Publication: Magyar Közlöny
Issue: MK-2011-73 (Year: 2011, Number: 73)
Era: contemporary
Section: 1. melléklet a 2011. évi LXXIX. törvényhez
Paragraph Index: 263

(2) UN No. Name and description Transport category (Tunnel restriction code) Hazard identification No. Vehicle for tank carriage SGAN TU3 AT (E) CV24 CV35 3487 CALCIUM HYPOCHLORITE, HYDRATED, CORROSIVE or CALCIUM HYPOCHLORITE, HYDRATED MIXTURE, CORROSIVE with not less than 5.5% but not more than 16% water L15CH TU14 TU15 TE19 TE21 FL (C/D) CV1 CV13 CV28 S2 S9 S14 3488 TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m³ and saturated vapour concentration greater than or equal to 500 LC50 L10CH TU14 TU15 TE19 TE21 FL (C/D) CV1 CV13 CV28 S2 S9 S14 3489 TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m³ and saturated vapour concentration greater than or equal to 10 LC50 L15CH TU14 TU15 TE19 TE21 FL (C/D) CV1 CV13 CV28 S2 S9 S14 3490 TOXIC BY INHALATION LIQUID, WATER- REACTIVE, FLAMMABLE, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m³ and saturated vapour concentration greater than or equal to 500 LC50 L10CH TU14 TU15 TE19 TE21 FL (C/D) CV1 CV13 CV28 S2 S9 S14 3491 TOXIC BY INHALATION LIQUID, WATER- REACTIVE, FLAMMABLE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m³ and saturated vapour concentration greater than or equal to 10 LC50 L15CH TU14 TU15 TE19 TE21 FL (C/D) CV1 CV13 CV28 S2 S9 S14 3492 TOXIC BY INHALATION LIQUID, CORROSIVE, FLAMMABLE, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m³ and saturated vapour concentration greater than or equal to 500 LC50 L10CH TU14 TU15 TE19 TE21 FL (C/D) CV1 CV13 CV28 S2 S9 S14 3493 TOXIC BY INHALATION LIQUID, CORROSIVE, FLAMMABLE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m³ and saturated vapour concentration greater than or equal to 10 LC50 L10CH TU14 TU15 TE21 FL (C/E) CV13 CV28 S2 S22 3494 PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC L4BH TU15 FL (D/E) CV13 CV28 S2 S19 3494 PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC L4BH TU15 FL (D/E) V12 CV13 CV28 S2 3494 PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC SGAV L4BN AT (E) VV9 CV13 CV28 3495 IODINE NOT SUBJECT TO ADR 3496 Batteries, nickel-metal hydride - 559 - Copyright © United Nations, 2010. All rights reserved - 560 - 3.2.2 Table B: Alphabetic index of substances and articles of ADR This index is an alphabetical list of the substances and articles which are listed in the UN numerical order in Table A of 3.2.1. It does not form an integral part of ADR. It has been submitted neither to the Working Party on the Transport of Dangerous Goods of the Inland Transport Committee for checking and approval nor to the Contracting Parties to ADR for formal acceptance. It has been prepared, with all necessary care by the Secretariat of the United Nations Economic Commission for Europe, in order to facilitate the consultation of Annexes A and B, but it cannot be relied upon as a substitute for the careful study and observance of the actual provisions of those annexes which, in case of conflict, are deemed to be authoritative. NOTE 1: For the purpose of determining the alphabetical order the following information has been ignored, even when it forms part of the proper shipping name: numbers; Greek letters; the abbreviations "sec" and "tert"; and the letters "N" (nitrogen), "n" (normal), "o" (ortho), "m" (meta), "p" (para) and "N.O.S." (not otherwise specified). NOTE 2: The name of a substance or article in block capital letters indicates a proper shipping name (see 3.1.2). NOTE 3: The name of a substance or article in block capital letters followed by the word "see" indicates an alternative proper shipping name or part of a proper shipping name (except for PCBs) (see 3.1.2.1). NOTE 4: An entry in lower case letters followed by the word "see" indicates that the entry is not a proper shipping name; it is a synonym. NOTE 5: Where an entry is partly in block capital letters and partly in lower case letters, the latter part is considered not to be part of the proper shipping name (see 3.1.2.1). NOTE 6: A proper shipping name may be used in the singular or plural, as appropriate, for the purposes of documentation and package marking (see 3.1.2.3). NOTE 7: For the exact determination of a proper shipping name, see 3.1.2. Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 561 - Accumulators, electric, see 4.3 ACETAL ACETALDEHYDE ACETALDEHYDE AMMONIA ACETALDEHYDE OXIME ACETIC ACID, GLACIAL ACETIC ACID SOLUTION, more than 10% but not more than 80% acid, by mass ACETIC ACID SOLUTION, more than 80% acid, by mass ACETIC ANHYDRIDE Acetoin, see ACETONE ACETONE CYANOHYDRIN, STABILIZED 6.1 ACETONE OILS ACETONITRILE ACETYL BROMIDE ACETYL CHLORIDE ACETYLENE, DISSOLVED ACETYLENE, SOLVENT FREE Acetylene tetrabromide, see 6.1 Acetylene tetrachloride, see 6.1 ACETYL IODIDE ACETYL METHYL CARBINOL Acid butyl phosphate, see Acid mixture, hydrofluoric and sulphuric, see Acid mixture, nitrating acid, see Acid mixture, spent, nitrating acid, see Acraldehyde, inhibited, see 6.1 ACRIDINE 6.1 ACROLEIN DIMER, STABILIZED ACROLEIN, STABILIZED 6.1 ACRYLAMIDE, SOLID 6.1 ACRYLAMIDE, SOLUTION 6.1 ACRYLIC ACID, STABILIZED ACRYLONITRILE, STABILIZED Actinolite, see Activated carbon, see 4.2 Activated charcoal, see 4.2 ADHESIVES containing flammable liquid ADIPONITRILE 6.1 Aeroplane flares, see AEROSOLS AGENT, BLASTING, TYPE B AGENT, BLASTING, TYPE E AIR BAG INFLATORS AIR BAG MODULES AIR, COMPRESSED Aircraft evacuation slides, see AIRCRAFT HYDRAULIC POWER UNIT FUEL TANK (containing a mixture of anhydrous hydrazine and methylhydrazine) (M86 fuel) Aircraft survival kits, see AIR, REFRIGERATED LIQUID ALCOHOLATES SOLUTION, N.O.S., in alcohol Alcohol, denaturated, see Alcohol, industrial, see ALCOHOLS, N.O.S. ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. ALCOHOLIC BEVERAGES, with more than 24% but not more than 70% alcohol by volume ALCOHOLIC BEVERAGES, with more than 70% alcohol by volume Aldehyde, see ALDEHYDES, N.O.S. ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. ALDOL 6.1 ALKALI METAL ALCOHOLATES, SELF- HEATING, CORROSIVE, N.O.S. 4.2 ALKALI METAL ALLOY, LIQUID, N.O.S. 4.3 ALKALI METAL AMALGAM, LIQUID 4.3 Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 562 - ALKALI METAL AMALGAM, SOLID 4.3 ALKALI METAL AMIDES 4.3 ALKALI METAL DISPERSION 4.3 ALKALI METAL DISPERSION, FLAMMABLE 4.3 Alkaline corrosive battery fluid, see ALKALINE EARTH METAL ALCOHOLATES, N.O.S. 4.2 ALKALINE EARTH METAL ALLOY, N.O.S. 4.3 ALKALINE EARTH METAL AMALGAM, LIQUID 4.3 ALKALINE EARTH METAL AMALGAM, SOLID 4.3 ALKALINE EARTH METAL DISPERSION 4.3 ALKALINE EARTH METAL DISPERSION, FLAMMABLE 4.3 ALKALOIDS, LIQUID, N.O.S. 6.1 ALKALOIDS, SOLID, N.O.S. 6.1 ALKALOID SALTS, LIQUID, N.O.S. 6.1 ALKALOID SALTS, SOLID, N.O.S. 6.1 Alkyl aluminium halides, see 4.2 ALKYLPHENOLS, LIQUID, N.O.S. (including C2-C12 homologues) ALKYLPHENOLS, SOLID, N.O.S. (including C2-C12 homologues) ALKYLSULPHONIC ACIDS, LIQUID with more than 5% free sulphuric acid ALKYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid ALKYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid ALKYLSULPHONIC ACIDS, SOLID with not more than 5% free sulphuric acid ALKYLSULPHURIC ACIDS Allene, see ALLYL ACETATE ALLYL ALCOHOL 6.1 ALLYLAMINE 6.1 ALLYL BROMIDE ALLYL CHLORIDE Allyl chlorocarbonate, see 6.1 ALLYL CHLOROFORMATE 6.1 ALLYL ETHYL ETHER ALLYL FORMATE ALLYL GLYCIDYL ETHER ALLYL IODIDE ALLYL ISOTHIOCYANATE, STABILIZED 6.1 ALLYLTRICHLOROSILANE, STABILIZED Aluminium alkyls, see 4.2 Aluminium alkyl halides, liquid, see 4.2 Aluminium alkyl halides, solid, see 4.2 Aluminium alkyl hydrides, see 4.2 ALUMINIUM BOROHYDRIDE 4.2 ALUMINIUM BOROHYDRIDE IN DEVICES 4.2 ALUMINIUM BROMIDE, ANHYDROUS ALUMINIUM BROMIDE SOLUTION ALUMINIUM CARBIDE 4.3 ALUMINIUM CHLORIDE, ANHYDROUS ALUMINIUM CHLORIDE SOLUTION Aluminium dross, see 4.3 ALUMINIUM FERROSILICON POWDER 4.3 ALUMINIUM HYDRIDE 4.3 ALUMINIUM NITRATE 5.1 ALUMINIUM PHOSPHIDE 4.3 ALUMINIUM PHOSPHIDE PESTICIDE 6.1 ALUMINIUM POWDER, COATED 4.1 ALUMINIUM POWDER, UNCOATED 4.3 ALUMINIUM REMELTING BY- PRODUCTS 4.3 ALUMINIUM RESINATE 4.1 ALUMINIUM SILICON POWDER, UNCOATED 4.3 ALUMINIUM SMELTING BY- PRODUCTS 4.3 Amatols, see AMINES, FLAMMABLE, CORROSIVE, N.O.S. AMINES, LIQUID, CORROSIVE, N.O.S. Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 563 - AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. AMINES, SOLID, CORROSIVE, N.O.S. Aminobenzene, see 6.1 2-Aminobenzotrifluoruride, see 6.1 3-Aminobenzotrifluoruride, see 6.1 Aminobutane, see 2-AMINO-4-CHLOROPHENOL 6.1 2-AMINO-5-DIETHYL- AMINOPENTANE 6.1 2-AMINO-4,6-DINITROPHENOL, WETTED with not less than 20% water, by mass 4.1 2-(2-AMINOETHOXY) ETHANOL N-AMINOETHYLPIPERAZINE 1-Amino-2-nitrobenzene, see 6.1 1-Amino-3-nitrobenzene, see 6.1 1-Amino-4-nitrobenzene, see 6.1 AMINOPHENOLS (o-, m-, p-) 6.1 AMINOPYRIDINES (o-, m-, p-) 6.1 AMMONIA, ANHYDROUS AMMONIA SOLUTION relative density between 0.880 and 0.957 at 15 °C in water, with more than 10% but not more than 35% ammonia AMMONIA SOLUTION, relative density less than 0.880 at 15 °C in water, with more than 35% but not more than 50% ammonia AMMONIA SOLUTION, relative density less than 0.880 at 15 °C in water, with more than 50% ammonia AMMONIUM ARSENATE 6.1 Ammonium bichromate, see 5.1 Ammonium bifluoride solid, see Ammonium bifluoride solution, see Ammonium bisulphate, see Ammonium bisulphite solution, see AMMONIUM DICHROMATE 5.1 AMMONIUM DINITRO-o- CRESOLATE, SOLID 6.1 AMMONIUM DINITRO-o- CRESOLATE, SOLUTION 6.1 AMMONIUM FLUORIDE 6.1 AMMONIUM FLUORO-SILICATE 6.1 Ammonium hexafluorosilicate, see 6.1 AMMONIUM HYDROGENDIFLUORIDE, SOLID AMMONIUM HYDROGENDIFLUORIDE SOLUTION AMMONIUM HYDROGEN SULPHATE Ammonium hydrosulphide solution (treat as ammonium sulphide solution), see AMMONIUM METAVANADATE 6.1 AMMONIUM NITRATE with more than 0.2% combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance AMMONIUM NITRATE with not more than 0.2% total combustible material, including any organic substance calculated as carbon, to the exclusion of any other added substance 5.1 AMMONIUM NITRATE EMULSION, intermediate for blasting explosives, liquid 5.1 AMMONIUM NITRATE EMULSION, intermediate for blasting explosives, solid 5.1 Ammonium nitrate explosive, see AMMONIUM NITRATE BASED FERTILIZER 5.1 Ammonium nitrate based fertilizer, uniform mixtures of the nitrogen/phosphate, nitrogen/potash or nitrogen/phosphate/potash type, containing not more than 70% ammonium nitrate and not more than 0.4% total combustible/organic material calculated as carbon or with not more than 45% ammonium nitrate and unrestricted combustible material Not subject to ADR AMMONIUM NITRATE GEL, intermediate for blasting explosives, liquid 5.1 AMMONIUM NITRATE GEL, intermediate for blasting explosives, solid 5.1 AMMONIUM NITRATE, LIQUID hot concentrated solution, in a concentration of more than 80% but not more than 93% 5.1 Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 564 - AMMONIUM NITRATE SUSPENSION, intermediate for blasting explosives, liquid 5.1 AMMONIUM NITRATE SUSPENSION, intermediate for blasting explosives, solid 5.1 AMMONIUM PERCHLORATE 5.1 Ammonium permanganate, see 5.1 AMMONIUM PERSULPHATE 5.1 AMMONIUM PICRATE dry or wetted with less than 10% water, by mass AMMONIUM PICRATE, WETTED with not less than 10% water, by mass 4.1 AMMONIUM POLYSULPHIDE SOLUTION AMMONIUM POLYVANADATE 6.1 Ammonium silicofluoride, see 6.1 AMMONIUM SULPHIDE SOLUTION Ammunition, blank, see Ammunition, fixed Ammunition, semi-fixed Ammunition, separate loading, see AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge AMMUNITION, INCENDIARY, liquid or gel, with burster, expelling charge or propelling charge AMMUNITION, INCENDIARY with or without burster, expelling charge or propelling charge Ammunition, incendiary (wateractivated contrivances) with burster, expelling charge or propelling charge, see AMMUNITION, INCENDIARY, WHITE PHOSPHORUS with burster, expelling charge or propelling charge Ammunition, industrial, see Ammunition, lachrymatory, see AMMUNITION, PRACTICE AMMUNITION, PROOF AMMUNITION, SMOKE with or without burster, expelling charge or propelling charge Ammunition, smoke (water-activated contrivances), white phosphorus with burster, expelling charge or propelling charge, see Ammunition, smoke (water-activated contrivances), without white phosphorus or phosphides with burster, expelling charge or propelling charge, see AMMUNITION, SMOKE, WHITE PHOSPHORUS with burster, expelling charge or propelling charge Ammunition, sporting, see AMMUNITION, TEAR- PRODUCING, NON-EXPLOSIVE without burster or expelling charge, non-fuzed 6.1 AMMUNITION, TEAR- PRODUCING with burster, expelling charge or propelling charge AMMUNITION, TOXIC with burster, expelling charge or propelling charge Carriage prohibited AMMUNITION, TOXIC with burster, expelling charge or propelling charge Carriage prohibited Ammunition, toxic (water-activated contrivances) with burster, expelling charge or propelling charge, see AMMUNITION, TOXIC, NON- EXPLOSIVE without burster or expelling charge, non-fuzed 6.1 Amosite, see AMYL ACETATES AMYL ACID PHOSPHATE Amyl aldehyde, see AMYLAMINE AMYL BUTYRATES AMYL CHLORIDE Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 565 - n-AMYLENE, see AMYL FORMATES AMYL MERCAPTAN n-AMYL METHYL KETONE AMYL NITRATE AMYL NITRITE AMYLTRICHLOROSILANE Anaesthetic ether, see ANILINE 6.1 Aniline chloride, see 6.1 ANILINE HYDROCHLORIDE 6.1 Aniline oil, see 6.1 Aniline salt, see 6.1 ANISIDINES 6.1 ANISOLE ANISOYL CHLORIDE Anthophyllite, see Antimonous chloride, see ANTIMONY COMPOUND, INORGANIC, LIQUID, N.O.S. 6.1 ANTIMONY COMPOUND, INORGANIC, SOLID, N.O.S. 6.1 Antimony hydride, see ANTIMONY LACTATE 6.1 Antimony (III) lactate, see 6.1 ANTIMONY PENTACHLORIDE, LIQUID ANTIMONY PENTACHLORIDE SOLUTION ANTIMONY PENTAFLUORIDE Antimony perchloride, liquid, see ANTIMONY POTASSIUM TARTRATE 6.1 ANTIMONY POWDER 6.1 ANTIMONY TRICHLORIDE A.n.t.u., see 6.1 ARGON, COMPRESSED ARGON, REFRIGERATED LIQUID Arsenates, n.o.s., see 6.1 6.1 ARSENIC 6.1 ARSENIC ACID, LIQUID 6.1 ARSENIC ACID, SOLID 6.1 ARSENICAL DUST 6.1 Arsenical flue dust, see 6.1 ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 °C ARSENICAL PESTICIDE, LIQUID, TOXIC 6.1 ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23 °C 6.1 ARSENICAL PESTICIDE, SOLID, TOXIC 6.1 ARSENIC BROMIDE 6.1 Arsenic (III) bromide, see 6.1 Arsenic chloride, see 6.1 ARSENIC COMPOUND, LIQUID, N.O.S., inorganic, including: Arsenates, n.o.s., Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 6.1 ARSENIC COMPOUND, SOLID, N.O.S., inorganic, including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 6.1 Arsenic (III) oxide, see 6.1 Arsenic (V) oxide, see 6.1 ARSENIC PENTOXIDE 6.1 Arsenic sulphides, see 6.1 6.1 ARSENIC TRICHLORIDE 6.1 ARSENIC TRIOXIDE 6.1 Arsenious chloride, see 6.1 Arsenites, n.o.s., see 6.1 6.1 Arsenous chloride, see 6.1 ARSINE ARTICLES, EEI, see ARTICLES, EXPLOSIVE, EXTREMELY INSENSITIVE Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 566 - ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, PRESSURIZED, HYDRAULIC (containing nonflammable gas) ARTICLES, PRESSURIZED, PNEUMATIC (containing nonflammable gas) ARTICLES, PYROPHORIC ARTICLES, PYROTECHNIC for technical purposes ARYLSULPHONIC ACIDS, LIQUID with more than 5% free sulphuric acid ARYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid ARYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid ARYLSULPHONIC ACIDS, SOLID with not more than 5% free sulphuric acid Asbestos, blue or brown, see Asbestos, white, see Asphalt, with a flash-point above 60 °C, at or above its flash-point, see Asphalt, at or above 100 °C and below its flash-point, see Aviation regulated liquid, n.o.s. Not subject to ADR Aviation regulated solid, n.o.s. Not subject to ADR AZODICARBONAMIDE 4.1 Bag charges, see Ballistite, see Bangalore torpedoes, see BARIUM 4.3 BARIUM ALLOYS, PYROPHORIC 1854 4.2 BARIUM AZIDE, dry or wetted with less than 50% water, by mass BARIUM AZIDE, WETTED with not less than 50% water, by mass 4.1 Barium binoxide, see 5.1 BARIUM BROMATE 5.1 BARIUM CHLORATE, SOLID 5.1 BARIUM CHLORATE, SOLUTION 3405 5.1 BARIUM COMPOUND, N.O.S. 6.1 BARIUM CYANIDE 6.1 Barium dioxide, see 5.1 BARIUM HYPOCHLORITE with more than 22% available chlorine 5.1 BARIUM NITRATE 5.1 BARIUM OXIDE 6.1 BARIUM PERCHLORATE, SOLID 5.1 BARIUM PERCHLORATE, SOLUTION 5.1 BARIUM PERMANGANATE 5.1 BARIUM PEROXIDE 5.1 Barium selenate, see 6.1 Barium selenite, see 6.1 Barium superoxide, see 5.1 BATTERIES, CONTAINING SODIUM 4.3 BATTERIES, DRY, CONTAINING POTASSIUM HYDROXIDE SOLID, electric storage Batteries, nickel-metal hydride Not subject to ADR BATTERIES, WET, FILLED WITH ACID, electric storage BATTERIES, WET, FILLED WITH ALKALI, electric storage BATTERIES, WET, NON- SPILLABLE, electric storage BATTERY FLUID, ACID BATTERY FLUID, ALKALI Battery-powered vehicle or Batterypowered equipment Not subject to ADR BENZALDEHYDE Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 567 - BENZENE BENZENESULPHONYL CHLORIDE Benzenethiol, see 6.1 BENZIDINE 6.1 Benzol, see Benzolene, see BENZONITRILE 6.1 BENZOQUINONE 6.1 Benzosulphochloride, see BENZOTRICHLORIDE BENZOTRIFLUORIDE BENZOYL CHLORIDE BENZYL BROMIDE 6.1 BENZYL CHLORIDE 6.1 Benzyl chlorocarbonate, see BENZYL CHLOROFORMATE Benzyl cyanide, see 6.1 BENZYLDIMETHYLAMINE BENZYLIDENE CHLORIDE 6.1 BENZYL IODIDE 6.1 BERYLLIUM COMPOUND, N.O.S. 1566 6.1 BERYLLIUM NITRATE 5.1 BERYLLIUM POWDER 6.1 Bhusa 4.1 Not subject to ADR BICYCLO[2.2.1]HEPTA-2,5- DIENE, STABILIZED Bifluorides, n.o.s., see BIOLOGICAL SUBSTANCE, CATEGORY B 6.2 (BIO) MEDICAL WASTE, N.O.S. 6.2 BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC 6.1 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 6.1 BIPYRIDILIUM PESTICIDE, SOLID, TOXIC 6.1 BISULPHATES, AQUEOUS SOLUTION BISULPHITES, AQUEOUS SOLUTION, N.O.S. Bitumen, with a flash-point above 60 °C, at or above its flash-point, see Bitumen, at or above 100 °C and below its flash-point, see BLACK POWDER, COMPRESSED BLACK POWDER, granular or as a meal BLACK POWDER, IN PELLETS Blasting cap assemblies, see Blasting caps, electric, see Blasting caps, non electric, see Bleaching powder, see 5.1 BLUE ASBESTOS (crocidolite) BOMBS with bursting charge Bombs, illuminating, see BOMBS, PHOTO-FLASH BOMBS, SMOKE, NON- EXPLOSIVE with corrosive liquid, without initiating device Bombs, target identification, see BOMBS WITH FLAMMABLE LIQUID with bursting charge BOOSTERS WITH DETONATOR BOOSTERS without detonator Borate and chlorate mixture, see 5.1 BORNEOL 4.1 BORON TRIBROMIDE BORON TRICHLORIDE BORON TRIFLUORIDE ACETIC ACID COMPLEX, LIQUID BORON TRIFLUORIDE ACETIC ACID COMPLEX, SOLID BORON TRIFLUORIDE BORON TRIFLUORIDE DIETHYL ETHERATE Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 568 - BORON TRIFLUORIDE DIHYDRATE BORON TRIFLUORIDE DIMETHYL ETHERATE 4.3 BORON TRIFLUORIDE PROPIONIC ACID COMPLEX, LIQUID BORON TRIFLUORIDE PROPIONIC ACID COMPLEX, SOLID BROMATES, INORGANIC, N.O.S. 5.1 BROMATES, INORGANIC, AQUEOUS SOLUTION, N.O.S 5.1 BROMINE BROMINE CHLORIDE BROMINE PENTAFLUORIDE 5.1 BROMINE SOLUTION BROMINE TRIFLUORIDE 5.1 BROMOACETIC ACID, SOLID BROMOACETIC ACID, SOLUTION BROMOACETONE 6.1 omega-Bromoacetone, see 6.4 BROMOACETYL BROMIDE BROMOBENZENE BROMOBENZYL CYANIDES, LIQUID 6.1 BROMOBENZYL CYANIDES, SOLID 6.1 1-BROMOBUTANE 2-BROMOBUTANE BROMOCHLOROMETHANE 6.1 1-BROMO-3-CHLOROPROPANE 6.1 1-Bromo-2,3-epoxypropane, see 6.1 Bromoethane, see 6.1 2-BROMOETHYL ETHYL ETHER BROMOFORM 6.1 Bromomethane, see 1-BROMO-3-METHYLBUTANE BROMOMETHYLPROPANES 2-BROMO-2-NITROPROPANE- 1,3-DIOL 4.1 2-BROMOPENTANE BROMOPROPANES 3-BROMOPROPYNE BROMOTRIFLUOROETHYLENE BROMOTRIFLUOROMETHANE BROWN ASBESTOS (amosite, mysorite) BRUCINE 6.1 BURSTERS, explosive BUTADIENES AND HYDROCARBON MIXTURE, STABILIZED, having a vapour pressure at 70 °C not exceeding 1.1 MPa (11 bar) and a density at 50 °C not lower than 0.525 kg/l BUTADIENES, STABILIZED, (1,2butadiene) BUTADIENES, STABILIZED, (1,3butadiene) BUTANE BUTANEDIONE Butane-1-thiol, see BUTANOLS 1-Butanol, see Butan-2-ol, see Butanol, secondary, see Butanol, tertiary, see Butanone, see 2-Butenal, see 6.1 Butene, see Bute-1-ene-3-one, see 1,2-Buteneoxide, see 2-Buten-1-ol, see BUTYL ACETATES Butyl acetate, secondary, see BUTYL ACID PHOSPHATE BUTYL ACRYLATES, STABILIZED Butyl alcohols, see n-BUTYLAMINE N-BUTYLANILINE 6.1 sec-Butyl benzene, see BUTYLBENZENES n-Butyl bromide, see n-Butyl chloride, see n-BUTYL CHLOROFORMATE 6.1 tert-BUTYLCYCLOHEXYL CHLOROFORMATE 6.1 BUTYLENES MIXTURE or 1- BUTYLENE or CIS-2-BUTYLENE or TRANS-2-BUTYLENE Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 569 - 1,2-BUTYLENE OXIDE, STABILIZED Butyl ethers, see Butyl ethyl ether, see n-BUTYL FORMATE tert-BUTYL HYPOCHLORITE 4.2 Carriage prohibited N,n-BUTYLIMIDAZOLE 6.1 N,n-Butyliminazole, see 6.1 n-BUTYL ISOCYANATE 6.1 tert-BUTYL ISOCYANATE 6.1 Butyl lithium, see 4.2 BUTYL MERCAPTAN n-BUTYL METHACRYLATE, STABILIZED BUTYL METHYL ETHER BUTYL NITRITES Butylphenols, liquid, see Butylphenols, solid, see BUTYL PROPIONATES p-tert-Butyltoluene, see 6.1 BUTYLTOLUENES 6.1 BUTYLTRICHLOROSILANE 5-tert-BUTYL-2,4,6-TRINITRO-m- XYLENE 4.1 BUTYL VINYL ETHER, STABILIZED But-1-yne, see 1,4-BUTYNEDIOL 6.1 2-Butyne-1,4-diol, see 6.1 BUTYRALDEHYDE BUTYRALDOXIME BUTYRIC ACID BUTYRIC ANHYDRIDE Butyrone, see BUTYRONITRILE Butyroyl chloride, see BUTYRYL CHLORIDE Cable cutters, explosive, see CACODYLIC ACID 6.1 CADMIUM COMPOUND 6.1 CAESIUM 4.3 CAESIUM HYDROXIDE CAESIUM HYDROXIDE SOLUTION CAESIUM NITRATE 5.1 Caffeine, see 6.1 Cajeputene, see CALCIUM 4.3 CALCIUM ALLOYS, PYROPHORIC 4.2 CALCIUM ARSENATE 6.1 CALCIUM ARSENATE AND CALCIUM ARSENITE MIXTURE, SOLID 6.1 Calcium bisulphite solution, see CALCIUM CARBIDE 4.3 CALCIUM CHLORATE 5.1 CALCIUM CHLORATE, AQUEOUS SOLUTION 5.1 CALCIUM CHLORITE 5.1 CALCIUM CYANAMIDE with more than 0.1% calcium carbide 4.3 CALCIUM CYANIDE 6.1 CALCIUM DITHIONITE 4.2 CALCIUM HYDRIDE 4.3 CALCIUM HYDROSULPHITE, see 4.2 CALCIUM HYPOCHLORITE, DRY with more than 39% available chlorine (8.8% available oxygen) 5.1 CALCIUM HYPOCHLORITE, DRY, CORROSIVE with more than 39% available chlorine (8.8% available oxygen) 5.1 CALCIUM HYPOCHLORITE, HYDRATED with not less than 5.5% but not more than 16% water 5.1 CALCIUM HYPOCHLORITE, HYDRATED MIXTURE with not less than 5.5% but not more than 16% water 5.1 CALCIUM HYPOCHLORITE, HYDRATED, CORROSIVE with not less than 5.5% but not more than 16% water 5.1 CALCIUM HYPOCHLORITE, HYDRATED MIXTURE, CORROSIVE with not less than 5.5% but not more than 16% water 5.1 CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 10% but not more than 39% available chlorine 5.1 CALCIUM HYPOCHLORITE MIXTURE, DRY with more than 39% available chlorine (8.8% available oxygen) 5.1 Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 570 - CALCIUM HYPOCHLORITE MIXTURE, DRY, CORROSIVE with more than 10% but not more than 39% available chlorine 5.1 CALCIUM HYPOCHLORITE MIXTURE, DRY, CORROSIVE with more than 39% available chlorine (8.8% available oxygen) 5.1 CALCIUM MANGANESE SILICON 4.3 CALCIUM NITRATE 5.1 Calcium oxide Not subject to ADR CALCIUM PERCHLORATE 5.1 CALCIUM PERMANGANATE 5.1 CALCIUM PEROXIDE 5.1 CALCIUM PHOSPHIDE 4.3 CALCIUM, PYROPHORIC 4.2 CALCIUM RESINATE 4.1 CALCIUM RESINATE, FUSED 4.1 Calcium selenate, see 6.1 CALCIUM SILICIDE 4.3 Calcium silicon, see 4.3 Calcium superoxide, see 5.1 Camphanone, see 4.1 CAMPHOR OIL CAMPHOR, synthetic 4.1 CAPROIC ACID CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C CARBAMATE PESTICIDE, LIQUID, TOXIC 6.1 CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 6.1 CARBAMATE PESTICIDE, SOLID, TOXIC 6.1 Carbolic acid, see 6.1 6.1 6.1 CARBON, animal or vegetable origin 4.2 CARBON, ACTIVATED 4.2 Carbon bisulphide, see Carbon black (animal or vegetable origin), see 4.2 CARBON DIOXIDE Carbon dioxide and ethylene oxide mixture, see CARBON DIOXIDE, REFRIGERATED LIQUID Carbon dioxide, solid Not subject to ADR CARBON DISULPHIDE Carbonic anhydride, see CARBON MONOXIDE, COMPRESSED Carbon oxysulphide, see 2.3 CARBON TETRABROMIDE 6.1 CARBON TETRACHLORIDE 6.1 Carbonyl chloride, see CARBONYL FLUORIDE CARBONYL SULPHIDE Cartridge cases, empty, primed, see Cartridges, actuating, for fire extinguisher or apparatus valve, see Cartridges, explosive, see CARTRIDGES, FLASH CARTRIDGES FOR WEAPONS with bursting charge CARTRIDGES FOR WEAPONS, BLANK CARTRIDGES FOR WEAPONS, INERT PROJECTILE Cartridges, illuminating, see CARTRIDGES, OIL WELL CARTRIDGES, POWER DEVICE Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 571 - CARTRIDGES, SIGNAL CARTRIDGES, SMALL ARMS CARTRIDGES, SMALL ARMS, BLANK Cartridges, starter, jet engine, see CASES, CARTRIDGE, EMPTY, WITH PRIMER CASES, COMBUSTIBLE, EMPTY, WITHOUT PRIMER Casinghead gasoline, see CASTOR BEANS CASTOR FLAKE CASTOR MEAL CASTOR POMACE CAUSTIC ALKALI LIQUID, N.O.S. Caustic potash, see Caustic soda, see Caustic soda liquor, see CELLS, CONTAINING SODIUM 4.3 CELLULOID in block, rods, rolls, sheets, tubes, etc., except scrap 4.1 CELLULOID, SCRAP 4.2 Cement, see CERIUM, slabs, ingots or rods 4.1 CERIUM, turnings or gritty powder 4.3 Cer mishmetall, see 4.1 Charcoal, activated, see 4.1 Charcoal, non-activated, see 4.2 CHARGES, BURSTING, PLASTICS BONDED CHARGES, DEMOLITION CHARGES, DEPTH Charges, expelling, explosive, for fire extinguishers, see CHARGES, EXPLOSIVE, COMMERCIAL without detonator CHARGES, PROPELLING CHARGES, PROPELLING, FOR CANNON CHARGES, SHAPED, FLEXIBLE, LINEAR CHARGES, SHAPED, without detonator CHARGES, SUPPLEMENTARY, EXPLOSIVE CHEMICAL KIT CHEMICAL SAMPLE, TOXIC 6.1 Chile saltpetre, see 5.1 CHLORAL, ANHYDROUS, STABILIZED 6.1 CHLORATE AND BORATE MIXTURE 5.1 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE, SOLID 5.1 CHLORATE AND MAGNESIUM CHLORIDE MIXTURE, SOLUTION 5.1 CHLORATES, INORGANIC, N.O.S. 5.1 CHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 CHLORIC ACID, AQUEOUS SOLUTION with not more than 10% chloric acid 5.1 CHLORINE CHLORINE PENTAFLUORIDE CHLORINE TRIFLUORIDE CHLORITES, INORGANIC, N.O.S. 5.1 CHLORITE SOLUTION Chloroacetaldehyde, see 6.1 CHLOROACETIC ACID, MOLTEN 3250 6.1 CHLOROACETIC ACID, SOLID 6.1 CHLOROACETIC ACID SOLUTION 6.1 CHLOROACETONE, STABILIZED 1695 6.1 CHLOROACETONITRILE 6.1 CHLOROACETOPHENONE, LIQUID 6.1 CHLOROACETOPHENONE, SOLID 6.1 CHLOROACETYL CHLORIDE 6.1 Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 572 - CHLOROANILINES, LIQUID 6.1 CHLOROANILINES, SOLID 6.1 CHLOROANISIDINES 6.1 CHLOROBENZENE CHLOROBENZO-TRIFLUORIDES CHLOROBENZYL CHLORIDES, LIQUID 6.1 CHLOROBENZYL CHLORIDES, SOLID 6.1 1-Chloro-3-bromopropane, see 6.1 1-Chlorobutane, see 2-Chlorobutane, see CHLOROBUTANES CHLOROCRESOLS, SOLUTION 6.1 CHLOROCRESOLS, SOLID 6.1 CHLORODIFLUORO- BROMOMETHANE 1-CHLORO-1,1-DIFLUORO- ETHANE CHLORODIFLUOROMETHANE CHLORODIFLUOROMETHANE AND CHLORO- PENTAFLUOROETHANE MIXTURE with fixed boiling point, with approximately 49% chlorodifluoromethane 3-Chloro-1,2-dihydroxypropane, see 6.1 Chlorodimethyl ether, see 6.1 CHLORODINITROBENZENES, LIQUID 6.1 CHLORODINITROBENZENES, SOLID 6.1 2-CHLOROETHANAL 6.1 Chloroethane, see Chloroethane nitrile, see 6.1 2-Chloroethanol, see 6.1 CHLOROFORM 6.1 CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S. 6.1 CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. 6.1 Chloromethane, see 1-Chloro-3-methylbutane, see 2-Chloro-2-methylbutane, see CHLOROMETHYL CHLOROFORMATE 6.1 Chloromethyl cyanide, see 6.1 CHLOROMETHYL ETHYL ETHER Chloromethyl methyl ether, see 6.1 3-CHLORO-4-METHYLPHENYL ISOCYANATE, LIQUID 6.1 3-CHLORO-4-METHYLPHENYL ISOCYANATE, SOLID 6.1 3-Chloro-2-methylprop-1-ene, see CHLORONITROANILINES 6.1 CHLORONITROBENZENES LIQUID 6.1 CHLORONITROBENZENES SOLID 6.1 CHLORONITROTOLUENES, LIQUID 6.1 CHLORONITROTOLUENES, SOLID 6.1 CHLOROPENTAFLUORO- ETHANE CHLOROPHENOLATES, LIQUID CHLOROPHENOLATES, SOLID CHLOROPHENOLS, LIQUID 6.1 CHLOROPHENOLS, SOLID 6.1 CHLOROPHENYL- TRICHLOROSILANE CHLOROPICRIN 6.1 CHLOROPICRIN AND METHYL BROMIDE MIXTURE, with more than 2% chloropicrin CHLOROPICRIN AND METHYL CHLORIDE MIXTURE CHLOROPICRIN MIXTURE, N.O.S. 6.1 CHLOROPLATINIC ACID, SOLID CHLOROPRENE, STABILIZED 1-CHLOROPROPANE 2-CHLOROPROPANE 3-Chloro-propanediol-1,2, see 6.1 3-CHLOROPROPANOL-1 6.1 2-CHLOROPROPENE 3-Chloropropene, see 3-Chloroprop-1-ene, see 2-CHLOROPROPIONIC ACID 2-CHLOROPYRIDINE 6.1 CHLOROSILANES, CORROSIVE, N.O.S. Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 573 - CHLOROSILANES, CORROSIVE, FLAMMABLE, N.O.S. CHLOROSILANES, FLAMMABLE, CORROSIVE, N.O.S. CHLOROSILANES, TOXIC, CORROSIVE, N.O.S. 6.1 CHLOROSILANES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. 