Abstract:
According to an aspect of the present invention, there is provided a semiconductor device manufacturing method, including: preparing a support plate having a mounting portion on which a mounting terminal is mountable; preparing a circuit board having a mounting surface on which a semiconductor chip is mounted and a connection pad is formed; bringing the support plate to face the mounting surface of the circuit board, and connecting the support plate to the connection pad through the mounting terminal; forming a resin layer between the support plate and the mounting surface of the circuit board to cover the mounting terminal; and removing the support plate, thereby faulting a via in the resin layer along a shape of the mounting portion so as to expose the mounting terminal therethrough.

Description:
CROSS-REFERENCE TO RELATED APPLICATION(S) 
       [0001]    This application claims priorities from Japanese Patent Application No. 2010-260708 filed on Nov. 23, 2010, the entire contents of which are incorporated herein by reference. 
       FIELD 
       [0002]    The present invention relates to a semiconductor device manufacturing method, and a semiconductor device. 
       BACKGROUND 
       [0003]    In electronic devices such as digital cameras and portable telephones, as realization of the functions, particularly in the image processing, advances, a so-called package-on-package (POP) form is often adapted in order to use two or more semiconductor packages. In the POP form, the semiconductor packages are stacked on each other. 
         [0004]    There have been proposed various POP semiconductor packages. 
         [0005]    For example, in U.S. Pat. No. 7,777,351-B, a semiconductor package is formed such that a molding resin layer as an insulating material is formed on a top surface of a lower circuit board, conical vias are formed in the insulating material, and solder balls are supplied in the vias so as to be connected with upper connection terminals on the lower circuit board. The top surfaces of the solder balls are exposed upwardly. 
         [0006]    Alternatively, a semiconductor package may be formed such that solder balls are supplied to upper connection terminals on a lower circuit board, a molding resin layer as an insulating material is formed on the top surface of the lower circuit board to cover the solder balls, and conical vias are formed above the solder balls so as to upwardly expose the solder balls from the molding resin layer by performing a laser boring process on the molding resin layer. 
         [0007]    In order to implement a POP structure, solder balls on the bottom surface of an upper circuit board are respectively arranged in the vias of the above-mentioned lower circuit board, and solder reflow processing is performed, thereby solder-connecting the upper circuit board and the lower circuit board with each other. 
         [0008]    When the vias are formed in the lower circuit board by removing the molding resin layer with the laser boring process, it is extremely difficult to completely remove resin components from the surfaces of the solder balls. 
         [0009]    If a resin component film remains on the surfaces of the solder balls, even when the solder reflow processing is performed, the solder balls of the lower circuit board will not be surely solder-connected with the solder balls of the upper circuit board. As a result, the reliability of the electrical connection between the boards in the semiconductor package will be deteriorated. 
       SUMMARY 
       [0010]    According to an aspect of the present invention, there is provided a semiconductor device manufacturing method, including: preparing a support plate having a mounting portion on which a mounting terminal is mountable; preparing a circuit board having a mounting surface on which a semiconductor chip is mounted and a connection pad is formed; bringing the support plate to face the mounting surface of the circuit board, and connecting the support plate to the connection pad through the mounting terminal; forming a resin layer between the support plate and the mounting surface of the circuit board to cover the mounting terminal; and removing the support plate, thereby forming a via in the resin layer along a shape of the mounting portion so as to expose the mounting terminal therethrough. 
         [0011]    According to another aspect of the present invention, there is provided a semiconductor device, including: a circuit board having a mounting surface a semiconductor chip mounted on the mounting surface; a connection pad formed on the mounting surface; a mounting terminal formed on the connection pad; and a resin layer formed on the mounting surface to cover the mounting terminal, the resin layer having a via through which the mounting terminal is exposed, wherein the via is formed by removing a support plate which has abutted the mounting terminal at least when the mounting terminal was formed on the connection pad and the resin layer was formed on the mounting surface to cover the mounting terminal. 
         [0012]    According to the above-mentioned aspects of the present invention, the mounting terminal of the semiconductor device is formed by being partly exposed through a via formed in the resin layer along the shape of the solder ball mounting portion on the support plate when the support plate is removed after the solder ball is connected to the connection pad, and the resin layer is formed between the mounting surface of the circuit board and the support plate. Thus, the surface of the solder ball serving as the mounting terminal is put into a clean state when the support plate is removed. Consequently, a residue of the molding resin can be surely prevented from remaining on the surface of the solder ball. 
