Abstract:
Reflective luminescent markings on a road or sign surface are formed by applying onto the surface a base material which is liquid in an initial state for application and sets or cures to form a solid layer after application where the base material contains a fine/medium filler material of glass ground from recycled materials in a rotary mill. Coarse material from the grinder is separated out and supplied as a separate material to be applied onto the surface of the layer of base material and fine ground glass. The base material is connected or impregnated with a luminescent material such as photo luminescent 2 4 6 trichlorophenyl in a binder such as polyurea.

Description:
[0001]    This application is a continuation in part of application Ser. No. 14/812,385 filed Jul. 29, 2015. 
         [0002]    This application claims the benefit under 35 USC 119 (e) of Provisional Application 62/030,136 filed Jul. 29, 2014 and of Provisional Application 62/037,884 filed Aug. 15, 2014 the disclosures of which are hereby incorporated by reference. 
         [0003]    This invention relates to a luminescent glass material which can be for example used on roadways or on signs such as road signs or commercial signs. 
     
    
     BACKGROUND OF THE INVENTION 
       [0004]    Road surface markings are used on a road surface in order to convey official information. They can also be applied in other facilities used by vehicles to mark parking spaces or designate areas for other uses. Road surface markings are used on paved roadways to provide guidance and information to drivers and pedestrians. 
         [0005]    Paint can be used, sometimes with additives such as retro-reflective glass beads is generally used to mark travel lanes. It is also used to mark spaces in parking lots or special purpose spaces for disabled parking, loading zones, or time-restricted parking areas. Colors for these applications vary by locality. Paint is a low-cost marking and has been in widespread use since approximately the early 1950s. 
         [0006]    The paint consists of three main components: pigments, resins or binders, and water or solvents. Pigments are finely grounded materials that give out colors or block out the surface beneath it. They may contain other materials such as UV stabilizer, and fillers which bring out the color pigments to the required level. Resins or binders are the glue of the paint to bind pigment and glass beads together to the road surface. The resins for the water based paints are polyvinyl acetate latex, methyl methacrylate or acrylic resin. The resins for solvent based paints are linseed or soya oils, and alkyd resins. The pigments and resins are mixed with water for water based paints and solvents for solvent based paints so that they can be applied onto the road surface. Solvents that are use can be naphtha, toluene, methanol, methylene chloride, and acetone. Due to environmental concerns, some jurisdictions has some restriction on the solvent based paints. 
         [0007]    Epoxy can also be used which contains two parts which are a pigmented resin base and catalyst. The two parts are mixed in a specialized truck for epoxy marking application. The epoxy is then heated prior to spraying onto road surface. Retro-reflective glass beads are applied using a separate bead gun behind the epoxy spray gun. Typically, epoxy markings last about 4 years. Epoxy has been in use since the late 1970s and has gained popularity over the 1990s as the technology has become more affordable and reliable. 
         [0008]    In U.S. Pat. No. 6,045,069 (Steed) issued Apr. 4, 2000 is disclosed a rotary mill for reduction of recycled glass to ground glass particles. The rotary mill comprises a primary reduction chamber, a secondary reduction chamber and an outlet chamber. Glass entering the primary reduction chamber is deflected by an impact rotor, which shatters the material and sends the resulting particles into a plurality of shatter bars. The shatter bars further reduce these particles and deflect them back towards the rotor so that the reduced particles encounter newly shattered material, causing further attrition. In addition, the rotary mill includes an exhaust fan arranged to generate an airflow from the primary reduction chamber, through the secondary reduction chamber and into the outlet chamber. This airflow carries the reduced particles into the secondary reduction chamber wherein the particles are thrown against reduction means. The reduction means are positioned between the secondary reduction chamber and the outlet chamber such that only particles below a certain size enter the outlet chamber. Material of sufficiently reduced size enters the outlet chamber wherein it is separated into fine particles and heavier particles. Specifically, the heavier particles fall out of the airflow and gather at the base of the outlet chamber until a sufficient weight accumulates to open the balance door which expels the heavy material from the rotary mill. 
