Publication: Magyar Közlöny
Issue: MK-2009-89 (Year: 2009, Number: 89)
Era: 2004-2010
Section: Melléklet a 2009. évi LIX. törvényhez
Paragraph Index: 325

(4) Solids special form 10-2 A1 A1 10-3 A1 other form 10-2 A2 A2 10-3 A2 Liquids 10-3 A2 10-1 A2 10-4 A2 Gases tritium 2 x 10-2 A2 2 x 10-1 A2 2 x 10-2 A2 special form 10-3 A1 10-2 A1 10-3 A1 other form 10-3 A2 10-2 A2 10-3 A2 (a) For mixtures of radionuclides, see 2.2.7.2.2.4 to 2.2.7.2.2.6. 2009/89. szám 2.2.7.2.4.1.3 Radioactive material which is enclosed in or is included as a component part of an instrument or other manufactured article may be classified under UN No. 2911 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE – INSTRUMENTS or ARTICLES, provided that: (a) The radiation level at 10 cm from any point on the external surface of any unpackaged instrument or article is not greater than 0.1 mSv/h; and (b) Each instrument or manufactured article bears the marking "RADIOACTIVE" except: (i) radioluminescent time-pieces or devices; (ii) consumer products that either have received regulatory approval according to 1.7.1.4 (d) or do not individually exceed the activity limit for an exempt consignment in Table 2.2.7.2.2.1 (column 5), provided such products are carried in a package that bears the marking "RADIOACTIVE" on an internal surface in such a manner that warning of the presence of radioactive material is visible on opening the package; and (c) The active material is completely enclosed by non-active components (a device performing the sole function of containing radioactive material shall not be considered to be an instrument or manufactured article); and (d) The limits specified in columns 2 and 3 of Table 2.2.7.2.4.1.2 are met for each individual item and each package, respectively. 2.2.7.2.4.1.4 Radioactive material with an activity not exceeding the limit specified in column 4 of Table 2.2.7.2.4.1.2, may be classified under UN No. 2910 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE – LIMITED QUANTITY OF MATERIAL, provided that: (a) The package retains its radioactive contents under routine conditions of carriage; and (b) The package bears the marking "RADIOACTIVE" on an internal surface in such a manner that a warning of the presence of radioactive material is visible on opening the package. 2.2.7.2.4.1.5 An empty packaging which had previously contained radioactive material with an activity not exceeding the limit specified in column 4 of Table 2.2.7.2.4.1.2 may be classified under UN No. 2908 RADIOACTIVE MA- TERIAL, EXCEPTED PACKAGE – EMPTY PACKAGING, provided that: (a) It is in a well-maintained condition and securely closed; (b) The outer surface of any uranium or thorium in its structure is covered with an inactive sheath made of metal or some other substantial material; (c) The level of internal non-fixed contamination, when averaged over any 300 cm2, does not exceed: (i) 400 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters; and (ii) 40 Bq/cm2 for all other alpha emitters; and (d) Any labels which may have been displayed on it in conformity with 5.2.2.1.11.1 are no longer visible. 2.2.7.2.4.1.6 Articles manufactured of natural uranium, depleted uranium or natural thorium and articles in which the sole radioactive material is unirradiated natural uranium, unirradiated depleted uranium or unirradiated natural thorium may be classified under UN No. 2909 RADIOACTIVE MATERIAL, EXCEPTED PACKAGE – AR- TICLES MANUFACTURED FROM NATURAL URANIUM or DEPLETED URANIUM or NATURAL THO- RIUM, provided that the outer surface of the uranium or thorium is enclosed in an inactive sheath made of metal or some other substantial material. 2.2.7.2.4.2 Classification as Low specific activity (LSA) material Radioactive material may only be classified as LSA material if the conditions of 2.2.7.2.3.1 and 4.1.9.2 are met. 2.2.7.2.4.3 Classification as Surface contaminated object (SCO) Radioactive material may be classified as SCO if the conditions of 2.2.7.2.3.2 and 4.1.9.2 are met. 2.2.7.2.4.4 Classification as Type A package Packages containing radioactive material may be classified as Type A packages, provided that the following conditions are met: Type A packages shall not contain activities greater than the following: (a) For special form radioactive material: A1; or (b) For all other radioactive material: A2. For mixtures of radionuclides whose identities and respective activities are known, the following condition shall apply to the radioactive contents of a Type A package: ¦ ¦ d  j i )j( A )j( C )i( A )i( B 2009/89. szám where B(i) is the activity of radionuclide i as special form radioactive material; A1(i) is the A1 value for radionuclide i; C(j) is the activity of radionuclide j as other than special form radioactive material; and A2(j) is the A2 value for radionuclide j. 2.2.7.2.4.5 Classification of Uranium hexafluoride Uranium hexafluoride shall only be assigned to UN Nos. 2977 RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, FISSILE, or 2978 RADIOACTIVE MATERIAL, URANIUM HEXAFLUORIDE, non-fissile or fissile-excepted. 2.2.7.2.4.5.1 Packages containing uranium hexafluoride shall not contain: (a) A mass of uranium hexafluoride different from that authorized for the package design; (b) A mass of uranium hexafluoride greater than a value that would lead to an ullage smaller than 5% at the maximum temperature of the package as specified for the plant systems where the package shall be used; or (c) Uranium hexafluoride other than in solid form or at an internal pressure above atmospheric pressure when presented for carriage. 2.2.7.2.4.6 Classification as Type B(U), Type B(M) or Type C packages 2.2.7.2.4.6.1 Packages not otherwise classified in 2.2.7.2.4 (2.2.7.2.4.1 to 2.2.7.2.4.5) shall be classified in accordance with the competent authority approval certificate for the package issued by the country of origin of design. 2.2.7.2.4.6.2 A package may only be classified as a Type B(U) if it does not contain: (a) Activities greater than those authorized for the package design; (b) Radionuclides different from those authorized for the package design; or (c) Contents in a form, or a physical or chemical state different from those authorized for the package design; as specified in the certificate of approval. 2.2.7.2.4.6.3 A package may only be classified as a Type B(M) if it does not contain: (a) Activities greater than those authorized for the package design; (b) Radionuclides different from those authorized for the package design; or (c) Contents in a form, or a physical or chemical state different from those authorized for the package design; as specified in the certificate of approval. 2.2.7.2.4.6.4 A package may only be classified as a Type C if it does not contain: (a) Activities greater than those authorized for the package design; (b) Radionuclides different from those authorized for the package design; or (c) Contents in a form, or physical or chemical state different from those authorized for the package design; as specified in the certificate of approval. 