         [0013]    Accordingly, when a POP structure is formed by connecting the semiconductor package substrates to each other, the connection terminals thereof can surely be solder-connected to each other, thereby enhancing the reliability of the electrical connection therebetween. 
     
    
     
       BRIEF DESCRIPTION OF DRAWINGS 
         [0014]      FIG. 1  cross-sectional illustrates a semiconductor device according to a first embodiment. 
           [0015]      FIG. 2A to 2I  illustrate a method for manufacturing a semiconductor device according to the first embodiment. 
           [0016]      FIGS. 3A to 3D  illustrate a method for forming a solder ball mounting portion on a support plate. 
           [0017]      FIGS. 4A to 4C  illustrate a method for manufacturing a POP structure by stacking another circuit board on the manufactured semiconductor device. 
           [0018]      FIG. 5  cross-sectional illustrates a semiconductor device according to a second embodiment. 
           [0019]      FIGS. 6A to 6I  illustrate a method for manufacturing a semiconductor device according to the second embodiment. 
           [0020]      FIGS. 7A to 7H  illustrate a method for forming a metal plating coat on a solder ball mounting portion on a support plate. 
           [0021]      FIGS. 8A to 8D  illustrate the concept of forming a solder ball mounted on a solder ball mounting portion via a metal plating film and transferring both of them onto a connection pad side of a circuit board. 
           [0022]      FIGS. 9A to 9C  illustrate a method for manufacturing a POP structure by stacking another circuit board on the manufactured semiconductor device. 
           [0023]      FIGS. 10A to 10I  illustrate another method for manufacturing a semiconductor device according to the second embodiment. 
           [0024]      FIGS. 11A to 11D  illustrate the concept of forming a metal plating film on a support plate and transferring it onto a solder ball side of a circuit board according to another manufacturing method. 
       
    
    
     DETAILED DESCRIPTION 
       [0025]    Hereinafter, a semiconductor device according to a first embodiment is described with reference to  FIG. 1 . 
         [0026]    As illustrated in  FIG. 1 , a semiconductor device  1  according to the first embodiment has a circuit board  2 . A semiconductor chip  3  is mounted on the top surface (i.e., a semiconductor chip mounting surface) of the circuit board  2 . Two connection pads  4  are formed on both sides of the semiconductor chip  3 . A solder ball  5  is mounted on each connection pad  4 . 
         [0027]    A molding resin layer  7  is formed on the top surface of the circuit board  2  so as to cover the semiconductor chip  3  and to upwardly expose the solder balls  5  through vias  6 , respectively. The top surfaces of the solder balls  5  are put into a clean state when a copper support plate (to be described below) is removed by etching. Thus, there is no resin residue of the molding resin layer  7 . 
         [0028]    Plural connection terminals  8  are formed on the bottom surface of the circuit hoard  2 . A solder ball  9  is mounted on each connection terminal  8 . 
         [0029]    Next, a manufacturing method for the above-mentioned semiconductor device  1  is described hereinafter with reference to  FIGS. 2A to 4C . 
         [0030]    Referring to  FIGS. 2A to 2I , first, a solder ball mounting portion  11 , on which the solder ball  5  is to be mounted, is formed on a copper support plate  10  (see  FIG. 2A ). A method for forming the solder ball mounting portion  11  is described in detail with reference to  FIGS. 3A to 3D . 
         [0031]    First, a copper thin plate K is prepared as illustrated in  FIG. 3A , and a photoresist film  12  is formed entirely on the top surface of the copper thin plate K as illustrated in  FIG. 3B . Then, the photoresist film  12  is partially covered with a mask to open the part other than a part corresponding to each solder ball mounting portion  11 , and the exposure and development are performed as normal. Consequently, as illustrated in  FIG. 3C , only the part of the copper thin plate K, which corresponds to each solder ball mounting portion  11 , is covered with the photoresist film  12 . 
         [0032]    Then, a so-called “half etching” is performed by immersing the copper thin plate K in copper etching solution. Consequently, the non-covered parts of the copper thin plate K are etched to be thin, while the covered parts of the copper thin plate K corresponding to the solder ball mounting portions  11  are maintained. Then, the resist film  12  is peeled. Thus, as illustrated in  FIG. 3D , the copper support plate  10  having the solder ball mounting portions  11  is formed from the copper thin plate K. 