         [0009]    The particles generated by the above system tend to be much finer than conventional grinding systems so that the reflectivity of the ground material is improved. 
       SUMMARY OF THE INVENTION 
       [0010]    According to the invention there is provided a luminescent material comprising: 
         [0011]    a base material comprising ground glass particles; 
         [0012]    wherein the particles are impregnated or coated with a material comprising a luminescent material and a binder. 
         [0013]    Preferably the luminescent material is photo luminescent 2 4 6 trichlorophenyl although other commercially available materials can be used. 
         [0014]    Preferably the binder is polyurea although other materials can be used such as various setting plastics materials or epoxies. 
         [0015]    Typically the particles are colorless. 
         [0016]    The above material can be used in a method for providing reflective visible markings on a surface comprising: 
         [0017]    applying onto the surface a base material which is liquid in an initial state for application and sets or cures to form a solid layer after application; 
         [0018]    the base material containing a filler material of ground glass. 
         [0019]    Also the ground glass can be impregnated with a colorant. 
         [0020]    Preferably the ground glass is impregnated with the luminescent material in a process subsequent to grinding. 
         [0021]    Preferably the ground glass is impregnated with a luminescent material in a process including heating the glass in ground form. 
         [0022]    The application of heat to a temperature less than a melting point of the glass so as to expand the glass which can cause the binder and the luminescent material to be drawn into the outer surface of the glass particles as the particles cool so that there is a partial impregnation of the material into the outer surface of the glass with some of the material also remaining as a coating on the glass particles. As the glass is ground into individual particles, the coating material is applied over the outer surface of all the particles and thus creates a ground glass product which is luminescent from the luminescent material carried on the outer surface of the particles. 
         [0023]    Preferably the ground glass includes a mixture of particles of different size. 
         [0024]    Preferably the glass is ground from recycled glass material for example from plate glass or vehicle glass, or similar non-colored glass, since neither has color which can interfere with the luminescence of the glass in the present process, although bottles can be used in some cases. 
         [0025]    Preferably the ground glass is mixed through the base material. 
         [0026]    Preferably the ground glass is mixed through the base material so as to increase the hardness of the base material. 
         [0027]    Preferably the ground glass is applied to the road way as a common material simultaneously with the base material. 
         [0028]    Preferably the base material is cured with a catalyst such as epoxy. 
         [0029]    Preferably the ground glass is formed by a grinding process as shown in the above US patent. 
         [0030]    Preferably the markings are applied to a road way on the surface. However, the material can be applied in other locations, such as signs at the road way or other commercial signs. 
         [0031]    When applied over existing markings, the base material and the glass filler both are transparent or colorless to show through an underlying marking over which the material is applied. That is preferably the base material and the filler contain no pigment. 
         [0032]    Preferably the material includes a UN resistant material to prevent fading of an underlying marking over which the material is applied. 
         [0033]    Preferably the base material is a clear paint or varnish. 
         [0034]    The invention also relates to a roadway when coated in markings with a reflective luminescent material as defined above. 
         [0035]    The invention also relates to a method of coating a roadway with a reflective luminescent material comprising applying a material as defined above. 
         [0036]    The invention also relates to a sign with underlying markings when coated with a reflective material as defined above. 
         [0037]    The invention also relates to method of coating a sign with a reflective luminescent material comprising applying a material as defined above. 
         [0038]    Preferably material includes a UN resistant material to prevent fading of an underlying marking over which the material is applied. 
         [0039]    The filler can be ground glass of a very fine characteristic manufactured by the above process or the filler can be bead glass manufactured from recycled material by melting the glass and passing it through a beading process which is well known. 
