Abstract:
A manufacturing method of a semiconductor device includes: forming a first gate insulating film on a semiconductor substrate in first and second regions in an active area; forming first gate electrodes on the first gate insulating film in the first and second regions; forming source/drain regions by introducing impurities at both sides of the first gate electrode in the first and second regions; performing heat treatment of activating the impurities; forming a stress liner film so as to cover the whole surface of first gate electrodes in the first and second regions; removing the stress liner film at an upper portion of the first gate electrode in the second region while allowing the stress liner film at least at a portion in the first region to remain to expose the upper portion of the first gate electrode in the second region; forming a groove by removing the first gate electrode in the second region; and forming a second gate electrode in the groove.

Description:
FIELD 
     The present disclosure relates to a manufacturing method of a semiconductor device and the semiconductor device, and particularly relates to a manufacturing method of a semiconductor device and the semiconductor device having n-channel and p-channel field effect transistors. 
     BACKGROUND 
     A metal-insulator (oxide) semiconductor field effect transistor (MISFET or MOSFET) is a basic element of a semiconductor device. The MISFET is miniaturized more and more as miniaturization and high integration of the semiconductor device progress. 
     A structure in which an n-channel MISFET (hereinafter also referred to as NTr) and a p-channel MISFET (hereinafter also referred to as PTr) are included on the same substrate is generally called a CMOS circuit. 
     The CMOS circuit is widely used as a device included in many kinds of LSIs because power consumption is low as well as miniaturization and high integration are easy to realize high-speed operation in the device. 
     In related art, as a gate insulating film, a thermally-oxidized film of silicon (silicon oxide: SiO 2 ) or a film formed by nitriding the silicon oxide thermally or in plasma (silicon oxynitride: SiON) is widely used. 
     As a gate electrode, an n-type polysilicon layer to which phosphorus (P) or arsenic (As) is doped and a p-type polysilicon layer to which boron (B) is doped have been widely used to the NTr and the PTr. 
     However, when the gate insulting film is allowed to be thinner or a gate length is allowed to be reduced in accordance with a scaling law, increase of gate leak current and reduction of reliability occur by allowing the silicon oxide film and the silicon oxynitride film to be thinner. 
     Additionally, reduction of gate capacitance occurs due to a depletion layer formed in the gate electrode, therefore, a method of using an insulating material having a high-dielectric constant (a high-dielectric film) is used as the gate insulating film and a method of using a metal material as the gate electrode are proposed. 
     As materials for the high-dielectric film, for example, hafnium compounds and so on can be cited. Particularly, hafnium oxide (HfO 2 ) is a promising material in a point that reduction in electron/hole mobility can be suppressed while maintaining a high dielectric constant. 
     However, as disclosed in “High Performance nMOSFET with Hfsix/Hf02 Gate Stack by Low Temperature Process”, T, Hirano et al., Tech. Dig. IEDM, p. 911 (2005) (Non-Patent Document 1), there is a problem that the reduction in characteristics such as reduction in carrier mobility occurs by performing high-temperature processing such as an activation annealing process of source/drain (S/D). 
     As metal materials for making a gate electrode, materials having a desired value in the work function (WF) can give good transistor characteristics. 
     In order to increase performance of an LSI, it is necessary that a short channel effect and so on are suppressed while achieving a lower threshold value as the MISFET, and metal materials of the gate electrode are desired to have the WF close to 4.1 eV in the NTr and 5.2 eV in the PTr. 
     Not so much metal material satisfying the above is known, and there is description of hafnium silicide (HfSix) in the NTr, ruthenium (Ru) and titanium nitride (TiN) in the PTr in “High Performance nMOSFET with HfSix/Hf02 Gate Stack by Low Temperature Process”, K. Tai et al., ISTC, p 330 (2006); “High Performance Dual Metal Gate CMOS with High Mobility and Low Threshold Voltage Applicable to Bulk CMOS Technology”, S. Yamaguchi et al., Symp. VLSI Tech., p. 192 (2006); “Sub-1 nm EOT HfSix/Hf02 Gate Stack Using Novel Si Extrusion Process for High Performance Application”, T. Ando et al., Symp. VLSI Tech., p. 208 (2006); and “High Performance pMOSFET with ALD-TiN/Hf02 Gate Stack on (110) Substrate by Low Temperature Process”, K. Tai et al., ESSDERC., p. 121 (2006) (Non-Patent Documents 2 to 5) and the like. 
     However, the WF value varies also in the above materials by performing a high-temperature processing step, which generates reduction of characteristics such as reduction in carrier mobility. 
     Accordingly, a manufacturing method in which a gate insulating film and a gate electrode are formed after performing the high-temperature processing step is disclosed in JP-A-2000-40826 (Patent Document 1) with respect to a related art manufacturing method in which the high-temperature processing step is performed after forming the gate insulating film and the gate electrode. 
     Hereinafter, a transistor structure formed by the manufacturing method in which the gate insulating film and the gate electrode are formed after performing high-temperature processing step will be referred to as a “gate-last structure”. 
     On the other hand, a transistor structure formed by performing the high-temperature processing step after forming the gate insulating film and the gate electrode as in the related art will be referred to as a “gate-first structure”. 
     In JP-A-2002-198441 (Patent Document 2), a method of forming the gate electrode by using metals having suitable WF on the NTr and the PTr respectively in the gate-last structure is disclosed. 
     In this case, a dummy gate is removed in a first region, a first gate insulating film is formed, a first gate electrode is formed by using a metal and the metal other than the portion to be the first gate electrode is removed by etching. 
     Next, a dummy gate is removed in a second region, a second gate insulating film is formed, a second gate electrode is formed and metal other than the portion of the second gate electrode is removed by etching. 
     According to the above processes, the gate electrodes having suitable WF can be formed on the NTr and the PTr respectively. 
     As the example applying the gate-last structure, a Full Silicidation (FUSI) technique using a compound of a polysilicon layer and a transition metal applying the metal as the gate electrode as described above. 
     It is difficult to form the NTr and the PTr by optimizing silicidation respectively, however, a method of fully siliciding only the gate electrode of the PTr by making an opening only in a PTr region as in JP-A-2009-117621 (Patent Document 3) is known. 
     In recent years, a technique (hereinafter, referred to as e-SiGe structure) of forming silicon germanium (SiGe) having a different lattice constant from silicon on a source/drain of transistors is known. 
     Moreover, a technique of modulating stress in a channel region of the transistor by forming a silicon nitride film (hereinafter, referred to as a stress liner film SL) of tensile stress or compression stress on the source/drain to thereby improve carrier mobility is applied as in International Publication WO2002/043151 pamphlet (Patent Document 4). 
     In the case where the stress liner film is formed on the source/drain in the transistor having the gate-last structure, a structure and a forming method in which an upper portion of the stress liner film is polished by a chemical mechanical polishing process and removed are applied such as in JP-A-2008-263168 (Patent Document 5). 
     Accordingly, the stress in the channel direction is reinforced to thereby realize a high-performance transistor having high carrier mobility. 
     In the above structure in which the upper portion of the stress liner film of the gate-last structure is polished by the CMP process and removed, the action of the stress due to the stress liner film is changed when removing the polysilicon layer which is a dummy gate. A difference occurs in effects with respect to carrier mobility between the NTr and the PTr due to the above change as shown in the following expressions (1), (2). 
     
