user: Question: How many times was leather introduced before Pedal Steel Guitars in episode 111?
Columns: ['Series Ep.', 'Episode', 'Netflix', 'Segment A', 'Segment B', 'Segment C', 'Segment D']
Types: ['text', 'real', 'text', 'text', 'text', 'text', 'text']
Sample row: ['9-01', 105.0, 'S05E01', 'Solid Tires', 'Cheesecake', 'Canoe Paddles', 's Globe']
SQL:

assistant: SELECT COUNT("Segment C") FROM "Table" WHERE "Segment D" = 'Pedal Steel Guitars';