Publication: Magyar Közlöny
Issue: MK-2006-128 (Year: 2006, Number: 128)
Era: 2004-2010
Section: 217/1998. (XII. 30.) Korm. rendelet
Paragraph Index: 4508

(29) Not subject to the requirements of RID for Class 5.2. 2006/128. szám 2.2.61 Class 6.1: Toxic substances 2.2.61.1 Criteria 2.2.61.1.1 The heading of Class 6.1 covers substances of which it is known by experience or regarding which it is presumed from experiments on animals that in relatively small quantities they are able by a single action or by action of short duration to cause damage to human health, or death, by inhalation, by cutaneous absorption or by ingestion. 2.2.61.1.2 Substances of Class 6.1 are subdivided as follows: T Toxic substances without subsidiary risk: T1 Organic, liquid; T2 Organic, solid; T3 Organometallic substances; T4 Inorganic, liquid; T5 Inorganic, solid; T6 Liquid, used as pesticides; T7 Solid, used as pesticides; T8 Samples; T9 Other toxic substances; TF Toxic substances, flammable: TF1 Liquid; TF2 Liquid, used as pesticides; TF3 Solid; TS Toxic substances, self-heating, solid; TW Toxic substances, which, in contact with water, emit flammable gases: TW1 Liquid; TW2 Solid; TO Toxic substances, oxidizing: TO1 Liquid; TO2 Solid; TC Toxic substances, corrosive: TC1 Organic, liquid; TC2 Organic, solid; TC3 Inorganic, liquid; TC4 Inorganic, solid; TFC Toxic substances, flammable, corrosive. Definitions 2.2.61.1.3 For the purposes of RID: LD50 (median lethal dose) for acute oral toxicity is the statistically derived single dose of a substance that can be expected to cause death within 14 days in 50 per cent of young adult albino rats when administered by the oral route. The LD50 value is expressed in terms of mass of test substance per mass of test animal (mg/kg); LD50 for acute dermal toxicity is that dose of the substance which, administered by continuous contact for 24 hours with the bare skin of albino rabbits, is most likely to cause death within 14 days in one half of the animals tested. The number of animals tested shall be sufficient to give a statistically significant result and be in conformity with good pharmacological practice. The result is expressed in milligrams per kg body mass; LC50 for acute toxicity on inhalation is that concentration of vapour, mist or dust which, administered by continuous inhalation to both male and female young adult albino rats for one hour, is most likely to cause death within 14 days in one half of the animals tested. A solid substance shall be tested if at least 10% (by mass) of its total mass is likely to be dust in a respirable range, e.g. the aerodynamic diameter of that particle-fraction is 10 µm or less. A liquid substance shall be tested if a mist is likely to be generated in a leakage of the transport containment. Both for solid and liquid substances more than 90% (by mass) of a specimen prepared for inhalation toxicity shall be in the respirable range as defined above. The result is expressed in milligrams per litre of air for dusts and mists or in millilitres per cubic metre of air (parts per million) for vapours. 2006/128. szám Classification and assignment of packing groups 2.2.61.1.4 Substances of Class 6.1 shall be classified in three packing groups according to the degree of danger they present for carriage, as follows: Packing group I: highly toxic substances Packing group II: toxic substances Packing group III: slightly toxic substances. 2.2.61.1.5 Substances, mixtures, solutions and articles classified in Class 6.1 are listed in Table A of Chapter 3.2. The assignment of substances, mixtures and solutions not mentioned by name in Table A of Chapter 3.2 to the relevant entry of 2.2.61.3 and to the relevant packing group in accordance with the provisions of Chapter 2.1, shall be made according to the following criteria in 2.2.61.1.6 to 2.2.61.1.11. 2.2.61.1.6 To assess the degree of toxicity, account shall be taken of human experience of instances of accidental poisoning, as well as special properties possessed by any individual substances: liquid state, high volatility, any special likelihood of cutaneous absorption, and special biological effects. 2.2.61.1.7 In the absence of observations on humans, the degree of toxicity shall be assessed using the available data from animal experiments in accordance with the table below: Packing group Oral toxicity LD50 (mg/kg) Dermal toxicity LD50 (mg/kg) Toxicity on inhalation of dusts and mists LC50 (mg/l) Highly toxic I ≤ 5 ≤ 40 ≤ 0.5 Toxic II > 5 – 50 > 40 – 200 > 0.5 – 2 Slightly toxic III(a) solids: > 50 – 200 liquids: > 50 – 500 > 200 – 1000 > 2 – 10 (a) Tear gas substances shall be included in packing group II even if data concerning their toxicity correspond to packing group III criteria. 2.2.61.1.7.1 Where a substance exhibits different degrees of toxicity for two or more kinds of exposure, it shall be classified under the highest such degree of toxicity. 