Abstract:
A semiconductor workpiece cleaning apparatus comprises a cleaning means of a semiconductor workpiece by use of cleaning liquid, charging means of drying liquid, and discharging means of the cleaning liquid. The cleaning means cleans the workpiece by spraying chemical liquid and/or pure water in a chamber, and/or by immersing the workpiece in the chemical liquid and/or pure water. The charging means takes in drying chemical liquid or vapor into contact with the processing chemical liquid or pure water in which the semiconductor workpiece is immersed. The discharging means discharges the processing chemical liquid or pure water interfaced by the processing chemical liquid or pure water.

Description:
This application is a Division of application Ser. No. 08/857,364 Filed on May 15, 1997, and now U.S. Pat. No. 6,145,519. 
    
    
     BACKGROUND OF THE INVENTION 
     1. Technical Field 
     The present invention relates to a semiconductor workpiece cleaning method and apparatus and, more particularly, to a semiconductor workpiece cleaning method and apparatus to be adopted or installed in a semiconductor wafer processing line to clean a semiconductor workpiece. 
     2. Background Art 
     The importance of a semiconductor workpiece cleaning process in a semiconductor device fabricating process has been increased with the fine-structured semiconductor devices. Recently, single-tank cleaning apparatus which carries out a plurality of chemical cleaning processes in one tank has often been used to reduce floor space (footprint) necessary for installing the cleaning apparatus. 
     Wet semiconductor workpiece cleaning apparatuses are classified roughly into immersion cleaning apparatuses which immerse a workpiece in a chemical liquid for cleaning, and spray cleaning apparatuses which spray a chemical liquid on the workpiece for cleaning. 
     A conventional single-tank dip type cleaning apparatus will be described with reference to FIG.  7 . In this conventional cleaning apparatus, a workpiece  2  is held fixedly on guide members  3  in a chamber  1  defined by a vessel, and a cleaning chemical liquid or pure water is supplied into the chamber  1  through a lower part of the vessel, and discharged from the chamber  1  through an upper part of the vessel to clean the workpiece  2 . Hot pure water and cold pure water are mixed in a line  4   a  to supply pure water of a predetermined temperature at a predetermined flow rate into the chamber  1 . The chemical liquid is supplied from a chemical liquid supply unit  4   b  to the line  4   a , so that the chemical liquid can be supplied into the chamber  1  simultaneously with pure water. 
     In this cleaning apparatus, pure water contained in the chamber  1  needs to be replaced with the chemical liquid to immerse the workpiece  2  in the chemical liquid. The chemical liquid contained in the chamber  1  needs to be replaced with pure water for water rinsing after the workpiece  2  has been immersed in the chemical liquid. The process of replacing pure water with the chemical liquid and the process of replacing the chemical liquid with pure water take much time. In particular, the water rinsing process subsequent to the dipping process of immersing the workpiece in the chemical liquid takes considerable time to restore the resistivity of the rinsing water, which reduces processing efficiency (throughput) of the process. 
     A conventional single-tank spray type cleaning apparatus will be described with reference to FIG.  8 . In this single-tank spray type cleaning apparatus, a workpiece  2  is held by guide members  3  and is turned, and a nozzle  4  sprays a cleaning liquid  5  on the workpiece  2  for cleaning. This single-tank spray type cleaning apparatus, as compared with the single-tank dip type cleaning apparatus, can easily be changed from a chemical cleaning process to a water rinsing process, and hence the throughput of the single-tank spray type cleaning apparatus is higher than that of the single-tank dip type cleaning apparatus. However, when the workpiece is rotated to spin-dry the same after the last rinsing process, water marks, i.e., stains, are formed on the surfaces of the workpiece. Water marks formed on the workpiece affect adversely to the characteristics of a device fabricated by processing the workpiece, and reduce the yield of the device production system remarkably. Thus, formation of water marks on the workpiece is a problem in the spray type cleaning apparatus. 
     There has been no single-tank cleaning apparatus provided with a single tank in which a plurality of chemical liquids are used for cleaning, and capable of cleaning workpieces at a high throughput and of cleaning the workpieces without forming water marks thereon. 
     As mentioned above, the conventional semiconductor workpiece cleaning apparatuses require much time for cleaning, and are inefficient, and form water marks on the workpieces during drying after cleaning. 