         [0040]    Preferably the glass is ground to provide finer material and coarser material where the finer material is mixed into the base material and the coarser material is applied at the surface of the base material. It has been found in this regard that the irregular outer surface of the ground particles provide a significantly increased bond to the base material relative to spherical beads, so that the particles remain bound into the base material for a much longer time period. This avoids the situation where the conventional round or spherical beads break away and leave the subsequent holes containing moisture which can make the surface very slippery. Also the rough particles provide an increased traction effect for the exposed surface of the road markings. 
         [0041]    Preferably the coarser material is applied separately onto the surface of the base material. 
         [0042]    Preferably the glass is ground in a rotary mill where the coarser material is collected at a bottom of a discharge chamber and at least some of the finer material is collected in an air stream at a top of the discharge chamber. 
         [0043]    In this arrangement preferably the material collected from the bottom of the discharge material is separated into a medium grind material for mixing with the fine material in the base material, a coarse grind material for application separately onto a surface of the base material and a return material for return to the rotary mill. 
         [0044]    Preferably the base material is a clear paint or varnish. 
         [0045]    Preferably the ground glass includes a mixture of particles of different size. 
         [0046]    Preferably the glass is ground from recycled glass material for example from bottles. 
         [0047]    Preferably the ground glass is mixed through the base material so as to increase the hardness of the base material. 
         [0048]    Preferably the ground glass is applied simultaneously with the base material. 
         [0049]    Preferably the base material is cured. 
         [0050]    Preferably the base material is epoxy but other materials can be used. 
         [0051]    Preferably the ground glass is formed by a grinding process as shown in the above US patent but other processes can be used. 
         [0052]    The invention also provides a sign for providing visible markings including a substrate, a layer of a marking material over the substrate containing visibly distinguishing markings viewable by a person looking at a front face of the substrate and a material as defined above applied over the markings. 
         [0053]    This protects the underlying markings of the sign and also can provide a reflective character to the sign. 
         [0054]    In some cases the underlying markings use a coating such as paint or can be a layer plastics layer such as vinyl cut to form the markings and adhesively attached to the substrate. 
         [0055]    Preferably the sign includes a mast for presenting the substrate to passing viewers. 
         [0056]    Preferably the substrate is aluminum although other base materials such as those typically used for signs can be used. 
         [0057]    The coating of the markings on the sign can be carried out on existing signs while in situ or while temporarily removed or the coating can be applied on new signs during manufacture. The coating will protect the underlying marking material whether that is itself an applied coating or more typically a plastics cut out sheet applied onto the base substrate. In both cases fading or wear can be reduced particularly if the UV protectant is included. The addition of the reflective glass in the coating makes the sign reflective in a manner which cannot be achieved using conventional materials. Bead glass can be used if preferred. Both the base material and the glass filler should be sufficiently transparent to allow the underlying color and/or luminescence to be visible through the coating layer. 
     
    
     
       BRIEF DESCRIPTION OF THE FIGURES 
         [0058]      FIG. 1  is a side view in cross-section of a rotary mill for use in the present invention. 
           [0059]      FIG. 2  is a cross-sectional view on an enlarged scale of the rotary mill of  FIG. 1  showing the relationship between the tips of the rotor and the feed chute. 
           [0060]      FIG. 3  is a schematic illustration of the system of the present invention. 
       
    
    
     DETAILED DESCRIPTION 
       [0061]    Referring to the drawing, a rotary mill  1  comprises a housing  10 , a material delivery system  12  and an exhaust fan  14 . The housing  10  comprises a rotor  16 , a primary reduction chamber  18 , a secondary reduction chamber  20  and an outlet chamber  22 , as shown in  FIG. 1 . 
         [0062]    The primary reduction chamber  18  comprises an inlet opening  24 , an intake guide surface  26  and a plurality of shatter bars  28 . The inlet opening  24  provides access to the interior of the housing  10  for incoming material and for airflow generated by the exhaust fan  14 . In this embodiment, the inlet opening  24  is positioned beneath the material delivery system  12 . The intake guide surface  26  is arranged to direct material from the inlet opening  24  into the swept area of the rotor  16 . The plurality of shatter bars  28  are arranged to further reduce particles deflected by the rotor  16  and direct these particles back toward the rotor  16  as described below. 