6.1 CHLOROSILANES, WATER- REACTIVE, FLAMMABLE, CORROSIVE, N.O.S. 4.3 CHLOROSULPHONIC ACID (with or without sulphur trioxide) 1-CHLORO-1,2,2,2-TETRA- FLUOROETHANE CHLOROTOLUENES 4-CHLORO-o-TOLUIDINE HYDROCHLORIDE, SOLID 6.1 4-CHLORO-o-TOLUIDINE HYDROCHLORIDE, SOLUTION 6.1 CHLOROTOLUIDINES LIQUID 6.1 CHLOROTOLUIDINES SOLID 6.1 1-CHLORO-2,2,2-TRIFLUORO- ETHANE Chlorotrifluoroethylene, see CHLOROTRIFLUOROMETHANE CHLOROTRIFLUOROMETHANE AND TRIFLUOROMETHANE AZEOTROPIC MIXTURE with approximately 60% chlorotrifluoromethane Chromic acid, solid, see 5.1 CHROMIC ACID SOLUTION Chromic anhydride, solid, see 5.1 CHROMIC FLUORIDE, SOLID CHROMIC FLUORIDE SOLUTION 1757 Chromic nitrate, see 5.1 Chromium (VI) dichloride dioxide, see Chromium (III) fluoride, solid, see CHROMIUM NITRATE 5.1 Chromium (III) nitrate, see 5.1 CHROMIUM OXYCHLORIDE CHROMIUM TRIOXIDE, ANHYDROUS 5.1 CHROMOSULPHURIC ACID Chryosotile, see Cinene, see Cinnamene, see Cinnamol, see CLINICAL WASTE, UNSPECIFIED, N.O.S. 6.2 COAL GAS, COMPRESSED COAL TAR DISTILLATES, FLAMMABLE Coal tar naphtha, see Coal tar oil, see COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) COBALT NAPHTHENATES, POWDER 4.1 COBALT RESINATE, PRECIPITATED 4.1 Cocculus, see 6.1 6.1 Collodion cottons, see 4.1 4.1 4.1 COMPONENTS, EXPLOSIVE TRAIN, N.O.S. Composition B, see COMPRESSED GAS, N.O.S. COMPRESSED GAS, FLAMMABLE, N.O.S. COMPRESSED GAS, OXIDIZING, N.O.S. COMPRESSED GAS, TOXIC, N.O.S. COMPRESSED GAS, TOXIC, CORROSIVE, N.O.S. COMPRESSED GAS, TOXIC, FLAMMABLE, N.O.S. COMPRESSED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. COMPRESSED GAS, TOXIC, OXIDIZING, N.O.S. COMPRESSED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 574 - CONTRIVANCES, WATER- ACTIVATED with burster, expelling charge or propelling charge COPPER ACETOARSENITE 6.1 COPPER ARSENITE 6.1 Copper (II) arsenite, see 6.1 COPPER BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C COPPER BASED PESTICIDE, LIQUID, TOXIC 6.1 COPPER BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 6.1 COPPER BASED PESTICIDE, SOLID, TOXIC 6.1 COPPER CHLORATE 5.1 Copper (II) chlorate, see 5.1 COPPER CHLORIDE COPPER CYANIDE 6.1 Copper selenate, see 6.1 Copper selenite, see 6.1 COPRA 4.2 CORD, DETONATING, flexible CORD, DETONATING, metal clad CORD, DETONATING, MILD EFFECT, metal clad CORD, IGNITER Cordite, see CORROSIVE LIQUID, N.O.S. CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. CORROSIVE LIQUID, FLAMMABLE, N.O.S. CORROSIVE LIQUID, OXIDIZING, N.O.S. CORROSIVE LIQUID, SELF- HEATING, N.O.S. CORROSIVE LIQUID, TOXIC, N.O.S. CORROSIVE LIQUID, WATER- REACTIVE, N.O.S. CORROSIVE SOLID, N.O.S. CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. CORROSIVE SOLID, FLAMMABLE, N.O.S. CORROSIVE SOLID, OXIDIZING, N.O.S. CORROSIVE SOLID, SELF- HEATING, N.O.S. CORROSIVE SOLID, TOXIC, N.O.S. CORROSIVE SOLID, WATER- REACTIVE, N.O.S. COTTON WASTE, OILY 4.2 COTTON, WET 4.2 COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 °C COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC 6.1 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 6.1 COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC 6.1 Creosote, see 6.1 Creosote salts, see 4.1 CRESOLS, LIQUID 6.1 CRESOLS, SOLID 6.1 CRESYLIC ACID 6.1 Crocidolite, see CROTONALDEHYDE or CROTONALDEHYDE, STABILIZED 6.1 CROTONIC ACID, LIQUID CROTONIC ACID, SOLID Crotonic aldehyde / Crotonic aldehyde, stabilized, see 6.1 CROTONYLENE Crude naphtha, see Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 575 - Cumene, see Cupric chlorate, see 5.1 CUPRIETHYLENEDIAMINE SOLUTION Cutback bitumen, with a flash-point not greater than 60 °C, see Cutback bitumen, with a flash-point above 60 °C, at or above its flashpoint, see Cutback bitumen, at or above 100 °C and below its flash-point, see CUTTERS, CABLE, EXPLOSIVE CYANIDE SOLUTION, N.O.S. 6.1 CYANIDES, INORGANIC, SOLID, N.O.S. 6.1 Cyanides, organic, flammable, toxic, n.o.s., see Cyanides, organic, toxic, n.o.s., see 6.1 Cyanides, organic, toxic, flammable, n.o.s., see 6.1 Cyanoacetonitrile, see 6.1 CYANOGEN CYANOGEN BROMIDE 6.1 CYANOGEN CHLORIDE, STABILIZED CYANURIC CHLORIDE CYCLOBUTANE CYCLOBUTYL CHLOROFORMATE 6.1 1,5,9-CYCLODODECATRIENE 6.1 CYCLOHEPTANE CYCLOHEPTATRIENE 1,3,5-Cycloheptatriene, see CYCLOHEPTENE 1,4-Cyclohexadienedione, see 6.1 CYCLOHEXANE Cyclehexanethiol, see CYCLOHEXANONE CYCLOHEXENE CYCLOHEXENYLTRI- CHLOROSILANE CYCLOHEXYL ACETATE CYCLOHEXYLAMINE CYCLOHEXYL ISOCYANATE 6.1 CYCLOHEXYL MERCAPTAN CYCLOHEXYLTRICHLORO- SILANE CYCLONITE AND CYCLOTETRAMETHYLENE- TETRANITRAMINE MIXTURE, WETTED with not less than 15% water, by mass or DESENSITIZED with not less than 10% phlegmatiser by mass, see CYCLONITE, DESENSITIZED, see CYCLONITE, WETTED with not less than 15% water, by mass, see CYCLOOCTADIENES CYCLOOCTADIENE PHOSPHINES, see 4.2 CYCLOOCTATETRAENE CYCLOPENTANE CYCLOPENTANOL CYCLOPENTANONE CYCLOPENTENE CYCLOPROPANE CYCLOTETRAMETHYLENE- TETRANITRAMINE, DESENSITIZED CYCLOTETRAMETHYLENE- TETRANITRAMINE, WETTED with not less than 15% water, by mass CYCLOTRIMETHYLENE- TRINITRAMINE AND CYCLOTETRAMETHYLENE- TETRANITRAMINE MIXTURE, DESENSITIZED with not less than 10% phlegmatiser by mass CYCLOTRIMETHYLENE- TRINITRAMINE AND CYCLOTETRAMETHYLENE- TETRANITRAMINE MIXTURE, WETTED with not less than 15% water, by mass CYCLOTRIMETHYLENE- TRINITRAMINE, DESENSITIZED CYCLOTRIMETHYLENE- TRINITRAMINE, WETTED with not less than 15% water, by mass CYMENES Cymol, see Deanol, see Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 576 - Dangerous goods in machinery or dangerous goods in apparatus Not subject to ADR [see also 1.1.3.1 (b)] DECABORANE 4.1 DECAHYDRONAPHTHALENE Decalin, see n-DECANE DEFLAGRATING METAL SALTS OF AROMATIC NITRODERIVATIVES, N.O.S. Depth charge, see DESENSITIZED EXPLOSIVE, LIQUID, N.O.S. DESENSITIZED EXPLOSIVE, SOLID, N.O.S. 4.1 Detonating relays, see DETONATOR ASSEMBLIES, NON-ELECTRIC for blasting DETONATORS FOR AMMUNITION DETONATORS, ELECTRIC for blasting DETONATORS, NON-ELECTRIC for blasting DEUTERIUM, COMPRESSED DEVICES, SMALL, HYDROCARBON GAS POWERED with release device DIACETONE ALCOHOL DIALLYLAMINE DIALLYL ETHER 4,4'-DIAMINODIPHENYL- METHANE 6.1 1,2-Diaminoethane, see Diaminopropylamine, see DI-n-AMYLAMINE DIAZODINITROPHENOL, WETTED with not less than 40% water, or mixture of alcohol and water, by mass Dibenzopyridine, see 6.1 DIBENZYLDICHLORO-SILANE DIBORANE 1,2-DIBROMOBUTAN-3-ONE 6.1 DIBROMOCHLOROPROPANES 6.1 1,2-Dibromo-3-chloropropane, see 6.1 DIBROMODIFLUOROMETHANE DIBROMOMETHANE 6.1 DI-n-BUTYLAMINE DIBUTYLAMINOETHANOL 6.1 2-Dibutylaminoethanol, see 6.1 N,N-Di-n-butylaminoethanol, see 6.1 DIBUTYL ETHERS DICHLOROACETIC ACID 1,3-DICHLOROACETONE 6.1 DICHLOROACETYL CHLORIDE DICHLOROANILINES, LIQUID 6.1 DICHLOROANILINES, SOLID 6.1 o-DICHLOROBENZENE 6.1 2,2'-DICHLORODIETHYL ETHER 6.1 DICHLORODIFLUORO- METHANE DICHLORODIFLUORO- METHANE AND DIFLUOROETHANE AZEOTROPIC MIXTURE with approximately 74% dichlorodifluoromethane Dichlorodifluoromethane and ethylene oxide mixture, see DICHLORODIMETHYL ETHER, SYMMETRICAL 6.1 Carriage prohibited 1,1-DICHLOROETHANE 1,2-Dichloroethane, see 1,2-DICHLOROETHYLENE Di(2-chloroethyl) ether, see 6.1 DICHLOROFLUOROMETHANE alpha-Dichlorohydrin, see 6.1 DICHLOROISOCYANURIC ACID, DRY 5.1 DICHLOROISOCYANURIC ACID SALTS 5.1 DICHLOROISOPROPYL ETHER 6.1 DICHLOROMETHANE 6.1 1,1-DICHLORO-1-NITROETHANE 6.1 DICHLOROPENTANES Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 577 - Dichlorophenol, see 6.1 6.1 DICHLOROPHENYL ISOCYANATES 6.1 DICHLOROPHENYLTRI- CHLOROSILANE 1,2-DICHLOROPROPANE 1,3-DICHLOROPROPANOL-2 6.1 1,3-Dichloro-2-propanone, see 6.1 DICHLOROPROPENES DICHLOROSILANE 1,2-DICHLORO-1,1,2,2- TETRAFLUOROETHANE Dichloro-s-triazine-2,4,6-trione, see 5.1 1,4-Dicyanobutane, see 6.1 Dicycloheptadiene, see DICYCLOHEXYLAMINE Dicyclohexylamine nitrite, see 4.1 DICYCLOHEXYL-AMMONIUM NITRITE 4.1 DICYCLOPENTADIENE 1,2-DI-(DIMETHYLAMINO) ETHANE DIDYMIUM NITRATE 5.1 DIESEL FUEL 1,1-Diethoxyethane, see 1,2-Diethoxyethane, see DIETHOXYMETHANE 3,3-DIETHOXYPROPENE DIETHYLAMINE 2-DIETHYLAMINOETHANOL 3-DIETHYLAMINO- PROPYLAMINE N,N-DIETHYLANILINE 6.1 DIETHYLBENZENE Diethylcarbinol, see DIETHYL CARBONATE DIETHYLDICHLOROSILANE Diethylenediamine, see DIETHYLENEGLYCOL DINITRATE, DESENSITIZED with not less than 25% non-volatile, water-insoluble phlegmatizer, by mass DIETHYLENETRIAMINE N,N-Diethylethanolamine, see DIETHYL ETHER N,N-DIETHYLETHYLENE- DIAMINE Di-(2-ethylhexyl) phosphoric acid, see DIETHYL KETONE DIETHYL SULPHATE 6.1 DIETHYL SULPHIDE DIETHYLTHIOPHOSPHORYL CHLORIDE Diethylzinc, see 4.2 2,4-Difluoroaniline, see 6.1 Difluorochloroethane, see 1,1-DIFLUOROETHANE 1,1-DIFLUOROETHYLENE DIFLUOROMETHANE Difluoromethane, pentafluoroethane, and 1,1,1,2-tetrafluoroethane zeotropic mixture with approximately 10% difluoromethane and 70% pentafluoroethane, see Difluoromethane, pentafluoroethane, and 1,1,1,2-tetrafluoroethane zeotropic mixture with approximately 20% difluoromethane and 40% pentafluoroethane, see Difluoromethane, pentafluoroethane, and 1,1,1,2-tetrafluoroethane zeotropic mixture with approximately 23%difluoromethane and 25% pentafluoroethane, see DIFLUOROPHOSPHORIC ACID, ANHYDROUS 2,3-DIHYDROPYRAN DIISOBUTYLAMINE DIISOBUTYLENE, ISOMERIC COMPOUNDS alpha-Diisobutylene, see beta-Diisobutylene, see DIISOBUTYL KETONE DIISOOCTYL ACID PHOSPHATE DIISOPROPYLAMINE DIISOPROPYL ETHER DIKETENE, STABILIZED 6.1 1,1-DIMETHOXYETHANE 1,2-DIMETHOXYETHANE Dimethoxystrychnine, see 6.1 Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 578 - DIMETHYLAMINE, ANHYDROUS DIMETHYLAMINE AQUEOUS SOLUTION 2-DIMETHYLAMINO- ACETONITRILE 2-DIMETHYLAMINOETHANOL 2-DIMETHYLAMINOETHYL ACRYLATE 6.1 2-DIMETHYLAMINOETHYL METHACRYLATE 6.1 N,N-DIMETHYLANILINE 6.1 Dimethylarsenic acid, see 6.1 N,N-Dimethylbenzylamine, see 2,3-DIMETHYLBUTANE 1,3-DIMETHYLBUTYLAMINE DIMETHYLCARBAMOYL CHLORIDE DIMETHYL CARBONATE DIMETHYLCYCLOHEXANES N,N-DIMETHYLCYCLO- HEXYLAMINE DIMETHYLDICHLOROSILANE DIMETHYLDIETHOXYSILANE DIMETHYLDIOXANES DIMETHYL DISULPHIDE Dimethylethanolamine, see DIMETHYL ETHER N,N-DIMETHYLFORMAMIDE DIMETHYLHYDRAZINE, SYMMETRICAL 6.1 DIMETHYLHYDRAZINE, UNSYMMETRICAL 6.1 1,1-Dimethylhydrazine, see 6.1 N,N-Dimethyl-4-nitrosoaniline, see 4.2 2,2-DIMETHYLPROPANE DIMETHYL-N-PROPYLAMINE DIMETHYL SULPHATE 6.1 DIMETHYL SULPHIDE DIMETHYL THIOPHOSPHORYL CHLORIDE 6.1 Dimethylzinc, see 4.2 DINGU, see DINITROANILINES 6.1 DINITROBENZENES, LIQUID 6.1 DINITROBENZENES, SOLID 6.1 Dinitrochlorobenzene, see 6.1 6.1 DINITRO-o-CRESOL 6.1 DINITROGEN TETROXIDE DINITROGLYCOLURIL DINITROPHENOL, dry or wetted with less than 15% water, by mass DINITROPHENOL SOLUTION 6.1 DINITROPHENOL, WETTED with not less than 15% water, by mass 4.1 DINITROPHENOLATES, alkali metals, dry or wetted with less than 15% water, by mass DINITROPHENOLATES, WETTED with not less than 15% water, by mass 4.1 DINITRORESORCINOL, dry or wetted with less than 15% water, by mass DINITRORESORCINOL, WETTED with not less than 15% water, by mass 4.1 DINITROSOBENZENE Dinitrotoluene mixed with sodium chlorate, see DINITROTOLUENES, LIQUID 6.1 DINITROTOLUENES, MOLTEN 6.1 DINITROTOLUENES, SOLID 6.1 DIOXANE DIOXOLANE DIPENTENE DIPHENYLAMINE CHLOROARSINE 6.1 DIPHENYLCHLOROARSINE, LIQUID 6.1 DIPHENYLCHLOROARSINE, SOLID 6.1 DIPHENYLDICHLOROSILANE DIPHENYLMETHYL BROMIDE DIPICRYLAMINE, see DIPICRYL SULPHIDE, dry or wetted with less than 10% water, by mass DIPICRYL SULPHIDE, WETTED with not less than 10% water, by mass 4.1 DIPROPYLAMINE Dipropylene triamine, see DI-n-PROPYL ETHER DIPROPYL KETONE Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 579 - DISINFECTANT, LIQUID, CORROSIVE, N.O.S. DISINFECTANT, LIQUID, TOXIC, N.O.S. 6.1 DISINFECTANT, SOLID, TOXIC, N.O.S. 6.1 DISODIUM TRIOXOSILICATE DIVINYL ETHER, STABILIZED DODECYLTRICHLOROSILANE Dry ice, see Not subject to ADR DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. 6.1 DYE INTERMEDIATE, SOLID, CORROSIVE, N.O.S. DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. 6.1 DYE, LIQUID, CORROSIVE, N.O.S. DYE, LIQUID, TOXIC, N.O.S. 6.1 DYE, SOLID, CORROSIVE, N.O.S. 3147 DYE, SOLID, TOXIC, N.O.S. 6.1 Dynamite, see Electric storage batteries, see Electrolyte (acid or alkaline) for batteries, see ELEVATED TEMPERATURE LIQUID, N.O.S., at or above 100 °C and below its flash-point (including molten metals, molten salts, etc.) ELEVATED TEMPERATURE LIQUID, FLAMMABLE, N.O.S. with flash-point above 60 °C, at or above its flash-point ELEVATED TEMPERATURE SOLID, N.O.S., at or above 240 °C Empty battery-vehicle, uncleaned See 4.3.2.4, 5.1.3 and 5.4.1.1.6 Empty IBC, uncleaned See 4.1.1.11, 5.1.3 and 5.4.1.1.6 Empty large packaging, uncleaned See 4.1.1.11, 5.1.3 and 5.4.1.1.6 Empty MEGC, uncleaned See 4.3.2.4, 5.1.3 and 5.4.1.1.6 Empty packaging, uncleaned See 4.1.1.11, 5.1.3 and 5.4.1.1.6 Empty receptacle, uncleaned See 5.1.3 and 5.4.1.1.6 Empty tank, uncleaned See 4.3.2.4, 5.1.3 and 5.4.1.1.6 Empty vehicle, uncleaned See 5.1.3 and 5.4.1.1.6 Enamel, see Engine, fuel cell, flammable gas powered Not subject to ADR Engine, fuel cell, flammable liquid powered Not subject to ADR Engine, internal combustion Not subject to ADR Engines, rocket, see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. EPIBROMOHYDRIN 6.1 EPICHLOROHYDRIN 6.1 1,2-Epoxybutane, stabilized, see Epoxyethane, see 1,2-EPOXY-3-ETHOXYPROPANE 2,3-Epoxy-1-propanal, see 2,3-Epoxypropyl ethyl ether, see ESTERS, N.O.S. ETHANE ETHANE, REFRIGERATED LIQUID Ethanethiol, see ETHANOL ETHANOL AND GASOLINE MIXTURE or ETHANOL AND MOTOR SPIRIT MIXTURE or ETHANOL AND PETROL MIXTURE, with more than 10% ethanol ETHANOL SOLUTION Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 580 - ETHANOLAMINE ETHANOLAMINE SOLUTION Ether, see ETHERS, N.O.S. 2-Ethoxyethanol, see 2-Ethoxyethyl acetate, see Ethoxy propane-1, see ETHYL ACETATE ETHYLACETYLENE, STABILIZED ETHYL ACRYLATE, STABILIZED 1917 ETHYL ALCOHOL, see ETHYL ALCOHOL SOLUTION, see ETHYLAMINE ETHYLAMINE, AQUEOUS SOLUTION with not less than 50% but not more than 70% ethylamine ETHYL AMYL KETONE N-ETHYLANILINE 6.1 2-ETHYLANILINE 6.1 ETHYLBENZENE N-ETHYL-N-BENZYLANILINE 6.1 N-ETHYLBENZYLTOLUIDINES, LIQUID 6.1 N-ETHYLBENZYLTOLUIDINES, SOLID 6.1 ETHYL BORATE ETHYL BROMIDE 6.1 ETHYL BROMOACETATE 6.1 2-ETHYLBUTANOL 2-ETHYLBUTYL ACETATE ETHYL BUTYL ETHER 2-ETHYLBUTYRALDEHYDE ETHYL BUTYRATE ETHYL CHLORIDE ETHYL CHLOROACETATE 6.1 Ethyl chlorocarbonate, see 6.1 ETHYL CHLOROFORMATE 6.1 ETHYL 2-CHLOROPROPIONATE Ethyl-alpha-chloropropionate, see ETHYL CHLOROTHIOFORMATE ETHYL CROTONATE ETHYLDICHLOROARSINE 6.1 ETHYLDICHLOROSILANE 4.3 ETHYLENE, ACETYLENE AND PROPYLENE MIXTURE, REFRIGERATED LIQUID containing at least 71.5% ethylene with not more than 22.5% acetylene and not more than 6% propylene ETHYLENE CHLOROHYDRIN 6.1 ETHYLENE ETHYLENEDIAMINE ETHYLENE DIBROMIDE 6.1 Ethylene dibromide and methyl bromide, liquid mixture, see 6.1 ETHYLENE DICHLORIDE ETHYLENE GLYCOL DIETHYL ETHER ETHYLENE GLYCOL MONOETHYL ETHER ETHYLENE GLYCOL MONOETHYL ETHER ACETATE ETHYLENE GLYCOL MONOMETHYL ETHER ETHYLENE GLYCOL MONOMETHYL ETHER ACETATE ETHYLENEIMINE, STABILIZED 6.1 ETHYLENE OXIDE ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 87% ethylene oxide ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 9% but not more than 87% ethylene oxide ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with not more than 9% ethylene oxide ETHYLENE OXIDE AND CHLOROTETRAFLUORO- ETHANE MIXTURE with not more than 8.8% ethylene oxide ETHYLENE OXIDE AND DICHLORODIFLUORO- METHANE MIXTURE with not more than 12.5% ethylene oxide ETHYLENE OXIDE AND PENTAFLUOROETHANE MIXTURE with not more than 7.9% ethylene oxide ETHYLENE OXIDE AND PROPYLENE OXIDE MIXTURE, not more than 30% ethylene oxide Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 581 - ETHYLENE OXIDE AND TETRAFLUOROETHANE MIXTURE with not more than 5.6% ethylene oxide ETHYLENE OXIDE WITH NITROGEN up to a total pressure of 1 MPa (10 bar) at 50 °C ETHYLENE, REFRIGERATED LIQUID ETHYL ETHER, see ETHYL FLUORIDE ETHYL FORMATE 2-ETHYLHEXYLAMINE 2-ETHYLHEXYL CHLOROFORMATE 6.1 Ethylidene chloride, see ETHYL ISOBUTYRATE ETHYL ISOCYANATE 6.1 ETHYL LACTATE ETHYL MERCAPTAN ETHYL METHACRYLATE, STABILIZED ETHYL METHYL ETHER ETHYL METHYL KETONE ETHYL NITRITE SOLUTION ETHYL ORTHOFORMATE ETHYL OXALATE 6.1 ETHYLPHENYL- DICHLOROSILANE 1-ETHYLPIPERIDINE ETHYL PROPIONATE ETHYL PROPYL ETHER Ethyl silicate, see Ethyl sulphate, see 6.1 N-ETHYLTOLUIDINES 6.1 ETHYLTRICHLOROSILANE EXPLOSIVE, BLASTING, TYPE A EXPLOSIVE, BLASTING, TYPE B EXPLOSIVE, BLASTING, TYPE C EXPLOSIVE, BLASTING, TYPE D EXPLOSIVE, BLASTING, TYPE E Explosives, emulsion, see Explosive, seismic, see Explosive, slurry, see Explosive, water gel, see EXTRACTS, AROMATIC, LIQUID 1169 EXTRACTS, FLAVOURING, LIQUID FABRICS, ANIMAL, N.O.S. with oil 4.2 FABRICS IMPREGNATED WITH WEAKLY NITRATED NITROCELLULOSE, N.O.S. 4.1 FABRICS, SYNTHETIC, N.O.S. with oil 4.2 FABRICS, VEGETABLE, N.O.S. with oil 4.2 FERRIC ARSENATE 6.1 FERRIC ARSENITE 6.1 FERRIC CHLORIDE, ANHYDROUS FERRIC CHLORIDE SOLUTION FERRIC NITRATE 5.1 FERROCERIUM 4.1 FERROSILICON with 30% or more but less than 90% silicon 4.3 FERROUS ARSENATE 6.1 FERROUS METAL BORINGS in a form liable to self-heating 4.2 FERROUS METAL CUTTINGS in a form liable to self-heating 4.2 FERROUS METAL SHAVINGS in a form liable to self-heating 4.2 FERROUS METAL TURNINGS in a form liable to self-heating 4.2 FERTILIZER AMMONIATING SOLUTION with free ammonia Fertilizer with ammonium nitrate, n.o.s., see 5.1 Fibres, animal, burnt wet or damp 4.2 Not subject to ADR FIBRES, ANIMAL, N.O.S. with oil 4.2 FIBRES IMPREGNATED WITH WEAKLY NITRATED NITROCELLULOSE, N.O.S. 4.1 FIBRES, SYNTHETIC, N.O.S. with oil 4.2 Fibres, vegetable, burnt wet or damp 4.2 Not subject to ADR Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 582 - Fibres, vegetable, dry 4.1 Not subject to ADR FIBRES, VEGETABLE, N.O.S. with oil 4.2 Films, nitrocellulose base, from which gelatine has been removed; film scrap, see 4.2 FILMS, NITROCELLULOSE BASE, gelatin coated, except scrap 4.1 Filler, liquid, see FIRE EXTINGUISHER CHARGES, corrosive liquid Fire extinguisher charges, expelling, explosive, see FIRE EXTINGUISHERS with compressed or liquefied gas FIRELIGHTERS, SOLID with flammable liquid 4.1 FIREWORKS See 2.2.1.1.7 FIRST AID KIT Fish meal, stabilized Not subject to ADR FISH MEAL, UNSTABILIZED 4.2 Fish scrap, stabilized, see Not subject to ADR FISH SCRAP, UNSTABILIZED, see 1374 4.2 Flammable gas in lighters, see FLAMMABLE LIQUID, N.O.S. FLAMMABLE LIQUID, CORROSIVE, N.O.S. FLAMMABLE LIQUID, TOXIC, N.O.S. FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S. FLAMMABLE SOLID, CORROSIVE, INORGANIC, N.O.S. 4.1 FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S. 4.1 FLAMMABLE SOLID, INORGANIC, N.O.S. 4.1 FLAMMABLE SOLID, ORGANIC, N.O.S. 4.1 FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. 4.1 FLAMMABLE SOLID, OXIDIZING, N.O.S. 4.1 Carriage prohibited FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S. 4.1 FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. 4.1 FLARES, AERIAL Flares, aeroplane, see Flares, highway, Flares, distress, small, Flares, railway or highway, see FLARES, SURFACE Flares, water-activated, see FLASH POWDER Flue dusts, toxic, see 6.1 Fluoric acid, see FLUORINE, COMPRESSED FLUOROACETIC ACID 6.1 FLUOROANILINES 6.1 2-Fluoroaniline, see 6.1 4-Fluoroaniline, see 6.1 o-Fluoroaniline, see 6.1 p-Fluoroaniline, see 6.1 FLUOROBENZENE FLUOROBORIC ACID Fluoroethane, see Fluoroform, see Fluoromethane, see FLUOROPHOSPHORIC ACID, ANHYDROUS FLUOROSILICATES, N.O.S. 6.1 FLUOROSILICIC ACID FLUOROSULPHONIC ACID FLUOROTOLUENES Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 583 - FORMALDEHYDE SOLUTION with not less than 25% formaldehyde FORMALDEHYDE SOLUTION, FLAMMABLE Formalin, see Formamidine sulphinic acid, see 4.2 FORMIC ACID with more than 85% acid by mass FORMIC ACID with not more than 85% acid by mass Formic aldehyde, see 2-Formyl-3,4-dihydro-2H-pyran, see FRACTURING DEVICES, EXPLOSIVE without detonator, for oil wells FUEL, AVIATION, TURBINE ENGINE FUEL CELL CARTRIDGES 4.3 FUEL CELL CARTRIDGES CONTAINED IN EQUIPMENT 4.3 FUEL CELL CARTRIDGES PACKED WITH EQUIPMENT 4.3 Fumaroyl dichloride, see FUMARYL CHLORIDE FUMIGATED CARGO TRANSPORT UNIT FURALDEHYDES 6.1 FURAN FURFURYL ALCOHOL 6.1 FURFURYLAMINE Furyl carbinol, see 6.1 FUSE, DETONATING, metal clad FUSE, DETONATING, MILD EFFECT, metal clad FUSE, IGNITER, tubular, metal clad FUSE, NON-DETONATING FUSEL OIL FUSE, SAFETY Fuze, combination, percussion or time, see FUZES, DETONATING FUZES, DETONATING with protective features FUZES, IGNITING GALLIUM GAS CARTRIDGES without a release device, non-refillable, see Gas drips, hydrocarbon, see GAS OIL GASOLINE Gasoline and ethanol mixture, with more than 10% ethanol, see Gasoline, casinghead, see GAS, REFRIGERATED LIQUID, N.O.S. GAS, REFRIGERATED LIQUID, FLAMMABLE, N.O.S. GAS, REFRIGERATED LIQUID, OXIDIZING, N.O.S. GAS SAMPLE, NON- PRESSURIZED, FLAMMABLE, N.O.S., not refrigerated liquid GAS SAMPLE, NON- PRESSURIZED, TOXIC, N.O.S., not refrigerated liquid GAS SAMPLE, NON- PRESSURIZED, TOXIC, FLAMMABLE, N.O.S., not refrigerated liquid Gelatin, blasting, see Gelatin, dynamites, see GENETICALLY MODIFIED MICROORGANISMS GENETICALLY MODIFIED ORGANISMS GERMANE Germanium hydride, see Glycer-1,3-dichlorohydrin, see 6.1 GLYCEROL alpha- MONOCHLOROHYDRIN 6.1 Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 584 - Glyceryl trinitrate, see GLYCIDALDEHYDE GRENADES, hand or rifle, with bursting charge Grenades, illuminating, see GRENADES, PRACTICE, hand or rifle Grenades, smoke, see GUANIDINE NITRATE 5.1 GUANYLNITROSAMINO- GUANYLIDENE HYDRAZINE, WETTED with not less than 30% water, by mass GUANYLNITROSAMINO- GUANYLTETRAZENE, WETTED with not less than 30% water, or mixture of alcohol and water, by mass GUNPOWDER, COMPRESSED, see GUNPOWDER, granular or as a meal, see GUNPOWDER, IN PELLETS, see Gutta percha solution, see HAFNIUM POWDER, DRY 4.2 HAFNIUM POWDER, WETTED with not less than 25% water 4.1 Hay 4.1 Not subject to ADR HEATING OIL, LIGHT Heavy hydrogen, see HELIUM, COMPRESSED HELIUM, REFRIGERATED LIQUID HEPTAFLUOROPROPANE n-HEPTALDEHYDE n-Heptanal, see HEPTANES 4-Heptanone, see n-HEPTENE HEXACHLOROACETONE 6.1 HEXACHLOROBENZENE 6.1 HEXACHLOROBUTADIENE 6.1 Hexachloro-1,3-butadiene, see 6.1 HEXACHLOROCYCLO- PENTADIENE 6.1 HEXACHLOROPHENE 6.1 Hexachloro-2-propanone, see 6.1 HEXADECYLTRICHLORO- SILANE HEXADIENES HEXAETHYL TETRAPHOSPHATE 6.1 HEXAETHYL TETRAPHOSPHATE AND COMPRESSED GAS MIXTURE HEXAFLUOROACETONE HEXAFLUOROACETONE HYDRATE, LIQUID 6.1 HEXAFLUOROACETONE HYDRATE, SOLID 6.1 HEXAFLUOROETHANE HEXAFLUOROPHOSPHORIC ACID HEXAFLUOROPROPYLENE Hexahydrocresol, see Hexahydromethyl phenol, see HEXALDEHYDE HEXAMETHYLENEDIAMINE, SOLID HEXAMETHYLENEDIAMINE SOLUTION HEXAMETHYLENE DIISOCYANATE 6.1 HEXAMETHYLENEIMINE HEXAMETHYLENETETRAMINE 4.1 Hexamine, see 4.1 HEXANES HEXANITRODIPHENYLAMINE HEXANITROSTILBENE Hexanoic acid, see HEXANOLS 1-HEXENE Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 585 - HEXOGEN AND CYCLOTETRAMETHYLENE- TETRANITRAMINE MIXTURE, WETTED with not less than 15% water, by mass or DESENSITIZED with not less than 10% phlegmatiser by mass, see HEXOGEN, DESENSITIZED, see HEXOGEN, WETTED with not less than 15% water, by mass, see HEXOLITE, dry or wetted with less than 15% water, by mass HEXOTOL, dry or wetted with less than 15% water, by mass, see HEXOTONAL HEXOTONAL, cast, see HEXYL, see HEXYLTRICHLOROSILANE HMX, see HMX, DESENSITIZED, see HMX, WETTED with not less than 15% water, by mass, see HYDRAZINE, ANHYDROUS HYDRAZINE AQUEOUS SOLUTION, with more than 37% hydrazine by mass HYDRAZINE, AQUEOUS SOLUTION with not more than 37% hydrazine, by mass 6.1 HYDRAZINE AQUEOUS SOLUTION, FLAMMABLE with more than 37% hydrazine, by mass Hydrides, metal, water-reactive, n.o.s., see 4.3 Hydriodic acid, anhydrous, see HYDRIODIC ACID HYDROBROMIC ACID HYDROCARBON GAS MIXTURE, COMPRESSED, N.O.S. HYDROCARBON GAS MIXTURE, LIQUEFIED, N.O.S. such as mixtures A, A01, A02, A0, A1, B1, B2, B or C HYDROCARBON GAS REFILLS FOR SMALL DEVICES with release device HYDROCARBONS, LIQUID, N.O.S. HYDROCHLORIC ACID HYDROCYANIC ACID, AQUEOUS SOLUTION with not more than 20% hydrogen cyanide 6.1 HYDROFLUORIC ACID with more than 60% but not more than 85% hydrogen fluoride HYDROFLUORIC ACID with more than 85% hydrogen fluoride HYDROFLUORIC ACID with not more than 60% hydrogen fluoride HYDROFLUORIC ACID AND SULPHURIC ACID MIXTURE Hydrofluoroboric acid, see Hydrofluorosilicic acid, see HYDROGEN AND METHANE MIXTURE, COMPRESSED Hydrogen arsenide, see HYDROGEN BROMIDE, ANHYDROUS Hydrogen bromide solution, see HYDROGEN CHLORIDE, ANHYDROUS HYDROGEN CHLORIDE, REFRIGERATED LIQUID Carriage prohibited HYDROGEN, COMPRESSED HYDROGEN CYANIDE, AQUEOUS SOLUTION with not more than 20% hydrogen cyanide, see 6.1 HYDROGEN CYANIDE, SOLUTION IN ALCOHOL with not more than 45% hydrogen cyanide 6.1 HYDROGEN CYANIDE, STABILIZED containing less than 3% water 6.1 HYDROGEN CYANIDE, STABILIZED, containing less than 3% water and absorbed in a porous inert material 6.1 HYDROGENDIFLUORIDES, SOLID, N.O.S. HYDROGENDIFLUORIDES SOLUTION, N.O.S. HYDROGEN FLUORIDE, ANHYDROUS Hydrogen fluoride solution, see HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM CONTAINED IN EQUIPMENT HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM PACKED WITH EQUIPMENT Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 586 - HYDROGEN IODIDE, ANHYDROUS Hydrogen iodide solution, see HYDROGEN PEROXIDE AND PEROXYACETIC ACID MIXTURE with acid(s), water and not more than 5% peroxyacetic acid, STABILIZED 5.1 HYDROGEN PEROXIDE, AQUEOUS SOLUTION with not less than 8% but less than 20% hydrogen peroxide (stabilized as necessary) 5.1 HYDROGEN PEROXIDE, AQUEOUS SOLUTION with not less than 20% but not more than 60% hydrogen peroxide (stabilized as necessary) 5.1 HYDROGEN PEROXIDE, AQUEOUS SOLUTION, STABILIZED with more than 60% hydrogen peroxide and not more than 70% hydrogen peroxide 5.1 HYDROGEN PEROXIDE, AQUEOUS SOLUTION, STABILIZED with more than 70% hydrogen peroxide 5.1 HYDROGEN, REFRIGERATED LIQUID HYDROGEN SELENIDE, ANHYDROUS Hydrogen silicide, see HYDROGEN SULPHIDE Hydroselenic acid, see Hydrosilicofluoric acid, see 1-HYDROXYBENZOTRIAZOLE, ANHYDROUS, dry or wetted with less than 20% water, by mass 1-HYDROXYBENZOTRIAZOLE MONOHYDRATE 4.1 3-Hydroxybutan-2-one, see HYDROXYLAMINE SULPHATE 1-Hydroxy-3-methyl-2-penten-4-yne, see 3-Hydroxyphenol, see 6.1 HYPOCHLORITES, INORGANIC, N.O.S. 5.1 HYPOCHLORITE SOLUTION IGNITERS 3,3'-IMINODIPROPYLAMINE Indiarubber, see INFECTIOUS SUBSTANCE, AFFECTING ANIMALS only 6.2 INFECTIOUS SUBSTANCE, AFFECTING HUMANS 6.2 Ink, printer's, flammable, see INSECTICIDE GAS, N.O.S. INSECTICIDE GAS, FLAMMABLE, N.O.S. INSECTICIDE GAS, TOXIC, N.O.S. INSECTICIDE GAS, TOXIC, FLAMMABLE, N.O.S. IODINE IODINE MONOCHLORIDE IODINE PENTAFLUORIDE 5.1 2-IODOBUTANE Iodomethane, see 6.1 IODOMETHYLPROPANES IODOPROPANES alpha-Iodotoluene, see 6.1 I.p.d.i., see 6.1 Iron chloride, anhydrous, see Iron (III) chloride, anhydrous, see Iron chloride solution, see IRON OXIDE, SPENT obtained from coal gas purification 4.2 IRON PENTACARBONYL 6.1 Iron perchloride, anhydrous, see Iron powder, pyrophoric, see 4.2 Iron sesquichloride, anhydrous, see IRON SPONGE, SPENT obtained from coal gas purification 4.2 Iron swarf, see 4.2 ISOBUTANE ISOBUTANOL Isobutene, see ISOBUTYL ACETATE ISOBUTYL ACRYLATE, STABILIZED ISOBUTYL ALCOHOL, see ISOBUTYL ALDEHYDE, see ISOBUTYLAMINE ISOBUTYLENE ISOBUTYL FORMATE Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 587 - ISOBUTYL ISOBUTYRATE ISOBUTYL ISOCYANATE 6.1 ISOBUTYL METHACRYLATE, STABILIZED ISOBUTYL PROPIONATE ISOBUTYRALDEHYDE ISOBUTYRIC ACID ISOBUTYRONITRILE ISOBUTYRYL CHLORIDE ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. ISOCYANATES, TOXIC, N.O.S. 6.1 ISOCYANATES, TOXIC, FLAMMABLE, N.O.S. 6.1 ISOCYANATE SOLUTION, FLAMMABLE, TOXIC, N.O.S. ISOCYANATE SOLUTION, TOXIC, N.O.S. 6.1 ISOCYANATE SOLUTION, TOXIC, FLAMMABLE, N.O.S. 6.1 ISOCYANATO- BENZOTRIFLUORIDES 6.1 3-Isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate, see 6.1 Isododecane, see ISOHEPTENE ISOHEXENE Isooctane, see ISOOCTENE Isopentane, see ISOPENTENES Isopentylamine, see Isopentyl nitrite, see ISOPHORONEDIAMINE ISOPHORONE DIISOCYANATE 6.1 ISOPRENE, STABILIZED ISOPROPANOL ISOPROPENYL ACETATE ISOPROPENYLBENZENE ISOPROPYL ACETATE ISOPROPYL ACID PHOSPHATE ISOPROPYL ALCOHOL, see ISOPROPYLAMINE ISOPROPYLBENZENE ISOPROPYL BUTYRATE Isopropyl chloride, see ISOPROPYL CHLOROACETATE ISOPROPYL CHLOROFORMATE 6.1 ISOPROPYL 2-CHLORO- PROPIONATE Isopropyl-alpha-chloropropionate, see Isopropyl ether, see Isopropylethylene, see Isopropyl formate, see ISOPROPYL ISOBUTYRATE ISOPROPYL ISOCYANATE 6.1 Isopropyl mercaptan, see ISOPROPYL NITRATE ISOPROPYL PROPIONATE Isolpropyltoluene, see Isopropyltoluol, see ISOSORBIDE DINITRATE MIXTURE with not less than 60% lactose, mannose, starch or calcium hydrogen phosphate 4.1 ISOSORBIDE-5-MONONITRATE 4.1 Isovaleraldehyde, see JET PERFORATING GUNS, CHARGED, oil well, without detonator Jet tappers, without detonator, see KEROSENE KETONES, LIQUID, N.O.S. KRYPTON, COMPRESSED KRYPTON, REFRIGERATED LIQUID Lacquer, see Lacquer base, liquid, see Lacquer base or lacquer chips, nitrocellulose, dry, see 4.1 Lacquer base or lacquer chips, plastic, wet with alcohol or solvent, see 4.1 4.1 LEAD ACETATE 6.1 Lead (II) acetate, see 6.1 LEAD ARSENATES 6.1 LEAD ARSENITES 6.1 Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 588 - LEAD AZIDE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass Lead chloride, solid, see 6.1 LEAD COMPOUND, SOLUBLE, N.O.S. 6.1 LEAD CYANIDE 6.1 Lead (II) cyanide 6.1 LEAD DIOXIDE 5.1 LEAD NITRATE 5.1 Lead (II) nitrate 5.1 LEAD PERCHLORATE, SOLID 5.1 LEAD PERCHLORATE, SOLUTION 5.1 Lead (II) perchlorate 5.1 5.1 Lead peroxide, see 5.1 LEAD PHOSPHITE, DIBASIC 4.1 LEAD STYPHNATE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass LEAD SULPHATE with more than 3% free acid Lead tetraethyl, see 6.1 Lead tetramethyl, see 6.1 LEAD TRINITRORESORCINATE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass, see LIFE-SAVING APPLIANCES NOT SELF-INFLATING containing dangerous goods as equipment LIFE-SAVING APPLIANCES, SELF-INFLATING LIGHTER REFILLS containing flammable gas LIGHTERS containing flammable gas LIGHTERS, FUSE Limonene, inactive, see LIQUEFIED GAS, N.O.S. LIQUEFIED GAS, FLAMMABLE, N.O.S. LIQUEFIED GASES, nonflammable, charged with nitrogen, carbon dioxide or air LIQUEFIED GAS, OXIDIZING, N.O.S. LIQUEFIED GAS, TOXIC, N.O.S. LIQUEFIED GAS, TOXIC, CORROSIVE, N.O.S. LIQUEFIED GAS, TOXIC, FLAMMABLE, N.O.S. LIQUEFIED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. LIQUEFIED GAS, TOXIC, OXIDIZING, N.O.S. LIQUEFIED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. Liquefied petroleum gas, see Liquid filler, see Liquid lacquer base, see LITHIUM 4.3 Lithium alkyls, liquid, see 4.2 Lithium alkyls, solid, see 4.2 LITHIUM ALUMINIUM HYDRIDE 4.3 LITHIUM ALUMINIUM HYDRIDE, ETHEREAL 4.3 LITHIUM BOROHYDRIDE 4.3 LITHIUM FERROSILICON 4.3 LITHIUM HYDRIDE 4.3 LITHIUM HYDRIDE, FUSED SOLID 4.3 LITHIUM HYDROXIDE LITHIUM HYDROXIDE SOLUTION LITHIUM HYPOCHLORITE, DRY 1471 5.1 LITHIUM HYPOCHLORITE MIXTURE 5.1 Lithium in cartouches, see 4.3 LITHIUM ION BATTERIES (including lithium ion polymer batteries) LITHIUM ION BATTERIES CONTAINED IN EQUIPMENT (including lithium ion polymer batteries) LITHIUM ION BATTERIES PACKED WITH EQUIPMENT (including lithium ion polymer batteries) LITHIUM METAL BATTERIES (including lithium alloy batteries) Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 589 - LITHIUM METAL BATTERIES CONTAINED IN EQUIPMENT (including lithium alloy batteries) LITHIUM METAL BATTERIES PACKED WITH EQUIPMENT (including lithium alloy batteries) LITHIUM NITRATE 5.1 LITHIUM NITRIDE 4.3 LITHIUM PEROXIDE 5.1 Lithium silicide, see 4.3 LITHIUM SILICON 4.3 L.n.g., see LONDON PURPLE 6.1 L.p.g., see Lye, see Lythene, see MAGNESIUM in pellets, turnings or ribbons 4.1 Magnesium alkyls, see 4.2 MAGNESIUM ALLOYS with more than 50% magnesium in pellets, turnings or ribbons 4.1 MAGNESIUM ALLOYS POWDER 4.3 MAGNESIUM ALUMINIUM PHOSPHIDE 4.3 MAGNESIUM ARSENATE 6.1 Magnesium bisulphite solution, see MAGNESIUM BROMATE 5.1 MAGNESIUM CHLORATE 5.1 Magnesium chloride and chlorate mixture, see 5.1 5.1 MAGNESIUM DIAMIDE 4.2 Magnesium diphenyl, see 4.2 MAGNESIUM FLUORO- SILICATE 6.1 MAGNESIUM GRANULES, COATED, particle size not less than 149 microns 4.3 MAGNESIUM HYDRIDE 4.3 MAGNESIUM NITRATE 5.1 MAGNESIUM PERCHLORATE 5.1 MAGNESIUM PEROXIDE 5.1 MAGNESIUM PHOSPHIDE 4.3 MAGNESIUM POWDER 4.3 Magnesium scrap, see 4.1 MAGNESIUM SILICIDE 4.3 Magnesium silicofluoride, see 6.1 Magnetized material Not subject to ADR MALEIC ANHYDRIDE MALEIC ANHYDRIDE, MOLTEN Malonic dinitrile, see 6.1 Malonodinitrile, see 6.1 MALONONITRILE 6.1 MANEB 4.2 MANEB PREPARATION with not less than 60% maneb 4.2 MANEB PREPARATION, STABILIZED against self-heating 4.3 MANEB, STABILIZED against selfheating 4.3 Manganese ethylene-didithiocarbamate, see 4.2 Manganese ethylene-1,2dithiocarbamate, see 4.2 MANGANESE NITRATE 5.1 Manganese (II) nitrate, see 5.1 MANGANESE RESINATE 4.1 Manganous nitrate, see 5.1 MANNITOL HEXANITRATE, WETTED with not less than 40% water, or mixture of alcohol and water, by mass MATCHES, FUSEE 4.1 MATCHES, SAFETY (book, card or strike on box) 4.1 MATCHES, "STRIKE ANYWHERE" 4.1 MATCHES, WAX "VESTA" 4.1 MEDICAL WASTE, N.O.S. 6.2 MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S. MEDICINE, LIQUID, TOXIC, N.O.S. 6.1 MEDICINE, SOLID, TOXIC, N.O.S. 3249 6.1 p-Mentha-1,8-diene, see MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. MERCAPTANS, LIQUID, TOXIC, FLAMMABLE, N.O.S. 6.1 MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 590 - MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S. MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAMMABLE, N.O.S. 6.1 2-Mercaptoethanol, see 6.1 2-Mercaptopropionic acid, see 6.1 5-MERCAPTOTETRAZOL-1- ACETIC ACID MERCURIC ARSENATE 6.1 MERCURIC CHLORIDE 6.1 MERCURIC NITRATE 6.1 MERCURIC POTASSIUM CYANIDE 6.1 Mercuric sulphate, see 6.1 Mercurol, see 6.1 Mercurous bisulphate, see 6.1 MERCUROUS NITRATE 6.1 Mercurous sulphate, see 6.1 MERCURY MERCURY ACETATE 6.1 MERCURY AMMONIUM CHLORIDE 6.1 MERCURY BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C MERCURY BASED PESTICIDE, LIQUID, TOXIC 6.1 MERCURY BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 6.1 MERCURY BASED PESTICIDE, SOLID, TOXIC 6.1 MERCURY BENZOATE 6.1 Mercury bichloride, see 6.1 MERCURY BROMIDES 6.1 MERCURY COMPOUND, LIQUID, N.O.S. 6.1 MERCURY COMPOUND, SOLID, N.O.S. 6.1 MERCURY CYANIDE 6.1 MERCURY FULMINATE, WETTED with not less than 20% water, or mixture of alcohol and water, by mass MERCURY GLUCONATE 6.1 MERCURY IODIDE 6.1 MERCURY NUCLEATE 6.1 MERCURY OLEATE 6.1 MERCURY OXIDE 6.1 MERCURY OXYCYANIDE, DESENSITIZED 6.1 MERCURY POTASSIUM IODIDE 6.1 MERCURY SALICYLATE 6.1 MERCURY SULPHATE 6.1 MERCURY THIOCYANATE 6.1 Mesitylene, see MESITYL OXIDE Metal alkyl halides, water-reactive, n.o.s. / Metal aryl halides, waterreactive, n.o.s., see 4.2 Metal alkyl hydrides, water-reactive, n.o.s. / Metal aryl hydrides, waterreactive, n.o.s., see 4.2 Metal alkyls, water-reactive, n.o.s. / Metal aryls, water-reactive, n.o.s., see 4.2 METAL CARBONYLS, LIQUID, N.O.S. 6.1 METAL CARBONYLS, SOLID, N.O.S. 6.1 METAL CATALYST, DRY 4.2 METAL CATALYST, WETTED with a visible excess of liquid 4.2 METALDEHYDE 4.1 METAL HYDRIDES, FLAMMABLE, N.O.S. 4.1 METAL HYDRIDES, WATER- REACTIVE, N.O.S. 4.3 METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S. 4.3 METALLIC SUBSTANCE, WATER-REACTIVE, SELF- HEATING, N.O.S. 4.3 METAL POWDER, FLAMMABLE, N.O.S. 4.1 METAL POWDER, SELF- HEATING, N.O.S. 4.2 METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S. 4.1 METHACRYLALDEHYDE, STABILIZED METHACRYLIC ACID, STABILIZED METHACRYLONITRILE, STABILIZED 6.1 METHALLYL ALCOHOL Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 591 - Methanal, see Methane and hydrogen mixture, see METHANE, COMPRESSED METHANE, REFRIGERATED LIQUID METHANESULPHONYL CHLORIDE 6.1 METHANOL 2-Methoxyethyl acetate, see METHOXYMETHYL ISOCYANATE 6.1 4-METHOXY-4- METHYLPENTAN-2-ONE 1-Methoxy-2-nitrobenzene, see 6.1 6.1 1-Methoxy-3-nitrobenzene, see 6.1 6.1 1-Methoxy-4-nitrobenzene, see 6.1 6.1 1-METHOXY-2-PROPANOL METHYL ACETATE METHYLACETYLENE AND PROPADIENE MIXTURE, STABILIZED such as mixture P1 or mixture P2 beta-Methyl acrolein, see 6.1 METHYL ACRYLATE, STABILIZED METHYLAL Methyl alcohol, see Methyl allyl alcohol, see METHYLALLYL CHLORIDE METHYLAMINE, ANHYDROUS METHYLAMINE, AQUEOUS SOLUTION METHYLAMYL ACETATE Methyl amyl alcohol, see Methyl amyl ketone, see N-METHYLANILINE 6.1 Methylated spirit, see alpha-METHYLBENZYL ALCOHOL, LIQUID 6.1 alpha-METHYLBENZYL ALCOHOL, SOLID 6.1 METHYL BROMIDE with not more than 2% chloropicrin Methyl bromide and chloropicrin mixture, with more than 2% chloropicrin, see METHYL BROMIDE AND ETHYLENE DIBROMIDE MIXTURE, LIQUID 6.1 METHYL BROMOACETATE 6.1 2-METHYLBUTANAL 3-METHYLBUTAN-2-ONE 2-METHYL-1-BUTENE 2-METHYL-2-BUTENE 3-METHYL-1-BUTENE N-METHYLBUTYLAMINE METHYL tert-BUTYL ETHER METHYL BUTYRATE METHYL CHLORIDE Methyl chloride and chloropicrin mixture, see METHYL CHLORIDE AND METHYLENE CHLORIDE MIXTURE METHYL CHLOROACETATE 6.1 Methyl chlorocarbonate, see 6.1 Methyl chloroform, see 6.1 METHYL CHLOROFORMATE 6.1 METHYL CHLOROMETHYL ETHER 6.1 METHYL 2-CHLORO- PROPIONATE Methyl alpha-chloropropionate, see METHYLCHLOROSILANE Methyl cyanide, see METHYLCYCLOHEXANE METHYLCYCLOHEXANOLS, flammable METHYLCYCLOHEXANONE METHYLCYCLOPENTANE METHYL DICHLOROACETATE 6.1 METHYLDICHLOROSILANE 4.3 Methylene bromide, see 6.1 Methylene chloride, see 6.1 Methylene chloride and methyl chloride mixture, see Methylene cyanide, see 6.1 p,p'-Methylene dianiline, see 6.1 Methylene dibromide, see 6.1 Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 592 - 2,2'-Methylene-di-(3,4,6trichlorophenol), see 6.1 Methyl ethyl ether, see METHYL ETHYL KETONE, see 2-METHYL-5-ETHYLPYRIDINE 6.1 METHYL FLUORIDE METHYL FORMATE 2-METHYLFURAN Methyl glycol, see Methyl glycol acetate, see 2-METHYL-2-HEPTANETHIOL 6.1 5-METHYLHEXAN-2-ONE METHYLHYDRAZINE 6.1 METHYL IODIDE 6.1 METHYL ISOBUTYL CARBINOL METHYL ISOBUTYL KETONE METHYL ISOCYANATE 6.1 METHYL ISOPROPENYL KETONE, STABILIZED METHYL ISOTHIOCYANATE 6.1 METHYL ISOVALERATE METHYL MAGNESIUM BROMIDE IN ETHYL ETHER 4.3 METHYL MERCAPTAN Methyl mercapto-propionaldehyde, see 6.1 METHYL METHACRYLATE MONOMER, STABILIZED 4-METHYLMORPHOLINE N-METHYLMORPHOLINE, see METHYL NITRITE Carriage prohibited METHYL ORTHOSILICATE 6.1 METHYLPENTADIENE Methylpentanes, see 2-METHYLPENTAN-2-OL 4-Methylpentan-2-ol, see 3-Methyl-2-penten-4ynol, see METHYLPHENYL- DICHLOROSILANE 2-Methyl-2-phenylpropane, see 1-METHYLPIPERIDINE METHYL PROPIONATE Methylpropylbenzene, see METHYL PROPYL ETHER METHYL PROPYL KETONE Methyl pyridines, see Methylstyrene, inhibited, see alpha-Methylstyrene, see Methyl sulphate, see 6.1 Methyl sulphide, see METHYLTETRAHYDROFURAN METHYL TRICHLOROACETATE 6.1 METHYLTRICHLOROSILANE alpha-METHYLVALERAL- DEHYDE Methyl vinyl benzene, inhibited, see METHYL VINYL KETONE, STABILIZED 6.1 M.i.b.c., see MINES with bursting charge Mirbane oil, see 6.1 Missiles, guided, see Mixtures A, A01, A02, A0, A1, B1, B2, B or C, see Mixture F1, mixture F2 or mixture F3, see MIXTURES OF 1,3-BUTADIENE AND HYDROCARBONS, STABILIZED, having a vapour pressure at 70 °C not exceeding 1.1 MPa (11 bar) and a density at 50 °C not lower than 0.525 kg/l Mixture P1 or mixture P2, see MOLYBDENUM PENTACHLORIDE Monochloroacetic acid, see 6.1 6.1 Monochlorobenzene, see Monochlorodifluoromethane, see Monochlorodifluoromethane and monochloropentafluoroethane mixture, see Monochlorodifluoromonobromomethane, see Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 593 - Monochloropentafluoroethane and monochlorodifluoromethane mixture, see Monoethylamine, see MONONITROTOLUIDINES, see 6.1 Monopropylamine, see MORPHOLINE MOTOR FUEL ANTI-KNOCK MIXTURE 6.1 MOTOR FUEL ANTI-KNOCK MIXTURE, FLAMMABLE 6.1 MOTOR SPIRIT Motor spirit and ethanol mixture, with more than 10% ethanol, see Muriatic acid, see MUSK XYLENE, see 4.1 Mysorite, see Naphta, see Naphta, petroleum, see Naphta, solvent, see NAPHTHALENE, CRUDE 4.1 NAPHTHALENE, MOLTEN 4.1 NAPHTHALENE, REFINED 4.1 alpha-NAPHTHYLAMINE 6.1 beta-NAPHTHYLAMINE, SOLID 6.1 beta-NAPHTHYLAMINE, SOLUTION 6.1 NAPHTHYLTHIOUREA 6.1 1-Naphthylthiourea, see 6.1 NAPHTHYLUREA 6.1 NATURAL GAS, COMPRESSED with high methane content NATURAL GAS, REFRIGERATED LIQUID with high methane content Natural gasoline, see Neohexane, see NEON, COMPRESSED NEON, REFRIGERATED LIQUID Neothyl, see NICKEL CARBONYL 6.1 NICKEL CYANIDE 6.1 Nickel (II) cyanide, see 6.1 NICKEL NITRATE 5.1 Nickel (II) nitrate, see 5.1 NICKEL NITRITE 5.1 Nickel (II) nitrite, see 5.1 Nickelous nitrate, see 5.1 Nickelous nitrite, see 5.1 Nickel tetracarbonyl, see 6.1 NICOTINE 6.1 NICOTINE COMPOUND, LIQUID, N.O.S 6.1 NICOTINE COMPOUND, SOLID, N.O.S. 6.1 NICOTINE HYDROCHLORIDE, LIQUID 6.1 NICOTINE HYDROCHLORIDE, SOLID 6.1 NICOTINE HYDROCHLORIDE, SOLUTION 6.1 NICOTINE PREPARATION, LIQUID, N.O.S. 6.1 NICOTINE PREPARATION, SOLID, N.O.S. 6.1 NICOTINE SALICYLATE 6.1 NICOTINE SULPHATE, SOLID 6.1 NICOTINE SULPHATE, SOLUTION 6.1 NICOTINE TARTRATE 6.1 NITRATES, INORGANIC, N.O.S. 5.1 NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 NITRATING ACID MIXTURE with more than 50% nitric acid NITRATING ACID MIXTURE with not more than 50% nitric acid NITRATING ACID MIXTURE, SPENT, with more than 50% nitric acid NITRATING ACID MIXTURE, SPENT, with not more than 50% nitric acid NITRIC ACID, other than red fuming, with at least 65% but not more than 70% nitric acid NITRIC ACID, other than red fuming, with less than 65% nitric acid NITRIC ACID, other than red fuming, with more than 70% nitric acid NITRIC ACID, RED FUMING NITRIC OXIDE, COMPRESSED NITRIC OXIDE AND DINITROGEN TETROXIDE MIXTURE Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 594 - NITRIC OXIDE AND NITROGEN DIOXIDE MIXTURE, see NITRILES, FLAMMABLE, TOXIC, N.O.S. NITRILES, TOXIC, LIQUID, N.O.S. 6.1 NITRILES, TOXIC, SOLID, N.O.S. 6.1 NITRILES, TOXIC, FLAMMABLE, N.O.S. 6.1 NITRITES, INORGANIC, N.O.S. 5.1 NITRITES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 NITROANILINES (o-, m-, p-) 6.1 NITROANISOLES, LIQUID 6.1 NITROANISOLES, SOLID 6.1 NITROBENZENE 6.1 Nitrobenzene bromide, see 6.1 NITROBENZENESULPHONIC ACID Nitrobenzol, see 6.1 5-NITROBENZOTRIAZOL NITROBENZOTRIFLUORIDES, LIQUID 6.1 NITROBENZOTRIFLUORIDES, SOLID 6.1 NITROBROMOBENZENES, LIQUID 6.1 NITROBROMOBENZENES, SOLID 6.1 NITROCELLULOSE, dry or wetted with less than 25% water (or alcohol), by mass NITROCELLULOSE, unmodified or plasticized with less than 18% plasticizing substance, by mass NITROCELLULOSE MEMBRANE FILTERS, with not more than 12.6% nitrogen, by dry mass 4.1 NITROCELLULOSE, with not more than 12.6% nitrogen, by dry mass, MIXTURE WITH PLASTICIZER, WITH PIGMENT 4.1 NITROCELLULOSE, with not more than 12.6% nitrogen, by dry mass, MIXTURE WITH PLASTICIZER, WITHOUT PIGMENT 4.1 NITROCELLULOSE, with not more than 12.6% nitrogen, by dry mass, MIXTURE WITHOUT PLASTICIZER, WITH PIGMENT 4.1 NITROCELLULOSE, with not more than 12.6% nitrogen, by dry mass, MIXTURE WITHOUT PLASTICIZER, WITHOUT PIGMENT 4.1 NITROCELLULOSE, PLASTICIZED with not less than 18% plasticizing substance, by mass NITROCELLULOSE SOLUTION, FLAMMABLE with not more than 12.6% nitrogen, by dry mass, and not more than 55% nitrocellulose NITROCELLULOSE, WETTED with not less than 25% alcohol, by mass NITROCELLULOSE WITH ALCOHOL (not less than 25% alcohol, by mass, and not more than 12.6% nitrogen, by dry mass) 4.1 NITROCELLULOSE WITH WATER (not less than 25% water, by mass) 4.1 Nitrochlorobenzenes, see 6.1 3-NITRO-4-CHLOROBENZO- TRIFLUORIDE 6.1 NITROCRESOLS, LIQUID 6.1 NITROCRESOLS, SOLID 6.1 NITROETHANE NITROGEN, COMPRESSED NITROGEN DIOXIDE, see NITROGEN, REFRIGERATED LIQUID NITROGEN TRIFLUORIDE NITROGEN TRIOXIDE Carriage prohibited NITROGLYCERIN, DESENSITIZED with not less than 40% non-volatile water-insoluble phlegmatizer, by mass NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, N.O.S. with not more than 30% nitroglycerin, by mass NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, FLAMMABLE, N.O.S. with not more than 30% nitroglycerin, by mass NITROGLYCERIN MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 2% but not more than 10% nitroglycerin, by mass 4.1 Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 595 - NITROGLYCERIN, SOLUTION IN ALCOHOL with more than 1% but not more than 5% nitroglycerin NITROGLYCERIN SOLUTION IN ALCOHOL with more than 1% but not more than 10% nitroglycerin NITROGLYCERIN SOLUTION IN ALCOHOL with not more than 1% nitroglycerin NITROGUANIDINE, dry or wetted with less than 20% water, by mass NITROGUANIDINE, WETTED with not less than 20% water, by mass 4.1 NITROHYDROCHLORIC ACID Carriage prohibited NITROMANNITE, WETTED, see NITROMETHANE Nitromuriatic acid, see NITRONAPHTHALENE 4.1 NITROPHENOLS (o-, m-, p-) 6.1 4-NITROPHENYL-HYDRAZINE, with not less than 30% water, by mass 4.1 NITROPROPANES p-NITROSODIMETHYLANILINE 4.2 NITROSTARCH, dry or wetted with less than 20% water, by mass NITROSTARCH, WETTED with not less than 20% water, by mass 4.1 NITROSYL CHLORIDE NITROSYLSULPHURIC ACID, LIQUID NITROSYLSULPHURIC ACID, SOLID NITROTOLUENES, LIQUID 6.1 NITROTOLUENES, SOLID 6.1 NITROTOLUIDINES 6.1 NITROTRIAZOLONE NITRO UREA NITROUS OXIDE NITROUS OXIDE, REFRIGERATED LIQUID NITROXYLENES, LIQUID 6.1 NITROXYLENES, SOLID 6.1 Non-activated carbon, see 4.2 Non-activated charcoal, see 4.2 NONANES NONYLTRICHLOROSILANE 2,5-NORBORNADIENE, STABILIZED, see Normal propyl alcohol, see NTO, see OCTADECYLTRICHLORO- SILANE OCTADIENE OCTAFLUOROBUT-2-ENE OCTAFLUOROCYCLOBUTANE OCTAFLUOROPROPANE OCTANES OCTOGEN, see OCTOL, dry or wetted with less than 15% water, by mass, see OCTOLITE, dry or wetted with less than 15% water, by mass OCTONAL OCTYL ALDEHYDES tert-Octyl mercaptan, see 6.1 OCTYLTRICHLOROSILANE Oenanthol, see OIL GAS, COMPRESSED Oleum, see ORGANIC PEROXIDE TYPE B, LIQUID 5.2 ORGANIC PEROXIDE TYPE B, LIQUID, TEMPERATURE CONTROLLED 5.2 ORGANIC PEROXIDE TYPE B, SOLID 5.2 ORGANIC PEROXIDE TYPE B, SOLID, TEMPERATURE CONTROLLED 5.2 ORGANIC PEROXIDE TYPE C, LIQUID 5.2 ORGANIC PEROXIDE TYPE C, LIQUID, TEMPERATURE CONTROLLED 5.2 ORGANIC PEROXIDE TYPE C, SOLID 5.2 ORGANIC PEROXIDE TYPE C, SOLID, TEMPERATURE CONTROLLED 5.2 ORGANIC PEROXIDE TYPE D, LIQUID 5.2 ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED 5.2 Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 596 - ORGANIC PEROXIDE TYPE D, SOLID 5.2 ORGANIC PEROXIDE TYPE D, SOLID, TEMPERATURE CONTROLLED 5.2 ORGANIC PEROXIDE TYPE E, LIQUID 5.2 ORGANIC PEROXIDE TYPE E, LIQUID, TEMPERATURE CONTROLLED 5.2 ORGANIC PEROXIDE TYPE E, SOLID 5.2 ORGANIC PEROXIDE TYPE E, SOLID, TEMPERATURE CONTROLLED 5.2 ORGANIC PEROXIDE TYPE F, LIQUID 5.2 ORGANIC PEROXIDE TYPE F, LIQUID, TEMPERATURE CONTROLLED 5.2 ORGANIC PEROXIDE TYPE F, SOLID 5.2 ORGANIC PEROXIDE TYPE F, SOLID, TEMPERATURE CONTROLLED 5.2 Organic peroxides, see 2.2.52.4 for an alphabetic list of currently assigned organic peroxides and see to 5.2 ORGANIC PIGMENTS, SELF- HEATING 4.2 ORGANOARSENIC COMPOUND, LIQUID, N.O.S. 6.1 ORGANOARSENIC COMPOUND, SOLID, N.O.S. 6.1 ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC 6.1 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 6.1 ORGANOCHLORINE PESTICIDE, SOLID, TOXIC 6.1 ORGANOMETALLIC COMPOUND, TOXIC, LIQUID, N.O.S., 6.1 ORGANOMETALLIC COMPOUND, TOXIC, SOLID, N.O.S., 6.1 Organometallic compound, solid, water-reactive, flammable, n.o.s., see 4.3 Organometallic compound or Organometallic compound solution or Organometallic compound dispersion, water-reactive, flammable, n.o.s., see 4.3 ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC 4.2 ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC 4.2 ORGANOMETALLIC SUBSTANCE, SOLID, SELF- HEATING 4.2 ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATER- REACTIVE 4.2 ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC, WATER- REACTIVE 4.2 ORGANOMETALLIC SUBSTANCE, LIQUID, WATER- REACTIVE 4.3 ORGANOMETALLIC SUBSTANCE, SOLID, WATER- REACTIVE 4.3 ORGANOMETALLIC SUBSTANCE, LIQUID, WATER- REACTIVE, FLAMMABLE 4.3 ORGANOMETALLIC SUBSTANCE, SOLID, WATER- REACTIVE, FLAMMABLE 4.3 ORGANOMETALLIC SUBSTANCE, SOLID, WATER- REACTIVE, SELF-HEATING 4.3 ORGANOPHOSPHORUS COMPOUND, TOXIC, LIQUID, N.O.S. 6.1 ORGANOPHOSPHORUS COMPOUND, TOXIC, SOLID N.O.S. 6.1 ORGANOPHOSPHORUS COMPOUND, TOXIC, FLAMMABLE, N.O.S. 6.1 ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 °C ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC 6.1 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 6.1 Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 597 - ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC 6.1 ORGANOTIN COMPOUND, LIQUID, N.O.S. 6.1 ORGANOTIN COMPOUND, SOLID, N.O.S. 6.1 ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C ORGANOTIN PESTICIDE, LIQUID, TOXIC 6.1 ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 6.1 ORGANOTIN PESTICIDE, SOLID, TOXIC 6.1 Orthophospohoric acid, see OSMIUM TETROXIDE 6.1 OXIDIZING LIQUID, N.O.S. 5.1 OXIDIZING LIQUID, CORROSIVE, N.O.S. 5.1 OXIDIZING LIQUID, TOXIC, N.O.S. 5.1 OXIDIZING SOLID, N.O.S. 5.1 OXIDIZING SOLID, CORROSIVE, N.O.S. 5.1 OXIDIZING SOLID, FLAMMABLE, N.O.S. 5.1 Carriage prohibited OXIDIZING SOLID, SELF- HEATING, N.O.S. 5.1 Carriage prohibited OXIDIZING SOLID, TOXIC, N.O.S. 5.1 OXIDIZING SOLID, WATER- REACTIVE, N.O.S. 5.1 Carriage prohibited Oxirane, see OXYGEN, COMPRESSED OXYGEN DIFLUORIDE, COMPRESSED OXYGEN GENERATOR, CHEMICAL 5.1 OXYGEN, REFRIGERATED LIQUID 1-Oxy-4-nitrobenzene, see 6.1 PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) PAINT RELATED MATERIAL (including paint thinning and reducing compound) Paint thinning and reducing compound, see PAPER, UNSATURATED OIL TREATED, incompletely dried (including carbon paper) 4.2 Paraffin, see PARAFORMALDEHYDE 4.1 PARALDEHYDE PCBs, see PENTABORANE 4.2 PENTACHLOROETHANE 6.1 PENTACHLOROPHENOL 6.1 PENTAERYTHRITE TETRANITRATE with not less than 7% wax, by mass PENTAERYTHRITE TETRANITRATE, DESENSITIZED with not less than 15% phlegmatizer, by mass PENTAERYTHRITE TETRANITRATE MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 10% but not more than 20% PETN, by mass 4.1 PENTAERYTHRITE TETRANITRATE, WETTED with not less than 25% water, by mass PENTAERYTHRITOL TETRANITRATE, see 4.1 PENTAFLUOROETHANE Pentafluoroethane, 1,1,1trifluoroethane, and 1,1,1,2tetrafluoroethane zeotropic mixture with approximately 44% pentafluoroethane and 52% 1,1,1trifluoroethane, see PENTAMETHYLHEPTANE Pentanal, see PENTANE-2,4-DIONE PENTANES, liquid n-Pentane, see PENTANOLS 3-Pentanol, see 1-PENTENE 1-PENTOL PENTOLITE, dry or wetted with less than 15% water, by mass Pentyl nitrite, see Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 598 - PERCHLORATES, INORGANIC, N.O.S. 5.1 PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 PERCHLORIC ACID with more than 50% but not more than 72% acid, by mass 5.1 PERCHLORIC ACID with not more than 50% acid, by mass Perchlorobenzene, see 6.1 Perchlorocyclopentadiene, see 6.1 Perchloroethylene, see 6.1 PERCHLOROMETHYL MERCAPTAN 6.1 PERCHLORYL FLUORIDE Perfluoroacetylchloride, see PERFLUORO (ETHYL VINYL ETHER) PERFLUORO (METHYL VINYL ETHER) Perfluoropropane, see PERFUMERY PRODUCTS with flammable solvents PERMANGANATES, INORGANIC, N.O.S. 5.1 PERMANGANATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 PEROXIDES, INORGANIC, N.O.S. 5.1 PERSULPHATES, INORGANIC, N.O.S. 5.1 PERSULPHATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. 5.1 PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S., flash-point less than 23 °C PESTICIDE, LIQUID, TOXIC, N.O.S. 6.1 PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S., flash-point not less than 23 °C 6.1 PESTICIDE, SOLID, TOXIC, N.O.S. 6.1 Pesticide, toxic, under compressed gas, n.o.s, see PETN, see 4.1 PETN/TNT, see PETROL Petrol and ethanol mixture, with more than 10% ethanol, see PETROLEUM CRUDE OIL PETROLEUM DISTILLATES, N.O.S. Petroleum ether, see PETROLEUM GASES, LIQUEFIED 1075 Petroleum naphtha, see Petroleum oil, see PETROLEUM PRODUCTS, N.O.S. Petroleum raffinate, see PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC Petroleum spirit, see PHENACYL BROMIDE 6.1 PHENETIDINES 6.1 PHENOLATES, LIQUID PHENOLATES, SOLID PHENOL, MOLTEN 6.1 PHENOL, SOLID 6.1 PHENOL SOLUTION 6.1 PHENOLSULPHONIC ACID, LIQUID PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC 6.1 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 6.1 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC 6.1 PHENYLACETONITRILE, LIQUID 2470 6.1 PHENYLACETYL CHLORIDE Phenylamine, see 6.1 1-Phenylbutane, see 2-Phenylbutane, see PHENYLCARBYLAMINE CHLORIDE 6.1 PHENYL CHLOROFORMATE 6.1 Phenyl cyanide, see 6.1 PHENYLENEDIAMINES (o-, m-, p-) 6.1 Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 599 - Phenylethylene, see PHENYLHYDRAZINE 6.1 PHENYL ISOCYANATE 6.1 Phenylisocyanodichloride, see 6.1 PHENYL MERCAPTAN 6.1 PHENYLMERCURIC ACETATE 6.1 PHENYLMERCURIC COMPOUND, N.O.S. 6.1 PHENYLMERCURIC HYDROXIDE 6.1 PHENYLMERCURIC NITRATE 6.1 PHENYLPHOSPHORUS DICHLORIDE PHENYLPHOSPHORUS THIODICHLORIDE 2-Phenylpropene, see PHENYLTRICHLOROSILANE PHOSGENE 9-PHOSPHABICYCLO-NONANES 2940 4.2 PHOSPHINE Phosphoretted hydrogen, see PHOSPHORIC ACID, SOLUTION PHOSPHORIC ACID, SOLID Phosphoric acid, anhydrous, see PHOSPHOROUS ACID PHOSPHORUS, AMORPHOUS 4.1 Phosphorus bromide, see Phosphorus chloride, see 6.1 PHOSPHORUS HEPTASULPHIDE, free from yellow and white phosphorus 4.1 PHOSPHORUS OXYBROMIDE PHOSPHORUS OXYBROMIDE, MOLTEN PHOSPHORUS OXYCHLORIDE 6.1 PHOSPHORUS PENTABROMIDE PHOSPHORUS PENTACHLORIDE 1806 PHOSPHORUS PENTAFLUORIDE PHOSPHORUS PENTASULPHIDE, free from yellow and white phosphorus 4.3 PHOSPHORUS PENTOXIDE PHOSPHORUS SESQUISULPHIDE, free from yellow and white phosphorus 4.1 Phosphorus (V) sulphide, free from yellow and white phosphorus, see 4.3 Phosphorus sulphochloride, see PHOSPHORUS TRIBROMIDE PHOSPHORUS TRICHLORIDE 6.1 PHOSPHORUS TRIOXIDE PHOSPHORUS TRISULPHIDE, free from yellow and white phosphorus 4.1 PHOSPHORUS, WHITE, DRY 4.2 PHOSPHORUS, WHITE IN SOLUTION 4.2 PHOSPHORUS, WHITE, MOLTEN 4.2 PHOSPHORUS, WHITE, UNDER WATER 4.2 PHOSPHORUS, YELLOW, DRY 4.2 PHOSPHORUS, YELLOW, IN SOLUTION 4.2 PHOSPHORUS, YELLOW, UNDER WATER 4.2 Phosphoryl chloride, see 6.1 PHTHALIC ANHYDRIDE with more than 0.05% of maleic anhydride PICOLINES PICRAMIDE, see PICRIC ACID, WETTED, see 4.1 4.1 PICRITE, see PICRITE, WETTED, see 4.1 Picrotoxin, see 6.1 6.1 PICRYL CHLORIDE, see PICRYL CHLORIDE, WETTED, see 4.1 alpha-PINENE PINE OIL PIPERAZINE PIPERIDINE Pivaloyl chloride, see 6.1 Plastic explosives, see PLASTICS MOULDING COMPOUND in dough, sheet or extruded rope form evolving flammable vapour PLASTICS, NITROCELLULOSE- BASED, SELF-HEATING, N.O.S. 4.2 Polish, see Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 600 - POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. POLYAMINES, LIQUID, CORROSIVE, N.O.S. POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. POLYAMINES, SOLID, CORROSIVE, N.O.S. POLYCHLORINATED BIPHENYLS, LIQUID POLYCHLORINATED BIPHENYLS, SOLID POLYESTER RESIN KIT POLYHALOGENATED BIPHENYLS, LIQUID POLYHALOGENATED BIPHENYLS, SOLID POLYHALOGENATED TERPHENYLS, LIQUID POLYHALOGENATED TERPHENYLS, SOLID POLYMERIC BEADS, EXPANDABLE, evolving flammable vapour Polystyrene beads, expandable, see POTASSIUM 4.3 POTASSIUM ARSENATE 6.1 POTASSIUM ARSENITE 6.1 Potassium bifluoride, see Potassium bisulphate, see Potassium bisulphite solution, see POTASSIUM BOROHYDRIDE 4.3 POTASSIUM BROMATE 5.1 POTASSIUM CHLORATE 5.1 POTASSIUM CHLORATE, AQUEOUS SOLUTION 5.1 Potassium chlorate mixed with mineral oil, see POTASSIUM CUPROCYANIDE 6.1 POTASSIUM CYANIDE, SOLID 6.1 POTASSIUM CYANIDE, SOLUTION 6.1 Potassium dicyanocuprate (I), see 6.1 POTASSIUM DITHIONITE 4.2 POTASSIUM FLUORIDE, SOLID 6.1 POTASSIUM FLUORIDE, SOLUTION 6.1 POTASSIUM FLUOROACETATE 6.1 POTASSIUM FLUOROSILICATE 6.1 Potassium hexafluorosilicate, see 6.1 Potassium hydrate, see POTASSIUM HYDROGENDIFLUORIDE, SOLID POTASSIUM HYDROGENDIFLUORIDE, SOLUTION POTASSIUM HYDROGEN SULPHATE POTASSIUM HYDROSULPHITE, see 4.2 Potassium hydroxide, liquid, see POTASSIUM HYDROXIDE, SOLID POTASSIUM HYDROXIDE SOLUTION POTASSIUM METAL ALLOYS, LIQUID 4.3 POTASSIUM METAL ALLOYS, SOLID 4.3 POTASSIUM METAVANADATE 6.1 POTASSIUM MONOXIDE POTASSIUM NITRATE 5.1 Potassium nitrate and sodium nitrate mixture, see 5.1 POTASSIUM NITRATE AND SODIUM NITRITE MIXTURE 5.1 POTASSIUM NITRITE 5.1 POTASSIUM PERCHLORATE 5.1 POTASSIUM PERMANGANATE 5.1 POTASSIUM PEROXIDE 5.1 POTASSIUM PERSULPHATE 5.1 POTASSIUM PHOSPHIDE 4.3 Potassium selenate, see 6.1 Potassium selenite, see 6.1 Potassium silicofluoride, see 6.1 POTASSIUM SODIUM ALLOYS, LIQUID 4.3 POTASSIUM SODIUM ALLOYS, SOLID 4.3 POTASSIUM SULPHIDE with less than 30% water of crystallization 4.2 POTASSIUM SULPHIDE, ANHYDROUS 4.2 POTASSIUM SULPHIDE, HYDRATED with not less than 30% water of crystallization Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 601 - POTASSIUM SUPEROXIDE 5.1 Potassium tetracyanomercurate (II), see 6.1 POWDER CAKE, WETTED with not less than 17% alcohol, by mass POWDER CAKE, WETTED with not less than 25% water, by mass POWDER PASTE, see POWDER, SMOKELESS Power devices, explosive, see PRIMERS, CAP TYPE Primers, small arms, see PRIMERS, TUBULAR PRINTING INK, flammable or PRINTING INK RELATED MATERIAL (including printing ink thinning or reducing compound), flammable Projectiles, illuminating, see PROJECTILES, inert with tracer PROJECTILES with burster or expelling charge PROJECTILES with bursting charge PROPADIENE, STABILIZED Propadiene and methyl acetylene mixture, stabilized, see PROPANE PROPANETHIOLS n-PROPANOL PROPELLANT, LIQUID PROPELLANT, SOLID Propellant with a single base, Propellant with a double base, Propellant with a triple base, see Propene, see PROPIONALDEHYDE PROPIONIC ACID with not less than 10% and less than 90% acid by mass PROPIONIC ACID with not less than 90% acid by mass PROPIONIC ANHYDRIDE PROPIONITRILE PROPIONYL CHLORIDE n-PROPYL ACETATE PROPYL ALCOHOL, NORMAL, see PROPYLAMINE n-PROPYLBENZENE Propyl chloride, see n-PROPYL CHLOROFORMATE 6.1 PROPYLENE PROPYLENE CHLOROHYDRIN 6.1 1,2-PROPYLENEDIAMINE Propylene dichloride, see PROPYLENEIMINE, STABILIZED PROPYLENE OXIDE PROPYLENE TETRAMER Propylene trimer, see PROPYL FORMATES n-PROPYL ISOCYANATE 6.1 Propyl mercaptan, see n-PROPYL NITRATE PROPYLTRICHLOROSILANE Pyrazine hexahydride, see PYRETHROID PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C PYRETHROID PESTICIDE, LIQUID, TOXIC 6.1 PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 6.1 PYRETHROID PESTICIDE, SOLID, TOXIC 6.1 PYRIDINE Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 602 - PYROPHORIC ALLOY, N.O.S. 4.2 Pyrophoric organometallic compound, water-reactive, n.o.s., liquid, see 4.2 Pyrophoric organometallic compound, water-reactive, n.o.s., solid, see 4.2 PYROPHORIC LIQUID, INORGANIC, N.O.S. 4.2 PYROPHORIC LIQUID, ORGANIC, N.O.S. 4.2 PYROPHORIC METAL, N.O.S. 4.2 PYROPHORIC SOLID, INORGANIC, N.O.S. 4.2 PYROPHORIC SOLID, ORGANIC, N.O.S. 4.2 PYROSULPHURYL CHLORIDE Pyroxylin solution, see PYRROLIDINE QUINOLINE 6.1 Quinone, see 6.1 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - ARTICLES MANUFACTURED FROM NATURAL URANIUM or DEPLETED URANIUM or NATURAL THORIUM RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - EMPTY PACKAGING RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - INSTRUMENTS or ARTICLES RADIOACTIVE MATERIAL, EXCEPTED PACKAGE - LIMITED QUANTITY OF MATERIAL RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-I), non fissile or fissile-excepted RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-II), FISSILE RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-II), non fissile or fissile-excepted RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY, (LSA-III), FISSILE RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-III), non fissile or fissile-excepted RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I or SCO-II), FISSILE RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I or SCO-II), non fissile or fissile-excepted RADIOACTIVE MATERIAL, TRANSPORTED UNDER SPECIAL ARRANGEMENT, FISSILE RADIOACTIVE MATERIAL, TRANSPORTED UNDER SPECIAL ARRANGEMENT, non fissile or fissile-excepted RADIOACTIVE MATERIAL, TYPE A PACKAGE, FISSILE, non-special form RADIOACTIVE MATERIAL, TYPE A PACKAGE, non-special form, non fissile or fissile-excepted RADIOACTIVE MATERIAL, TYPE A PACKAGE, SPECIAL FORM, FISSILE RADIOACTIVE MATERIAL, TYPE A PACKAGE, SPECIAL FORM, non fissile or fissileexcepted RADIOACTIVE MATERIAL, TYPE B(M) PACKAGE, FISSILE RADIOACTIVE MATERIAL, TYPE B(M) PACKAGE, non fissile or fissile-excepted RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, FISSILE RADIOACTIVE MATERIAL, TYPE B(U) PACKAGE, non fissile or fissile-excepted RADIOACTIVE MATERIAL, TYPE C PACKAGE, FISSILE RADIOACTIVE MATERIAL, TYPE C PACKAGE, non fissile or fissile-excepted RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, FISSILE RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, non fissile or fissile-excepted Rags, oily 4.2 Not subject to ADR RDX, see Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 603 - RECEPTACLES, SMALL, CONTAINING GAS without a release device, non-refillable Red phosphorus, see 4.1 REFRIGERANT GAS, N.O.S., such as mixture F1, mixture F2 or mixture P2 REFRIGERANT GAS R 12, see REFRIGERANT GAS R 12B1, see REFRIGERANT GAS R 13, see REFRIGERANT GAS R 13B1, see REFRIGERANT GAS R 14, see REFRIGERANT GAS R 21, see REFRIGERANT GAS R 22, see REFRIGERANT GAS R 23, see REFRIGERANT GAS R 32, see REFRIGERANT GAS R 40, see REFRIGERANT GAS R 41, see REFRIGERANT GAS R 114, see REFRIGERANT GAS R 115, see REFRIGERANT GAS R 116, see REFRIGERANT GAS R 124, see REFRIGERANT GAS R 125, see REFRIGERANT GAS R 133a, see REFRIGERANT GAS R 134a, see REFRIGERANT GAS R 142b, see REFRIGERANT GAS R 143a, see REFRIGERANT GASR 152a, see REFRIGERANT GAS R 161, see REFRIGERANT GAS R 218, see REFRIGERANT GAS R 227, see REFRIGERANT GAS R 404A REFRIGERANT GAS R 407A REFRIGERANT GAS R 407B REFRIGERANT GAS R 407C REFRIGERANT GAS R 500, see REFRIGERANT GAS R 502, see REFRIGERANT GAS R 503, see REFRIGERANT GAS R 1132a, see REFRIGERANT GAS R 1216, see REFRIGERANT GAS R 1318, see REFRIGERANT GAS RC 318, see REFRIGERATING MACHINES containing flammable, non-toxic, liquefied gas REFRIGERATING MACHINES containing non-flammable, nontoxic, gases or ammonia solutions (UN 2672) REGULATED MEDICAL WASTE, N.O.S. 6.2 RELEASE DEVICES, EXPLOSIVE RESIN SOLUTION, flammable Resorcin, see 6.1 RESORCINOL 6.1 RIVETS, EXPLOSIVE Road oil, with a flash-point not greater than 60 °C, see Road oil, with a flash-point above 60 °C, at or above its flash-point, see Road oil, at or above 100 °C and below its flash-point, see ROCKET MOTORS ROCKET MOTORS, LIQUID FUELLED ROCKET MOTORS WITH HYPERGOLIC LIQUIDS with or without expelling charge ROCKETS with bursting charge ROCKETS with expelling charge ROCKETS with inert head ROCKETS, LINE-THROWING ROCKETS, LIQUID FUELLED with bursting charge ROSIN OIL RUBBER SCRAP, powdered or granulated 4.1 RUBBER SHODDY, powdered or granulated 4.1 RUBBER SOLUTION RUBIDIUM 4.3 RUBIDIUM HYDROXIDE RUBIDIUM HYDROXIDE SOLUTION Rubidium nitrate, see 5.1 Saltpetre, see 5.1 Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 604 - SAMPLES, EXPLOSIVE, other than initiating explosive Sand acid, see SEAT-BELT PRETENSIONERS SEED CAKE with more than 1.5% oil and not more than 11% moisture 4.2 SEED CAKE with not more than 1.5% oil and not more than 11% moisture 4.2 Seed expellers, see 4.2 4.2 SELENATES 6.1 SELENIC ACID SELENITES 6.1 SELENIUM COMPOUND, LIQUID, N.O.S. 6.1 SELENIUM COMPOUND, SOLID, N.O.S. 6.1 SELENIUM DISULPHIDE 6.1 SELENIUM HEXAFLUORIDE SELENIUM OXYCHLORIDE SELF-HEATING LIQUID, CORROSIVE, INORGANIC, N.O.S. 4.2 SELF-HEATING LIQUID, CORROSIVE, ORGANIC, N.O.S. 4.2 SELF-HEATING LIQUID, INORGANIC, N.O.S. 4.2 SELF-HEATING LIQUID, ORGANIC, N.O.S. 4.2 SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S. 4.2 SELF-HEATING LIQUID, TOXIC, ORGANIC, N.O.S. 4.2 SELF-HEATING SOLID, CORROSIVE, INORGANIC, N.O.S. 4.2 SELF-HEATING SOLID, CORROSIVE, ORGANIC, N.O.S. 4.2 SELF-HEATING SOLID, INORGANIC, N.O.S. 4.2 SELF-HEATING SOLID, ORGANIC, N.O.S. 4.2 SELF-HEATING SOLID, OXIDIZING, N.O.S 4.2 Carriage prohibited SELF-HEATING SOLID, TOXIC, INORGANIC, N.O.S. 4.2 SELF-HEATING SOLID, TOXIC, ORGANIC, N.O.S. 4.2 SELF-REACTIVE LIQUID TYPE B 4.1 SELF-REACTIVE LIQUID TYPE B, TEMPERATURE