Abstract:
A galvanic measuring device for detecting oxygen content in a gas flow, having a sealed gas flow chamber and a layer of sodium chloride saturated sponge material lining the interior of the gas flow chamber, for providing a constant source of humidity to the chamber.

Description:
BACKGROUND OF THE INVENTION  
         [0001]    The present invention relates to oxygen sensors, and more particularly, oxygen sensors having an internal humidification apparatus for extending the useful life of the sensor. Oxygen sensors functioning as coulometric sensors have long been useful in the test and measurement field, as for example, sensors described in U.S. Pat. No. 3,223,597 issued Dec. 14, 1965 to Hersch. Such sensors typically use a glass envelope having an inlet and an outlet to permit the flow of a gas therethrough, and an anode and cathode inside the glass envelope, exposed to the flow of the gas. Oxygen molecules in the gas cause a current flow between the cathode and anode, and the current flow is conveyed via wires to an indicator circuit, where the amount of current flow is representative of the amount of oxygen flow through the glass envelope. A solution of potassium hydroxide (KOH) is placed in the envelope, to facilitate the flow of current as described. Eventually, the KOH solution dries out inside the glass envelope, and the device must be recharged with KOH or replaced.  
           [0002]    More recently, improvements in sensitivity of instruments of this type have led to the construction of sensors having two such coulometric sensors of the type described above inside a single sealed container, and connected in series gas flow relationship. In order to extend the sensor life, the interior of the single container is at least partially filled with KOH, and the gas flow path includes a section of nafion tubing which is immersed in the KOH solution. Since nafion has the characteristic of being a barrier to oxygen and being permeable to water vapor, the presence of the section of nafion tubing allows water vapor to enter the gas flow path, and to humidify the gas flowing through the flow path. A device of this type is disclosed in U.S. Pat. No. 4,973,395, owned by the assignee of the present invention, and incorporated by reference herein.  
           [0003]    The downside to at least partially filling the sensor container with KOH, as shown in the &#39;395 patent, is that this material is hazardous and is extremely corrosive to other materials. If the sensor container should develop a leak, the KOH may leak out of the container and corrode any materials or components which might be nearby. This corrosive action could destroy the relatively expensive equipment associated with the sensing and measurement device. Therefore, there is a need to provide the relative humidity needed to conduct many measurement tests without risking the possible leakage of hazardous and corrosive liquids from within the sensor device.  
         SUMMARY OF THE INVENTION  
         [0004]    An oxygen detection device having internal humidification without the need to partially fill the inside of the detector body with hazardous and corrosive material. This is accomplished by lining the interior surface of the device with a material that is saturated with a solution including sodium chloride (NaCl), otherwise known as common table salt. The material is a liquid absorbent material such as a plastic sponge, which retains a saturated solution without creating a dripping of the solution on other interior components.  
           [0005]    It is therefore a principal object of the present invention to provide a humidification feature for coulometric detectors which does not involve the use of KOH or other hazardous and corrosive materials.  
           [0006]    Other and further objects and advantages of the invention will become apparent from the following specification and claims and with reference to the appended drawings. 
       
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS  
       [0007]    [0007]FIG. 1 shows a side cross-sectional view of a detector having the invention installed in the interior;  
         [0008]    [0008]FIG. 2 shows a top cross-sectional view orthogonal to the view of FIG. 1;  
         [0009]    [0009]FIG. 3 shows a cross-sectional view taken along the lines  3 - 3  of FIG. 1; and  
         [0010]    [0010]FIG. 4 shows a wiring diagram of the circuits formed by the invention. 
     
    
     DESCRIPTION OF THE PREFERRED EMBODIMENT  
       [0011]    Referring to the drawing figures, like reference characters refer to the same or functionally similar parts of the device illustrated in each of the figures. FIGS. 1 and 2 respectively show a side and top cross-sectional view of an enclosure  34  having a pair of galvanic cells  10   a  and  10   b  sealed within the enclosure by a plug  36 . They are supported at their inner ends by a spacer  38 .  
         [0012]    An inlet  42  is adapted for coupling to a source of test gas, and is coupled to a gas conduit  44  which passes through outer wall  43  of enclosure  34 . Gas conduit  44  sealably passes through plug  36  and is coupled to a gas humidifier  46 , which has an internal nafion tube  47 . Nafion has the characteristic that it is permeable to water, and is chemically resistant to and a barrier to KOH. Enclosure  34  also contains an oxygen getter  46   a  to remove any trace amounts of oxygen which may accumulate inside sealed enclosure  34 , particularly in the KOH solution. The name “nafion” is a trademark of the E.I. Dupont de Nemours Company.  
         [0013]    The output of nafion tube  47  is coupled to a conduit  48 , which is connected to an inlet  50  of galvanic cell  10   a . Galvanic cell  10   a  has an outlet  52  coupled to a further conduit  54  outside of the sealed portion of enclosure  34 . Conduit  54  sealably passes through plug  36 , and passes through the getter  46   a , and is connected to an inlet  56  of galvanic cell  10   b . Galvanic cell  10   b  has an outlet  58  which is coupled to a conduit  59  which passes through the outer wall  43 , and is connected to an outlet coupling  60 , adapted for connection to an exhaust circuit.  
         [0014]    An interior resilient and absorbent pad or sponge  100  is arranged around the inner periphery of enclosure  34 , inside the sealed portion of the interior. This sponge is made from a very absorbent material, and is saturated with a sodium chloride (NaCl) solution in water prior to inserting it into the enclosure  34 . This provides a continuous source of humidification for so long as any NaCl solution remains in the sponge  100 , and maintains a relatively constant relative humidity in the enclosure at about 75%. There is no excessive KOH inside the enclosure  34 , beyond the saturated condition that each of the galvanic cells normally require during the manufacturing process; therefore, there is no chance of leakage of KOH from the enclosure, even in the event it becomes cracked or broken during use.  
         [0015]    [0015]FIG. 3 shows a cross-section view taken along the lines  3 - 3  of FIG. 1. This shows the inner liner sponge  100  wrapped around the entire inside periphery of enclosure  34 .  
         [0016]    [0016]FIG. 4 shows the electrical circuit diagram of the invention, illustrating how the galvanic cells are wired to produce an output electrical signal representative of the oxygen content of the gas passing through the cells. For example, if the value of the resistances R 1  and R 2  are each selected to be 10,000 ohms (10 k) and the test gas is passed through the device at a 10 cc per minute flow rate, the useful output signal will be in the microvolt range. A one microvolt change in output voltage is equivalent to an oxygen permeability measurement of 0.0001 cc per square meter per day (cc/m 2 /day); this is approximately a concentration measurement of 36 parts per trillion. The saturated sponge contained within the sensor enclosure permits a constant control of relative humidity of the test gas, and replenishes water loss which otherwise would occur in the galvanic cells during extended periods of operation.  
         [0017]    The present invention may be embodied in other forms without departing from the spirit or essential attributes thereof; and it is, therefore, desired that the present embodiment be considered in all respects as illustrative and not restrictive, reference being made to the appended claims rather than to the foregoing description to indicate the scope of the invention.