         [0063]    The secondary reduction chamber  20  is connected to the primary reduction chamber  18  by a curved portion  30  as described below. The secondary reduction chamber  18  includes reduction elements  32  positioned between the secondary reduction chamber  20  and the outlet chamber  22 , arranged such that particles above a given size are prevented from entering the outlet chamber  22 . The reduction elements  32  may comprise staggered bars, perforated metal plates, wire screens or combinations thereof. 
         [0064]    The outlet chamber  22  comprises an outlet opening  34  in one wall of the chamber  22 , a fan control flap  36  and a lower material outlet  38 . The outlet  34  comprises the exit from the housing  10  for fine particles and for airflow generated by the exhaust fan  14  as described below which generates an airflow through the chambers by injecting air at the inlet  24  as indicated at  14 A. The lower material outlet  38  comprises a balanced door  40  situated at the base of the outlet chamber  22  for removal of heavy particles. Specifically, once a mass of material equal to the balance weight has gathered, the balanced door  40  opens and expels the material from the housing  10 . The fan control flap  36  comprises a movable baffle  42  located within the outlet chamber  22  for controlling airflow through the housing  10  so that the amount and size of particles drawn off at the outlet  34  and the lower material outlet  38  may be varied as described below. 
         [0065]    The rotor  16  is arranged for rotation within the housing  10  and is driven by a motor, the details of which are not shown as these will be obvious to one skilled in the art. The rotor  16  includes peripheral impact hammers  44  and is situated below the intake guide surface  26 . While a rotor that exposes more blades will move more air, durable construction and suitable mass for reducing incoming material conflict with ideal air moving capabilities. However, generation of airflow by the rotor  16  is not an important consideration due to the airflow generated by the exhaust fan  14 . Thus, the rotor  16  is arranged so that the impact hammers  44  have the largest mass possible within the swept area of the rotor  16 . In this embodiment, the rotor  16  includes three impact hammers  44 , although it is of note that the construction of the rotor  16  may vary greatly. 
         [0066]    The exhaust fan  14  is arranged to produce an airflow through the housing. Specifically, the exhaust fan  14  connected to the fan outlet such that the airflow generated by the exhaust fan  14  is drawn into the housing  10  via the inlet opening  24  and is drawn out of the housing  10  via the outlet  34 . The details of the exhaust fan  14  are not shown as these will be obvious to one skilled in the art. 
         [0067]    The material delivery system  12  transports material to the rotary mill  1 . In this embodiment, the material delivery system  12  comprises a conveyor  46 . For reasons that will become apparent, the rotary mill  1  cannot be “choke” loaded. As a result, computerized control of the conveyor  46  may be used to provide a steady input volume regardless of input material size. Specifically, rotor speed and airflow may be monitored to determine loading efficiency and this information may be used to control the power source driving the conveyor  46 . In this manner, the mass of material within the rotary mill  1  may be closely controlled so that attrition of material occurs at a steady rate. 
         [0068]    In operation, the material to be reduced is transported by the conveyor  46  to the inlet opening  24 . The material passes therethrough onto the intake guide surface  26  at a speed at or near free fall. The intake guide surface  26  directs the material into the swept area of the impact hammers  44  of the rotor  16 . Of note is that the intake guide surface  26  is positioned such that a maximum amount of the kinetic energy generated by the rotor  16  is transferred to the material with minimal strain on the rotor  16 , so that the rotor  16  needs only to tip or bump the incoming material. This transfer of kinetic energy shatters the material along natural fault planes, producing smaller particles. The smaller particles are accelerated away from the rotor  16  and into the shatter bars  28  where further reductions occur as a result of collisions between the shatter bars  28  and the smaller particles. Of note is that the shatter bars  28  do not have to be of massive structure or unusual hardness because of the reduced size of the particles. The shatter bars  28  also direct the smaller particles back towards the swept area of the rotor  16  where, in a continuous feed situation, the smaller particles encounter new particles produced by the impact hammers  44  of the rotor  16  striking newly introduced material and these secondary impacts between reflected material and recently shattered material result in further reduced particles. Of note is that the rotor  16  causes a localized increase in the pressure of the airflow generated by the exhaust fan  14 . This forces entrained particles, which are naturally quite abrasive, away from the housing  10 , thereby drastically reducing scrubbing and wear on the rotary mill  1 . Furthermore, the reduced particles are swept by the airflow drawn through the housing generated by the exhaust fan  14  around the curved portion  30  into the secondary reduction chamber  20 . 