2.2.7.2.5 Special arrangements Radioactive material shall be classified as transported under special arrangement when it is intended to be carried in accordance with 1.7.4. 2009/89. szám 2.2.8 Class 8: Corrosive substances 2.2.8.1 Criteria 2.2.8.1.1 The heading of Class 8 covers substances and articles containing substances of this class which by chemical action attack epithelial tissue – of skin or mucous membranes – with which they are in contact, or which in the event of leakage are capable of damaging or destroying other goods, or means of transport. The heading of this class also covers other substances which form a corrosive liquid only in the presence of water, or which produce corrosive vapour or mist in the presence of natural moisture of the air. 2.2.8.1.2 Substances and articles of Class 8 are subdivided as follows: C1 - C10 Corrosive substances without subsidiary risk: C1 - C4 Acid substances: C1 Inorganic, liquid; C2 Inorganic, solid; C3 Organic, liquid; C4 Organic, solid; C5 - C8 Basic substances: C5 Inorganic, liquid; C6 Inorganic, solid; C7 Organic, liquid; C8 Organic, solid; C9 - C10 Other corrosive substances: C9 Liquid; C10 Solid; C11 Articles; CF Corrosive substances, flammable: CF1 Liquid; CF2 Solid; CS Corrosive substances, self-heating: CS1 Liquid; CS2 Solid; CW Corrosive substances which, in contact with water, emit flammable gases: CW1 Liquid; CW2 Solid; CO Corrosive substances, oxidizing: CO1 Liquid; CO2 Solid; CT Corrosive substances, toxic: CT1 Liquid; CT2 Solid; CFT Corrosive substances, flammable, liquid, toxic; COT Corrosive substances, oxidizing, toxic. Classification and assignment of packing groups 2.2.8.1.3 Substances of Class 8 shall be classified in three packing groups according to the degree of danger they present for carriage, as follows: Packing group I: highly corrosive substances Packing group II: corrosive substances Packing group III: slightly corrosive substances. 2.2.8.1.4 Substances and articles classified in Class 8 are listed in Table A of Chapter 3.2. Allocation of substances to packing groups I, II and III has been made on the basis of experience taking into account such additional factors as inhalation risk (see 2.2.8.1.5) and reactivity with water (including the formation of dangerous decomposition products). 2.2.8.1.5 A substance or preparation meeting the criteria of Class 8 having an inhalation toxicity of dusts and mists (LC50) in the range of packing group I, but toxicity through oral ingestion or dermal contact only in the range of packing group III or less, shall be allocated to Class 8. 2009/89. szám 2.2.8.1.6 Substances, including mixtures, not mentioned by name in Table A of Chapter 3.2 can be assigned to the relevant entry of 2.2.8.3, and to the relevant packing group on the basis of the length of time of contact necessary to produce full thickness destruction of human skin in accordance with the criteria of (a) to (c) below. Liquids, and solids which may become liquid during carriage, which are judged not to cause full thickness destruction of human skin shall still be considered for their potential to cause corrosion to certain metal surfaces. In assigning the packing group, account shall be taken of human experience in instances of accidental exposure. In the absence of human experience, the grouping shall be based on data obtained from experiments in accordance with OECD Guideline 4047. (a) Packing group I is assigned to substances that cause full thickness destruction of intact skin tissue within an observation period up to 60 minutes starting after the exposure time of 3 minutes or less. (b) Packing group II is assigned to substances that cause full thickness destruction of intact skin tissue within an observation period up to 14 days starting after the exposure time of more than 3 minutes but not more than 60 minutes. (c) Packing group III is assigned to substances that: – cause full thickness destruction of intact skin tissue within an observation period up to 14 days starting after the exposure time of more than 60 minutes but not more than 4 hours; or – are judged not to cause full thickness destruction of intact skin tissue, but which exhibit a corrosion rate on either steel or aluminium surfaces exceeding 6.25 mm a year at a test temperature of 55 °C when tested on both materials. For the purposes of testing steel, type S235JR+CR (1.0037 resp. St 37-2), S275J2G3+CR (1.0144 resp. St 44-3), ISO 3574, Unified Numbering System (UNS) G10200 or SAE 1020, and for testing aluminium, non-clad, types 7075-T6 or AZ5GU-T6 shall be used. An acceptable test is prescribed in the Manual of Tests and Criteria, Part III, Section 37. NOTE: Where an initial test on either steel or aluminium indicates the substance being tested is corrosive the follow up test on the other metal is not required. 2.2.8.1.7 If substances of Class 8, as a result of admixtures, come into categories of risk different from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures or solutions shall be assigned to the entries to which they belong, on the basis of their actual degree of danger. NOTE: For the classification of solutions and mixtures (such as preparations and wastes), see also 2.1.3. 2.2.8.1.8 On the basis of the criteria set out in paragraph 2.2.8.1.6, it may also be determined whether the nature of a solution or mixture mentioned by name or containing a substance mentioned by name is such that the solution or mixture is not subject to the provisions for this class. 2.2.8.1.9 Substances, solutions and mixtures, which – do not meet the criteria of Directives 67/548/EEC8 or 1999/45/EC9 as amended and therefore are not classified as corrosive according to these directives, as amended; and – do not exhibit a corrosive effect on steel or aluminium, may be considered as substances not belonging to Class 8. NOTE: UN No. 1910 calcium oxide and UN No. 2812 sodium aluminate, listed in the UN Model Regulations, are not subject to the provisions of RID. 2.2.8.2 Substances not accepted for carriage 2.2.8.2.1 The chemically unstable substances of Class 8 shall not be accepted for carriage unless the necessary steps have been taken to prevent their dangerous decomposition or polymerization during carriage. To this end it shall in particular be ensured that receptacles and tanks do not contain any substance liable to promote these reactions. 2.2.8.2.2 The following substances shall not be accepted for carriage: – UN No. 1798 NITROHYDROCHLORIC ACID; – Chemically unstable mixtures of spent sulphuric acid; OECD guidelines for Testing of Chemicals, No. 404 "Acute Dermal Irritation/Corrosion" (1992). Council Directive 67/548/EEC of 27 June 1967 on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances (Official Journal of the European Communities No. L 196 of 16 August 1967, page 1). Directive 1999/45/EC of the European Parliament and of the Council of 31 May 1999 on the approximation of laws, regulations and administrative provisions of the Member States relating to the classification, packaging and labelling of dangerous preparations (Official Journal of the European Communities No. L 200 of 30 July 1999, pages 1 to 68). 