Abstract:
A method of forming one or more protrusions on an outer surface of a polished face of a solid state material, said method including the step of applying focused inert gas ion beam local irradiation towards an outer surface of a polished facet of a solid state material in a way of protruding top surface material; wherein irradiated focused inert gas ions from said focused inert gas ion bean penetrate the outer surface of said polished facet of said solid state material; and wherein irradiated focused inert gas ions cause expansive strain within the solid state crystal lattice of the solid state material below said outer surface at a pressure so as to induce expansion of solid state crystal lattice, and form a protrusion on the outer surface of the polished face of said solid state material.

Description:
FIELD OF THE INVENTION 
       [0001]    The present invention relates to a method of providing a marking on a solid state material. In particular, the present invention relates to providing a marking on a surface of a solid state material such as a gemstone or the like, whereby the marking is not optically viewable. 
       BACKGROUND OF THE INVENTION 
       [0002]    Marking of solid materials, in particular precious gemstones or the like, may be required for example in identification or quality markings. For the marking of gemstones, it is desirable that marking be performed in a manner such that the gemstone is not damaged or any damage is minimised, the integrity of the gemstone is preserved, no significant loss in mass occurs, no chemical residue remains, and the marking does not detract from the clarity or colour of the gemstone. 
         [0003]    For ornamental gemstones, the marking technique should not be visible to the naked eye so as not to detract from the quality of the stone from an aesthetic standpoint, whereby visible identification of marking may detract from the visual result in devaluation of a gemstone. 
         [0004]    The techniques of etching, engraving and micro-milling processes exist in the prior art, which may impact on the integrity and quality of a gemstone, and may be viewed unfavourably. Furthermore, such processes result in some amount of loss of material, again which may be viewed unfavourably. 
         [0005]    Other marking techniques exist within the prior art including those such as disclosed in U.S. Pat. No. 6,391,215B1, whereby an information mark is applied to a polished facet of a diamond or silicon carbide gemstone whereby the gemstone is coated with an electrically conductive layer. The electrically conductive layer prevents the gemstone from becoming charged and the mark is formed by a focused ion beam whereby a portion of the surface is ablated to a requisite depth, and whereby the surface to which the mark is applied is subsequently cleaned utilising a powerful oxidizing agent. 
       OBJECT OF THE INVENTION 
       [0006]    Accordingly, it is an object of the present invention to provide a method of providing a marking on a solid state material and a solid state material having said marking thereon, which overcomes or at least partly ameliorates at least some of the deficiencies as associated with the prior art. 
       SUMMARY OF THE INVENTION 
       [0007]    In a first aspect, the present invention provides a method of forming one or more protrusions on an outer surface of a polished facet of a solid state material, said method including the step of: 
         [0008]    (i) applying focused inert gas ion beam local irradiation towards an outer surface of a polished facet of a solid state material in a way of protruding top surface material; 
         [0009]    wherein irradiated focused inert gas ions from said focused inert gas ion beam penetrate the outer surface of said polished facet of said solid state material; and 
         [0010]    wherein irradiated focused inert gas ions cause expansive strain within the solid state crystal lattice of the solid state material below said outer surface at a pressure so as to induce expansion of solid state crystal lattice, and form a protrusion on the outer surface of the polished facet of said solid state material. 
         [0011]    Preferably, the focused inert gas ion beam has a beam energy in the range of from 5 keV to 50 keV and probe current in the range of 1 fA to 200 pA. 
         [0012]    The solid state crystal lattice may be in the form of a single crystalline, poly-crystalline, or amorphous form, and the solid state material is a material in solid state form under ambient temperature and under a pressure from atmospheric to high vacuum. 
         [0013]    Preferably the solid state material is a precious stone. More preferably, the solid state material is a material selected from the group including Diamond, Ruby, Sapphire, Emerald, Pearl, Jade or the like. 
         [0014]    The focused inert gas ion beam is an ion source which may be selected from any inert gas in Group VIII of the periodic table. 
         [0015]    Preferably, the polished facet of the solid state material has an average surface roughness of less than 50 nm. 
         [0016]    Preferably, the protrusion has an average width in the nanometer or micrometer order of magnitude, and an average height in the nanometer or micrometer order of magnitude. 
