Publication: Magyar Közlöny
Issue: MK-2011-73 (Year: 2011, Number: 73)
Era: contemporary
Section: 1. melléklet a 2011. évi LXXIX. törvényhez
Paragraph Index: 36

8. Consequences of occurrence Personal injury in connection with the dangerous goods involved: Ƒ Ƒ Loss of product: Ƒ Yes Ƒ No Ƒ Imminent risk of loss of product Material/Environmental damage: Ƒ Estimated level of damage d 50,000 Euros Ƒ Estimated level of damage > 50,000 Euros Involvement of authorities: Ƒ Yes Ƒ Evacuation of persons for a duration of at least three hours caused by the dangerous goods involved Ƒ Closure of public traffic routes for a duration of at least three hours caused by the dangerous goods involved Ƒ No If necessary, the competent authority may request further relevant information. Copyright © United Nations, 2010. All rights reserved - 79 - 1.8.6 Administrative controls for application of the conformity assessments, periodic inspections, intermediate inspections and exceptional checks described in 1.8.7 1.8.6.1 Approval of inspection bodies The competent authority may approve inspection bodies for conformity assessments, periodic inspections, intermediate inspections, exceptional checks and surveillance of the inhouse inspection service as specified in 1.8.7. 1.8.6.2 Operational obligations for the competent authority, its delegate or inspection body 1.8.6.2.1 The competent authority, its delegate or inspection body shall carry out conformity assessments, periodic inspections, intermediate inspections and exceptional checks in a proportionate manner, avoiding unnecessary burdens. The competent authority, its delegate or inspection body shall perform its activities taking into consideration the size, the sector and the structure of the undertakings involved, the relative complexity of the technology and the serial character of production. 1.8.6.2.2 Nevertheless the competent authority, its delegate or inspection body shall respect the degree of rigour and the level of protection required for the compliance of the transportable pressure equipment by the provisions of parts 4 and 6 as applicable. 1.8.6.2.3 Where a competent authority, its delegate or inspection body finds out that requirements laid down in parts 4 or 6 have not been met by the manufacturer, it shall require the manufacturer to take appropriate corrective measures and it shall not issue any type approval certificate or certificate of conformity. 1.8.6.3 Information obligation Contracting Parties to ADR shall publish their national procedures for the assessment, appointment and monitoring of inspection bodies and of any changes to that information. 1.8.6.4 Delegation of inspection tasks NOTE: In-house inspection services according to 1.8.7.6 are not covered by 1.8.6.4. 1.8.6.4.1 Where an inspection body uses the services of any other entity (e.g. subcontractor, subsidiary), to carry out specific tasks connected with the conformity assessment, periodic inspection, intermediate inspection or exceptional checks, this entity shall be included in the accreditation of the inspection body, or it shall be accredited separately. The inspection body shall ensure that this entity meets the requirements set out for the tasks given to it with the same level of competence and safety as laid down for inspection bodies (see 1.8.6.8) and the inspection body shall monitor it. The inspection body shall inform the competent authority about the above mentioned arrangements. 1.8.6.4.2 The inspection body shall take full responsibility for the tasks performed by such entities wherever the tasks are performed by them. 1.8.6.4.3 The inspection body shall not delegate the whole task of conformity assessment, periodic inspection, intermediate inspection or exceptional checks. In any case, the assessment and the issue of certificates shall be carried out by the inspection body itself. 1.8.6.4.4 Activities shall not be delegated without the agreement of the applicant. Copyright © United Nations, 2010. All rights reserved - 80 - 1.8.6.4.5 The inspection body shall keep at the disposal of the competent authority the relevant documents concerning the assessment of the qualifications and the work carried out by the above mentioned entities. 1.8.6.5 Information obligations for inspection bodies Any inspection body shall inform the competent authority, which had approved it, of the following: (a) Except when the provisions of 1.8.7.2.4 apply, any refusal, restriction, suspension or withdrawal of type approval certificates; (b) Any circumstance(s) affecting the scope of and conditions for the approval as granted by the competent authority; (c) Any request for information on conformity assessment activities performed which they have received from competent authorities monitoring compliance according to 1.8.1 or 1.8.6.6; (d) On request, conformity assessment activities performed within the scope of their approval and any other activity performed, including delegation of tasks. 1.8.6.6 The competent authority shall ensure the monitoring of the inspection bodies and shall revoke or restrict the approval given, if it notes that an approved body is no longer in compliance with the approval and the requirements of 1.8.6.8 or does not follow the procedures specified in the provisions of ADR. 1.8.6.7 If the approval of the inspection body is revoked or restricted or if the inspection body ceased activity, the competent authority shall take the appropriate steps to ensure that the files are either processed by another inspection body or kept available. 1.8.6.8 The inspection body shall: (a) Have a staff with an organisational structure, capable, trained, competent and skilled, to satisfactorily perform its technical functions; (b) Have access to suitable and adequate facilities and equipment; (c) Operate in an impartial manner and be free from any influence which could prevent it from doing so; (d) Ensure commercial confidentiality of the commercial and proprietary activities of the manufacturer and other bodies; (e) Maintain clear demarcation between actual inspection body functions and unrelated functions; (f) Have a documented quality system; (g) Ensure that the tests and inspections specified in the relevant standard and in ADR are performed; and (h) Maintain an effective and appropriate report and record system in accordance with 1.8.7 and 1.8.8. Copyright © United Nations, 2010. All rights reserved - 81 - The inspection body shall additionally be accredited according to the standard EN ISO/IEC 17020:2004, as specified in 6.2.2.10, 6.2.3.6 and TA4 and TT9 of 6.8.4. An inspection body starting a new activity may be approved temporarily. Before temporary designation, the competent authority shall ensure that the inspection body meets the requirements of the standard EN ISO/IEC 17020:2004. The inspection body shall be accredited in its first year of activity to be able to continue this new activity. 1.8.7 Procedures for conformity assessment and periodic inspection NOTE: In this section, "relevant body" means a body assigned in 6.2.2.10 when certifying UN pressure receptacles, in 6.2.3.6 when approving non-UN pressure receptacles and in special provisions TA4 and TT9 of 6.8.4. 1.8.7.1 General provisions 1.8.7.1.1 The procedures in section 1.8.7 shall be applied according to 6.2.3.6 when approving non- UN pressure receptacles and according to TA4 and TT9 of 6.8.4 when approving tanks, battery-vehicles and MEGCs. The procedures in section 1.8.7 may be applied according to the table in 6.2.2.10 when certifying UN pressure receptacles. 1.8.7.1.2 Each application for (a) The type approval in accordance with 1.8.7.2 or; (b) The supervision of manufacture in accordance with 1.8.7.3 and the initial inspection and test in accordance with 1.8.7.4; or (c) The periodic inspection, intermediate inspection and exceptional checks in accordance with 1.8.7.5 shall be lodged by the applicant with a single competent authority, its delegate or an approved inspection body of his choice. 1.8.7.1.3 The application shall include: (a) The name and address of the applicant; (b) For conformity assessment where the applicant is not the manufacturer, the name and address of the manufacturer; (c) A written declaration that the same application has not been lodged with any other competent authority, its delegate or inspection body; (d) The relevant technical documentation specified in 1.8.7.7; (e) A statement allowing the competent authority, its delegate or inspection body access for inspection purposes to the locations of manufacture, inspection, testing and storage and providing it with all necessary information. 1.8.7.1.4 Where the applicant can demonstrate to the satisfaction of the competent authority or its delegated inspection body conformity with 1.8.7.6 the applicant may establish an in-house inspection service which may perform part or all of the inspections and tests when specified in 6.2.2.10 or 6.2.3.6. Copyright © United Nations, 2010. All rights reserved - 82 - 1.8.7.1.5 Design type approval certificates and certificates of conformity - including the technical documentation - shall be retained by the manufacturer or by the applicant for the type approval, if he is not the manufacturer, and by the inspection body, who issued the certificate, for a period of at least 20 years starting from the last date of production of products of the same type. 1.8.7.1.6 When a manufacturer or owner intends to cease operation, he shall send the documentation to the competent authority. The competent authority shall then retain the documentation for the rest of the period specified in 1.8.7.1.5. 1.8.7.2 Type approval Type approvals authorise the manufacture of pressure receptacles, tanks, battery-vehicles or MEGCs within the period of validity of that approval. 1.8.7.2.1 The applicant shall: (a) In the case of pressure receptacles, place at the disposal of the relevant body representative samples of the production envisaged. The relevant body may request further samples if required by the test programme; (b) In the case of tanks, battery-vehicles or MEGCs, give access to the prototype for type testing. 1.8.7.2.2 The relevant body shall: (a) Examine the technical documentation specified in 1.8.7.7.1 to verify that the design is in accordance with the relevant provisions of ADR, and the prototype or the prototype lot has been manufactured in conformity with the technical documentation and is representative of the design; (b) Perform the examinations and witness the tests specified in ADR, to determine that the provisions have been applied and fulfilled, and the procedures adopted by the manufacturer meet the requirements; (c) Check the certificate(s) issued by the materials manufacturer(s) against the relevant provisions of ADR; (d) As applicable, approve the procedures for the permanent joining of parts or check that they have been previously approved, and verify that the staff undertaking the permanent joining of parts and the non-destructive tests are qualified or approved; (e) Agree with the applicant the location and testing facilities where the examinations and necessary tests are to be carried out. The relevant body shall issue a type-examination report to the applicant. 1.8.7.2.3 Where the type satisfies all applicable provisions, the competent authority, its delegate or the inspection body, shall issue a type approval certificate to the applicant. This certificate shall contain: (a) The name and address of the issuer; (b) The name and address of the manufacturer and of the applicant when the applicant is not the manufacturer; Copyright © United Nations, 2010. All rights reserved - 83 - (c) A reference to the version of ADR and standards used for the type examination; (d) Any requirements resulting from the examination; (e) The necessary data for identification of the type and variation, as defined by the relevant standard; (f) The reference to the type examination report(s); and (g) The maximum period of validity of the type approval. A list of the relevant parts of the technical documentation shall be annexed to the certificate (see 1.8.7.7.1). 1.8.7.2.4 The type approval shall be valid for a maximum of ten years. If within that period the relevant technical requirements of ADR (including referenced standards) have changed so that the approved type is no longer in conformity with them, the relevant body which issued the type approval shall withdraw it and inform the holder of the type approval. NOTE: For the ultimate dates for withdrawal of existing type approvals, see column (5) of the tables in 6.2.4 and 6.8.2.6 or 6.8.3.6 as appropriate. If a type approval has expired or has been withdrawn, the manufacture of the pressure receptacles, tanks, battery-vehicles or MEGCs according to that type approval is no longer authorised. In such a case, the relevant provisions concerning the use, periodic inspection and intermediate inspection of pressure receptacles, tanks, battery-vehicles or MEGCs contained in the type approval which has expired or has been withdrawn shall continue to apply to these pressure receptacles, tanks, battery-vehicles or MEGCs constructed before the expiry or the withdrawal if they may continue to be used. They may continue to be used as long as they remain in conformity with the requirements of ADR. If they are no longer in conformity with the requirements of ADR they may continue to be used only if such use is permitted by relevant transitional measures in Chapter 1.6. Type approvals may be renewed by a complete review and assessment for conformity with the provisions of ADR applicable at the date of renewal. Renewal is not permitted after a type approval has been withdrawn. Interim amendments of an existing type approval (e.g. for pressure receptacles minor amendments such as the addition of further sizes or volumes not affecting conformity, or for tanks see 6.8.2.3.2) do not extend or modify the original validity of the certificate. NOTE: The review and assessment of conformity can be done by a body other than the one which issued the original type approval. The issuing body shall keep all documents for the type approval (see 1.8.7.7.1) for the whole period of validity including its renewals if granted. 1.8.7.3 Supervision of manufacture 1.8.7.3.1 The manufacturing process shall be subject to a survey by the relevant body to ensure the product is produced in conformity with the provisions of the type approval. Copyright © United Nations, 2010. All rights reserved - 84 - 1.8.7.3.2 The applicant shall take all the necessary measures to ensure that the manufacturing process complies with the applicable provisions of ADR and of the type approval certificate and its annexes. 1.8.7.3.3 The relevant body shall: (a) Verify the conformity with the technical documentation specified in 1.8.7.7.2; (b) Verify that the manufacturing process produces products in conformity with the requirements and the documentation which apply to it; (c) Verify the traceability of materials and check the material certificate(s) against the specifications; (d) As applicable, verify that the personnel undertaking the permanent joining of parts and the non-destructive tests are qualified or approved; (e) Agree with the applicant on the location where the examinations and necessary tests are to be carried out; and (f) Record the results of its survey. 1.8.7.4 Initial inspection and tests 1.8.7.4.1 The applicant shall: (a) Affix the marks specified in ADR; and (b) Supply to the relevant body the technical documentation specified in 1.8.7.7. 1.8.7.4.2 The relevant body shall: (a) Perform the necessary examinations and tests in order to verify that the product is manufactured in accordance with the type approval and the relevant provisions; (b) Check the certificates supplied by the manufacturers of service equipment against the service equipment; (c) Issue an initial inspection and test report to the applicant relating to the detailed tests and verifications carried out and the verified technical documentation; (d) Draw up a written certificate of conformity of the manufacture and affix its registered mark when the manufacture satisfies the provisions; and (e) Check if the type approval remains valid after provisions of ADR (including referenced standards) relevant to the type approval have changed. The certificate in (d) and report in (c) may cover a number of items of the same type (group certificate or report). 1.8.7.4.3 The certificate shall contain as a minimum: (a) The name and address of the relevant body; (b) The name and address of the manufacturer and the name and address of the applicant, if not the manufacturer; Copyright © United Nations, 2010. All rights reserved - 85 - (c) A reference to the version of the ADR and standards used for the initial inspections and tests; (d) The results of the inspections and tests; (e) The data for identification of the inspected product(s), at least the serial number or for non refillable cylinders the batch number; and (f) The type approval number. 1.8.7.5 Periodic inspection, intermediate inspection and exceptional checks 1.8.7.5.1 The relevant body shall: (a) Perform the identification and verify the conformity with the documentation; (b) Carry out the inspections and witness the tests in order to check that the requirements are met; (c) Issue reports of the results of the inspections and tests, which may cover a number of items; and (d) Ensure that the required marks are applied. 1.8.7.5.2 Reports of periodic inspections and tests of pressure receptacles shall be retained by the applicant at least until the next periodic inspection. NOTE: For tanks, see provisions for tank records in 4.3.2.1.7. 1.8.7.6 Surveillance of the applicant’s in-house inspection service 1.8.7.6.1 The applicant shall: (a) Implement an in-house inspection service with a quality system for inspections and tests documented in 1.8.7.7.5 and subject to surveillance; (b) Fulfil the obligations arising out of the quality system as approved and to ensure that it remains satisfactory and efficient; (c) Appoint trained and competent personnel for the in-house inspection service; and (d) Affix the registered mark of the inspection body where appropriate. 1.8.7.6.2 The inspection body shall carry out an initial audit. If satisfactory the inspection body shall issue an authorisation for a period not exceeding three years. The following provisions shall be met: (a) This audit shall confirm that the inspections and tests performed on the product are in compliance with the requirements of ADR; (b) The inspection body may authorise the in-house inspection service of the applicant to affix the registered mark of the inspection body to each approved product; (c) The authorisation may be renewed after a satisfactory audit in the last year prior to the expiry. The new period of validity shall begin with the date of expiry of the authorisation; and Copyright © United Nations, 2010. All rights reserved - 86 - (d) The auditors of the inspection body shall be competent to carry out the assessment of conformity of the product covered by the quality system. 1.8.7.6.3 The inspection body shall carry out periodic audits within the duration of the authorisation to make sure that the applicant maintains and applies the quality system. The following provisions shall be met: (a) A minimum of two audits shall be carried out in a 12 month period; (b) The inspection body may require additional visits, training, technical changes, modifications of the quality system, restrict or prohibit the inspections and tests to be done by the applicant; (c) The inspection body shall assess any changes in the quality system and decide whether the modified quality system will still satisfy the requirements of the initial audit or whether a full reassessment is required; (d) The auditors of the inspection body shall be competent to carry out the assessment of conformity of the product covered by the quality system; and (e) The inspection body shall provide the applicant with a visit or audit report and, if a test has taken place, with a test report. 1.8.7.6.4 In cases of non conformity with the relevant requirements the inspection body shall ensure that corrective measures are taken. If corrective measures are not taken in due time, the inspection body shall suspend or withdraw the permission for the in-house inspection service to carry out its activities. The notice of suspension or withdrawal shall be transmitted to the competent authority. A report shall be provided to the applicant giving detailed reasons for the decisions taken by the inspection body. 1.8.7.7 Documents The technical documentation shall enable an assessment to be made of conformity with the relevant requirements. 1.8.7.7.1 Documents for type approval The applicant shall provide as appropriate: (a) The list of standards used for the design and manufacture; (b) A description of the type including all variations; (c) The instructions according to the relevant column of table A of Chapter 3.2 or a list of dangerous goods to be transported for dedicated products; (d) A general assembly drawing or drawings; (e) The detailed drawings, including the dimensions used for the calculations, of the product, the service equipment, the structural equipment, the marking and/or the labelling necessary to verify the conformity; (f) The calculation notes, results and conclusions; (g) The list of the service equipment with the relevant technical data and information on the safety devices including the calculation of the relief capacity if relevant; Copyright © United Nations, 2010. All rights reserved - 87 - (h) The list of material requested in the standard for manufacture used for every part, subpart, lining, service and structural equipment and the corresponding material specifications or the corresponding declaration of conformity to ADR; (i) The approved qualification of permanent joining process; (j) The description of the heat treatment process(es); and (k) The procedures, descriptions and records of all relevant tests listed in the standards or ADR for the type approval and for the manufacture. 1.8.7.7.2 Documents for the supervision of manufacture The applicant shall make available as appropriate: (a) The documents listed in 1.8.7.7.1; (b) A copy of the type approval certificate; (c) The manufacturing procedures including test procedures; (d) The manufacturing records; (e) The approved qualifications of permanent joining operators; (f) The approved qualifications of the non destructive test operators; (g) The reports of the destructive and non destructive tests; (h) The heat treatment records; and (i) The calibration records. 1.8.7.7.3 Documents for initial inspection and tests The applicant shall make available as appropriate: (a) The documents listed in 1.8.7.7.1 and 1.8.7.7.2; (b) The material certificates of the product and any sub-parts; (c) The declarations of conformity and material certificates of the service equipment; and (d) A declaration of conformity including the description of the product and all the variations adopted from the type approval. 