     SUMMARY OF THE INVENTION 
     Accordingly, the objects of the present invention are to solve the above problems, and to provide a semiconductor workpiece cleaning method and apparatus capable of efficiently cleaning semiconductor workpieces, and of preventing the formation of water marks on the semiconductor workpieces. 
     According to one aspect of the present invention, a semiconductor workpiece cleaning apparatus comprises a cleaning means of a semiconductor workpiece by use of chemical liquid or pure water, charging means of drying liquid, and discharging means of the cleaning liquid. The cleaning means cleans the workpiece by spraying processing chemical liquid and/or pure water in a chamber, and/or by immersing the workpiece in the processing chemical liquid and/or pure water. The charging means takes in drying chemical liquid or vapour into contact with the processing chemical liquid or pure water in which the semiconductor workpiece is immersed. The discharging means discharges the processing chemical liquid or pure water interfaced by the processing chemical liquid or pure water. 
     In another aspect of the present invention, in the semiconductor workpiece cleaning apparatus, the processing chemical liquid and/or pure water is sprayed to clean the semiconductor workpiece, and then other processing chemical liquid is supplied into the chamber to immerse the semiconductor workpiece. 
     In another aspect of the present invention, in the semiconductor workpiece cleaning apparatus, the processing chemical liquid or pure water is supplied into and discharged from the chamber through a lower part of the chamber. 
     In another aspect of the present invention, in the semiconductor workpiece cleaning apparatus, the semiconductor workpiece is inverted when the lower half of the semiconductor workpiece is immersed in the processing chemical liquid while the processing chemical liquid is being supplied into the chamber. Then, the processing chemical liquid is further supplied into the chamber. 
     In another aspect of the present invention, in the semiconductor workpiece cleaning apparatus, the drying chemical liquid is supplied through an upper part of the chamber, and the drying chemical liquid forms a boundary layer which separates an upper gas phase from a lower liquid phase when the drying chemical liquid comes into contact with or dissolves in the processing chemical liquid or pure water. 
     In another aspect of the present invention, in the semiconductor workpiece cleaning apparatus, the drying chemical vapor is supplied through an upper part of the chamber so that the drying chemical vapor dissolves or condenses in a surface layer of the processing chemical liquid or pure water to form a blocking boundary layer in the processing chemical liquid or pure water. Preferably, the thickness of the blocking boundary layer is greater than the wave height of surface waves of the processing chemical liquid or the pure water. Further, preferably the thickness of the blocking boundary layer is 2 mm or more. 
     In another aspect of the present invention, in the semiconductor workpiece cleaning apparatus, the drying chemical liquid is supplied into the chamber through a lower part of the chamber to replace the processing chemical liquid or pure water in which the semiconductor workpiece is immersed with the drying chemical liquid. 
     In another aspect of the present invention, in the semiconductor workpiece cleaning apparatus, the processing chemical liquid is selected from a group of mixed liquid prepared by mixing ammonia, hydrogen peroxide and water; hydrochloric acid, hydrogen peroxide and water; sulfuric acid, hydrogen peroxide and water; hydrofluoric acid and water; hydrofluoric acid, hydrogen peroxide and water; hydrofluoric acid, ammonium fluoride and water (buffered hydrofluoric acid); or ozone and water; or electrolytic ionic water. 
     In another aspect of the present invention, in the semiconductor workpiece cleaning apparatus, the processing chemical liquid is selected from a group of mixed liquid prepared by mixing hydrofluoric acid and water; hydrofluoric acid, hydrogen peroxide and water; or hydrofluoric acid, ammonium fluoride and water (buffered hydrofluoric acid), and the processing chemical liquid is used for oxide film removal. 
     In another aspect of the present invention, in the semiconductor workpiece cleaning apparatus, the drying chemical liquid is isopropyl alcohol or the product “FLUORINERT”, which is a registered trademark for an inert liquid of the fluorine group owned by 3M Company. 
     In another aspect of the present invention, in the semiconductor workpiece cleaning apparatus, the chamber is provided with one or a plurality of nozzles for spraying the processing chemical liquid or pure water. 