         [0033]    Turning back to  FIG. 2B , after the solder ball mounting portions  11  are formed on the copper support plate  10 , a solder ball  5  is mounted on each solder ball mounting portion  11  by performing solder reflowing. 
         [0034]    Then, flip chip mounting is performed on the circuit board  2  (see  FIG. 2C ), so that semiconductor chips  3  are mounted on the top surface of the circuit board  2  (see  FIG. 2D ). 
         [0035]    The copper support plate  10  is faced to the circuit board  2  so that the solder balls  5  respectively abut the connection pads  4 , and solder reflowing is performed to thereby respectively solder-connect the solder balls  5  to the connection pads  4 , as illustrated in  FIG. 2E . 
         [0036]    Then, as illustrated in  FIG. 2F , the space between the mounting surface of the circuit board  2  and the copper support plate  10  is filled with epoxy resin by a so-called transfer molding method. Thus, the molding resin layer  7  is formed. 
         [0037]    Thereafter, etching is performed using, e.g., alkali etchant (manufactured by Meltex Incorporated (trade name is “A Process”) to selectively remove only the copper support plate  10  (see  FIG. 2G )). 
         [0038]    In this state, the vias  6  are formed in the molding resin layer  7  along the shapes of the solder ball mounting portions  11  formed on the copper support plate  10 . 
         [0039]    Further, the top surfaces of the solder balls  5  are brought into a clean state by the etchant when the copper support plate  10  is removed by etching, and there is no resin residue of the molding resin layer  7 . 
         [0040]    Solder reflowing may be additionally performed. Then, a solder ball  9  is mounted on each connection terminal  8  formed on the bottom surface of the circuit board  2 , as illustrated in  FIG. 2H . 
         [0041]    Then, the circuit board  2  is cut at positions P illustrated in  FIG. 2I  via a blade into individual separated pieces, thereby manufacturing individual separated semiconductor devices  1 . In each semiconductor device  1 , the top portion of the solder hall  5 , which is exposed from each via  6  formed in the molding resin layer  7 , functions as a mounting terminal for connecting other circuit boards and the like. 
         [0042]    As illustrated in  FIGS. 4A to 4C , another package substrate  13  is stacked on the above-mentioned semiconductor device  1 , thereby forming a POP structure. 
         [0043]    Hereinafter, a method for stacking another package substrate  13  on the semiconductor device  1  is described with reference to  FIGS. 4A to 4C . 
         [0044]    As illustrated in  FIGS. 4A to 4C , a solder ball  14  is mounted on each connection terminal formed on the bottom surface of the package substrate  13 . First, as illustrated in  FIG. 4A , the solder balls  14  on the package substrate  13  are faced to the solder balls  5  on the semiconductor device  1 , respectively. And, as illustrated in  FIG. 4B , the solder balls  14  are arranged in the vias  6  from which the solder balls  5  are exposed, respectively. Thus, the package substrate  13  is pre-stacked on the semiconductor device  1 . 
         [0045]    Then, the solder reflowing is performed so that the solder balls  14  on the package substrate  13  and the solder balls  5  on the semiconductor device  1  are respectively melt-connected to each other, as illustrated in  FIG. 4C . 
         [0046]    On this occasion, the solder balls  14  on the package substrate  13  can easily be arranged in the respective vias  6  formed in the molding resin layer  7  of the semiconductor device  1  because the inverted-cone-like vias  6  expose the respective solder balls  5 . Consequently, the package substrate  13  can be mounted easily and surely on the semiconductor device  1 . 
         [0047]    According to the first embodiment, when the copper support plate  10  is removed by etching, the top portion of each solder ball  5 , which is exposed from an associated one of the vias  6  formed in the molding resin layer  7  of the semiconductor device  1 , is maintained in a clean state in which no residue of the molding resin layer  7  remains. Consequently, the wettability of each solder ball  5  is enhanced. Thus, the solder balls  5  and the solder balls  14  are surely connected, respectively, and the electrical connection between the semiconductor device  1  and the package substrate  13  is enhanced. 