       
         
           
             
               
                 
                   
                     
                       μ 
                       xx 
                     
                     
                       μ 
                       0 
                     
                   
                   = 
                   
                     1 
                     + 
                     
                       0.316 
                       ⁢ 
                       
                           
                       
                       ⁢ 
                       
                         S 
                         xx 
                       
                     
                     - 
                     
                       0.534 
                       ⁢ 
                       
                           
                       
                       ⁢ 
                       
                         S 
                         yy 
                       
                     
                     + 
                     
                       0.176 
                       ⁢ 
                       
                           
                       
                       ⁢ 
                       
                         S 
                         zz 
                       
                     
                   
                 
               
               
                 
                   ( 
                   1 
                   ) 
                 
               
             
             
               
                 
                   
                     
                       μ 
                       xx 
                     
                     
                       μ 
                       0 
                     
                   
                   = 
                   
                     1 
                     - 
                     
                       0.718 
                       ⁢ 
                       
                           
                       
                       ⁢ 
                       
                         S 
                         xx 
                       
                     
                     + 
                     
                       0.011 
                       ⁢ 
                       
                           
                       
                       ⁢ 
                       
                         S 
                         yy 
                       
                     
                     + 
                     
                       0.663 
                       ⁢ 
                       
                           
                       
                       ⁢ 
                       
                         S 
                         zz 
                       
                     
                   
                 
               
               
                 
                   ( 
                   2 
                   ) 
                 
               
             
           
         
       
     