         [0017]    The distance from the outer surface of said solid state material to the region of irradiated inert gas accumulation below the outer surface is preferably in the range of from 1 nm to 100 μm. 
         [0018]    The protrusion may be provided so as to form an identifiable mark or pattern, and the identifiable mark is in the form of a single or array of dot, pillar, dome, hemisphere, line, irregular shape, symmetric or asymmetric shape, or the like. 
         [0019]    The identifiable mark may be provided as a periodic line array, hole/dot array, circular array, spiral array, fractal array or multiple periods array, or the like. 
         [0020]    Alternatively, the identifiable mark may be provided as a continuous protruded shape to form arbitrary patterns. 
         [0021]    A plurality of protrusions may be formed that are nanometer sized so as to provide an information mark invisible to the naked eye due to Rayleigh Criterion in optical limit. The protrusions may be arranged in a periodic array viewable by specified lighting conditions and by a camera equipped microscope in the visible and invisible light range. The one or more protrusions forms an identifiable security mark. 
         [0022]    The method preferably maintains integrity of said solid state material such that there exists substantially no loss in mass. 
         [0023]    In a second aspect, the present invention provides a solid state material having one or more protrusions formed on an outer surface of a polished facet of the solid state material, wherein said one or more protrusions are formed from a method including the step of: 
         [0024]    (i) applying focused inert gas ion beam local irradiation towards an outer surface of a polished facet of a solid state material in a way of protruding top surface material; 
         [0025]    wherein irradiated focused inert gas ions from said focused inert gas ion beam penetrate the outer surface of said polished facet of said solid state material; and 
         [0026]    wherein irradiated focused inert gas ions cause expansive strain within the solid state crystal lattice of the solid state material below said outer surface at a pressure so as to induce expansion of solid state crystal lattice, and form a protrusion on the outer surface of the polished facet of said solid state material. 
         [0027]    Preferably, the focused inert gas ion beam has a beam energy in the range of from 5 keV to 50 keV and probe current in the range of 1 fA to 200 pA. 
         [0028]    The solid state crystal lattice may be in a form of single crystalline, poly-crystalline, or amorphous form. The solid state material is a material in solid state form under ambient temperature and under a pressure from atmospheric to high vacuum. 
         [0029]    The solid state material is preferably a precious stone, and more preferably selected from the group including Diamond, Ruby, Sapphire, Emerald, Pearl, Jade or the like. 
         [0030]    The focused inert gas ion beam utilised to form said one or more protrusions is an ion source which may be selected from any inert gas in Group VIII of the periodic table. 
         [0031]    Preferably, the polished facet of the solid state material has an average surface roughness of less than 50 nm. 
         [0032]    The protrusion preferably has an average width in the nanometer or micrometer order of magnitude, and an average height in the nanometer or micrometer order of magnitude. 
         [0033]    Preferably, the distance from the outer surface of said solid state material to the region of irradiated inert gas accumulation below the outer surface is in the range of from 1 nm to 100 μm. 
         [0034]    The one or more protrusions are preferably provided so as to form an identifiable mark or pattern. The identifiable mark may be in a form of single or array of dot, pillar, dome, hemisphere, line, irregular shape, symmetric or asymmetric shape, or the like. 
         [0035]    Alternatively, the identifiable mark may be provided as a periodic line array, hole/dot array, circular array, spiral array, fractal array or multiple periods array, or the like, or the identifiable mark may be provided as a continuous protruded shape to form arbitrary patterns. 
         [0036]    The solid state material may have a plurality of protrusions formed which are nanometer sized so as to provide an information mark invisible to the naked eye due to Rayleigh Criterion in optical limit. The protrusions may be arranged in a periodic array viewable by specified lighting conditions and by a camera equipped microscope in the visible and invisible light range. 
         [0037]    The one or more protrusions may form an identifiable security mark. 
         [0038]    The integrity of solid state material is preserved such that during formation of the one or more protrusions, there exists substantially no loss in mass of the solid state material. 