         [0048]    Next, a semiconductor device according to a second embodiment is described hereinafter with reference to  FIGS. 5 to 9C . 
         [0049]    As illustrated in  FIG. 5 , a semiconductor device  21  according to the second embodiment has a circuit board  22 . A semiconductor chip  23  is mounted on the top surface (i.e., a semiconductor chip mounting surface) of the circuit board  22 . Two connection pads  24  are formed on both sides of the semiconductor chip  23 . A solder ball  25  is mounted on each connection pad  24 . 
         [0050]    A molding resin layer  27  is formed on the top surface of the circuit board  22  so as to cover the semiconductor chip  23  and to upwardly expose the solder balls  25  through vias  26 , respectively. A metal plating film M formed by a method to be described below is formed on and covers the top surface of each solder ball  25  exposed from an associated one of the vias  26  formed in the molding resin layer  27 . 
         [0051]    Plural connection terminals  28  are formed on the bottom surface of the circuit board  22 . A solder ball  29  is mounted on each connection terminal  28 . 
         [0052]    Next, a manufacturing method for the above-mentioned semiconductor device  2  is described hereinafter with reference to  FIGS. 6A to 8D . 
         [0053]    Referring to  FIGS. 6A to 6I , first, a solder ball mounting portion  31 , on which the solder ball  25  is to be mounted, is formed on a copper support plate  30  (see  FIG. 6A ). The metal plating films M are formed to cover the top surfaces of the solder ball mounting portions  31 , respectively. A method for forming such a solder ball mounting portion  31 , and a method for forming metal plating film M on the solder ball mounting portion  31  are described in detail with reference to  FIGS. 7A to 7H . 
         [0054]    First, a copper thin plate K is prepared as illustrated in  FIG. 7A , and a photoresist film  32  is formed entirely on the top surface of the copper thin plate K as illustrated in  FIG. 7B . Then, the photoresist film  32  is partially covered with a mask to open the part other than a part corresponding to each solder ball mounting portion  31 , and the exposure and development are performed as normal. Consequently, as illustrated in  FIG. 7C , only the part of the copper thin plate K, which corresponds to each solder ball mounting portion  31 , is covered with the photoresist film  32 . 
         [0055]    Then, a so-called “half etching” is performed by immersing the copper thin plate K in copper etching solution. Consequently, the non-covered parts of the copper thin plate K are etched to be thin, while the covered parts of the copper thin plate K corresponding to the solder ball mounting portions  31  are maintained. Then, the resist film  32  is peeled. Thus, as illustrated in  FIG. 7D , the copper support plate  30  having the solder ball mounting portions  31  is formed from the copper thin plate K. 
         [0056]    Next, as illustrated in  FIG. 7E , an electrodeposited resist film  33  prepared from acrylic polymer is formed on the entire surface of the copper support plate  30 . Then, the top surface of the copper support plate  30 , on which the solder ball mounting portions  31  are formed, is covered with a mask, and the exposure and development are performed as normal. Consequently, as illustrated in  FIG. 7F , an opening  34  is fowled in the electrodeposited resist film  33  correspondingly with the solder ball mounting portions  31 . 
         [0057]    Then, as illustrated in  FIG. 7G , the metal plating film M is formed on each solder hall mounting portion  31  through the opening  34 . The metal plating film M have a four layer structure formed of a gold plating film M 1 , a palladium plating film M 2 . a nickel plating film M 3 . and a palladium plating film M 4  arranged in this order outwardly from the side of the solder ball mounting portion  31  (see  FIGS. 8A to 8D ). 
         [0058]    In order to form such a metal plating film M, first, the copper support plate  30 , on which the electrodeposited resist film  33  having the opening  34  is formed, is immersed in a gold plating bath for a given time. 
         [0059]    A plating solution retained in the gold plating bath is made up of 50 grams (g)/liter (l) of potassium citrate, and 50 g/l of tripotassium citrate. 
         [0060]    Consequently, a first layer formed of a gold plating film M 1  is formed on the solder ball mounting portion  31 . 
         [0061]    Next, the copper support plate  30  with the gold plating film M 1  is immersed in a palladium plating bath for a given time. A plating solution retained in the palladium plating bath is made up of 150 g/l of potassium phosphate, and 15 of Pd(NH 3 ) 4 Cl 2 . 
