Publication: Magyar Közlöny
Issue: MK-2009-89 (Year: 2009, Number: 89)
Era: 2004-2010
Section: Melléklet a 2009. évi LIX. törvényhez
Paragraph Index: 538

(10) p EN 12755:2000 Transportable gas cylinders – Filling conditions for acetylene bundles Table 1: Compressed gases UN No. Name and description Classification code LC50 ml/m3 Cylinders Tubes Pressure drums Bundles of cylinders Test period, years(a) Test pressure, bar(b) Maximum working pressure, bar(b) Special packing provisions AIR, COMPRESSED 1 A X X X X ARGON, COMPRESSED 1 A X X X X CARBON MONOXIDE, COMPRESSED 1 TF X X X X u COAL GAS, COMPRESSED 1 TF X X X X FLUORINE, COMPRESSED 1 TOC X X a, k, n, o HELIUM, COMPRESSED 1 A X X X X HYDROGEN, COMPRESSED 1 F X X X X d KRYPTON, COMPRESSED 1 A X X X X NEON, COMPRESSED 1 A X X X X NITROGEN, COMPRESSED 1 A X X X X OIL GAS, COMPRESSED 1 TF X X X X OXYGEN, COMPRESSED 1 O X X X X s HEXAETHYL TETRAPHOSPHATE AND COMPRESSED GAS MIXTURE 1 T X X X X z NITRIC OXIDE, COMPRESSED 1 TOC X X k, o COMPRESSED GAS, TOXIC, FLAMMABLE, N.O.S. 1 TF d X X X X z COMPRESSED GAS, FLAMMABLE, N.O.S 1 F X X X X z COMPRESSED GAS, TOXIC, N.O.S. 1 T d X X X X z COMPRESSED GAS, N.O.S. 1 A X X X X z DEUTERIUM, COMPRESSED 1 F X X X X d HYDROCARBON GAS MIXTURE, COMPRESSED, N.O.S. 1 F X X X X z METHANE, COMPRESSED or NATURAL GAS, COMPRESSED with high methane content 1 F X X X X 2009/89. szám UN No. Name and description Classification code LC50 ml/m3 Cylinders Tubes Pressure drums Bundles of cylinders Test period, years(a) Test pressure, bar(b) Maximum working pressure, bar(b) Special packing provisions HYDROGEN AND METHANE MIXTURE, COMPRESSED 1 F X X X X d OXYGEN DIFLUORIDE, COMPRESSED 1 TOC 2,6 X X a, k, n, o COMPRESSED GAS, OXIDIZING, N.O.S. 1 O X X X X z COMPRESSED GAS, TOXIC, OXIDIZING, N.O.S. 1 TO d X X X X z COMPRESSED GAS, TOXIC, CORROSIVE, N.O.S. 1 TC d X X X X z COMPRESSED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. 1 TFC d X X X X z COMPRESSED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. 1 TOC d X X X X z (a) Not applicable for pressure receptacles made of composite materials. (b) Where the entries are blank, the working pressure shall not exceed two thirds of the test pressure. Table 2: Liquefied gases and dissolved gases UN No. Name and description Classification code LC50 ml/m3 Cylinders Tubes Pressure drums Bundles of cylinders Test period, years(a) Test pressure, bar Filling ratio Special packing provisions ACETYLENE, DISSOLVED 4 F X X c, p AMMONIA, ANHYDROUS 2 TC X X X X 0.54 b, ra BORON TRIFLUORIDE 2 TC X X X X 0.715 0.86 BROMOTRIFLUOROMETHANE (REFRIGERANT GAS R 13B1) 2 A X X X X 1.13 1.44 1.60 ra ra ra BUTADIENES, STABILIZED (1,2-butadiene) or BUTADIENES, STABILIZED (1,3-butadiene) or BUTADIENES AND HYDROCARBON MIX- TURE, STABILIZED 2 F 2 F 2 F X X X X X X X X X X X X 0.59 0.55 0.50 ra ra ra, v, z BUTANE 2 F X X X X 0.52 ra, v BUTYLENES MIXTURES or 1-BUTYLENE or CIS-2-BUTYLENE or TRANS-2 BUTYLENE 2 F 2 F 2 