user: Question: Which overall's pick number was 14?
Columns: ['Round', 'Pick #', 'Overall', 'Name', 'Position', 'College']
Types: ['real', 'real', 'real', 'text', 'text', 'text']
Sample row: [1.0, 6.0, 6.0, 'Julio Jones', 'Wide Receiver', 'Alabama']
SQL:

assistant: SELECT "Overall" FROM "Table" WHERE "Pick #" = 14.0;