         [0039]    In a third aspect, the present invention provides a system for forming one or more protrusions on an outer surface of a polished facet of a solid state material, said system including: 
         [0040]    a focused inert gas ion beam device for applying focused inert gas ion beam local irradiation towards an outer surface of a polished facet of a solid state material 
         [0041]    a computer control device for controlling discharge of a focused inert gas ion beam local irradiation towards an outer surface of a polished facet of a solid state material, 
         [0042]    wherein the computer control device controls irradiated focused inert gas ions from said focused inert gas ion beam so as to penetrate the outer surface of said polished facet of said solid state material; and irradiated focused inert gas ions cause expansive strain within the solid state crystal lattice of the solid state material below said outer surface at a pressure so as to induce expansion of solid state crystal lattice, and so as to form a protrusion on the outer surface of the polished facet of said solid state material. 
         [0043]    Preferably, the focused inert gas ion beam device has a beam energy in the range of from 5 keV to 50 keV and probe current in the range of 1 fA to 200 pA. 
         [0044]    The focused inert gas ion beam utilised to form said one or more protrusions is an ion source which may be selected from any inert gas in Group VIII of the periodic table. 
         [0045]    The system provides a protrusion having an average width in the nanometer or micrometer order of magnitude, and an average height in the nanometer or micrometer order of magnitude. 
         [0046]    Preferably, the system is adapted to provide a protrusion whereby the distance from the outer surface of said solid state material to the region of irradiated inert gas accumulation below the outer surface is in the range of from 1 nm to 100 μm. 
         [0047]    The system is adapted so as to provide an identifiable mark or pattern on an outer surface of a polished facet of a solid state material. The identifiable mark provided by the system may be in a form of a single or array of dot, pillar, dome, hemisphere, line, irregular shape, symmetric or asymmetric shape, or the like. 
         [0048]    Alternatively, the identifiable mark may be provided as a periodic line array, hole/dot array, circular array, spiral array, fractal array or multiple periods array, or the like. The identifiable mark may be provided as a continuous protruded shape to form arbitrary patterns. 
         [0049]    Preferably, the system is adapted to provide a plurality of protrusions which are nanometer sized so as to provide an information mark invisible to the naked eye due to Rayleigh Criterion in optical limit. 
         [0050]    The system is preferably adapted so as to provide a plurality of protrusions which are arranged in a periodic array viewable by specified lighting conditions and by a camera equipped microscope in the visible and invisible light range. 
         [0051]    The system may be adapted to provide one or more protrusions so as to form an identifiable security mark. 
         [0052]    The system is adapted so as to maintain the integrity of said solid state material during formation of the one or more protrusions, and such that there exists substantially no loss in mass of the solid state material. 
         [0053]    Preferably, the system is adapted so as to provide one or more protrusions on the outer surface of a precious stone. More preferably, the system is adapted so as to provide one or more protrusions on the outer surface of a Diamond, Ruby, Sapphire, Emerald, Pearl, Jade or the like. 
         [0054]    The system is preferably adapted so as to provide one or more protrusions on a polished facet of the solid state material having an average surface roughness of less than 50 nm. 
         [0055]    The system is preferably adapted so as to provide one or more protrusions on the outer surface of a solid state material, wherein the one or more protrusions has an average width in the nanometer or micrometer order of magnitude, and an average height in the nanometer or micrometer order of magnitude. 
         [0056]    Preferably, the system is adapted so as to provide one or more protrusions on the outer surface of a solid state material such that the region of irradiated inert gas accumulation below the outer surface is in the range of from 1 nm to 100 μm. 
     
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         [0057]    Preferred embodiments of the present invention will be explained in further detail below by way of examples and with reference to the accompanying drawings, in which: 
           [0058]      FIG. 1  shows an exemplary schematic diagram of a configuration of a focused inert gas ion beam system as utilised in embodiments of the present invention; 
           [0059]      FIG. 2  shows an exemplary schematic representation of a computer stimulated interaction volume of incident energetic focused inert gas ions with a solid state material specimen at a top surface region, in accordance with embodiments of the present invention; 
           [0060]      FIG. 3  shows an exemplary schematic representation depicting interaction of primary incident energetic inert gas ion with a solid state specimen, the Figure showing the production of charged particles such as electrons and ions along the displaced path of incident ion, in accordance with embodiments of the present invention; 
           [0061]      FIG. 4  depicts an ion microscope image of an experimentally protruded array of nanometer sized dots, in accordance with embodiments of the present invention; 
           [0062]      FIG. 5  depicts an ion microscope image of a further experimentally protruded array of nanometer sized dots, in accordance with embodiments of the present invention; 
           [0063]      FIG. 6  depicts an ion microscope image of another experimentally protruded array of nanometer sized dots, in accordance with embodiments of the present invention; 
           [0064]      FIG. 7   a  depicts a graph showing a schematic representation of a surface profile of an untreated flat surface; 
           [0065]      FIG. 7   b  depicts a graph of a schematic representation of the profile of protruded surface according to embodiments of the present invention; 
           [0066]      FIG. 8  depicts a schematic three-dimensional contour representation of a protruded surface profile on a flat surface with proportional dimensions in reference to the experimental results as described with reference to  FIGS. 4 ,  5  and  6 ; 
           [0067]      FIG. 9   a  depicts an ion microscope image of an untreated surface on a single crustal diamond facet with a programmed dot array to be incident by focused inert gas ion beam in accordance with embodiments of the present invention; and 
           [0068]      FIG. 9   b  depicts an ion microscope image of the surface of the single crystal diamond facet of  FIG. 9   a , after incident by focused inert bas ion beam at assigned position on the diamond specimen surface, in accordance with embodiments of the present invention. 