F 2 F X X X X X X X X X X X X X X X X 0.50 0.53 0.55 0.54 ra, z CARBON DIOXIDE 2 A X X X X 0.68 0.76 ra ra CHLORINE 2 TOC 293 X X X X 1.25 a, ra CHLORODIFLUOROMETHANE (REFRIGERANT GAS R 22) 2 A X X X X 1.03 ra CHLOROPENTAFLUOROETHANE (REFRIGERANT GAS R 115) 2 A X X X X 1.05 ra 1-CHLORO-1,2,2,2- TETRAFLUOROETHANE (REFRIGERANT GAS R 124) 2 A X X X X 1.20 CHLOROTRIFLUOROMETHANE (REFRIGERANT GAS R 13) 2 A X X X X 0.83 0.90 1.04 1.11 ra ra ra ra CYANOGEN 2 TF X X X X 0.70 ra, u CYCLOPROPANE 2 F X X X X 0.55 ra DICHLORODIFLUOROMETHANE (REFRIGERANT GAS R 12) 2 A X X X X 1.15 ra DICHLOROFLUOROMETHANE (REFRIGERANT GAS R 21) 2 A X X X X 1.23 ra 2009/89. szám UN No. Name and description Classification code LC50 ml/m3 Cylinders Tubes Pressure drums Bundles of cylinders Test period, years(a) Test pressure, bar Filling ratio Special packing provisions 1,1-DIFLUOROETHANE (REFRIGERANT GAS R 152a) 2 F X X X X 0.79 ra DIMETHYLAMINE, ANHYDROUS 2 F X X X X 0.59 b, ra DIMETHYL ETHER 2 F X X X X 0.58 ra ETHANE 2 F X X X X 0.25 0.30 0.40 ra ra ra ETHYLAMINE 2 F X X X X 0.61 b, ra ETHYL CHLORIDE 2 F X X X X 0.80 a, ra ETHYL METHYL ETHER 2 F X X X X 0.64 ra ETHYLENE OXIDE, or ETHYLENE OXIDE WITH NITROGEN up to a total pressure of 1MPa (10 bar) at 50 °C 2 TF X X X X 0.78 l, ra ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 9% but not more than 87% ethylene oxide 2 F X X X X 0.66 0.75 ra ra FERTILIZER AMMONIATING SOLUTION with free ammonia CARRIAGE PROHIBITED HYDROGEN BROMIDE, ANHYDROUS 2 TC X X X X 1.51 a, d, ra HYDROGEN CHLORIDE, ANHYDROUS 2 TC X X X X 0.30 0.56 0.67 0.74 a, d, ra a, d, ra a, d, ra a, d, ra HYDROGEN SULPHIDE 2 TF X X X X 0.67 d, ra, u ISOBUTYLENE 2 F X X X X 0.52 ra LIQUEFIED GASES, non-flammable, charged with nitrogen, carbon dioxide or air 2 A X X X X Test pressure = 1.5 x working pressure ra METHYLACETYLENE AND PROPADIENE MIXTURE, STABILIZED Propadiene with 1% to 4% methylacetylene Mixture P1 Mixture P2 2 F X X X X X X X X X X X X X X X X 0.52 0.49 0.47 c, ra, z c, ra c, ra c, ra METHYLAMINE, ANHYDROUS 2 F X X X X 0.58 b, ra METHYL BROMIDE with not more than 2% chloropicrin 2 T X X X X 1.51 a METHYL CHLORIDE (REFRIGERANT GAS R 40) 2 F X X X X 0.81 a, ra METHYL MERCAPTAN 2 TF X X X X 0.78 d, ra, u DINITROGEN TETROXIDE (NITROGEN DIOXIDE) 2 TOC 115 X X X 1.30 k NITROSYL CHLORIDE 2 TC X X 1.10 k, ra NITROUS OXIDE 2 O X X X X 0.68 0.74 0.75 PETROLEUM GASES, LIQUEFIED 2 F X X X X v, z PHOSGENE 2 TC X X X 1.23 k, ra PROPYLENE 2 F X X X X 0.43 ra REFRIGERANT GAS, N.O.S. Mixture F 1 Mixture F 2 Mixture F 3 2 A X X X X X X X X X X X X X X X X 1.23 1.15 1.03 ra, z SULPHUR DIOXIDE 2 TC X X X X 1.23 ra SULPHUR HEXAFLUORIDE 2 A X X X X 1.06 1.34 1.38 ra ra ra TETRAFLUOROETHYLENE, STABILIZED 2 F X X X X m, o, ra TRIFLUOROCHLOROETHYLENE, STABILIZED 2 TF X X X X 1.13 ra, u TRIMETHYLAMINE, ANHYDROUS 2 F X X X X 0.56 b, ra VINYL BROMIDE, STABILIZED 2 F X X X X 1.37 a, ra 2009/89. szám UN No. Name and description Classification