1.8.7.7.4 Documents for periodic inspections, intermediate inspections and exceptional checks The applicant shall make available as appropriate: (a) For pressure receptacles, the documents specifying special requirements when the manufacturing and periodic inspections and tests standards so require; (b) For tanks: (i) the tank record; and (ii) one or more of the documents mentioned in 1.8.7.7.1 to 1.8.7.7.3. Copyright © United Nations, 2010. All rights reserved - 88 - 1.8.7.7.5 Documents for the assessment of in-house inspection service The applicant for in-house inspection service shall make available the quality system documentation as appropriate: (a) The organisational structure and responsibilities; (b) The relevant inspection and test, quality control, quality assurance and process operation instructions, and systematic actions that will be used; (c) The quality records, such as inspection reports, test data, calibration data and certificates; (d) The management reviews to ensure the effective operation of the quality system arising from the audits in accordance with 1.8.7.6; (e) The process describing how customer and regulation requirements are met; (f) The process for control of documents and their revision; (g) The procedures for dealing with non-conforming products; and (h) The training programmes and qualification procedures for relevant personnel. 1.8.7.8 Products manufactured, approved, inspected and tested according to standards The requirements of 1.8.7.7 are considered to have been complied with if the following standards, as relevant, are applied: Applicable subsection and paragraph References Title of the document 1.8.7.7.1 to 1.8.7.7.4 EN 12972:2007 Tanks for transport of dangerous goods - Testing, inspection and marking of metallic tanks 1.8.8 Procedures for conformity assessment of gas cartridges When assessing the conformity of gas cartridges, one of the following procedures shall be applied: (a) The procedure in section 1.8.7 for non-UN pressure receptacles, with the exception of 1.8.7.5; or (b) The procedure in sub-sections 1.8.8.1 to 1.8.8.7. 1.8.8.1 General provisions 1.8.8.1.1 The supervision of manufacture shall be carried out by an Xa body and the tests as required in 6.2.6 shall be carried out either by that Xa body or by an IS-body approved by that Xa body; for definition of Xa and IS bodies see definitions in 6.2.3.6.1. Conformity assessment shall be carried out by the competent authority, its delegate or its approved inspection body of a Contracting Party to ADR. Copyright © United Nations, 2010. All rights reserved - 89 - 1.8.8.1.2 By the application of 1.8.8, the applicant shall demonstrate, ensure and declare on his sole responsibility the conformity of gas cartridges with the provisions of 6.2.6 and all further applicable provisions of ADR. 1.8.8.1.3 The applicant shall (a) Carry out a design type examination of each type of gas cartridges (including materials to be used and variations of that type, e.g. volumes, pressures, drawings and closing and release devices) according to 1.8.8.2; (b) Operate an approved quality system for design, manufacture, inspection and testing according to 1.8.8.3; (c) Operate an approved testing regime according to 1.8.8.4 for the tests required in 6.2.6; (d) Apply for the approval of his quality system for supervision of manufacture and for testing to one Xa body of his choice of the Contracting Party; if the applicant is not established in a Contracting Party he shall apply to one Xa body of a Contracting Party prior to first transport into a Contracting Party; (e) If the gas cartridge is finally assembled from parts manufactured by the applicant by one or more other enterprise(s), provide written instructions how to assemble and fill the gas cartridges to meet the provisions of his type examination certificate. 1.8.8.1.4 Where the applicant and enterprises assembling or filling gas cartridges according to the instructions of the applicant, can demonstrate to the satisfaction of the Xa body conformity with the provisions of 1.8.7.6 excluding 1.8.7.6.1 (d) and 1.8.7.6.2 (b), they may establish an in-house inspection service which may perform part or all of the inspections and tests specified in 6.2.6. 1.8.8.2 Design type examination 1.8.8.2.1 The applicant shall establish a technical documentation for each type of gas cartridges including the technical standard(s) applied. If he chooses to apply a standard not referenced in 6.2.6, he shall add the standard applied to the documentation. 1.8.8.2.2 The applicant shall retain the technical documentation together with samples of that type at the disposal of the Xa body during production and afterwards for a period of minimum five years starting from the last date of production of gas cartridges according to that type examination certificate. 1.8.8.2.3 The applicant shall after careful examination issue a design type certificate which shall be valid for a maximum period of ten years; he shall add this certificate to the documentation. This certificate authorises him to produce gas cartridges of that type for that period. 1.8.8.2.4 If within that period the relevant technical requirements of ADR (including referenced standards) have changed so that the design type is no longer in conformity with them, the applicant shall withdraw his type examination certificate and inform the Xa body. 1.8.8.2.5 The applicant may after careful and complete review reissue the certificate for another period of maximum ten years. Copyright © United Nations, 2010. All rights reserved - 90 - 1.8.8.3 Supervision of manufacture 1.8.8.3.1 The procedure of design type examination as well as the manufacturing process shall be subject to a survey by the Xa body to ensure the type certified by the applicant and the product as produced are in conformity with the provisions of the design type certificate and the applicable provisions of ADR. If 1.8.8.1.3 (e) applies, the assembling and filling enterprises shall be included in that procedure. 1.8.8.3.2 The applicant shall take all the necessary measures to ensure that the manufacturing process complies with the applicable provisions of ADR and of his design type certificate and its annexes. If 1.8.8.1.3 (e) applies, the assembling and filling enterprises shall be included in that procedure. 1.8.8.3.3 The Xa body shall: (a) Verify the conformity of the design type examination of the applicant and conformity of the type of gas cartridges with the technical documentation specified in 1.8.8.2; (b) Verify that the manufacturing process produces products in conformity with the requirements and the documentation which apply to it; if the gas cartridge is finally assembled from parts manufactured by the applicant by one or more enterprise(s), the Xa body shall also verify that the gas cartridges are in full conformity with all applicable provisions after final assembly and filling and that the instructions of the applicant are correctly applied; (c) Verify that the personnel undertaking the permanent joining of parts and the tests are qualified or approved; (d) Record the results of its surveys. 1.8.8.3.4 If the findings of the Xa body show non-conformity of the design type certificate of the applicant or the manufacturing process, he shall require appropriate corrective measures or withdrawal of the certificate from the applicant. 1.8.8.4 Leakproofness test 1.8.8.4.1 The applicant and enterprises finally assembling and filling gas cartridges according to the instructions of the applicant shall: (a) Carry out the tests required in 6.2.6; (b) Record the test results; (c) Issue a certificate of conformity only for gas cartridges, which are in full compliance with the provisions of his design type examination and the applicable provisions of ADR and have successfully passed the tests as required in 6.2.6; (d) Retain the documentation as specified in 1.8.8.7 during production and afterwards for a period of minimum five years from the last date of production of gas cartridges belonging to one type approval for inspection by the Xa body at random intervals; (e) Affix a durable and legible mark identifying the type of gas cartridge, the applicant and the date of production or batch number; where due to limited available space the mark cannot be fully applied to the body of the gas cartridge, he shall affix a durable tag with this information to the gas cartridge or place it together with a gas cartridge in an inner packaging. Copyright © United Nations, 2010. All rights reserved - 91 - 1.8.8.4.2 The Xa body shall: (a) Perform the necessary examinations and tests at random intervals, but at least shortly after starting of manufacture of a type of gas cartridges and thereafter at least once every three years, in order to verify that the procedure for design type examination of the applicant as well as that the manufacture and testing of the product are carried out in accordance with the design type certificate and the relevant provisions; (b) Check the certificates supplied by the applicant; (c) Carry out the tests as required in 6.2.6 or approve the program of testing and the inhouse inspection service to carry out the tests. 1.8.8.4.3 The certificate shall contain as a minimum: (a) The name and address of the applicant and, when the final assembly is not carried out by the applicant but by an enterprise or enterprises in accordance with the written instructions of the applicant, the name(s) and address(es) of these enterprises; (b) A reference to the version of ADR and the standard(s) used for manufacture and tests; (c) The result of inspections and tests; (d) The data for the marking as required in 1.8.8.4.1 (e). 1.8.8.5 (Reserved) 1.8.8.6 Surveillance of the in-house inspection service When the applicant or enterprise assembling or filling gas cartridges has established an inhouse inspection service, the provisions of 1.8.7.6 excluding 1.8.7.6.1 (d) and 1.8.7.6.2 (b) shall be applied. The enterprise assembling or filling gas cartridges shall comply with the provisions relevant to the applicant. 1.8.8.7 Documents The provisions of 1.8.7.7.1, 1.8.7.7.2, 1.8.7.7.3 and 1.8.7.7.5 shall be applied. Copyright © United Nations, 2010. All rights reserved - 93 - CHAPTER 1.9 TRANSPORT RESTRICTIONS BY THE COMPETENT AUTHORITIES 1.9.1 In accordance with Article 4, paragraph 1 of ADR, the entry of dangerous goods into the territory of Contracting Parties may be subject to regulations or prohibitions imposed for reasons other than safety during carriage. Such regulations or prohibitions shall be published in an appropriate form. 1.9.2 Subject to the provisions of 1.9.3, a Contracting Party may apply to vehicles engaged in the international carriage of dangerous goods by road on its territory certain additional provisions not included in ADR, provided that those provisions do not conflict with Article 2, paragraph 2 of the Agreement, and are contained in its domestic legislation applying equally to vehicles engaged in the domestic carriage of dangerous goods by road on the territory of that Contracting Party. 1.9.3 Additional provisions falling within the scope of 1.9.2 are as follows: (a) Additional safety requirements or restrictions concerning vehicles using certain structures such as bridges, vehicles using combined transport modes such as ferries or trains, or vehicles entering or leaving ports or other transport terminals; (b) Requirements for vehicles to follow prescribed routes to avoid commercial or residential areas, environmentally sensitive areas, industrial zones containing hazardous installations or roads presenting severe physical hazards; (c) Emergency requirements regarding routeing or parking of vehicles carrying dangerous goods resulting from extreme weather conditions, earthquake, accident, industrial action, civil disorder or military hostilities; (d) Restrictions on movement of dangerous goods traffic on certain days of the week or year. 1.9.4 The competent authority of the Contracting Party applying on its territory any additional provisions within the scope of 1.9.3 (a) and (d) above shall notify the secretariat of the United Nations Economic Commission for Europe of the additional provisions, which secretariat shall bring them to the attention of the Contracting Parties1. 1.9.5 Tunnel restrictions NOTE: Provisions concerning restrictions for the passage of vehicles through road tunnels are also included in Chapter 8.6. 1.9.5.1 General provisions When applying restrictions to the passage of vehicles carrying dangerous goods through tunnels, the competent authority shall assign the road tunnel to one of the tunnel categories defined in 1.9.5.2.2. Account should be taken of the tunnel characteristics, risk assessment including availability and suitability of alternative routes and modes and traffic management considerations. The same tunnel may be assigned to more than one tunnel category, e.g. depending on the hours of the day, or the day of the week etc. A General Guideline for the Calculation of Risks in the Transport of Dangerous Goods by Road may be consulted on the website of the secretariat of the United Nations Economic Commission for Europe (http://www.unece.org/trans/danger/danger.htm). Copyright © United Nations, 2010. All rights reserved - 94 - 1.9.5.2 Categorization 1.9.5.2.1 The categorization shall be based on the assumption that in tunnels there are three major dangers which may cause numerous victims or serious damage to the tunnel structure: (a) Explosions; (b) Release of toxic gas or volatile toxic liquid; (c) Fires. 1.9.5.2.2 The five tunnel categories are the following: Tunnel category A: No restrictions for the transport of dangerous goods; Tunnel category B: Restriction for dangerous goods which may lead to a very large explosion; The following dangerous goods are considered to fulfil this criterion2: Class 1: Compatibility groups A and L; Class 3: Classification code D (UN Nos. 1204, 2059, 3064, 3343, 3357 and 3379); Classification codes D and DT; and Class 4.1: Self-reactive substances, type B (UN Nos. 3221, 3222, 3231 and 3232); Class 5.2: Organic peroxides, type B (UN Nos. 3101, 3102, 3111 and 3112). When the total net explosive mass per transport unit is greater than 1000 kg: Class 1: Divisions 1.1, 1.2 and 1.5 (except compatibility groups A and L). When carried in tanks: Class 2: Classification codes F, TF and TFC; Class 4.2: Packing group I; Class 4.3: Packing group I; Class 5.1: Packing group I. Class 6.1: UN No. 1510 Tunnel category C: Restriction for dangerous goods which may lead to a very large explosion, a large explosion or a large toxic release; The following dangerous goods are considered to fulfil this criterion2: - the dangerous goods restricted in tunnel category B, and - the following dangerous goods: The assessment is based on the intrinsic dangerous properties of the goods, the type of containment and the quantity carried. Copyright © United Nations, 2010. All rights reserved - 95 - Class 1: Divisions 1.1, 1.2 and 1.5 (except compatibility groups A and L); and Division 1.3 (compatibility groups H and J); Class 7: UN Nos. 2977 and 2978. When the net explosive mass per transport unit is greater than 5000 kg: Class 1: Division 1.3 (compatibility groups C and G). When carried in tanks: Class 2: Classification codes 2A, 2O, 3A and 3O, and classification codes containing the letter T only or letter groups TC, TO and TOC Class 3: Packing group I for classification codes FC, FT1, FT2 and FTC; Class 6.1: Packing group I, except UN No. 1510 Class 8: Packing group I for classification codes CT1, CFT and COT. Tunnel category D: Restriction for dangerous goods which may lead to a very large explosion, to a large explosion, to a large toxic release or to a large fire; The following dangerous goods are considered to fulfil this criterion2: - the dangerous goods restricted in tunnel category C, and - the following dangerous goods: Class 1: Division 1.3 (compatibility groups C and G); Class 2: Classification codes F, FC, T, TF, TC, TO, TFC and TOC; Class 4.1: Self-reactive substances, types C, D, E and F; and UN Nos. 2956, 3241, 3242 and 3251; Class 5.2: Organic peroxides, types C, D, E and F; Class 6.1: Packing group I for classification codes TF1, TFC and TFW; and Toxic by inhalation entries for which special provision 354 is assigned in column (6) of Table A of Chapter 3.2 and toxic by inhalation entries of UN Nos. 3381 to 3390; Class 8: Packing group I for classification codes CT1, CFT and COT; Class 9: Classification codes M9 and M10. When carried in bulk or in tanks: Class 3 Class 4.2: Packing group II; Class 4.3: Packing group II; Class 6.1: Packing group II; and Packing group III for classification code TF2; Class 8: Packing group I for classification codes CF1, CFT and CW1; and Packing group II for classification codes CF1 and CFT Class 9: Classification codes M2 and M3. Tunnel category E: Restriction for all dangerous goods other than UN Nos. 2919, 3291, 3331, 3359 and 3373. The assessment is based on the intrinsic dangerous properties of the goods, the type of containment and the quantity carried. Copyright © United Nations, 2010. All rights reserved - 96 - NOTE: For the dangerous goods assigned to UN Nos. 2919 and 3331, restrictions to the passage through tunnels may, however, be part of the special arrangement approved by the competent authority(ies) on the basis of 1.7.4.2. 1.9.5.3 Provisions for road signs and notification of restrictions 1.9.5.3.1 Contracting Parties shall indicate tunnel prohibitions and alternative routes by means of signs and signals. 1.9.5.3.2 For this purpose, they may use signs C, 3h and D, 10a, 10b and 10c and signals according to the Vienna Convention on Road Signs and Signals (Vienna, 1968) and the European Agreement supplementing the Convention on Road Signs and Signals (Geneva, 1971) as interpreted by the Resolution on Road Signs and Signals (R.E.2) of the UNECE Inland Transport Committee Principal Working Party on Road Transport, as amended. 1.9.5.3.3 In order to facilitate international understanding of signs, the system of signs and signals prescribed in the Vienna Convention is based on the use of shapes, and colours characteristic of each class of signs and wherever possible, on the use of graphic symbols rather than inscriptions. Where Contracting Parties consider it necessary to modify the signs and symbols prescribed, the modifications made shall not alter their essential characteristics. Where Contracting Parties do not apply the Vienna Convention, the prescribed signs and symbols may be modified, provided that the modifications made shall not alter their essential intent. 1.9.5.3.4 Traffic signs and signals intended to prohibit access of vehicles carrying dangerous goods to road tunnels shall be affixed at a place where the choice of alternative routes is possible. 1.9.5.3.5 When access to tunnels is restricted or alternative routes are prescribed, the signs shall be displayed with additional panels as follows: No sign: no restriction Sign with additional panel bearing the letter B: applies to vehicles carrying dangerous goods not allowed in tunnels of category B; Sign with additional panel bearing the letter C: applies to vehicles carrying dangerous goods not allowed in tunnels of category C; Sign with additional panel bearing the letter D: applies to vehicles carrying dangerous goods not allowed in tunnels of category D; Sign with additional panel bearing the letter E: applies to vehicles carrying dangerous goods not allowed in tunnels of category E. 1.9.5.3.6 Tunnel restrictions shall not apply when dangerous goods are carried in accordance with 1.1.3 1.9.5.3.7 Restrictions shall be published officially and made publicly available. Contracting Parties shall notify the secretariat of UNECE of such restrictions and the secretariat shall make this information publicly available on its website. 1.9.5.3.8 When Contracting Parties apply specific operating measures designed to reduce the risks and related to some or all vehicles using tunnels, such as declaration before entering or passage in convoys escorted by accompanying vehicles, such operating measures shall be published officially and made publicly available. Copyright © United Nations, 2010. All rights reserved - 97 - CHAPTER 1.10 SECURITY PROVISIONS NOTE: For the purposes of this Chapter, security means measures or precautions to be taken to minimise theft or misuse of dangerous goods that may endanger persons, property or the environment. 1.10.1 General provisions 1.10.1.1 All persons engaged in the carriage of dangerous goods shall consider the security requirements set out in this Chapter commensurate with their responsibilities. 1.10.1.2 Dangerous goods shall only be offered for carriage to carriers that have been appropriately identified. 1.10.1.3 Areas within temporary storage terminals, temporary storage sites, vehicle depots, berthing areas and marshalling yards used for the temporary storage during carriage of dangerous goods shall be properly secured, well lit and, where possible and appropriate, not accessible to the general public. 1.10.1.4 Each member of a vehicle crew shall carry with them means of identification, which includes their photograph, during carriage of dangerous goods. 1.10.1.5 Safety inspections in accordance with 1.8.1 and 7.5.1.1 shall cover appropriate security measures. 1.10.1.6 The competent authority shall maintain up-to-date registers of all valid training certificates for drivers stipulated in 8.2.1 issued by it or by any recognized organization. 1.10.2 Security training 1.10.2.1 The training and the refresher training specified in Chapter 1.3 shall also include elements of security awareness. The security refresher training need not be linked to regulatory changes only. 1.10.2.2 Security awareness training shall address the nature of security risks, recognising security risks, methods to address and reduce such risks and actions to be taken in the event of a security breach. It shall include awareness of security plans (if appropriate) commensurate with the responsibilities and duties of individuals and their part in implementing security plans. 1.10.2.3 Such training shall be provided or verified upon employment in a position involving dangerous goods transport and shall be periodically supplemented with refresher training. 1.10.2.4 Records of all security training received shall be kept by the employer and made available to the employee or competent authority, upon request. Records shall be kept by the employer for a period of time established by the competent authority. 1.10.3 Provisions for high consequence dangerous goods 1.10.3.1 "High consequence dangerous goods" are those which have the potential for misuse in a terrorist incident and which may, as a result, produce serious consequences such as mass casualties or mass destruction. The list of high consequence dangerous goods is provided in Table 1.10.5. Copyright © United Nations, 2010. All rights reserved - 98 - 1.10.3.2 Security plans 1.10.3.2.1 Carriers, consignors and other participants specified in 1.4.2 and 1.4.3 engaged in the carriage of high consequence dangerous goods (see Table 1.10.5) shall adopt, implement and comply with a security plan that addresses at least the elements specified in 1.10.3.2.2. 