user: Question: Which player's pick number was 25?
Columns: ['Pick #', 'MLS Team', 'Player', 'Position', 'Affiliation']
Types: ['real', 'text', 'text', 'text', 'text']
Sample row: [15.0, 'San Jose Earthquakes', 'Shea Salinas', 'M', 'Furman Carolina Dynamo']
SQL:

assistant: SELECT "Player" FROM "Table" WHERE "Pick #" = 25.0;