     The expression (1) indicates an effect of a stress (S xx , S yy , S zz ) with respect to a ratio of mobility of electrons (μ xx /μ 0 ). The expression (2) indicates an effect of the stress (S xx , S yy , S zz ) with respect to the ratio of mobility of holes (μ xx /μ 0 ). Here, “xx” denotes a channel-length direction, “yy” denotes a vertical direction with respect to the channel and “zz” denotes a channel-width direction. 
     In Patent Document 5, the stress liner film of tensile stress is provided in the NTr and the stress liner film of compression stress is applied to the PTr. 
     In the case of the NTr in which electrons are carriers, the tensile stress in the “xx” direction (+S xx ) is increased and the compression stress in the “yy” direction (−S yy ) is reduced, thereby cancelling effects to the mobility as a coefficient of S xx  is approximately the same as a coefficient of S yy . 
     On the other hand, in the case of the PTr in which holes are carriers, the compression stress in the “ xx ” direction (+S xx ) is increased and the tensile stress in the “yy” direction (−S yy ) is reduced, however, the coefficient of S xx  is larger than the coefficient of S yy  by approximately 70 times, thereby obtaining effects of the increase of mobility due to action in the “xx” direction. 
       FIG. 10  shows results obtained by plotting relative variations of mobility in respective processes with respect to the gate pitch in the NTr having the gate-last structure. In the drawing, (a) indicates mobility after forming the stress liner, (b) indicates mobility after removing the stress liner on the gate electrode, (c) indicates mobility after removing the polysilicon and (d) indicates mobility after forming the metal gate electrode. The relative mobility when there is no stress liner film is set to 1.0. 
     When the gate pitch is long (0.83 μl, 0.5 μm), the mobility is relatively increased after removing the polysilicon layer as shown in (c), whereas when the gate pitch is short (0.19 μm), the mobility is relatively reduced after removing the polysilicon layer. 
     This is because the effects to the mobility are cancelled as the coefficient of S xx  is the approximately same as the coefficient of S yy , as described above and that S xx  is relatively reduced when the gate pitch is short, as a result, the mobility is reduced. 
     Accordingly, it is found that, as the distance between gates is reduced due to miniaturization of the semiconductor device, characteristics of the NTr is reduced in the gate-last structure is reduced as compared with the gate-first structure. 
     In the structure of Patent Document 3, a technique for applying the gate-first structure only to the NTr is disclosed. 
     However, as the process of removing the polysilicon layer in the PTr in the structure of Patent Document 3, the mobility of the PTr is not increased though reduction of mobility of the NTr is suppressed, therefore, it is difficult to obtain the high-performance CMOS circuit. 
     Additionally, there is a description concerning a method of using a high-dielectric constant film as the gate insulating film and using a metal material as the gate electrode in, for example, “A Novel “Hybrid” High-k/Metal Gate Process for 28 nm High Performance CMOSFETs”, C. M. Lai et al., Tech. Dig. IEDM, p. 655 (2009) (Non-Patent Document 6). 
     The CMOS structure disclosed in Non-Patent Document 6 applies the gate-first structure for the NTr and applies the gate-last structure for the PTr, however, the CMOS structure has a process of removing the upper portion of the stress liner film by the chemical mechanical polishing process and removing the polysilicon layer in the NTr. Accordingly, the reduction of mobility in the NTr occurs. As a result, it is difficult to obtain the high-performance CMOS circuit particularly in a micro area in which the distance between gates is short. 
     SUMMARY 
     It is desirable to increase carrier mobility and realize high performance particularly in a micro area in which the distance between electrodes is short both in an n-channel MISFET (NTr) and a p-channel MISFET (PTr) included in a CMOS circuit. 
     An embodiment of the present disclosure is directed to a manufacturing method of a semiconductor device including forming a first gate insulating film on a semiconductor substrate in a first region as a forming region of an n-channel field effect transistor and in a second region as a forming region of a p-channel field effect transistor on the semiconductor substrate in an active area, forming first gate electrodes on the first gate insulating film in the first region and the second region, forming source/drain regions by introducing impurities in the semiconductor substrate at both sides of the first gate electrode in the first region and the second region, performing heat treatment of activating the impurities in the source/drain regions, forming a stress liner film applying stress on the semiconductor substrate so as to cover the whole surface of the first gate electrodes in the first region and the second region, removing the stress liner film at an upper portion of the first gate electrode in the second region while allowing the stress liner film at least at a portion formed in the first region to remain to expose the upper portion of the first gate electrode in the second region, forming a groove for forming a second gate electrode by removing the first gate electrode in the second region completely, and forming a second gate electrode in the groove for forming the second gate electrode. 
     In the manufacturing method of the semiconductor device according to the embodiment of the disclosure, the first gate insulating film is formed on the semiconductor substrate in the first region as the forming region of the n-channel field effect transistor and in the second region as the forming region of the p-channel field effect transistor on the semiconductor in the active area. 
     Next, the first gate electrodes are formed on the first gate insulating film in the first region and the second region. 
     Next, the source/drain regions are formed by introducing the impurities in the semiconductor substrate at both sides of the first gate electrode in the first region and the second region. 
     Next, the heat treatment of activating the impurities in the source/drain region is performed. 
     Next, the stress liner film applying stress on the semiconductor substrate so as to cover the whole surface of the first gate electrode in the first region and the second region. 
     Next, the stress liner film at the upper portion of the first gate electrode in the second region is removed while allowing the stress liner film at least at the portion formed in the first region to remain to expose the upper portion of the first gate electrode in the second region. 
     Next, the first gate electrode in the second region is completely removed to form the groove for forming the second gate electrode. 
     Next, the second gate electrode is formed in the groove for forming the second gate electrode. 
     Another embodiment of the disclosure is directed to a semiconductor device including a first gate insulating film formed on a semiconductor substrate in a first region as a forming region of an n-channel field effect transistor of the semiconductor substrate in an active area, a second gate insulating film formed on the semiconductor substrate in a second region as a forming region of a p-channel field effect transistor of the semiconductor substrate, a first gate electrode formed on the first gate insulating film in the first region, a second gate electrode formed on the second gate insulating film in the second region, in which a portion touching the second gate insulating film is made of a metal or a metal compound, source/drain regions formed by introducing impurities in the semiconductor substrate at both sides of the first gate electrode and the second gate electrode in the first region and the second region, and a stress liner film applying stress on the semiconductor substrate formed so as to cover the whole surface of the first gate electrode in the first region and cover regions other than an upper portion of the second gate electrode in the second region. 
     In the semiconductor device according to the embodiment of the disclosure, the first gate insulating film is formed on the semiconductor substrate in the first region as the forming region of the n-channel field effect transistor of the semiconductor substrate in the active region. The second gate insulating film is formed on the semiconductor substrate in the second region as the forming region of the p-channel field effect transistor. 
     The first gate electrode is formed on the first gate insulating film in the first region and the second gate electrode is formed on the second gate insulating film in the second region, in which the portion touching the second gate insulating film is made of the metal or the metal compound. 
     The source/drain regions are formed by introducing the impurities in the semiconductor substrate at both sides of the first gate electrode and the second gate electrode in the first region and the second region. 
     The stress liner film applying stress on the semiconductor substrate formed so as to cover the whole surface of the first gate electrode in the first region and cover regions other than an upper portion of the second gate electrode in the second region. 
     In the manufacturing method of the semiconductor device according to the embodiment of the disclosure, the carrier mobility can be increased and the high performance can be realized particularly in the micro area in which the distance between electrodes is short both in the n-channel MISFET (NTr) and the p-channel MISFET (PTr) included in the CMOS circuit. 
     In the semiconductor device according to the embodiment of the disclosure, the carrier mobility can be increased and the high performance can be realized particularly in the micro area in which the distance between electrodes is short both in the n-channel MISFET (NTr) and the p-channel MISFET (PTr) included in the CMOS circuit. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  is a schematic cross-sectional view of a semiconductor device according to a first embodiment of the disclosure; 
         FIGS. 2A to 2C  are schematic cross-sectional views showing manufacturing processes in a manufacturing method of the semiconductor device according to the first embodiment of the disclosure; 
         FIGS. 3A to 3C  are schematic cross-sectional views showing manufacturing processes in the manufacturing method of the semiconductor device according to the first embodiment of the disclosure; 
         FIGS. 4A to 4C  are schematic cross-sectional views showing manufacturing processes in the manufacturing method of the semiconductor device according to the first embodiment of the disclosure; 
         FIGS. 5A and 5B  are schematic cross-sectional views showing manufacturing processes in the manufacturing method of the semiconductor device according to the first embodiment of the disclosure; 
         FIGS. 6A to 6C  are schematic cross-sectional views showing manufacturing processes in the manufacturing method of the semiconductor device according to a modification example of the first embodiment of the disclosure; 
         FIG. 7  is a schematic cross-sectional view of a semiconductor device according to a second embodiment of the disclosure; 
         FIGS. 8A to 8C  are schematic cross-sectional views showing manufacturing processes in a manufacturing method of the semiconductor device according to the second embodiment of the disclosure; 
         FIGS. 9A to 9C  are schematic cross-sectional views showing manufacturing processes in the manufacturing method of the semiconductor device according to the second embodiment of the disclosure; and 
         FIG. 10  shows results obtained by plotting relative variations of carrier mobility in respective processes with respect to the gate pitch in the NTr having a gate-last structure according to a related-art example. 
     