     In another aspect of the present invention, in the semiconductor workpiece cleaning apparatus, the spraying direction of the nozzle or nozzles is varied while spraying the processing chemical liquid or pure water. 
     In another aspect of the present invention, in the semiconductor workpiece cleaning apparatus, the semiconductor workpiece held within the chamber are turned while the processing chemical liquid or the pure water is sprayed. 
     In another aspect of the present invention, in the semiconductor workpiece cleaning apparatus, different processing chemical liquids or water are sprayed on the workpiece sequentially through the nozzle or nozzles within the chamber. 
     In another aspect of the present invention, the semiconductor workpiece cleaning apparatus further comprises a means for heating the processing chemical liquid or pure water to be supplied into the chamber at a predetermined temperature, or means for regulating the concentration of the processing chemical liquid. 
     In another aspect of the present invention, the semiconductor workpiece cleaning apparatus further comprises a temperature regulating means for regulating the temperature of the interior of the chamber. 
     In another aspect of the present invention, the semiconductor workpiece cleaning apparatus further comprises a returning means for recovering the processing chemical liquid discharged from the chamber and returning the same into the chamber. 
     In another aspect of the present invention, the semiconductor workpiece cleaning apparatus further comprises a megasonic oscillation means disposed at the chamber. 
     In another aspect of the present invention, in the semiconductor workpiece cleaning apparatus, the megasonic oscillation means is disposed at a portion of the chamber, and the semiconductor workpiece are turned to exert megasonic effect on the entire semiconductor workpiece. 
     According to another aspect of the present invention, a semiconductor workpiece cleaning method is characterized in the way as performed in each of the above cleaning apparatuses. 
     In another aspect of the present invention, the semiconductor workpiece cleaning method is performed by using either one of the cleaning apparatuses as explained above. 
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS 
     A more complete appreciation of the invention and many of the attendant advantages thereof will be readily obtained as the same becomes better understood by reference to the following detailed description when considered in connection with the accompanying drawings, wherein: 
     FIGS.  1 ( a ),  1 ( b ) and  1 ( c ) are conceptional views for explaining a semiconductor workpiece cleaning apparatus in a first embodiment according to the present invention. 
     FIGS.  2 ( a ),  2 ( b ),  2 ( c ) and  2 ( d ) are conceptional views for explaining a semiconductor workpiece cleaning apparatus in a second embodiment according to the present invention. 
     FIG. 3 is a conceptionl view for explaining a semiconductor workpiece cleaning apparatus in a third embodiment according to the present invention. 
     FIGS.  4 ( a ),  4 ( b ) and  4 ( c ) are conceptional views for explaining a semiconductor workpiece cleaning apparatus in a fourth embodiment according to the present invention. 
     FIG. 5 is a typical view for explaining a semiconductor workpiece cleaning apparatus in a fifth embodiment according to the present invention. 
     FIGS.  6 ( a ) and  6 ( b ) are conceptional views for explaining a semiconductor workpiece cleaning apparatus in a sixth embodiment according to the present invention. 
     FIG. 7 is a conceptional view of a conventional single-tank dip type cleaning apparatus. 
     FIG. 8 is a conceptional view of a conventional single-tank spray type cleaning apparatus. 
    
    
     DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS 
     Referring now to the drawings, wherein like reference numerals designate identical or corresponding parts throughout the several views, first through sixth embodiments of the present invention are next described. 
     First Embodiment 
     FIGS.  1 ( a ),  1 ( b ) and  1 ( c ) are conceptional views explaining a semiconductor workpiece cleaning method and apparatus in a first embodiment according to the present invention. 
     Shown in FIG.  1 ( a ), is a casetteless semiconductor workpiece cleaning apparatus, which holds a semiconductor wafer  2 , i.e., a semiconductor workpiece to be cleaned, in a vertical position by guide members  3 , rotates the semiconductor wafer  2  in a chamber  1 , and sprays a cleaning liquid or pure water  5  on the semiconductor wafer  2  by a nozzle  4  to clean the semiconductor wafer  2 . The guide members  3  are rotated to rotate the wafer  2 , a first processing chemical liquid (first cleaning liquid) prepared by mixing sulfuric acid, hydrogen peroxide and water is sprayed by the nozzle  4  on the wafer  2  to remove organic substances and the like from the wafer  2 . Then, pure water is sprayed on the wafer  2  for rinsing. Then, a second cleaning liquid prepared by mixing ammonia, hydrogen peroxide and water is sprayed on the wafer  2  to remove particles, and then pure water is sprayed on the wafer  2  for rinsing. Then, a third cleaning liquid prepared by mixing hydrochloric acid, hydrogen peroxide and water is sprayed on the wafer  2  to remove metallic contaminants and the pure water is sprayed for rinsing. 