2009/89. szám – Chemically unstable mixtures of nitrating acid or mixtures of residual sulphuric and nitric acids, not denitrated; – Perchloric acid aqueous solution with more than 72% pure acid, by mass, or mixtures of perchloric acid with any liquid other than water. The following substance shall not be accepted for carriage by rail: – Sulphur trioxide, at least 99.95% pure, without inhibitor (non-stabilized). 2.2.8.3 List of collective entries Classification code UN Name of the substance or article No. Corrosive substances without subsidiary risk 2584 ALKYLSULPHONIC ACIDS, LIQUID with more than 5% free sulphuric acid or 2584 ARYLSULPHONIC ACIDS, LIQUID with more than 5% free sulphuric acid liquid 2693 BISULPHITES, AQUEOUS SOLUTION, N.O.S. C1 2837 BISULPHATES, AQUEOUS SOLUTION 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. inorganic 1740 HYDROGENDIFLUORIDES, SOLID, N.O.S. Acid solid C2 2583 ALKYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid or 2583 ARYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid 3260 CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. 2586 ALKYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid or 2586 ARYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid liquid 2987 CHLOROSILANES, CORROSIVE, N.O.S. C3 3145 ALKYLPHENOLS, LIQUID, N.O.S. (including C2-C12 homologues) 3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. organic 2430 ALKYLPHENOLS, SOLID, N.O.S. (including C2-C12 homologues) solid C4 2585 ALKYLSULPHONIC ACIDS, SOLID with not more than 5% free sulphuric acid or 2585 ARYLSULPHONIC ACIDS, SOLID with not more than 5% free sulphuric acid 3261 CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. 1719 CAUSTIC ALKALI LIQUID, N.O.S. liquid 2797 BATTERY FLUID, ALKALI C5 3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. inorganic solid C6 3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. Basic 2735 AMINES, LIQUID, CORROSIVE, N.O.S. or liquid 2735 POLYAMINES, LIQUID, CORROSIVE, N.O.S. C7 3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. organic solid 3259 AMINES, SOLID, CORROSIVE, N.O.S., or 3259 POLYAMINES, SOLID, CORROSIVE, N.O.S. C8 3263 CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. 2009/89. szám Corrosive substances without subsidiary risk (cont’d) 1903 DISINFECTANT, LIQUID, CORROSIVE, N.O.S. 2801 DYE, LIQUID, CORROSIVE, N.O.S. or 2801 DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. liquid C9 3066 PAINT (including paint, enamel, stain, shellac, varnish, polish, liquid filler and lacquer base) or 3066 PAINT RELATED MATERIAL (including paint thinning or reducing compound) Other 1760 CORROSIVE LIQUID, N.O.S. corrosive Substances solid(a) C10 3147 DYE, SOLID, CORROSIVE, N.O.S. or 3147 DYE INTERMEDIATE, SOLID, CORROSIVE, N.O.S. 3244 SOLIDS CONTAINING CORROSIVE LIQUID, N.O.S. 1759 CORROSIVE SOLID, N.O.S. 2794 BATTERIES, WET, FILLED WITH ACID, electric storage Articles C11 2795 BATTERIES, WET, FILLED WITH ALKALI, electric storage 2800 BATTERIES, WET, NON-SPILLABLE, electric storage 3028 BATTERIES, DRY, CONTAINING POTASSIUM HY- DROXIDE SOLID, electric storage 2009/89. szám Subsidiary risk Classification code UN Name of the substance or article No. Corrosive substances with subsidiary risk 3470 PAINT, CORROSIVE, FLAMMABLE (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid lacquer base) or 3470 PAINT RELATED MATERIAL, CORROSIVE, FLAM- MABLE (including paint thinning and reducing compound) liquid(b) CF1 2734 AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or 2734 POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. 2986 CHLOROSILANES, CORROSIVE, FLAMMABLE, N.O.S. Flammable 2920 CORROSIVE LIQUID, FLAMMABLE, N.O.S. CF solid CF2 2921 CORROSIVE SOLID, FLAMMABLE, N.O.S. liquid CS1 3301 CORROSIVE LIQUID, SELF-HEATING, N.O.S. Self-heating CS solid CS2 3095 CORROSIVE SOLID, SELF-HEATING, N.O.S. liquid(b) CW1 3094 CORROSIVE LIQUID, WATER-REACTIVE, N.O.S. Water-reactive CW solid CW2 3096 CORROSIVE SOLID, WATER-REACTIVE, N.O.S. Oxidizing liquid CO1 3093 CORROSIVE LIQUID, OXIDIZING, N.O.S. CO solid CO2 3084 CORROSIVE SOLID, OXIDIZING, N.O.S. 3471 HYDROGENDIFLUORIDES SOLUTION, N.O.S. liquid(c) CT1 2922 CORROSIVE LIQUID, TOXIC, N.O.S. Toxic(d) CT solid(e) CT2 2923 CORROSIVE SOLID, TOXIC, N.O.S. Flammable, liquid, toxic(d) CFT (No collective entry with this classification code available; if need be, classification under a collective entry with a classification code to be determined according to table of precedence of hazard in 2.1.3.10.) Oxidizing, toxic(d),(e) COT (No collective entry with this classification code available; if need be, classification under a collective entry with a classification code to be determined according to table of precedence of hazard in 2.1.3.10.) Footnotes (a) Mixtures of solids which are not subject to the provisions of RID and of corrosive liquids may be carried under UN No. 3244 without being subject to the classification criteria of Class 8, provided there is no free liquid visible at the time the substance is loaded or at the time the packaging, wagon or container is closed. Each packaging shall correspond to a design type which has passed the leakproofness test for Packing group II level. (b) Chlorosilanes which, in contact with water or moist air, emit flammable gases, are substances of Class 4.3. (c) Chloroformates having predominantly toxic properties are substances of Class 6.1. (d) Corrosive substances which are highly toxic by inhalation, as defined in 2.2.61.1.4 to 2.2.61.1.9 are substances of Class 6.1. (e) UN No. 1690 SODIUM FLUORIDE, SOLID, UN No. 1812 POTASSIUM FLUORIDE, SOLID, UN No. 2505 AMMONIUM FLUORIDE, UN No. 2674 SODIUM FLUOROSILICATE, UN No. 2856 FLUORO- SILICATES, N.O.S., UN No. 3415 SODIUM FLUORIDE SOLUTION and UN No. 3422 POTASSIUM FLUORIDE SOLUTION are substances of Class 6.1. 2009/89. szám 2.2.9 Class 9: Miscellaneous dangerous substances and articles 2.2.9.1 Criteria 2.2.9.1.1 The heading of Class 9 covers substances and articles which, during carriage, present a danger not covered by the heading of other classes. 