Publication: Magyar Közlöny
Issue: MK-2011-73 (Year: 2011, Number: 73)
Era: contemporary
Section: 1. melléklet a 2011. évi LXXIX. törvényhez
Paragraph Index: 424

(4) Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2). Additional requirements: 1. IBCs shall only be used for free flowing substances. 2. Flexible IBCs shall only be used for solids. Special packing provisions: B9 For UN No. 0082, this packing instruction may only be used when the substances are mixtures of ammonium nitrate or other inorganic nitrates with other combustible substances which are not explosive ingredients. Such explosives shall not contain nitroglycerin, similar liquid organic nitrates, or chlorates. Metal IBCs are not authorized. B10 For UN No. 0241, this packing instruction may only be used for substances which consist of water as an essential ingredient and high proportions of ammonium nitrate or other oxidizing substances some or all of which are in solution. The other constituents may include hydrocarbons or aluminium powder, but shall not include nitro-derivatives such as trinitrotoluene. Metal IBCs are not authorized. Copyright © United Nations, 2010. All rights reserved - 161 - IBC520 PACKING INSTRUCTION IBC520 This instruction applies to organic peroxides and self-reactive substances of type F. The IBCs listed below are authorized for the formulations listed, provided the general provisions of 4.1.1, 4.1.2 and 4.1.3 and special provisions of 4.1.7.2 are met. For formulations not listed below, only IBCs which are approved by the competent authority may be used (see 4.1.7.2.2). UN No. Organic peroxide Type of IBC Maximum quantity (litres/kg) Control Temperature Emer-gency Temperature ORGANIC PEROXIDE, TYPE F, LIQUID tert-Butyl hydroperoxide, not more than 72% with water 31A 1 250 tert-Butyl peroxyacetate, not more than 32% in diluent type A 31A 31HA1 1 250 1 000 tert-Butyl peroxybenzoate, not more than 32% in diluent type A 31A 1 250 tert-Butyl peroxy-3,5,5-trimethylhexanoate, not more than 37% in diluent type A 31A 31HA1 1 250 1 000 Cumyl hydroperoxide, not more than 90% in diluent type A 31HA1 1 250 Dibenzoyl peroxide, not more than 42% as a stable dispersion in water 31H1 1 000 Di-tert-butyl peroxide, not more than 52% in diluent type A 31A 31HA1 1 250 1 000 1,1-Di-(tert-butylperoxy) cyclohexane, not more than 42% in diluent type A 31H1 1 000 1,1-Di-(tert-butylperoxy) cyclohexane, not more than 37% in diluent type A 31A 1 250 Dilauroyl peroxide, not more than 42%, stable dispersion, in water 31HA1 1 000 Isopropyl cumyl hydroperoxide, not more than 72% in diluent type A 31HA1 1 250 p-Menthyl hydroperoxide, not more than 72% in diluent type A 31HA1 1 250 Peroxyacetic acid, stabilized, not more than 17% 31A 31H1 31H2 31HA1 1 500 1 500 1 500 1 500 ORGANIC PEROXIDE, TYPE F, SOLID Dicumyl peroxide 31A 31H1 31HA1 2 000 ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED tert-Amyl peroxypivalate, not more than 32% in diluent type A 31A 1 250 +10 °C +15 °C tert-Butyl peroxy-2-ethylhexanoate, not more than 32% in diluent type B 31HA1 31A 1 000 1 250 +30 °C +30 °C +35 °C +35 °C tert-Butyl peroxyneodecanoate, not more than 32% in diluent type A 31A 1 250 0 °C +10 °C tert-Butyl peroxyneodecanoate, not more than 52%, stable dispersion, in water 31A 1 250 -5 °C +5 °C tert-Butyl peroxypivalate, not more than 27% in diluent type B 31HA1 31A 1 000 1 250 +10 °C +10 °C +15 °C +15 °C Cumyl peroxyneodecanoate, not more than 52%, stable dispersion, in water 31A 1 250 -15 °C - 5 °C (Cont'd on next page) Copyright © United Nations, 2010. All rights reserved - 162 - IBC520 PACKING INSTRUCTION (cont’d) IBC520 UN No. Organic peroxide Type of IBC Maximum quantity (litres) Control