     Then, as shown in FIG.  1 ( b ), a hydrofluoric acid solution  6 , i.e., a processing chemical liquid, is supplied through a lower part of the chamber  1  into the chamber  1  to fill up the chamber  1  with the hydrofluoric acid solution for final cleaning to remove an oxide film formed by natural oxidation. Pure water  9  is supplied through the lower part of the chamber  1  into the chamber  1  to replace the hydrofluoric acid solution for rinsing. After the chamber  1  has been filled up with the pure water  9 , a drying process is started. 
     As shown in FIG.  1 ( c ), an isopropyl alcohol vapor (IPA vapor)  7 , i.e., a drying chemical vapor, is supplied for drying through an upper part of the chamber  1  into the chamber  1  filled up with the pure water  9 . The IPA vapor  7  supplied into an upper portion of the chamber  1  comes into contact with the pure water  9 , the IPA vapor  7  dissolves in the pure water  9  or condenses and an IPA/pure water boundary layer  8  is formed. The boundary layer  8  separates the pure water  9  from a gas phase, i.e., the IPA vapor  7 , prevailing over the boundary layer  8 . Consequently, the pure water  9  is isolated from the ambient gas (ambient air, ambient atmosphere or the atmosphere). 
     While the IPA vapor  7  is supplied through the upper part of the chamber  1  into the chamber  1 , the pure water  9  is drained through a lower part of the chamber  1  at a rate which enables the maintenance of the boundary layer  8 . After the pure water  9  has completely been drained from the chamber  1 , nitrogen gas (N2) is supplied through an upper part of the chamber  1  into the chamber  1  to purge the chamber  1  of the IPA vapor. Thus, the gas (ambient air, ambient atmosphere or the atmosphere) and the liquid (pure water) can perfectly be separated from each other during drying, so that the wafer  2  can be cleaned and dried without forming any water mark thereon. 
     Workpieces to be cleaned by the semiconductor workpiece cleaning apparatus include semiconductor wafers, masks and the like. 
     The semiconductor workpiece may be held in a cassetteless mode as shown in FIGS.  1 ( a ) to  1 ( c ) or in a cassette mode as shown in FIG.  8 . 
     Liquid-phase IPA may be used instead of vapor-phase IPA as a drying chemical liquid. 
     Possible processing (cleaning) chemical liquid is one or a plurality of a mixture of ammonia, hydrogen peroxide and water, a mixture of hydrochloric acid, hydrogen peroxide and water, a mixture of sulfuric acid, hydrogen peroxide and water, a mixture of hydrofluoric acid and water, a mixture of hydrofluoric acid, hydrogen peroxide and water, a mixture of hydrofluoric acid, ammonium fluoride and water (buffered hydrofluoric acid), a mixture of ozone and water, and electrolytic ionic water. 
     The processing chemical liquid for removing oxide films after cleaning is a mixture of hydrofluoric acid and water, a mixture of hydrofluoric acid, hydrogen peroxide and water, or a mixture of hydrofluoric acid, ammonium fluoride and water (buffered hydrofluoric acid). 
     The drying chemical is liquid-phase or gas-phase isopropyl alcohol, FLUORINERT (C8F18, C4F9, C 4 F 7 O). 
     The chamber may be provided with one or a plurality of nozzles at one or a plurality of positions to spray the chemical liquid and pure water. 
     It is preferable for effective cleaning to hold the semiconductor workpiece stationary and to reciprocate and turn the nozzle to spray the chemical liquid from different directions on the semiconductor workpiece. 
     The semiconductor workpiece may be held in a vertical or nearly vertical position, and the chemical liquid may be sprayed on the semiconductor workpiece while the semiconductor workpiece is rotated. 
     Generally, different processing liquids are sprayed sequentially from the nozzle to remove different kinds of foreign matters adhering to the semiconductor workpiece. 