1.10.3.2.2 The security plan shall comprise at least the following elements: (a) Specific allocation of responsibilities for security to competent and qualified persons with appropriate authority to carry out their responsibilities; (b) Records of dangerous goods or types of dangerous goods concerned; (c) Review of current operations and assessment of security risks, including any stops necessary to the transport operation, the keeping of dangerous goods in the vehicle, tank or container before, during and after the journey and the intermediate temporary storage of dangerous goods during the course of intermodal transfer or transhipment between units as appropriate; (d) Clear statement of measures that are to be taken to reduce security risks, commensurate with the responsibilities and duties of the participant, including: - training; - security policies (e.g. response to higher threat conditions, new employee/employment verification, etc.); - operating practices (e.g. choice/use of routes where known, access to dangerous goods in intermediate temporary storage (as defined in (c)), proximity to vulnerable infrastructure etc.); - equipment and resources that are to be used to reduce security risks; (e) Effective and up to date procedures for reporting and dealing with security threats, breaches of security or security incidents; (f) Procedures for the evaluation and testing of security plans and procedures for periodic review and update of the plans; (g) Measures to ensure the physical security of transport information contained in the security plan; and (h) Measures to ensure that the distribution of information relating to the transport operation contained in the security plan is limited to those who need to have it. Such measures shall not preclude the provision of information required elsewhere in ADR. NOTE: Carriers, consignors and consignees should co-operate with each other and with competent authorities to exchange threat information, apply appropriate security measures and respond to security incidents. 1.10.3.3 Devices, equipment or arrangements to prevent the theft of the vehicle carrying high consequence dangerous goods (see Table 1.10.5) and its cargo, shall be applied and measures taken to ensure that these are operational and effective at all times. The application of these protective measures shall not jeopardize emergency response. NOTE: When appropriate and already fitted, the use of transport telemetry or other tracking methods or devices should be used to monitor the movement of high consequence dangerous goods (see Table 1.10.5). Copyright © United Nations, 2010. All rights reserved - 99 - 1.10.4 In accordance with the provisions of 1.1.3.6, the requirements of 1.10.1, 1.10.2, 1.10.3 and 8.1.2.1 (d) do not apply when the quantities carried in packages on a transport unit do not exceed those referred to in 1.1.3.6.3, except for UN Nos. 0104, 0237, 0255, 0267, 0289, 0361, 0365, 0366, 0440, 0441, 0455, 0456 and 0500 (see first indent of 1.1.3.6.2). In addition, the requirements of 1.10.1, 1.10.2, 1.10.3 and 8.1.2.1 (d) do not apply when the quantities carried in tanks or in bulk on a transport unit do not exceed those referred to in 1.1.3.6.3. 1.10.5 High consequence dangerous goods are those listed in the table below and carried in quantities greater than those indicated therein. Table 1.10.5: List of high consequence dangerous goods Quantity Class Division Substance or article Tank (l) c Bulk (kg) d Packages (kg) 1.1 Explosives a a 1.2 Explosives a a 1.3 Compatibility group C explosives a a 1.4 Explosives of UN Nos. 0104, 0237, 0255, 0267, 0289, 0361, 0365, 0366, 0440, 0441, 0455, 0456 and a a 1.5 Explosives a Flammable gases (classification codes including only the letter F) a b Toxic gases (classification codes including letters T, TF, TC, TO, TFC or TOC) excluding aerosols a Flammable liquids of packing groups I and II a b Desensitized explosives a 4.1 Desensitized explosives a a 4.2 Packing group I substances a b 4.3 Packing group I substances a b Oxidizing liquids of packing group I a b 5.1 Perchlorates, ammonium nitrate, ammonium nitrate fertilisers and ammonium nitrate emulsions or suspensions or gels b 6.1 Toxic substances of packing group I a 6.2 Infectious substances of Category A (UN Nos. 2814 and 2900, except for animal material) a Radioactive material 3000 A1 (special form) or 3000 A2, as applicable, in Type B(U), B(M) or C packages Corrosive substances of packing group I a b a Not relevant. b The provisions of 1.10.3 do not apply, whatever the quantity is. c A value indicated in this column is applicable only if carriage in tanks is authorized, in accordance with Chapter 3.2, Table A, column (10) or (12). For substances that are not authorized for carriage in tanks, the instruction in this column is not relevant. d A value indicated in this column is applicable only if carriage in bulk is authorized, in accordance with Chapter 3.2, Table A, column (10) or (17). For substances that are not authorized for carriage in bulk, the instruction in this column is not relevant. Copyright © United Nations, 2010. All rights reserved - 100 - 1.10.6 For radioactive material, the provisions of this Chapter are deemed to be complied with when the provisions of the Convention on Physical Protection of Nuclear Material1 and the IAEA circular on "The Physical Protection of Nuclear Material and Nuclear Facilities"2 are applied. INFCIRC/274/Rev.1, IAEA, Vienna (1980). INFCIRC/225/Rev.4 (Corrected), IAEA, Vienna (1999). See also "Guidance and Considerations for the Implementation of INFCIRC/225/Rev.4, the Physical Protection of Nuclear Material and Nuclear Facilities, IAEA-TECDOC-967/Rev.1. Copyright © United Nations, 2010. All rights reserved - 101 - PART 2 Classification Copyright © United Nations, 2010. All rights reserved - 103 - CHAPTER 2.1 GENERAL PROVISIONS 2.1.1 Introduction 2.1.1.1 The classes of dangerous goods according to ADR are the following: Class 1 Explosive substances and articles Class 2 Gases Class 3 Flammable liquids Class 4.1 Flammable solids, self-reactive substances and solid desensitized explosives Class 4.2 Substances liable to spontaneous combustion Class 4.3 Substances which, in contact with water, emit flammable gases Class 5.1 Oxidizing substances Class 5.2 Organic peroxides Class 6.1 Toxic substances Class 6.2 Infectious substances Class 7 Radioactive material Class 8 Corrosive substances Class 9 Miscellaneous dangerous substances and articles 2.1.1.2 Each entry in the different classes has been assigned a UN number. The following types of entries are used: A. Single entries for well defined substances or articles including entries for substances covering several isomers, e.g.: UN No. 1090 ACETONE UN No. 1104 AMYL ACETATES UN No. 1194 ETHYL NITRITE SOLUTION B. Generic entries for a well defined group of substances or articles, which are not n.o.s. entries, e.g.: UN No. 1133 ADHESIVES UN No. 1266 PERFUMERY PRODUCTS UN No. 2757 CARBAMATE PESTICIDE, SOLID, TOXIC UN No. 3101 ORGANIC PEROXIDE TYPE B, LIQUID C. Specific n.o.s. entries covering a group of substances or articles of a particular chemical or technical nature, not otherwise specified, e.g.: UN No. 1477 NITRATES, INORGANIC, N.O.S. UN No. 1987 ALCOHOLS, N.O.S. D. General n.o.s. entries covering a group of substances or articles having one or more dangerous properties, not otherwise specified, e.g.: UN No. 1325 FLAMMABLE SOLID, ORGANIC, N.O.S. UN No. 1993 FLAMMABLE LIQUID, N.O.S. The entries defined under B., C. and D. are defined as collective entries. Copyright © United Nations, 2010. All rights reserved - 104 - 2.1.1.3 For packing purposes, substances other than those of Classes 1, 2, 5.2, 6.2 and 7, and other than self-reactive substances of Class 4.1 are assigned to packing groups in accordance with the degree of danger they present: Packing group I: Substances presenting high danger; Packing group II: Substances presenting medium danger; Packing group III: Substances presenting low danger. The packing group(s) to which a substance is assigned is (are) indicated in Table A of Chapter 3.2. 2.1.2 Principles of classification 2.1.2.1 The dangerous goods covered by the heading of a class are defined on the basis of their properties according to sub-section 2.2.x.1 of the relevant class. Assignment of dangerous goods to a class and a packing group is made according to the criteria mentioned in the same sub-section 2.2.x.1. Assignment of one or several subsidiary risk(s) to a dangerous substance or article is made according to the criteria of the class or classes corresponding to those risks, as mentioned in the appropriate sub-section(s) 2.2.x.1. 2.1.2.2 All dangerous goods entries are listed in Table A of Chapter 3.2 in the numerical order of their UN Number. This table contains relevant information on the goods listed, such as name, class, packing group(s), label(s) to be affixed, packing and carriage provisions 1. 2.1.2.3 A substance may contain technical impurities (for example those deriving from the production process) or additives for stability or other purposes that do not affect their classification. However, a substance mentioned by name, i.e. listed as a single entry in Table A of Chapter 3.2, containing technical impurities or additives for stability or other purposes affecting its classification shall be considered a solution or mixture (see 2.1.3.3). 2.1.2.4 Dangerous goods which are listed or defined in sub-section 2.2.x.2 of each class are not to be accepted for carriage. 2.1.2.5 Goods not mentioned by name, i.e. goods not listed as single entries in Table A of Chapter 3.2 and not listed or defined in one of the above-mentioned sub-sections 2.2.x.2 shall be assigned to the relevant class in accordance with the procedure of section 2.1.3. In addition, the subsidiary risk (if any) and the packing group (if any) shall be determined. Once the class, subsidiary risk (if any) and packing group (if any) have been established the relevant UN number shall be determined. The decision trees in sub-sections 2.2.x.3 (list of collective entries) at the end of each class indicate the relevant parameters for selecting the relevant collective entry (UN number). In all cases the most specific collective entry covering the properties of the substance or article shall be selected, according to the hierarchy indicated in 2.1.1.2 by the letters B, C and D respectively. If the substance or article cannot be classified under entries of type B or C according to 2.1.1.2, then, and only then shall it be classified under an entry of type D. 2.1.2.6 On the basis of the test procedures of Chapter 2.3 and the criteria set out in sub-sections 2.2.x.1 of classes when it is so specified, it may be determined that a substance, solution or mixture of a certain class, mentioned by name in Table A of Chapter 3.2, does not meet the criteria of that class. In such a case, the substance, solution or mixture is deemed not to belong to that class. Note by the Secretariat: An alphabetic list of these entries has been prepared by the secretariat and is reproduced in Table B of Chapter 3.2. This table is not an official part of the ADR. Copyright © United Nations, 2010. All rights reserved - 105 - 2.1.2.7 For the purposes of classification, substances with a melting point or initial melting point of 20 °C or lower at a pressure of 101.3 kPa shall be considered to be liquids. A viscous substance for which a specific melting point cannot be determined shall be subjected to the ASTM D 4359-90 test or to the test for determining fluidity (penetrometer test) prescribed in 2.3.4. 2.1.3 Classification of substances, including solutions and mixtures (such as preparations and wastes), not mentioned by name 2.1.3.1 Substances including solutions and mixtures not mentioned by name shall be classified according to their degree of danger on the basis of the criteria mentioned in sub-section 2.2.x.1 of the various classes. The danger(s) presented by a substance shall be determined on the basis of its physical and chemical characteristics and physiological properties. Such characteristics and properties shall also be taken into account when such experience leads to a more stringent assignment. 2.1.3.2 A substance not mentioned by name in Table A of Chapter 3.2 presenting a single hazard shall be classified in the relevant class under a collective entry listed in sub-section 2.2.x.3 of that class. 2.1.3.3 A solution or mixture composed of a single predominant substance mentioned by name in Table A of Chapter 3.2 and one or more substances not subject to ADR or traces of one or more substances mentioned by name in Table A of Chapter 3.2, shall be assigned the UN number and proper shipping name of the predominant substance mentioned by name in Table A of Chapter 3.2 unless: (a) The solution or mixture is mentioned by name in Table A of Chapter 3.2; (b) The name and description of the substance mentioned by name in Table A of Chapter 3.2 specifically indicate that they apply only to the pure substance; (c) The class, classification code, packing group, or physical state of the solution or mixture is different from that of the substance mentioned by name in Table A of Chapter 3.2; or (d) The hazard characteristics and properties of the solution or mixture necessitate emergency response measures that are different from those required for the substance mentioned by name in Table A of Chapter 3.2. In those other cases, except the one described in (a), the solution or mixture shall be classified as a substance not mentioned by name in the relevant class under a collective entry listed in sub-section 2.2.x.3 of that class taking account of the subsidiary risks presented by that solution or mixture, if any, unless the solution or mixture does not meet the criteria of any class, in which case it is not subject to ADR. 2.1.3.4 Solutions and mixtures containing substances belonging to one of the entries mentioned in 2.1.3.4.1 or 2.1.3.4.2 shall be classified in accordance with the provisions of these paragraphs. 2.1.3.4.1 Solutions and mixtures containing one of the following substances mentioned by name shall always be classified under the same entry as the substance they contain, provided they do not have the hazard characteristics as indicated in 2.1.3.5.3: Copyright © United Nations, 2010. All rights reserved - 106 - - Class 3 UN No. PROPYLENEIMINE, STABILIZED; UN No. NITROGLYCERIN SOLUTION IN ALCOHOL with more than 1% but not more than 5% nitroglycerin; - Class 6.1 UN No. 1051 HYDROGEN CYANIDE, STABILIZED, containing less than 3% water; UN No. 1185 ETHYLENEIMINE, STABILIZED; UN No. 1259 NICKEL CARBONYL; UN No. 1613 HYDROCYANIC ACID, AQUEOUS SOLUTION (HYDROGEN CYANIDE, AQUEOUS SOLUTION), with not more than 20% hydrogen cyanide; UN No. 1614 HYDROGEN CYANIDE, STABILIZED, containing not more than 3% water and absorbed in a porous inert material; UN No. 1994 IRON PENTACARBONYL; UN No. 2480 METHYL ISOCYANATE; UN No. 2481 ETHYL ISOCYANATE; UN No. 3294 HYDROGEN CYANIDE, SOLUTION IN ALCOHOL, with not more than 45% hydrogen cyanide; - Class 8 UN No. 1052 HYDROGEN FLUORIDE, ANHYDROUS; UN No. 1744 BROMINE or UN No. 1744 BROMINE SOLUTION; UN No. 1790 HYDROFLUORIC ACID with more than 85% hydrogen fluoride; UN No. 2576 PHOSPHORUS OXYBROMIDE, MOLTEN; 2.1.3.4.2 Solutions and mixtures containing a substance belonging to one of the following entries of Class 9: UN No. 2315 POLYCHLORINATED BIPHENYLS, LIQUID; UN No. 3151 POLYHALOGENATED BIPHENYLS, LIQUID; UN No. 3151 POLYHALOGENATED TERPHENYLS, LIQUID; UN No. 3152 POLYHALOGENATED BIPHENYLS, SOLID; UN No. 3152 POLYHALOGENATED TERPHENYLS, SOLID; or UN No. 3432 POLYCHLORINATED BIPHENYLS, SOLID shall always be classified under the same entry of Class 9 provided that: - they do not contain any additional dangerous component other than components of packing group III of classes 3, 4.1, 4.2, 4.3, 5.1, 6.1 or 8; and - they do not have the hazard characteristics as indicated in 2.1.3.5.3. 2.1.3.5 Substances not mentioned by name in Table A of Chapter 3.2, having more than one hazard characteristic and solutions or mixtures containing several dangerous substances shall be classified under a collective entry (see 2.1.2.5) and packing group of the appropriate class in accordance with their hazard characteristics. Such classification according to the hazard characteristics shall be carried out as follows: 2.1.3.5.1 The physical and chemical characteristics and physiological properties shall be determined by measurement or calculation and the substance, solution or mixture shall be classified according to the criteria mentioned in sub-section 2.2.x.1 of the various classes. 2.1.3.5.2 If this determination is not possible without disproportionate cost or effort (as for some kinds of wastes), the substance, solution or mixture shall be classified in the class of the component presenting the major hazard. Copyright © United Nations, 2010. All rights reserved - 107 - 2.1.3.5.3 If the hazard characteristics of the substance, solution or mixture fall within more than one class or group of substances listed below then the substance, solution or mixture shall be classified in the class or group of substances corresponding to the major hazard on the basis of the following order of precedence: (a) Material of Class 7 (apart from radioactive material in excepted packages for which special provision 290 of Chapter 3.3 applies, where the other hazardous properties take precedence); (b) Substances of Class 1; (c) Substances of Class 2; (d) Liquid desensitized explosives of Class 3; (e) Self-reactive substances and solid desensitized explosives of Class 4.1; (f) Pyrophoric substances of Class 4.2; (g) Substances of Class 5.2; (h) Substances of Class 6.1 or Class 3 which, on the basis of their inhalation toxicity, are to be classified under Packing group I (Substances meeting the classification criteria of Class 8 and having an inhalation toxicity of dust and mist (LC50) in the range of Packing group I and a toxicity through oral ingestion or dermal contact only in the range of Packing group III or less, shall be allocated to Class 8); (i) Infectious substances of Class 6.2. 2.1.3.5.4 If the hazard characteristics of the substance fall within more than one class or group of substances not listed in 2.1.3.5.3 above, the substance shall be classified in accordance with the same procedure but the relevant class shall be selected according to the precedence of hazards table in 2.1.3.10. 2.1.3.5.5 If the substance to be carried is a waste, with a composition that is not precisely known, its assignment to a UN number and packing group in accordance with 2.1.3.5.2 may be based on the consignor’s knowledge of the waste, including all available technical and safety data as requested by safety and environmental legislation in force 2. In case of doubt, the highest danger level shall be taken. If however, on the basis of the knowledge of the composition of the waste and the physical and chemical properties of the identified components, it is possible to demonstrate that the properties of the waste do not correspond to the properties of the packing group I level, the waste may be classified by default in the most appropriate n.o.s. entry of packing group II. This procedure may not be used for wastes containing substances mentioned in 2.1.3.5.3, substances of Class 4.3, substances of the case mentioned in 2.1.3.7 or substances which are not accepted for carriage in accordance with 2.2.x.2. Such legislation is for instance the Commission Decision 2000/532/EC of 3 May 2000 replacing Decision 94/3/EC establishing a list of wastes pursuant to Article 1(a) of Council Directive 75/442/EEC on waste (replaced by the Directive 2006/12/EC of the European Parliament and of the Council (Official Journal of the European Union No. L 114 of 27 April 2006, page 9)) and Council Decision 94/904/EC establishing a list of hazardous wastes pursuant to Article 1(4) of Council Directive 91/689/EEC on hazardous wastes (Official Journal of the European Communities No. L 226 of 6 September 2000, page 3). Copyright © United Nations, 2010. All rights reserved - 108 - 2.1.3.6 The most specific applicable collective entry (see 2.1.2.5) shall always be used, i.e. a general n.o.s. entry shall only be used if a generic entry or a specific n.o.s. entry cannot be used. 2.1.3.7 Solutions and mixtures of oxidizing substances or substances with an oxidizing subsidiary risk may have explosive properties. In such a case they are not to be accepted for carriage unless they meet the requirements for Class 1. 2.1.3.8 Substances of classes 1 to 9, other than those assigned to UN Nos. 3077 or 3082, meeting the criteria of 2.2.9.1.10 are additionally to their hazards of classes 1 to 9 considered to be environmentally hazardous substances. Other substances meeting the criteria of 2.2.9.1.10 are to be assigned to UN Nos. 3077 or 3082 as appropriate. 