user: Question: In what round did someone from north carolina state get picked larger than 91?
Columns: ['Round', 'Pick', 'Player', 'Nationality', 'School/Club Team']
Types: ['real', 'real', 'text', 'text', 'text']
Sample row: [1.0, 22.0, 'Jerry Reynolds', 'United States', 'Louisiana State']
SQL:

assistant: SELECT "Round" FROM "Table" WHERE "School/Club Team" = 'north carolina state' AND "Pick" > 91.0;