     As is apparent from the foregoing description, the cleaning apparatus or the cleaning method cleans the semiconductor workpiece efficiently in the process without forming any water marks on the semiconductor workpiece. 
     Second Embodiment 
     FIGS.  2 ( a ),  2 ( b ),  2 ( c ) and  2 ( d ) are conceptional views for explaining a semiconductor workpiece cleaning method and apparatus in a second embodiment according to the present invention. 
     As shown in FIG.  2 ( a ), the semiconductor workpiece cleaning apparatus holds a semiconductor wafer  2 , i.e., a semiconductor workpiece to be cleaned, in a vertical position by guide members  3 , rotates the semiconductor wafer  2  in a chamber  1 , and sprays a cleaning liquid or pure water  5  on the semiconductor wafer  2  by nozzles  4  disposed at a plurality of positions within the chamber  1  to clean the semiconductor wafer  2 . The guide members  3  are rotated to rotate the wafer  2 , a first processing chemical liquid (first cleaning liquid) prepared by mixing sulfuric acid, hydrogen peroxide and water is sprayed by the nozzles  4  on the wafer  2  to remove organic substances and the like from the wafer  2 . Then, pure water is sprayed on the wafer  2  for rinsing. Then, a second cleaning liquid prepared by mixing ammonia, hydrogen peroxide and water is sprayed on the wafer  2  to remove particles, and then pure water is sprayed on the wafer  2  for rinsing. Then, a third cleaning liquid prepared by mixing hydrochloric acid, hydrogen peroxide and water is  13  sprayed on the wafer  2  to remove metallic contaminants and pure water is sprayed for rinsing. Since the semiconductor workpiece cleaning apparatus is provided with the plurality of nozzles  4 , the time necessary for cleaning the semiconductor workpiece can be curtailed, and semiconductor workpiece cleaning apparatus operates at a high efficiency (throughput). 
     After the spray-cleaning process has been completed, a hydrofluoric acid solution  6  (second processing liquid) is supplied through a lower part of the chamber  1  into the chamber at a predetermined supply rate of a velocity of x l/min as shown in FIG.  2 ( b ) for final cleaning. After the chamber  1  is filled half full, the guide members  3  are rotated to invert the semiconductor wafer  2  as shown in FIG.  2 ( c ), and the hydrofluoric acid solution  6  is supplied at the supply rate of a velocity of x l/min through the lower part of the chamber  1  to fill up the chamber  1 . 
     After the semiconductor wafer  2  has been immersed in the hydrofluoric acid solution  6  for a predetermined immersing time, the hydrofluoric acid solution  6  is drained from the chamber  1  through the lower part of the chamber  1  at a drain rate of a velocity of x l/min, which is equal to the supply rate, and liquid-phase isopropyl alcohol (IPA)  10 , i.e., a drying chemical liquid, is supplied through an upper part of the chamber  1  into the chamber  1 . Part of the liquid-phase IPA  10  in contact with the surface of the hydrofluoric acid solution  6  dissolves in the hydrofluoric acid solution  6 , and a boundary layer  11  of hydrofluoric acid solution and IPA is formed. The supply of the liquid-phase IPA is stopped after the thickness of the boundary layer  11  has increased 2 mm or more, and then the hydrofluoric acid solution  6  is drained through a lower part of the chamber  1  at a predetermined drain rate of a velocity of x l/min. 
     Nitrogen gas (N2) is supplied through an upper part of the chamber  1  into the chamber  1  at a supply rate which will not change the thickness of the boundary layer  11  of hydrofluoric acid solution and IPA, while the hydrofluoric acid solution  6  is being drained. After the liquid has completely been drained from the chamber  1 , the chamber  1  is purged with nitrogen gas (N2). Thus, the hydrofluoric acid solution  6 , i.e., the processing chemical liquid, is separated from the drying chemical liquid, i.e., IPA, by the boundary layer  11  to separate the processing chemical liquid from the gas-phase layer, i.e., the nitrogen layer. Consequently, hydrofluoric acid solution  6 , i.e., the processing chemical liquid, can perfectly be separated from the gas (ambient air, ambient atmosphere or the atmosphere) during drying, so that the semiconductor wafer  2  can be cleaned without forming any water mark thereon. 