CONTROLLED 4.1 SELF-REACTIVE LIQUID TYPE C 4.1 SELF-REACTIVE LIQUID TYPE C, TEMPERATURE CONTROLLED 4.1 SELF-REACTIVE LIQUID TYPE D 3225 4.1 SELF-REACTIVE LIQUID TYPE D, TEMPERATURE CONTROLLED 4.1 SELF-REACTIVE LIQUID TYPE E 4.1 SELF-REACTIVE LIQUID TYPE E, TEMPERATURE CONTROLLED 4.1 SELF-REACTIVE LIQUID TYPE F 4.1 SELF-REACTIVE LIQUID TYPE F, TEMPERATURE CONTROLLED 4.1 SELF-REACTIVE SOLID TYPE B 4.1 SELF-REACTIVE SOLID TYPE B, TEMPERATURE CONTROLLED 4.1 SELF-REACTIVE SOLID TYPE C 4.1 SELF-REACTIVE SOLID TYPE C, TEMPERATURE CONTROLLED 4.1 SELF-REACTIVE SOLID TYPE D 4.1 SELF-REACTIVE SOLID TYPE D, TEMPERATURE CONTROLLED 4.1 SELF-REACTIVE SOLID TYPE E 4.1 SELF-REACTIVE SOLID TYPE E, TEMPERATURE CONTROLLED 4.1 SELF-REACTIVE SOLID TYPE F 4.1 SELF-REACTIVE SOLID TYPE F, TEMPERATURE CONTROLLED 4.1 SHALE OIL Shaped charges, see Shellac, see SIGNAL DEVICES, HAND SIGNALS, DISTRESS, ship Signals, distress, ship, wateractivated, see Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 605 - SIGNALS, RAILWAY TRACK, EXPLOSIVE SIGNALS, SMOKE SILANE Silicofluoric acid, see Silicofluorides, n.o.s., see 6.1 Silicon chloride, see SILICON POWDER, AMORPHOUS 4.1 SILICON TETRACHLORIDE SILICON TETRAFLUORIDE SILVER ARSENITE 6.1 SILVER CYANIDE 6.1 SILVER NITRATE 5.1 SILVER PICRATE, WETTED with not less than 30% water, by mass 4.1 SLUDGE ACID SODA LIME with more than 4% sodium hydroxide SODIUM 4.3 Sodium aluminate, solid Not subject to ADR SODIUM ALUMINATE SOLUTION SODIUM ALUMINIUM HYDRIDE 4.3 SODIUM AMMONIUM VANADATE 6.1 SODIUM ARSANILATE 6.1 SODIUM ARSENATE 6.1 SODIUM ARSENITE, AQUEOUS SOLUTION 6.1 SODIUM ARSENITE, SOLID 6.1 SODIUM AZIDE 6.1 Sodium bifluoride, see Sodium binoxide, see 5.1 Sodium bisulphite solution, see SODIUM BOROHYDRIDE 4.3 SODIUM BOROHYDRIDE AND SODIUM HYDROXIDE SOLUTION, with not more than 12% sodium borohydride and not more than 40% sodium hydroxide by mass SODIUM BROMATE 5.1 SODIUM CACODYLATE 6.1 SODIUM CARBONATE PEROXYHYDRATE 5.1 SODIUM CHLORATE 5.1 SODIUM CHLORATE, AQUEOUS SOLUTION 5.1 Sodium chlorate mixed with dinitrotoluene, see SODIUM CHLORITE 5.1 SODIUM CHLOROACETATE 6.1 SODIUM CUPROCYANIDE, SOLID 6.1 SODIUM CUPROCYANIDE SOLUTION 6.1 SODIUM CYANIDE, SOLID 6.1 SODIUM CYANIDE, SOLUTION 6.1 Sodium dicyanocuprate (I), solid, see 6.1 Sodium dicyanocuprate (I) solution, see 6.1 Sodium dimethylarsenate, see 6.1 SODIUM DINITRO-o- CRESOLATE, dry or wetted with less than 15% water, by mass SODIUM DINITRO-o- CRESOLATE, WETTED with not less than 10% water, by mass 4.1 SODIUM DINITRO-o- CRESOLATE, WETTED with not less than 15% water, by mass 4.1 Sodium dioxide, see 5.1 SODIUM DITHIONITE 4.2 SODIUM FLUORIDE, SOLID 6.1 SODIUM FLUORIDE, SOLUTION 6.1 SODIUM FLUOROACETATE 6.1 SODIUM FLUOROSILICATE 6.1 Sodium hexafluorosilicate, see 6.1 Sodium hydrate, see SODIUM HYDRIDE 4.3 Sodium hydrogen 4-aminophenylarsenate, see 6.1 SODIUM HYDROGEN- DIFLUORIDE SODIUM HYDROSULPHIDE with less than 25% water of crystallization 4.2 SODIUM HYDROSULPHIDE, HYDRATED with not less than 25% water of crystallization SODIUM HYDROSULPHITE, see 4.2 Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 606 - SODIUM HYDROXIDE, SOLID SODIUM HYDROXIDE SOLUTION Sodium metasilicate pentahydrate, see SODIUM METHYLATE 4.2 SODIUM METHYLATE SOLUTION in alcohol SODIUM MONOXIDE SODIUM NITRATE 5.1 SODIUM NITRATE AND POTASSIUM NITRATE MIXTURE 5.1 SODIUM NITRITE 5.1 Sodium nitrite and potassium nitrate mixture, see 5.1 SODIUM PENTACHLORO- HENATE 6.1 SODIUM PERBORATE MONOHYDRATE 5.1 SODIUM PERCHLORATE 5.1 SODIUM PERMANGANATE 5.1 SODIUM PEROXIDE 5.1 SODIUM PEROXOBORATE, ANHYDROUS 5.1 SODIUM PERSULPHATE 5.1 SODIUM PHOSPHIDE 4.3 SODIUM PICRAMATE, dry or wetted with less than 20% water, by mass SODIUM PICRAMATE, WETTED with not less than 20% water, by mass 4.1 Sodium potassium alloys, liquid, see 4.3 Sodium selenate, see 6.1 Sodium selenite, see 6.1 Sodium silicofluoride, see 6.1 SODIUM SULPHIDE, ANHYDROUS 4.2 SODIUM SULPHIDE with less than 30% water of crystallization 4.2 SODIUM SULPHIDE, HYDRATED with not less than 30% water SODIUM SUPEROXIDE 5.1 SOLIDS CONTAINING CORROSIVE LIQUID, N.O.S. SOLIDS or mixtures of solids (such as preparations and wastes) CONTAINING FLAMMABLE LIQUID, N.O.S. having a flashpoint up to 60 °C 4.1 SOLIDS CONTAINING TOXIC LIQUID, N.O.S. 6.1 Solvents, flammable, n.o.s., see Solvents, flammable, toxic, n.o.s., see 1992 SOUNDING DEVICES, EXPLOSIVE Squibs, see Stain, see STANNIC CHLORIDE, ANHYDROUS STANNIC CHLORIDE PENTAHYDRATE STANNIC PHOSPHIDES 4.3 Steel swarf, see 4.2 STIBINE Straw 4.1 Not subject to ADR Strontium alloys, pyrophoric, see 4.2 STRONTIUM ARSENITE 6.1 STRONTIUM CHLORATE 5.1 Strontium dioxide, see 5.1 STRONTIUM NITRATE 5.1 STRONTIUM PERCHLORATE 5.1 STRONTIUM PEROXIDE 5.1 STRONTIUM PHOSPHIDE 4.3 STRYCHNINE 6.1 STRYCHNINE SALTS 6.1 STYPHNIC ACID, see STYRENE MONOMER, STABILIZED SUBSTANCES, EVI, N.O.S., see Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 607 - SUBSTANCES, EXPLOSIVE, N.O.S. SUBSTANCES, EXPLOSIVE, VERY INSENSITIVE, N.O.S. Substances liable to spontaneous combustion, n.o.s., see 4.2 4.2 4.2 4.2 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 °C SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC 6.1 SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 6.1 SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC 6.1 SULPHAMIC ACID SULPHUR 4.1 SULPHUR CHLORIDES Sulphur dichloride, see SULPHUR DIOXIDE Sulphuretted hydrogen, see SULPHUR HEXAFLUORIDE SULPHURIC ACID with more than 51% acid SULPHURIC ACID with not more than 51% acid SULPHURIC ACID, FUMING SULPHURIC ACID, SPENT Sulphuric and hydrofluoric acid mixture, see SULPHUR, MOLTEN 4.1 Sulphur monochloride, see SULPHUROUS ACID SULPHUR TETRAFLUORIDE SULPHUR TRIOXIDE, STABILIZED SULPHURYL CHLORIDE 6.1 SULPHURYL FLUORIDE Talcum with tremolite and/or actinolite, see TARS, LIQUID, including road oils, and cutback bitumens, with a flashpoint not greater than 60 °C Tars, liquid, with a flash-point above 60 °C, at or above its flash-point, see Tars, liquid, at or above 100 °C and below its flash-point, see Tartar emetic, see 6.1 TEAR GAS CANDLES 6.1 TEAR GAS SUBSTANCE, LIQUID, N.O.S. 6.1 TEAR GAS SUBSTANCE, SOLID, N.O.S. 6.1 TELLURIUM COMPOUND, N.O.S. 3284 6.1 TELLURIUM HEXAFLUORIDE TERPENE HYDROCARBONS, N.O.S. TERPINOLENE TETRABROMOETHANE 6.1 1,1,2,2-TETRACHLOROETHANE 6.1 TETRACHLOROETHYLENE 6.1 TETRAETHYL DITHIO- PYROPHOSPHATE 6.1 TETRAETHYLENEPENTAMINE Tetraethyl lead, see 6.1 TETRAETHYL SILICATE Tetraethyoxysilane, see Tetrafluorodichloroethane, see 1,1,1,2-TETRAFLUOROETHANE TETRAFLUOROETHYLENE, STABILIZED TETRAFLUOROMETHANE 1,2,3,6-TETRAHYDRO- BENZALDEHYDE TETRAHYDROFURAN TETRAHYDRO- FURFURYLAMINE Tetrahydro-1,4-oxazine, see TETRAHYDROPHTHALIC ANHYDRIDES with more than 0.05% of maleic anhydride 1,2,3,6-TETRAHYDROPYRIDINE TETRAHYDROTHIOPHENE Tetramethoxysilane, see 6.1 Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 608 - TETRAMETHYLAMMONIUM HYDROXIDE SOLID TETRAMETHYLAMMONIUM HYDROXIDE SOLUTION Tetramethylene, see Tetramethylene cyanide, see 6.1 Tetramethyl lead, see 6.1 TETRAMETHYLSILANE TETRANITROANILINE TETRANITROMETHANE 6.1 TETRAPROPYL ORTHOTITANATE TETRAZENE, WETTED with not less than 30% water, or mixture of alcohol and water, by mass, see TETRAZOL-1-ACETIC ACID 1H-TETRAZOLE TETRYL, see Textile waste, wet 4.2 Not subject to ADR THALLIUM CHLORATE 5.1 Thallium (I) chlorate, see 5.1 THALLIUM COMPOUND, N.O.S. 6.1 THALLIUM NITRATE 6.1 Thallium (I) nitrate, see 6.1 Thallous chlorate, see 5.1 4-THIAPENTANAL 6.1 Thia-4-pentanal, see 6.1 THIOACETIC ACID THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash-point less than 23 °C THIOCARBAMATE PESTICIDE, LIQUID, TOXIC 6.1 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash-point not less than 23 °C 6.1 THIOCARBAMATE PESTICIDE, SOLID, TOXIC 6.1 THIOGLYCOL 6.1 THIOGLYCOLIC ACID THIOLACTIC ACID 6.1 THIONYL CHLORIDE THIOPHENE Thiophenol, see 6.1 THIOPHOSGENE 6.1 THIOPHOSPHORYL CHLORIDE THIOUREA DIOXIDE 4.2 Tin (IV) chloride, anhydrous, see Tin (IV) chloride pentahydrate, see TINCTURES, MEDICINAL Tin tetrachloride, see TITANIUM DISULPHIDE 4.2 TITANIUM HYDRIDE 4.1 TITANIUM POWDER, DRY 4.2 TITANIUM POWDER, WETTED with not less than 25% water 4.1 TITANIUM SPONGE GRANULES 4.1 TITANIUM SPONGE POWDERS 4.1 TITANIUM TETRACHLORIDE 6.1 TITANIUM TRICHLORIDE MIXTURE TITANIUM TRICHLORIDE MIXTURE, PYROPHORIC 4.2 TITANIUM TRICHLORIDE, PYROPHORIC 4.2 TNT, see TNT mixed with aluminium, see TNT, WETTED with not less than 30% water, by mass, see 4.1 TNT, WETTED with not less than 10% water, by mass, see 4.1 Toe puffs, nitrocellulose base, see 4.1 TOLUENE TOLUENE DIISOCYANATE 6.1 TOLUIDINES, LIQUID 6.1 TOLUIDINES, SOLID 6.1 Toluol, see 2,4-TOLUYLENEDIAMINE, SOLID 6.1 2,4-TOLUYLENEDIAMINE, SOLUTION 6.1 Toluylene diisocyanate, see 6.1 Tolylene diisocyanate, see 6.1 Tolylethylene, inhibited, see TORPEDOES with bursting charge TORPEDOES, LIQUID FUELLED with inert head TORPEDOES, LIQUID FUELLED with or without bursting charge Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 609 - TOXIC BY INHALATION LIQUID, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 6.1 TOXIC BY INHALATION LIQUID, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 6.1 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 6.1 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 6.1 TOXIC BY INHALATION LIQUID, CORROSIVE, FLAMMABLE, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m³ and saturated vapour concentration greater than or equal to 500 LC50 6.1 TOXIC BY INHALATION LIQUID, CORROSIVE, FLAMMABLE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m³ and saturated vapour concentration greater than or equal to 10 LC50 6.1 TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 6.1 TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 6.1 TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m³ and saturated vapour concentration greater than or equal to 500 LC50 6.1 TOXIC BY INHALATION LIQUID, FLAMMABLE, CORROSIVE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m³ and saturated vapour concentration greater than or equal to 10 LC50 6.1 TOXIC BY INHALATION LIQUID, OXIDIZING, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 6.1 TOXIC BY INHALATION LIQUID, OXIDIZING, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 6.1 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 6.1 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 6.1 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, FLAMMABLE, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m³ and saturated vapour concentration greater than or equal to 500 LC50 6.1 TOXIC BY INHALATION LIQUID, WATER-REACTIVE, FLAMMABLE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m³ and saturated vapour concentration greater than or equal to 10 LC50 6.1 TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S. 6.1 TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. 6.1 TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. 6.1 TOXIC LIQUID, INORGANIC, N.O.S. 6.1 TOXIC LIQUID, ORGANIC, N.O.S. 2810 6.1 TOXIC LIQUID, OXIDIZING, N.O.S. 6.1 TOXIC LIQUID, WATER- REACTIVE, N.O.S. 6.1 TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S. 6.1 TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. 6.1 TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. 6.1 Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 610 - TOXIC SOLID, INORGANIC, N.O.S. 6.1 TOXIC SOLID, ORGANIC, N.O.S. 6.1 TOXIC SOLID, OXIDIZING, N.O.S. 6.1 TOXIC SOLID, SELF-HEATING, N.O.S. 6.1 TOXIC SOLID, WATER- REACTIVE, N.O.S. 6.1 TOXINS, EXTRACTED FROM LIVING SOURCES, LIQUID, N.O.S. 6.1 TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S. 6.1 TRACERS FOR AMMUNITION Tremolite, see TRIALLYLAMINE TRIALLYL BORATE 6.1 TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 °C TRIAZINE PESTICIDE, LIQUID, TOXIC 6.1 TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23 °C 6.1 TRIAZINE PESTICIDE, SOLID, TOXIC 6.1 Tribromoborane, see TRIBUTYLAMINE 6.1 TRIBUTYLPHOSPHANE 4.2 Trichloroacetaldehyde, see 6.1 TRICHLOROACETIC ACID TRICHLOROACETIC ACID SOLUTION Trichlororaceticaldehyde, see 6.1 TRICHLOROACETYL CHLORIDE TRICHLOROBENZENES, LIQUID 6.1 TRICHLOROBUTENE 6.1 1,1,1-TRICHLOROETHANE 6.1 TRICHLOROETHYLENE 6.1 TRICHLOROISOCYANURIC ACID, DRY 5.1 Trichloronitromethane, see 6.1 TRICHLOROSILANE 4.3 1,3,5-Trichloro-s-triazine-2,4,6trione, see 5.1 2,4,6-Trichloro-1,3,5- triazine, see TRICRESYL PHOSPHATE with more than 3% ortho isomer 6.1 TRIETHYLAMINE Triethyl borate, see TRIETHYLENETETRAMINE Triethyl orthoformate, see TRIETHYL PHOSPHITE TRIFLUOROACETIC ACID TRIFLUOROACETYL CHLORIDE Trifluorobromomethane, see Trifluorochloroethane, see TRIFLUOROCHLORO- ETHYLENE, STABILIZED Trifluorochloromethane, see 1,1,1-TRIFLUOROETHANE TRIFLUOROMETHANE TRIFLUOROMETHANE, REFRIGERATED LIQUID 2-TRIFLUOROMETHYLANILINE 6.1 3-TRIFLUOROMETHYLANILINE 6.1 TRIISOBUTYLENE TRIISOPROPYL BORATE TRIMETHYLACETYL CHLORIDE 2438 6.1 TRIMETHYLAMINE, ANHYDROUS TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 50% trimethylamine, by mass 1,3,5-TRIMETHYLBENZENE TRIMETHYL BORATE TRIMETHYLCHLOROSILANE TRIMETHYLCYCLOHEXYL- AMINE Trimethylene chlorobromide, see 6.1 TRIMETHYLHEXA- METHYLENEDIAMINES TRIMETHYLHEXAMETHYLENE DIISOCYANATE 6.1 2,4,4-Trimethylpentene-1, see 2,4,4-Trimethylpentene-2, see TRIMETHYL PHOSPHITE TRINITROANILINE TRINITROANISOLE TRINITROBENZENE, dry or wetted with less than 30% water, by mass Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 611 - TRINITROBENZENE, WETTED with not less than 10% water, by mass 4.1 TRINITROBENZENE, WETTED with not less than 30% water, by mass 4.1 TRINITROBENZENE- SULPHONIC ACID TRINITROBENZOIC ACID, dry or wetted with less than 30% water, by mass TRINITROBENZOIC ACID, WETTED with not less than 10% water, by mass 4.1 TRINITROBENZOIC ACID, WETTED with not less than 30% water, by mass 4.1 TRINITROCHLOROBENZENE TRINITROCHLOROBENZENE WETTED with not less than 10% water, by mass 4.1 TRINITRO-m-CRESOL TRINITROFLUORENONE TRINITRONAPHTHALENE TRINITROPHENETOLE TRINITROPHENOL, dry or wetted with less than 30% water, by mass TRINITROPHENOL (PICRIC ACID), WETTED with not less than 30% water, by mass 4.1 TRINITROPHENOL WETTED with not less than 10% water, by mass 4.1 TRINITROPHENYL- METHYLNITRAMINE TRINITRORESORCINOL, dry or wetted with less than 20% water, or mixture of alcohol and water, by mass TRINITRORESORCINOL, WETTED with not less than 20% water, or mixture of alcohol and water, by mass TRINITROTOLUENE (TNT), dry or wetted with less than 30% water, by mass TRINITROTOLUENE AND HEXANITROSTILBENE MIXTURE TRINITROTOLUENE MIXTURE CONTAINING TRINITROBENZENE AND HEXANITROSTILBENE TRINITROTOLUENE AND TRINITROBENZENE MIXTURE TRINITROTOLUENE, WETTED with not less than 10% water, by mass 4.1 TRINITROTOLUENE, WETTED with not less than 30% water, by mass 4.1 TRIPROPYLAMINE TRIPROPYLENE TRIS-(1-AZIRIDINYL) PHOSPHINE OXIDE SOLUTION 6.1 TRITONAL Tropilidene, see TUNGSTEN HEXAFLUORIDE TURPENTINE TURPENTINE SUBSTITUTE UNDECANE UREA HYDROGEN PEROXIDE 5.1 UREA NITRATE, dry or wetted with less than 20% water, by mass UREA NITRATE, WETTED with not less than 10% water, by mass 4.1 UREA NITRATE, WETTED with not less than 20% water, by mass 4.1 Valeral, see VALERALDEHYDE n-Valeraldehyde, see Valeric aldehyde, see VALERYL CHLORIDE VANADIUM COMPOUND, N.O.S. 6.1 Vanadium (IV) oxide sulphate, see 6.1 Vanadium oxysulphate, see 6.1 VANADIUM OXYTRICHLORIDE VANADIUM PENTOXIDE, nonfused form 6.1 VANADIUM TETRACHLORIDE VANADIUM TRICHLORIDE VANADYL SULPHATE 6.1 Varnish, see Vehicle, flammable gas powered Not subject to ADR Vehicle, flammable liquid powered Not subject to ADR Vehicle, fuel cell, flammable gas powered Not subject to ADR Vehicle, fuel cell, flammable liquid powered Not subject to ADR Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 612 - Villiaumite, see 6.1 VINYL ACETATE, STABILIZED Vinylbenzene, see VINYL BROMIDE, STABILIZED VINYL BUTYRATE, STABILIZED VINYL CHLORIDE, STABILIZED VINYL CHLOROACETATE 6.1 VINYL ETHYL ETHER, STABILIZED VINYL FLUORIDE, STABILIZED VINYLIDENE CHLORIDE, STABILIZED VINYL ISOBUTYL ETHER, STABILIZED VINYL METHYL ETHER, STABILIZED VINYLPYRIDINES, STABILIZED 6.1 VINYLTOLUENES, STABILIZED VINYLTRICHLOROSILANE Warheads for guided missiles, see WARHEADS, ROCKET with burster or expelling charge WARHEADS, ROCKET with bursting charge WARHEADS, TORPEDO with bursting charge WATER-REACTIVE LIQUID, N.O.S. 4.3 WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. 4.3 WATER-REACTIVE LIQUID, TOXIC, N.O.S. 4.3 WATER-REACTIVE SOLID, N.O.S. 4.3 WATER-REACTIVE SOLID, CORROSIVE, N.O.S. 4.3 WATER-REACTIVE SOLID, FLAMMABLE, N.O.S. 4.3 WATER-REACTIVE SOLID, OXIDIZING, N.O.S. 4.3 Carriage prohibited WATER-REACTIVE SOLID, SELF-HEATING, N.O.S. 4.3 WATER-REACTIVE SOLID, TOXIC, N.O.S. 4.3 White arsenic, see 6.1 WHITE ASBESTOS (chrysotile, actinolite, anthophyllite, tremolite) White spirit, see WOOD PRESERVATIVES, LIQUID Wool waste, wet 4.2 Not subject to ADR XANTHATES 4.2 XENON XENON, REFRIGERATED LIQUID XYLENES XYLENOLS, LIQUID 6.1 XYLENOLS, SOLID 6.1 XYLIDINES, LIQUID 6.1 XYLIDINES, SOLID 6.1 Xylols, see XYLYL BROMIDE, LIQUID 6.1 XYLYL BROMIDE, SOLID 6.1 ZINC AMMONIUM NITRITE 5.1 ZINC ARSENATE 6.1 ZINC ARSENATE AND ZINC ARSENITE MIXTURE 6.1 ZINC ARSENITE 6.1 ZINC ASHES 4.3 Zinc bisulphite solution, see ZINC BROMATE 5.1 ZINC CHLORATE 5.1 ZINC CHLORIDE, ANHYDROUS ZINC CHLORIDE SOLUTION ZINC CYANIDE 6.1 ZINC DITHIONITE ZINC DUST 4.3 ZINC FLUOROSILICATE 6.1 Zinc hexafluorosilicate, see 6.1 ZINC HYDROSULPHITE, see ZINC NITRATE 5.1 ZINC PERMANGANATE 5.1 ZINC PEROXIDE 5.1 ZINC PHOSPHIDE 4.3 ZINC POWDER 4.3 ZINC RESINATE 4.1 Zinc selenate, see 4.1 Zinc selenite, see 4.1 Zinc silicofluoride, see 6.1 Copyright © United Nations, 2010. All rights reserved Name and description UN No. Class Remarks Name and description UN No. Class Remarks - 613 - ZIRCONIUM, DRY, coiled wire, finished metal sheets, strip (thinner than 254 microns but not thinner than 18 microns) 4.1 ZIRCONIUM, DRY, finished sheets, strip or coiled wire 4.2 ZIRCONIUM HYDRIDE 4.1 ZIRCONIUM NITRATE 5.1 ZIRCONIUM PICRAMATE, dry or wetted with less than 20% water, by mass ZIRCONIUM PICRAMATE, WETTED with not less than 20% water, by mass 4.1 ZIRCONIUM POWDER, DRY 4.2 ZIRCONIUM POWDER, WETTED with not less than 25% water 4.1 ZIRCONIUM SCRAP 4.2 ZIRCONIUM SUSPENDED IN A FLAMMABLE LIQUID ZIRCONIUM TETRACHLORIDE Copyright © United Nations, 2010. All rights reserved ECE/TRANS/215 (Vol.II) Volume II applicable as from 1 January 2011 Economic Commission for Europe Committee on Inland Transport UNITED NATIONS New York and Geneva, 2010 European Agreement Concerning the International Carriage of Dangerous Goods by Road Copyright © United Nations, 2010. All rights reserved NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory, city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries. ECE/TRANS/215 (Vol.II) Copyright  United Nations, 2010 All rights reserved. No part of this publication may, for sales purposes, be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the United Nations. UNITED NATIONS PUBLICATION Sales No.: E. 10.VIII.4 ISBN 978-92-1-139140-4 (complete set of 2 volumes) Volumes I and II not to be sold separately. Copyright © United Nations, 2010. All rights reserved - 1 - ANNEX A GENERAL PROVISIONS AND PROVISIONS CONCERNING DANGEROUS SUBSTANCES AND ARTICLES (cont'd) Copyright © United Nations, 2010. All rights reserved - 3 - PART 3 Dangerous goods list, special provisions and exemptions related to limited and excepted quantities (cont'd) Copyright © United Nations, 2010. All rights reserved - 5 - CHAPTER 3.3 SPECIAL PROVISIONS APPLICABLE TO CERTAIN ARTICLES OR SUBSTANCES 3.3.1 When Column (6) of Table A of Chapter 3.2 indicates that a special provision is relevant to a substance or article, the meaning and requirements of that special provision are as set forth below. Samples of new or existing explosive substances or articles may be carried as directed by the competent authorities (see 2.2.1.1.3) for purposes including: testing, classification, research and development, quality control, or as a commercial sample. Explosive samples which are not wetted or desensitized shall be limited to 10 kg in small packages as specified by the competent authorities. Explosive samples which are wetted or desensitized shall be limited to 25 kg. Even though this substance has a flammability hazard, it only exhibits such hazard under extreme fire conditions in confined areas. This substance is not subject to the requirements of ADR when in any other form. This substance is not subject to the requirements of ADR when coated. This substance is not subject to the requirements of ADR when it contains not more than 0.1% calcium carbide. This substance is not subject to the requirements of ADR when it contains less than 30% or not less than 90% silicon. When offered for carriage as pesticides, these substances shall be carried under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see 2.2.61.1.10 to 2.2.61.1.11.2). Antimony sulphides and oxides which contain not more than 0.5% of arsenic calculated on the total mass are not subject to the requirements of ADR. Ferricyanides and ferrocyanides are not subject to the requirements of ADR. The carriage of this substance, when it contains more than 20% hydrocyanic acid, is prohibited. These substances are not subject to the requirements of ADR when they contain not more than 50% magnesium. If the concentration is more than 72%, the carriage of this substance is prohibited. The technical name which shall supplement the proper shipping name shall be the ISO common name (see also ISO 1750:1981 "Pesticides and other agrochemicals - common names", as amended), other name listed in the WHO "Recommended Classification of Pesticides by Hazard and Guidelines to Classification" or the name of the active substance (see also 3.1.2.8.1 and 3.1.2.8.1.1). This substance is not subject to the requirements of ADR when it contains not more than 4% sodium hydroxide. Hydrogen peroxide aqueous solutions with less than 8% hydrogen peroxide are not subject to the requirements of ADR. Copyright © United Nations, 2010. All rights reserved - 6 - The carriage of ammonium nitrites and mixtures of an inorganic nitrite with an ammonium salt is prohibited. Nitrocellulose meeting the descriptions of UN No. 2556 or UN No. 2557 may be classified in Class 4.1. The carriage of chemically unstable mixtures is prohibited. Refrigerating machines include machines or other appliances which have been designed for the specific purpose of keeping food or other items at a low temperature in an internal compartment, and air conditioning units. Refrigerating machines and refrigerating machine components are not subject to the provisions of ADR if they contain less than 12 kg of gas in Class 2, group A or O according to 2.2.2.1.3, or if they contain less than 12 litres ammonia solution (UN No. 2672). The subsidiary risks, control and emergency temperatures if any, and the UN number (generic entry) for each of the currently assigned organic peroxide formulations are given in 2.2.52.4. Other inert material or inert material mixture may be used, provided this inert material has identical phlegmatizing properties. The phlegmatized substance shall be significantly less sensitive than dry PETN. The dihydrated sodium salt of dichloroisocyanuric acid is not subject to the requirements of ADR. p-Bromobenzyl cyanide is not subject to the requirements of ADR. Products which have undergone sufficient heat treatment so that they present no hazard during carriage are not subject to the requirements of ADR. Solvent extracted soya bean meal containing not more than 1.5% oil and 11% moisture, which is substantially free of flammable solvent, is not subject to the requirements of ADR. An aqueous solution containing not more than 24% alcohol by volume is not subject to the requirements of ADR. Alcoholic beverages of packing group III, when carried in receptacles of 250 litres or less, are not subject to the requirements of ADR. The classification of this substance will vary with particle size and packaging, but borderlines have not been experimentally determined. Appropriate classifications shall be made in accordance with 2.2.1. This entry applies only if it is demonstrated, on the basis of tests, that the substances when in contact with water are not combustible nor show a tendency to auto-ignition and that the mixture of gases evolved is not flammable. (Deleted) A substance mentioned by name in Table A of Chapter 3.2 shall not be carried under this entry. Substances carried under this entry may contain 20% or less nitrocellulose provided the nitrocellulose contains not more than 12.6% nitrogen (by dry mass). Asbestos which is immersed or fixed in a natural or artificial binder (such as cement, plastics, asphalt, resins or mineral ore) in such a way that no escape of hazardous quantities of respirable asbestos fibres can occur during carriage is not subject to the requirements of ADR. Manufactured articles containing asbestos and not meeting this provision are nevertheless not subject to the requirements of ADR when packed so Copyright © United Nations, 2010. All rights reserved - 7 - that no escape of hazardous quantities of respirable asbestos fibres can occur during carriage. Phthalic anhydride in the solid state and tetrahydrophthalic anhydrides, with not more than 0.05% maleic anhydride, are not subject to the requirements of ADR. Phthalic anhydride molten at a temperature above its flash-point, with not more than 0.05% maleic anhydride, shall be classified under UN No. 3256. For radioactive material with a subsidiary risk: (a) The packages shall be labelled with a label corresponding to each subsidiary risk exhibited by the material; corresponding placards shall be affixed to vehicles or containers in accordance with the relevant provisions of 5.3.1; (b) The radioactive material shall be allocated to packing groups I, II or III, as and if appropriate, by application of the grouping criteria provided in Part 2 corresponding to the nature of the predominant subsidiary risk. The description required in 5.4.1.2.5.1 (b) shall include a description of these subsidiary risks (e.g. "Subsidiary risk: 3, 6.1"), the name of the constituents which most predominantly contribute to this (these) subsidiary risk(s), and where applicable, the packing group. For packing, see also 4.1.9.1.5. Barium sulphate is not subject to the requirements of ADR. This designation shall be used only when no other appropriate designation exists in Table A of Chapter 3.2, and only with the approval of the competent authority of the country of origin (see 2.2.1.1.3). Packages containing this type of substance shall bear a label conforming to model No. 1 (see 5.2.2.2.2) unless the competent authority of the country of origin has permitted this label to be dispensed with for the specific packaging employed because test data have proved that the substance in this packaging does not exhibit explosive behaviour (see 5.2.2.1.9). The group of alkali metals includes lithium, sodium, potassium, rubidium and caesium. The group of alkaline earth metals includes magnesium, calcium, strontium and barium. In determining the ammonium nitrate content, all nitrate ions for which a molecular equivalent of ammonium ions is present in the mixture shall be calculated as ammonium nitrate. Cells and batteries offered for carriage are not subject to other provisions of ADR if they meet the following: (a) For a lithium metal or lithium alloy cell, the lithium content is not more than 1 g, and for a lithium ion cell, the Watt-hour rating is not more than 20 Wh; (b) For a lithium metal or lithium alloy battery the aggregate lithium content is not more than 2 g, and for a lithium ion battery, the Watt-hour rating is not more than 100 Wh. Lithium ion batteries subject to this provision shall be marked with the Watt-hour rating on the outside case; (c) Each cell or battery is of the type proved to meet the requirements of each test in the Manual of Tests and Criteria, Part III, sub-section 38.3; (d) Cells and batteries, except when installed in equipment, shall be packed in inner packagings that completely enclose the cell or battery. Cells and batteries shall Copyright © United Nations, 2010. All rights reserved - 8 - be protected so as to prevent short circuits. This includes protection against contact with conductive materials within the same packaging that could lead to a short circuit. The inner packagings shall be packed in strong outer packagings which conform to the provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.5; (e) Cells and batteries when installed in equipment shall be protected from damage and short circuit, and the equipment shall be equipped with an effective means of preventing accidental activation. When batteries are installed in equipment, the equipment shall be packed in strong outer packagings constructed of suitable material of adequate strength and design in relation to the packaging’s capacity and its intended use unless the battery is afforded equivalent protection by the equipment in which it is contained; (f) Except for packages containing button cell batteries installed in equipment (including circuit boards), or no more than four cells installed in equipment or no more than two batteries installed in equipment, each package shall be marked with the following: (i) an indication that the package contains "lithium metal" or "lithium ion" cells or batteries, as appropriate; (ii) an indication that the package shall be handled with care and that a flammability hazard exists if the package is damaged; (iii) an indication that special procedures shall be followed in the event the package is damaged, to include inspection and repacking if necessary; and (iv) a telephone number for additional information; (g) Each consignment of one or more packages marked in accordance with paragraph (f) shall be accompanied with a document including the following: (i) an indication that the package contains "lithium metal" or "lithium ion" cells or batteries, as appropriate; (ii) an indication that the package shall be handled with care and that a flammability hazard exists if the package is damaged; (iii) an indication that special procedures shall be followed in the event the package is damaged, to include inspection and repacking if necessary; and (iv) a telephone number for additional information; (h) Except when batteries are installed in equipment, each package shall be capable of withstanding a 1.2 m drop test in any orientation without damage to cells or batteries contained therein, without shifting of the contents so as to allow battery to battery (or cell to cell) contact and without release of contents; and (i) Except when batteries are installed in or packed with equipment, packages shall not exceed 30 kg gross mass. As used above and elsewhere in ADR, "lithium content" means the mass of lithium in the anode of a lithium metal or lithium alloy cell. Separate