    
    
     DETAILED DESCRIPTION 
     Hereinafter, embodiments of a semiconductor device and a manufacturing method thereof in the present disclosure will be explained with reference to the drawings. 
     The explanation will be made in the following order. 
     1. First Embodiment (Basic structure) 
     2. Modification Example of First Embodiment 
     3. Second Embodiment (Method of forming a gate electrode of PTr to be higher than a gate electrode of NTr) 
     &lt;First Embodiment&gt; 
     [Structure of a Semiconductor Device] 
       FIG. 1  is a schematic cross-sectional view of a semiconductor device according to the embodiment. 
     For example, an element isolation trench  10   a  is formed and a STI (shallow trench isolation) element isolation insulating film  13  is formed so as to divide a semiconductor substrate made of a silicon substrate and so on into a first region A 1  and a second region A 2 . 
     The first region A 1  is a forming region of an n-channel field effect transistor (NTr) and the second region A 2  is a forming region of a p-channel field effect transistor (PTr). 
     A p-type well  10   b  is formed in the first region A 1  of the semiconductor substrate and an n-type well  10   c  is formed in the second region A 2 . 
     For example, a first gate insulating film  15   a  made of hafnium oxide (HfO 2 ) and the like is formed on the semiconductor substrate in the p-type well  10   b  region of the first region A 1 . 
     A first gate electrode made of a layered body and the like which includes a titanium nitride (TiN) film  16  and a polysilicon layer  17  is formed over the first gate insulating film  15   a.    
     As the first gate insulating film  15   a , so-called High-k (high-dielectric constant) materials having higher dielectric constant than silicon oxide such as hafnium oxide silicon (HfSiO), hafnium oxide silicon nitride (HfSiON), zirconium oxide (ZrOx) can be also used. 
     In a portion touching the first gate insulating film  15   a  of the first gate electrode, a film made of a metal or a metal compound having a work function suitable for the NTr is used, and the TiN film  16  is used in the embodiment. 
     A sidewall insulating film made of a layered body including a silicon nitride film  20 , a silicon oxide film  21  and a silicon nitride film  22  is formed at both sides of the first electrode. 
     For example, in a surface layer portion of the P-type well  10   b  of the semiconductor substrate at both sides of the first gate electrode, an n-type extension region  18  and an n-type source/drain region  23  extending to a lower portion of the first gate electrode are formed. 
     For example, high-melting point metal silicide layers ( 25 ,  26 ) such as NiSi are formed on surface layer portions of the polysilicon layer  17  of the first gate electrode and the source/drain region  23  respectively. 
     According to the above, an n-channel field effect transistor (NTr) is formed. 
     For example, a second gate insulating film  15   b  made of hafnium oxide and so on is formed on the semiconductor substrate in the n-type well  10   c  region in the second region A 2 . 
     A second gate electrode made of a layered body and the like which includes a titanium nitride (TiN)  31 , a conductive layer  32  made of aluminum and the like is formed over the second gate insulating film  15   b.    
     As the second gate insulating film  15   b , so-called High-k (high-dielectric constant) materials having higher dielectric constant than silicon oxide such as hafnium oxide silicon (HfSiO), hafnium oxide silicon nitride (HfSiON), zirconium oxide (ZrOx) can be also used. 
     The first gate insulating film  15   a  and the second gate insulating film  15   b  can be made of the same insulating material as long as necessary dielectric constant characteristics and so on correspond to each other, and a case where the same insulating material is used is shown in the embodiment. 
     At the same time, the first gate insulating film  15   a  and the second gate insulating film  15   b  can be made of different materials according to necessary dielectric constant characteristics and so on, which will be explained in a later-described modification example. 
     In a portion touching the second gate insulating film  15   b  of the second gate electrode, a film made of a metal or a metal compound having a work function suitable for the PTr is used. For example, ruthenium (Ru), tantalum carbide (TaC) and the like can be suitably used in addition to the above titanium nitride. 
     Additionally, it is preferable to use metals with low resistance as the conductive layer  32  such as copper (Cu) and tungsten (W), in addition to the above aluminum. 
     The sidewall insulating film made of the layered body including the silicon nitride film  20 , the silicon oxide film  21  and the silicon nitride film  22  is formed at both sides of the second gate electrode. 
     The first gate insulating film and the second gate insulating film are formed by using the high-dielectric constant film, and the metal or the metal compound is used for portions touching the gate insulating films of the first gate electrode and the second gate electrode, thereby allowing effective gate oxide thickness (EOT) to be thinner. 
     For example, in the surface layer portion of the n-type well  10   c  of the semiconductor substrate at both sides of the second gate electrode, a p-type extension region  19  and a p-type source/drain region  24  extending to a lower portion of the second gate electrode are formed. 
     For example, the high-melting point metal silicide layer  26  such as NiSi is formed on a surface layer portion of the source/drain region  24 . 
     As described above, a p-channel field effect transistor (PTr) is formed. 
     In the first region A 1 , a first stress liner film  27  made of silicon nitride and the like is formed on the whole surface of the region so as to cover the NTr. 
     On the other hand, in the second region A 2 , a second stress liner film  28  made of silicon nitride is formed on the whole surface of the region so as to cover the PTr. Here, the second stress liner film  28  is formed on the whole surface of the region so as to cover regions other than the upper portion of the second gate electrode. 
     The first stress liner film  27  and the second stress liner film  28  are respectively films for applying stress on the semiconductor substrate. 
     The first stress liner film  27  preferably has characteristics in which stress is applied to the semiconductor substrate so as to improve characteristics of the NTr, which is, for example, the film for applying tensile stress on the semiconductor substrate with respect to a gate length direction of the first gate electrode. 
     The second stress liner film  28  preferably has characteristics in which stress is applied to the semiconductor substrate so as to improve characteristics of the PTr, which is, for example, the film for applying compression stress on the semiconductor substrate with respect to a gate length direction of the second gate electrode. 
     When stress characteristics different from each other are given to the NTr and the PTr respectively, the structure in which the stress liner films having different stress characteristics are formed in the first region A 1  and the second region A 2  is applied. 
     When the same stress characteristics are allowed, the common stress liner film can be formed. 
     In the first region A 1  and the second regio A 2 , a first insulating film  29  made of silicon oxide and so on is formed on surfaces of the first stress liner film  27  and the second stress liner film  28 . 