         [0062]    Consequently, a second layer formed of a palladium plating film M 2  is formed on the gold plating film M 1 . 
         [0063]    Next, the copper support plate  30  with the gold plating film M 1  and the palladium plating film M 2  is immersed in a nickel plating bath for a given time. 
         [0064]    A plating solution retained in the nickel plating bath is made up of 320 g/l of nickel sulphamate. 
         [0065]    Consequently, a third layer formed of a nickel plating film M 3  is formed on the palladium plating film M 2 . 
         [0066]    Finally, the copper support plate  30  with the first layer, i.e., the gold plating film M 1 , the second layer, i.e., the palladium plating film M 2 , and the third layer, i.e., the nickel plating film M 3  is immersed in a palladium plating bath for a given time. 
         [0067]    A plating solution retained in this palladium plating bath is made up of 150 g/l of potassium phosphate, and 15 g/l of Pd(NH 3 ) 4 Cl 2 . 
         [0068]    Consequently, a fourth layer formed of a palladium plating film M 4  is formed on the nickel plating film M 3 . 
         [0069]    After the metal plating film M configured by the gold plating film M 1 , the palladium plating film M 2 , the nickel plating film M 3  and the palladium plating film M 4  is formed on the solder ball mounting portion  31 , the electrodeposited resist film  33  is removed by etching. Thus, the copper support plate  30  in which the metal plating films M are respectively formed on the solder ball mounting portions  31  is obtained, as illustrated in  FIG. 7H . 
         [0070]    Turning back to  FIG. 6B , after the solder ball mounting portions  31  each having the metal plating film M are formed on the copper support plate  30 , a solder ball  25  is mounted on each solder ball mounting portion  31  by performing solder reflowing. 
         [0071]    In the copper support plate  30 , as shown in  FIG. 8A , the metal plating film M initially has the four layer structure formed of the gold plating film M 1 , the palladium plating film M 2 , the nickel plating film M 3 , and the palladium plating film M 4  arranged from the side of the solder ball mounting portion  31 . And, the solder reflowing is performed by melting the solder balls  25  at a temperature equal to or higher than the melting point, as illustrated in  FIG. 8B . Consequently, a solder alloy of the solder ball  25  and the nickel plating film M 3  is formed. The outermost palladium plating film M 4  is formed at the time of reflowing in order not only to prevent the oxidation of the nickel plating film M 3 , but also to contribute to the enhancement of wettability when being melt into the solder alloy. After the solder alloy is formed, the gold plating film M 1  and the palladium plating film M 2  maintain a two layer structure without change, and serves to prevent the oxidation of a nickel alloy. 
         [0072]    Then, flip chip mounting is performed on the circuit board  22  (see  FIG. 6C ), so that semiconductor chips  23  are mounted on the top surface of the circuit board  22  (see  FIG. 6D ). 
         [0073]    The copper support portion  30  is faced to the circuit board  22  so that the solder balls  25  respectively abut the connection pads  24 , and solder reflowing is performed to thereby respectively solder-connect the solder balls  25  to the connection pads  24 , as illustrated in  FIG. 6E . 
         [0074]    Then, as illustrated in  FIG. 6F , the space between the mounting surface of the circuit board  22  and the copper support plate  30  is filled with epoxy resin by a so-called transfer molding method. Thus, the molding resin layer  27  is formed.  FIG. 8C  schematically illustrates this state. In  FIG. 8C , illustration of the connection pad  24  is omitted. 
         [0075]    Thereafter, etching is performed using, e.g., alkali etchant (manufactured by Meltex Incorporated (trade name is “A Process”) to selectively remove only the copper support plate  30  (see  FIG. 6G )). 
         [0076]    At that time, as illustrated in  FIG. 8D , only the copper support plate  30  is removed by etching. The gold plating film M 1  and the palladium plating film M 2  that are formed on the solder ball mounting portion  31  maintain the two layer structure and remain at the side of the solder ball  25  so that the outer surfaces of the gold plating film M 1  are respectively exposed from the vias  26  formed in the molding resin layer  27 . When the copper support plate  30  is removed by etching, the surface of each gold plating film M 1  is put into a clean state by etchant. Thus, there is no resin residue of the molding resin layer  27 . Also in  FIG. 8D , illustration of the connection pad  24  is omitted. 