Temperature Emer-gency Temperature (cont'd) tert-Butyl peroxyneodecanoate, not more than 42% stable dispersion, in water 31A 1 250 - 5 °C + 5 °C Di-(4-tert-butylcyclohexyl) peroxydicarbonate, not more than 42%, stable dispersion, in water 31HA1 1 000 +30 °C +35 °C Dicetyl peroxydicarbonate, not more than 42%, stable dispersion, in water 31HA1 1 000 +30 °C +35 °C Di-(2-neodecanoylperoxyisopropyl)benzene, not more than 42%, stable dispersion, in water 31A 1 250 -15 °C -5 °C 3-Hydroxy-1,1-dimethylbutyl peroxyneodecanoate, not more than 52%, stable dispersion, in water 31A 1 250 -15 °C -5 °C Di-(2-ethylhexyl) peroxydicarbonate, not more than 62%, stable dispersion, in water 31A 1 250 -20 °C -10 °C Dimyristyl peroxydicarbonate, not more than 42%, stable dispersion, in water 31HA1 1 000 +15 °C +20 °C Di-(3,5,5-trimethylhexanoyl) peroxide, not more than 38% in diluent type A 31HA1 31A 1 000 1 250 +10 °C +10 °C +15 °C +15 °C Di-(3,5,5-trimethylhexanoyl) peroxide, not more than 52%, stable dispersion, in water 31A 1 250 +10 °C +15 °C 1,1,3,3-Tetramethylbutyl peroxyneodecanoate, not more than 52%, stable dispersion, in water 31A 1 250 - 5 °C + 5 °C Dicyclohexylperoxydicarbonate, not more than 42% as a stable dispersion, in water 31A 1 250 +10 °C +15 °C ORGANIC PEROXIDE, TYPE F, SOLID, TEMPERATURE CONTROLLED No formulation listed Additional requirements: 1. IBCs shall be provided with a device to allow venting during carriage. The inlet to the pressure-relief device shall be sited in the vapour space of the IBC under maximum filling conditions during carriage. 2. To prevent explosive rupture of metal IBCs or composite IBCs with complete metal casing, the emergency-relief devices shall be designed to vent all the decomposition products and vapours evolved during self-accelerating decomposition or during a period of not less than one hour of fire-engulfment as calculated by the formula in 4.2.1.13.8. The control and emergency temperatures specified in this packing instruction are based on a non-insulated IBC. When consigning an organic peroxide in an IBC in accordance with this instruction, it is the responsibility of the consignor to ensure that: (a) the pressure and emergency relief devices installed on the IBC are designed to take appropriate account of the self-accelerating decomposition of the organic peroxide and of fire-engulfment; and (b) when applicable, the control and emergency temperatures indicated are appropriate, taking into account the design (e.g. insulation) of the IBC to be used. IBC620 PACKING INSTRUCTION IBC620 This instruction applies to UN No. 3291. The following IBCs are authorized, provided the general provisions of 4.1.1, except 4.1.1.15, 4.1.2 and 4.1.3 are met: Rigid, leakproof IBCs conforming to the packing group II performance level. Additional requirements: 1. There shall be sufficient absorbent material to absorb the entire amount of liquid present in the IBC. 2. IBCs shall be capable of retaining liquids. 3. IBCs intended to contain sharp objects such as broken glass and needles shall be resistant to puncture. Copyright © United Nations, 2010. All rights reserved - 163 - 4.1.4.3 Packing instructions concerning the use of large packagings LP01 PACKING INSTRUCTION (LIQUIDS) LP01 The following large packagings are authorized provided the general provision of 4.1.1 and 4.1.3 are met: Inner packagings Large outer packagings Packing group I Packing group II Packing group III Glass 10 litres Steel (50A) Plastics 30 litres Aluminium (50B) Metal 40 litres Metal other than steel or aluminium (50N) Rigid plastics (50H) Natural wood (50C) Plywood (50D) Reconstituted wood (50F) Fibreboard (50G) Not allowed Not allowed Maximum capacity: 3 m3 LP02 