     In this embodiment, the boundary layer for separating the processing chemical liquid and the drying chemical liquid from each other is formed in a thickness not less than 2 mm. The thickness of the separating layer for separating the gas (ambient air, ambient atmosphere or the atmosphere) from water or the cleaning chemical liquid is greater than the height of waves generated by the disturbance of the liquid surface so that the separating layer may not be broken. 
     In this embodiment, the semiconductor wafer  2  is rotated to immerse the entire surfaces of the semiconductor wafer  2  evenly in the processing chemical liquid, and hence oxide films formed by natural oxidation on the surfaces of the semiconductor wafer  2  can evenly be removed by etching. 
     When supplying the drying chemical liquid into the chamber in which the semiconductor workpiece is immersed in the processing chemical liquid or pure water, the drying chemical liquid is supplied through an upper part of the chamber into the chamber if the specific gravity of the drying chemical liquid is smaller than the processing chemical liquid to replace the cleaning liquid or the pure water contained in the chamber with the drying chemical liquid. If the specific gravity of the drying chemical liquid is greater than that of the processing chemical liquid contained in the chamber, the drying chemical liquid is supplied through a lower part of the chamber into the chamber to replace the processing chemical liquid with the drying chemical liquid. The drying chemical liquid is isopropyl alcohol or FLUORINERT (C8F18, C4F9, C 4 F 7 O). 
     Third Embodiment 
     FIG. 3 is a conceptional view for explaining a semiconductor workpiece cleaning method and apparatus in a third embodiment according to the present invention. 
     This semiconductor workpiece cleaning apparatus comprises a cleaning system similar to those of the first and the second embodiment, and a chemical liquid recycling system for recovering the used cleaning chemical liquid, refining the recovered cleaning chemical liquid and using the refined cleaning chemical liquid. 
     A cleaning system  12  sprays a processing chemical liquid on a workpiece, and then the contaminated processing chemical liquid contaminated with foreign matters washed off the workpiece is discharged through a discharge line  13  into a waste liquid recovering unit  15  provided with waste liquid tanks  14  for different processing chemical liquids. The waste liquid recovering unit  15  stores the different waste chemical liquids separately in those waste liquid tanks  14 , respectively. The recovered waste chemical liquids are refined by refining units  16 . Residues remaining in the refining units  16  after refining the waste chemical liquids are discharged from the refining units  16 . The refined chemical liquids are sent to and stored in chemical liquid tanks  17  of a chemical liquid supply unit  18 . New chemical liquids can be supplied to the chemical liquid tanks  17 . When the quantity of the chemical liquid contained in each chemical liquid tank  17  decreases below a predetermined quantity, the chemical liquid tank  17  is replenished with the new chemical liquid. 
     As is apparent from the foregoing description, in the cleaning system  12  of the semiconductor workpiece cleaning apparatus similar to those of the first and the second embodiment, the used chemical liquid is discharged from the cleaning system  12  through the discharge line  13 , the used chemical liquid is recovered and refined, and then the refined chemical liquid is stored in the chemical liquid supply tank  17  of the chemical liquid supply unit  18  to use the recovered chemical liquid again. 
     Since the processing chemical liquid used for cleaning can be reused, the cleaning cost is reduced. The reduction of the waste chemical liquid is advantageous in respect of environmental protection. 
     Fourth Embodiment 
     FIGS.  4 ( a ),  4 ( b ) and  4 ( c ) are conceptional views for explaining a semiconductor workpiece cleaning method and apparatus in a fourth embodiment according to the present invention. 
     This semiconductor workpiece cleaning apparatus is provided with a cleaning system  12  similar to those of the first and the second embodiment, and capable of recovering and reusing a used drying chemical liquid. 
     Referring to FIG.  4 ( a ), a semiconductor wafer  2 , i.e., a semiconductor workpiece, is held in a vertical position by guide members  3  in a chamber  1 , a processing chemical liquid, i.e., cleaning liquid, or pure water  5  is sprayed from nozzles  4  on the semiconductor wafer  2  to clean the semiconductor wafer  2  while the semiconductor wafer  2  is rotated. Then, as shown in FIG.  4 ( b ), a hydrofluoric acid solution  6 , i.e., a processing chemical liquid for final cleaning, is supplied through a lower part of the chamber  1  into the chamber  1  at a predetermined supply rate of a velocity x l/min. After the semiconductor wafer  2  has been immersed in the hydrofluoric acid solution  6  for a predetermined time, vapor-phase IPA  7 , i.e., drying chemical vapor, is supplied through an upper part of the chamber  1  into the chamber  1 . 