         [0069]    As noted above, the curved portion  30  is arranged such that the airflow generated by the exhaust fan  14  directs the reduced particles toward the reduction elements  32  in the secondary reduction chamber  20 . As noted above, the reduction elements  32  are arranged such that only particles below a given size, or fine particles, pass through the reduction elements  32  and enter the outlet chamber  22  while oversized particles are directed back into the flow of reduced particles leaving the rotor path. Thus, the reduction elements  32  provide the particle size control, forming a restriction in the path that material follows through the housing  10 . Furthermore, the close, staggered configuration of the reduction elements  32  causes the airflow generated by the exhaust fan  14  to change direction rapidly several times before being drawn out of the secondary impact chamber  20 . This turbulent airflow prevents particle build-up from occurring on the reduction elements  32 . Of note is that the position and orientation of the reduction elements  32  is not critical as they may be placed either vertically or horizontally with little or no change in their effectiveness. 
         [0070]    Upon entry into the outlet chamber  22 , the fine particles remain in the airflow generated by the exhaust fan  14  and are drawn off through the outlet  34  while heavy particles fall to the lower material outlet  38  until a mass accumulates that equals the balance weight, which opens the balanced door  40  and releases the heavy particles. The balanced door  40  ensures that air is drawn into the rotary mill  1  only through the inlet opening  24 , thereby keeping a negative pressure on all parts of the housing  10  and serving as a form of dust control. Furthermore, the position of the movable baffle  42  within the outlet chamber  22  may be altered to vary the intensity of the airflow, thereby varying the amount and size of the particles drawn off through the outlet  34 . In cases where this fine product has value, the flow of fine particles may, for example, be blown into a bag house or cyclone or may be turned into a slurry by the addition of a water spray. Furthermore, the heavy material which exits the lower opening can be fed into any suitable classification machinery for further processing. Thus, this arrangement also serves as a simple means of material classification. 
         [0071]    Of note is that the position of the rotor  16  within the housing  10  is quite critical. In this embodiment, a clearance of 0.125 inches is optimum, wherein clearance refers to the ideal spacing between the rotor  16  and the housing  10  as well as the clearance between the impact hammers  44  and the housing  10 . If too much clearance is allowed, turbulence occurs and entrained particles build up which greatly increase the wear on the rotary mill  1 . 
         [0072]    The importance of having a constant and steady flow of incoming material can be shown when a large particle is introduced and allowed to pass through the rotary mill  1  alone. The resulting pile of reduced material consists of a light scattering of larger particles on the top and bottom of a cross section with the majority in the center finely pulverized, as there are few particles to carry out the attrition process. However, with a constant, regulated flow of input material, there is a steady impingement between fractured particles and the particle size distribution is more even. 
         [0073]    Clearly, time of material residency is an important factor in the successful operation of the above-described rotary mill  1 . However, the tendency to return particles to the new product flow can cause a buildup of material in the system. This has been overcome by the addition of a supplementary airflow generated by the exhaust fan  14 . The exhaust fan  14  creates a path of steadily moving air from the inlet opening  24  to the outlet  34 . Furthermore, the airflow overcomes turbulence created by the rotor  16  and ensures that all material continues to follow the desired path through the rotary mill  1 . 