2.1.3.9 Wastes that do not meet the criteria for classification in classes 1 to 9 but are covered by the Basel Convention on the Control of Transboundary Movements of Hazardous Wastes and their Disposal may be carried under UN Nos. 3077 or 3082. Copyright © United Nations, 2010. All rights reserved - 109 - 2.1.3.10 Table of precedence of hazards Class and packing group 4.1, II 4.1, III 4.2, II 4.2, III 4.3, I 4.3, II 4.3, III 5.1, I 5.1, II 5.1, III 6.1, I DERMAL 6.1, I ORAL 6.1, II 6.1, III 8, I 8, II 8, III 3, I SOL LIQ 4.1 3, I SOL LIQ 4.1 3, I SOL LIQ 4.2 3, I SOL LIQ 4.2 3, I 4.3, I 4.3, I 4.3, I SOL LIQ 5.1, I 3, I SOL LIQ 5.1, I 3, I SOL LIQ 5.1, I 3, I 3, I 3, I 3, I 3, I 3, I 3, I 3, I 3, I 3, II SOL LIQ 4.1 3, II SOL LIQ 4.1 3, II SOL LIQ 4.2 3, II SOL LIQ 4.2 3, II 4.3, I 4.3, II 4.3, II SOL LIQ 5.1, I 3, I SOL LIQ 5.1, II 3, II SOL LIQ 5.1, II 3, II 3, I 3, I 3, II 3, II 8, I 3, II 3, II 3, II 3, III SOL LIQ 4.1 3, II SOL LIQ 4.1 3, III SOL LIQ 4.2 3, II SOL LIQ 4.2 3, III 4.3, I 4.3, II 4.3, III SOL LIQ 5.1, I 3, I SOL LIQ 5.1, II 3, II SOL LIQ 5.1, III 3, III 6.1, I 6.1, I 6.1, II 3, III a 8, I 8, II 3, III 3, III 4.1, II 4.2, II 4.2, II 4.3, I 4.3, II 4.3, II 5.1, I 4.1, II 4.1, II 6.1, I 6.1, I SOL LIQ 4.1, II 6.1, II SOL LIQ 4.1, II 6.1, II 8, I SOL LIQ 4.1, II 8, II SOL LIQ 4.1, II 8, II 4.1, II 4.1, III 4.2, II 4.2, III 4.3, I 4.3, II 4.3, III 5.1, I 4.1, II 4.1, III 6.1, I 6.1, I 6.1, II SOL LIQ 4.1, III 6.1, III 8, I 8, II SOL LIQ 4.1, III 8, III 4.1, III 4.2, II 4.3, I 4.3, II 4.3, II 5.1, I 4.2, II 4.2, II 6.1, I 6.1, I 4.2, II 4.2, II 8, I 4.2, II 4.2, II 4.2, II 4.2, III 4.3, I 4.3, II 4.3, III 5.1, I 5.1, II 4.2, III 6.1, I 6.1, I 6.1, II 4.2, III 8, I 8, II 4.2, III 4.2, III 4.3, I 5.1, I 4.3, I 4.3, I 6.1, I 4.3, I 4.3, I 4.3, I 4.3, I 4.3, I 4.3, I 4.3, I 4.3, II 5.1, I 4.3, II 4.3, II 6.1, I 4.3, I 4.3, II 4.3, II 8, I 4.3, II 4.3, II 4.3, II 4.3, III 5.1, I 5.1, II 4.3, III 6.1, I 6.1, I 6.1, II 4.3, III 8, I 8, II 4.3, III 4.3, III 5.1, I 5.1, I 5.1, I 5.1, I 5.1, I 5.1, I 5.1, I 5.1, I 5.1, I 5.1, II 6.1, I 5.1, I 5.1, II 5.1, II 8, I 5.1, II 5.1, II 5.1, II 5.1, III 6.1, I 6.1, I 6.1, II 5.1, III 8, I 8, II 5.1, III 5.1, III 6.1, I DERMAL SOL LIQ 6.1, I 8, I 6.1, I 6.1, I 6.1, I 6.1, I ORAL SOL LIQ 6.1, I 8, I 6.1, I 6.1, I 6.1, I 6.1, II INHAL SOL LIQ 6.1, I 8, I 6.1, II 6.1, II 6.1, II 6.1, II DERMAL SOL LIQ 6.1, I 8, I SOL LIQ 6.1, II 8, II 6.1, II 6.1, II 6.1, II ORAL 8.1 SOL LIQ 6.1, II 8, II 6.1, II 6.1, II 6.1, III 8, I 8, II 8, III 6.1, III 8, I 8, I 8, II 8, II 8, III SOL = Solid substances and mixtures LIQ = Liquid substances, mixtures and solutions DERMAL = Dermal toxicity ORAL = Oral toxicity INHAL = Inhalation toxicity a Class 6.1 for pesticides 8, III Copyright © United Nations, 2010. All rights reserved - 110 - NOTE 1: Examples to explain the use of the table Classification of a single substance Description of the substance to be classified: An amine not mentioned by name meeting the criteria for Class 3, packing group II as well as those for Class 8, packing group I. Procedure: The intersection of line 3 II with column 8 I gives 8 I. This amine has therefore to be classified in Class 8 under: UN No. 2734 AMINES LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or UN No. 2734 POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. packing group I Classification of a mixture Description of the mixture to be classified: Mixture consisting of a flammable liquid classified in Class 3, packing group III, a toxic substance in Class 6.1, packing group II and a corrosive substance in Class 8, packing group I. Procedure: The intersection of line 3 III with column 6.1 II gives 6.1 II. The intersection of line 6.1 II with column 8 I gives 8 I LIQ. This mixture not further defined has therefore to be classified in Class 8 under: UN No. 2922 CORROSIVE LIQUID, TOXIC, N.O.S. packing group I. NOTE 2: Examples for the classification of mixtures and solutions under a class and a packing group: A phenol solution of Class 6.1, (II), in benzene of Class 3, (II) is to be classified in Class 3, (II); this solution is to be classified under UN No. 1992 FLAMMABLE LIQUID, TOXIC, N.O.S., Class 3, (II), by virtue of the toxicity of the phenol. A solid mixture of sodium arsenate of Class 6.1, (II) and sodium hydroxide of Class 8, (II) is to be classified under UN No. 3290 TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S., in Class 6.1 (II). A solution of crude or refined naphthalene of Class 4.1, (III) in petrol of Class 3, (II), is to be classified under UN No. 3295 HYDROCARBONS, LIQUID, N.O.S. in Class 3, (II). A mixture of hydrocarbons of Class 3, (III), and of polychlorinated biphenyls (PCB) of Class 9, (II), is to be classified under UN No. 2315 POLYCHLORINATED BIPHENYLS LIQUID or UN No. 3432 POLYCHLORINATED BIPHENYLS SOLID in Class 9, (II). A mixture of propyleneimine of Class 3, and polychlorinated biphenyls (PCB) of Class 9, (II), is to be classified under UN No. 1921 PROPYLENEIMINE, INHIBITED in Class 3. Copyright © United Nations, 2010. All rights reserved - 111 - 2.1.4 Classification of samples 2.1.4.1 When the class of a substance is uncertain and it is being carried for further testing, a tentative class, proper shipping name and UN number shall be assigned on the basis of the consignor's knowledge of the substance and application of: (a) the classification criteria of Chapter 2.2; and (b) the requirements of this Chapter. The most severe packing group possible for the proper shipping name chosen shall be used. Where this provision is used the proper shipping name shall be supplemented with the word "SAMPLE" (e.g., "FLAMMABLE LIQUID, N.O.S., SAMPLE"). In certain instances, where a specific proper shipping name is provided for a sample of a substance considered to meet certain classification criteria (e.g., GAS SAMPLE, NON-PRESSURIZED, FLAMMABLE, UN No. 3167) that proper shipping name shall be used. When an N.O.S. entry is used to carry the sample, the proper shipping name need not be supplemented with the technical name as required by special provision 274 of Chapter 3.3. 2.1.4.2 Samples of the substance shall be carried in accordance with the requirements applicable to the tentative assigned proper shipping name provided: (a) The substance is not considered to be a substance not accepted for carriage by sub-sections 2.2.x.2 of Chapter 2.2 or by Chapter 3.2; (b) The substance is not considered to meet the criteria for Class 1 or considered to be an infectious substance or a radioactive material; (c) The substance is in compliance with 2.2.41.1.15 or 2.2.52.1.9 if it is a self-reactive substance or an organic peroxide, respectively; (d) The sample is carried in a combination packaging with a net mass per package not exceeding 2.5 kg; and (e) The sample is not packed together with other goods. Copyright © United Nations, 2010. All rights reserved - 113 - CHAPTER 2.2 CLASS SPECIFIC PROVISIONS 2.2.1 Class 1 Explosive substances and articles 2.2.1.1 Criteria 2.2.1.1.1 The heading of Class 1 covers: (a) Explosive substances: solid or liquid substances (or mixtures of substances) capable by chemical reaction of producing gases at such a temperature and pressure and at such a speed as to cause damage to the surroundings. Pyrotechnic substances: substances or mixtures of substances designed to produce an effect by heat, light, sound, gas or smoke or a combination of these as the result of non-detonating self-sustaining exothermic chemical reactions; NOTE 1: Substances which are not themselves explosive but which may form an explosive mixture of gas, vapour or dust are not substances of Class 1. NOTE 2: Also excluded from Class 1 are: water- or alcohol-wetted explosives of which the water or alcohol content exceeds the limits specified and those containing plasticizers - these explosives are assigned to Class 3 or Class 4.1 - and those explosives which, on the basis of their predominant hazard, are assigned to Class 5.2. (b) Explosive articles: articles containing one or more explosive or pyrotechnic substances; NOTE: Devices containing explosive or pyrotechnic substances in such small quantity or of such a character that their inadvertent or accidental ignition or initiation during carriage would not cause any manifestation external to the device by projection, fire, smoke, heat or loud noise are not subject to the requirements of Class 1. (c) Substances and articles not mentioned above which are manufactured with a view to producing a practical effect by explosion or a pyrotechnic effect. For the purposes of Class 1, the following definition applies: Phlegmatized means that a substance (or "phlegmatizer") has been added to an explosive to enhance its safety in handling and carriage. The phlegmatizer renders the explosive insensitive, or less sensitive, to the following actions: heat, shock, impact, percussion or friction. Typical phlegmatizing agents include, but are not limited to: wax, paper, water, polymers (such as chlorofluoropolymers), alcohol and oils (such as petroleum jelly and paraffin). 2.2.1.1.2 Any substance or article having or suspected of having explosive properties shall be considered for assignment to Class 1 in accordance with the tests, procedures and criteria prescribed in Part I, Manual of Tests and Criteria. A substance or article assigned to Class 1 can only be accepted for carriage when it has been assigned to a name or n.o.s. entry listed in Table A of Chapter 3.2 and meets the criteria of the Manual of Tests and Criteria. Copyright © United Nations, 2010. All rights reserved - 114 - 2.2.1.1.3 The substances and articles of Class 1 shall be assigned to a UN Number and a name or n.o.s. entry listed in Table A of Chapter 3.2. Interpretation of the names of substances and articles in Table A of Chapter 3.2 shall be based upon the glossary in 2.2.1.1.8. Samples of new or existing explosive substances or articles carried for purposes including: testing, classification, research and development quality control, or as a commercial sample, other than initiating explosive, may be assigned to UN No. 0190 SAMPLES, EXPLOSIVE. The assignment of explosive substances and articles not mentioned by name as such in Table A of Chapter 3.2 to an n.o.s entry of Class 1 or UN No. 0190 SAMPLES, EXPLOSIVE as well as the assignment of certain substances the carriage of which is subject to a specific authorization by the competent authority according to the special provisions referred to in Column (6) of Table A of Chapter 3.2 shall be made by the competent authority of the country of origin. This competent authority shall also approve in writing the conditions of carriage of these substances and articles. If the country of origin is not a Contracting Party to ADR, the classification and the conditions of carriage shall be recognized by the competent authority of the first country Contracting Party to ADR reached by the consignment. 2.2.1.1.4 Substances and articles of Class 1 shall have been assigned to a division in accordance with 2.2.1.1.5 and to a compatibility group in accordance with 2.2.1.1.6. The division shall be based on the results of the tests described in 2.3.0 and 2.3.1 applying the definitions in 2.2.1.1.5. The compatibility group shall be determined in accordance with the definitions in 2.2.1.1.6. The classification code shall consist of the division number and the compatibility group letter. 2.2.1.1.5 Definition of divisions Division 1.1 Substances and articles which have a mass explosion hazard (a mass explosion is an explosion which affects almost the entire load virtually instantaneously). Division 1.2 Substances and articles which have a projection hazard but not a mass explosion hazard. Division 1.3 Substances and articles which have a fire hazard and either a minor blast hazard or a minor projection hazard or both, but not a mass explosion hazard: (a) combustion of which gives rise to considerable radiant heat; or (b) which burn one after another, producing minor blast or projection effects or both. Division 1.4 Substances and articles which present only a slight risk of explosion in the event of ignition or initiation during carriage. The effects are largely confined to the package and no projection of fragments of appreciable size or range is to be expected. An external fire shall not cause virtually instantaneous explosion of almost the entire contents of the package. Division 1.5 Very insensitive substances having a mass explosion hazard which are so insensitive that there is very little probability of initiation or of transition from burning to detonation under normal conditions of carriage. As a minimum requirement they must not explode in the external fire test. Copyright © United Nations, 2010. All rights reserved - 115 - Division 1.6 Extremely insensitive articles which do not have a mass explosion hazard. The articles contain only extremely insensitive detonating substances and demonstrate a negligible probability of accidental initiation or propagation. NOTE: The risk from articles of Division 1.6 is limited to the explosion of a single article. 2.2.1.1.6 Definition of compatibility groups of substances and articles A Primary explosive substance. B Article containing a primary explosive substance and not having two or more effective protective features. Some articles, such as detonators for blasting, detonator assemblies for blasting and primers, cap-type, are included, even though they do not contain primary explosives. C Propellant explosive substance or other deflagrating explosive substance or article containing such explosive substance. D Secondary detonating explosive substance or black powder or article containing a secondary detonating explosive substance, in each case without means of initiation and without a propelling charge, or article containing a primary explosive substance and having two or more effective protective features. E Article containing a secondary detonating explosive substance, without means of initiation, with a propelling charge (other than one containing a flammable liquid or gel or hypergolic liquids). F Article containing a secondary detonating explosive substance with its own means of initiation, with a propelling charge (other than one containing a flammable liquid or gel or hypergolic liquids) or without a propelling charge. G Pyrotechnic substance, or article containing a pyrotechnic substance, or article containing both an explosive substance and an illuminating, incendiary, tear- or smoke-producing substance (other than a water-activated article or one which contains white phosphorus, phosphides, a pyrophoric substance, a flammable liquid or gel or hypergolic liquids). H Article containing both an explosive substance and white phosphorus. J Article containing both an explosive substance and a flammable liquid or gel. K Article containing both an explosive substance and a toxic chemical agent. L Explosive substance or article containing an explosive substance and presenting a special risk (e.g. due to water activation or the presence of hypergolic liquids, phosphides or a pyrophoric substance) necessitating isolation of each type. N Articles containing only extremely insensitive detonating substances. S Substance or article so packed or designed that any hazardous effects arising from accidental functioning are confined within the package unless the package has been degraded by fire, in which case all blast or projection effects are limited to the extent that they do not significantly hinder or prevent fire-fighting or other emergency response efforts in the immediate vicinity of the package. Copyright © United Nations, 2010. All rights reserved - 116 - NOTE 1: Each substance or article, packed in a specified packaging, may be assigned to one compatibility group only. Since the criterion of compatibility group S is empirical, assignment to this group is necessarily linked to the tests for assignment of a classification code. NOTE 2: Articles of compatibility groups D and E may be fitted or packed together with their own means of initiation provided that such means have at least two effective protective features designed to prevent an explosion in the event of accidental functioning of the means of initiation. Such articles and packages shall be assigned to compatibility groups D or E. NOTE 3: Articles of compatibility groups D and E may be packed together with their own means of initiation, which do not have two effective protective features (i.e. means of initiation assigned to compatibility group B), provided that they comply with mixed packing provision MP21 of Section 4.1.10. Such packages shall be assigned to compatibility groups D or E. NOTE 4: Articles may be fitted or packed together with their own means of ignition provided that the means of ignition cannot function during normal conditions of carriage. NOTE 5: Articles of compatibility groups C, D and E may be packed together. Such packages shall be assigned to compatibility group E. 2.2.1.1.7 Assignment of fireworks to divisions 2.2.1.1.7.1 Fireworks shall normally be assigned to divisions 1.1, 1.2, 1.3, and 1.4 on the basis of test data derived from Test Series 6 of the Manual of Tests and Criteria. However, since the range of such articles is very extensive and the availability of test facilities may be limited, assignment to divisions may also be made in accordance with the procedure in 2.2.1.1.7.2. 2.2.1.1.7.2 Assignment of fireworks to UN Nos. 0333, 0334, 0335 and 0336 may be made on the basis of analogy, without the need for Test Series 6 testing, in accordance with the default fireworks classification table in 2.2.1.1.7.5. Such assignment shall be made with the agreement of the competent authority. Items not specified in the table shall be classified on the basis of test data derived from Test Series 6. NOTE 1: The addition of other types of fireworks to column 1 of the table in 2.2.1.1.7.5 shall only be made on the basis of full test data submitted to the UN Sub-Committee of Experts on the Transport of Dangerous Goods for consideration. NOTE 2: Test data derived by competent authorities which validates, or contradicts the assignment of fireworks specified in column 4 of the table in 2.2.1.1.7.5 to divisions in column 5 should be submitted to the UN Sub-Committee of Experts on the Transport of Dangerous Goods for information. 2.2.1.1.7.3 Where fireworks of more than one division are packed in the same package, they shall be classified on the basis of the most dangerous division unless test data derived from Test Series 6 indicate otherwise. 2.2.1.1.7.4 The classification shown in the table in 2.2.1.1.7.5 applies only for articles packed in fibreboard boxes (4G). Copyright © United Nations, 2010. All rights reserved - 117 - 2.2.1.1.7.5 Default fireworks classification table 1 NOTE 1: References to percentages in the table, unless otherwise stated, are to the mass of all pyrotechnic substances (e.g. rocket motors, lifting charge, bursting charge and effect charge). NOTE 2: "Flash composition" in this table refers to pyrotechnic substances in powder form or as pyrotechnic units as presented in the fireworks, that are used to produce an aural effect, or used as a bursting charge or lifting charge, unless the time taken for the pressure rise is demonstrated to be more than 8 ms for 0.5 g of pyrotechnic substance in the HSL Flash Composition Test in Appendix 7 of the Manual of Tests and Criteria. NOTE 3: Dimensions in mm refer to: - for spherical and peanut shells the diameter of the sphere of the shell; - for cylinder shells the length of the shell; - for a shell in mortar, Roman candle, shot tube firework or mine the inside diameter of the tube comprising or containing the firework; - for a bag mine or cylinder mine, the inside diameter of the mortar intended to contain the mine. This table contains a list of firework classifications which may be used in the absence of Test Series 6 data (see 2.2.1.1.7.2). Copyright © United Nations, 2010. All rights reserved - 118 - Type Includes: / Synonym: Definition Specification Classification All report shells 1.1G Colour shell: t 180 mm 1.1G Colour shell: < 180 mm with > 25% flash composition, as loose powder and/or report effects 1.1G Colour shell: < 180 mm with d 25% flash composition, as loose powder and/or report effects 1.3G Shell, spherical or cylindrical Spherical display shell: aerial shell, colour shell, dye shell, multi-break shell, multi-effect shell, nautical shell, parachute shell, smoke shell, star shell; report shell: maroon, salute, sound shell, thunderclap, aerial shell kit Device with or without propellant charge, with delay fuse and bursting charge, pyrotechnic unit(s) or loose pyrotechnic substance and designed to be projected from a mortar Colour shell: d 50 mm, or d 60 g pyrotechnic substance, with d 2% flash composition as loose powder and/or report effects 1.4G Peanut shell Device with two or more spherical aerial shells in a common wrapper propelled by the same propellant charge with separate external delay fuses The most hazardous spherical aerial shell determines the classification All report shells 1.1G Colour shell: t 180 mm 1.1G Colour shell: > 25% flash composition as loose powder and/or report effects 1.1G Colour shell: > 50 mm and < 180 mm 1.2G Preloaded mortar, shell in mortar Assembly comprising a spherical or cylindrical shell inside a mortar from which the shell is designed to be projected Colour shell: d 50 mm, or d 60 g pyrotechnic substance, with d 25% flash composition as loose powder and/or report effects 1.3G Copyright © United Nations, 2010. All rights reserved - 119 - Type Includes: / Synonym: Definition Specification Classification Device without propellant charge, with delay fuse and bursting charge, containing report shells and inert materials and designed to be projected from a mortar > 120 mm 1.1G Device without propellant charge, with delay fuse and bursting charge, containing report shells  25g flash composition per report unit, with  33% flash composition and t 60% inert materials and designed to be projected from a mortar  120 mm 1.3G Device without propellant charge, with delay fuse and bursting charge, containing colour shells and/or pyrotechnic units and designed to be projected from a mortar > 300 mm 1.1G Device without propellant charge, with delay fuse and bursting charge, containing colour shells  70mm and/or pyrotechnic units, with  25% flash composition and  60% pyrotechnic substance and designed to be projected from a mortar > 200 mm and  300 mm 1.3G Shell, spherical or cylindrical (cont'd) Shell of shells (spherical) (Reference to percentages for shell of shells are to the gross mass of the fireworks article) Device with propellant charge, with delay fuse and bursting charge, containing colour shells  70 mm and/or pyrotechnic units, with  25% flash composition and  60% pyrotechnic substance and designed to be projected from a mortar  200 mm 1.3G Battery/ combination Barrage, bombardos, cakes, finale box, flowerbed, hybrid, multiple tubes, shell cakes, banger batteries, flash banger batteries Assembly including several elements either containing the same type or several types each corresponding to one of the types of fireworks listed in this table, with one or two points of ignition The most hazardous firework type determines the classification Copyright © United Nations, 2010. All rights reserved - 120 - Type Includes: / Synonym: Definition Specification Classification t 50 mm inner diameter, containing flash composition, or < 50 mm with > 25% flash composition 1.1G t 50 mm inner diameter, containing no flash composition 1.2G < 50 mm inner diameter and  25% flash composition 1.3G Roman candle Exhibition candle, candle, bombettes Tube containing a series of pyrotechnic units consisting of alternate pyrotechnic substance, propellant charge, and transmitting fuse d 30 mm inner diameter, each pyrotechnic unit  25 g and  5% flash composition 1.4G  30 mm inner diameter and pyrotechnic unit > 25 g, or > 5% and  25% flash composition 1.3G Shot tube Single shot Roman candle, small preloaded mortar Tube containing a pyrotechnic unit consisting of pyrotechnic substance, propellant charge with or without transmitting fuse d 30 mm inner diameter, pyrotechnic unit  25 g and  5% flash composition 1.4G Flash composition effects only 1.1G Flash composition > 25% of the pyrotechnic substance 1.1G > 20 g pyrotechnic substance and flash composition  25% 1.3G Rocket Avalanche rocket, signal rocket, whistling rocket, bottle rocket, sky rocket, missile type rocket, table rocket Tube containing pyrotechnic substance and/or pyrotechnic units, equipped with stick(s) or other means for stabilization of flight, and designed to be propelled into the air d 20 g pyrotechnic substance, black powder bursting charge and  0.13 g flash composition per report and  1 g in total 1.4G Copyright © United Nations, 2010. All rights reserved - 121 - Type Includes: / Synonym: Definition Specification Classification > 25% flash composition, as loose powder and/ or report effects 1.1G t 180 mm and d 25% flash composition, as loose powder and/ or report effects 1.1G < 180 mm and d 25% flash composition, as loose powder and/ or report effects 1.3G Mine Pot-a-feu, ground mine, bag mine, cylinder mine Tube containing propellant charge and pyrotechnic units and designed to be placed on the ground or to be fixed in the ground. The principal effect is ejection of all the pyrotechnic units in a single burst producing a widely dispersed visual and/or aural effect in the air or: Cloth or paper bag or cloth or paper cylinder containing propellant charge and pyrotechnic units, designed to be placed in a mortar and to function as a mine d 150 g pyrotechnic substance, containing d 5% flash composition as loose powder and/ or report effects. Each pyrotechnic unit d 25 g, each report effect < 2g; each whistle, if any, d 3 g 1.4G t 1 kg pyrotechnic substance 1.3G Fountain Volcanos, gerbs, showers, lances, Bengal fire, flitter sparkle, cylindrical fountains, cone fountains, illuminating torch Non-metallic case containing pressed or consolidated pyrotechnic substance producing sparks and flame < 1 kg pyrotechnic substance 1.4G Perchlorate based sparklers: > 5 g per item or > 10 items per pack 1.3G Sparkler Handheld sparklers, non-handheld sparklers, wire