       
    
    
     DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS 
       [0069]    Referring to  FIG. 1 , there is shown an exemplary schematic diagram of a configuration of a focused inert gas ion beam system  100  as utilised in accordance with embodiments of the marking method of the present invention. 
         [0070]    In comparison to typical scanning electron microscopy (SEM), the focused inert gas ion beam system  100  has a similar basic configuration, whereby the schematic diagram of  FIG. 1  shows the configuration of a focused inert gas ion beam system  100  for producing and imaging the protruded array of nanometer sized dots in accordance with embodiments of the present invention is shown. 
         [0071]    The gas sources  101  at the top of the electrostatic lens column  102  may be any known inert gases in Group VIII of the periodic table, and the choice of inert gas sources utilised depends on the requisite resulting resolution and fabrication time. Further, an inert gas is preferably utilised in order to minimise any alterations in electrical, optical, or chemical properties of a specimen to be marked. 
         [0072]    For example, for the fabrication of protruded nanometer sized dots is shown and discussed further below in reference to  FIG. 4 ,  FIG. 5  and  FIG. 6 , a low pressure of the inert gas with light atomic mass is preferred, such as Helium or Neon gas for the gas source  101  of the focused inert gas ion beam system  100 . 
         [0073]    Once the inert gas ion is emitted from the gas source  101 , it is accelerated and focused along the top of the electrostatic lens column  102 , and then deflected by scanning deflectors  103  and  104  which are controlled by a computer system, typically a mainframe computer control system or the like, which finally forms a scanning focused inert gas ion beam  105  to incident on surface of a specimen  109 . 
         [0074]    During the scanning or continuous incident of the focused inert gas ion beam  105  to incident on surface of the specimen  109 , a beam  108  of electrons or negative charges emitted from an emission device  106  and  107 , such as electron flood gun or charge compensator, is used to compensate the positively charged up specimen surface  109  due to continuous incident of gas ions on specimen surface  109 . 
         [0075]    As the charged up ions inhibit further incident of focused inert gas ions  105 , this results in image burr or drift in position or shape of a requisite protruded mark. 
         [0076]    During incident of the focused inert gas ion beam  105  on the surface of the specimen  109 , the interaction of incident inert gas ions with the surface of the specimen  109  produces different charged species  110  such as electrons or ions which are detected by an ion or electron detector  111  for imaging, species qualification and quantification. 
         [0077]    Referring to  FIG. 2 , there is shown an exemplary schematic representation of a computer simulated interaction volume of incident energetic focused inert gas ions with a solid state material specimen  203  at a top surface region,  202  in accordance with the present invention, whereby an example of the computer simulated Monte Carlo plot is depicted showing of the trajectory of the incident ions  204  during the interaction of an incident energetic focused inert gas ion beam  201  with a top surface region  202  of a solid state material specimen  203 . 
         [0078]    The Monte Carlo simulation of the interaction is based upon Helium ion as the source of incident energetic focused inert gas ion beam  201  which is accelerated at 30 keV and the solid state material specimen  203  is silicon substrate. 