2.2.9.1.2 The substances and articles of Class 9 are subdivided as follows: M1 Substances which, on inhalation as fine dust, may endanger health; M2 Substances and apparatus which, in the event of fire, may form dioxins; M3 Substances evolving flammable vapour; M4 Lithium batteries; M5 Life-saving appliances; M6-M8 Environmentally hazardous substances: M6 Pollutant to the aquatic environment, liquid; M7 Pollutant to the aquatic environment, solid; M8 Genetically modified microorganisms and organisms; M9-M10 Elevated temperature substances: M9 Liquid; M10 Solid; M11 Other substances presenting a danger during carriage, but not meeting the definitions of another class. Definitions and classification 2.2.9.1.3 Substances and articles classified in Class 9 are listed in Table A of Chapter 3.2. The assignment of substances and articles not mentioned by name in Table A of Chapter 3.2 to the relevant entry of that Table or of 2.2.9.3 shall be done in accordance with 2.2.9.1.4 to 2.2.9.1.14 below. Substances which, on inhalation as fine dust, may endanger health 2.2.9.1.4 Substances which, on inhalation as fine dust, may endanger health include asbestos and mixtures containing asbestos. Substances and apparatus which, in the event of fire, may form dioxins 2.2.9.1.5 Substances and apparatus which, in the event of fire, may form dioxins include polychlorinated biphenyls (PCBs) and terphenyls (PCTs) and polyhalogenated biphenyls and terphenyls and mixtures containing these substances, as well as apparatus such as transformers, condensers and apparatus containing those substances or mixtures. NOTE: Mixtures with a PCB or PCT content of not more than 50 mg/kg are not subject to the provisions of RID. Substances evolving flammable vapour 2.2.9.1.6 Substances evolving flammable vapour include polymers containing flammable liquids with a flash-point not exceeding 55 °C. Lithium batteries 2.2.9.1.7 The term "lithium battery" covers all cells and batteries containing lithium in any form. They may be assigned to Class 9 if they meet the requirements of special provision 230 of Chapter 3.3. They are not subject to the provisions of RID if they meet the requirements of special provision 188 of Chapter 3.3. They shall be classified in accordance with the procedures of Section 38.3 of the Manual of Tests and Criteria. Life-saving appliances 2.2.9.1.8 Life-saving appliances include life-saving appliances and motor vehicle components which meet the descriptions of special provisions 235 or 296 of Chapter 3.3. 2.2.9.1.9 (Deleted) 2009/89. szám 2.2.9.1.10 Environmentally hazardous substances (aquatic environment) 2.2.9.1.10.1 General definitions 2.2.9.1.10.1.1 Environmentally hazardous substances include, inter alia, liquid or solid substances pollutant to the aquatic environment and solutions and mixtures of such substances (such as preparations and wastes). For the purposes of 2.2.9.1.10, "substance" means chemical elements and their compounds in the natural state or obtained by any production process, including any additive necessary to preserve the stability of the product and any impurities deriving from the process used, but excluding any solvent which may be separated without affecting the stability of the substance or changing its composition. 2.2.9.1.10.1.2 The aquatic environment may be considered in terms of the aquatic organisms that live in the water, and the aquatic ecosystem of which they are part10. The basis, therefore, of the identification of hazard is the aquatic toxicity of the substance or mixture, although this may be modified by further information on the degradation and bioaccumulation behaviour. 2.2.9.1.10.1.3 While the following classification procedure is intended to apply to all substances and mixtures, it is recognised that in some cases, e.g. metals or poorly soluble inorganic compounds, special guidance will be necessary11. 2.2.9.1.10.1.4 The following definitions apply for acronyms or terms used in this section: – BCF: Bioconcentration Factor; – BOD: Biochemical Oxygen Demand; – COD: Chemical Oxygen Demand; – GLP: Good Laboratory Practices; – EC50: the effective concentration of substance that causes 50% of the maximum response; – ErC50: EC50 in terms of reduction of growth; – Kow: octanol/water partition coefficient; – LC50 (50% lethal concentration): the concentration of a substance in water which causes the death of 50% (one half) in a group of test animals; – L(E)C50: LC50 or EC50; – NOEC: No Observed Effect Concentration; – OECD Test Guidelines: Test guidelines published by the Organization for Economic Cooperation and Development (OECD). 2.2.9.1.10.2 Definitions and data requirements 2.2.9.1.10.2.1 The basic elements for classification of environmentally hazardous substances (aquatic environment) are: – Acute aquatic toxicity; – Potential for or actual bioaccumulation; – Degradation (biotic or abiotic) for organic chemicals; and – Chronic aquatic toxicity. 2.2.9.1.10.2.2 While data from internationally harmonised test methods are preferred, in practice, data from national methods may also be used where they are considered as equivalent. In general, it has been agreed that freshwater and marine species toxicity data can be considered as equivalent data and are preferably to be derived using OECD Test Guidelines or equivalent according to the principles of Good Laboratory Practices (GLP). Where such data are not available, classification shall be based on the best available data. 2.2.9.1.10.2.3 Acute aquatic toxicity shall normally be determined using a fish 96 hour LC50 (OECD Test Guideline 203 or equivalent), a crustacea species 48 hour EC50 (OECD Test Guideline 202 or equivalent) and/or an algal species 72 or 96 hour EC50 (OECD Test Guideline 201 or equivalent). These species 10 This does not address aquatic pollutants for which there may be a need to consider effects beyond the aquatic environment such as the impacts on human health etc. 11 This can be found in Annex 10 of the GHS. 2009/89. szám are considered as surrogate for all aquatic organisms and data on other species such as Lemna may also be considered if the test methodology is suitable. 2.2.9.1.10.2.4 Bioaccumulation means net result of uptake, transformation and elimination of a substance in an organism due to all routes of exposure (i.e. air, water, sediment/soil and food). The potential for bioaccumulation shall normally be determined by using the octanol/water partition coefficient, usually reported as a log Kow determined according to OECD Test Guideline 107 or 117. While this represents a potential to bioaccumulate, an experimentally determined Bioconcentration Factor (BCF) provides a better measure and shall be used in preference when available. A BCF shall be determined according to OECD Test Guideline 305. 2.2.9.1.10.2.5 Environmental degradation may be biotic or abiotic (e.g. hydrolysis) and the criteria used reflect this fact. Ready biodegradation is most easily defined using the OECD biodegradability tests (OECD Test Guideline 301 (A – F)). A pass level in these tests may be considered as indicative of rapid degradation in most environments. These are freshwater tests and thus the use of the results from OECD Test Guideline 306, which is more suitable for marine environments, has also been included. Where such data are not available, a BOD5 (5 days)/COD ratio t 0.5 is considered as indicative of rapid degradation. Abiotic degradation such as hydrolysis, primary degradation, both abiotic and biotic, degradation in non-aquatic media and proven rapid degradation in the environment may all be considered in defining rapid degradability12. Substances are considered rapidly degradable in the environment if the following criteria are met: (a) In 28-day ready biodegradation studies, the following levels of degradation are achieved: (i) Tests based on dissolved organic carbon: 70%; (ii) Tests based on oxygen depletion or carbon dioxide generation: 60% of theoretical maxima; These levels of biodegradation shall be achieved within 10 days of the start of degradation which point is taken as the time when 10% of the substance has been degraded; or (b) In those cases where only BOD and COD data are available, when the ratio of BOD5/COD is t 0.5; or (c) If other convincing scientific evidence is available to demonstrate that the substance or mixture can be degraded (biotically and/or abiotically) in the aquatic environment to a level above 70% within a 28 day period. 