sparklers Rigid wire partially coated (along one end) with slow burning pyrotechnic substance with or without an ignition tip Perchlorate based sparklers:  5 g per item and  10 items per pack; Nitrate based sparklers:  30 g per item 1.4G Copyright © United Nations, 2010. All rights reserved - 122 - Type Includes: / Synonym: Definition Specification Classification Perchlorate based items: > 5 g per item or > 10 items per pack 1.3 G Bengal stick Dipped stick Non-metallic stick partially coated (along one end) with slow-burning pyrotechnic substance and designed to be held in the hand Perchlorate based items:  5 g per item and  10 items per pack; nitrate based items:  30 g per item 1.4G Low hazard fireworks and novelties Table bombs, throwdowns, crackling granules, smokes, fog, snakes, glow worm, serpents, snaps, party poppers Device designed to produce very limited visible and/ or audible effect which contains small amounts of pyrotechnic and/or explosive composition. Throwdowns and snaps may contain up to 1.6 mg of silver fulminate; snaps and party poppers may contain up to 16 mg of potassium chlorate/red phosphorous mixture; other articles may contain up to 5 g of pyrotechnic substance, but no flash composition 1.4G Pyrotechnic substance per item > 20 g, containing d 3% flash composition as report effects, or whistle composition d 5 g 1.3G Spinner Aerial spinner, helicopter, chaser, ground spinner Non-metallic tube or tubes containing gas- or spark-producing pyrotechnic substance, with or without noise producing composition, with or without aerofoils attached Pyrotechnic substance per item d 20 g, containing d 3% flash composition as report effects, or whistle composition d 5 g 1.4G t 1 kg total pyrotechnic substance, no report effect, each whistle (if any) d 25 g and  50 g whistle composition per wheel 1.3G Wheels Catherine wheels, Saxon Assembly including drivers containing pyrotechnic substance and provided with a means of attaching it to a support so that it can rotate < 1 kg total pyrotechnic substance, no report effect, each whistle (if any) d 5 g and  10 g whistle composition per wheel 1.4G Copyright © United Nations, 2010. All rights reserved - 123 - Type Includes: / Synonym: Definition Specification Classification > 200 g total pyrotechnic substance or > 60 g pyrotechnic substance per driver, d 3% flash composition as report effects, each whistle (if any) d 25 g and  50 g whistle composition per wheel 1.3G Aerial wheel Flying Saxon, UFO's, rising crown Tubes containing propellant charges and sparksflame- and/or noise producing pyrotechnic substances, the tubes being fixed to a supporting ring d 200 g total pyrotechnic substance and d 60 g pyrotechnic substance per driver, d 3% flash composition as report effects, each whistle (if any) d 5 g and  10 g whistle composition per wheel 1.4G Selection pack Display selection box, display selection pack, garden selection box, indoor selection box; assortment A pack of more than one type each corresponding to one of the types of fireworks listed in this table The most hazardous firework type determines the classification Firecracker Celebration cracker, celebration roll, string cracker Assembly of tubes (paper or cardboard) linked by a pyrotechnic fuse, each tube intended to produce an aural effect Each tube  140 mg of flash composition or  1 g black powder 1.4G > 2 g flash composition per item 1.1G d 2 g flash composition per item and  10 g per inner packaging 1.3G Banger Salute, flash banger, lady cracker Non-metallic tube containing report composition intended to produce an aural effect d 1 g flash composition per item and  10 g per inner packaging or  10 g black powder per item 1.4G Copyright © United Nations, 2010. All rights reserved - 124 - 2.2.1.1.8 Glossary of names NOTE 1: The descriptions in the glossary are not intended to replace the test procedures, nor to determine the hazard classification of a substance or article of Class 1. Assignment to the correct division and a decision on whether Compatibility Group S is appropriate shall be based on testing of the product in accordance with the Manual of Tests and Criteria, Part I or by analogy with similar products which have already been tested and assigned in accordance with the procedures of the Manual of Tests and Criteria. NOTE 2: The figures given after the names refer to the relevant UN numbers (Column 1 of Table A of Chapter 3.2). For the classification code, see 2.2.1.1.4. AIR BAG INFLATORS or AIR BAG MODULES or SEAT-BELT PRETENSIONERS: UN No. 0503 Articles which contain pyrotechnic substances and are used as life-saving vehicle airbags or seat-belts. AMMUNITION, ILLUMINATING, with or without burster, expelling charge or propelling charge: UN Nos. 0171, 0254, 0297 Ammunition designed to produce a single source of intense light for lighting up an area. The term includes illuminating cartridges, grenades and projectiles; and illuminating and target identification bombs. NOTE: The following articles: CARTRIDGES, SIGNAL; SIGNAL DEVICES HAND; SIGNALS, DISTRESS; FLARES, AERIAL; FLARES, SURFACE are not included in this definition. They are listed separately. AMMUNITION, INCENDIARY, liquid or gel, with burster, expelling charge or propelling charge: UN No. 0247 Ammunition containing liquid or gelatinous incendiary substance. Except when the incendiary substance is an explosive per se, it also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. AMMUNITION, INCENDIARY, WHITE PHOSPHORUS with burster, expelling charge or propelling charge: UN Nos. 0243, 0244 Ammunition containing white phosphorus as incendiary substance. It also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge: UN Nos. 0009, 0010, 0300 Ammunition containing incendiary composition. Except when the composition is an explosive per se, it also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. AMMUNITION, PRACTICE: UN Nos. 0362, 0488 Ammunition without a main bursting charge, containing a burster or expelling charge. Normally it also contains a fuze and a propelling charge. NOTE: GRENADES, PRACTICE are not included in this definition. They are listed separately. Copyright © United Nations, 2010. All rights reserved - 125 - AMMUNITION, PROOF: UN No. 0363 Ammunition containing pyrotechnic substances, used to test the performance or strength of new ammunition, weapon components or assemblies. AMMUNITION, SMOKE, WHITE PHOSPHORUS, with burster, expelling charge or propelling charge: UN Nos. 0245, 0246 Ammunition containing white phosphorus as a smoke-producing substance. It also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. The term includes grenades, smoke. AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge: UN Nos. 0015, 0016, 0303 Ammunition containing a smoke-producing substance such as chlorosulphonic acid mixture or titanium tetrachloride; or a smoke-producing pyrotechnic composition based on hexachloroethane or red phosphorus. Except when the substance is an explosive per se, the ammunition also contains one or more of the following: a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. The term includes grenades, smoke. NOTE: SIGNALS, SMOKE are not included in this definition. They are listed separately. AMMUNITION, TEAR-PRODUCING, with burster, expelling charge or propelling charge: UN Nos. 0018, 0019, 0301 Ammunition containing a tear-producing substance. It also contains one or more of the following: a pyrotechnic substance; a propelling charge with primer and igniter charge; a fuze with burster or expelling charge. ARTICLES, EXPLOSIVE, EXTREMELY INSENSITIVE (ARTICLES EEI): UN No. 0486 Articles containing only extremely insensitive detonating substances (EIDS) which demonstrate a negligible probability of accidental initiation or propagation under normal conditions of transport, and which have passed Test Series 7. ARTICLES, PYROPHORIC: UN No. 0380 Articles which contain a pyrophoric substance (capable of spontaneous ignition when exposed to air) and an explosive substance or component. The term excludes articles containing white phosphorus. ARTICLES, PYROTECHNIC, for technical purposes: UN Nos. 0428, 0429, 0430, 0431, Articles which contain pyrotechnic substances and are used for technical purposes such as heat generation, gas generation, theatrical effects, etc. NOTE: The following articles: all ammunition; CARTRIDGES, SIGNAL; CUTTERS, CABLE, EXPLOSIVE; FIREWORKS; FLARES, AERIAL; FLARES, SURFACE; RELEASE DEVICES, EXPLOSIVE; RIVETS, EXPLOSIVE; SIGNAL DEVICES, HAND; SIGNALS, DISTRESS; SIGNALS, RAILWAY TRACK, EXPLOSIVES; SIGNALS, SMOKE are not included in this definition. They are listed separately. Copyright © United Nations, 2010. All rights reserved - 126 - BLACK POWDER (GUNPOWDER), COMPRESSED or BLACK POWDER (GUNPOWDER), IN PELLETS: UN No. 0028 Substance consisting of a pelletized form of black powder. BLACK POWDER (GUNPOWDER), granular or as meal: UN No. 0027 Substance consisting of an intimate mixture of charcoal or other carbon and either potassium nitrate or sodium nitrate, with or without sulphur. BOMBS, WITH FLAMMABLE LIQUID, with bursting charge: UN Nos. 0399, 0400 Articles which are dropped from aircraft, consisting of a tank filled with inflammable liquid and bursting charge. BOMBS, PHOTO-FLASH: UN No. 0038 Explosive articles which are dropped from aircraft to provide brief, intense illumination for photography. They contain a charge of detonating explosive without means of initiation or with means of initiation containing two or more effective protective features. BOMBS, PHOTO-FLASH: UN No. 0037 Explosive articles which are dropped from aircraft to provide brief, intense illumination for photography. They contain a charge of detonating explosive with means of initiation not containing two or more effective protective features. BOMBS, PHOTO-FLASH: UN Nos. 0039, 0299 Explosive articles which are dropped from aircraft to provide brief, intense illumination for photography. They contain a photo-flash composition. BOMBS with bursting charge: UN Nos. 0034; 0035 Explosive articles which are dropped from aircraft, without means of initiation or with means of initiation containing two or more effective protective features. BOMBS with bursting charge: UN Nos. 0033, 0291 Explosive articles which are dropped from aircraft, with means of initiation not containing two or more effective protective features. BOOSTERS WITH DETONATOR: UN Nos. 0225, 0268 Articles consisting of a charge of detonating explosive with means of initiation. They are used to increase the initiating power of detonators or detonating cord. BOOSTERS without detonator: UN Nos. 0042, 0283 Articles consisting of a charge of detonating explosive without means of initiation. They are used to increase the initiating power of detonators or detonating cord. BURSTERS, explosive: UN No. 0043 Articles consisting of a small charge of explosive used to open projectiles or other ammunition in order to disperse their contents. Copyright © United Nations, 2010. All rights reserved - 127 - CARTRIDGES, FLASH: UN Nos. 0049, 0050 Articles consisting of a casing, a primer and flash powder, all assembled in one piece ready for firing. CARTRIDGES FOR WEAPONS, BLANK: UN Nos. 0326, 0413, 0327, 0338, 0014 Ammunition consisting of a closed cartridge case with a centre or rim fire primer and a charge of smokeless or black powder but no projectile. It produces a loud noise and is used for training, saluting, propelling charge, starter pistols, etc. The term includes ammunition, blank. CARTRIDGES FOR WEAPONS, INERT PROJECTILE: UN Nos. 0328, 0417, 0339, 0012 Ammunition consisting of a projectile without bursting charge but with a propelling charge with or without a primer. The articles may include a tracer, provided that the predominant hazard is that of the propelling charge. CARTRIDGES FOR WEAPONS with bursting charge: UN Nos. 0006, 0321, 0412 Ammunition consisting of a projectile with a bursting charge without means of initiation or with means of initiation containing two or more effective protective features; and a propelling charge with or without a primer. The term includes fixed (assembled) ammunition, semi-fixed (partially assembled) ammunition and separate loading ammunition when the components are packed together. CARTRIDGES FOR WEAPONS with bursting charge: UN Nos. 0005, 0007, 0348 Ammunition consisting of a projectile with a bursting charge with means of initiation not containing two or more effective protective features; and a propelling charge with or without a primer. The term includes fixed (assembled) ammunition, semi-fixed (partially assembled) ammunition and separate loading ammunition when the components are packed together. CARTRIDGES, OIL WELL: UN Nos. 0277, 0278 Articles consisting of a thin casing of fibreboard, metal or other material containing only propellant powder which projects a hardened projectile to perforate an oil well casing. NOTE: CHARGES, SHAPED are not included in this definition. They are listed separately. CARTRIDGES, POWER DEVICE: UN Nos. 0275, 0276, 0323, 0381 Articles designed to accomplish mechanical actions. They consist of a casing with a charge of deflagrating explosive and a means of ignition. The gaseous products of the deflagration produce inflation, linear or rotary motion or activate diaphragms, valves or switches or project fastening devices or extinguishing agents. CARTRIDGES, SIGNAL: UN Nos. 0054, 0312, 0405 Articles designed to fire coloured flares or other signals from signal pistols, etc. CARTRIDGES, SMALL ARMS: UN Nos. 0417, 0339, 0012 Ammunition consisting of a cartridge case fitted with a centre or rim fire primer and containing both a propelling charge and solid projectile. They are designed to be fired in Copyright © United Nations, 2010. All rights reserved - 128 - weapons of calibre not larger than 19.1 mm. Shot-gun cartridges of any calibre are included in this description. NOTE: CARTRIDGES, SMALL ARMS, BLANK, are not included in this definition. They are listed separately. Some military small arms cartridges are not included in this definition. They are listed under CARTRIDGES FOR WEAPONS, INERT PROJECTILE. CARTRIDGES, SMALL ARMS, BLANK: UN Nos. 0014, 0327, 0338 Ammunition consisting of a closed cartridge case with a centre or rim fire primer and a charge of smokeless or black powder. The cartridge cases contain no projectiles. The cartridges are designed to be fired from weapons with a calibre of at most 19.1 mm and serve to produce a loud noise and are used for training, saluting, propelling charge, starter pistols, etc. CASES, CARTRIDGE, EMPTY, WITH PRIMER: UN Nos. 0379; 0055 Articles consisting of a cartridge case made from metal, plastics or other non-inflammable material, in which the only explosive component is the primer. CASES, COMBUSTIBLE, EMPTY, WITHOUT PRIMER: UN Nos. 0447, 0446 Articles consisting of a cartridge case made partly or entirely from nitrocellulose. CHARGES, BURSTING, PLASTICS BONDED: UN Nos. 0457, 0458, 0459, 0460 Articles consisting of a charge of detonating explosive, plastics bonded, manufactured in a specific form without a casing and without means of initiation. They are designed as components of ammunition such as warheads. CHARGES, DEMOLITION: UN No. 0048 Articles containing a charge of a detonating explosive in a casing of fibreboard, plastics, metal or other material. The articles are without means of initiation or with means of initiation containing two or more effective protective features. NOTE: The following articles: BOMBS; MINES; PROJECTILES are not included in this definition. They are listed separately. CHARGES, DEPTH: UN No. 0056 Articles consisting of a charge of detonating explosive contained in a drum or projectile without means of initiation or with means of initiation containing two or more effective protective features. They are designed to detonate under water. CHARGES, EXPLOSIVE, COMMERCIAL without detonator: UN Nos. 0442, 0443, 0444, Articles consisting of a charge of detonating explosive without means of initiation, used for explosive welding, jointing, forming and other metallurgical processes. CHARGES, PROPELLING, FOR CANNON: UN Nos. 0242, 0279, 0414 Charges of propellant in any physical form for separate-loading ammunition for cannon. Copyright © United Nations, 2010. All rights reserved - 129 - CHARGES, PROPELLING: UN Nos. 0271, 0272, 0415, 0491 Articles consisting of a charge of a propellant charge in any physical form, with or without a casing, as a component of rocket motors or for reducing the drag of projectiles. CHARGES, SHAPED, without detonator: UN Nos. 0059, 0439, 0440, 0441 Articles consisting of a casing containing a charge of detonating explosive with a cavity lined with rigid material, without means of initiation. They are designed to produce a powerful, penetrating jet effect. CHARGES, SHAPED, FLEXIBLE, LINEAR: UN Nos. 0237, 0288 Articles consisting of a V-shaped core of a detonating explosive clad by a flexible sheath. CHARGES, SUPPLEMENTARY, EXPLOSIVE: UN No. 0060 Articles consisting of a small removable booster placed in the cavity of a projectile between the fuze and the bursting charge. COMPONENTS, EXPLOSIVE TRAIN, N.O.S.: UN Nos. 0382, 0383, 0384, 0461 Articles containing an explosive designed to transmit detonation or deflagration within an explosive train. CONTRIVANCES, WATER-ACTIVATED with burster, expelling charge or propelling charge: UN Nos. 0248, 0249 Articles whose functioning depends upon physico-chemical reaction of their contents with water. CORD, DETONATING, flexible: UN Nos. 0065, 0289 Article consisting of a core of detonating explosive enclosed in spun fabric and a plastics or other covering. The covering is not necessary if the spun fabric is sift-proof. CORD (FUSE) DETONATING, metal clad: UN Nos. 0102, 0290 Article consisting of a core of detonating explosive clad by a soft metal tube with or without protective covering. CORD (FUSE) DETONATING, MILD EFFECT, metal clad: UN No. 0104 Article consisting of a core of detonating explosive clad by a soft metal tube with or without a protective covering. The quantity of explosive substance is so small that only a mild effect is manifested outside the cord. CORD, IGNITER: UN No. 0066 Article consisting of textile yarns covered with black powder or another fast burning pyrotechnic composition and of a flexible protective covering; or it consists of a core of black powder surrounded by a flexible woven fabric. It burns progressively along its length with an external flame and is used to transmit ignition from a device to a charge or primer. Copyright © United Nations, 2010. All rights reserved - 130 - CUTTERS, CABLE, EXPLOSIVE: UN No. 0070 Articles consisting of a knife-edged device which is driven by a small charge of deflagrating explosive into an anvil. DETONATOR ASSEMBLIES, NON-ELECTRIC for blasting: UN Nos. 0360, 0361, 0500 Non-electric detonators assembled with and activated by such means as safety fuse, shock tube, flash tube or detonating cord. They may be of instantaneous design or incorporate delay elements. Detonating relays incorporating detonating cord are included. DETONATORS, ELECTRIC for blasting: UN Nos. 0030, 0255, 0456 Articles specially designed for the initiation of blasting explosives. These detonators may be constructed to detonate instantaneously or may contain a delay element. Electric detonators are activated by an electric current. DETONATORS FOR AMMUNITION: UN Nos. 0073, 0364, 0365, 0366 Articles consisting of a small metal or plastics tube containing explosives such as lead azide, PETN or combinations of explosives. They are designed to start a detonation train. DETONATORS, NON-ELECTRIC for blasting: UN Nos. 0029, 0267, 0455 Articles specially designed for the initiation of blasting explosives. These detonators may be constructed to detonate instantaneously or may contain a delay element. Non-electric detonators are activated by such means as shock tube, flash tube, safety fuse, other igniferous device or flexible detonating cord. Detonating relays without detonating cord are included. EXPLOSIVE, BLASTING, TYPE A: UN No. 0081 Substances consisting of liquid organic nitrates such as nitroglycerine or a mixture of such ingredients with one or more of the following: nitrocellulose; ammonium nitrate or other inorganic nitrates; aromatic nitro-derivatives, or combustible materials, such as wood-meal and aluminium powder. They may contain inert components such as kieselguhr, and additives such as colouring agents and stabilizers. Such explosives shall be in powdery, gelatinous or elastic form. The term includes dynamite; gelatine, blasting and gelatine dynamites. EXPLOSIVE, BLASTING, TYPE B: UN Nos. 0082, 0331 Substances consisting of (a) a mixture of ammonium nitrate or other inorganic nitrates with an explosive such as trinitrotoluene, with or without other substances such as wood-meal and aluminium powder; or (b) a mixture of ammonium nitrate or other inorganic nitrates with other combustible substances which are not explosive ingredients. In both cases they may contain inert components such as kieselguhr, and additives such as colouring agents and stabilizers. Such explosives must not contain nitroglycerine, similar liquid organic nitrates or chlorates. Copyright © United Nations, 2010. All rights reserved - 131 - EXPLOSIVE, BLASTING, TYPE C: UN No. 0083 Substances consisting of a mixture of either potassium or sodium chlorate or potassium, sodium or ammonium perchlorate with organic nitro-derivatives or combustible materials such as wood-meal or aluminium powder or a hydrocarbon. They may contain inert components such as kieselguhr and additives such as colouring agents and stabilizers. Such explosives must not contain nitroglycerine or similar liquid organic nitrates. EXPLOSIVE, BLASTING, TYPE D: UN No. 0084 Substances consisting of a mixture of organic nitrated compounds and combustible materials such as hydrocarbons and aluminium powder. They may contain inert components such as kieselguhr and additives such as colouring agents and stabilizers. Such explosives must not contain nitroglycerine, similar liquid organic nitrates, chlorates and ammonium nitrate. The term generally includes plastic explosives. EXPLOSIVES, BLASTING, TYPE E: UN Nos. 0241, 0332 Substances consisting of water as an essential ingredient and high proportions of ammonium nitrate or other oxidizers, some or all of which are in solution. The other constituents may include nitro-derivatives such as trinitrotoluene, hydrocarbons or aluminium powder. They may contain inert components such as kieselguhr and additives such as colouring agents and stabilizers. The term includes explosives, emulsion, explosives, slurry and explosives, watergel. FIREWORKS: UN Nos. 0333, 0334, 0335, 0336, 0337 Pyrotechnic articles designed for entertainment. FLARES, AERIAL: UN Nos. 0093, 0403, 0404, 0420, 0421; Articles containing pyrotechnic substances which are designed to be dropped from an aircraft to illuminate, identify, signal or warn. FLARES, SURFACE: UN Nos. 0092, 0418, 0419 Articles containing pyrotechnic substances which are designed for use on the surface to illuminate, identify, signal or warn. FLASH POWDER: UN Nos. 0094, 0305 Pyrotechnic substance which, when ignited, produces an intense light. FRACTURING DEVICES, EXPLOSIVE without detonator, for oil wells: UN No. 0099 Articles consisting of a charge of detonating explosive contained in a casing without