         [0079]    The cross-section of interaction volume of the solid state material specimen  203  is defined with the penetration depth  205  and dispersed width  206  which is perpendicular to penetration depth  205  of incident ions, and the Monte Carlo simulated numerical results of the penetration depth  205  and dispersed width  206  is about 100 nm. Further, due to a high penetration depth and less lateral straggle of Helium gas ion into the silicon substrate, the size of the focused ion beam spot  207  at the top surface region  202 , in range of 10 nm, is as small as 1 nm or less in order to fulfill the requisite criteria of embodiments of the present invention in creating requisite nanometer sized structures or marks. 
         [0080]    Referring to  FIG. 3 , the detailed interaction of incident energetic inert gas ion  301  with a solid state material  305  as utilised in accordance with embodiments of the present invention is schematically shown. 
         [0081]    For explanatory purposes of embodiments of the present invention, the experimental environment is assumed to be in high vacuum, such as at pressure of 5×10 −6  Torr or lower pressure, and the energetic inert gas ion  301  incident along the path  302  is at an incident angle  303  to the surface or interface  304  between vacuum and the solid state specimen  305 . 
         [0082]    At the instance of energetic inert gas ion  301  incident at the specimen surface or interface  304 , possible energetic species  306  may be generated such as secondary electrons, Auger electrons, X-ray, secondary ions, sputtered particles from the solid state specimen  305 , or even back-scattered energetic inert gas ion  301 . 
         [0083]    The circumstance of said possible energetic species depends on the atomic mass and carried energy of energetic inert gas ion  301 , density and crystallinity of the solid state specimen  305 , chemical bonding between atoms, and the charge state of the specimen surface or interface  304 . 
         [0084]    If the energetic inert gas ion  301  has sufficient energy, then there exists a high probability of entry of said energetic species into the solid state specimen  305  and continued to penetration. 
         [0085]    Along the propagation paths  309  and  312 , the energetic inert gas ion  301  may possibly undergo inelastic collision with adjacent atoms inside the solid state specimen  305 , and one possibility is the generation of energetic species  311  such as secondary ion or secondary electron and possibly coming along the path  310  out from the specimen surface or interface  304 . 
         [0086]    Another possibility is for said possible energetic species to stop at certain local regions for example  308  and  313  as depicted inside the solid state specimen  305  due to energy loss as resulting in accumulation of inert gas ion or amorphisation of crystalline at local regions  308  and  313 . 
         [0087]    By appropriate control of the condition of the incident angle  303  of the energetic inert gas ion  301 , accelerating voltage, and species selection of energetic inert gas ion  301 , the incident energetic inert gas ion  301  has high probability to stop at region  308  and result in either or both accumulation of inert gas ion or amorphisation of crystalline at local region which has lower density but larger volume than crystalline structure. 
         [0088]    Thus, local internal strain is built up within the solid state specimen  305  slightly below the specimen surface or interface  304  which finally leads to expansion of solid state crystalloid lattice at the specimen surface or interface  304 , hence resulting in the formation of a protruded dot  307  in accordance with embodiments of the present invention. 
         [0089]    Referring to the ion microscope image as depicted in  FIG. 4 , there is shown an experimentally protruded array of nanometer sized dots  401  on single crystal diamond facet  402  by the focused inert gas ion beam system. 
         [0090]    The acceleration voltage of gas ions utilised is about 35 kV, and the beam current utilised is about 0.5 pA with ions dose of about 0.1 nC/μm 2 , and the dwell time is of about 1 us. As will be understood, other applicable acceleration voltages and beam currents may be utilised, whilst falling within the scope of the present invention. For example, a focused inert gas ion beam device utilising focused inert gas ion beam having a beam energy in the range of from 5 keV to 50 keV and probe current in the range of 1 fA to 200 pA, will be understood to be applicable, although utilizing equipment capable of generating parameters outside of 5 keV to 50 keV and probe current in the range of 1 fA to 200 pA, may also be considered by those skilled in the art to be applicable to embodiments of the present invention. 
         [0091]    The incident position of the focused inert gas ion beam is programmed by the computer and then controlled by scanning lens column  103  and  104  as exemplified and described with to  FIG. 1 , and as results as shown in  FIG. 4 , the array of 3×3 protruded nanometer sized dots is formed with each protruded nanometer sized dots  401  having diameter of about 130 nm and the vertical period  403  and horizontal period  405  with reference to the plane of the diamond facet  402 , displacement between centers of adjacent protruded nanometer sized dots  401 , are same of about 200 nm. 