2.2.9.1.10.2.6 Chronic toxicity data are less available than acute data and the range of testing procedures less standardised. Data generated according to the OECD Test Guidelines 210 (Fish Early Life Stage) or 211 (Daphnia Reproduction) and 201 (Algal Growth Inhibition) may be accepted. Other validated and internationally accepted tests may also be used. The "No Observed Effect Concentrations" (NOECs) or other equivalent L(E)Cx shall be used. 2.2.9.1.10.3 Substance classification categories and criteria Substances shall be classified as "environmentally hazardous substances (aquatic environment)", if they satisfy the criteria for Acute 1, Chronic 1 or Chronic 2, according to the following Tables: Acute toxicity Category: Acute 1 Acute toxicity: 96 hr LC50 (for fish) d 1 mg/l and/or 48 hr EC50 (for crustacea) d 1 mg/l and/or 72 or 96hr ErC50 (for algae or other aquatic plants) d 1 mg/l Chronic toxicity Category: Chronic 1 Acute toxicity: 96 hr LC50 (for fish) d 1 mg/l and/or 48 hr EC50 (for crustacea) d 1 mg/l and/or 72 or 96hr ErC50 (for algae or other aquatic plants) d 1 mg/l and the substance is not rapidly degradable and/or the log Kow t 4 (unless the experimentally determined BCF < 500) 12 Special guidance on data interpretation is provided in Chapter 4.1 and Annex 9 of the GHS. 2009/89. szám Category: Chronic 2 Acute toxicity: 96 hr LC50 (for fish) > 1 to d 10 mg/l and/or 48 hr EC50 (for crustacea) > 1 to d 10 mg/l and/or 72 or 96hr ErC50 (for algae or other aquatic plants) > 1 to d 10 mg/l and the substance is not rapidly degradable and/or the log Kow t 4 (unless the experimentally determined BCF < 500), unless the chronic toxicity NOECs are > 1 mg/l The classification flowchart below outlines the process to be followed: a Lowest value of 96-hour LC50, 48-hour EC50 or 72-hour or 96-hour ErC50, as appropriate. 2.2.9.1.10.4 Mixtures classification categories and criteria 2.2.9.1.10.4.1 The classification system for mixtures covers the classification categories which are used for substances meaning acute category 1 and chronic categories 1 and 2. In order to make use of all available data for purposes of classifying the aquatic environmental hazards of the mixture, the following assumption is made and is applied where appropriate: The "relevant ingredients" of a mixture are those which are present in a concentration of 1% (by mass) or greater, unless there is a presumption (e.g. in the case of highly toxic ingredients) that an L(E)C50 a d 1 mg/l Rapidly degradable Bioaccumulation NOEC > 1 mg/l L(E)C50 a d 10 mg/l Rapidly degradable Bioaccumulation Environmentally hazardous substance Acute 1 Environmentally hazardous substance Chronic 1 Environmentally hazardous substance Chronic 2 Not environmentally hazardous substance Yes No Yes Yes Yes Yes Yes No No No No Yes No No or unknown 2009/89. szám ingredient present at less than 1% can still be relevant for classifying the mixture for aquatic environmental hazards. 2.2.9.1.10.4.2 The approach for classification of aquatic environmental hazards is tiered, and is dependent upon the type of information available for the mixture itself and for its ingredients. Elements of the tiered approach include: (a) Classification based on tested mixtures; (b) Classification based on bridging principles; (c) The use of "summation of classified ingredients" and/or an "additivity formula". Figure 2.2.9.1.10.4.2 below outlines the process to be followed. Figure 2.2.9.1.10.4.2: Tiered approach to classification of mixtures for acute and chronic aquatic environmental hazards Aquatic toxicity test data available on the mixture as a whole Sufficient data available on similar mixtures to estimate hazards Apply bridging principles (2.2.9.1.10.4.4) Classify for acute/chronic toxicity hazard (2.2.9.1.10.4.3) Classify for acute/chronic toxicity hazard Either aquatic toxicity or classification data available for all relevant ingredients Apply Summation Method (2.2.9.1.10.4.6.1 to 2.2.9.1.10.4.6.4) using: x Percentage of all ingredients classified as "Chronic" x Percentage of ingredients classified as "Acute" x Percentage of ingredients with acute toxicity data: apply additivity formula (2.2.9.1.10.4.5.2) and convert the derived L(E)C50 to the appropriate "Acute" Category Classify for acute/chronic toxicity hazard Use available hazard data of known ingredients Apply Summation Method and additivity formula (2.2.9.1.10.4.6.1 to 2.2.9.1.10.4.6.4) and apply 2.2.9.1.10.4.6.5 Classify for acute/chronic toxicity hazard No Yes Yes No No Yes Yes 2009/89. szám 2.2.9.1.10.4.3 Classification of mixtures when data are available for the complete mixture 2.2.9.1.10.4.3.1 When the mixture as a whole has been tested to determine its aquatic toxicity, it shall be classified according to the criteria that have been agreed for substances, but only for acute toxicity. The classification is based on the data for fish, crustacea and algae/plants. Classification of mixtures by using LC50 or EC50 data for the mixture as a whole is not possible for chronic categories since both toxicity data and environmental fate data are needed, and there are no degradability and bioaccumulation data for mixtures as a whole. It is not possible to apply the criteria for chronic classification because the data from degradability and bioaccumulation tests of mixtures cannot be interpreted; they are meaningful only for single substances. 2.2.9.1.10.4.3.2 When there are acute toxicity test data (LC50 or EC50) available for the mixture as a whole, these data as well as information with respect to the classification of ingredients for chronic toxicity shall be used to complete the classification for tested mixtures as follows. When chronic (long term) toxicity data (NOEC) are also available, they shall be used as well. (a) L(E)C50 (LC50 or EC50) of the tested mixture d 1 mg/l and NOEC of the tested mixture d 1.0 mg/l or unknown: – classify mixture as category acute 1; – apply summation of classified ingredients approach (see 2.2.9.1.10.4.6.3 and 2.2.9.1.10.4.6.4) for chronic classification (chronic 1, 2, or no need of chronic classification); (b) L(E)C50 of the tested mixture d 1 mg/l and NOEC of the tested mixture > 1.0 mg/l: – classify mixture as category acute 1; – apply summation of classified ingredients approach (see 2.2.9.1.10.4.6.3 and 2.2.9.1.10.4.6.4) for classification as category chronic 1. If the mixture is not classified as category chronic 1, then there is no need for chronic classification; (c) L(E)C50 of the tested mixture > 1 mg/l, or above the water solubility, and NOEC of the tested mixture d 1.0 mg/l or unknown: – no need to classify for acute toxicity; – apply summation of classified ingredients approach (see 2.2.9.1.10.4.6.3 and 2.2.9.1.10.4.6.4) for chronic classification or no need for chronic classification; (d) L(E)C50 of the tested mixture > 1 mg/l, or above the water solubility, and NOEC of the tested mixture > 1.0 mg/l: – No need to classify for acute or chronic toxicity. 