         [0077]    Solder reflowing may be additionally performed. Then, a solder ball  29  may be mounted on each connection terminal  28  formed on the bottom surface of the circuit board  22 , as illustrated in  FIG. 6H . 
         [0078]    Then, the circuit board  22  is cut at positions P illustrated in  FIG. 6I  via a blade into individual separated pieces, thereby manufacturing individual separated semiconductor devices  21 . In each semiconductor device  21 , the gold plating film M 1  exposed from each via  26  formed in the molding resin layer  27  functions as a mounting terminal for connecting other circuit boards and the like. 
         [0079]    As illustrated in  FIGS. 9A to 9C , another package substrate  33  is stacked on the above-mentioned semiconductor device  21 , thereby forming a POP structure. 
         [0080]    Hereinafter, a method for stacking another package substrate  33  on the semiconductor device  21  is described with reference to  FIGS. 9A to 9C . 
         [0081]    As illustrated in  FIGS. 9A to 9C , a solder ball  34  is mounted on each connection terminal formed on the bottom surface of the package substrate  33 . First, as illustrated in  FIG. 9A , the solder balls  34  on the package substrate  33  are faced to the gold plating films M 1  on the semiconductor device  21 , respectively. And, as illustrated in  FIG. 9B  the solder balls  34  are arranged in the vias  26  from which the gold plating films M 1  formed on the top surfaces of the solder balls  25  are exposed. Thus, the package substrate  33  is pre-stacked on the semiconductor device  21 . 
         [0082]    Then, the solder reflowing is performed so that the solder balls  34  on the package substrate  33  and the solder balls  25  on the semiconductor device  21  are respectively melt-connected to each other with the gold plating film M 1  and the nickel plating film M 2 , as illustrated in  FIG. 9C . 
         [0083]    On this occasion, the solder balls  34  on the package substrate  33  can easily be arranged in the respective vias  26  formed in the molding resin layer  27  of the semiconductor device  21  because the inverted-cone-like vias  26  expose the respective solder balls  25 . Consequently, the package substrate  33  can be mounted easily and surely on the semiconductor device  21 . 
         [0084]    According to the second embodiment, the metal plating film M having at least three layers of the gold plating film M 1 , the nickel plating film M 2 , and the palladium plating film M 3  are formed on the solder ball mounting portions  31 . In addition, after the copper support plate  30  is removed by etching, the metal plating films M remain at the side of the solder balls  25 . The nickel plating film M 2  and the gold plating film M 1  formed on the top portion of each solder ball  25 , which is exposed from an associated one of the vias  26  formed in the molding resin layer  27 , is maintained in a clean state in which there is no residue of the molding resin layer  27 , when the copper support plate  30  is subjected to etching. Consequently, the wettability of each solder ball  25  is enhanced. Thus, the solder balls  25  and the solder balls  34  are surely connected, respectively, and the electrical connection between the semiconductor device  21  and the package substrate  33  is enhanced. 
         [0085]    The above-described embodiments are not limited to the above-described devices/methods as they are, and various improvements and modifications can be made without departing from the scope of the invention. 
         [0086]    For example, in the second embodiment, the metal plating films M (each having the four layer structure formed of the gold plating film M 1 , the palladium plating film M 2 , the nickel plating film M 3 , and the palladium plating film M 4 ) are respectively formed on the solder ball mounting portions  31  of the copper support plate  30 . After the solder balls  25  are connected to the metal plating films M by solder reflowing (see  FIGS. 6A and 6B ), the solder balls  25  are connected to the connection pads  24  on the circuit board  22  (see  FIG. 6E ). However, the manufacturing method according to the invention is not limited thereto. The method illustrated in  FIGS. 10A to 10I  can be employed. 
         [0087]    As illustrated in  FIGS. 10A to 10I , the metal plating films M (each having the four layer structure formed of the gold plating film M 1 , the palladium plating film M 2 , the nickel plating film M 3 , and the palladium plating film M 4 ) are respectively formed on the solder ball mounting portions  31  of the copper support plate  30  (see  FIG. 10A ). Then. each solder ball  25  is mounted on and connected to an associated connection pad  24  formed on the circuit board  22  through solder reflowing (see  FIG. 10D ). Thereafter, each solder ball mounting portion  31  formed on the copper support plate  30  is connected to an associated solder ball  25  by solder reflowing (see  FIG. 10E ). 