         [0092]    The field of view of whole image in this example as shown in both vertical and horizontal directions is 2.00 μm×2.00 μm under magnification of 57,150×, which in this example is imaged by the same focused inert gas ion beam system after fabrication of protruded nanometer sized dots  401 , and with the same acceleration voltage of gas ions but less beam current than under scanning mode. 
         [0093]    The scale bar  404  is shown for reference to the dimension of the protruded nanometer sized dots  401 . 
         [0094]    Similarly to  FIG. 4 ,  FIG. 5  shows an exemplary embodiment of a protruded array of nanometer sized dots  501  fabricated by the focused inert gas ion beam system on single crystal diamond facet  502 , however the diameter of the protruded nanometer sized dots  501  in this example is reduced to 80 nm and both the vertical period  503 , and the horizontal period  505  is increased to 400 nm. 
         [0095]    The reduction of the protruded nanometer sized dots  501  diameter is achieved by reducing the inert gas ions dose to less than 0.05 nC/μm 2  and also reducing the beam current to less than 0.5 pA. 
         [0096]    The imaging conditions of  FIG. 5  are the same as set in  FIG. 4  with the scale bar  505  for reference. 
         [0097]    By way of a further exemplary embodiment, further reducing the inert gas ions dose, for example to 0.03 nC/μm 2  or less, and also further reducing the beam current to 0.4 pA or less, the diameter of the protruded nanometer sized dots  601  is reduced to 50 nm fabricated on single crystal diamond facet  602  as shown in  FIG. 6 . 
         [0098]    The array of protruded nanometer sized dots  601  has both the same vertical period  603  and horizontal period  605  as shown in  FIG. 5  with a similar scale bar  604  for reference and comparative purposes. 
         [0099]    As will be understood and appreciated by those skilled in the art, the exemplary embodiments as described with reference to  FIG. 4 ,  FIG. 5 , and  FIG. 6  show that the diameter of protruded nanometer sized dots can be controlled by appropriately tuning the incident gas ions dose and the probe current, hence the beam size of incident gas ions, from diameter of 200 nm shown in  FIG. 4 , to a significantly lower size down to 50 nm shown in  FIG. 6 . 
         [0100]    Furthermore, the change of the both vertical and horizontal periods in the protruded array of nanometer sized dots from 200 nm as shown in  FIGS. 4  to 400 nm as shown in both  FIG. 5 , and  FIG. 6 , indicate that the focused inert gas ion beam has the ability and efficacy to be utilised to fabricate those protruded nanometer sized dots at arbitrary positions on a specimen surface as a result of a protruded mark in a form of a single or array of dot, pillar, dome, hemisphere, line, irregular shape, symmetric or asymmetric shape, or arbitrary shape which is in periodic line array, hole/dot array, circular array, spiral array, fractal array or multiple periods array, by way of example. 
         [0101]    Reference is made to  FIGS. 7   a  and  7   b , in order to further explain the geometry of the protruded nanometer sized dots, whereby a schematic graph shows the cross-sections between the surface profiles of untreated flat specimen surface  702  and the protruded surface  703  with nanometer sized dots. 
         [0102]    With reference to the Z-direction axis  701 , the untreated flat surface  702  of 
         [0103]      FIG. 7   a  is at the level of Z=0 whilst the protruded surface  703  of  FIG. 7   b  is deformed to the positive sign of Z-direction, thus having a profile higher than the untreated flat surface  702 . 
         [0104]    Further space upper than the untreated flat surface  702  or the protruded surface  703  may be exposed to air/vacuum in the positive sign of Z-direction axis, whilst in the negative side of Z-direction the specimen depth may be finite or semi-infinite. 
         [0105]    The height  705  of the protruded surface  703  is defined as being from the displacement of the protruded surface  703  top from Z=0 while the width or diameter  704  of the protruded surface  703  or dot is defined as the greatest displacement between two lowest points in the surface profile of the protruded surface  703  just above Z=0. 
         [0106]    Referring to  FIG. 8 , there is shown an example of schematic three-dimensional contour diagram of a protruded mark  801  profile so as to provide for enhanced illustration, appreciation and understanding of the shape of the protruded mark  801  fabricated on flat surface  802  by focused inert gas ion beam. 