     On the surface of the first insulating film  29 , a polish stopper film  30  made of silicon nitride and so on is formed. 
     A second insulating film  33  made of silicon oxide and so on is formed on the surface of the polish stopper film  30 . 
     Openings reaching the gate electrodes and the source/drain regions of the NTr and the PTr are formed so as to pierce through the second insulating film  33 , the polish stopper film  30  and the first insulating film  29 , in which contact plugs  34  are buried. Moreover, an upper wiring  35  is formed on the surface of the second insulating film  33  so as to connect to the contact plugs  34 . 
     The NTr is a transistor having the gate-first structure in which the stress liner film for giving tensile stress with respect to the gate length direction is formed on the whole surface, which can improve mobility of carriers (electrons) the NTr by applying the tensile stress on the semiconductor substrate. 
     The PTr is a transistor having the gate-last structure in which the stress liner film for giving compression stress with respect to the gate length direction is formed at regions other than the upper portion of the gate, which can improve mobility of carriers (holes) the PTr by applying the compression stress on the semiconductor substrate. 
     According to the above, the semiconductor device of the embodiment can increase the carrier mobility both in the n-channel MISFET (NTr) and the p-channel MISFET (PTr) included in the CMOS circuit. Therefore, high performance can be realized particularly in the micro area in which the distance between gate electrodes is short. 
     [Manufacturing Method of the Semiconductor Device] 
     A manufacturing method of the semiconductor device according to the embodiment will be explained with reference to  FIGS. 2A to 2C  to  FIGS. 5A ,  5 B. 
     First, as shown in  FIG. 2A , a silicon oxide film  11  is formed over a semiconductor substrate  10  by, for example, a dry oxidation process and a silicon nitride film  12  is deposited by a reduced-pressure CVD method and so on in the first region A 1  and the second region A 2 . 
     A resist film having a pattern protecting the first region A 1  and the second region A 2  is patterned by using a photolithography process. 
     Next, etching processing such as RIE (reactive ion etching) is performed by using the resist film as a mask to remove the silicon oxide film  11  and the silicon nitride film  12  at portions other than the first region A 1  and the second region A 2 . 
     Furthermore, the semiconductor substrate  10  is etched to the depth of, for example, 350 to 400 nm to form the element isolation trench  10   a  for the STI. 
     Next, a silicon oxide film is deposited to have a thickness of 650 nm to 700 nm so as to fill the element isolation trench  10   a  by, for example, a high-density plasma CVD method and the like. The dense film with good step coverage can be formed by the high-density plasma CVD method. 
     Subsequently, the silicon oxide at the outside of the trench for STI is removed to form the STI element isolation insulating film  13 . The silicon oxide film is polished from the upper surface until the upper surface of the silicon nitride film  12  is exposed by, for example, a CMP (chemical mechanical polishing) process to planarize the film. The forming region of the silicon nitride film  12  is polished to a degree that the silicon oxide film on the silicon nitride film is removed. 
     It is also possible to remove the silicon oxide film in the wide active region by lithography patterning and etching processing in advance for reducing the global step by CMP. 
     The forming region of the STI element isolation insulating film  13  is a field oxide film region, the region where the silicon nitride film  12  is formed is the active region (the first region A 1  and the second region A 2 ). 
     Next, as shown in  FIG. 2B , the silicon nitride film  12  is removed by hot phosphoric acid in the first region A 1  and the second region A 2 . It is also preferable to perform annealing in nitrogen, oxygen, hydrogen/oxygen before removing the silicon nitride film  12  to allow the STI element isolation insulating film  13  to be dense as well as for rounding corner portions of the active region. 
     In the above state, the silicon oxide film  11  is substantially removed. Here, the surface of the active region is oxidized to have a film thickness of 10 nm in the first region A 1  and the second region A 2  to form a sacrificial oxide film  14 . 
     Next, the p-type well  10   b  is formed by ion implantation in the first region A 1 . Further, ion implantation for forming an embedded layer for preventing punch-through and ion implantation for adjusting a threshold Vth of the NTr are performed. 
     Additionally, the n-type well  10   c  is formed in the second region A 2  by ion implantation. Further, ion implantation for forming an embedded layer for preventing punch-through and ion implantation for adjusting a threshold Vth of the PTr are performed. 
     Next, as shown in  FIG. 2C , the sacrificial oxide film  14  is peeled off in the first region A 1  and the second region A 2  by, for example, an HF solution to form an interfacial oxide silicon film (not shown) to have a film thickness of 0.5 to 1.5 nm. 
     As methods for forming the interfacial oxide silicon film, an RTO (Rapid Thermal Oxidization) process, an oxygen plasma process and a chemical oxidization process by, for example, processing of hydrogen peroxide chemicals can be cited. 
     Next, the first gate insulating film  15   a  and the second gate insulating film  15   b  are formed by, for example, a CVD (Chemical Vapor Deposition) method or an ALD (Atomic Layer Deposition) method to have a film thickness of approximately 2 to 3 nm in the first region A 1  and the second region A 2 . 
     As the first gate insulating film  15   a  and the second gate insulating film  15   b , so-called High-k (high-dielectric constant) materials having higher dielectric constant than silicon oxide such as hafnium oxide (HfO 2 ), hafnium oxide silicon (HfSiO), hafnium oxide silicon nitride (HfSiON), zirconium oxide (ZrOx) can be also used. 
     In the present embodiment, the case where the first gate insulating film  15   a  and the second gate insulating film  15   b  use the same insulating material is shown. 
     Next, the TiN film  16  is formed to have a film thickness of 5 to 20 nm by, for example, a sputtering method, the CVD method, the ALD method and so on in the first region A 1  and the second region A 2 . It is also possible that a thin film made of La, LaOx, AlOx and so on can be inserted with a thickness of approximately 0.1 to 1.0 nm under the TiN film  16  for controlling the threshold Vth of the transistor. 
     Next, the polysilicon layer  17  is deposited to have a film thickness of 50 to 150 nm by the reduced-pressure CVD method with a deposition temperature of 580 to 620° C. by using, for example, SiH 4  as a source gas in the first region A 1  and the second region A 2 . 
     Subsequently, a resist film having a pattern of the first gate electrode and the second gate electrode is pattern-formed by the photolithography process to be processed to be a pattern of the gate electrodes by anisotropic etching using an etching gas of HBr or Cl. 
     According to the above, the first gate electrode and the second gate electrode made of the layered body and the like including the titanium nitride (TiN) film  16  and the polysilicon layer  17  are formed respectively in the first region A 1  and the second region A 2 . 
