user: Question: Which Pick # has a Round smaller than 6, and an Overall larger than 13, and a College of Penn State?
Columns: ['Round', 'Pick #', 'Overall', 'Name', 'Position', 'College']
Types: ['real', 'real', 'real', 'text', 'text', 'text']
Sample row: [1.0, 13.0, 13.0, 'Marcus Stroud', 'Defensive Tackle', 'Georgia']
SQL:

assistant: SELECT "Pick #" FROM "Table" WHERE "Round" < 6.0 AND "Overall" > 13.0 AND "College" = 'Penn State';