         [0107]    The height of the protruded mark, has the same definition as  705  explained and discussed in reference to  FIG. 7   b , whereby the protruded mark  801  extends from the flat surface  802  in reference to axis  803 , while the width and depth have the same definition as  704  as explained and described in reference to  FIG. 7   a  and  FIG. 7   b , of the protruded mark  801  are in reference to  804  and  805  respectively. 
         [0108]    In reference to the illustrative example of  FIG. 8  to those protruded nanometer sized dots shown in  FIG. 4 ,  FIG. 5  and  FIG. 6 , the dimension units of all axes  803 ,  804  and  805  are in nanometers. 
         [0109]    Referring to the ion microscope images shown in  FIG. 9   a  and  FIG. 9   b , an exemplary embodiment of the invention is shown whereby the feasibility is demonstrated of fabricating a predetermined and designed nanometer sized continue pattern or mark  905  on single crystal diamond facet  902  and  906  by a programmed array  903 , whereby the energetic inert gas ion incident at which is shown as white dots  901 . The displacement between centers of adjacent white dots  901  is about 120 nm with reference to the scale bar  904 . 
         [0110]    By controlling the dose and beam current of the incident energetic inert gas ions, in order to achieve each protruded nanometer sized dot having a diameter of not less than 120 nm, a continued protruded line  905  and further a two-dimensional protruded pattern or mark  907  on facet  906  with a size of around 800 nm×800 nm, with reference to the scale bar  908 , instead of discrete dots has been formed as shown in  FIG. 9   b.    
         [0111]    Those skilled in the art will appreciate that the present invention allows for the provision of numerous other and alternate embodiments utilising the methodology and process of the present invention, so as to provide marking to a solid state material in a predetermined manner, for a variety of applications depending upon the requirements of such applications. 
         [0112]    The present invention provides a method and system for the application of a marking to a solid state material and a marked solid state material resulting therefrom, preferably a precious stone, which provides marking having the advantages including those of the following:
       (i) marking which is not unsightly and which may not be readily viewed without the knowledge of specific parameters for the viewing and identification of such marking;   (ii) marking, which when applied to precious stones or gemstones, allows for identification for security purposes, as well as tracking and origin purchases, benefits and advantages in the precious stone industry;   (iii) security purposes for marking of solid state materials which may be identified in the event of impropriety, theft or the like;   (iv) marking of a solid state material, without the disadvantages associated with destructive and invasive methods of marking such as etching, ablation, millings, engravings or the like;   (v) a methodology and product thereof which does not result in removal of material or any significant loss in weight or mass of the solid state material to which the marking is to be applied;   (vi) a methodology and product thereof which does not alter the optical properties of a solid state material, and which does not detrimentally affect the clarity or colour of the solid state material;   (vii) a methodology and product thereof which utilises an inert gas, and does not introduce contaminants or impurities to the solid state material;   (viii) a methodology and product thereof which obviates the necessity of post-processing of the solid state material;   (ix) a methodology and product thereof that requires no significant removal of material from the surface of solid state material;   (x) a methodology and product thereof which obviates the necessity of pre-treatment of coating of the solid state material prior to application of marking;   (xi) a methodology and product thereof, having no associated chemical residue;   (xii) a methodology and product thereof which obviates the necessity of post-processing and the utilisation of complex post-processing techniques such as chemical and plasma cleaning and the like.       
 
         [0125]    By providing a method of marking a surface of solid state material by applying focused inert gas ion beam local irradiation in a way of protruding up a top surface of a material to form patterns or marks, due to expansion of solid state crystalloid lattice underneath its top surface by the force of inert gas accumulation or amorphisation of crystalline underneath, instead of etching, engraving, milling or removing top surface material, which are concerned as destructive and invasive and ablative to the solid state material, the present invention provides significant advantages over those of the prior art. 
         [0126]    Those skilled in the art will appreciate the advantages associated with such a marking technique and methodology for solid state material which may be utilised and implemented in other applications in addition to those as described in the exemplary embodiments and examples thereof. 
         [0127]    While the present invention has been explained by reference to the examples or preferred embodiments described above, it will be appreciated that those are examples to assist understanding of the present invention and are not meant to be restrictive. Variations or modifications which are obvious or trivial to persons skilled in the art, as well as improvements made thereon, should be considered as equivalents of this invention.