means of initiation. They are used to fracture the rock around a drill shaft to assist the flow of crude oil from the rock. FUSE, IGNITER, tubular, metal clad: UN No. 0103 Article consisting of a metal tube with a core of deflagrating explosive. Copyright © United Nations, 2010. All rights reserved - 132 - FUSE, NON-DETONATING: UN No. 0101 Article consisting of cotton yarns impregnated with fine black powder (quickmatch). It burns with an external flame and is used in ignition trains for fireworks, etc. FUSE, SAFETY: UN No. 0105 Article consisting of a core of fine grained black powder surrounded by a flexible woven fabric with one or more protective outer coverings. When ignited, it burns at a predetermined rate without any external explosive effect. FUZES, DETONATING: UN Nos. 0106, 0107, 0257, 0367 Articles with explosive components designed to produce a detonation in ammunition. They incorporate mechanical, electrical, chemical or hydrostatic components to initiate the detonation. They generally incorporate protective features. FUZES, DETONATING with protective features: UN Nos. 0408, 0409, 0410 Articles with explosive components designed to produce a detonation in ammunition. They incorporate mechanical, electrical, chemical or hydrostatic components to initiate the detonation. The detonating fuze must incorporate two or more effective protective features. FUZES, IGNITING: UN Nos. 0316, 0317, 0368 Articles with primary explosive components designed to produce a deflagration in ammunition. They incorporate mechanical, electrical, chemical or hydrostatic components to start the deflagration. They generally incorporate protective features. GRENADES, hand or rifle, with bursting charge: UN Nos. 0284, 0285 Articles which are designed to be thrown by hand or to be projected by a rifle. They are without means of initiation or with means of initiation containing two or more effective protective features. GRENADES, hand or rifle, with bursting charge: UN Nos. 0292, 0293 Articles which are designed to be thrown by hand or to be projected by a rifle. They are with means of initiation not containing two or more effective protective features. GRENADES, PRACTICE, hand or rifle: UN Nos. 0110, 0372, 0318, 0452 Articles without a main bursting charge which are designed to be thrown by hand or to be projected by a rifle. They contain the priming device and may contain a spotting charge. HEXOTONAL: UN No. 0393 Substance consisting of an intimate mixture of cyclotrimethylene-trinitramine (RDX), trinitrotoluene (TNT) and aluminium. HEXOLITE (HEXOTOL), dry or wetted with less than 15% water, by mass: UN No. 0118 Substance consisting of an intimate mixture of cyclotrimethylene-trinitramine (RDX) and trinitrotoluene (TNT). The term includes "Composition B". Copyright © United Nations, 2010. All rights reserved - 133 - IGNITERS: UN Nos. 0121, 0314, 0315, 0325, 0454 Articles containing one or more explosive substances designed to produce a deflagration in an explosive train. They may be actuated chemically, electrically or mechanically. NOTE: The following articles: CORD, IGNITER; FUSE, IGNITER; FUSE, NON-DETONATING; FUZES, IGNITING; LIGHTERS, FUSE; PRIMERS, CAP TYPE; PRIMERS, TUBULAR are not included in this definition. They are listed separately. JET PERFORATING GUNS, CHARGED, oil well, without detonator: UN Nos. 0124, 0494 Articles consisting of a steel tube or metallic strip, into which are inserted shaped charges connected by detonating cord, without means of initiation. LIGHTERS, FUSE: UN No. 0131 Articles of various design actuated by friction, percussion or electricity and used to ignite safety fuse. MINES with bursting charge: UN Nos. 0137, 0138 Articles consisting normally of metal or composition receptacles filled with a detonating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are designed to be operated by the passage of ships, vehicles or personnel. The term includes "Bangalore torpedoes". MINES with bursting charge: UN Nos. 0136, 0294 Articles consisting normally of metal or composition receptacles filled with a detonating explosive, with means of initiation not containing two or more effective protective features. They are designed to be operated by the passage of ships, vehicles or personnel. The term includes "Bangalore torpedoes". OCTOLITE (OCTOL), dry or wetted with less than 15% water, by mass: UN No. 0266 Substance consisting of an intimate mixture of cyclotetramethylene-tetranitramine (HMX) and trinitrotoluene (TNT). OCTONAL: UN No. 0496 Substance consisting of an intimate mixture of cyclotetramethylenetetranitramine (HMX), trinitrotoluene (TNT) and aluminium. PENTOLITE, dry or wetted with less than 15% water, by mass: UN No. 0151 Substance consisting of an intimate mixture of pentaerythrite tetranitrate (PETN) and trinitrotoluene (TNT). POWDER CAKE (POWDER PASTE), WETTED with not less than 17% alcohol, by mass; POWDER CAKE (POWDER PASTE), WETTED with not less than 25% water, by mass: UN Nos. 0433, 0159 Substance consisting of nitrocellulose impregnated with not more than 60% of nitroglycerine or other liquid organic nitrates or a mixture of these. Copyright © United Nations, 2010. All rights reserved - 134 - POWDER, SMOKELESS: UN Nos. 0160, 0161, 0509 Substance based on nitrocellulose used as propellant. The term includes propellants with a single base (nitrocellulose (NC) alone), those with a double base (such as NC and nitroglycerine/(NG)) and those with a triple base (such as NC/NG/nitroguanidine). NOTE: Cast, pressed or bag-charges of smokeless powder are listed under CHARGES, PROPELLING or CHARGES, PROPELLING, FOR CANON. PRIMERS, CAP TYPE: UN Nos. 0044, 0377, 0378 Articles consisting of a metal or plastics cap containing a small amount of primary explosive mixture that is readily ignited by impact. They serve as igniting elements in small arms cartridges and in percussion primers for propelling charges. PRIMERS, TUBULAR: UN Nos. 0319, 0320, 0376 Articles consisting of a primer for ignition and an auxiliary charge of deflagrating explosive such as black powder used to ignite the propelling charge in a cartridge case for cannon, etc. PROJECTILES, inert with tracer: UN Nos. 0345, 0424, 0425 Articles such as a shell or bullet, which are projected from a cannon or other gun, rifle or other small arm. PROJECTILES with burster or expelling charge: UN Nos. 0346, 0347 Articles such as a shell or bullet, which are projected from a cannon or other gun. They are without means of initiation or with means of initiation containing two or more effective protective features. They are used to scatter dyes for spotting or other inert materials. PROJECTILES with burster or expelling charge: UN Nos. 0426, 0427 Articles such as a shell or bullet, which are projected from a cannon or other gun. They are with means of initiation not containing two or more effective protective features. They are used to scatter dyes for spotting or other inert materials. PROJECTILES with burster or expelling charge: UN Nos. 0434, 0435 Articles such as a shell or bullet, which are projected from a cannon or other gun, rifle or other small arm. They are used to scatter dyes for spotting or other inert materials. PROJECTILES with bursting charge: UN Nos. 0168, 0169, 0344 Articles such as a shell or bullet, which are projected from a cannon or other gun. They are without means of initiation or with means of initiation containing two or more effective protective features. PROJECTILES with bursting charge: UN Nos. 0167, 0324 Articles such as a shell or bullet, which are projected from a cannon or other gun. They are with means of initiation not containing two or more effective protective features. PROPELLANT, LIQUID: UN Nos. 0495, 0497 Substance consisting of a deflagrating liquid explosive, used for propulsion. Copyright © United Nations, 2010. All rights reserved - 135 - PROPELLANT, SOLID: UN Nos. 0498, 0499, 0501 Substance consisting of a deflagrating solid explosive, used for propulsion. RELEASE DEVICES, EXPLOSIVE: UN No. 0173 Articles consisting of a small charge of explosive with means of initiation and rods or links. They sever the rods or links to release equipment quickly. RIVETS, EXPLOSIVE: UN No. 0174 Articles consisting of a small charge of explosive inside a metallic rivet. ROCKET MOTORS: UN Nos. 0186, 0280, 0281 Articles consisting of a charge of explosive, generally a solid propellant, contained in a cylinder fitted with one or more nozzles. They are designed to propel a rocket or a guided missile. ROCKET MOTORS, LIQUID FUELLED: UN Nos. 0395, 0396 Articles consisting of a liquid fuel within a cylinder fitted with one or more nozzles. They are designed to propel a rocket or a guided missile. ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without expelling charge: UN Nos. 0322, 0250 Articles consisting of a hypergolic fuel contained in a cylinder fitted with one or more nozzles. They are designed to propel a rocket or a guided missile. ROCKETS, LINE THROWING: UN Nos. 0238, 0240, 0453 Articles consisting of a rocket motor which is designed to extend a line. ROCKETS, LIQUID FUELLED with bursting charge: UN Nos. 0397, 0398 Articles consisting of a liquid fuel within a cylinder fitted with one or more nozzles and fitted with a warhead. The term includes guided missiles. ROCKETS with bursting charge: UN Nos. 0181, 0182 Articles consisting of a rocket motor and a warhead without means of initiation or with means of initiation containing two or more effective protective features. The term includes guided missiles. ROCKETS with bursting charge: UN Nos. 0180, 0295 Articles consisting of a rocket motor and a warhead with means of initiation not containing two or more effective protective features. The term includes guided missiles. ROCKETS with expelling charge: UN Nos. 0436, 0437, 0438 Articles consisting of a rocket motor and a charge to expel the payload from a rocket head. The term includes guided missiles. Copyright © United Nations, 2010. All rights reserved - 136 - ROCKETS with inert head: UN Nos. 0183, 0502 Articles consisting of a rocket motor and an inert head. The term includes guided missiles. SAMPLES, EXPLOSIVE, other than initiating explosive UN No. 0190 New or existing explosive substances or articles, not yet assigned to a name in Table A of Chapter 3.2 and carried in conformity with the instructions of the competent authority and generally in small quantities, inter alia, for the purposes of testing, classification, research and development, or quality control, or as commercial samples. NOTE: Explosive substances or articles already assigned to another name in Table A of Chapter 3.2 are not included in this definition. SIGNAL DEVICES, HAND: UN Nos. 0191, 0373 Portable articles containing pyrotechnic substances which produce visual signals or warnings. The term includes small surface flares such as highway or railway flares and small distress flares. SIGNALS, DISTRESS, ship: UN Nos. 0194, 0195, 0505, 0506 Articles containing pyrotechnic substances designed to produce signals by means of sound, flame or smoke or any combination thereof. SIGNALS, RAILWAY TRACK, EXPLOSIVE: UN Nos. 0192, 0193, 0492, 0493 Articles containing a pyrotechnic substance which explodes with a loud report when the article is crushed. They are designed to be placed on a rail. SIGNALS, SMOKE: UN Nos. 0196, 0197, 0313, 0487, 0507 Articles containing pyrotechnic substances which emit smoke. In addition they may contain devices for emitting audible signals. SOUNDING DEVICES, EXPLOSIVE: UN Nos. 0374, 0375 Articles consisting of a charge of detonating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are dropped from ships and function when they reach a predetermined depth or the sea bed. SOUNDING DEVICES, EXPLOSIVE: UN Nos. 0204, 0296 Articles consisting of a charge of detonating explosive with means of initiation not containing two or more effective protective features. They are dropped from ships and function when they reach a predetermined depth or the sea bed. SUBSTANCES, EXPLOSIVE, VERY INSENSITIVE (Substances, EVI), N.O.S.: UN No. 0482 Substances presenting a mass explosion hazard but which are so insensitive that there is very little probability of initiation or of transition from burning to detonation under normal conditions of transport, and which have passed Test Series 5. Copyright © United Nations, 2010. All rights reserved - 137 - TORPEDOES, LIQUID FUELLED with inert head: UN No. 0450 Articles consisting of a liquid explosive system to propel the torpedo through the water, with an inert head. TORPEDOES, LIQUID FUELLED with or without bursting charge: UN No. 0449 Articles consisting of either a liquid explosive system to propel the torpedo through the water, with or without a warhead; or a liquid non-explosive system to propel the torpedo through the water, with a warhead. TORPEDOES with bursting charge: UN No. 0451 Articles consisting of a non-explosive system to propel the torpedo through the water, and a warhead without means of initiation or with means of initiation containing two or more effective protective features. TORPEDOES with bursting charge: UN No. 0329 Articles consisting of an explosive system to propel the torpedo through the water, and a warhead without means of initiation or with means of initiation containing two or more effective protective features. TORPEDOES with bursting charge: UN No. 0330 Articles consisting of an explosive or non-explosive system to propel the torpedo through the water, and a warhead with means of initiation not containing two or more effective protective features. TRACERS FOR AMMUNITION: UN Nos. 0212, 0306 Sealed articles containing pyrotechnic substances, designed to reveal the trajectory of a projectile. TRITONAL: UN No. 0390 Substance consisting of trinitrotoluene (TNT) mixed with aluminium. WARHEADS, ROCKET with burster or expelling charge: UN No. 0370 Articles consisting of an inert payload and a small charge of detonating or deflagrating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are designed to be fitted to a rocket motor to scatter inert material. The term includes warheads for guided missiles. WARHEADS, ROCKET with burster or expelling charge: UN No. 0371 Articles consisting of an inert payload and a small charge of detonating or deflagrating explosive, with means of initiation not containing two or more effective protective features. They are designed to be fitted to a rocket motor to scatter inert material. The term includes warheads for guided missiles. Copyright © United Nations, 2010. All rights reserved - 138 - WARHEADS, ROCKET with bursting charge: UN Nos. 0286, 0287 Articles consisting of a detonating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are designed to be fitted to a rocket. The term includes warheads for guided missiles. WARHEADS, ROCKET with bursting charge: UN No. 0369 Articles consisting of a detonating explosive, with means of initiation not containing two or more effective protective features. They are designed to be fitted to a rocket. The term includes warheads for guided missiles. WARHEADS, TORPEDO with bursting charge: UN No. 0221 Articles consisting of a detonating explosive, without means of initiation or with means of initiation containing two or more effective protective features. They are designed to be fitted to a torpedo. 2.2.1.2 Substances and articles not accepted for carriage 2.2.1.2.1 Explosive substances which are unduly sensitive according to the criteria of the Manual of Tests and Criteria, Part I, or are liable to spontaneous reaction, as well as explosive substances and articles which cannot be assigned to a name or n.o.s. entry listed in Table A of Chapter 3.2, shall not be accepted for carriage. 2.2.1.2.2 Articles of compatibility group K shall not be accepted for carriage (1.2K, UN No. 0020 and 1.3K, UN No. 0021). Copyright © United Nations, 2010. All rights reserved - 139 - 2.2.1.3 List of collective entries Classification code (see 2.2.1.1.4) UN No. Name of the substance or article 1.1A SUBSTANCES, EXPLOSIVE, N.O.S. 1.1B COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1.1C SUBSTANCES, EXPLOSIVE, N.O.S. PROPELLANT, LIQUID PROPELLANT, SOLID ARTICLES, EXPLOSIVE, N.O.S. 1.1D SUBSTANCES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. 1.1E ARTICLES, EXPLOSIVE, N.O.S. 1.1F ARTICLES, EXPLOSIVE, N.O.S. 1.1G SUBSTANCES, EXPLOSIVE, N.O.S. 1.1L SUBSTANCES, EXPLOSIVE, N.O.S. 0354 ARTICLES, EXPLOSIVE, N.O.S. 1.2B COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1.2C ARTICLES, EXPLOSIVE, N.O.S. 1.2D ARTICLES, EXPLOSIVE, N.O.S. 1.2E ARTICLES, EXPLOSIVE, N.O.S. 1.2F ARTICLES, EXPLOSIVE, N.O.S. 1.2L SUBSTANCES, EXPLOSIVE, N.O.S. CONTRIVANCES, WATER-ACTIVATED with burster, expelling charge or propelling charge ARTICLES, EXPLOSIVE, N.O.S. 1.3C DEFLAGRATING METAL SALTS OF AROMATIC NITRO- DERIVATIVES, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S. PROPELLANT, LIQUID 0499 PROPELLANT, SOLID 0470 ARTICLES, EXPLOSIVE, N.O.S. 1.3G 0478 SUBSTANCES, EXPLOSIVE, N.O.S. 1.3L SUBSTANCES, EXPLOSIVE, N.O.S. 0249 CONTRIVANCES, WATER-ACTIVATED with burster, expelling charge or propelling charge 0356 ARTICLES, EXPLOSIVE, N.O.S. 1.4B 0350 ARTICLES, EXPLOSIVE, N.O.S. 0383 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1.4C 0479 SUBSTANCES, EXPLOSIVE, N.O.S. PROPELLANT, SOLID 0351 ARTICLES, EXPLOSIVE, N.O.S. Copyright © United Nations, 2010. All rights reserved - 140 - Classification code (see 2.2.1.1.4) UN No. Name of the substance or article 1.4D 0480 SUBSTANCES, EXPLOSIVE, N.O.S. 0352 ARTICLES, EXPLOSIVE, N.O.S. 1.4E ARTICLES, EXPLOSIVE, N.O.S. 1.4F 0472 ARTICLES, EXPLOSIVE, N.O.S. 1.4G 0485 SUBSTANCES, EXPLOSIVE, N.O.S. 0353 ARTICLES, EXPLOSIVE, N.O.S. 1.4S 0481 SUBSTANCES, EXPLOSIVE, N.O.S. 0349 ARTICLES, EXPLOSIVE, N.O.S. 0384 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. 1.5D 0482 SUBSTANCES, EXPLOSIVE, VERY INSENSITIVE (SUBSTANCES, EVI) N.O.S. 1.6N 0486 ARTICLES, EXPLOSIVE, EXTREMELY INSENSITIVE (ARTICLES, EEI) SAMPLES, EXPLOSIVE other than initiating explosive NOTE: Division and Compatibility Group shall be defined as directed by the competent authority and according to the principles in 2.2.1.1.4. Copyright © United Nations, 2010. All rights reserved - 141 - 2.2.2 Class 2 Gases 2.2.2.1 Criteria 2.2.2.1.1 The heading of Class 2 covers pure gases, mixtures of gases, mixtures of one or more gases with one or more other substances and articles containing such substances. A gas is a substance which: (a) at 50 °C has a vapour pressure greater than 300 kPa (3 bar); or (b) is completely gaseous at 20 °C at the standard pressure of 101.3 kPa. NOTE 1: UN No. 1052 HYDROGEN FLUORIDE, ANHYDROUS is nevertheless classified in Class 8. NOTE 2: A pure gas may contain other components deriving from its production process or added to preserve the stability of the product, provided that the level of these components does not change its classification or its conditions of carriage, such as filling ratio, filling pressure, test pressure. NOTE 3: N.O.S. entries in 2.2.2.3 may cover pure gases as well as mixtures. 2.2.2.1.2 The substances and articles of Class 2 are subdivided as follows: 1. Compressed gas: a gas which when packaged under pressure for carriage is entirely gaseous at -50 °C; this category includes all gases with a critical temperature less than or equal to -50 °C; 2. Liquefied gas: a gas which when packaged under pressure for carriage is partially liquid at temperatures above -50 °C. A distinction is made between: High pressure liquefied gas: a gas with a critical temperature above -50 °C and equal to or below +65 °C; and Low pressure liquefied gas: a gas with a critical temperature above +65 °C; 3. Refrigerated liquefied gas: a gas which when packaged for carriage is made partially liquid because of its low temperature; 4. Dissolved gas: a gas which when packaged under pressure for carriage is dissolved in a liquid phase solvent; 5. Aerosol dispensers and receptacles, small, containing gas (gas cartridges); 6. Other articles containing gas under pressure; 7. Non-pressurized gases subject to special requirements (gas samples). 2.2.2.1.3 Substances and articles (except aerosols) of Class 2 are assigned to one of the following groups according to their hazardous properties, as follows: A asphyxiant; O oxidizing; Copyright © United Nations, 2010. All rights reserved - 142 - F flammable; T toxic; TF toxic, flammable; TC toxic, corrosive; TO toxic, oxidizing; TFC toxic, flammable, corrosive; TOC toxic, oxidizing, corrosive. For gases and gas mixtures presenting hazardous properties associated with more than one group according to the criteria, the groups designated by letter T take precedence over all other groups. The groups designated by letter F take precedence over the groups designated by letters A or O. NOTE 1: In the UN Model Regulations, the IMDG Code and the ICAO Technical Instructions, gases are assigned to one of the following three divisions, based on the primary hazard: Division 2.1: flammable gases (corresponding to the groups designated by the capital letter F); Division 2.2: non-flammable, non-toxic gases (corresponding to the groups designated by the capital letters A or O); Division 2.3: toxic gases (corresponding to the groups designated by the capital letter T i.e. T, TF, TC, TO, TFC and TOC). NOTE 2: Receptacles, small containing gas (UN No. 2037) shall be assigned to the groups A to TOC according to the hazard of the contents. For aerosols (UN No. 1950), see 2.2.2.1.6. NOTE 3: Corrosive gases are considered to be toxic, and are therefore assigned to the group TC, TFC or TOC. 2.2.2.1.4 If a mixture of Class 2 mentioned by name in Table A of Chapter 3.2 meets different criteria as mentioned in 2.2.2.1.2 and 2.2.2.1.5, this mixture shall be classified according to the criteria and assigned to an appropriate N.O.S. entry. 