         [0074]    The housing  10  thus provides the impact chamber  18  defined within the housing with the rotor  16  mounted in the impact chamber  18  of the housing  10  rotatable about a longitudinal axis  16 A of the rotor  16 . The impact chamber  18  of the housing has a peripheral wall  18 A which forms generally a cylinder surrounding the axis  16 A of the rotor. 
         [0075]    The feed opening  24  in the peripheral wall  18 A of the impact chamber forms a space in the cylindrical wall defined by edges  18 B and  18 C. The feed opening is arranged for deposit of the feed material onto the rotor so that rotation of the rotor acts to throw the solid materials against the peripheral wall  18 A. 
         [0076]    The rotor  16  has a plurality of axially extending, angularly spaced impact hammers  44  at its periphery for rotation about the axis  16 A of the rotor which is transverse to the feed opening  24  so that the materials are fed generally radially inwardly toward the axis. 
         [0077]    The rotor  16  is positioned relative to the feed opening such that the impact hammers  44  impact and deflect the solid materials entering through the feed opening, thereby fragmenting the solid materials to form finer and coarser particles and throw the particles outwardly toward the plurality of shatter bars  28  located at the peripheral wall  18 A of the impact chamber arranged such that the shatter bars contact the deflected solid materials, thereby further fragmenting the solid material into said particles. The shatter bars extend parallel to the axis and are arranged at angularly spaced positions around the axis. 
         [0078]    The second outlet chamber  22  is defined within the housing downstream of the rotor  16  with the first impact chamber and the second outlet chamber being connected by the chamber  20  and the separate elements  32  so that the particles pass from the first chamber  18  to the second chamber  22 . 
         [0079]    The finer particle outlet duct  34  is connected to the outlet chamber  22  and is arranged to so that the airstream acts to extract the particles from the chamber  22  to a separator outside the outlet  34 . The coarser particles are collected at the bottom discharge  38  for allowing release of coarser particles from a bottom of the outlet chamber. 
         [0080]    The guide surface  26  forms an inclined guide wall at the feed opening  24  starting at the edge  18 C in the peripheral wall of the impact chamber which is directed from the opening toward the rotor  16 . The guide wall  26  forms a planar surface  26 A which is inclined downwardly into the impact chamber  18  and transversely across the opening  24  so that the solid material falling from the conveyor  46  slides along the guide wall surface  26 A into the chamber to the rotor. A bottom edge  26 B of the guide wall is located closely adjacent the impact hammers  44  as they rotate with the rotor  16  so that the solid material is fed off the bottom edge onto the impact hammers. Each of the impact hammers has along its axial length a leading blade element  44 A carried on a support  44 B of the impact hammer  44 . The leading blade element, when viewed in the cross-section of  FIG. 2  extends generally radially outwardly of the axis of the rotor from an inner edge  44 C to an outer edge  44 D which passes closely adjacent the edge  26 B. Thus the blade element  44 A forms a leading or front face  44 E so as to engage and carry the solid material angularly forwardly around the axis of the rotor as it falls from the bottom edge  26 B. 
         [0081]    The leading blade elements  44 A are formed of a hardened steel material harder than the support  44 B of the impact hammer. As previously explained, the impact hammers  44  are arranged to form elements of a large mass so that the support of the impact hammer comprises a metal block extending longitudinally of the rotor and radially outwardly of the axis so that the leading blade element is mounted on a front face of the block. 
         [0082]    The hardened steel material is an iron based steel overlay wear plate material with a near nanoscale submicron microstructure. This provides a  68  to  71  HRc single and double pass deposit and maintains a high hardness after exposure to high temperatures. This provides an exceptional resistance to severe sliding abrasion ad a toughness equivalent to 400 Brinell Q&amp;T plate. It provides a forming or cutting response similar to standard chrome carbide plate. This is a steel alloy with a unique glass forming chemistry that allow high undercooling to be achieved during application. This results in a considerable refinement of the crystalline microstructure to a near nanosize range. It has a density of the order of 7.36 g/cm3. 