PACKING INSTRUCTION (SOLIDS) LP02 The following large packagings are authorized provided the general provisions of 4.1.1 and 4.1.3 are met: Inner packagings Large outer packagings Packing group I Packing group II Packing group III Glass 10 kg Steel (50A) Plastics b 50 kg Aluminium (50B) Metal 50 kg Paper a, b 50 kg Metal other than steel or aluminium (50N) Fibre a, b 50 kg Rigid plastics (50H) Natural wood (50C) Plywood (50D) Reconstituted wood (50F) Fibreboard (50G) Flexible plastics (51H) c Not allowed Not allowed Maximum capacity: 3 m3 a These inner packagings shall not be used when the substances being carried may become liquid during carriage. b These inner packagings shall be sift-proof. c To be used with flexible inner packagings only. Special packing provision: L2 For UN 1950 aerosols, the large packaging shall meet the packing group III performance level. Large packagings for waste aerosols carried in accordance with special provision 327 shall have in addition a means of retaining any free liquid that might escape during carriage e.g. absorbent material. LP99 PACKING INSTRUCTION LP99 Only large packagings which are approved for these goods by the competent authority may be used. A copy of the competent authority approval shall accompany each consignment or the transport document shall include an indication that the packaging was approved by the competent authority. Copyright © United Nations, 2010. All rights reserved - 164 - LP101 PACKING INSTRUCTION LP101 The following packagings are authorized, provided the general provisions of 4.1.1 and 4.1.3 and special provisions of 4.1.5 are met: Inner packagings Intermediate packagings Large packagings Not necessary Not necessary Steel (50A) Aluminium (50B) Metal other than steel or aluminium (50N) Rigid plastics (50H) Natural wood (50C) Plywood (50D) Reconstituted wood (50F) Fibreboard (50G) Special packing provision: L1 For UN Nos. 0006, 0009, 0010, 0015, 0016, 0018, 0019, 0034, 0035, 0038, 0039, 0048, 0056, 0137, 0138, 0168, 0169, 0171, 0181, 0182, 0183, 0186, 0221, 0243, 0244, 0245, 0246, 0254, 0280, 0281, 0286, 0287, 0297, 0299, 0300, 0301, 0303, 0321, 0328, 0329, 0344, 0345, 0346, 0347, 0362, 0363, 0370, 0412, 0424, 0425, 0434, 0435, 0436, 0437, 0438, 0451, 0488 and 0502: Large and robust explosives articles, normally intended for military use, without their means of initiation or with their means of initiation containing at least two effective protective features, may be carried unpackaged. When such articles have propelling charges or are self-propelled, their ignition systems shall be protected against stimuli encountered during normal conditions of carriage. A negative result in Test Series 4 on an unpackaged article indicates that the article can be considered for carriage unpackaged. Such unpackaged articles may be fixed to cradles or contained in crates or other suitable handling devices. LP102 PACKING INSTRUCTION LP102 The following packagings are authorized, provided the general provisions of 4.1.1 and 4.1.3 and special provisions of 4.1.5 are met: Inner packagings Intermediate packagings Outer packagings Bags water resistant Receptacles fibreboard metal plastics wood Sheets fibreboard, corrugated Tubes fibreboard Not necessary Steel (50A) Aluminium (50B) Metal other than steel or aluminium (50N) Rigid plastics (50H) Natural wood (50C) Plywood (50D) Reconstituted wood (50F) Fibreboard (50G) Copyright © United Nations, 2010. All rights reserved - 165 - LP621 PACKING INSTRUCTION LP621 This instruction applies to UN No. 3291. The following large packagings are authorized, provided the general provisions of 4.1.1 and 4.1.3 are met:

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