2.2.9.1.10.4.4 Bridging principles 2.2.9.1.10.4.4.1 Where the mixture itself has not been tested to determine its aquatic environmental hazard, but there are sufficient data on the individual ingredients and similar tested mixtures to adequately characterise the hazards of the mixture, these data shall be used in accordance with the following agreed bridging rules. This ensures that the classification process uses the available data to the greatest extent possible in characterising the hazards of the mixture without the necessity for additional testing in animals. 2.2.9.1.10.4.4.2 Dilution 2.2.9.1.10.4.4.2.1 If a mixture is formed by diluting another classified mixture or a substance with a diluent which has an equivalent or lower aquatic hazard classification than the least toxic original ingredient and which is not expected to affect the aquatic hazards of other ingredients, then the mixture shall be classified as equivalent to the original mixture or substance. 2.2.9.1.10.4.4.2.2 If a mixture is formed by diluting another classified mixture or a substance with water or other totally non-toxic material, the toxicity of the mixture shall be calculated from the original mixture or substance. 2.2.9.1.10.4.4.3 Batching The aquatic hazard classification of one production batch of a complex mixture shall be assumed to be substantially equivalent to that of another production batch of the same commercial product and produced by or under the control of the same manufacturer, unless there is reason to believe there is significant variation such that the aquatic hazard classification of the batch has changed. If the latter occurs, new classification is necessary. 2.2.9.1.10.4.4.4 Concentration of mixtures which are classified with the most severe classification categories (chronic 1 and acute 1) If a mixture is classified as chronic 1 and/or acute 1, and ingredients of the mixture which are classified as chronic 1 and/or acute 1 are further concentrated, the more concentrated mixture shall be classified with the same classification category as the original mixture without additional testing. 2009/89. szám 2.2.9.1.10.4.4.5 Interpolation within one toxicity category If mixtures A and B are in the same classification category and mixture C is made in which the toxicologically active ingredients have concentrations intermediate to those in mixtures A and B, then mixture C shall be in the same category as A and B. Note that the identity of the ingredients is the same in all three mixtures. 2.2.9.1.10.4.4.6 Substantially similar mixtures Given the following: (a) two mixtures: (i) A + B; (ii) C + B; (b) the concentration of ingredient B is the same in both mixtures; (c) the concentration of ingredient A in mixture (i) equals that of ingredient C in mixture (ii); (d) classification for A and C are available and are the same, i.e. they are in the same hazard category and are not expected to affect the aquatic toxicity of B, then there shall be no need to test mixture (ii) if mixture (i) is already characterised by testing and both mixtures are classified in the same category. 2.2.9.1.10.4.5 Classification of mixtures when data are available for all ingredients or only for some ingredients of the mixture 2.2.9.1.10.4.5.1 The classification of a mixture shall be based on summation of the concentrations of its classified ingredients. The percentage of ingredients classified as "Acute" or "Chronic" will feed straight into the summation method. Details of the summation method are described in 2.2.9.1.10.4.6.1 to 2.2.9.1.10.4.6.4. 2.2.9.1.10.4.5.2 Mixtures may be made of a combination of both ingredients that are classified (as Acute 1 and/or Chronic 1, 2) and those for which adequate test data are available. When adequate toxicity data are available for more than one ingredient in the mixture, the combined toxicity of those ingredients shall be calculated using the following additivity formula, and the calculated toxicity shall be used to assign that portion of the mixture an acute toxicity hazard which is then subsequently used in applying the summation method. ¦ ¦ n i i m i C ) E ( L C C ) E ( L C where: Ci = concentration of ingredient i (mass percentage); L(E)C50i = (mg/l) LC50 or EC50 for ingredient i; n = number of ingredients, and i is running from 1 to n; L(E)C50m = L(E)C50 of the part of the mixture with test data. 2.2.9.1.10.4.5.3 When applying the additivity formula for part of the mixture, it is preferable to calculate the toxicity of this part of the mixture using for each substance toxicity values that relate to the same species (i.e. fish, daphnia or algae) and then to use the highest toxicity (lowest value) obtained (i.e. use the most sensitive of the three species). However, when toxicity data for each ingredient are not available in the same species, the toxicity value of each ingredient shall be selected in the same manner that toxicity values are selected for the classification of substances, i.e. the higher toxicity (from the most sensitive test organism) is used. The calculated acute toxicity shall then be used to classify this part of the mixture as Acute 1 using the same criteria described for substances. 2.2.9.1.10.4.5.4 If a mixture is classified in more than one way, the method yielding the more conservative result shall be used. 2.2.9.1.10.4.6 Summation method 2.2.9.1.10.4.6.1 Classification procedure In general a more severe classification for mixtures overrides a less severe classification, e.g. a classification with chronic 1 overrides a classification with chronic 2. As a consequence the classification procedure is already completed if the result of the classification is chronic 1. A more severe classification than chronic 1 is not possible; therefore, it is not necessary to pursue the classification procedure further. 2009/89. szám 2.2.9.1.10.4.6.2 Classification for the acute category 1 2.2.9.1.10.4.6.2.1 All ingredients classified as acute 1 shall be considered. If the sum of these ingredients is greater than or equal to 25% the whole mixture shall be classified as category acute 1. If the result of the calculation is a classification of the mixture as category acute 1, the classification process is completed. 2.2.9.1.10.4.6.2.2 The classification of mixtures for acute hazards based on this summation of classified ingredients, is summarised in Table 2.2.9.1.10.4.6.2.2 below. Table 2.2.9.1.10.4.6.2.2: Classification of a mixture for acute hazards, based on summation of classified ingredients Sum of ingredients classified as: Mixture is classified as: Acute 1 x M(a)  25% Acute 1 (a) For explanation of the M factor, see 2.2.9.1.10.4.6.4. 