         [0088]      FIGS. 11A to 11D  schematically illustrate the above method. In  FIGS. 11A to 11D , illustration of the connection pad  24  is omitted. As illustrated in  FIG. 11A , the metal plating film M formed on the copper support plate  30  initially has the four layer structure formed of the gold plating film M 1 , the palladium plating film M 2 , the nickel plating film M 3 , and the palladium plating film M 4  arranged from the side of the solder ball mounting portion  31 . After the metal plating film M formed on the solder bah mounting portion  31  of the copper support plate  30  is connected to the solder ball  25  formed on the circuit board  22 , as illustrated in  FIG. 11B , the solder ball  25  is melted at a temperature equal to or higher than the melting point and subjected to solder reflowing. Thus, a solder alloy of the solder ball  25 , the outermost palladium plating film M 4 , and the next nickel plating film M 3  is formed, while the palladium plating film M 2  and the gold plating film M 1  maintain their structure without change. 
         [0089]    In addition, according to the so-called transfer molding method, the space between the mounting surface of the circuit board  22  and the copper support plate  30  is tilled with epoxy resin. Thus, the molding resin layer  27  is formed (see  FIG. 11C ). Thereafter, etching is performed with alkali etchant to selectively remove only the copper support plate  30  ( FIG. 11D ). Thus, only the copper support plate  30  is removed by etching. The gold plating film M 1  and the palladium plating film M 2  formed on the solder ball mounting portion  31  maintain a two layer structure and remain at the side of the solder ball  25 . A surface of the gold plating film M 1  existing on an outer side of the plating film M is exposed from each via  26  formed in the molding resin layer  27  and put into a clean state by etchant when the copper support plate  30  is removed by etching. Thus, there is no residue of the molding resin layer  7 . And, the wettability of each solder ball  25  is enhanced. Thus, the solder balls  25  and the solder balls  34  are surely connected, respectively, and the electrical connection between the semiconductor device  21  and the package substrate  33  is enhanced. 
         [0090]    The semiconductor device  21  and the manufacturing method therefor illustrated in  FIGS. 10A to 11D  are similar to those according to the second embodiment except the above-mentioned differences. Thus, the description of similar respects therebetween is omitted. 
         [0091]    In the first and second embodiments, the solder balls  9 ,  29  are mounted on the connection terminals  8 ,  28  formed on the bottom surface of the circuit board  2 ,  22 , respectively. However, if the semiconductor devices  1  and  21  are used in a land grid array (LGA) structure, it is unnecessary that the solder balls  9  and  29  are mounted on the connection terminals  8  and  28 , respectively. 
         [0092]    According to the first and second embodiments, the semiconductor chips  3 ,  23  are mounted on the circuit boards  2 ,  22  by flip chip mounting. The cases to which the first and second embodiments can be applied are not limited thereto. The first and second embodiments can be applied to the cases where the semiconductor chip is connected to the circuit hoard by wire bonding, and where the semiconductor device of the so-called chip stack type, in which two semiconductor chips are respectively stacked at upper and lower positions, is configured so that the upper semiconductor chip is mounted on the circuit board by wire bonding, and that the lower semiconductor chip is mounted thereon by flip chip mounting. 
         [0093]    According to the first and second embodiments, the metal plating film M has the four layer structure formed of the gold plating film M 1 , the palladium plating film M 2 , the nickel plating film M 3 , and the palladium plating film M 4 . The structure of the metal plating film M is not limited thereto. The metal plating film M may have a three layer structure formed of e.g., a set of a gold plating film, a nickel plating film, and a palladium plating film, or a set of a gold plating film, a palladium plating film, and a gold plating film. 
         [0094]    According to the first and second embodiments, the metal plating film is formed by plating. However, for example, the metal film may be formed by another method such as sputtering. 
         [0095]    According to the first and second embodiments, the solder balls  5 ,  25  are formed as the mounting terminals on the copper support plate  10 ,  30  or on the circuit board  22  (connection pad  24 ) by solder reflowing. However, instead of the solder balls, mounting terminals may be formed, for example, by printing solder paste on the connection pad  24 . 
         [0096]    Instead of the solder balls  5 ,  25 , Cu-core solder balls (solder coated Cu balls) may be used.