which is partially cut away at the bottom to show flame  13 . In actual practice, the barrel  12  will be on the outside of the furnace  30  and the reentrant throat  14  and the slag tap opening  16  will be on the inside. 
         [0041]    The control system illustrated in  FIG. 5  is representative of those that can be employed and preferably includes sensors indicated in the drawings by a symbol which comprises the letter “X” in a box (very small), and electrical connectors shown as dotted lines. The connectors can be hard-wired or wireless. The control system includes a controller  40  as shown with a monitor or other reporting device, which will receive signals from the various sensors, calculate the appropriate control response by feed forward and feedback logic and send control signals to the various pumps shown in the drawings as a triangle within a circle. The controller  40  will control both the coal feed  18  and a borate or other boron composition feed  21  as necessary to provide precise targeting of the borate compound onto the surface of the slag within the barrel  12  in a manner that enhances the contact of the boron composition with the slag layer  17 . It is an advantage of the invention that the dosing can also be highly effective as a remedial measure when slagging anomalies are identified. As noted, doses may be increased for a time period as necessary to achieve mixing and slag modification. 
         [0042]    The boron composition will be fed from injectors  20  in  FIG. 2  or  54  in  FIG. 4 , in a suitable vehicle, e.g., slurry, particulate solid or solution form, by controlled feeding through injection ports on each cyclone barrel  12  such that the boron composition, e.g., borate, borax or blend, lowers the melt point of the slag while making slag thicker (more plastic), causing a protective layer of slag to form on the cyclone barrel  12  inside wall, but still able to flow to drains  16 . The boron composition is provided as a fine powder, preferably from drying a solution or suspension by hot air in an air duct such as  52  in  FIGS. 3 and 4 . The gas flow makes a swirling pattern as it moves from the entrance end of the burner  10  and the coal source  18  upstream within an annular region, exiting from the barrel through the reentrant throat  14  into the furnace  30 . 
         [0043]    Preferably, the boron composition is introduced as determined by computational fluid dynamics (CFD), which can be used to determine the location of injection ports within ducts  52  as shown in  FIGS. 3 and 4 . To get the best distribution, each cyclone barrel is individually modeled to help determine the concentration of the boron composition solution or suspension, the size of droplets sprayed from nozzles  54 , the direction and velocity of the spray, for given gas flow and temperature measurements within duct  52 . Nozzles  54  will be capable of forming fine sprays, and their final selection will depend on the results of the CFD modeling. The particles of the boron composition after spray and drying will be very fine, on the order of 0.1μ on a weight average basis. In preferred embodiments the boron compositions will be sprayed as soluble compositions to form dry salts in finely divided form. 
         [0044]    The use of modeling can assure that the boron composition is properly administered in accord with the disclosures of U.S. Pat. No. 5,740,745, U.S. Pat. No. 5,894,806 and U.S. Pat. No. 7,162,960, which are incorporated by reference herein for their descriptions of suitable computational fluid dynamic and other modeling techniques. Once a model for a given combustor is made, further similar units can take advantage of that as following that iteration of the inventive process.  FIG. 4  illustrates a single secondary air feed duct  52  having a transition  53  to a secondary air duct  15 , which is oriented to direct the air tangentially into cyclone burner  10 . The secondary air feed duct  52  contains within its interior a nozzle  54  for spraying a solution or suspension of boron composition. The hot, preheated air from preheater  34  in  FIG. 3  moves rapidly through the duct as the spray pattern  56  is seen to enlarge radially without contacting the interior surfaces of the duct  52  while it is wet. If contact were to occur, deposits of boron composition would form and ultimately cause problems. 
         [0045]    Process operating variations and physical combustor designs will cause the temperature of the hot air in duct  52  to vary. However, it is desired to use a temperature of above about 300° F., and preferably within the range of from 400° to 700° F. If needed, supplemental heaters can be employed. It is attempted in the drawing by means of shading to show that at a point approximately at  58 , the spray will be dry and covering about 80 to 99%, e.g., 90%, of the area of the duct  52 . The modeling should determine that first contact of the injected materials with the wall should occur no sooner than where drying finally occurs and the boron composition is in a fine powder form, the wall have not been significantly wetted with the solution or suspension. The modeling preferably takes into account the whole length of duct  52  from the point of introduction to at least the transition  53 , and preferably into secondary air duct  15  and most preferably to final introduction into cyclone burner  10 . 
         [0046]    As described in patents cited just above, a suitable computational fluid dynamics (CFD) modeling technique can establish a three-dimensional temperature profile. For applications involving future construction or where direct measurements are impractical, CFD modeling alone can sufficiently predict furnace conditions. 
         [0047]    A computational fluid dynamics software package called “PHOENICS” (Cham. LTD.), has been found effective. This program and others can solve a set of conservation equations in order to predict fluid flow patterns, temperature distributions, and chemical concentrations within cells representing the geometry of the physical unit. It has been found helpful to also run, in addition to the standard program features, a set of subroutines to describe flue gas properties and injector characteristics which for utilization in the solution of the equations. 
         [0048]    Typical sprays produce droplets with a range of sizes traveling at different velocities and directions. These drops interact with the flue gas and evaporate at a rate dependent on their size and trajectory and the temperatures along the trajectory. Improper spray patterns and improper location are typical of prior art slag reducing procedures and result in less than adequate chemical distributions and lessen the opportunity for effective treatment. 
         [0049]    A frequently used spray model is the PSI-Cell model for droplet evaporation and motion, which is convenient for iterative CFD solutions of steady state processes. The PSI-Cell method uses the gas properties from the fluid dynamics calculations to predict droplet trajectories and evaporation rates from mass, momentum, and energy balances. The momentum, heat, and mass changes of the droplets are then included as source terms for the next iteration of the fluid dynamics calculations, hence after enough iterations both the fluid properties and the droplet trajectories converge to a steady solution. Sprays are treated as a series of individual droplets having different initial velocities and droplet sizes emanating from a central point. Correlations between droplet trajectory angle and the size or mass flow distribution are included, and the droplet frequency is determined from the droplet size and mass flow rate at each angle. 
         [0050]    The correlations for droplet size, spray angle, mass flow droplet size distributions, and droplet velocities are found from laboratory measurements using laser light scattering and the Doppler techniques. Characteristics for many types of nozzles under various operating conditions have been determined and are used to prescribe parameters for the CFD model calculations. 
         [0051]    The above description is for the purpose of teaching the person of ordinary skill in the art how to practice the invention. It is not intended to detail all of those obvious modifications and variations, which will become apparent to the skilled worker upon reading the description. It is intended, however, that all such obvious modifications and variations be included within the scope of the invention which is defined by the following claims. The claims are meant to cover the claimed components and steps in any sequence which is effective to meet the objectives there intended, unless the context specifically indicates the contrary.