2.2.9.1.10.4.6.3 Classification for the chronic categories 1, 2 2.2.9.1.10.4.6.3.1 First, all ingredients classified as chronic 1 are considered. If the sum of these ingredients is greater than or equal to 25% the mixture shall be classified as category chronic 1. If the result of the calculation is a classification of the mixture as category chronic 1 the classification procedure is completed. 2.2.9.1.10.4.6.3.2 In cases where the mixture is not classified as chronic 1, classification of the mixture as chronic 2 is considered. A mixture shall be classified as chronic 2 if 10 times the sum of all ingredients classified as chronic 1 plus the sum of all ingredients classified as chronic 2 is greater than or equal to 25%. If the result of the calculation is classification of the mixture as chronic 2, the classification process is completed. 2.2.9.1.10.4.6.3.3 The classification of mixtures for chronic hazards, based on this summation of classified ingredients, is summarised in Table 2.2.9.1.10.4.6.3.3 below. Table 2.2.9.1.10.4.6.3.3: Classification of a mixture for chronic hazards, based on summation of classified ingredients Sum of ingredients classified as: Mixture is classified as: Chronic 1 x M(a)  25 % Chronic 1 (M x 10 x Chronic 1) + Chronic 2  25 % Chronic 2 (a) For explanation of the M factor, see 2.2.9.1.10.4.6.4. 2.2.9.1.10.4.6.4 Mixtures with highly toxic ingredients Category acute 1 ingredients with toxicities well below 1 mg/l may influence the toxicity of the mixture and are given increased weight in applying the summation method. When a mixture contains ingredients classified as acute 1 or chronic 1, the tiered approach described in 2.2.9.1.10.4.6.2 and 2.2.9.1.10.4.6.3 shall be applied using a weighted sum by multiplying the concentrations of acute 1 ingredients by a factor, instead of merely adding up the percentages. This means that the concentration of "Acute 1" in the left column of Table 2.2.9.1.10.4.6.2.2 and the concentration of "Chronic 1" in the left column of Table 2.2.9.1.10.4.6.3.3 are multiplied by the appropriate multiplying factor. The multiplying factors to be applied to these ingredients are defined using the toxicity value, as summarised in Table 2.2.9.1.10.4.6.4 below. Therefore, in order to classify a mixture containing acute 1 and/or chronic 1 ingredients, the classifier needs to be informed of the value of the M factor in order to apply the summation method. Alternatively, the additivity formula (see 2.2.9.1.10.4.5.2) may be used when toxicity data are available for all highly toxic ingredients in the mixture and there is convincing evidence that all other ingredients, including those for which specific acute toxicity data are not available, are of low or no toxicity and do not significantly contribute to the environmental hazard of the mixture. Table 2.2.9.1.10.4.6.4: Multiplying factors for highly toxic ingredients of mixtures L(E)C50 value Multiplying factor (M) 0.1 < L(E)C50 d 1 0.01 < L(E)C50 d 0.1 0.001 < L(E)C50 d 0.01 0.0001 < L(E)C50 d 0.001 0.00001 < L(E)C50 d 0.0001 (continue in factor 10 intervals) 2009/89. szám 2.2.9.1.10.4.6.5 Classification of mixtures with ingredients without any useable information In the event that no useable information on acute and/or chronic aquatic hazard is available for one or more relevant ingredients, it is concluded that the mixture cannot be attributed (a) definitive hazard category(ies). In this situation the mixture shall be classified based on the known ingredients only with the additional statement that: "x percent of the mixture consists of ingredient(s) of unknown hazard to the aquatic environment". 2.2.9.1.10.5 Substances or mixtures dangerous to the aquatic environment not otherwise classified under RID 2.2.9.1.10.5.1 Substances or mixtures dangerous to the aquatic environment not otherwise classified under RID shall be designated: UN No. 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. or UN No. 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. They shall be assigned to packing group III. 2.2.9.1.10.5.2 Notwithstanding the provisions of 2.2.9.1.10, (a) Substances which cannot be assigned to entries other than UN Nos. 3077 and 3082 in Class 9 or to other entries in classes 1 to 8, but which are identified in Council Directive 67/548/EEC of 27 June 1967 on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances1413, as amended, as substances to which letter N "Environmentally hazardous" (R50; R50/53; R51/53) has been allocated; and (b) Solutions and mixtures (such as preparations and wastes) of substances to which letter N "Environmentally hazardous" (R50; R50/53; R51/53) has been allocated in Directive 67/548/EEC, as amended, and which, according to Directive 1999/45/EC of the European Parliament and of the Council of 31 May 1999 concerning the approximation of the laws, regulations and administrative provisions of the Member States relating to the classification, packaging and labelling of dangerous preparations1514, as amended, are also allocated letter N "Environmentally hazardous" (R50; R50/53; R51/53), and which cannot be assigned to entries other than UN Nos. 3077 and 3082 in Class 9 or to other entries in classes 1 to 8; shall be assigned to UN Nos. 3077 or 3082 of Class 9 as appropriate. Genetically modified microorganisms or organisms 2.2.9.1.11 Genetically modified microorganisms (GMMOs) and genetically modified organisms (GMOs) are microorganisms and organisms in which genetic material has been purposely altered through genetic engineering in a way that does not occur naturally. They are assigned to Class 9 (UN No. 3245) if they do not meet the definition of infectious substances, but are capable of altering animals, plants or microbiological substances in a way not normally the result of natural reproduction. NOTE 1: GMMOs and GMOs which are infectious are substances of Class 6.2, UN Nos. 2814, 2900 or 3373. 2: GMMOs or GMOs are not subject to the provisions of RID when authorized for use by the competent authorities of the countries of origin, transit and destination15. 3: Live animals shall not be used to carry genetically modified microorganisms classified in Class 9 unless the substance can be carried no other way. 2.2.9.1.12 (Reserved) Elevated temperature substances 2.2.9.1.13 Elevated temperature substances include substances which are carried or handed over for carriage in the liquid state at or above 100 °C and, in the case of those with a flash-point, below their flash-point. They also include solids which are carried or handed over for carriage at or above 240 °C. NOTE: Elevated temperature substances may be assigned to Class 9 only if they do not meet the criteria of any other class. 13 Official Journal of the European Communities No.196, of 16 August 1967, pp. 1 – 5. 