     Then as shown in FIG.  4 ( c ), part of the vapor-phase IPA  7  in contact with the surface of the hydrofluoric acid solution  6  dissolves in the hydrofluoric acid solution  6  or condenses on the surface of the hydrofluoric acid solution  6 , and a boundary layer  11  of the hydrofluoric acid solution and IPA is formed. Upon the increase of the thickness of the boundary layer  11  not less than 2 mm, the hydrofluoric acid solution  6  is discharged from a lower part of the chamber  1  at a discharge rate equal to the supply rate of a velocity x l/min, and the vapor-phase IPA is supplied at a supply rate which will not change the thickness of the boundary layer  11  of the hydrofluoric acid solution and IPA. 
     While the vapor-phase IPA is supplied into the chamber  1  to dry the semiconductor wafer  2  and to replace the processing chemical liquid, the mixture of the hydrofluoric acid solution and IPA is drained from the cleaning system  12 . The drained mixture of the hydrofluoric acid solution and IPA is recovered by a recovering unit  19 , the recovered mixture is sent to a fluorine (F) removing system  20 . The fluorine removing system  20  has, for example, a fluorine removing vessel packed with an ion exchange resin. When a liquid containing fluorine is passed through the fluorine removing vessel, fluorine contained in the liquid is removed. The waste liquid is sent to a distilling refining system  21  after fluorine has been removed therefrom, only IPA is recovered and sent to an IPA supply unit  22 . New IPA can be supplied to the IPA supply unit  22 . If the quantity of IPA contained in the IPA supply unit  22  decreases below a predetermined quantity, the IPA supply unit  22  is replenished with new IPA. 
     When the semiconductor workpiece is dried by direct replacement drying in the cleaning system  12  of the semiconductor workpiece cleaning apparatus in the fourth embodiment similar to those of the first and the second embodiment, fluorine is removed selectively from the drying chemical liquid, i.e., a mixture of IPA and other substances, and the thus recovered and refined drying chemical liquid is used again. 
     Since the drying chemical liquid, i.e., IPA, used for direct replacement drying is recycled, the cost is reduced. The reduction of the waste liquid is advantageous in respect of environmental protection. 
     Fifth Embodiment 
     FIG. 5 is a typical view for explaining a semiconductor workpiece cleaning method and apparatus in a fifth embodiment according to the present invention. 
     This semiconductor workpiece cleaning apparatus is provided with a chemical liquid quality control device for adjusting the temperature and the concentration of a chemical liquid to be supplied into a chamber to a desired temperature and a desired concentration. 
     As shown in FIG. 5, a chemical liquid supply unit  23  has chemical liquid supply tanks  22  respectively containing processing chemical liquids, i.e., cleaning chemical liquids. A chemical liquid preparing unit  25  has adjusting tanks  24  capable of adjusting the concentrations and temperatures of the cleaning chemical liquids. The chemical liquid preparing unit  25  adjusts the temperatures and the concentrations of the chemical liquids to desired temperatures and desired concentrations, respectively. 
     The cleaning chemical liquid of a temperature and a concentration adjusted by the chemical liquid preparing unit  25  is supplied into a chamber  1  for cleaning a semiconductor workpiece. The chamber  1  is provided with a temperature regulating device  26  including a heater, a water-cooling device and an electronic refrigerator to regulate the temperature of the cleaning chemical liquid. Therefore, the temperature of the cleaning chemical liquid can very accurately be regulated, which enhances cleaning efficiency and enables the accurate control of etching rate. 
     This semiconductor workpiece cleaning apparatus in the fifth embodiment is provided with the devices for adjusting the temperature and the concentration of the chemical liquids to desired temperatures and desired concentration in the chemical liquid supply line through which the chemical liquids are supplied into the chamber  1 . Since the chamber  1  of the semiconductor workpiece cleaning apparatus is provided with a temperature regulating device, cleaning effect and uniformity of etching can be improved. 