     It is also possible to form the gate electrode pattern finely by trimming processing using oxygen plasma after the resist patterning, and the gate length can be formed to be approximately 20 to 30 nm in, for example, a 32 nm node technique (hp45). 
     Next, the silicon nitride film is deposited to be approximately 5 to 15 nm by, for example, the reduced-pressure CVD method in the first region A 1  and the second region A 2  as shown in  FIG. 3A  and etched back by the anisotropic etching to form the silicon nitride film  20  forming the sidewall insulating film. 
     Next, in the first region A 1 , As+ is ion-implanted with 5 to 10 keV, 5 to 20×10 14 /cm 2  by using the first gate electrode and the silicon nitride film  20  as a mask to form the n-type extension region  18 . 
     Also in the first region A 1 , BF 2 + is ion-implanted with 3 to 5 keV, 5 to 20×10 14 /cm 2  by using the first gate electrode and the silicon nitride film  20  as a mask to form the p-type extension region  19 . 
     The above ion implantation is performed after forming the silicon nitride film  20  which is an offset spacer to thereby suppress the short channel effect and suppressing variations in transistor characteristics. 
     Next, as shown in  FIG. 3B , the silicon oxide is deposited to have a film thickness of 10 to 30 nm by, for example, the plasma CVD method in the first region A 1  and the second region A 2  to thereby form the silicon oxide film  21 . 
     Next, the silicon nitride is deposited to have a film thickness of 30 to 50 nm by, for example, the plasma CVD method to form the silicon nitride film  22 . 
     Next, the silicon oxide film  21  and the silicon nitride film  22  are etched back by the anisotropic etching to form the sidewall insulating film including the silicon nitride film  20 , the silicon oxide film  21  and the silicon nitride film  22 . 
     Next, as shown in  FIG. 3C , As+ is ion-implanted with 40 to 50 keV, 1 to 2×10 15 /cm 2  in the first region A 1  by using the first gate electrode and the sidewall insulating film as a mask to form the n-type source/drain region  23 . 
     In the second region A 2 , BF 2 + is ion-implanted with 5 to 10 keV, 1 to 2×10 15 /cm 2  by using the second gate electrode and the sidewall insulating film as a mask to form the p-type source/drain region  24 . 
     Next, an impurity is activated by an RTA process, for example, at 1000° C. for 5 seconds. 
     It is also possible to perform thermal processing by a spike RTA process for promoting dopant activation and suppressing diffusion. 
     Next, as shown in  FIG. 4A , a high-melting point metal such as Ni is deposited to have a film thickness of 6 to 8 nm by the sputtering method and performs the RTA process at 300 to 450° C. for 10 to 60 seconds. According to the processing, only a portion touching silicon of the semiconductor substrate and the polysilicon layer forming the gate electrodes are solicited in a self-aligned manner. 
     Accordingly, the high-melting point metal silicide layers ( 25 ,  26 ) such as NiSi are respectively formed at the surface portions of the polysilicon layer  17  of the first gate electrode and the second gate electrode and the source/drain regions ( 23 ,  24 )  22 . 
     Next, unreacted Ni is removed by H 2 SO 4 /H 2 O 2 . 
     It is also possible to form CoSi 2  or NiSi by depositing Co or NiPt instead of Ni. In both cases, temperature of the RTA process can be suitably set. 
     Next, as shown in  FIG. 4B , the first stress liner film  27  having tensile stress is formed on the whole surface of the first region A 1 . The first stress liner film  27  is formed by using the silicon nitride film having a film thickness of 30 to 50 nm and tensile stress of approximately 1.2 GPa by, for example, the plasma CVD method. 
     The first stress liner film  27  can be deposited by chemical reaction in the following conditions. 
     Nitrogen (N 2 ) gas: 500 to 2000 cm 3 /minute 
     Ammonia (NH 3 ) gas: 500 to 1500 cm 3 /minute 
     Monosilane (SiH 4 ) gas: 50 to 300 cm 3 /minute 
     Substrate temperature: 200 to 400° C. 
     Pressure: 0.67 to 2.0 kPa 
     RF power: 50 to 500 W 
     Furthermore, ultraviolet rays (UV) irradiation processing is performed in the following conditions after deposition. 
     Helium (He) gas: 10 to 20 liters/minute 
     Processing temperature: 400 to 600° C. 
     Pressure: 0.67 to 2.0 kPa 
     Ultraviolet rays (UV) ramp power: 1 to 10 kW 
     After that, processing is performed so that the first stress liner film  27  remains only in the first region A 1  by using the photolithography technique and a dry etching technique. 
     Next, the second stress liner film  28  having compression stress is formed on the whole surface of the second region A 2 . The second stress liner film  28  is formed by using the silicon nitride film having a film thickness of 40 nm and having compression stress of approximately 1.2 GPa by, for example, the plasma CVD method. 
     The second stress liner film  28  can be deposited by chemical reaction in the following conditions. 
     Hydrogen (H 2 ) gas: 1000 to 5000 cm 3 /minute 
     Nitrogen (N 2 ) gas: 500 to 2500 cm 3 /minute 
     Argon (Ar) gas: 1000 to 5000 cm 3 /minute 
     Ammonia (NH 3 ) gas: 50 to 250 cm 3 /minute 
     Trimethylsilanemonosilane gas: 10 to 50 cm 3 /minute 
     Substrate temperature: 400 to 600° C. 
     Pressure: 0.13 to 0.67 kPa 
     RF power: 50 to 500 W 
     After that, processing is performed so that the second stress liner film  28  remains only in the second region A 2  by using the photolithography technique and the dry etching technique by using the photolithography technique and the dry etching technique. 
     The film having compression stress of 1.2 GPa is formed in the present embodiment, however, the stress is not limited to the value. The film thickness is not limited to the film thickness of the embodiment either. 
     Next, silicon oxide is deposited to have a film thickness of 500 to 1500 nm by using the CVD method and planarized by the CMP process to form the first insulating film  29 . At this time, polishing is performed until reaching the stress liner films ( 27 ,  28 ). 
     Next, for example, silicon nitride is deposited to be approximately 20 to 50 nm by, for example, the plasma CVD method to form the polish stopper film  30 . 
     Next, as shown in  FIG. 4C , a resist film (not shown) having a pattern of having an opening on the second gate electrode by optical lithography and performs etching processing. 
     At this time, the pattern of the opening region is set to be, for example, approximately 10 to 20 nm larger than the pattern of the second gate electrode as a base in consideration of variations of the line width and alignment. 
     In the opening region, the polish stopper film  30  and the second stress line film  28  are removed by the dry etching processing by using, for example, fluorocarbon gas and the like. 
     Next, the high-melting point metal silicide layer  25  is removed by the dry etching processing using a chlorine gas and so on. 
     Next, the poly silicon layer  17  and the TiN film  16  are sequentially removed by the dry etching processing using chlorine or HBr gas. 
     Next, it is possible to remove the TiN film  16  as well as possible not to remove the TiN film  16 . The film is removed in the drawing. 
     According to the above processes, a groove for forming the second gate electrode “T” is formed. 
     Next, as shown in  FIG. 5A , the top of the second gate insulating film  15   b  is covered in the groove for forming the second gate electrode “T” and an inner wall of the groove for forming the second gate electrode “T” is covered by using, for example, the ALD method, the sputtering method or the CVD method to form the TiN film  31  to have a film thickness of 10 to 30 nm. 