2.2.2.1.5 Substances and articles (except aerosols) of Class 2 which are not mentioned by name in Table A of Chapter 3.2 shall be classified under a collective entry listed in 2.2.2.3 in accordance with 2.2.2.1.2 and 2.2.2.1.3. The following criteria shall apply: Asphyxiant gases Gases which are non-oxidizing, non-flammable and non-toxic and which dilute or replace oxygen normally in the atmosphere. Flammable gases Gases which at 20 °C and a standard pressure of 101.3 kPa: (a) are ignitable when in a mixture of 13% or less by volume with air; or Copyright © United Nations, 2010. All rights reserved - 143 - (b) have a flammable range with air of at least 12 percentage points regardless of the lower flammable limit. Flammability shall be determined by tests or by calculation, in accordance with methods adopted by ISO (see ISO 10156:1996). Where insufficient data are available to use these methods, tests by a comparable method recognized by the competent authority of the country of origin may be used. If the country of origin is not a Contracting Party to ADR these methods shall be recognized by the competent authority of the first country Contracting Party to ADR reached by the consignment. Oxidizing gases Gases, which may, generally by providing oxygen, cause or contribute to the combustion of other material more than air does. These are pure gases or gas mixtures with an oxidizing power greater than 23.5% as determined by a method specified in ISO 10156:1996 or ISO 10156-2:2005. Toxic gases NOTE: Gases meeting the criteria for toxicity in part or completely owing to their corrosivity are to be classified as toxic. See also the criteria under the heading "Corrosive gases" for a possible subsidiary corrosivity risk. Gases which: (a) are known to be so toxic or corrosive to humans as to pose a hazard to health; or (b) are presumed to be toxic or corrosive to humans because they have a LC50 value for acute toxicity equal to or less than 5 000 ml/m³ (ppm) when tested in accordance with 2.2.61.1. In the case of gas mixtures (including vapours of substances from other classes) the following formula may be used: T f = (mixture) Toxic LC i i n = i ¦ where fi = mole fraction of the ith component substance of the mixture; Ti = toxicity index of the ith component substance of the mixture. The Ti equals the LC50 value as found in packing instruction P200 of 4.1.4.1. When no LC50 value is listed in packing instruction P200 of 4.1.4.1, a LC50 value available in scientific literature shall be used. When the LC50 value is unknown, the toxicity index is determined by using the lowest LC50 value of substances of similar physiological and chemical effects, or through testing if this is the only practical possibility. Copyright © United Nations, 2010. All rights reserved - 144 - Corrosive gases Gases or gas mixtures meeting the criteria for toxicity completely owing to their corrosivity are to be classified as toxic with a subsidiary corrosivity risk. A gas mixture that is considered to be toxic due to the combined effects of corrosivity and toxicity has a subsidiary risk of corrosivity when the mixture is known by human experience to be destructive to the skin, eyes or mucous membranes or when the LC50 value of the corrosive components of the mixture is equal to or less than 5 000 ml/m3 (ppm) when the LC50 is calculated by the formula: T f = (mixture) Corrosive LC ci ci n = i ¦ where fci = mole fraction of the ith corrosive component substance of the mixture; Tci = toxicity index of the ith corrosive component substance of the mixture. The Tci equals the LC50 value as found in packing instruction P200 of 4.1.4.1. When no LC50 value is listed in packing instruction P200 of 4.1.4.1, a LC50 value available in scientific literature shall be used. When the LC50 value is unknown the toxicity index is determined by using the lowest LC50 value of substances of similar physiological and chemical effects, or through testing if this is the only practical possibility. 2.2.2.1.6 Aerosols Aerosols (UN No. 1950) are assigned to one of the following groups according to their hazardous properties, as follows: A asphyxiant; O oxidizing; F flammable; T toxic; C corrosive; CO corrosive, oxidizing; FC flammable, corrosive; TF toxic, flammable; TC toxic, corrosive; TO toxic, oxidizing; TFC toxic, flammable, corrosive; Copyright © United Nations, 2010. All rights reserved - 145 - TOC toxic, oxidizing, corrosive. The classification depends on the nature of the contents of the aerosol dispenser. NOTE: Gases, which meet the definition of toxic gases according to 2.2.2.1.5 or of pyrophoric gases according to packing instruction P200 in 4.1.4.1, shall not be used as a propellant in an aerosol dispenser. Aerosols with contents meeting the criteria for packing group I for toxicity or corrosivity shall not be accepted for carriage (see also 2.2.2.2.2). The following criteria shall apply: (a) Assignment to group A shall apply when the contents do not meet the criteria for any other group according to sub-paragraphs (b) to (f) below; (b) Assignment to group O shall apply when the aerosol contains an oxidizing gas according to 2.2.2.1.5; (c) Assignment to group F shall apply if the contents include 85% by mass or more flammable components and the chemical heat of combustion is 30 kJ/g or more. It shall not apply if the contents contain 1% by mass or less flammable components and the heat of combustion is less than 20 kJ/g. Otherwise the aerosol shall be tested for flammability in accordance with the tests described in the Manual of Tests and Criteria, Part III, section 31. Extremely flammable and flammable aerosols shall be assigned to group F; NOTE: Flammable components are flammable liquids, flammable solids or flammable gases and gas mixtures as defined in Notes 1 to 3 of sub-section 31.1.3 of Part III of the Manual of Tests and Criteria. This designation does not cover pyrophoric, self-heating or water-reactive substances. The chemical heat of combustion shall be determined by one of the following methods ASTM D 240, ISO/FDIS 13943:1999 (E/F) 86.1 to 86.3 or NFPA 30B. (d) Assignment to group T shall apply when the contents, other than the propellant of aerosol dispensers to be ejected, are classified as Class 6.1, packing groups II or III; (e) Assignment to group C shall apply when the contents, other than the propellant of aerosol dispensers to be ejected, meet the criteria for Class 8, packing groups II or III; (f) When the criteria for more than one group amongst groups O, F, T, and C are met, assignment to groups CO, FC, TF, TC TO, TFC or TOC shall apply, as relevant. 2.2.2.2 Gases not accepted for carriage 2.2.2.2.1 Chemically unstable substances of Class 2 shall not be accepted for carriage, unless the necessary steps have been taken to prevent all possibility of a dangerous reaction e.g. decomposition, dismutation or polymerisation under normal conditions during transport. To this end particular care shall be taken to ensure that receptacles and tanks do not contain any substances liable to promote these reactions. 2.2.2.2.2 The following substances and mixtures shall not be accepted for carriage: - UN No. 2186 HYDROGEN CHLORIDE, REFRIGERATED LIQUID; Copyright © United Nations, 2010. All rights reserved - 146 - - UN No. 2421 NITROGEN TRIOXIDE; - UN No. 2455 METHYL NITRITE; - Refrigerated liquefied gases which cannot be assigned to classification codes 3A, 3O or 3F; - Dissolved gases which cannot be classified under UN Nos. 1001, 2073 or 3318; - Aerosols where gases which are toxic according to 2.2.2.1.5 or pyrophoric according to packing instruction P200 in 4.1.4.1 are used as propellants; - Aerosols with contents meeting the criteria for packing group I for toxicity or corrosivity (see 2.2.61 and 2.2.8); - Receptacles, small, containing gases which are very toxic (LC50 lower than 200 ppm) or pyrophoric according to packing instruction P200 in 4.1.4.1. Copyright © United Nations, 2010. All rights reserved - 147 - 2.2.2.3 List of collective entries Compressed gases Classification code UN No. Name of the substance or article 1 A COMPRESSED GAS, N.O.S. 1 O COMPRESSED GAS, OXIDIZING, N.O.S. 1 F HYDROCARBON GAS MIXTURE, COMPRESSED, N.O.S. COMPRESSED GAS, FLAMMABLE, N.O.S. 1T COMPRESSED GAS, TOXIC, N.O.S. 1 TF COMPRESSED GAS, TOXIC, FLAMMABLE, N.O.S. 1 TC COMPRESSED GAS, TOXIC, CORROSIVE, N.O.S. 1 TO COMPRESSED GAS, TOXIC, OXIDIZING, N.O.S. 1 TFC COMPRESSED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. 1 TOC COMPRESSED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. Liquefied gases Classification code UN No. Name of the substance or article 2 A LIQUEFIED GASES, non-flammable, charged with nitrogen, carbon dioxide or air REFRIGERANT GAS, N.O.S. such as mixtures of gases, indicated by the letter R..., which as: Mixture F1, have a vapour pressure at 70 °C not exceeding 1.3 MPa (13 bar) and a density at 50 °C not lower than that of dichlorofluoromethane (1.30 kg/l); Mixture F2, have a vapour pressure at 70 °C not exceeding 1.9 MPa (19 bar) and a density at 50 °C not lower than that of dichlorodifluoromethane (1.21 kg/l); Mixture F3, have a vapour pressure at 70 °C not exceeding 3 MPa (30 bar) and a density at 50 °C not lower than that of chlorodifluoromethane (1.09 kg/l). NOTE: Trichlorofluoromethane (Refrigerant R 11), 1,1,2-trichloro-1,2,2trifluoroethane (Refrigerant R 113), 1,1,1-trichloro-2,2,2-trifluoroethane (Refrigerant R 113a), 1-chloro-1,2,2-trifluoroethane (Refrigerant R 133) and 1-chloro-1,1,2trifluoroethane (Refrigerant R 133b) are not substances of Class 2. They may, however, enter into the composition of mixtures F1 to F3. INSECTICIDE GAS, N.O.S. LIQUEFIED GAS, N.O.S. 2 O LIQUEFIED GAS, OXIDIZING, N.O.S. 2 F BUTADIENES AND HYDROCARBON MIXTURE, STABILIZED, having a vapour pressure at 70 °C not exceeding 1.1 MPa (11 bar) and a density at 50 °C not lower than 0.525 kg/l. NOTE: Butadienes, stabilized are also classified under UN No. 1010, see Table A of Chapter 3.2. METHYLACETYLENE AND PROPADIENE MIXTURE, STABILIZED such as mixtures of methylacetylene and propadiene with hydrocarbons, which as: Mixture P1, contain not more than 63% methylacetylene and propadiene by volume and not more than 24% propane and propylene by volume, the percentage of C4- saturated hydrocarbons being not less than 14% by volume; and as Mixture P2, contain not more than 48% methylacetylene and propadiene by volume and not more than 50% propane and propylene by volume, the percentage of C4- saturated hydrocarbons being not less than 5% by volume, as well as mixtures of propadiene with 1 to 4% methylacetylene. Copyright © United Nations, 2010. All rights reserved - 148 - Liquefied gases (cont'd) Classification code UN No. Name of the substance or article 2 F (cont'd) HYDROCARBON GAS MIXTURE, LIQUEFIED, N.O.S such as mixtures, which as: Mixture A, have a vapour pressure at 70 °C not exceeding 1.1 MPa (11 bar) and a density at 50 °C not lower than 0.525 kg/l; Mixture A01, have a vapour pressure at 70 °C not exceeding 1.6 MPa (16 bar) and a relative density at 50 °C not lower than 0.516 kg/l; Mixture A02, have a vapour pressure at 70 °C not exceeding 1.6 MPa (16 bar) and a relative density at 50 °C not lower than 0.505 kg/l; Mixture A0, have a vapour pressure at 70 °C not exceeding 1.6 MPa (16 bar) and a density at 50 °C not lower than 0.495 kg/l; Mixture A1, have a vapour pressure at 70 °C not exceeding 2.1 MPa (21 bar) and a density at 50 °C not lower than 0.485 kg/l; Mixture B1 have a vapour pressure at 70 °C not exceeding 2.6 MPa (26 bar) and a relative density at 50 °C not lower than 0.474 kg/l; Mixture B2 have a vapour pressure at 70 °C not exceeding 2.6 MPa (26 bar) and a relative density at 50 °C not lower than 0.463 kg/l; Mixture B, have a vapour pressure at 70 °C not exceeding 2.6 MPa (26 bar) and a density at 50 °C not lower than 0.450 kg/l; Mixture C, have a vapour pressure at 70 °C not exceeding 3.1 MPa (31 bar) and a relative density at 50 °C not lower than 0.440 kg/l; NOTE 1: In the case of the foregoing mixtures, the use of the following names customary in the trade is permitted for describing these substances: for mixtures A, A01, A02 and A0: BUTANE; for mixture C: PROPANE. NOTE 2: UN No. 1075 PETROLEUM GASES, LIQUEFIED may be used as an alternative entry for UN No. 1965 HYDROCARBON GAS MIXTURE LIQUEFIED, N.O.S. for carriage prior to or following maritime or air carriage. INSECTICIDE GAS, FLAMMABLE, N.O.S. LIQUEFIED GAS, FLAMMABLE, N.O.S. 2 T INSECTICIDE GAS, TOXIC, N.O.S. LIQUEFIED GAS, TOXIC, N.O.S. 2 TF INSECTICIDE GAS, TOXIC, FLAMMABLE, N.O.S. LIQUEFIED GAS, TOXIC, FLAMMABLE, N.O.S. 2 TC LIQUEFIED GAS, TOXIC, CORROSIVE, N.O.S. 2 TO LIQUEFIED GAS, TOXIC, OXIDIZING, N.O.S. 2 TFC LIQUEFIED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. 2 TOC LIQUEFIED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. Refrigerated liquefied gases Classification code UN No. Name of the substance or article 3 A GAS, REFRIGERATED LIQUID, N.O.S. 3 O GAS, REFRIGERATED LIQUID, OXIDIZING, N.O.S. 3 F GAS, REFRIGERATED LIQUID, FLAMMABLE, N.O.S. Dissolved gases Classification code UN No. Name of the substance or article Only substances listed in Table A of Chapter 3.2 are to be accepted for carriage. Copyright © United Nations, 2010. All rights reserved - 149 - Aerosols and receptacles, small, containing gas Classification code UN No. Name of the substance or article AEROSOLS RECEPTACLES, SMALL CONTAINING GAS (GAS CARTRIDGES) without a release device, non-refillable Other articles containing gas under pressure Classification code UN No. Name of the substance or article 6A REFRIGERATING MACHINES containing non-flammable, non-toxic gases or ammonia solutions (UN 2672) ARTICLES, PRESSURIZED, PNEUMATIC (containing non-flammable gas) or ARTICLES, PRESSURIZED, HYDRAULIC (containing non-flammable gas) 6F DEVICES, SMALL, HYDROCARBON GAS POWERED or HYDROCARBON GAS REFILLS FOR SMALL DEVICES, with release device FUEL CELL CARTRIDGES, containing liquefied flammable gas or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT, containing liquefied flammable gas or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing liquefied flammable gas FUEL CELL CARTRIDGES, containing hydrogen in metal hydride or FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT, containing hydrogen in metal hydride or FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT, containing hydrogen in metal hydride Gas samples Classification code UN No. Name of the substance or article 7 F GAS SAMPLE, NON-PRESSURIZED, FLAMMABLE, N.O.S., not refrigerated liquid 7 T GAS SAMPLE, NON-PRESSURIZED, TOXIC, N.O.S., not refrigerated liquid 7 TF GAS SAMPLE, NON-PRESSURIZED, TOXIC, FLAMMABLE, N.O.S., not refrigerated liquid Copyright © United Nations, 2010. All rights reserved - 150 - 2.2.3 Class 3 Flammable liquids 2.2.3.1 Criteria 2.2.3.1.1 The heading of Class 3 covers substances and articles containing substances of this Class which: - are liquids according to subparagraph (a) of the definition for "liquid" in 1.2.1; - have at 50 °C a vapour pressure of not more than 300 kPa (3 bar) and are not completely gaseous at 20 °C and at standard pressure of 101.3 kPa; and - have a flash-point of not more than 60 °C (see 2.3.3.1 for the relevant test). The heading of Class 3 also covers liquid substances and molten solid substances with a flash-point of more than 60°C and which are carried or handed over for carriage whilst heated at temperatures equal to or higher than their flash-point. These substances are assigned to UN No. 3256. The heading of Class 3 also covers liquid desensitized explosives. Liquid desensitized explosives are explosive substances which are dissolved or suspended in water or other liquid substances, to form an homogeneous liquid mixture to suppress their explosive properties. Such entries in Table A of Chapter 3.2 are UN Nos. 1204, 2059, 3064, 3343, 3357 and 3379. NOTE 1: Substances having a flash-point above 35 °C, non-toxic and non-corrosive, which do not sustain combustion according to the criteria of sub-section 32.2.5 of Part III of the Manual of Tests and Criteria, are not substances of Class 3; if, however, these substances are handed over for carriage and carried whilst heated at temperatures equal to or higher than their flash-point, they are substances of Class 3. NOTE 2: By derogation from paragraph 2.2.3.1.1 above, diesel fuel, gasoil, heating oil (light) having a flash-point above 60 °C and not more than 100 °C shall be deemed substances of Class 3, UN No. 1202. NOTE 3: Liquids which are highly toxic on inhalation, having a flash-point below 23 °C and toxic substances, having a flash-point of 23 °C or above are substances of Class 6.1 (see 2.2.61.1). NOTE 4: Flammable liquid substances and preparations used as pesticides, which are highly toxic, toxic or slightly toxic and have a flash-point of 23 °C or above are substances of Class 6.1 (see 2.2.61.1). 2.2.3.1.2 The substances and articles of Class 3 are subdivided as follows: F Flammable liquids, without subsidiary risk: F1 Flammable liquids having a flash-point of or below 60 °C; F2 Flammable liquids having a flash-point above 60 °C which are carried or handed over for carriage at or above their flash-point (elevated temperature substances); FT Flammable liquids, toxic: FT1 Flammable liquids, toxic; FT2 Pesticides; Copyright © United Nations, 2010. All rights reserved - 151 - FC Flammable liquids, corrosive; FTC Flammable liquids, toxic, corrosive; D Liquid desensitized explosives. 2.2.3.1.3 Substances and articles classified in Class 3 are listed in Table A of Chapter 3.2. Substances not mentioned by name in Table A of Chapter 3.2 shall be assigned to the relevant entry of 2.2.3.3 and the relevant packing group in accordance with the provisions of this section. Flammable liquids shall be assigned to one of the following packing groups according to the degree of danger they present for carriage: Packing group Flash point (closed cup) Initial boiling point I -- d 35°C II a < 23°C > 35°C III a t 23°C d 60°C > 35°C a See also 2.2.3.1.4. For a liquid with (a) subsidiary risk(s), the packing group determined in accordance with the table above and the packing group based on the severity of the subsidiary risk(s) shall be considered; the classification and packing group shall then be determined in accordance with the table of precedence of hazards in 2.1.3.10. 2.2.3.1.4 Liquid or viscous mixtures and preparations, including those containing no more than 20% nitrocellulose with a nitrogen content not exceeding 12.6% (by dry mass), shall be assigned to packing group III only if the following requirements are met: (a) the height of the separated layer of solvent is less than 3% of the total height of the sample in the solvent-separation test (see Manual of Tests and Criteria, Part III, sub-section 32.5.1); and (b) the viscosity 2 and flash-point are in accordance with the following table: Flow time t in accordance with ISO 2431:1993 Kinematic viscosity (extrapolated) Q (at nearzero shear rate) mm2/s at 23 °C in s Jet diameter in mm Flash-point in °C 20  Q d 80 20  t d 60 above 17 80  Q d 135 60  t d 100 above 10 135  Q d 220 20  t d 32 above 5 220  Q d 300 32  t d 44 above -1 300  Q d 700 44  t d 100 above -5 700  Q 100  t -5 and below Viscosity determination: Where the substance concerned is non-Newtonian, or where a flow cup method of viscosity determination is otherwise unsuitable, a variable shear-rate viscometer shall be used to determine the dynamic viscosity coefficient of the substance, at 23 °C, at a number of shear rates. The values obtained are plotted against shear rate and then extrapolated to zero shear rate. The dynamic viscosity thus obtained, divided by the density, gives the apparent kinematic viscosity at near-zero shear rate. Copyright © United Nations, 2010. All rights reserved - 152 - NOTE: Mixtures containing more than 20% but not more than 55% nitrocellulose with a nitrogen content not exceeding 12.6% by dry mass are substances assigned to UN No. 2059. Mixtures having a flash-point below 23 °C and containing: - more than 55% nitrocellulose, whatever their nitrogen content; or - not more than 55% nitrocellulose with a nitrogen content above 12.6% by dry mass, are substances of Class 1 (UN Nos. 0340 or 0342) or of Class 4.1 (UN Nos. 2555, 2556 or 2557). 2.2.3.1.5 Non-toxic, non-corrosive and non-environmentally hazardous solutions and homogeneous mixtures having a flash-point of 23 °C or above (viscous substances, such as paints or varnishes, excluding substances containing more than 20% nitrocellulose) packed in receptacles of less than 450 litres capacity, are not subject to ADR if, in the solvent-separation test (see Manual of Tests and Criteria, Part III, sub-section 32.5.1), the height of the separated layer of solvent is less than 3% of the total height, and if the substances at 23 °C have, in the flow cup conforming to ISO 2431:1993 having a jet 6 mm in diameter, a flow time of: (a) not less than 60 seconds; or (b) not less than 40 seconds and contain not more than 60% of substances of Class 3. 2.2.3.1.6 If substances of Class 3, as a result of admixtures, come into categories of risk different from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures or solutions shall be assigned to the entries to which they belong on the basis of their actual degree of danger. NOTE: For the classification of solutions and mixtures (such as preparations and wastes) see also 2.1.3. 2.2.3.1.7 On the basis of the test procedures in accordance with 2.3.3.1 and 2.3.4, and the criteria set out in 2.2.3.1.1, it may also be determined whether the nature of a solution or a mixture mentioned by name or containing a substance mentioned by name is such that the solution or mixture is not subject to the provisions for this Class (see also 2.1.3). 2.2.3.2 Substances not accepted for carriage 2.2.3.2.1 Substances of Class 3 which are liable to form peroxides easily (as happens with ethers or with certain heterocyclic oxygenated substances) shall not be accepted for carriage if their peroxide content, calculated as hydrogen peroxide (H2O2), exceeds 0.3%. The peroxide content shall be determined as indicated in 2.3.3.3. 2.2.3.2.2 The chemically unstable substances of Class 3 shall not be accepted for carriage unless the necessary steps have been taken to prevent their dangerous decomposition or polymerization during carriage. To this end, it shall be ensured in particular that receptacles and tanks do not contain any substance liable to promote these reactions. 2.2.3.2.3 Liquid desensitized explosives other than those listed in Table A of Chapter 3.2 shall not be accepted for carriage as substances of Class 3. Copyright © United Nations, 2010. All rights reserved - 153 - 2.2.3.3 List of collective entries Flammable liquids F1 Without subsidiary risk F 1133 ADHESIVES containing flammable liquid 1136 COAL TAR DISTILLATES, FLAMMABLE 1139 COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle undercoating, drum or barrel lining) 1169 EXTRACTS, AROMATIC, LIQUID 1197 EXTRACTS, FLAVOURING, LIQUID 1210 PRINTING INK, flammable or 1210 PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable 1263 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or 1263 PAINT RELATED MATERIAL (including paint thinning or reducing compound) 1266 PERFUMERY PRODUCTS with flammable solvents 1293 TINCTURES, MEDICINAL 1306 WOOD PRESERVATIVES, LIQUID 1866 RESIN SOLUTION, flammable 1999 TARS, LIQUID, including road oils, and cutback bitumens 3065 ALCOHOLIC BEVERAGES 3269 POLYESTER RESIN KITS 1224 KETONES, LIQUID, N.O.S. 1268 PETROLEUM DISTILLATES, N.O.S. or 1268 PETROLEUM PRODUCTS, N.O.S. 1987 ALCOHOLS, N.O.S. 1989 ALDEHYDES, N.O.S. 2319 TERPENE HYDROCARBONS, N.O.S. 3271 ETHERS, N.O.S. 3272 ESTERS, N.O.S. 3295 HYDROCARBONS, LIQUID, N.O.S. 3336 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or 3336 MERCAPTANS MIXTURE, LIQUID, FLAMMABLE, N.O.S. 1993 FLAMMABLE LIQUID, N.O.S. F2 elevated temperature 3256 ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S., with flash-point above 60 °C, at or above its flash-point (cont'd on next page) Copyright © United Nations, 2010. All rights reserved - 154 - 2.2.3.3 List of collective entries (cont'd) FT1 1228 MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or 1228 MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 1986 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. 1988 ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. 