     Sixth Embodiment 
     FIGS.  6 ( a ) and  6 ( b ) are conceptional views for explaining a semiconductor workpiece cleaning method and apparatus in a sixth embodiment according to the present invention. 
     This semiconductor workpiece cleaning apparatus is provided with temperature controllers  30  in a chemical liquid supply line  28  and a pure water supply line  29  at positions close to a chamber  1 , respectively. The chamber  1  is provided with a megasonic oscillation plate  32 . 
     As shown in FIG.  6 ( a ), a semiconductor wafer  2 , i.e., semiconductor workpiece, is held in the chamber  1  by guide members  3  in a vertical position and rotated, while a processing chemical liquid (cleaning liquid) or pure water  5  is sprayed on the semiconductor wafer  2  by nozzles  4  to clean the semiconductor wafer  2 . 
     As shown in FIG.  6 ( b ), a chemical liquid supply system  27  regulates the temperature and the concentration of the cleaning liquid, and supplies the cleaning liquid through the chemical liquid supply line  28  into the chamber  1 . Pure water of a desired temperature is prepared by mixing hot pure water and cold pure water, and pure water is supplied through the pure water supply line  29  into the chamber  1 . The respective temperatures of the chemical liquid and the pure water changes while the chemical liquid and the pure water are flowing through the supply lines  28  and  29 , respectively. Therefore, the temperature regulators  30  are disposed in the chemical liquid supply line  28  and the pure water supply line  29  at positions immediately before the chamber  1  for the accurate temperature control of the chemical liquid and the pure water to ensure high cleaning effect. 
     After the semiconductor wafer  2  has been cleaned, the chamber  1  is filled up with pure water  31 . The megasonic plate  32  provided in the chamber  1  is driven for oscillation to remove particles adhering to the semiconductor wafer  2 . The effective area of the megasonic plate is half the area of the walls of the chamber  1 . During megasonic cleaning operation, the guide members  3  are rotated to rotate the semiconductor wafer  2 . Therefore, a megasonic effect can be exerted uniformly on the semiconductor wafer  2  even though the effective area of the megasonic plate is half the area of the walls of the chamber  1 . 
     As is apparent from the foregoing description, the semiconductor workpiece cleaning apparatus in the sixth embodiment is provided with the temperature controllers in the chemical liquid supply line from the chemical liquid supply system  27  and in the pure water supply line at positions near the chamber  1 . Therefore, the temperatures of the chemical liquid and the pure water can accurately be controlled to enhance the cleaning effect. The semiconductor workpiece cleaning apparatus is provided with the megasonic plate  32  for megasonic cleaning to achieve high cleaning effect. 
     As is apparent from the foregoing description, according to the present invention, spray type cleaning operation and dip type cleaning operation are used in combination for cleaning a semiconductor workpiece. Therefore, the semiconductor workpiece can quickly and efficiently be cleaned. 
     Since the processing chemical liquid or pure water is isolated from the ambience by the drying chemical liquid or the vapor of the drying chemical liquid when discharging the cleaning chemical liquid or pure water before drying, the semiconductor workpiece can be cleaned without being stained with water marks. 
     According to the present invention, the semiconductor workpiece is inverted when the lower half of the semiconductor workpiece is immersed in the processing chemical liquid supplied through a lower part of the chamber into the chamber, and then the chemical liquid is supplied continuously. Therefore the semiconductor workpiece can uniformly be processed for etching and the like. 
     Since the present invention regulates the temperature or the concentration of the processing chemical liquid or pure water to be supplied into the chamber, cleaning efficiency is enhanced. 
     Since the semiconductor workpiece cleaning apparatus of the present invention recovers the chemical liquid discharged from the chamber and returns the same after cleaning into the chamber, the chemical liquid can be recycled, the cleaning cost can be reduced, and the effluence of the waste chemical liquid is reduced. 
     Furthermore, since efficient megasonic oscillation is used for cleaning, cleaning effect can effectively be enhanced without increasing the cost. 
     Obviously, numerous additional modifications and variations of the present invention are possible in light of the above teachings. It is therefore to be understood that within the scope of the appended claims, the invention may be practiced otherwise than as specifically described herein.