     The portion touching the second gate insulating film  15   b  can be the film made of a metal or a metal compound having the work function suitable for the PTr, and ruthenium (Ru), tantalum carbide (TaC) and so on can be preferably used in addition to the TiN film  31 . 
     Next, for example, the conductive layer  32  made of aluminum and so on is formed to have a film thickness of 30 to 100 nm on the TiN layer  31  so as to fill the groove for forming the second gate electrode “T” by using, for example, the sputtering method. 
     As the conductive layer  32 , metals with low resistance are preferably used, and copper (Cu), tungsten (W) and so on can be preferably used in addition to the above aluminum. 
     Next, the CMP process is performed by using the polish stopper film  30  as a stopper and the TiN film  31  and the conductive layer  32  deposited on the outside of the groove for forming the second gate electrode “T” are removed. 
     As described above, the second gate electrode having the gate-last structure made of the layered body including the TiN film  31  and the conductive layer  32  is formed, which is buried in the groove for forming the second gate electrode “T”. 
     Next, as shown in  FIG. 5B , silicon oxide is deposited to have a film thickness of 100 to 500 nm on the whole surface of the first region A 1  and the second region A 2  by using, for example, the CVD method to form the second insulating film  33 . 
     Next, openings reaching the gate electrodes and the source/drain regions of the NTr and the PTr are formed so as to pierce through the second insulating film  33 , the polish stopper film  30  and the first insulating film  29 , a Ti/TiN and W are deposited and the CMP process is performed to form the contact plugs  34  so as to be buried. Moreover, the upper wiring  35  is formed on the surface of the second insulating film  33  so as to connect to the contact plugs  34 . 
     As a method of forming the Ti/TiN film, the sputtering method using IMP can be also applied in addition to the CVD method, and the whole surface etch back can be used as the method of forming the plugs. 
     It is possible to perform multiwiring as wiring above the upper wiring  35  and to set the wiring according to the purpose. Additionally, wiring of Al and so on can be also formed. 
     In the manufacturing method of the semiconductor device according to the embodiment, the film can be removed by patterning and etching by lithography in the process of removing only the stress liner film having compression stress in part of the second gate electrode. 
     In the manufacturing method of the semiconductor device according to the embodiment, the carrier mobility can be increased and the high performance can be realized particularly in the micro area in which the distance between electrodes is short both in the n-channel MISFET (NTr) and the p-channel MISFET (PTr) included in the CMOS circuit. 
     The semiconductor device according to the embodiment has the structure in which the film having tensile stress is continuously formed in the first region NTr, the film having compression stress is formed in the second region PTr and the upper part of the second gate electrode is removed. 
     The manufacturing process includes the gate last structure in which the second gate electrode is displaced after removing the film having compression stress. 
     The compression stress S yy  in the “yy” direction is maintained in the NTr and the stress in the “xx” direction is efficiently increased in the PTr, thereby realizing the CMOS circuit having higher carrier mobility. 
     The tensile stress film and the compression stress film are formed by using the silicon nitride film, thereby controlling the stress flexibly. 
     The films also double as the etching stopper film (Contact Etch Stopper Liner) of the contact hole. 
     Additionally, the high-dielectric film is formed as the first and second gate insulating films and a metal or a metal compound is used for the portion touching the second gate insulating film made of the second gate electrode material, thereby allowing the effective gate oxide thickness (EOT) to be thinner as well as forming the transistor having the suitable threshold Vth. The CMOS circuit suppressing the short-channel effect can be realized as described above. 
     It is preferable that the first gate insulating film is formed by using an insulating material having a relative dielectric constant at least higher than 8.0 in the process forming the first gate insulating film and that the second gate electrode is formed by using a metal or a metal compound at the portion touching the first gate insulating film in the process forming the second gate electrode. Accordingly, the effective gate oxide thickness (EOT) can be made thinner. 
     &lt;Modification Example&gt; 
     In the above first embodiment, the first gate insulating film  15   a  and the second gate insulating film  15   b  are made of the same material. 
     However, the first gate insulating film  15   a  and the second gate insulating film  15   b  can be made of different insulating materials in accordance with necessary dielectric constant characteristics and so on. 
     In the modification example, the first gate insulating film  15   a  and the second gate insulating film  15   b  are made of different materials. 
     Processes in the modification example are the same as in the first embodiment until the process reaches the step shown in  FIG. 4C . 
     Next, as shown in  FIG. 6A , the second gate insulating film  15   b  is removed. 
     The groove for forming the second gate electrode “T” is formed in this manner. 
     Next, as shown in  FIG. 6B , at least a bottom surface of the groove for forming the second gate electrode “T” is covered as well as the inner wall thereof is covered by using, for example, the CVD (Chemical Vapor Deposition) method, the ALD (Atomic Layer Deposition) method or the like to form a second gate insulating film  36 . 
     Next, the TiN film  31  is formed to have a film thickness of 10 to 30 nm on the second gate insulating film  36  in the groove for forming the second gate electrode “T” by using, for example, the ALD method, the sputtering method, the CVD method or the like. 
     Next, the conductive layer  32  made of aluminum and the like is formed to have a film thickness of 30 to 100 nm on the TiN film  31  so as to fill the groove for forming the second gate electrode “T” by using, for example, the sputtering method and so on. 
     Next, the second gate insulating film  36 , the TiN film  31  and the conductive layer  32  deposited at the outside of the groove for forming the second gate electrode “T” are removed by performing the CMP process using the polish stopper film  30  as a stopper. 
     According to the above process, the second gate electrode having the gate-last structure made of the layered body including the TiN film  31  and the conductive layer  32  is formed, which is buried in the groove for forming the second gate electrode “T”. 
     Next, as shown in  FIG. 6C , the second insulating film  33  is formed, openings reaching the gate electrodes and the source/drain regions of the NTr and the PTr are formed, the contact plugs  34  and the upper wiring  35  are formed. 
     In the manufacturing method of the semiconductor device according to the embodiment, the carrier mobility can be increased and the high performance can be realized particularly in the micro area in which the distance between electrodes is short both in the n-channel MISFET (NTr) and the p-channel MISFET (PTr) included in the CMOS circuit. 
