in the face that 's simultaneously painful and refreshing 
(ROOT (PP (IN in) (NP (NP (DT the) (NN face)) (SBAR (WHNP (WDT that)) (S (VP (VBZ 's) (ADJP (RB simultaneously) (JJ painful) (CC and) (JJ refreshing))))))))
(ROOT (PP (IN ) (NP (NP (DT ) (NN )) (SBAR (WHNP (WDT )) (S (VP (VBZ ) (ADJP (RB ) (JJ ) (CC ) (JJ ))))))))