code LC50 ml/m3 Cylinders Tubes Pressure drums Bundles of cylinders Test period, years(a) Test pressure, bar Filling ratio Special packing provisions VINYL CHLORIDE, STABILIZED 2 F X X X X 0.81 a, ra VINYL METHYL ETHER, STABILIZED 2 F X X X X 0.67 ra CHLOROPICRIN AND METHYL BROMIDE MIXTURE with more than 2% chloropicrin 2 T X X X X 1.51 a CHLOROPICRIN AND METHYL CHLORIDE MIXTURE 2 T (d) X X X X 0.81 a CYANOGEN CHLORIDE, STABILIZED 2 TC X X 1.03 k BORON TRICHLORIDE 2 TC X X X X 1.19 ra CHLORINE TRIFLUORIDE 2 TOC 299 X X X X 1.40 a HEXAFLUOROPROPYLENE (REFRIGERANT GAS R 1216) 2 A X X X X 1.11 ra SILICON TETRAFLUORIDE 2 TC X X X X 0.74 1.10 VINYL FLUORIDE, STABILIZED 2 F X X X X 0.64 a, ra DIBORANE 2 TF X X 0.07 d, k, o METHYL CHLORIDE AND METHYLENE CHLORIDE MIXTURE 2 F X X X X 0.81 a, ra ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with not more than 9% ethylene oxide 2 A X X X X 0.66 0.75 ra ra 1,2-DICHLORO-1,1,2,2- TETRAFLUOROETHANE (REFRIGERANT GAS R 114) 2 A X X X X 1.30 ra 1,1-DIFLUOROETHYLENE (REFRIGERANT GAS R 1132a) 2 F X X X X 0.77 ra ETHYLENE 2 F X X X X 0.34 0.38 HYDROCARBON GAS MIXTURE, LIQUEFIED,N.O.S Mixture A Mixture A 01 Mixture A 02 Mixture A 0 Mixture A 1 Mixture B 1 Mixture B 2 Mixture B Mixture C 2 F X X X X (b) 0.50 0.49 0.48 0.47 0.46 0.45 0.44 0.43 0.42 ra, v, z INSECTICIDE GAS, TOXIC, N.O.S. 2 T X X X X z INSECTICIDE GAS, N.O.S. 2 A X X X X ra, z ISOBUTANE 2 F X X X X 0.49 ra, v CHLORODIFLUOROMETHANE AND CHLOROPENTAFLUOROETHANE MIXTURE with fixed boiling point, with approximately 49% chlorodifluoromethane (REFRIGERANT GAS R 502) 2 A X X X X 1.01 ra CHLORODIFLUOROBROMOMETHANE (REFRIGERANT GAS R 12B1) 2 A X X X X 1.61 ra NITRIC OXIDE AND DINITROGEN TETROXIDE MIXTURE (NITRIC OXIDE AND NITROGEN DIOXIDE MIXTURE) 2 TOC 115 X X X k, z OCTAFLUOROCYCLOBUTANE (REFRIGERANT GAS RC 318) 2 A X X X X 1.32 ra PROPANE 2 F X X X X 0.43 ra, v TETRAFLUOROMETHANE (REFRIGERANT GAS R 14) 2 A X X X X 0.71 0.90 1-CHLORO-2,2,2-TRIFLUOROETHANE (REFRIGERANT GAS R 133a) 2 A X X X X 1.18 ra TRIFLUOROMETHANE (REFRIGERANT GAS R 23) 2 A X X X X 0.88 0.96 ra ra 1,1,1-TRIFLUOROETHANE (REFRIGERANT GAS R 143a) 2 F X X X X 0.73 ra 2009/89. szám UN No. Name and description Classification code LC50 ml/m3 Cylinders Tubes Pressure drums Bundles of cylinders Test period, years(a) Test pressure, bar Filling ratio Special packing provisions XENON 2 A X X X X 1.28 2,2-DIMETHYLPROPANE 2 F X X X X 0.53 ra AMMONIA SOLUTION, relative density less than 0.880 at 15 °C in water, with more than 35% but not more than 40% ammonia with more than 40% but not more than 50% ammonia 4 A X X X X X X X X 0.80 0.77 b b ARSINE 2 TF X X 1.10 d, k 0.90 DICHLOROSILANE 2 TFC X X X X 1.08 SULPHURYL FLUORIDE 2 T X X X X 1.10 u GERMANE(c) 2 TF X X X X 0.064 d, q, r, ra HEXAFLUOROETHANE (REFRIGERANT GAS R 116) 2 A X X X X 1.13 SELENIUM HEXAFLUORIDE 2 TC X X 1.46 k, ra TELLURIUM HEXAFLUORIDE 2 TC X X 1.00 k, ra TUNGSTEN HEXAFLUORIDE 2 TC X X 3.08 