     It is preferable that the second gate insulating film is formed by using an insulating material having a relative dielectric constant at least higher than 8.0 in the process forming the second gate insulating film. Accordingly, the effective gate oxide thickness (EOT) can be made thinner. 
     &lt;Second Embodiment&gt; 
     [Structure of the Semiconductor Device] 
       FIG. 7  is a schematic cross-sectional view of a semiconductor device according to the embodiment. 
     In the embodiment, the second gate electrode is formed to be higher than that of the first embodiment. In addition, the polish stopper film is omitted. 
     The structure is the same as that of the semiconductor device of the first embodiment except the above. 
     [Manufacturing Method of the Semiconductor Device] 
     Processes in the embodiment are the same as in the first embodiment until the process reaches the step shown in  FIG. 2B . 
     Next, as shown in  FIG. 8A , an silicon oxide film (not shown) of approximately 1 to 3 nm is formed on the surface of the polysilicon layer  17  in, for example, the second region A 2  and a height adjustment layer  37  made of, for example, the polysilicon layer is formed to have a film thickness of 30 to 100 nm. 
     The silicon oxide film (not shown) is formed by a thermal oxidation process, the RTO processing, a plasma oxidation process and so on. 
     The height adjustment layer  37  is a layer for changing the height with respect to a first gate electrode of the NTr for polishing only the stress liner film in the PTr region at the time of the later-described CMP process. The height adjustment layer  37  can be made of amorphous silicon, silicon oxide, silicon nitride and the like. 
     The subsequent processes are performed in substantially the same manner as the first embodiment. 
     That is, as shown in  FIG. 8B , the first gate electrode made of the layered body including the titanium nitride (TiN) film  16  and the polysilicon layer  17  is formed in the first region A 1 . 
     In the second region A 2 , a second gate electrode made of a layered body and so on including the titanium nitride (TiN) film  16  and the polysilicon layer  17  and the height adjustment layer  37 . 
     Next, as shown in  FIG. 8C , the extension regions ( 18 ,  19 ), the sidewall insulating film including the silicon nitride film  20 , the silicon oxide film  21  and the silicon nitride film  22 , the source/drain regions ( 23 ,  24 ) and the high-melting point metal silicide layers ( 25 ,  26 ) are formed. 
     Next, as shown in  FIG. 9A , the first stress liner film  27  having tensile stress is formed on the whole surface of the first region A 1  and the second stress liner film  28  having compression stress is formed on the whole surface of the second region A 2 . 
     Next, silicon oxide is deposited to have a film thickness of 500 to 1500 nm by the CVD method and planarized by the CMP process to thereby form the first insulating film  29 . 
     At this time, the height adjustment layer  37  is removed and polished until the polysilicon layer  17  in the second region A 2  is exposed, thereby removing only the second stress liner film  28  in the PTr region by polishing. 
     Next, as shown in  FIG. 9B , the polysilicon layer  17  exposed in the above process and the TiN film  16  are sequentially removed. 
     Next, it is possible to remove the TiN film  16  as well as possible not to remove the TiN film  16 . The film is removed in the drawing. 
     According to the above, the groove for forming the second gate electrode “T” is formed. 
     Next, as shown in  FIG. 9C , the top of the second gate insulating film  15   b  is covered in the groove for forming the second gate electrode “T” and an inner wall of the groove for forming the second gate electrode “T” is covered to form the TiN film  31 . 
     Next, the conductive layer  32  is formed on the TiN layer  31  so as to fill the groove for forming the second electrode “T” by using, for example, the sputtering method. 
     Next, the TiN film  31  and the conductive layer  32  deposited at the outside of the groove for forming the second gate electrode “T” are removed. 
     According to the above process, the second gate electrode having the gate last structure made of a layered body including the TiN film  31  and the conductive layer  32  is formed, which is buried in the groove for forming the second gate electrode “T”. 
     Next, the second insulating film  33  is formed, openings reaching the gate electrodes and the source/drain regions of the NTr and the PTr are formed, the contact plugs  34  are formed so as to be buried and the upper wiring  35  is formed. 
     The semiconductor device according to the embodiment can be manufactured as described above. 
     In the manufacturing method of the semiconductor device according to the embodiment, the carrier mobility can be increased and the high performance can be realized particularly in the micro area in which the distance between electrodes is short both in the n-channel MISFET (NTr) and the p-channel MISFET (PTr) included in the CMOS circuit. 
     The semiconductor device according to the embodiment has the structure in which the film having tensile stress is continuously formed in the first region NTr, the film having compression stress is formed in the second region PTr and the upper part of the second gate electrode is removed. 
     The manufacturing process includes the gate last structure in which the second gate electrode is displaced after removing the film having compression stress. 
     The compression stress S yy  in the “yy” direction is maintained in the NTr and the stress in the “xx” direction is efficiently increased in the PTr, thereby realizing the CMOS circuit having higher carrier mobility. 
     The tensile stress film and the compression stress film are formed by using the silicon nitride film, thereby controlling the stress flexibly. 
     The films also double as the etching stopper film (Contact Etch Stopper Liner) of the contact hole. 
     Additionally, the high-dielectric film is formed as the first and second gate insulating films and a metal or a metal compound is used for the portion touching the second gate insulating film made of the second gate electrode material, thereby allowing the effective gate oxide thickness (EOT) to be thinner as well as forming the transistor having the suitable threshold Vth. The CMOS circuit suppressing the short-channel effect can be realized as described above. 
     As described above, in the process of removing only the film having compression stress on the part of the second gate electrode, the film can be removed by the CMP process. 
     The film can be also removed in the in a self-aligned manner by forming a higher region in advance. 
     The present disclosure is not limited to the above explanation. 
     For example, different types of stress liner films in the NTr and the PTr can be formed in the embodiment, however, it is not limited to this, and a structure of including the stress liner film common to the NTr and the PTr can be also applied. 
     In the second embodiment, it is also preferable that the second gate insulating film is removed as in the modification example of the first embodiment and the second gate insulating film having a high-dielectric constant is formed. 
     Other various modifications can be made within the scope not departing from the gist of the disclosure. 
     The present disclosure contains subject matter related to that disclosed in Japanese Priority Patent Application JP 2010-139847 filed in the Japan Patent Office on Jun. 18, 2010, the entire contents of which is hereby incorporated by reference.