entries exist for lithium metal batteries and lithium ion batteries to facilitate the carriage of these batteries for specific modes of carriage and to enable the application of different emergency response actions. Copyright © United Nations, 2010. All rights reserved - 9 - Aerosol dispensers shall be provided with protection against inadvertent discharge. Aerosols with a capacity not exceeding 50 ml containing only non-toxic constituents are not subject to the requirements of ADR. Receptacles, small, with a capacity not exceeding 50 ml, containing only non-toxic constituents are not subject to the requirements of ADR. The control and emergency temperatures, if any, and the UN number (generic entry) for each of the currently assigned self-reactive substances are given in 2.2.41.4. Formulations which in laboratory testing neither detonate in the cavitated state nor deflagrate, which show no effect when heated under confinement and which exhibit no explosive power may be carried under this entry. The formulation must also be thermally stable (i.e. the SADT is 60 °C or higher for a 50 kg package). Formulations not meeting these criteria shall be carried under the provisions of Class 5.2, (see 2.2.52.4). Nitrocellulose solutions containing not more than 20% nitrocellulose may be carried as paint, perfumery products or printing ink, as applicable (see UN Nos. 1210, 1263, 1266, 3066, 3469 and 3470). Lead compounds which, when mixed in a ratio of 1:1000 with 0.07M hydrochloric acid and stirred for one hour at a temperature of 23 °C ± 2 °C, exhibit a solubility of 5% or less (see ISO 3711:1990 "Lead chromate pigments and lead chromate - molybdate pigments – Specifications and methods of test") are considered insoluble and are not subject to the requirements of ADR unless they meet the criteria for inclusion in another class. Lighters and lighter refills shall comply with the provisions of the country in which they were filled. They shall be provided with protection against inadvertent discharge. The liquid portion of the gas shall not exceed 85% of the capacity of the receptacle at 15 °C. The receptacles, including the closures, shall be capable of withstanding an internal pressure of twice the pressure of the liquefied petroleum gas at 55 °C. The valve mechanisms and ignition devices shall be securely sealed, taped or otherwise fastened or designed to prevent operation or leakage of the contents during carriage. Lighters shall not contain more than 10 g of liquefied petroleum gas. Lighter refills shall not contain more than 65 g of liquefied petroleum gas. NOTE: For waste lighters collected separately see Chapter 3.3, special provision 654. This entry shall not be used for polychlorinated biphenyls, liquid, UN No. 2315 and polychlorinated biphenyls, solid, UN No.3432. (Deleted) This entry shall not be used for UN No. 3155 PENTACHLOROPHENOL. Polymeric beads and moulding compounds may be made from polystyrene, poly(methyl methacrylate) or other polymeric material. The commercial grade of calcium nitrate fertilizer, when consisting mainly of a double salt (calcium nitrate and ammonium nitrate) containing not more than 10% ammonium nitrate and at least 12% water of crystallization, is not subject to the requirements of ADR. Toxins from plant, animal or bacterial sources which contain infectious substances, or toxins that are contained in infectious substances, shall be classified in Class 6.2. Copyright © United Nations, 2010. All rights reserved - 10 - This entry only applies to the technically pure substance or to formulations derived from it having an SADT higher than 75 °C and therefore does not apply to formulations which are self-reactive substances (for self-reactive substances, see 2.2.41.4). Homogeneous mixtures containing not more than 35% by mass of azodicarbonamide and at least 65% of inert substance are not subject to the requirements of ADR unless criteria of other classes are met. Mixtures of solids which are not subject to the requirements of ADR and flammable liquids may be carried under this entry without first applying the classification criteria of Class 4.1, provided there is no free liquid visible at the time the substance is loaded or at the time the packaging, vehicle or container is closed. Sealed packets and articles containing less than 10 ml of a packing group II or III flammable liquid absorbed into a solid material are not subject to ADR provided there is no free liquid in the packet or article. Mixtures of solids which are not subject to the requirements of ADR and toxic liquids may be carried under this entry without first applying the classification criteria of Class 6.1, provided there is no free liquid visible at the time the substance is loaded or at the time the packaging, vehicle or container is closed. This entry shall not be used for solids containing a packing group I liquid. Mixtures of solids which are not subject to the requirements of ADR and corrosive liquids may be carried under this entry without first applying the classification criteria of Class 8, provided there is no free liquid visible at the time the substance is loaded or at the time the packaging, vehicle or container is closed. Genetically modified microorganisms (GMMOs) and genetically modified organisms (GMOs) packed and marked in accordance with packing instruction P904 of 4.1.4.1 are not subject to any other requirements of ADR. If GMMOs or GMOs meet the criteria for inclusion in Class 6.1 or 6.2 (see 2.2.61.1 and 2.2.62.1) the requirements in ADR for the carriage of toxic substances or infectious substances apply. Only the technical name of the flammable liquid component of this solution or mixture shall be shown in parentheses immediately following the proper shipping name. Substances included under this entry shall not be of packing group I. Unless it can be demonstrated by testing that the sensitivity of the substance in its frozen state is no greater than in its liquid state, the substance shall remain liquid during normal transport conditions. It shall not freeze at temperatures above -15 °C. Fire extinguishers under this entry may include installed actuating cartridges (cartridges, power device of classification code 1.4C or 1.4S), without changing the classification of Class 2, group A or O according to 2.2.2.1.3 provided the total quantity of deflagrating (propellant) explosives does not exceed 3.2 g per extinguishing unit. Formulations of this substance containing not less than 30% non-volatile, nonflammable phlegmatizer are not subject to the requirements of ADR. When phlegmatized with water and inorganic inert material the content of urea nitrate may not exceed 75% by mass and the mixture shall not be capable of being detonated by the Series 1, type (a), test in the Manual of Tests and Criteria, Part 1. Mixtures not meeting the criteria for flammable gases (see 2.2.2.1.5) shall be carried under UN No. 3163. Copyright © United Nations, 2010. All rights reserved - 11 - This entry applies to cells and batteries containing lithium in any form, including lithium polymer and lithium ion cells and batteries. Lithium cells and batteries may be carried under this entry if they meet the following provisions: (a) Each cell or battery is of the type proved to meet the requirements of each test of the Manual of Tests and Criteria, Part III, sub-section 38.3; (b) Each cell and battery incorporates a safety venting device or is designed to preclude a violent rupture under normal conditions of carriage; (c) Each cell and battery is equipped with an effective means of preventing external short circuits; (d) Each battery containing cells or series of cells connected in parallel is equipped with effective means as necessary to prevent dangerous reverse current flow (e.g. diodes, fuses, etc.). This entry applies to articles which contain Class 1 explosive substances and which may also contain dangerous goods of other classes. These articles are used as life-saving vehicle air bag inflators or air bag modules or seat-belt pretensioners. Polyester resin kits consist of two components: a base material (Class 3, packing group II or III) and an activator (organic peroxide). The organic peroxide shall be type D, E or F, not requiring temperature control. Packing group shall be II or III, according to the criteria for Class 3, applied to the base material. The quantity limit referred to in Column (7a) of Table A of Chapter 3.2 applies to the base material. The membrane filters, including paper separators, coating or backing materials, etc., that are present in carriage, shall not be liable to propagate a detonation as tested by one of the tests described in the Manual of Tests and Criteria, Part I, Test series 1 (a). In addition the competent authority may determine, on the basis of the results of suitable burning rate tests taking account of the standard tests in the Manual of Tests and Criteria, Part III, sub-section 33.2.1, that nitrocellulose membrane filters in the form in which they are to be carried are not subject to the requirements applicable to flammable solids in Class 4.1. (a) Batteries can be considered as non-spillable provided that they are capable of withstanding the vibration and pressure differential tests given below, without leakage of battery fluid. Vibration test: The battery is rigidly clamped to the platform of a vibration machine and a simple harmonic motion having an amplitude of 0.8 mm (1.6 mm maximum total excursion) is applied. The frequency is varied at the rate of 1 Hz/min between the limits of 10 Hz and 55 Hz. The entire range of frequencies and return is traversed in 95 ± 5 minutes for each mounting position (direction of vibration) of the battery. The battery is tested in three mutually perpendicular positions (to include testing with fill openings and vents, if any, in an inverted position) for equal time periods. Pressure differential test: Following the vibration test, the battery is stored for six hours at 24 °C ± 4 °C while subjected to a pressure differential of at least 88 kPa. The battery is tested in three mutually perpendicular positions (to include testing with fill openings and vents, if any, in an inverted position) for at least six hours in each position. (b) Non-spillable batteries are not subject to the requirements of ADR if, at a temperature of 55 °C, the electrolyte will not flow from a ruptured or cracked case and there is no free liquid to flow and if, as packaged for carriage, the terminals are protected from short circuit. Copyright © United Nations, 2010. All rights reserved - 12 - Batteries or cells shall not contain dangerous substances other than sodium, sulphur and/or polysulphides. Batteries or cells shall not be offered for carriage at a temperature such that liquid elemental sodium is present in the battery or cell unless approved and under the conditions established by the competent authority of the country of origin. If the country of origin is not a Contracting Party to ADR, the approval and conditions of carriage shall be recognized by the competent authority of the first country Contracting Party to ADR reached by the consignment. Cells shall consist of hermetically sealed metal casings which fully enclose the dangerous substances and which are so constructed and closed as to prevent the release of the dangerous substances under normal conditions of carriage. Batteries shall consist of cells secured within and fully enclosed by a metal casing so constructed and closed as to prevent the release of the dangerous substances under normal conditions of carriage. The formulation shall be prepared so that it remains homogeneous and does not separate during carriage. Formulations with low nitrocellulose contents and not showing dangerous properties when tested for their liability to detonate, deflagrate or explode when heated under defined confinement by tests of Test series 1 (a), 2 (b) and 2 (c) respectively in the Manual of Tests and Criteria, Part I and not being a flammable solid when tested in accordance with test No. 1 in the Manual of Tests and Criteria, Part III, sub-section 33.2.1.4 (chips, if necessary, crushed and sieved to a particle size of less than 1.25 mm) are not subject to the requirements of ADR. Sulphur is not subject to the requirements of ADR when it has been formed to a specific shape (e.g. prills, granules, pellets, pastilles or flakes). Gasoline, motor spirit and petrol for use in spark-ignition engines (e.g. in automobiles, stationary engines and other engines) shall be assigned to this entry regardless of variations in volatility. This entry includes e.g. aluminium dross, aluminium skimmings, spent cathodes, spent potliner, and aluminium salt slags. Alcoholic beverages containing more than 24% alcohol but not more than 70% by volume, when carried as part of the manufacturing process, may be carried in wooden barrels with a capacity of more than 250 litres and not more than 500 litres meeting the general requirements of 4.1.1, as appropriate, on the following conditions: (a) The wooden barrels shall be checked and tightened before filling; (b) Sufficient ullage (not less than 3%) shall be left to allow for the expansion of the liquid; (c) The wooden barrels shall be carried with the bungholes pointing upwards; (d) The wooden barrels shall be carried in containers meeting the requirements of the CSC. Each wooden barrel shall be secured in custom-made cradles and be wedged by appropriate means to prevent it from being displaced in any way during carriage. Ferrocerium, stabilized against corrosion, with a minimum iron content of 10% is not subject to the requirements of ADR. This entry may only be used for samples of chemicals taken for analysis in connection with the implementation of the Convention on the Prohibition of the Development, Production, Stockpiling and Use of Chemical Weapons and on their Destruction. The carriage of substances under this entry shall be in accordance with the chain of custody and security procedures specified by the Organisation for the Prohibition of Chemical Weapons. Copyright © United Nations, 2010. All rights reserved - 13 - The chemical sample may only be carried providing prior approval has been granted by the competent authority or the Director General of the Organisation for the Prohibition of Chemical Weapons and providing the sample complies with the following provisions: (a) It shall be packed according to packing instruction 623 in the ICAO Technical Instructions (see S-3-8 of the Supplement); and (b) During carriage, a copy of the document of approval for transport, showing the quantity limitations and the packing provisions shall be attached to the transport document. The entry CHEMICAL KIT or FIRST AID KIT is intended to apply to boxes, cases etc. containing small quantities of various dangerous goods which are used for example for medical, analytical or testing or repair purposes. Such kits may not contain dangerous goods for which the quantity "0"has been indicated in Column (7a) of Table A of Chapter 3.2. Components shall not react dangerously (see "dangerous reaction" in 1.2.1). The total quantity of dangerous goods in any one kit shall not exceed either 1 l or 1 kg. The packing group assigned to the kit as a whole shall be the most stringent packing group assigned to any individual substance in the kit. Kits which are carried on board vehicles for first-aid or operating purposes are not subject to the requirements of ADR. Chemical kits and first aid kits containing dangerous goods in inner packagings which do not exceed the quantity limits for limited quantities applicable to individual substances as specified in Column (7a) of Table A of Chapter 3.2 may be carried in accordance with Chapter 3.4. Provided the ammonium nitrate remains in solution under all conditions of carriage, aqueous solutions of ammonium nitrate, with not more than 0.2% combustible material, in a concentration not exceeding 80%, are not subject to the requirements of ADR. This substance, when containing less alcohol, water or phlegmatizer than specified, shall not be carried unless specifically authorized by the competent authority (see 2.2.1.1). Any explosives, blasting, type C containing chlorates shall be segregated from explosives containing ammonium nitrate or other ammonium salts. Aqueous solutions of Class 5.1 inorganic solid nitrate substances are considered as not meeting the criteria of Class 5.1 if the concentration of the substances in solution at the minimum temperature encountered during carriage is not greater than 80% of the saturation limit. Lactose or glucose or similar materials, may be used as a phlegmatizer provided that the substance contains not less than 90%, by mass, of phlegmatizer. The competent authority may authorize these mixtures to be classified in Class 4.1 on the basis of a test Series 6(c) of Section 16 of Part I of the Manual of Tests and Criteria on at least three packages as prepared for carriage. Mixtures containing at least 98%, by mass, of phlegmatizer are not subject to the requirements of ADR. Packages containing mixtures with not less than 90%, by mass, of phlegmatizer need not bear a label conforming to model No. 6.1. This substance shall not be carried under the provisions of Class 4.1 unless specifically authorized by the competent authority (see UN No. 0143). Copyright © United Nations, 2010. All rights reserved - 14 - Maneb and maneb preparations stabilized against self-heating need not be classified in Class 4.2 when it can be demonstrated by testing that a cubic volume of 1 m3 of substance does not self-ignite and that the temperature at the centre of the sample does not exceed 200 °C, when the sample is maintained at a temperature of not less than 75 °C ± 2 °C for a period of 24 hours. The provisions of 3.1.2.8 apply. These substances shall not be classified and carried unless authorized by the competent authority on the basis of results from Series 2 tests and a Series 6(c) test of Part I of the Manual of Tests and Criteria on packages as prepared for carriage (see 2.2.1.1). The competent authority shall assign the packing group on the basis of 2.2.3 criteria and the package type used for the Series 6(c) test. The substance is assigned to this classification or packing group based on human experience rather than the strict application of classification criteria set out in ADR. This entry applies to articles which are used as life-saving vehicle air bag inflators, or air bag modules or seat-belt pretensioners and which contain dangerous goods of Class 1 or dangerous goods of other classes and when carried as component parts and when these articles as presented for carriage have been tested in accordance with Test series 6 (c) of Part I of the Manual of Tests and Criteria, with no explosion of the device, no fragmentation of device casing or pressure vessel, and no projection hazard nor thermal effect which would significantly hinder fire-fighting or other emergency response efforts in the immediate vicinity. (Deleted) Articles, containing gas, intended to function as shock absorbers, including impact energy-absorbing devices, or pneumatic springs are not subject to the requirements of ADR provided: (a) Each article has a gas space capacity not exceeding 1.6 litres and a charge pressure not exceeding 280 bar where the product of the capacity (litres) and charge pressure (bars) does not exceed 80 (i.e. 0.5 litres gas space and 160 bar charge pressure, 1 litre gas space and 80 bar charge pressure, 1.6 litres gas space and 50 bar charge pressure, 0.28 litres gas space and 280 bar charge pressure); (b) Each article has a minimum burst pressure of 4 times the charge pressure at 20 °C for products not exceeding 0.5 litres gas space capacity and 5 times charge pressure for products greater than 0.5 litres gas space capacity; (c) Each article is manufactured from material which will not fragment upon rupture; (d) Each article is manufactured in accordance with a quality assurance standard acceptable to the competent authority; and (e) The design type has been subjected to a fire test demonstrating that the article relieves its pressure by means of a fire degradable seal or other pressure relief device, such that the article will not fragment and that the article does not rocket. See also 1.1.3.2 (d) for equipment used for the operation of the vehicle. An oxygen generator, chemical, containing oxidizing substances shall meet the following conditions: (a) The generator when containing an explosive actuating device shall only be carried under this entry when excluded from Class 1 in accordance with the NOTE under paragraph 2.2.1.1.1 (b); Copyright © United Nations, 2010. All rights reserved - 15 - (b) The generator, without its packaging, shall be capable of withstanding a 1.8 m drop test onto a rigid, non-resilient, flat and horizontal surface, in the position most likely to cause damage, without loss of its contents and without actuation; (c) When a generator is equipped with an actuating device, it shall have at least two positive means of preventing unintentional actuation. Nitrocellulose membrane filters covered by this entry, each with a mass not exceeding 0.5 g, are not subject to the requirements of ADR when contained individually in an article or a sealed packet. These substances shall not be classified and carried unless authorized by the competent authority on the basis of results from Series 2 tests and a Series 6(c) test of Part I of the Manual of tests and Criteria on packages as prepared for carriage (see 2.2.1.1). Air bag inflators, air bag modules or seat-belt pretensioners installed in conveyances or in completed conveyance components such as steering columns, door panels, seats, etc. are not subject to the requirements of ADR. When this radioactive material meets the definitions and criteria of other classes as defined in Part 2, it shall be classified in accordance with the following: (a) Where the substance meets the criteria for dangerous goods in excepted quantities as set out in Chapter 3.5, the packagings shall be in accordance with 3.5.2 and meet the testing requirements of 3.5.3. All other requirements applicable to radioactive material, excepted packages as set out in 1.7.1.5 shall apply without reference to the other class; (b) Where the quantity exceeds the limits specified in 3.5.1.2 the substance shall be classified in accordance with the predominant subsidiary risk. The transport document shall describe the substance with the UN number and proper shipping name applicable to the other class supplemented with the name applicable to the radioactive excepted package according to Column (2) of Table A of Chapter 3.2, and the substance shall be carried in accordance with the provisions applicable to that UN number. An example of the information shown on the transport document is: "UN 1993, Flammable liquid, n.o.s. (ethanol and toluene mixture), Radioactive material, excepted package – limited quantity of material, 3, PG II". In addition, the requirements of 2.2.7.2.4.1 shall apply; (c) The provisions of Chapter 3.4 for the carriage of dangerous goods packed in limited quantities shall not apply to substances classified in accordance with sub-paragraph (b); (d) When the substance meets a special provision that exempts this substance from all dangerous goods provisions of the other classes it shall be classified in accordance with the applicable UN number of Class 7 and all requirements specified in 1.7.1.5 shall apply. Flammable liquefied gases shall be contained within refrigerating machine components. These components shall be designed and tested to at least three times the working pressure of the machinery. The refrigerating machines shall be designed and constructed to contain the liquefied gas and preclude the risk of bursting or cracking of the pressure retaining components during normal conditions of carriage. Copyright © United Nations, 2010. All rights reserved - 16 - Refrigerating machines and refrigerating-machine components are not subject to the requirements of ADR if they contain less than 12 kg of gas. (Deleted) The following definitions apply to matches: (a) Fusee matches are matches the heads of which are prepared with a frictionsensitive igniter composition and a pyrotechnic composition which burns with little or no flame, but with intense heat; (b) Safety matches are matches which are combined with or attached to the box, book or card that can be ignited by friction only on a prepared surface; (c) Strike anywhere matches are matches that can be ignited by friction on a solid surface; (d) Wax Vesta matches are matches that can be ignited by friction either on a prepared surface or on a solid surface. Batteries need not be individually marked and labelled if the pallet bears the appropriate mark and label. These entries apply to life-saving appliances such as life rafts, personal flotation devices and self-inflating slides. UN No. 2990 applies to self-inflating appliances and UN No. 3072 applies to life-saving appliances that are not self-inflating. Life-saving appliances may contain: (a) Signal devices (Class 1) which may include smoke and illumination signal flares packed in packagings that prevent them from being inadvertently activated; (b) For UN No. 2990 only, cartridges, power device of Division 1.4, compatibility group S, may be contained for purposes of the self-inflating mechanism and provided that the quantity of explosives per appliance does not exceed 3.2 g; (c) Class 2 compressed gases, group A or O, according to 2.2.2.1.3; (d) Electric storage batteries (Class 8) and lithium batteries (Class 9); (e) First aid kits or repair kits containing small quantities of dangerous goods (e.g.: substances of Class 3, 4.1, 5.2, 8 or 9); or (f) "Strike anywhere" matches packed in packagings that prevent them from being inadvertently activated. (Deleted) Fish meal or fish scrap shall not be loaded if the temperature at the time of loading exceeds 35 °C or 5 °C above the ambient temperature whichever is higher. Fumigated cargo transport units containing no other dangerous goods are only subject to the provisions of 5.5.2. Receptacles shall be assigned to the classification code of the gas or mixture of gases contained therein determined in accordance with the provisions of section 2.2.2. This entry may only be used for the transport of non-activated batteries which contain dry potassium hydroxide and which are intended to be activated prior to use by addition of an appropriate amount of water to the individual cells. These substances are not subject to the requirements of ADR when in concentrations of not more than 50 mg/kg. Copyright © United Nations, 2010. All rights reserved - 17 - This entry may only be used for substances that do not exhibit explosive properties of Class 1 when tested in accordance to Test Series 1 and 2 of Class 1 (see Manual of Tests and Criteria, Part I). This entry may only be used for uniform mixtures containing ammonium nitrate as the main ingredient within the following composition limits: (a) Not less than 90% ammonium nitrate with not more than 0.2% total combustible/organic material calculated as carbon and with added matter, if any, which is inorganic and inert towards ammonium nitrate; or (b) Less than 90% but more than 70% ammonium nitrate with other inorganic materials or more than 80% but less than 90% ammonium nitrate mixed with calcium carbonate and/or dolomite and/or mineral calcium sulphate and not more than 0.4% total combustible/organic material calculated as carbon; or (c) Nitrogen type ammonium nitrate based fertilizers containing mixtures of ammonium nitrate and ammonium sulphate with more than 45% but less than 70% ammonium nitrate and not more than 0.4% total combustible/organic material calculated as carbon such that the sum of the percentage compositions of ammonium nitrate and ammonium sulphate exceeds 70%. This entry applies to non sensitized emulsions, suspensions and gels consisting primarily of a mixture of ammonium nitrate and fuel, intended to produce a Type E blasting explosive only after further processing prior to use. The mixture for emulsions typically has the following composition: 60-85% ammonium nitrate, 5-30% water, 2-8% fuel, 0.5-4% emulsifier agent, 0-10% soluble flame suppressants, and trace additives. Other inorganic nitrate salts may replace part of the ammonium nitrate. The mixture for suspensions and gels typically has the following composition: 60- 85% ammonium nitrate, 0-5% sodium or potassium perchlorate, 0-17% hexamine nitrate or monomethylamine nitrate, 5-30% water, 2-15% fuel, 0.5-4% thickening agent, 0-10% soluble flame suppressants, and trace additives. Other inorganic nitrate salts may replace part of the ammonium nitrate. Substances shall satisfactorily pass Test Series 8 of the Manual of Tests and Criteria, Part I, Section 18 and be approved by the competent authority. The testing requirements in sub-section 38.3 of the Manual of Tests and Criteria do not apply to production runs consisting of not more than 100 cells and batteries, or to pre-production prototypes of cells and batteries when these prototypes are carried for testing, if: (a) the cells and batteries are carried in an outer packaging that is a metal, plastics or plywood drum or a metal, plastics or wooden box and that meets the criteria for packing group I; and (b) each cell and battery is individually packed in an inner packaging inside an outer packaging and is surrounded by cushioning material that is noncombustible, and non-conductive. Substances shall not be carried under this entry unless approved by the competent authority on the basis of the results of appropriate tests according to Part I of the Manual of Tests and Criteria. Packaging shall ensure that the percentage of diluent does not fall below that stated in the competent authority approval, at any time during carriage. Copyright © United Nations, 2010. All rights reserved - 18 - (Reserved) (Deleted) (a) These substances are liable to exothermic decomposition at elevated temperatures. Decomposition can be initiated by heat or by impurities (e.g. powdered metals (iron, manganese, cobalt, magnesium) and their compounds); (b) During the course of carriage, these substances shall be shaded from direct sunlight and all sources of heat and be placed in adequately ventilated areas. This entry shall not be used for Class 6.1 substances which meet the inhalation toxicity criteria for packing group I described in 2.2.61.1.8. This entry applies only to calcium hypochlorite, dry, when carried in non friable tablet form. "Fissile-excepted" applies only to those packages complying with 6.4.11.2. For the purposes of documentation, the proper shipping name shall be supplemented with the technical name (see 3.1.2.8). When the infectious substances to be carried are unknown, but suspected of meeting the criteria for inclusion in Category A and assignment to UN No. 2814 or 2900, the words "suspected Category A infectious substance" shall be shown, in parentheses, following the proper shipping name on the transport document. Substances packed and packages which are marked in accordance with packing instruction P650 are not subject to any other requirements of ADR. (Deleted) These storage systems shall always be considered as containing hydrogen. When carried in non-friable tablet form, these goods are assigned to packing group III. (Reserved) This substance needs to be stabilized when in concentrations of not more than 99%. In the case of non-fissile or fissile excepted uranium hexafluoride, the material shall be classified under UN No. 2978. In the case of fissile uranium hexafluoride, the material shall be classified under UN No. 2977. 