         [0083]    Contents are as follows: 
         [0084]    Chromium 25% 
         [0085]    Boron 10% 
         [0086]    Molybdenum 10% 
         [0087]    Niobium 10% 
         [0088]    Manganese 5% 
         [0089]    Silicon 5% 
         [0090]    Carbon 2% 
         [0091]    Iron balance 
         [0092]    The leading blade element has a planar front face lying which is inclined relative to a bottom portion of the guide surface at the bottom edge at the location around the axis when the front face passes the bottom edge so that the outer edge  44 D of the front face is angularly advanced relative to the inner edge  44 C. 
         [0093]    In order to improve the fracturing of the particles, the shatter bars are also formed of the same hardened steel material. 
         [0094]    As shown in  FIG. 3 , the above grinding machine is used to generate ground glass from waste glass materials  60 . This generates ground materials of different grade of particle size from the size of crystals to fine powder. This includes fine materials  61 , medium materials  62 , coarse materials  63  and oversize materials  64 . The materials fine and medium materials  61 ,  62  are mixed in a chamber  65  with a base material from a supply  66  such as epoxy which is liquid in an initial state for application and sets or cures to form a solid layer after application. 
         [0095]    In a process after the grinding as shown at  67  including heating in a suitable container, the ground glass is impregnated with a colorant and/or with a luminescent material. 
         [0096]    The base material is colorless so that, when the ground glass is mixed through the base material, the color of the road markings is provided by the impregnated or applied colorant and the base material does not impede or hide the reflection of light from the glass particles within the base material. 
         [0097]    The mixing of the ground glass through the base material acts to increase the hardness of the base material. 
         [0098]    The base material with the ground glass admixed therein is applied simultaneously by a spray coating or brush coating process shown schematically at  68  onto a road surface and the base material  70  is cured. 
         [0099]    Thus there is provided a system  67  where the fine and medium ground glass  61 ,  62  is impregnated or coated with a colorant and/or with the luminescent material and a second system  67 A where the coarse material  63  is coated with the colorant and/or with the luminescent material. 
         [0100]    The mixing chamber  65  receives the materials  61 ,  62  for mixing the particles into the base material  66  where the finer material is mixed into the base material. As shown at  71 , the coarser material  63  is applied on the surface of the base material  70  on the road surface. 
         [0101]    As explained previously the coarser material  72  is collected at a bottom of a discharge chamber  22  and at least some of the finer material  61  is collected in an air stream at opening  34  at a top of the discharge chamber  22 . 
         [0102]    The material  72  collected from the bottom of the discharge material is separated at a separator  1  into a medium grind material  62  for mixing with the fine material in the base material  66  and a coarse grind material  73 . The material  73  is fed to a second separator  2  where it is separated into the material  63  for application separately onto a surface of the base material and the oversize material  64  as a return material for return to the rotary mill. 
         [0103]    In some cases the glass can be coated with both colourant and the luminescent material. However typically the product is used in an arrangement in which there is no colourant so that any colouring required is provided by the underlying markings over which the coating is applied. In this way the colourant from the underlying markings is visible through the coating of the impregnated ground glass. At the same time the product is luminescent since the glass particles at the top surface provide luminescence the top surface which is visible by adjacent observers. 
         [0104]    The application of heat to a temperature less than a melting point of the glass so as to expand the glass which can cause the binder and the luminescent material to be drawn into the outer surface of the glass particles as the particles cool so that there is a partial impregnation of the material into the outer surface of the glass with some of the material also remaining as a coating on the glass particles. As the glass is ground into individual particles, the coating material is applied over the outer surface of all the particles and thus creates a ground glass product which is luminescent from the luminescent material carried on the outer surface of the particles. 
         [0105]    Since various modifications can be made in my invention as herein above described, and many apparently widely different embodiments of same made within the spirit and scope of the claims without department from such spirit and scope, it is intended that all matter contained in the accompanying specification shall be interpreted as illustrative only and not in a limiting sense.