a, k, ra HYDROGEN IODIDE, ANHYDROUS 2 TC X X X X 2.25 a, d, ra PHOSPHORUS PENTAFLUORIDE 2 TC X X 0.90 1.25 k k PHOSPHINE(c) 2 TF X X 0.30 0.45 d, k, q d, k, q PROPADIENE, STABILIZED 2 F X X X X 0.50 ra HYDROGEN SELENIDE, ANHYDROUS 2 TF X X 1.60 k SILANE(c) 2 F X X X X 0.32 0.36 q q CARBONYL SULPHIDE 2 TF X X X X 0.87 ra, u CARBONYL FLUORIDE 2 TC X X X X 0.47 0.70 SULPHUR TETRAFLUORIDE 2 TC X X 0.91 k, ra BROMOTRIFLUORO-ETHYLENE 2 F X X X X 1.19 ra HEXAFLUOROACETONE 2 TC X X X X 1.08 ra NITROGEN TRIOXIDE 2 TOC CARRIAGE PROHIBITED OCTAFLUOROBUT-2-ENE (REFRIGERANT GAS R 1318) 2 A X X X X 1.34 ra OCTAFLUOROPROPANE (REFRIGERANT GAS R 218) 2 A X X X X 1.04 ra NITROGEN TRIFLUORIDE 2 O X X X X 0.50 ETHYLACETYLENE, STABILIZED 2 F X X X X 0.57 c, ra ETHYL FLUORIDE (REFRIGERANT GAS R 161) 2 F X X X X 0.57 ra METHYL FLUORIDE (REFRIGERANT GAS R 41) 2 F X X X X 0.63 ra METHYL NITRITE 2 A CARRIAGE PROHIBITED 1-CHLORO-1,1-DIFLUOROETHANE (REFRIGERANT GAS R 142b) 2 F X X X X 0.99 ra METHYLCHLOROSILANE 2 TFC X X X X ra, z CHLORINE PENTAFLUORIDE 2 TOC 122 X X 1.49 a, k CHLOROTRIFLUORO-METHANE AND TRIFLUOROMETHANE AZEOTROPIC MIXTURE with approximately 60% chlorotrifluoromethane (REFRIGERANT GAS R 503) 2 A X X X X 0.12 0.17 0.64 ra ra ra CYCLOBUTANE 2 F X X X X 0.63 ra DICHLORODIFLUORO-METHANE AND DI- FLUOROETHANE AZEOTROPIC MIXTURE with approximately 74% dichlorodifluoromethane (REFRIGERANT GAS R 500) 2 A X X X X 1.01 ra STIBINE 2 TF X X 0.49 k, r, ra BROMINE CHLORIDE 2 TOC 290 X X X X 1.50 a 2009/89. szám UN No. Name and description Classification code LC50 ml/m3 Cylinders Tubes Pressure drums Bundles of cylinders Test period, years(a) Test pressure, bar Filling ratio Special packing provisions TRIFLUOROACETYL CHLORIDE 2 TC X X X 1.17 k, ra ETHYLENE OXIDE AND DICHLORODI- FLUOROMETHANE MIXTURE with not more than 12,5% ethylene oxide 2 A X X X X 1.09 ra PERCHLORYL FLUORIDE 2 TO X X X X 1.21 u PERFLUORO(METHYL VINYL ETHER) 2 F X X X X 0.75 ra PERFLUORO(ETHYL VINYL ETHER) 2 F X X X X 0.98 ra LIQUEFIED GAS, OXIDIZING, N.O.S. 2 O X X X X z 1,1,1,2-TETRAFLUOROETHANE (REFRIGERANT GAS R 134a) 2 A X X X X 1.05 ra LIQUEFIED GAS, TOXIC, FLAMMABLE, N.O.S. 2 TF d X X X X ra, z LIQUEFIED GAS, FLAMMABLE, N.O.S. 2 F X X X X ra, z LIQUEFIED GAS, TOXIC, N.O.S. 2 T d X X X X z LIQUEFIED GAS, N.O.S. 2 A X X X X ra, z PENTAFLUOROETHANE (REFRIGERANT GAS R 125) 2 A X X X X 0.95 0.87 ra ra DIFLUOROMETHANE (REFRIGERANT GAS R 32) 2 F X X X X 0.78 ra HEPTAFLUOROPROPANE (REFRIGERANT GAS R 227) 2 A X X X X 1.21 ra ETHYLENE OXIDE AND CHLOROTETRA- FLUOROETHANE MIXTURE with not more than 8.8% ethylene oxide 2 A X X X X 1.16 ra ETHYLENE OXIDE AND PENTAFLUORO- ETHANE MIXTURE with not more than 7.9% ethylene oxide 2 A X X X X 1.02 ra ETHYLENE OXIDE AND TETRAFLUORO- ETHANE MIXTURE with not more than 5.6% ethylene oxide 2 A X X X X 1.03 ra ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 87% ethylene oxide 2 TF > X X X X 0.73 ra LIQUEFIED GAS, TOXIC, OXIDIZING, N.O.S. 2 TO d X X X X z LIQUEFIED GAS, TOXIC, CORROSIVE, N.O.S. 2 TC d X X X X ra, z LIQUEFIED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. 