327 Waste aerosols consigned in accordance with 5.4.1.1.3 may be carried under this entry for the purposes of reprocessing or disposal. They need not be protected against inadvertent discharge provided that measures to prevent dangerous build up of pressure and dangerous atmospheres are addressed. Waste aerosols, other than those leaking or severely deformed, shall be packed in accordance with packing instruction P003 and special provision PP87, or packing instruction LP02 and special packing provision L2. Leaking or severely deformed aerosols shall be carried in salvage packagings provided appropriate measures are taken to ensure there is no dangerous build up of pressure. Copyright © United Nations, 2010. All rights reserved - 19 - NOTE: For maritime carriage, waste aerosols shall not be carried in closed containers. 328 This entry applies to fuel cell cartridges including when contained in equipment or packed with equipment. Fuel cell cartridges installed in or integral to a fuel cell system are regarded as contained in equipment. Fuel cell cartridge means an article that stores fuel for discharge into the fuel cell through (a) valve(s) that control(s) the discharge of fuel into the fuel cell. Fuel cell cartridges, including when contained in equipment, shall be designed and constructed to prevent fuel leakage under normal conditions of carriage. Fuel cell cartridge design types using liquids as fuels shall pass an internal pressure test at a pressure of 100 kPa (gauge) without leakage. Except for fuel cell cartridges containing hydrogen in metal hydride which shall be in compliance with special provision 339, each fuel cell cartridge design type shall be shown to pass a 1.2 meter drop test onto an unyielding surface in the orientation most likely to result in failure of the containment system with no loss of contents. (Reserved) 330 (Deleted) 331 (Reserved) Magnesium nitrate hexahydrate is not subject to the requirements of ADR. Ethanol and gasoline, motor spirit or petrol mixtures for use in spark-ignition engines (e.g. in automobiles, stationary engines and other engines) shall be assigned to this entry regardless of variations in volatility. A fuel cell cartridge may contain an activator provided it is fitted with two independent means of preventing unintended mixing with the fuel during carriage. Mixtures of solids which are not subject to the requirements of ADR and environmentally hazardous liquids or solids shall be classified as UN 3077 and may be carried under this entry provided there is no free liquid visible at the time the substance is loaded or at the time the packaging or vehicle or container is closed. Each vehicle or container shall be leakproof when used for carriage in bulk. If free liquid is visible at the time the mixture is loaded or at the time the packaging or vehicle or container is closed, the mixture shall be classified as UN 3082. Sealed packets and articles containing less than 10 ml of an environmentally hazardous liquid, absorbed into a solid material but with no free liquid in the packet or article, or containing less than 10 g of an environmentally hazardous solid, are not subject to the requirements of ADR. A single package of non-combustible solid LSA-II or LSA-III material, if carried by air, shall not contain an activity greater than 3 000 A2. Type B(U) and Type B(M) packages, if carried by air, shall not contain activities greater than the following: (a) For low dispersible radioactive material: as authorized for the package design as specified in the certificate of approval; Copyright © United Nations, 2010. All rights reserved - 20 - (b) For special form radioactive material: 3 000 A1 or 100 000 A2, whichever is the lower; or (c) For all other radioactive material: 3 000 A2. Each fuel cell cartridge carried under this entry and designed to contain a liquefied flammable gas shall: (a) Be capable of withstanding, without leakage or bursting, a pressure of at least two times the equilibrium pressure of the contents at 55 ºC; (b) Not contain more than 200 ml of liquefied flammable gas with a vapour pressure not exceeding 1 000 kPa at 55 °C; and (c) Pass the hot water bath test prescribed in 6.2.6.3.1. Fuel cell cartridges containing hydrogen in a metal hydride carried under this entry shall have a water capacity less than or equal to 120 ml. The pressure in the fuel cell cartridge shall not exceed 5 MPa at 55 °C. The design type shall withstand, without leaking or bursting, a pressure of twice the design pressure of the cartridge at 55 °C or 200 kPa more than the design pressure of the cartridge at 55 °C, whichever is greater. The pressure at which this test is conducted is referred to in the drop test and the hydrogen cycling test as the "minimum shell burst pressure". Fuel cell cartridges shall be filled in accordance with procedures provided by the manufacturer. The manufacturer shall provide the following information with each fuel cell cartridge: (a) Inspection procedures to be carried out before initial filling and before refilling of the fuel cell cartridge; (b) Safety precautions and potential hazards to be aware of; (c) Method for determining when the rated capacity has been achieved; (d) Minimum and maximum pressure range; (e) Minimum and maximum temperature range; and (f) Any other requirements to be met for initial filling and refilling including the type of equipment to be used for initial filling and refilling. The fuel cell cartridges shall be designed and constructed to prevent fuel leakage under normal conditions of carriage. Each cartridge design type, including cartridges integral to a fuel cell, shall be subjected to and shall pass the following tests: Drop test A 1.8 metre drop test onto an unyielding surface in four different orientations: (a) Vertically, on the end containing the shut-off valve assembly; (b) Vertically, on the end opposite to the shut-off valve assembly; Copyright © United Nations, 2010. All rights reserved - 21 - (c) Horizontally, onto a steel apex with a diameter of 38 mm, with the steel apex in the upward position; and (d) At a 45° angle on the end containing the shut-off valve assembly. There shall be no leakage, determined by using a soap bubble solution or other equivalent means on all possible leak locations, when the cartridge is charged to its rated charging pressure. The fuel cell cartridge shall then be hydrostatically pressurized to destruction. The recorded burst pressure shall exceed 85% of the minimum shell burst pressure. Fire test A fuel cell cartridge filled to rated capacity with hydrogen shall be subjected to a fire engulfment test. The cartridge design, which may include a vent feature integral to it, is deemed to have passed the fire test if: (a) The internal pressure vents to zero gauge pressure without rupture of the cartridge; or (b) The cartridge withstands the fire for a minimum of 20 minutes without rupture. Hydrogen cycling test This test is intended to ensure that a fuel cell cartridge design stress limits are not exceeded during use. The fuel cell cartridge shall be cycled from not more than 5% rated hydrogen capacity to not less than 95% rated hydrogen capacity and back to not more than 5% rated hydrogen capacity. The rated charging pressure shall be used for charging and temperatures shall be held within the operating temperature range. The cycling shall be continued for at least 100 cycles. Following the cycling test, the fuel cell cartridge shall be charged and the water volume displaced by the cartridge shall be measured. The cartridge design is deemed to have passed the hydrogen cycling test if the water volume displaced by the cycled cartridge does not exceed the water volume displaced by an uncycled cartridge charged to 95% rated capacity and pressurized to 75% of its minimum shell burst pressure. Production leak test Each fuel cell cartridge shall be tested for leaks at 15 °C ± 5 °C, while pressurized to its rated charging pressure. There shall be no leakage, determined by using a soap bubble solution or other equivalent means on all possible leak locations. Each fuel cell cartridge shall be permanently marked with the following information: (a) The rated charging pressure in MPa; (b) The manufacturer's serial number of the fuel cell cartridges or unique identification number; and (c) The date of expiry based on the maximum service life (year in four digits; month in two digits). Copyright © United Nations, 2010. All rights reserved - 22 - Chemical kits, first aid kits and polyester resin kits containing dangerous substances in inner packagings which do not exceed the quantity limits for excepted quantities applicable to individual substances as specified in column (7b) of Table A of Chapter 3.2, may be carried in accordance with Chapter 3.5. Class 5.2 substances, although not individually authorized as excepted quantities in column (7b) of Table A of Chapter 3.2, are authorized in such kits and are assigned Code E2 (see 3.5.1.2). (Reserved) 342 Glass inner receptacles (such as ampoules or capsules) intended only for use in sterilization devices, when containing less than 30 ml of ethylene oxide per inner packaging with not more than 300 ml per outer packaging, may be carried in accordance with the provisions in Chapter 3.5, irrespective of the indication of "E0" in column (7b) of Table A of Chapter 3.2 provided that: (a) After filling, each glass inner receptacle has been determined to be leak-tight by placing the glass inner receptacle in a hot water bath at a temperature, and for a period of time, sufficient to ensure that an internal pressure equal to the vapour pressure of ethylene oxide at 55 °C is achieved. Any glass inner receptacle showing evidence of leakage, distortion or other defect under this test shall not be carried under the terms of this special provision; (b) In addition to the packaging required by 3.5.2, each glass inner receptacle is placed in a sealed plastics bag compatible with ethylene oxide and capable of containing the contents in the event of breakage or leakage of the glass inner receptacle; and (c) Each glass inner receptacle is protected by a means of preventing puncture of the plastics bag (e.g. sleeves or cushioning) in the event of damage to the packaging (e.g. by crushing). This entry applies to crude oil containing hydrogen sulphide in sufficient concentration that vapours evolved from the crude oil can present an inhalation hazard. The packing group assigned shall be determined by the flammability hazard and inhalation hazard, in accordance with the degree of danger presented. The provisions of 6.2.6 shall be met. This gas contained in open cryogenic receptacles with a maximum capacity of 1 litre constructed with glass double walls having the space between the inner and outer wall evacuated (vacuum insulated) is not subject to ADR provided each receptacle is carried in an outer packaging with suitable cushioning or absorbent materials to protect it from impact damage. Open cryogenic receptacles conforming to the requirements of packing instruction P203 of 4.1.4.1 and containing no dangerous goods except for UN No. 1977 nitrogen, refrigerated liquid, which is fully absorbed in a porous material are not subject to any other requirements of ADR. This entry shall only be used if the results of Test series 6 (d) of Part I of the Manual of Tests and Criteria have demonstrated that any hazardous effects arising from functioning are confined within the package. Batteries manufactured after 31 December 2011 shall be marked with the Watt-hour rating on the outside case. Copyright © United Nations, 2010. All rights reserved - 23 - Mixtures of a hypochlorite with an ammonium salt are not to be accepted for carriage. UN No. 1791 hypochlorite solution is a substance of Class 8. Ammonium bromate and its aqueous solutions and mixtures of a bromate with an ammonium salt are not to be accepted for carriage. Ammonium chlorate and its aqueous solutions and mixtures of a chlorate with an ammonium salt are not to be accepted for carriage. Ammonium chlorite and its aqueous solutions and mixtures of a chlorite with an ammonium salt are not to be accepted for carriage. Ammonium permanganate and its aqueous solutions and mixtures of a permanganate with an ammonium salt are not to be accepted for carriage. This substance is toxic by inhalation. Oxygen cylinders for emergency use carried under this entry may include installed actuating cartridges (cartridges, power device of Division 1.4, Compatibility Group C or S), without changing the classification in Class 2 provided the total quantity of deflagrating (propellant) explosives does not exceed 3.2 g per oxygen cylinder. The cylinders with the installed actuating cartridges as prepared for carriage shall have an effective means of preventing inadvertent activation. Metal hydride storage system(s) installed in conveyances or in completed conveyance components or intended to be installed in conveyances shall be approved by the competent authority of the country of manufacture1 before acceptance for carriage. The transport document shall include an indication that the package was approved by the competent authority of the country of manufacture1 or a copy of the competent authority of the country of manufacture1 approval shall accompany each consignment. Petroleum crude oil containing hydrogen sulphide in sufficient concentration that vapours evolved from the crude oil can present an inhalation hazard shall be consigned under the entry UN 3494 PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC. 358-499 (Reserved) UN No. 3064 nitroglycerin, solution in alcohol with more than 1% but not more than 5% nitroglycerin, packed in accordance with packing instruction P300 of 4.1.4.1, is a substance of Class 3. For naphthalene, molten, see UN No. 2304. UN No. 2006 plastics, nitrocellulose-based, self-heating, n.o.s., and 2002 celluloid scrap are substances of Class 4.2. For phosphorus, white, molten, see UN No. 2447. UN No. 1847 potassium sulphide, hydrated with not less than 30% water of crystallization, UN No. 1849 sodium sulphide, hydrated with not less than 30% water of crystallization and UN No. 2949 sodium hydrosulphide hydrated with not less than 25% water of crystallization are substances of Class 8. If the country of manufacture is not a Contracting Party to ADR, the approval shall be recognized by the competent authority of a Contracting Party to ADR. Copyright © United Nations, 2010. All rights reserved - 24 - UN No. 2004 magnesium diamide is a substance of Class 4.2. Alkaline earth metals and alkaline earth metal alloys in pyrophoric form are substances of Class 4.2. UN No. 1869 magnesium or magnesium alloys containing more than 50% magnesium as pellets, turnings or ribbons, are substances of Class 4.1. 507 UN No. 3048 aluminium phosphide pesticides, with additives inhibiting the emission of toxic flammable gases are substances of Class 6.1. UN No. 1871 titanium hydride and UN No. 1437 zirconium hydride are substances of Class 4.1. UN No. 2870 aluminium borohydride is a substance of Class 4.2. UN No. 1908 chlorite solution is a substance of Class 8. UN No. 1755 chromic acid solution is a substance of Class 8. UN No. 1625 mercuric nitrate, UN No. 1627 mercurous nitrate and UN No. 2727 thallium nitrate are substances of Class 6.1. Thorium nitrate, solid, uranyl nitrate hexahydrate solution and uranyl nitrate, solid are substances of Class 7. UN No. 1730 antimony pentachloride, liquid, UN No. 1731 antimony pentachloride solution, UN No. 1732 antimony pentafluoride and UN No. 1733 antimony trichloride are substances of Class 8. UN No. 0224 barium azide, dry or wetted with less than 50% water, by mass, is a substance of Class 1. UN No. 1571 barium azide, wetted with not less than 50% water, by mass, is a substance of Class 4.1. UN No. 1854 barium alloys, pyrophoric, are substances of Class 4.2. UN No. 1445 barium chlorate, solid, UN No. 1446 barium nitrate, UN No. 1447 barium perchlorate, solid, UN No. 1448 barium permanganate, UN No. 1449 barium peroxide, UN No. 2719 barium bromate, UN No. 2741 barium hypochlorite with more than 22% available chlorine, UN No. 3405 barium chlorate, solution and UN No. 3406 barium perchlorate, solution, are substances of Class 5.1. UN No. 1565 barium cyanide and UN No. 1884 barium oxide are substances of Class 6.1. UN No. 2464 beryllium nitrate is a substance of Class 5.1. UN No. 1581 chloropicrin and methyl bromide mixture and UN No. 1582 chloropicrin and methyl chloride mixture are substances of Class 2. UN No. 1912 methyl chloride and methylene chloride mixture is a substance of Class 2. UN No. 1690 sodium fluoride, solid, UN No. 1812 potassium fluoride, solid, UN No. 2505 ammonium fluoride, UN No. 2674 sodium fluorosilicate, UN No. 2856 fluorosilicates, n.o.s., UN No. 3415 sodium fluoride, solution and UN No. 3422 potassium fluoride, solution, are substances of Class 6.1. UN No. 1463 chromium trioxide, anhydrous (chromic acid, solid) is a substance of Class 5.1. UN No. 1048 hydrogen bromide, anhydrous, is a substance of Class 2. UN No. 1050 hydrogen chloride, anhydrous, is a substance of Class 2. Copyright © United Nations, 2010. All rights reserved - 25 - Solid chlorites and hypochlorites are substances of Class 5.1. UN No. 1873 perchloric acid aqueous solution with more than 50% but not more than 72% pure acid, by mass are substances of Class 5.1. Perchloric acid solutions containing more than 72% pure acid, by mass, or mixtures of perchloric acid with any liquid other than water, are not to be accepted for carriage. UN No. 1382 anhydrous potassium sulphide and UN No. 1385 anhydrous sodium sulphide and their hydrates with less than 30% water of crystallization, and UN No. 2318 sodium hydrosulphide with less than 25% water of crystallization are substances of Class 4.2. UN No. 2858 finished zirconium products of a thickness of 18 Pm or more are substances of Class 4.1. Solutions of inorganic cyanides with a total cyanide ion content of more than 30% shall be classified in packing group I, solutions with a total cyanide ion content of more than 3% and not more than 30% in packing group II and solutions with a cyanide ion content of more than 0.3% and not more than 3% in packing group III. UN No. 2000 celluloid is assigned to Class 4.1. UN No. 1353 fibres or fabrics impregnated with weakly nitrated cellulose, non-self heating are articles of Class 4.1. UN No. 0135 mercury fulminate, wetted with not less than 20% water, or mixture of alcohol and water, by mass, is a substance of Class 1. Mercurous chloride (calomel) is a substance of Class 9 (UN No. 3077). UN No. 3293 hydrazine, aqueous solution with not more than 37% hydrazine, by mass, is a substance of Class 6.1. Mixtures having a flash-point below 23 °C and containing more than 55% nitrocellulose, whatever its nitrogen content or containing not more than 55% nitrocellulose with a nitrogen content above 12.6% (by dry mass), are substances of Class 1 (see UN Nos. 0340 or 0342) or of Class 4.1. UN No. 2672 ammonia solution containing not less than 10% but not more than 35% ammonia is a substance of Class 8. UN No. 1198 formaldehyde solutions, flammable are substances of Class 3. Formaldehyde solutions, non-flammable, with less than 25% formaldehyde are not subject to the requirements of ADR. While in some climatic conditions, petrol (gasoline) may have a vapour pressure at 50 °C of more than 110 kPa (1.10 bar) but not more than 150 kPa (1.50 bar) it is to continue to be considered as a substance having a vapour pressure at 50 °C of not more than 110 kPa (1.10 bar). UN No. 1469 lead nitrate, UN No. 1470 lead perchlorate, solid and UN No. 3408 lead perchlorate, solution, are substances of Class 5.1. For naphthalene, solid, see UN No. 1334. UN No. 2869 titanium trichloride mixture, not pyrophoric, is a substance of Class 8. Copyright © United Nations, 2010. All rights reserved - 26 - For sulphur (in the solid state), see UN No. 1350. Solutions of isocyanates having a flash-point of not less than 23 °C are substances of Class 6.1. UN No. 1326 hafnium powder, wetted, UN No. 1352 titanium powder, wetted or UN No. 1358 zirconium powder, wetted, with not less than 25% water, are substances of Class 4.1. Nitrocellulose mixtures with a water content, alcohol content or plasticizer content lower than the stated limits are substances of Class 1. Talc containing tremolite and/or actinolite is covered by this entry. UN No. 1005 ammonia, anhydrous, UN No. 3318 ammonia solution with more than 50% ammonia and UN No. 2073 ammonia solution, with more than 35% but not more than 50% ammonia, are substances of Class 2. Ammonia solutions with not more than 10% ammonia are not subject to the requirements of ADR. UN No. 1032 dimethylamine, anhydrous, UN No. 1036 ethylamine, UN No. 1061 methylamine, anhydrous and UN No. 1083 trimethylamine, anhydrous, are substances of Class 2. UN No. 0401 dipicryl sulphide, wetted with less than 10% water by mass is a substance of Class 1. UN No. 2009 zirconium, dry, finished sheets, strip or coiled wire, in thicknesses of less than 18 Pm, is a substance of Class 4.2. Zirconium, dry, finished sheets, strip or coiled wire, in thicknesses of 254 Pm or more, is not subject to the requirements of ADR. UN No. 2210 maneb or UN No. 2210 maneb preparations in self-heating form are substances of Class 4.2. Chlorosilanes which, in contact with water, emit flammable gases, are substances of Class 4.3. Chlorosilanes having a flash-point of less than 23 °C and which, in contact with water, do not emit flammable gases are substances of Class 3. Chlorosilanes having a flash-point equal to or greater than 23 °C and which, in contact with water, do not emit flammable gases are substances of Class 8. UN No. 1333 cerium in slabs, rods or ingots is a substance of Class 4.1. Solutions of these isocyanates having a flash-point below 23 °C are substances of Class 3. Metals and metal alloys in powdered or other flammable form, liable to spontaneous combustion, are substances of Class 4.2. Metals and metal alloys in powdered or other flammable form which, in contact with water, emit flammable gases are substances of Class 4.3. This mixture of hydrogen peroxide and peroxyacetic acid shall, in laboratory testing (see Manual of Tests and Criteria, Part II, section 20), neither detonate in the cavitated state nor deflagrate at all and shall show no effect when heated under confinement nor any explosive power. The formulation shall be thermally stable (self- Copyright © United Nations, 2010. All rights reserved - 27 - accelerating decomposition temperature 60 °C or higher for a 50 kg package), and a liquid compatible with peroxyacetic acid shall be used for desensitization. Formulations not meeting these criteria are to be regarded as substances of Class 5.2 (see Manual of Tests and Criteria, Part II, paragraph 20.4.3(g)). Metal hydrides which, in contact with water, emit flammable gases are substances of Class 4.3. UN No. 2870 aluminium borohydride or UN No. 2870 aluminium borohydride in devices is a substance of Class 4.2. Dust and powder of metals in non-spontaneously combustible form, non-toxic which nevertheless, in contact with water, emit flammable gases, are substances of Class 4.3. Organometallic compounds and their solutions which ignite spontaneously are substances of Class 4.2. Flammable solutions with organometallic compounds in concentrations which, in contact with water, neither emit flammable gases in dangerous quantities nor ignite spontaneously are substances of Class 3. Dust and powder of metals in pyrophoric form are substances of Class 4.2. Metals and metal alloys in pyrophoric form are substances of Class 4.2. Metals and metal alloys which, in contact with water, do not emit flammable gases and are not pyrophoric or self-heating, but which are easily ignited, are substances of Class 4.1. (Deleted) UN No. 3257 elevated temperature liquid, n.o.s., at or above 100 °C and, for a substance with a flash-point below its flash-point (including molten metals and molten salts) is a substance of Class 9. Chloroformates having predominantly corrosive properties are substances of Class 8. Spontaneously combustible organometallic compounds are substances of Class 4.2. Water-reactive organometallic compounds, flammable, are substances of Class 4.3. UN No. 1905 selenic acid is a substance of Class 8. UN No. 2443 vanadium oxytrichloride, UN No. 2444 vanadium tetrachloride and UN No. 2475 vanadium trichloride are substances of Class 8. Unspecified wastes resulting from medical/veterinary treatment of humans/animals or from biological research, and which are unlikely to contain substances of Class 6.2 shall be assigned to this entry. Decontaminated clinical wastes or wastes resulting from biological research which previously contained infectious substances are not subject to the requirements of Class 6.2. UN No. 2030 hydrazine aqueous solution, with more than 37% hydrazine, by mass, is a substance of Class 8. (Deleted) Barium azide with a water content lower than the stated limit is a substance of Class 1, UN No. 0224. 569-579 (Reserved) Copyright © United Nations, 2010. All rights reserved - 28 - Tank-vehicles, specialized vehicles and specially equipped vehicles for carriage in bulk shall bear on both sides and at the rear the mark referred to in 5.3.3. Tank-containers, portable tanks, special containers and specially equipped containers for carriage in bulk shall bear this mark on both sides and at each end. This entry covers mixtures of methylacetylene and propadiene with hydrocarbons, which as Mixture P1, contain not more than 63% methylacetylene and propadiene by volume and not more than 24% propane and propylene by volume, the percentage of C4-saturated hydrocarbons being not less than 14% by volume; and as Mixture P2, contain not more than 48% methylacetylene and propadiene by volume and not more than 50% propane and propylene by volume, the percentage of C4-saturated hydrocarbons being not less than 5% by volume, as well as mixtures of propadiene with 1 to 4% methylacetylene. When relevant, in order to meet the requirements for the transport document (5.4.1.1), the term "Mixture P1" or "Mixture P2" may be used as technical name. This entry covers, inter alia, mixtures of gases indicated by the letter R ..., which as Mixture F1, have a vapour pressure at 70 °C not exceeding 1.3 MPa (13 bar) and a density at 50 °C not lower than that of dichlorofluoromethane (1.30 kg/l); Mixture F2, have a vapour pressure at 70 °C not exceeding 1.9 MPa (19 bar) and a density at 50 °C not lower than that of dichloridifluoromethane (1.21 kg/l); Mixture F3, have a vapour pressure at 70 °C not exceeding 3 MPa (30 bar) and a density at 50 °C not lower than that of chlorodifluoromethane (1.09 kg/l). NOTE: Trichlorofluoromethane (refrigerant R 11), 1,1,2-trichloro-1,2,2trifluoroethane (refrigerant R 113), 1,1,1-trichloro-2,2,2-trifluoroethane (refrigerant R 113a), 1-chloro-1,2,2-trifluoroethane (refrigerant R 133) and 1-chloro-1,1,2trifluoroethane (refrigerant R 133 b) are not substances of Class 2. They may, however, enter into the composition of mixtures F 1 to F 3. When relevant, in order to meet the requirements for the transport document (5.4.1.1), the term "Mixture F1", "Mixture F2" or "Mixture F3" may be used as technical name. 583 This entry covers, inter alia, mixtures which as Mixture A, have a vapour pressure at 70 °C not exceeding 1.1 MPa (11 bar) and a density at 50 °C not lower than 0.525 kg/l; Mixture A01, have a vapour pressure at 70 °C not exceeding 1.6 MPa (16 bar) and a relative density at 50 °C not lower than 0.516 kg/l; Mixture A02, have a vapour pressure at 70 °C not exceeding 1.6 MPa (16 bar) and a relative density at 50 °C not lower than 0.505 kg/l; Mixture A0, have a vapour pressure at 70 °C not exceeding 1.6 MPa (16 bar) and a density at 50 °C not lower than 0.495 kg/l; Copyright © United Nations, 2010. All rights reserved - 29 - Mixture A1, have a vapour pressure at 70 °C not exceeding 2.1 MPa (21 bar) and a density at 50 °C not lower than 0.485 kg/l; Mixture B1, have a vapour pressure at 70 °C not exceeding 2.6 MPa (26 bar) and a relative density at 50 °C not lower than 0.474 kg/l; Mixture B2, have a vapour pressure at 70 °C not exceeding 2.6 MPa (26 bar) and a relative density at 50 °C not lower than 0.463 kg/l; Mixture B, have a vapour pressure at 70 °C not exceeding 2.6 MPa (26 bar) and a density at 50 °C not lower than 0.450 kg/l; Mixture C, have a vapour pressure at 70 °C not exceeding 3.1 MPa (31 bar) and a relative density at 50 °C not lower than 0.440 kg/l; When relevant, in order to meet the requirements for the transport document (5.4.1.1), the following terms may be used as technical name: - "Mixture A" or "Butane"; - "Mixture A01" or "Butane"; - "Mixture A02" or "Butane"; - "Mixture A0" or "Butane"; - "Mixture A1"; - "Mixture B1"; - "Mixture B2"; - "Mixture B"; - "Mixture C" or "Propane". For carriage in tanks, the trade names "butane" or "propane" may be used only as a complement. This gas is not subject to the requirements of ADR when: - it is in the gaseous state; - it contains not more than 0.5% air; - it is contained in metal capsules (sodors, sparklets) free from defects which may impair their strength; - the leakproofness of the closure of the capsule is ensured; - a capsule contains not more than 25 g of this gas; - a capsule contains not more than 0.75 g of this gas per cm3 of capacity. Cinnabar is not subject to the requirements of ADR. Hafnium, titanium and zirconium powders shall contain a visible excess of water. Hafnium, titanium and zirconium powders, wetted, mechanically produced, of a particle size of 53 Pm and over, or chemically produced, of a particle size of 840 Pm and over, are not subject to the requirements of ADR. Copyright © United Nations, 2010. All rights reserved - 30 - Barium stearate and barium titanate are not subject to the requirements of ADR. Solid hydrated forms of aluminium bromide and aluminium chloride are not subject to the requirements of ADR. (Deleted) Ferric chloride hexahydrate is not subject to the requirements of ADR. Lead sulphate with not more than 3% free acid is not subject to the requirements of ADR. Uncleaned empty packagings (including empty IBCs and large packagings), empty tank-vehicles, empty demountable tanks, empty portable tanks, empty tank-containers and empty small containers which have contained this substance are not subject to the requirements of ADR. This gas, intended for the cooling of e.g. medical or biological specimens, if contained in double wall receptacles which comply with the provisions of packing instruction P203, paragraph (6) for open cryogenic receptacles of 4.1.4.1 is not subject to the requirements of ADR. The following articles, manufactured and filled according to the regulations of the manufacturing State and packaged in strong outer packagings, are not subject to the requirements of ADR: - UN No. 1044 fire extinguishers provided with protection against inadvertent discharge; - UN No. 3164 articles, pressurized pneumatic or hydraulic, designed to withstand stresses greater than the internal gas pressure by virtue of transmission of force, intrinsic strength or construction. Cadmium pigments, such as cadmium sulphides, cadmium sulphoselenides and cadmium salts of higher fatty acids (e.g. cadmium stearate), are not subject to the requirements of ADR. Acetic acid solutions with not more than 10% pure acid by mass, are not subject to the requirements of ADR. The following are not subject to the requirements of ADR: (a) New storage batteries when: - they are secured in such a way that they cannot slip, fall or be damaged; - they are provided with carrying devices, unless they are suitably stacked, e.g. on pallets; - there are no dangerous traces of alkalis or acids on the outside; - they are protected against short circuits; (b) Used storage batteries when: - their cases are undamaged; Copyright © United Nations, 2010. All rights reserved - 31 - - they are secured in such a way that they cannot leak, slip, fall or be damaged, e.g. by stacking on pallets; - there are no dangerous traces of alkalis or acids on the outside of the articles; - they are protected against short circuits. "Used storage batteries" means storage batteries carried for recycling at the end of their normal service life. Manufactured articles or instruments containing not more than 1 kg of mercury are not subject to the requirements of ADR. Vanadium pentoxide, fused and solidified, is not subject to the requirements of ADR. Pharmaceutical products (medicines) ready for use, which are substances manufactured and packaged for retail sale or distribution for personal or household consumption are not subject to the requirements of ADR. Phosphorus sulphides which are not free from yellow and white phosphorus are not to be accepted for carriage. Anhydrous hydrogen cyanide not meeting the description for UN No. 1051 or UN No. 1614 is not to be accepted for carriage. Hydrogen cyanide (hydrocyanic acid) containing less than 3% water is stable, if the pH-value is 2.5 ± 0.5 and the liquid is clear and colourless. 