14 Official Journal of the European Communities No. L 200, of 30 July 1999, pp. 1 – 68. 15 See in particular Part C of Directive 2001/18/EC of the European Parliament and of the Council on the deliberate release into the environment of genetically modified organisms and repealing Council Directive 90/220/EEC (Official Journal of the European Communities, No. L 106, of 17 April 2001, pp. 8-14), which sets out the authorization procedures for the European Community. 2009/89. szám Other substances presenting a danger during carriage but not meeting the definitions of another class. 2.2.9.1.14 The following other miscellaneous substances not meeting the definitions of another class are assigned to Class 9: Solid ammonia compounds having a flash-point below 60 °C Low hazard dithionites Highly volatile liquids Substances emitting noxious fumes Substances containing allergens Chemical kits and first aid kits NOTE: UN No. 1845 CARBON DIOXIDE, SOLID (DRY ICE), UN No. 2071 AMMONIUM NITRATE FERTILIZERS, UN No. 2216 FISH MEAL (FISH SCRAP), STABILIZED, UN No. 2807 MAGNETIZED MATERIAL, UN No. 3166 ENGINE, INTERNAL COMBUSTION or VEHICLE, FLAMMABLE GAS POWERED or VEHICLE, FLAMMABLE LIQUID POWERED, UN No. 3171 BATTERY-POWERED VEHICLE or 3171 BATTERY-POWERED EQUIPMENT (WET BATTERY), UN No. 3334 AVIATION REGULATED LIQUID, N.O.S., UN No. 3335 AVIATION REGULATED SOLID, N.O.S., UN No. 3363 DANGEROUS GOODS IN MACHINERY or UN No. 3363 DANGEROUS GOODS IN APPARATUS, listed in the UN Model Regulations, are not subject to the provisions of RID. Assignment of the packing groups 2.2.9.1.15 When indicated in column (4) of Table A of Chapter 3.2, substances and articles of Class 9 are assigned to one of the following packing groups according to their degree of danger: Packing group II: substances presenting medium danger; Packing group III: substances presenting low danger. 2.2.9.2 Substances and articles not accepted for carriage The following substances and articles shall not be accepted for carriage: – Lithium batteries which do not meet the relevant conditions of special provisions 188, 230 or 636 of Chapter 3.3. – Uncleaned empty containment vessels for apparatus such as transformers, condensers and hydraulic apparatus containing substances assigned to UN Nos. 2315, 3151, 3152 or 3432. 2.2.9.3 List of entries Classification code UN Name of the substance or article No. Miscellaneous dangerous substances and articles Substances which, on inhalation as fine dust, may M1 2212 BLUE ASBESTOS (crocidolite) or 2212 BROWN ASBESTOS (amosite, mysorite) endanger health 2590 WHITE ASBESTOS (chrysotile, actinolite, anthophyllite, tremolite) 2315 POLYCHLORINATED BIPHENYLS, LIQUID 3432 POLYCHLORINATED BIPHENYLS, SOLID Substances and apparatus which, in the event of fire, M2 3151 POLYHALOGENATED BIPHENYLS, LIQUID or 3151 POLYHALOGENATED TERPHENYLS, LIQUID may form dioxins 3152 POLYHALOGENATED BIPHENYLS, SOLID or 3152 POLYHALOGENATED TERPHENYLS, SOLID 2211 POLYMERIC BEADS, EXPANDABLE, evolving flammable vapour Substances evolving flammable vapour M3 3314 PLASTICS MOULDING COMPOUND in dough, sheet or extruded rope form evolving flammable vapour 2009/89. szám 3090 LITHIUM METAL BATTERIES (including lithium alloy batteries) Lithium batteries M4 3091 LITHIUM METAL BATTERIES CONTAINED IN EQUIPMENT (including lithium alloy batteries) or 3091 LITHIUM METAL BATTERIES PACKED WITH EQUIPMENT (including lithium alloy batteries) 3480 LITHIUM ION BATTERIES (including lithium ion polymer batteries) 3481 LITHIUM ION BATTERIES CONTAINED IN EQUIP- MENT (including lithium ion polymer batteries) or 3481 LITHIUM ION BATTERIES PACKED WITH EQUIP- MENT (including lithium ion polymer batteries) 2990 LIFE-SAVING APPLIANCES, SELF-INFLATING such as aircraft evacuation chutes, aircraft survival kits and maritime life-saving appliances Live-saving appliances M5 3072 LIFE-SAVING APPLIANCES NOT SELF-INFLATING containing dangerous goods as equipment 3268 AIR BAG INFLATORS or 3268 AIR BAG MODULES or 3268 SEAT-BELT PRETENSIONERS liquid M6 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. pollutant to the aquatic environment solid M7 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. Environmentally hazardous substances genetically modified microorganisms and organisms M8 3245 GENETICALLY MODIFIED MICROORGANISMS or GENETICALLY MODIFIED ORGANISMS liquid M9 3257 ELEVATED TEMPERATURE LIQUID, N.O.S., at or above 100 °C and below its flash-point (including molten metal, molten salts, etc.) Elevated temperature substances solid M10 3258 ELEVATED TEMPERATURE SOLID, N.O.S., at or above 240 °C Other substances or articles presenting a danger during carriage, but not meeting the definitions of another class M11 No collective entry available. Only substances listed in Table A of Chapter 3.2 are subject to the provisions for Class 9 under this classification code, as follows: 1841 ACETALDEHYDE AMMONIA 1931 ZINC DITHIONITE (ZINC HYDROSULPHITE) 1941 DIBROMODIFLUOROMETHANE 1990 BENZALDEHYDE 2969 CASTOR BEANS or 2969 CASTOR MEAL or 2969 CASTOR POMACE or 2969 CASTOR FLAKE 3316 CHEMICAL KIT or 3316 FIRST AID KIT 3359 FUMIGATED UNIT 2009/89. szám Chapter 2.3 Test methods 2.3.0 General Unless otherwise provided for in Chapter 2.2 or in this Chapter, the test methods to be used for the classification of dangerous goods are those described in the Manual of Tests and Criteria. 2.3.1 Exudation test for blasting explosives of Type A 2.3.1.1 Blasting explosives of type A (UN No. 0081) shall, if they contain more than 40% liquid nitric ester, in addition to the testing specified in the Manual of Tests and Criteria, satisfy the following exudation test. 2.3.1.2 The apparatus for testing blasting explosive for exudation (figs. 1 to 3) consists of a hollow bronze cylinder. This cylinder, which is closed at one end by a plate of the same metal, has an internal diameter of 15.7 mm and a depth of 40 mm. It is pierced by 20 holes 0.5 mm in diameter (four sets of five holes) on the circumference. A bronze piston, cylindrically fashioned over a length of 48 mm and having a total length of 52 mm, slides into the vertically placed cylinder. The piston, whose diameter is 15.6 mm, is loaded with a mass of 2 220 g so that a pressure of 120 kPa (1.20 bar) is exerted on the base of the cylinder. 2.3.1.3 A small plug of blasting explosive weighing 5 to 8 g, 30 mm long and 15 mm in diameter, is wrapped in very fine gauze and placed in the cylinder; the piston and its loading mass are then placed on it so that the blasting explosive is subjected to a pressure of 120 kPa (1.20 bar). The time taken for the appearance of the first signs of oily droplets (nitroglycerine) at the outer orifices of the cylinder holes is noted. 2.3.1.4 The blasting explosive is considered satisfactory if the time elapsing before the appearance of the liquid exudations is more than five minutes, the test having been carried out at a temperature of 15 °C to 25 °C. 2009/89. szám Test of blasting explosive for exudation Fig. 1 to 3:

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