2 TFC d X X X X ra, z LIQUEFIED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. 2 TOC d X X X X z AMMONIA SOLUTION, relative density less than 0.880 at 15 °C in water, with more than 50% ammonia 4 TC X X X X b REFRIGERANT GAS R 404A (Pentafluoroethane, 1,1,1-trifluoroethane, and 1,1,1,2-tetrafluoroethane zeotropic mixture with approximately 44% pentafluoroethane and 52% 1,1,1-trifluoroethane) 2 A X X X X 0.82 ra REFRIGERANT GAS R 407A (Difluoromethane, pentafluoroethane, and 1,1,1,2-tetrafluoroethane zeotropic mixture with approximately 20% difluoromethane and 40% pentafluoroethane) 2 A X X X X 0.94 ra REFRIGERANT GAS R 407B (Difluoromethane, pentafluoroethane, and 1,1,1,2-tetrafluoroethane zeotropic mixture with approximately 10% difluoromethane and 70% pentafluoroethane 2 A X X X X 0.93 ra 2009/89. szám UN No. Name and description Classification code LC50 ml/m3 Cylinders Tubes Pressure drums Bundles of cylinders Test period, years(a) Test pressure, bar Filling ratio Special packing provisions REFRIGERANT GAS R 407C (Difluoromethane, pentafluoroethane, and 1,1,1,2-tetrafluoroethane zeotropic mixture with approximately 23% difluoromethane and 25% pentafluoroethane) 2 A X X X X 0.95 ra INSECTICIDE GAS, FLAMMABLE, N.O.S 2 F X X X X ra, z INSECTICIDE GAS, TOXIC, FLAMMABLE, N.O.S. 2 TF X X X X ra, z ACETYLENE, SOLVENT FREE 2 F X X c, p (a) Not applicable for pressure receptacles made of composite materials. (b) For mixtures of UN No. 1965, the maximum permissible filling mass per litre of capacity is as follows: Maximum permissible mass of contents per litre of capacity o Commercial propanem m-Commercial butaneo 0,50 A 0,49 A 01 0,48 A 02 0,47 A 0 0,46 A 1 0,45 B 1 0,44 B 2 0,43 B 0,42 C 0,440 0,450 0,463 0,474 0,485 0,495 0,505 0,516 0,525 Density at 50 °C in kg/l (c) Considered as pyrophoric. (d) Considered to be toxic. The LC50 value still to be determined. 2009/89. szám Table 3: Substances not in class 2 UN No. Name and description Class Classification Code LC50 ml/m3 Cylinders Tubes Pressure drums Bundles of cylinders Test period, years(a) Test pressure, bar Filling ratio Special packing provisions HYDROGEN CYANIDE, STABILIZED containing less than 3% water 6.1 TF1 X X 0.55 k HYDROGEN FLUORIDE, ANHYDROUS CT1 X X X 0.84 ab,ac BROMINE PENTAFLUORIDE 5.1 OTC X X X (b) k,ab,ad, BROMINE TRIFLUORIDE 5.1 OTC X X X (b) k,ab,ad HYDROFLUORIC ACID, solution, with more than 85 % hydrofluoric acid CT1 X X X 0.84 ab,ac IODINE PENTAFLUORIDE 5.1 OTC X X X (b) k,ab,ad (a) Not applicable for pressure receptacles made of composite materials. (b) A minimum ullage of 8% by volume is required. P 201 PACKING INSTRUCTION P 201 This instruction applies to UN Nos. 3167, 3168 and 3169. The following packagings are authorized:

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