604-606 (Deleted) Mixtures of potassium nitrate and sodium nitrite with an ammonium salt are not to be accepted for carriage. (Deleted) Tetranitromethane not free from combustible impurities is not to be accepted for carriage. The carriage of this substance, when it contains more than 45% hydrogen cyanide is prohibited. Ammonium nitrate containing more than 0.2% combustible substances (including any organic substance calculated as carbon) is not to be accepted for carriage unless it is a constituent of a substance or article of Class 1. (Reserved) Chloric acid solution containing more than 10% chloric acid and mixtures of chloric acid with any liquid other than water is not to be accepted for carriage. 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) in concentrations considered highly toxic according to the criteria in 2.2.61.1 is not to be accepted for carriage. (Reserved) Substances containing more than 40% liquid nitric esters shall satisfy the exudation test specified in 2.3.1. Copyright © United Nations, 2010. All rights reserved - 32 - In addition to the type of explosive, the commercial name of the particular explosive shall be marked on the package. In receptacles containing 1,2-butadiene, the oxygen concentration in the gaseous phase shall not exceed 50 ml/m3. 619-622 (Reserved) UN No. 1829 sulphur trioxide shall be inhibited. Sulphur trioxide, 99.95% pure or above, may be carried without inhibitor in tanks provided that its temperature is maintained at or above 32.5 °C. For the carriage of this substance without inhibitor in tanks at a minimum temperature of 32.5 °C, the specification "Transport under minimum temperature of the product of 32.5 °C" shall appear in the transport document. Packages containing these articles shall be clearly marked as follows: "UN 1950 AEROSOLS" 626-627 (Reserved) Considered to be spontaneously flammable (pyrophoric). Packages and small containers containing this substance shall bear the following marking: "Keep away from any source of ignition". This marking shall be in an official language of the forwarding country, and also, if that language is not English, French or German, in English, French or German, unless any agreements concluded between the countries concerned in the transport operation provide otherwise. (Deleted) Packages containing these articles need not bear a label conforming to model No. 9 unless the article is fully enclosed by packaging, crates or other means that prevent the ready identification of the article. (a) Cells contained in equipment shall not be capable of being discharged during carriage to the extent that the open circuit voltage falls below 2 volts or two thirds of the voltage of the undischarged cell, whichever is the lower. (b) Used lithium cells and batteries with a gross mass of not more than 500 g each collected and presented for carriage for disposal between the consumer collecting point and the intermediate processing facility, together with other non-lithium cells or batteries, are not subject to the other provisions of ADR if they meet the following conditions: (i) The provisions of packing instruction P903b are complied with; (ii) A quality assurance system is in place to ensure that the total amount of lithium cells or batteries per transport unit does not exceed 333 kg; (iii) Packages shall bear the inscription: "USED LITHIUM CELLS". Genetically modified microorganisms and genetically modified organisms are those which are not dangerous for humans and animals, but which could alter animals, plants, microbiological substances and ecosystems in such a way as cannot occur naturally. Genetically modified microorganisms and genetically modified organisms Copyright © United Nations, 2010. All rights reserved - 33 - are not subject to the requirements of ADR when authorized for use by the competent authorities of the countries of origin, transit and destination2. Live vertebrate or invertebrate animals shall not be used to carry these substances classified under this UN number unless the substance can be carried in no other way. For the carriage of easily perishable substances under this UN number appropriate information shall be given, e.g.: "Cool at +2 °/+4 °C" or "Carry in frozen state" or "Do not freeze". Substances related to self-reactive substances (see 2.2.41.1.19). See 2.2.2.3, classification code 2F, UN No. 1965, Note 2. The physical and technical characteristics mentioned in column (2) of Table A of Chapter 3.2 determine different tank codes for the carriage of substances of the same packing group in ADR tanks. In order to identify these physical and technical characteristics of the product carried in the tank, the following shall be added, to the particulars required in the transport document, only in case of carriage in ADR tanks: "Special provision 640X" where "X" is the applicable capital letter appearing after the reference to special provision 640 in column (6) of Table A of Chapter 3.2. These particulars may, however, be dispensed with in the case of carriage in the type of tank which, for substances of a specific packing group of a specific UN number, meets at least the most stringent requirements. Except as authorized under 1.1.4.2, this entry of the UN Model Regulations shall not be used for the carriage of fertilizer ammoniating solutions with free ammonia. Stone or aggregate asphalt mixture is not subject to the requirements for Class 9. This substance is admitted for carriage provided that: - The pH is between 5 and 7 measured in an aqueous solution of 10% of the substance carried; - The solution does not contain more than 0.2% combustible material or chlorine compounds in quantities such that the chlorine level exceeds 0.02%. The classification code as mentioned in Column (3b) of Table A of Chapter 3.2 shall be used only with the approval of the competent authority of a Contracting Party to ADR prior to carriage. The approval shall be given in writing as a classification approval certificate (see 5.4.1.2.1 (g)) and shall be provided with a unique reference. When assignment to a division is made in accordance with the procedure in 2.2.1.1.7.2, the competent authority may require the default classification to be verified on the basis of test data derived from Test Series 6 of the Manual of Tests and Criteria, Part I, Section 16. See in particular Part C of Directive 2001/18/EC of the European Parliament and of the Council on the deliberate release into the environment of genetically modified organisms and repealing Council Directive 90/220/EEC (Official Journal of the European Communities, No. L 106, of 17 April 2001, pp. 8- 14), which sets out the authorization procedures for the European Community. Copyright © United Nations, 2010. All rights reserved - 34 - Carbon made by steam activation process is not subject to the requirements of ADR. The carriage of vinegar and acetic acid food grade with not more than 25% pure acid by mass is subject only to the following requirements: (a) Packagings, including IBCs and large packagings, and tanks shall be manufactured from stainless steel or plastic material which is permanently resistant to corrosion of vinegar/acetic acid food grade; (b) Packagings, including IBCs and large packagings, and tanks shall be subjected to a visual inspection by the owner at least once a year. The results of the inspections shall be recorded and the records kept for at least one year. Damaged packagings, including IBCs and large packagings, and tanks shall not be filled; (c) Packagings, including IBCs and large packagings, and tanks shall be filled in a way that no product is spilled or adheres to the outer surface; (d) Seals and closures shall be resistant to vinegar/acetic acid food grade. Packagings, including IBCs and large packagings, and tanks shall be hermetically sealed by the packer or the filler so that under normal conditions of carriage there will be no leakage; (e) Combination packagings with inner packaging made of glass or plastic (see packing instruction P001 in 4.1.4.1) which fulfil the general packing requirements of 4.1.1.1, 4.1.1.2, 4.1.1.4, 4.1.1.5, 4.1.1.6, 4.1.1.7 and 4.1.1.8 may be used; The other provisions of ADR do not apply. Articles impregnated with this pesticide, such as fibreboard plates, paper strips, cotton-wool balls, sheets of plastics material, in hermetically closed wrappings, are not subject to the provisions of ADR. (Deleted) Waste consisting of packaging residues, solidified residues and liquid residues of paint may be carried under the conditions of packing group II. In addition to the provisions of UN No. 1263 packing group II, the waste may also be packed and carried as follows: (a) The waste may be packed in accordance with packing instruction P002 of 4.1.4.1 or to packing instruction IBC06 of 4.1.4.2; (b) The waste may be packed in flexible IBCs of types 13H3, 13H4 and 13H5 in overpacks with complete walls; (c) Testing of packagings and IBCs indicated under (a) or (b) may be carried out in accordance with the requirements of Chapters 6.1 or 6.5, as appropriate, in relation to solids, at the packing group II performance level. The tests shall be carried out on packagings and IBCs, filled with a representative sample of the waste, as prepared for carriage; (d) Carriage in bulk in sheeted vehicles, closed containers or sheeted large containers, all with complete walls is allowed. The body of vehicles or containers shall be leakproof or rendered leakproof, for example by means of a suitable and sufficiently stout inner lining; Copyright © United Nations, 2010. All rights reserved - 35 - (e) If the waste is carried under the conditions of this special provision, the goods shall be declared in accordance with 5.4.1.1.3 in the transport document, as follows: "UN 1263 WASTE PAINT, 3, II, (D/E)", or "UN 1263 WASTE PAINT, 3, PG II, (D/E)". Special provision V2 (1) does not apply if the net explosive mass per transport unit does not exceed 4000 kg, provided that the net explosive mass per vehicle does not exceed 3000 kg. Austenitic stainless steel, ferritic and austenitic steel (Duplex steel) and welded titanium receptacles which do not meet the requirements of Chapter 6.2 but have been constructed and approved in accordance with national aviation provisions for use as hot air balloon or hot air airship fuel receptacles, brought into service (date of initial inspection) before 1 July 2004, may be carried by road provided they meet the following conditions: (a) The general provisions of 6.2.1 shall be complied with; (b) The design and construction of the receptacles shall have been approved for aviation use by a national air transport authority; (c) As an exemption from 6.2.3.1.2, the calculation pressure shall be derived from a reduced maximum ambient temperature of +40° C; in this case: (i) as an exemption from 6.2.5.1, cylinders may be manufactured from rolled and annealed commercially pure titanium with the minimum requirements of Rm > 450 MPa, İA > 20% (İA = elongation after fracture); (ii) austenitic stainless steel and ferritic and austenitic steel (Duplex steel) cylinders may be used with a stress level up to 85% of the minimum guaranteed yield strength (Re) at a calculation pressure derived from a reduced maximum ambient temperature of +40° C; (iii) the receptacles shall be equipped with a pressure relief device having a nominal set pressure of 26 bar; the test pressure of these receptacles shall be not less than 30 bar; (d) When the exemptions from (c) are not applied, the receptacles shall be designed for a reference temperature of 65° C and shall be equipped with pressure relief devices with a nominal set pressure specified by the competent authority of the country of use; (e) The main body of the receptacles shall be covered by an outer, water-resistant protective layer at least 25 mm thick made from structural cellular foam or similar material; (f) During carriage, the receptacle shall be firmly secured in a crate or an additional safety device; (g) The receptacles shall be marked with a clear, visible label stating that the receptacles are for use only in hot air balloons and hot air airships; (h) The duration of service (from the date of initial inspection) shall not exceed 25 years. Copyright © United Nations, 2010. All rights reserved - 36 - The carriage of this gas in cylinders having a test pressure capacity product of maximum 15 MPa.litre (150 bar.litre) is not subject to the other provisions of ADR if the following conditions are met: - The provisions for construction and testing of cylinders are observed; - The cylinders are contained in outer packagings which at least meet the requirements of Part 4 for combination packagings. The general provisions of packing of 4.1.1.1, 4.1.1.2 and 4.1.1.5 to 4.1.1.7 shall be observed; - The cylinders are not packed together with other dangerous goods; - The total gross mass of a package does not exceed 30 kg; and - Each package is clearly and durably marked with "UN 1013" for carbon dioxide or "UN 1066" for nitrogen, compressed. This marking is displayed within a diamond-shaped area surrounded by a line that measures at least 100 mm by 100 mm. Waste lighters collected separately and consigned in accordance with 5.4.1.1.3 may be carried under this entry for the purposes of disposal. They need not be protected against inadvertent discharge provided that measures are taken to prevent the dangerous build up of pressure and dangerous atmospheres. Waste lighters, other than those leaking or severely deformed, shall be packed in accordance with packing instruction P003. In addition the following provisions shall apply: - only rigid packagings of a maximum capacity of 60 litres shall be used; - the packagings shall be filled with water or any other appropriate protection material to avoid any ignition; - under normal conditions of carriage all ignition devices of the lighters shall fully be covered by the protection material; - the packagings shall be adequately vented to prevent the creation of flammable atmosphere and the build up of pressure; - the packages shall only be carried in ventilated or open vehicles or containers. Leaking or severely deformed lighters shall be carried in salvage packagings, provided appropriate measures are taken to ensure there is no dangerous build up of pressure. NOTE: Special provision 201 and special packing provisions PP84 and RR5 of packing instruction P002 in 4.1.4.1 do not apply to waste lighters. Copyright © United Nations, 2010. All rights reserved - 37 - Cylinders and their closures designed, constructed, approved and marked in accordance with Directive 97/23/EC3 and used for breathing apparatus may be carried without conforming to Chapter 6.2, provided that they are subject to inspections and tests specified in 6.2.1.6.1 and the interval between tests specified in packing instruction P200 in 4.1.4.1 is not exceeded. The pressure used for the hydraulic pressure test is the pressure marked on the cylinder in accordance with Directive 97/23/EC3. The requirement of the first sentence of special provision 188 (e) does not apply to devices which are intentionally active in transport (radio frequency identification (RFID) transmitters, watches, sensors, etc.) and which are not capable of generating a dangerous evolution of heat. Notwithstanding special provision 188 (b), batteries manufactured before 1 January 2009 may continue to be carried without the Watt-hour rating on the outside case after 31 December 2010. Directive 97/23/EC of the European Parliament and of the Council of 29 May 1997 on the approximation of the laws of the Member States concerning pressure equipment (PED) (Official Journal of the European Communities No. L 181 of 9 July 1997, p. 1 - 55). Copyright © United Nations, 2010. All rights reserved - 39 - CHAPTER 3.4 DANGEROUS GOODS PACKED IN LIMITED QUANTITIES 3.4.1 This Chapter provides the provisions applicable to the carriage of dangerous goods of certain classes packed in limited quantities. The applicable quantity limit for the inner packaging or article is specified for each substance in Column (7a) of Table A of Chapter 3.2. In addition, the quantity "0" has been indicated in this column for each entry not permitted to be carried in accordance with this Chapter. Limited quantities of dangerous goods packed in such limited quantities, meeting the provisions of this Chapter are not subject to any other provisions of ADR except the relevant provisions of: (a) Part 1, Chapters 1.1, 1.2, 1.3, 1.4, 1.5, 1.6, 1.8, 1.9; (b) Part 2; (c) Part 3, Chapters 3.1, 3.2, 3.3 (except special provisions 61, 178, 181, 220, 274, 625, 633 and 650 (e)); (d) Part 4, paragraphs 4.1.1.1, 4.1.1.2, 4.1.1.4 to 4.1.1.8; (e) Part 5, 5.1.2.1(a) (i) and (b), 5.1.2.2, 5.1.2.3, 5.2.1.9, 5.4.2; (f) Part 6, construction requirements of 6.1.4 and paragraphs 6.2.5.1 and 6.2.6.1 to 6.2.6.3; (g) Part 7, Chapter 7.1 and 7.2.1, 7.2.2, 7.5.1 (except 7.5.1.4), 7.5.7, 7.5.8 and 7.5.9; (h) 8.6.3.3. 3.4.2 Dangerous goods shall be packed only in inner packagings placed in suitable outer packagings. Intermediate packagings may be used. However, the use of inner packagings is not necessary for the carriage of articles such as aerosols or "receptacles, small, containing gas". The total gross mass of the package shall not exceed 30 kg. 3.4.3 Shrink-wrapped or stretch-wrapped trays meeting the conditions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8 are acceptable as outer packagings for articles or inner packagings containing dangerous goods carried in accordance with this Chapter. Inner packagings that are liable to break or be easily punctured, such as those made of glass, porcelain, stoneware or certain plastics, shall be placed in suitable intermediate packagings meeting the provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8, and be so designed that they meet the construction requirements of 6.1.4. The total gross mass of the package shall not exceed 20 kg. 3.4.4 Liquid goods of Class 8, packing group II in glass, porcelain or stoneware inner packagings shall be enclosed in a compatible and rigid intermediate packaging. 3.4.5 and 3.4.6 (Reserved) Copyright © United Nations, 2010. All rights reserved - 40 - 3.4.7 Except for air transport, packages containing dangerous goods in limited quantities shall bear the marking shown below. The marking shall be readily visible, legible and able to withstand open weather exposure without a substantial reduction in effectiveness. The top and bottom portions and the surrounding line shall be black. The centre area shall be white or a suitable contrasting background. The minimum dimensions shall be 100 mm u 100 mm and the minimum width of line forming the diamond shall be 2 mm. If the size of the package so requires, the dimension may be reduced, to be not less than 50 mm u 50 mm provided the marking remains clearly visible. 3.4.8 Packages containing dangerous goods consigned for air transport in conformity with the provisions of Part 3, Chapter 4 of the ICAO Technical Instructions for the Safe Transport of Dangerous Goods by Air shall bear the marking shown below. The marking shall be readily visible, legible and able to withstand open weather exposure without a substantial reduction in effectiveness. The top and bottom portions and the surrounding line shall be black. The centre area shall be white or a suitable contrasting background. The minimum dimensions shall be 100 mm u 100 mm. The minimum width of line forming diamond shall be 2 mm. The symbol "Y" shall be placed in the centre of the mark and shall be clearly visible. If the size of the package so requires, the dimension may be reduced, to be not less than 50 mm u 50 mm provided the marking remains clearly visible. 3.4.9 Packages containing dangerous goods bearing the marking shown in 3.4.8 shall be deemed to meet the provisions of sections 3.4.1 to 3.4.4 of this Chapter and need not bear the marking shown in 3.4.7. Y Copyright © United Nations, 2010. All rights reserved - 41 - 3.4.10 (Reserved) 3.4.11 When packages containing dangerous goods packed in limited quantities are placed in an overpack, the provisions of 5.1.2 shall apply. In addition the overpack shall be marked with the markings required by this Chapter unless the markings representative of all dangerous goods in the overpack are visible. The provisions of 5.1.2.1 (a) (ii) and 5.1.2.4 apply only if other dangerous goods which are not packed in limited quantities are contained, and only in relation to these other dangerous goods. 3.4.12 In advance of carriage, consignors of dangerous goods packed in limited quantities shall inform the carrier in a traceable form of the total gross mass of such goods to be consigned. 3.4.13 (a) Transport units with a maximum mass exceeding 12 tonnes carrying packages with dangerous goods in limited quantities shall be marked in accordance with 3.4.15 at the front and at the rear except when orange-coloured plate marking is displayed in accordance with 5.3.2. (b) Containers carrying packages with dangerous goods in limited quantities, on transport units with a maximum mass exceeding 12 tonnes, shall be marked in accordance with 3.4.15 on all four sides except when placards are already affixed in accordance with 5.3.1. The carrying transport unit need not be marked, except when the marking affixed to the containers is not visible from outside this carrying transport unit. In this latter case, the same marking shall be affixed at the front and at the rear of the transport unit. 3.4.14 Markings specified in 3.4.13 may be dispensed with, if the total gross mass of the packages containing dangerous goods packed in limited quantities carried does not exceed 8 tonnes per transport unit. 3.4.15 The marking shall be that required in 3.4.7, except that the minimum dimensions shall be 250 mm u 250 mm. Copyright © United Nations, 2010. All rights reserved - 43 - CHAPTER 3.5 DANGEROUS GOODS PACKED IN EXCEPTED QUANTITIES 3.5.1 Excepted quantities 3.5.1.1 Excepted quantities of dangerous goods of certain classes, other than articles, meeting the provisions of this Chapter are not subject to any other provisions of ADR except for: (a) The training requirements in Chapter 1.3; (b) The classification procedures and packing group criteria in Part 2; (c) The packaging requirements of 4.1.1.1, 4.1.1.2, 4.1.1.4 and 4.1.1.6. NOTE: In the case of radioactive material, the requirements for radioactive material in excepted packages in 1.7.1.5 apply. 3.5.1.2 Dangerous goods which may be carried as excepted quantities in accordance with the provisions of this Chapter are shown in column (7b) of Table A of Chapter 3.2 list by means of an alphanumeric code as follows: Code Maximum net quantity per inner packaging (in grams for solids and ml for liquids and gases) Maximum net quantity per outer packaging (in grams for solids and ml for liquids and gases, or sum of grams and ml in the case of mixed packing) E0 Not permitted as Excepted Quantity E1 E2 E3 E4 E5 For gases, the volume indicated for inner packagings refers to the water capacity of the inner receptacle and the volume indicated for outer packagings refers to the combined water capacity of all inner packagings within a single outer packaging. 3.5.1.3 Where dangerous goods in excepted quantities for which different codes are assigned are packaged together the total quantity per outer packaging shall be limited to that corresponding to the most restrictive code. 3.5.2 Packagings Packagings used for the carriage of dangerous goods in excepted quantities shall be in compliance with the following: (a) There shall be an inner packaging and each inner packaging shall be constructed of plastic (with a minimum thickness of 0.2 mm when used for liquids), or of glass, porcelain, stoneware, earthenware or metal (see also 4.1.1.2) and the closure of each inner packaging shall be held securely in place with wire, tape or other positive means; any receptacle having a neck with moulded screw threads shall have a leak proof threaded type cap. The closure shall be resistant to the contents; Copyright © United Nations, 2010. All rights reserved - 44 - (b) Each inner packaging shall be securely packed in an intermediate packaging with cushioning material in such a way that, under normal conditions of carriage, they cannot break, be punctured or leak their contents. The intermediate packaging shall completely contain the contents in case of breakage or leakage, regardless of package orientation. For liquids, the intermediate packaging shall contain sufficient absorbent material to absorb the entire contents of the inner packaging. In such cases, the absorbent material may be the cushioning material. Dangerous goods shall not react dangerously with cushioning, absorbent material and packaging material or reduce the integrity or function of the materials; (c) The intermediate packaging shall be securely packed in a strong, rigid outer packaging (wooden, fibreboard or other equally strong material); (d) Each package type shall be in compliance with the provisions in 3.5.3; (e) Each package shall be of such a size that there is adequate space to apply all necessary markings; and (f) Overpacks may be used and may also contain packages of dangerous goods or goods not subject to the requirements of ADR. 3.5.3 Tests for packages 3.5.3.1 The complete package as prepared for carriage, with inner packagings filled to not less than 95% of their capacity for solids or 98% for liquids, shall be capable of withstanding, as demonstrated by testing which is appropriately documented, without breakage or leakage of any inner packaging and without significant reduction in effectiveness: (a) Drops onto a rigid, non-resilient flat and horizontal surface from a height of 1.8 m: (i) Where the sample is in the shape of a box, it shall be dropped in each of the following orientations: - flat on the base; - flat on the top; - flat on the longest side; - flat on the shortest side; - on a corner; (ii) Where the sample is in the shape of a drum, it shall be dropped in each of the following orientations: - diagonally on the top chime, with the centre of gravity directly above the point of impact; - diagonally on the base chime; - flat on the side; NOTE: Each of the above drops may be performed on different but identical packages. (b) A force applied to the top surface for a duration of 24 hours, equivalent to the total weight of identical packages if stacked to a height of 3 m (including the sample). 3.5.3.2 For the purposes of testing, the substances to be carried in the packaging may be replaced by other substances except where this would invalidate the results of the tests. For solids, when another substance is used, it must have the same physical characteristics (mass, grain size, etc.) as the substance to be carried. In the drop tests for liquids, when another substance is used, its relative density (specific gravity) and viscosity should be similar to those of the substance to be carried. Copyright © United Nations, 2010. All rights reserved - 45 - 3.5.4 Marking of packages 3.5.4.1 Packages containing excepted quantities of dangerous goods prepared in accordance with this Chapter shall be durably and legibly marked with the mark shown in 3.5.4.2. The first or only label number indicated in column (5) of Table A of Chapter 3.2 for each of the dangerous goods contained in the package shall be shown in the mark. Where the name of the consignor or consignee is not shown elsewhere on the package this information shall be included within the mark. 3.5.4.2 The dimensions of the mark shall be a minimum of 100 mm u 100 mm. Excepted quantities mark Hatching and symbol of the same colour, black or red, on white or suitable contrasting background * The first or only label number indicated in column (5) of Table A of Chapter 3.2 shall be shown in this location. ** The name of the consignor or of the consignee shall be shown in this location if not shown elsewhere on the package. 