2478 ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. or 2478 ISOCYANATE SOLUTION, FLAMMABLE, TOXIC, N.O.S. 3248 MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 3273 NITRILES, FLAMMABLE, TOXIC, N.O.S. 1992 FLAMMABLE LIQUID, TOXIC, N.O.S. Toxic FT2 pesticide (f.p<23 °C) FT 2758 CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2760 ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2762 ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2764 TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2772 THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2776 COPPER BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2778 MERCURY BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2780 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2782 BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2784 ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC 2787 ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3024 COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3346 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC 3350 PYRETHROID PESTICIDE, LIQUID, FLAMMABLE TOXIC 3021 PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S. NOTE: The classification of a pesticide under an entry shall be effected on the basis of the active ingredient, of the physical state of the pesticide and any subsidiary risks it may exhibit. Corrosive FC 3469 PAINT, FLAMMABLE, CORROSIVE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or 3469 PAINT RELATED MATERIAL, FLAMMABLE, CORROSIVE (including paint thinning or reducing compound) 2733 AMINES, FLAMMABLE, CORROSIVE, N.O.S. or 2733 POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. 2985 CHLOROSILANES, FLAMMABLE, CORROSIVE, N.O.S. 3274 ALCOHOLATES SOLUTION, N.O.S., in alcohol 2924 FLAMMABLE LIQUID, CORROSIVE, N.O.S. Toxic, corrosive FTC 3286 FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. Liquid desensitised explosive D 3343 NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, FLAMMABLE, N.O.S. with not more than 30% nitroglycerin by mass 3357 NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, N.O.S. with not more than 30% nitroglycerin by mass 3379 DESENSITIZED EXPLOSIVE, LIQUID, N.O.S. Copyright © United Nations, 2010. All rights reserved - 155 - 2.2.41 Class 4.1 Flammable solids, self-reactive substances and solid desensitized explosives 2.2.41.1 Criteria 2.2.41.1.1 The heading of Class 4.1 covers flammable substances and articles, desensitized explosives which are solids according to subparagraph (a) of the definition "solid" in 1.2.1 and self-reactive liquids or solids. The following are assigned to Class 4.1: - readily flammable solid substances and articles (see paragraphs 2.2.41.1.3 to 2.2.41.1.8); - self-reactive solids or liquids (see paragraphs 2.2.41.1.9 to 2.2.41.1.17); - solid desensitized explosives (see 2.2.41.1.18); - substances related to self-reactive substances (see 2.2.41.1.19). 2.2.41.1.2 The substances and articles of Class 4.1 are subdivided as follows: F Flammable solids, without subsidiary risk: F1 Organic; F2 Organic, molten; F3 Inorganic; FO Flammable solids, oxidizing; FT Flammable solids, toxic: FT1 Organic, toxic; FT2 Inorganic, toxic; FC Flammable solids, corrosive: FC1 Organic, corrosive; FC2 Inorganic, corrosive; D Solid desensitized explosives without subsidiary risk; DT Solid desensitized explosives, toxic; SR Self-reactive substances: SR1 Not requiring temperature control; SR2 Requiring temperature control. Copyright © United Nations, 2010. All rights reserved - 156 - Flammable solids Definition and properties 2.2.41.1.3 Flammable solids are readily combustible solids and solids which may cause fire through friction. Readily combustible solids are powdered, granular, or pasty substances which are dangerous if they can be easily ignited by brief contact with an ignition source, such as a burning match, and if the flame spreads rapidly. The danger may come not only from the fire but also from toxic combustion products. Metal powders are especially dangerous because of the difficulty of extinguishing a fire since normal extinguishing agents such as carbon dioxide or water can increase the hazard. Classification 2.2.41.1.4 Substances and articles classified as flammable solids of Class 4.1 are listed in Table A of Chapter 3.2. The assignment of organic substances and articles not mentioned by name in Table A of Chapter 3.2 to the relevant entry of sub-section 2.2.41.3 in accordance with the provisions of Chapter 2.1 can be based on experience or on the results of the test procedures in accordance with Part III, sub-section 33.2.1 of the Manual of Tests and Criteria. The assignment of inorganic substances not mentioned by name shall be based on the results of the test procedures in accordance with Part III, sub-section 33.2.1 of the Manual of Tests and Criteria; experience shall also be taken into account when it leads to a more stringent assignment. 2.2.41.1.5 When substances not mentioned by name are assigned to one of the entries listed in 2.2.41.3 on the basis of the test procedures in accordance with the Manual of Tests and Criteria, Part III, sub-section 33.2.1, the following criteria apply: (a) With the exception of metal powders or powders of metal alloys, powdery, granular or pasty substances shall be classified as readily flammable substances of Class 4.1 if they can be easily ignited by brief contact with an ignition source (e.g. a burning match), or if, in the event of ignition, the flame spreads rapidly, the burning time is less than 45 seconds for a measured distance of 100 mm or the rate of burning is greater than 2.2 mm/s; (b) Metal powders or powders of metal alloys shall be assigned to Class 4.1 if they can be ignited by a flame and the reaction spreads over the whole length of the sample in 10 minutes or less. Solids which may cause fire through friction shall be classified in Class 4.1 by analogy with existing entries (e.g. matches) or in accordance with any appropriate special provision. 2.2.41.1.6 On the basis of the test procedure in accordance with the Manual of Tests and Criteria, Part III, Section 33.2.1 and the criteria set out in 2.2.41.1.4 and 2.2.41.1.5, it may also be determined whether the nature of a substance mentioned by name is such that the substance is not subject to the provisions for this Class. 2.2.41.1.7 If substances of Class 4.1, as a result of admixtures, come into different categories of risk from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures shall be assigned to the entries to which they belong on the basis of their actual degree of danger. NOTE: For the classification of solutions and mixtures (such as preparations and wastes), see also 2.1.3. Copyright © United Nations, 2010. All rights reserved - 157 - Assignment of packing groups 2.2.41.1.8 Flammable solids classified under the various entries in Table A of Chapter 3.2 shall be assigned to packing groups II or III on the basis of test procedures of the Manual of Tests and Criteria, Part III, sub-section 33.2.1, in accordance with the following criteria: (a) Readily flammable solids which, when tested, have a burning time of less than 45 seconds over a measured distance of 100 mm shall be assigned to: Packing group II: if the flame passes the wetted zone; Packing group III: if the wetted zone stops the flame for at least four minutes; (b) Metal powders or powders of metal alloys shall be assigned to: Packing group II: if, when tested, the reaction spreads over the whole length of the sample in five minutes or less; Packing group III: if, when tested, the reaction spreads over the whole length of the sample in more than five minutes. For solids which may cause fire through friction, the packing group shall be assigned by analogy with existing entries or in accordance with any special provision. Self-reactive substances Definitions 2.2.41.1.9 For the purposes of ADR, self-reactive substances are thermally unstable substances liable to undergo a strongly exothermic decomposition even without participation of oxygen (air). Substances are not considered to be self-reactive substances of Class 4.1, if: (a) they are explosives according to the criteria of Class 1; (b) they are oxidizing substances according to the classification procedure for Class 5.1 (see 2.2.51.1) except that mixtures of oxidizing substances which contain 5% or more of combustible organic substances shall be subjected to the classification procedure defined in Note 2; (c) they are organic peroxides according to the criteria of Class 5.2 (see 2.2.52.1); (d) their heat of decomposition is less than 300 J/g; or (e) their self-accelerating decomposition temperature (SADT) (see Note 3 below) is greater than 75 °C for a 50 kg package. NOTE 1: The heat of decomposition can be determined using any internationally recognised method e.g. differential scanning calorimetry and adiabatic calorimetry. NOTE 2: Mixtures of oxidizing substances meeting the criteria of Class 5.1 which contain 5% or more of combustible organic substances, which do not meet the criteria mentioned in (a), (c), (d) or (e) above, shall be subjected to the self-reactive substance classification procedure. A mixture showing the properties of a self-reactive substance, type B to F, shall be classified as a self-reactive substance of Class 4.1. Copyright © United Nations, 2010. All rights reserved - 158 - A mixture showing the properties of a self-reactive substance, type G, according to the principle given in sub-section 20.4.3 (g) of Part II of the Manual of Tests and Criteria shall be considered for classification as a substance of Class 5.1 (see 2.2.51.1). NOTE 3: The self-accelerating decomposition temperature (SADT) is the lowest temperature at which self-accelerating decomposition may occur with a substance in the packaging as used during carriage. Requirements for the determination of the SADT are given in the Manual of Tests and Criteria, Part II, Chapter 20 and section 28.4. NOTE 4: Any substance which shows the properties of a self-reactive substance shall be classified as such, even if this substance gives a positive test result according to 2.2.42.1.5 for inclusion in Class 4.2. Properties 2.2.41.1.10 The decomposition of self-reactive substances can be initiated by heat, contact with catalytic impurities (e.g. acids, heavy-metal compounds, bases), friction or impact. The rate of decomposition increases with temperature and varies with the substance. Decomposition, particularly if no ignition occurs, may result in the evolution of toxic gases or vapours. For certain self-reactive substances, the temperature shall be controlled. Some self-reactive substances may decompose explosively, particularly if confined. This characteristic may be modified by the addition of diluents or by the use of appropriate packagings. Certain selfreactive substances burn vigorously. Self-reactive substances are, for example, some compounds of the types listed below: aliphatic azo compounds (-C-N=N-C-); organic azides (-C-N3); diazonium salts (-CN2 + Z-); N-nitroso compounds (-N-N=O); and aromatic sulphohydrazides (-SO2-NH-NH2). This list is not exhaustive and substances with other reactive groups and some mixtures of substances may have similar properties. Classification 2.2.41.1.11 Self-reactive substances are classified into seven types according to the degree of danger they present. The types of self-reactive substances range from type A, which is not accepted for carriage in the packaging in which it is tested, to type G, which is not subject to the provisions for self-reactive substances of Class 4.1. The classification of types B to F is directly related to the maximum quantity allowed in one packaging. The principles to be applied for classification as well as the applicable classification procedures, test methods and criteria and an example of a suitable test report are given in Part II of the Manual of Tests and Criteria. 2.2.41.1.12 Self-reactive substances which have already been classified and are already permitted for carriage in packagings are listed in 2.2.41.4, those already permitted for carriage in IBCs are listed in 4.1.4.2, packing instruction IBC520 and those already permitted for carriage in tanks according to Chapter 4.2 are listed in 4.2.5.2, portable tank instruction T23. Each permitted substance listed is assigned to a generic entry of Table A of Chapter 3.2 (UN Nos. 3221 to 3240), and appropriate subsidiary risks and remarks providing relevant transport information are given. The collective entries specify: - self-reactive substances types B to F, see 2.2.41.1.11 above; Copyright © United Nations, 2010. All rights reserved - 159 - - physical state (liquid/solid); and - temperature control (when required), see 2.2.41.1.17 below. The classification of the self-reactive substances listed in 2.2.41.4 is based on the technically pure substance (except where a concentration of less than 100% is specified). 2.2.41.1.13 Classification of self-reactive substances not listed in 2.2.41.4, 4.1.4.2, packing instruction IBC520 or 4.2.5.2, portable tank instruction T23 and assignment to a collective entry shall be made by the competent authority of the country of origin on the basis of a test report. The statement of approval shall contain the classification and the relevant conditions of carriage. If the country of origin is not a Contracting Party to ADR, the classification and the conditions of carriage shall be recognized by the competent authority of the first country Contracting Party to ADR reached by the consignment. 2.2.41.1.14 Activators, such as zinc compounds, may be added to some self-reactive substances to change their reactivity. Depending on both the type and the concentration of the activator, this may result in a decrease in thermal stability and a change in explosive properties. If either of these properties is altered, the new formulation shall be assessed in accordance with the classification procedure. 2.2.41.1.15 Samples of self-reactive substances or formulations of self-reactive substances not listed in 2.2.41.4, for which a complete set of test results is not available and which are to be carried for further testing or evaluation, shall be assigned to one of the appropriate entries for selfreactive substances type C provided the following conditions are met: - the available data indicate that the sample would be no more dangerous than selfreactive substances type B; - the sample is packaged in accordance with packing method OP2 and the quantity per transport unit is limited to 10 kg; - the available data indicate that the control temperature, if any, is sufficiently low to prevent any dangerous decomposition and sufficiently high to prevent any dangerous phase separation. Desensitization 2.2.41.1.16 In order to ensure safety during carriage, self-reactive substances are in many cases desensitized by use of a diluent. Where a percentage of a substance is stipulated, this refers to the percentage by mass, rounded to the nearest whole number. If a diluent is used, the selfreactive substance shall be tested with the diluent present in the concentration and form used in carriage. Diluents which may allow a self-reactive substance to concentrate to a dangerous extent in the event of leakage from a packaging shall not be used. Any diluent shall be compatible with the self-reactive substance. In this regard, compatible diluents are those solids or liquids which have no detrimental influence on the thermal stability and hazard type of the self-reactive substance. Liquid diluents in formulations requiring temperature control (see 2.2.41.1.14) shall have a boiling point of at least 60 °C and a flash-point not less than 5 °C. The boiling point of the liquid shall be at least 50 °C higher than the control temperature of the self-reactive substance. Temperature control requirements 2.2.41.1.17 Certain self-reactive substances may only be carried under temperature controlled conditions. The control temperature is the maximum temperature at which the self-reactive substance can be safely carried. It is assumed that the temperature of the immediate Copyright © United Nations, 2010. All rights reserved - 160 - surroundings of a package only exceeds 55 °C during carriage for a relatively short time in a 24 hour period. In the event of loss of temperature control, it may be necessary to implement emergency procedures. The emergency temperature is the temperature at which such procedures shall be implemented. The control and emergency temperatures are derived from the SADT (see table 1). The SADT shall be determined in order to decide whether a substance shall be subjected to temperature control during carriage. Provisions for the determination of the SADT are given in the Manual of Tests and Criteria, Part II, Chapter 20 and Section 28.4. Table 1: Derivation of control and emergency temperatures Type of receptacle SADT a Control temperature Emergency temperature Single packagings and IBCs 20 °C or less 20 °C below SADT 10 °C below SADT over 20 °C to 35 °C 15 °C below SADT 10 °C below SADT over 35 °C 10 °C below SADT 5 °C below SADT Tanks not greater than 50 °C 10 °C below SADT 5 °C below SADT a SADT of the substance as packaged for carriage. Self-reactive substances with an SADT not greater than 55 °C shall be subject to temperature control during carriage. Where applicable, control and emergency temperatures are listed in 2.2.41.4. The actual temperature during carriage may be lower than the control temperature but shall be selected so as to avoid dangerous separation of phases. Solid desensitized explosives 2.2.41.1.18 Solid desensitized explosives are substances which are wetted with water or alcohols or are diluted with other substances to suppress their explosive properties. Such entries in Table A of Chapter 3.2 are: UN Nos. 1310, 1320, 1321, 1322, 1336, 1337, 1344, 1347, 1348, 1349, 1354, 1355, 1356, 1357, 1517, 1571, 2555, 2556, 2557, 2852, 2907, 3317, 3319, 3344, 3364, 3365, 3366, 3367, 3368, 3369, 3370, 3376, 3380 and 3474. Substances related to self-reactive substances 2.2.41.1.19 Substances that: (a) have been provisionally accepted into Class 1 according to Test Series 1 and 2 but exempted from Class 1 by Test Series 6; (b) are not self-reactive substances of Class 4.1; and (c) are not substances of Classes 5.1 or 5.2; are also assigned to Class 4.1. UN Nos. 2956, 3241, 3242 and 3251 are such entries. 2.2.41.2 Substances not accepted for carriage 2.2.41.2.1 The chemically unstable substances of Class 4.1 shall not be accepted for carriage unless the necessary steps have been taken to prevent their dangerous decomposition or polymerization during carriage. To this end, it shall in particular be ensured that receptacles and tanks do not contain any substance liable to promote these reactions. Copyright © United Nations, 2010. All rights reserved - 161 - 2.2.41.2.2 Flammable solids, oxidizing, assigned to UN No. 3097 shall not be accepted for carriage unless they meet the requirements for Class 1 (see also 2.1.3.7). 2.2.41.2.3 The following substances shall not be accepted for carriage: - Self-reactive substances of type A (see Manual of Tests and Criteria, Part II, paragraph 20.4.2 (a)); - Phosphorus sulphides which are not free from yellow and white phosphorus; - Solid densitized explosives other than those listed in Table A of Chapter 3.2; - Inorganic flammable substances in the molten form other than UN No. 2448 SULPHUR, MOLTEN. Copyright © United Nations, 2010. All rights reserved - 162 - 2.2.41.3 List of collective entries 3175 SOLIDS CONTAINING FLAMMABLE LIQUID, N.O.S. 1353 FIBRES IMPREGNATED WITH WEAKLY NITRATED NITROCELLULOSE, N.O.S. or 1353 FABRICS IMPREGNATED WITH WEAKLY NITRATED NITROCELLULOSE, N.O.S. organic F1 1325 FLAMMABLE SOLID, ORGANIC, N.O.S. organic molten F2 3176 FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. 3089 METAL POWDER, FLAMMABLE, N.O.S. a b inorganic F3 3181 METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S. 3182 METAL HYDRIDES, FLAMMABLE,N.O.S. c 3178 FLAMMABLE SOLID, INORGANIC, N.O.S. without subsidiary risk Flammable solids oxidizing FO 3097 FLAMMABLE SOLID, OXIDIZING, N.O.S. (not allowed, see para. 2.2.41.2.2) organic FT1 2926 FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. toxic FT inorganic FT2 3179 FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S. organic FC1 2925 FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S. corrosive FC inorganic FC2 3180 FLAMMABLE SOLID, CORROSIVE, INORGANIC, N.O.S. without subsidiary risk D 3319 NITROGLYCERIN MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 2% but not more than 10% nitroglycerin by mass 3344 PENTAERYTHRITE TETRANITRATE (PENTAERYTHRITOL TETRANITRATE, PETN) MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 10% but not more than 20% PETN by mass 3380 DESENSITIZED EXPLOSIVE, SOLID, N.O.S. Solid desensitized explosives toxic DT Only substances listed in Table A of Chapter 3.2 are to be accepted for carriage as substances of Class 4.1 SELF-REACTIVE LIQUID TYPE A SELF-REACTIVE SOLID TYPE A } Not accepted for carriage, see 2.2.41.2.3 3221 SELF-REACTIVE LIQUID TYPE B 3222 SELF-REACTIVE SOLID TYPE B 3223 SELF-REACTIVE LIQUID TYPE C 3224 SELF-REACTIVE SOLID TYPE C 3225 SELF-REACTIVE LIQUID TYPE D 3226 SELF-REACTIVE SOLID TYPE D 3227 SELF-REACTIVE LIQUID TYPE E not requiring temperature control 3228 SELF-REACTIVE SOLID TYPE E 3229 SELF-REACTIVE LIQUID TYPE F 3230 SELF-REACTIVE SOLID TYPE F SELF-REACTIVE LIQUID TYPE G SR1 SELF-REACTIVE SOLID TYPE G } Not subject to the provisions applicable to Class 4.1, see 2.2.41.1.11 Self-reactive substances 3231 SELF-REACTIVE LIQUID TYPE B, TEMPERATURE CONTROLLED 3232 SELF-REACTIVE SOLID TYPE B, TEMPERATURE CONTROLLED 3233 SELF-REACTIVE LIQUID TYPE C, TEMPERATURE CONTROLLED 3234 SELF-REACTIVE SOLID TYPE C, TEMPERATURE CONTROLLED requiring temperature control SR2 3235 SELF-REACTIVE LIQUID TYPE D, TEMPERATURE CONTROLLED 3236 SELF-REACTIVE SOLID TYPE D, TEMPERATURE CONTROLLED 3237 SELF-REACTIVE LIQUID TYPE E, TEMPERATURE CONTROLLED 3238 SELF-REACTIVE SOLID TYPE E, TEMPERATURE CONTROLLED 3239 SELF-REACTIVE LIQUID TYPE F, TEMPERATURE CONTROLLED SR 3240 SELF-REACTIVE SOLID TYPE F, TEMPERATURE CONTROLLED a Metals and metal alloys in powdered or other flammable form, liable to spontaneous combustion, are substances of Class 4.2. b Metals and metal alloys in powdered or other flammable form, which in contact with water, emit flammable gases, are substances of Class 4.3. c Metals hydrides which, in contact with water, emit flammable gases, are substances of Class 4.3. Aluminium borohydride or aluminium borohydride in devices are substances of Class 4.2, UN No. 2870. Copyright © United Nations, 2010. All rights reserved - 163 - 2.2.41.4 List of currently assigned self-reactive substances in packagings In the column "Packing Method" codes "OP1" to "OP8" refer to packing methods in 4.1.4.1, packing instruction P520 (see also 4.1.7.1). Self-reactive substances to be carried shall fulfil the classification and the control and emergency temperatures (derived from the SADT) as listed. For substances permitted in IBCs, see 4.1.4.2, packing instruction IBC520 and, for those permitted in tanks according to Chapter 4.2, see 4.2.5.2, portable tank instruction T23. NOTE: The classification given in this table is based on the technically pure substance (except where a concentration of less than 100% is specified). For other concentrations, the substance may be classified differently following the procedures given in Part II of the Manual of Tests and Criteria and in 2.2.41.1.17. SELF-REACTIVE SUBSTANCE Concentration (%) Packing method Control temperature (°C) Emergency temperature (°C) UN generic entry Remarks ACETONE-PYROGALLOL COPOLYMER 2-DIAZO-1-NAPHTHOL-5-SULPHONATE OP8 AZODICARBONAMIDE FORMULATION TYPE B, TEMPERATURE CONTROLLED < 100 OP5

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