3.5.4.3 An overpack containing dangerous goods in excepted quantities shall display the markings required by 3.5.4.1, unless such markings on packages within the overpack are clearly visible. 3.5.5 Maximum number of packages in any vehicle or container The number of packages in any vehicle or container shall not exceed 1 000. 3.5.6 Documentation If a document or documents (such as a bill of lading, air waybill or CMR/CIM consignment note) accompanies(y) dangerous goods in excepted quantities, at least one of these documents shall include the statement "Dangerous Goods in Excepted Quantities" and indicate the number of packages. Copyright © United Nations, 2010. All rights reserved - 47 - PART 4 Packing and tank provisions Copyright © United Nations, 2010. All rights reserved - 49 - CHAPTER 4.1 USE OF PACKAGINGS, INCLUDING INTERMEDIATE BULK CONTAINERS (IBCs) AND LARGE PACKAGINGS 4.1.1 General provisions for the packing of dangerous goods in packagings, including IBCs and large packagings NOTE: For the packing of goods of Classes 2, 6.2 and 7, the general provisions of this section only apply as indicated in 4.1.8.2 (Class 6.2), 4.1.9.1.5 (Class 7) and in the applicable packing instructions of 4.1.4 (P201 and LP02 for Class 2 and P620, P621, IBC620 and LP621 for Class 6.2). 4.1.1.1 Dangerous goods shall be packed in good quality packagings, including IBCs and large packagings, which shall be strong enough to withstand the shocks and loadings normally encountered during carriage, including trans-shipment between transport units and between transport units and warehouses as well as any removal from a pallet or overpack for subsequent manual or mechanical handling. Packagings, including IBCs and large packagings, shall be constructed and closed so as to prevent any loss of contents when prepared for transport which might be caused under normal conditions of transport, by vibration, or by changes in temperature, humidity or pressure (resulting from altitude, for example). Packagings, including IBCs and large packagings, shall be closed in accordance with the information provided by the manufacturer. No dangerous residue shall adhere to the outside of packagings, IBCs and large packagings during carriage. These provisions apply, as appropriate, to new, reused, reconditioned or remanufactured packagings and to new, reused, repaired or remanufactured IBCs, and to new, reused or remanufactured large packagings. 4.1.1.2 Parts of packagings, including IBCs and large packagings, which are in direct contact with dangerous goods: (a) shall not be affected or significantly weakened by those dangerous goods; (b) shall not cause a dangerous effect e.g. catalysing a reaction or reacting with the dangerous goods; and (c) shall not allow permeation of the dangerous goods that could constitute a danger under normal conditions of carriage. Where necessary, they shall be provided with a suitable inner coating or treatment. NOTE: For chemical compatibility of plastics packagings, including IBCs, made from polyethylene see 4.1.1.19. 4.1.1.3 Unless otherwise provided elsewhere in ADR, each packaging, including IBCs and large packagings, except inner packagings, shall conform to a design type successfully tested in accordance with the requirements of 6.1.5, 6.3.2, 6.5.6 or 6.6.5, as applicable. The packagings for which the test is not required are mentioned under 6.1.1.3. 4.1.1.4 When filling packagings, including IBCs and large packagings, with liquids, sufficient ullage (outage) shall be left to ensure that neither leakage nor permanent distortion of the packaging occurs as a result of an expansion of the liquid caused by temperatures likely to occur during transport. Unless specific requirements are prescribed, liquids shall not completely fill a packaging at a temperature of 55 °C. However, sufficient ullage shall be left Copyright © United Nations, 2010. All rights reserved - 50 - in an IBC to ensure that at the mean bulk temperature of 50 °C it is not filled to more than 98% of its water capacity. For a filling temperature of 15 °C, the maximum degree of filling shall be determined as follows, unless otherwise provided, either: (a) Boiling point (initial boiling point) of the substance in °C < 60 t 60 < 100 t 100 < 200 t 200 < 300 t 300 Degree of filling as a percentage of the capacity of the packaging or packaging. the of capacity the of % ) t - (50 filling of degree (b) f D  In this formula D represents the mean coefficient of cubic expansion of the liquid substance between 15 °C and 50 °C; that is to say, for a maximum rise in temperature of 35 °C, d d d : formula the to according calculated is u  D D d15 and d50 being the relative densities 1 of the liquid at 15 °C and 50 °C and tf the mean temperature of the liquid at the time of filling. 4.1.1.5 Inner packagings shall be packed in an outer packaging in such a way that, under normal conditions of carriage, they cannot break, be punctured or leak their contents into the outer packaging. Inner packagings containing liquids shall be packed with their closures upward and placed within outer packagings consistent with the orientation markings prescribed in 5.2.1.9. Inner packagings that are liable to break or be punctured easily, such as those made of glass, porcelain or stoneware or of certain plastics materials, etc., shall be secured in outer packagings with suitable cushioning material. Any leakage of the contents shall not substantially impair the protective properties of the cushioning material or of the outer packaging. 4.1.1.5.1 Where an outer packaging of a combination packaging or a large packaging has been successfully tested with different types of inner packagings, a variety of such different inner packagings may also be assembled in this outer packaging or large packaging. In addition, provided an equivalent level of performance is maintained, the following variations in inner packagings are allowed without further testing of the package: (a) Inner packagings of equivalent or smaller size may be used provided: (i) the inner packagings are of similar design to the tested inner packagings (e.g. shape - round, rectangular, etc.); (ii) the material of construction of the inner packagings (glass, plastics, metal, etc.) offers resistance to impact and stacking forces equal to or greater than that of the originally tested inner packaging; (iii) the inner packagings have the same or smaller openings and the closure is of similar design (e.g. screw cap, friction lid, etc.); Relative density (d) is considered to be synonymous with specific gravity (SG) and will be used throughout this Chapter. Copyright © United Nations, 2010. All rights reserved - 51 - (iv) sufficient additional cushioning material is used to take up void spaces and to prevent significant movement of the inner packagings; and (v) inner packagings are oriented within the outer packaging in the same manner as in the tested package. (b) A lesser number of the tested inner packagings, or of the alternative types of inner packagings identified in (a) above, may be used provided sufficient cushioning is added to fill the void space(s) and to prevent significant movement of the inner packagings. 4.1.1.6 Dangerous goods shall not be packed together in the same outer packaging or in large packagings, with dangerous or other goods if they react dangerously with each other and cause: (a) combustion or evolution of considerable heat; (b) evolution of flammable, asphyxiant, oxidizing or toxic gases; (c) the formation of corrosive substances; or (d) the formation of unstable substances. NOTE: For mixed packing special provisions, see 4.1.10. 4.1.1.7 The closures of packagings containing wetted or diluted substances shall be such that the percentage of liquid (water, solvent or phlegmatizer) does not fall below the prescribed limits during transport. 4.1.1.7.1 Where two or more closure systems are fitted in series on an IBC, that nearest to the substance being carried shall be closed first. 4.1.1.8 Where pressure may develop in a package by the emission of gas from the contents (as a result of temperature increase or other causes), the packaging or IBC may be fitted with a vent provided that the gas emitted will not cause danger on account of its toxicity, its flammability or the quantity released, for example. A venting device shall be fitted if dangerous overpressure may develop due to normal decomposition of substances. The vent shall be so designed that, when the packaging or IBC is in the attitude in which it is intended to be carried, leakages of liquid and the penetration of foreign substances are prevented under normal conditions of carriage. NOTE: Venting of the package is not permitted for air carriage. 4.1.1.8.1 Liquids may only be filled into inner packagings which have an appropriate resistance to internal pressure that may be developed under normal conditions of carriage. 4.1.1.9 New, remanufactured or reused packagings, including IBCs and large packagings, or reconditioned packagings and repaired or routinely maintained IBCs shall be capable of passing the tests prescribed in 6.1.5, 6.3.2, 6.5.6 or 6.6.5, as applicable. Before being filled and handed over for carriage, every packaging, including IBCs and large packagings, shall be inspected to ensure that it is free from corrosion, contamination or other damage and every IBC shall be inspected with regard to the proper functioning of any service equipment. Any packaging which shows signs of reduced strength as compared with the approved design type shall no longer be used or shall be so reconditioned, that it is able to withstand the design type tests. Any IBC which shows signs of reduced strength as compared with the Copyright © United Nations, 2010. All rights reserved - 52 - tested design type shall no longer be used or shall be so repaired or routinely maintained that it is able to withstand the design type tests. 4.1.1.10 Liquids shall be filled only into packagings, including IBCs, which have an appropriate resistance to the internal pressure that may develop under normal conditions of carriage. Packagings and IBCs marked with the hydraulic test pressure prescribed in 6.1.3.1 (d) and 6.5.2.2.1, respectively shall be filled only with a liquid having a vapour pressure: (a) such that the total gauge pressure in the packaging or IBC (i.e. the vapour pressure of the filling substance plus the partial pressure of air or other inert gases, less 100 kPa) at 55 °C, determined on the basis of a maximum degree of filling in accordance with 4.1.1.4 and a filling temperature of 15 °C, will not exceed two-thirds of the marked test pressure; or (b) at 50 °C less than four-sevenths of the sum of the marked test pressure plus 100 kPa; or (c) at 55 °C less than two-thirds of the sum of the marked test pressure plus 100 kPa. IBCs intended for the carriage of liquids shall not be used to carry liquids having a vapour pressure of more than 110kPa (1.1 bar) at 50 °C or 130kPa (1.3 bar) at 55 °C. Examples of required marked test pressures for packagings, including IBCs, calculated as in 4.1.1.10 (c) UN No Name Class Packing group Vp55 (kPa) Vp55 × 1.5 (kPa) (Vp55 × 1.5) minus 100 (kPa) Required minimum test pressure gauge under 6.1.5.5.4(c) (kPa) Minimum test pressure (gauge) to be marked on the packaging (kPa) Tetrahydrofuran n-Decane Dichloromethane Diethyl ether 6.1 II III III I 1.4 2.1 -97.9 NOTE 1: For pure liquids the vapour pressure at 55 °C (Vp55) can often be obtained from scientific tables. NOTE 2: The table refers to the use of 4.1.1.10 (c) only, which means that the marked test pressure shall exceed 1.5 times the vapour pressure at 55 °C less 100 kPa. When, for example, the test pressure for n-decane is determined according to 6.1.5.5.4 (a), the minimum marked test pressure may be lower. NOTE 3: For diethyl ether the required minimum test pressure under 6.1.5.5.5 is 250 kPa. 4.1.1.11 Empty packagings, including IBCs and large packagings, that have contained a dangerous substance are subject to the same requirements as those for a filled packaging, unless adequate measures have been taken to nullify any hazard. 4.1.1.12 Every packagings as specified in Chapter 6.1 intended to contain liquids shall successfully undergo a suitable leakproofness test, and be capable of meeting the appropriate test level indicated in 6.1.5.4.3: (a) before it is first used for carriage; Copyright © United Nations, 2010. All rights reserved - 53 - (b) after remanufacturing or reconditioning of any packaging, before it is re-used for carriage. For this test the packaging need not have its closures fitted. The inner receptacle of a composite packaging may be tested without the outer packaging, provided the test results are not affected. This test is not required for: - inner packagings of combination packagings or large packagings; - inner receptacles of composite packagings (glass, porcelain or stoneware) marked with the symbol "RID/ADR" in accordance with 6.1.3.1 (a) (ii); - light gauge metal packagings marked with the symbol "RID/ADR" in accordance with 6.1.3.1 (a) (ii). 4.1.1.13 Packagings, including IBCs, used for solids which may become liquid at temperatures likely to be encountered during carriage shall also be capable of containing the substance in the liquid state. 4.1.1.14 Packagings, including IBCs, used for powdery or granular substances shall be sift-proof or shall be provided with a liner. 4.1.1.15 For plastics drums and jerricans, rigid plastics IBCs and composite IBCs with plastics inner receptacles, unless otherwise approved by the competent authority, the period of use permitted for the carriage of dangerous substances shall be five years from the date of manufacture of the receptacles, except where a shorter period of use is prescribed because of the nature of the substance to be carried. 4.1.1.16 Packagings, including IBCs and large packagings, marked in accordance with 6.1.3, 6.2.2.7, 6.2.2.8, 6.3.1, 6.5.2 or 6.6.3 but which were approved in a State which is not a Contracting Party to ADR may nevertheless be used for carriage under ADR. 4.1.1.17 Explosives, self-reactive substances and organic peroxides Unless specific provision to the contrary is made in ADR, the packagings, including IBCs and large packagings, used for goods of Class 1, self-reactive substances of Class 4.1 and organic peroxides of Class 5.2 shall comply with the provisions for the medium danger group (packing group II). 4.1.1.18 Use of salvage packagings 4.1.1.18.1 Damaged, defective, leaking or non-conforming packages, or dangerous goods that have spilled or leaked may be carried in salvage packagings mentioned in 6.1.5.1.11. This does not prevent the use of a bigger size packaging of appropriate type and performance level under the conditions of 4.1.1.18.2 and 4.1.1.18.3. 4.1.1.18.2 Appropriate measures shall be taken to prevent excessive movement of the damaged or leaking packages within a salvage packaging. When the salvage packaging contains liquids, sufficient inert absorbent material shall be added to eliminate the presence of free liquid. 4.1.1.18.3 Appropriate measures shall be taken to ensure that there is no dangerous build up of pressure. Copyright © United Nations, 2010. All rights reserved - 54 - 4.1.1.19 Verification of the chemical compatibility of plastics packagings, including IBCs, by assimilation of filling substances to standard liquids 4.1.1.19.1 Scope For polyethylene packagings as specified in 6.1.5.2.6, and for polyethylene IBCs as specified in 6.5.6.3.5, the chemical compatibility with filling substances may be verified by assimilation to standard liquids following the procedures, as set out in 4.1.1.19.3 to 4.1.1.19.5 and using the list in table 4.1.1.19.6, provided that the particular design types have been tested with these standard liquids in accordance with 6.1.5 or 6.5.6, taking into account 6.1.6 and that the conditions in 4.1.1.19.2 are met. When assimilation in accordance with this sub-section is not possible, the chemical compatibility needs to be verified by design type testing in accordance with 6.1.5.2.5 or by laboratory tests in accordance with 6.1.5.2.7 for packagings, and in accordance with 6.5.6.3.3 or 6.5.6.3.6 for IBCs, respectively. NOTE: Irrespective of the provisions of this sub-section, the use of packagings, including IBCs, for a specific filling substance is subject to the limitations of Table A of Chapter 3.2, and the packing instructions in Chapter 4.1. 4.1.1.19.2 Conditions The relative densities of the filling substances shall not exceed that used to determine the height for the drop test performed successfully according to 6.1.5.3.5 or 6.5.6.9.4 and the mass for the stacking test performed successfully according to 6.1.5.6 or where necessary according to 6.5.6.6 with the assimilated standard liquid(s). The vapour pressures of the filling substances at 50 °C or 55 °C shall not exceed that used to determine the pressure for the internal pressure (hydraulic) test performed successfully according to 6.1.5.5.4 or 6.5.6.8.4.2 with the assimilated standard liquid(s). In case that filling substances are assimilated to a combination of standard liquids, the corresponding values of the filling substances shall not exceed the minimum values derived from the applied drop heights, stacking masses and internal test pressures. Example: UN 1736 Benzoyl chloride is assimilated to the combination of standard liquids "Mixture of hydrocarbons and wetting solution". It has a vapour pressure of 0.34 kPa at 50 °C and a relative density of approximately 1.2. Design type tests for plastics drums and jerricans were frequently performed at minimum required test levels. In practice this means that the stacking test is commonly performed with stacking loads considering only a relative density of 1.0 for the "Mixture of hydrocarbons" and a relative density of 1.2 for the "Wetting solution" (see definition of standard liquids in 6.1.6). As a consequence chemical compatibility of such tested design types would not be verified for benzoyl chloride by reason of the inadequate test level of the design type with the standard liquid "mixture of hydrocarbons". (Due to the fact that in the majority of cases the applied internal hydraulic test pressure is not less than 100 kPa, the vapour pressure of benzoyl chloride would be covered by such test level according to 4.1.1.10). All components of a filling substance, which may be a solution, mixture or preparation, such as wetting agents in detergents and disinfectants, irrespective whether dangerous or nondangerous, shall be included in the assimilation procedure. 4.1.1.19.3 Assimilation procedure The following steps shall be taken to assign filling substances to listed substances or groups of substances in table 4.1.1.19.6 (see also scheme in Figure 4.1.1.19.1): (a) Classify the filling substance in accordance with the procedures and criteria of Part 2 (determination of the UN number and packing group); Copyright © United Nations, 2010. All rights reserved - 55 - (b) If it is included there, go to the UN number in column (1) of table 4.1.1.19.6; (c) Select the line that corresponds in terms of packing group, concentration, flashpoint, the presence of non-dangerous components etc. by means of the information given in columns (2a), (2b) and (4), if there is more than one entry for this UN number. If this is not possible, the chemical compatibility shall be verified in accordance with 6.1.5.2.5 or 6.1.5.2.7 for packagings, and in accordance with 6.5.6.3.3 or 6.5.6.3.6 for IBCs (however, in the case of aqueous solutions, see 4.1.1.19.4); (d) If the UN number and packing group of the filling substance determined in accordance with (a) is not included in the assimilation list, the chemical compatibility shall be proved in accordance with 6.1.5.2.5 or 6.1.5.2.7 for packagings, and in accordance with 6.5.6.3.3 or 6.5.6.3.6 for IBCs; (e) Apply the "Rule for collective entries", as described in 4.1.1.19.5, if this is indicated in column (5) of the selected line; (f) The chemical compatibility of the filling substance may be regarded as verified taking into account 4.1.1.19.1 and 4.1.1.19.2, if a standard liquid or a combination of standard liquids is assimilated in column (5) and the design type is approved for that/those standard liquid(s). Figure 4.1.1.19.1: Scheme for the assimilation of filling substances to standard liquids Classification of the substance according to Part 2 to determine UN number and packing group Is the substance or group of substances mentioned by name in the assimilation list? Are the UN number and packing group included in the assimilation list? Further tests required (see 4.1.1.19.1) No Yes No Does the assimilation list indicate standard liquid or combination of standard liquids? No to be continued with "Rule for collective entries" Chemical compatibility may be regarded as verified, if packaging/IBC design type has been tested with indicated standard liquid(s); may be also valid for aqueous solutions Yes Yes Copyright © United Nations, 2010. All rights reserved - 56 - 4.1.1.19.4 Aqueous solutions Aqueous solutions of substances and groups of substances assimilated to specific standard liquid(s) in accordance with 4.1.1.19.3 may also be assimilated to that (those) standard liquid(s) provided the following conditions are met: (a) the aqueous solution can be assigned to the same UN number as the listed substance in accordance with the criteria of 2.1.3.3, and (b) the aqueous solution is not specifically mentioned by name otherwise in the assimilation list in 4.1.1.19.6, and (c) no chemical reaction is taking place between the dangerous substance and the solvent water. Example: Aqueous solutions of UN 1120 tert-Butanol: - Pure tert-Butanol itself is assigned to the standard liquid "acetic acid" in the assimilation list. - Aqueous solutions of tert-Butanol can be classified under the entry UN 1120 BUTANOLS in accordance with 2.1.3.3, because the aqueous solution of tert-Butanol does not differ from the entries of the pure substances relating to the class, the packing group(s) and the physical state. Furthermore, the entry "1120 BUTANOLS" is not explicitly limited to the pure substances, and aqueous solutions of these substances are not specifically mentioned by name otherwise in Table A of chapter 3.2 as well as in the assimilation list. - UN 1120 BUTANOLS do not react with water under normal conditions of carriage. As a consequence, aqueous solutions of UN 1120 tert-Butanol may be assigned to the standard liquid "acetic acid". 4.1.1.19.5 Rule for collective entries For the assimilation of filling substances for which "Rule for collective entries" is indicated in column (5), the following steps shall be taken and conditions be met (see also scheme in Figure 4.1.1.19.2): (a) Perform the assimilation procedure for each dangerous component of the solution, mixture or preparation in accordance with 4.1.1.19.3 taking into account the conditions in 4.1.1.19.2. In the case of generic entries, components may be neglected, that are known to have no damaging effect on high density polyethylene (e.g. solid pigments in UN 1263 PAINT or PAINT RELATED MATERIAL); (b) A solution, mixture or preparation cannot be assimilated to a standard liquid, if: (i) the UN number and packing group of one or more of the dangerous components does not appear in the assimilation list; or (ii) "Rule for collective entries" is indicated in column (5) of the assimilation list for one or more of the components; or (iii) (with the exception of UN 2059 NITROCELLULOSE SOLUTION, FLAMMABLE) the classification code of one or more of its dangerous components differs from that of the solution, mixture or preparation. Copyright © United Nations, 2010. All rights reserved - 57 - (c) If all dangerous components are listed in the assimilation list, and its classification codes are in accordance with the classification code of the solution, mixture or preparation itself, and all dangerous components are assimilated to the same standard liquid or combination of standard liquids in column (5), the chemical compatibility of the solution, mixture or preparation may be regarded as verified taking into account 4.1.1.19.1 and 4.1.1.19.2; (d) If all dangerous components are listed in the assimilation list and its classification codes are in accordance with the classification code of the solution, mixture or preparation itself, but different standard liquids are indicated in column (5), the chemical compatibility may only be regarded as verified for the following combinations of standard liquids taking into account 4.1.1.19.1 and 4.1.1.19.2: (i) water/nitric acid 55%; with the exception of inorganic acids with the classification code C1, which are assigned to standard liquid "water"; (ii) water/wetting solution; (iii) water/acetic acid; (iv) water/mixture of hydrocarbons; (v) water/n-butyl acetate – n-butyl acetate-saturated wetting solution; (e) In the scope of this rule, chemical compatibility is not regarded as verified for other combinations of standard liquids than those specified in (d) and for all cases specified in (b). In such cases the chemical compatibility shall be verified by other means (see 4.1.1.19.3 (d)). Example 1: Mixture of UN 1940 THIOGLYCOLIC ACID (50%) and UN 2531 METHACRYLIC ACID, STABILIZED (50%); classification of the mixture: UN 3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. - Both the UN numbers of the components and the UN number of the mixture are included in the assimilation list; - Both the components and the mixture have the same classification code: C3; - UN 1940 THIOGLYCOLIC ACID is assimilated to standard liquid "acetic acid", and UN 2531 METHACRYLIC ACID, STABILIZED is assimilated to standard liquid "nbutyl acetate/n-butyl acetate-saturated wetting solution". According to paragraph (d) this is not an acceptable combination of standard liquids. The chemical compatibility of the mixture has to be verified by other means. Example 2: Mixture of UN 1793 ISOPROPYL ACID PHOSPHATE (50%) and UN 1803 PHENOLSULPHONIC ACID, LIQUID (50%); classification of the mixture: UN 3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. - Both the UN numbers of the components and the UN number of the mixture are included in the assimilation list; - Both the components and the mixture have the same classification code: C3; - UN 1793 ISOPROPYL ACID PHOSPHATE is assimilated to standard liquid "wetting solution", and UN 1803 PHENOLSULPHONIC ACID, LIQUID is assimilated to standard liquid "water". According to paragraph (d) this is one of the acceptable combinations of standard liquids. As a consequence the chemical compatibility may be regarded as verified for this mixture, provided the packaging design type is approved for the standard liquids "wetting solution" and "water". Copyright © United Nations, 2010. All rights reserved - 58 - Figure 4.1.1.19.2: Scheme "Rules for collective entries" Acceptable combinations of standard liquids: - water/nitric acid (55%), with the exception of inorganic acids of classification code C1 which are assigned to standard liquid "water"; - water/wetting solution; - water/acetic acid; - water/mixture of hydrocarbons; - water/n-butyl acetate – n-butyl acetate saturated wetting solution Single entries, collective entries, solutions, mixtures, preparations with indication "Rule for collective entries" in assimilation list Are entries included in the assimilation list for all components of solution, mixture or preparation? Have all components the same classification code as the solution, mixture or preparation? Are all components assimilated to the same standard liquid or combination of standard liquids? Further testing required Chemical compatibility may be regarded as proven, if packaging/ IBC design type has been tested with indicated standard liquid(s) No No Yes Yes Yes Yes No No Are all components separately or together, assimilated to one of the combinations of standard liquids below? Copyright © United Nations, 2010. All rights reserved - 59 - 4.1.1.19.6 Assimilation list In the following table (assimilation list) dangerous substances are listed in the numerical order of their UN numbers. As a rule, each line deals with a dangerous substance, single entry or collective entry covered by a specific UN number. However, several consecutive lines may be used for the same UN number, if substances belonging to the same UN number have different names (e.g. individual isomers of a group of substances), different chemical properties, different physical properties and/or different transport conditions. In such cases the single entry or collective entry within the particular packing group is the last one of such consecutive lines. Columns (1) to (4) of table 4.1.1.19.6, following a structure similar to that of Table A of Chapter 3.2, are used to identify the substance for the purpose of this sub-section. The last column indicates the standard liquid(s) to which the substance can be assimilated. Explanatory notes for each column: Column (1) UN No. Contains the UN number: - of the dangerous substance, if the substance has been assigned its own specific UN number, or - of the collective entry to which dangerous substances not listed by name have been assigned in accordance with the criteria ("decision trees") of Part 2. Column (2a) Proper shipping name or technical name Contains the name of the substance, the name of the single entry, which may cover various isomers, or the name of the collective entry itself. The indicated name can deviate from the applicable proper shipping name. Column (2b) Description Contains a descriptive text to clarify the scope of the entry in those cases when the classification, the transport conditions and/or the chemical compatibility of the substance may be variable. Column (3a) Class Contains the number of the class, whose heading covers the dangerous substance. This class number is assigned in accordance with the procedures and criteria of Part 2. Column (3b) Classification code Contains the classification code of the dangerous substance in accordance with the procedures and criteria of Part 2. Copyright © United Nations, 2010. All rights reserved - 60 - Column (4) Packing group Contains the packing group number(s) (I, II or III) assigned to the dangerous substance in accordance with the procedures and criteria of Part 2. Certain substances are not assigned to packing groups. Column (5) Standard liquid This column indicates, as definite information, either a standard liquid or a combination of standard liquids to which the substance can be assimilated, or a reference to the rule for collective entries in 4.1.1.19.5. Table 4.1.1.19.6: Assimilation list UN No. Proper shipping name or technical name Description Class Classification Code Packing group Standard liquid 3.1.2 3.1.2 2.2 2.2 2.1.1.3

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