2.2.61.1.7.2 Substances meeting the criteria of Class 8 and with an inhalation toxicity of dusts and mists (LC50) leading to packing group I shall only be accepted for an allocation to Class 6.1 if the toxicity through oral ingestion or dermal contact is at least in the range of packing groups I or II. Otherwise an assignment to Class 8 shall be made if appropriate (see 2.2.8.1.5). 2.2.61.1.7.3 The criteria for inhalation toxicity of dusts and mists are based on LC50 data relating to 1-hour exposure, and where such information is available it shall be used. However, where only LC50 data relating to 4-hour exposure are available, such figures can be multiplied by four and the product substituted in the above criteria, i.e. LC50 value multiplied by four (4 hour) is considered the equivalent of LC50 (1 hour). Inhalation toxicity of vapours 2.2.61.1.8 Liquids giving off toxic vapours shall be classified into the following groups where "V" is the saturated vapour concentration (in ml/m3 of air) (volatility) at 20 °C and standard atmospheric pressure: Packing group Highly toxic I Where V  10 LC50 and LC50  1 000 ml/m3 Toxic II Where V  LC50 and LC50  3 000 ml/m3 and the criteria for packing group I are not met Slightly toxic III(a) Where V  1/5 LC50 and LC50  5 000 ml/m3 and the criteria for packing groups I and II are not met (a) Tear gas substances shall be included in packing group II even if data concerning their toxicity correspond to packing group III criteria. 2006/128. szám These criteria for inhalation toxicity of vapours are based on LC50 data relating to 1-hour exposure, and where such information is available, it shall be used. However, where only LC50 data relating to 4-hour exposure to the vapours are available, such figures can be multiplied by two and the product substituted in the above criteria, i.e. LC50 (4 hour) × 2 is considered the equivalent of LC50 (1 hour). Group borderlines inhalation toxicity of vapours In this figure, the criteria are expressed in graphical form, as an aid to easy classification. However, due to approximations inherent in the use of graphs, substances falling on or near group borderlines shall be checked using numerical criteria. Mixtures of liquids 2.2.61.1.9 Mixtures of liquids which are toxic on inhalation shall be assigned to packing groups according to the following criteria: 2.2.61.1.9.1 If LC50 is known for each of the toxic substances constituting the mixture, the packing group may be determined as follows: (a) Calculation of the LC50 of the mixture: LC50 (mixture) = f LC i i i n =¦ where Volatility ml/m LC50 ml/m Not dangerous for transport Packing group III Packing group II Packing group I 2006/128. szám fi = molar fraction of constituent i of the mixture; LC50i = average lethal concentration of constituent i in ml/m3. (b) Calculation of volatility of each mixture constituent: Vi = Pi x . (ml/m3) where Pi = partial pressure of constituent i in kPa at 20 °C and at standard atmospheric pressure. (c) Calculation of the ratio of volatility to LC50: R = V LC i i i n =¦ (d) The values calculated for LC50 (mixture) and R are then used to determine the packing group of the mixture: Packing group I: R ≥ 10 and LC50 (mixture) ≤ 1 000 ml/m3; Packing group II: R  1 and LC50 (mixture) ≤ 3 000 ml/m3, if the mixture does not meet the criteria for packing group I; Packing group III: R ≥ 1/5 and LC50 (mixture) ≤ 5 000 ml/m3, if the mixture does not meet the criteria of packing groups I or II. 2.2.61.1.9.2 In the absence of LC50 data on the toxic constituent substances, the mixture may be assigned to a group based on the following simplified threshold toxicity tests. When these threshold tests are used, the most restrictive group shall be determined and used for carrying the mixture. 2.2.61.1.9.3 A mixture is assigned to packing group I only if it meets both of the following criteria: (a) A sample of the liquid mixture is vaporized and diluted with air to create a test atmosphere of 1000 ml/m3 vaporized mixture in air. Ten albino rats (5 male and 5 female) are exposed to the test atmosphere for 1 hour and observed for 14 days. If five or more of the animals die within the 14-day observation period, the mixture is presumed to have an LC50 equal to or less than 1000 ml/m3; (b) A sample of vapour in equilibrium with the liquid mixture is diluted with 9 equal volumes of air to form a test atmosphere. Ten albino rats (5 male and 5 female) are exposed to the test atmosphere for 1 hour and observed for 14 days. If five or more of the animals die within the 14-day observation period, the mixture is presumed to have a volatility equal to or greater than 10 times the mixture LC50. 2.2.61.1.9.4 A mixture is assigned to packing group II only if it meets both of the following criteria, and does not meet the criteria for packing group I: (a) A sample of the liquid mixture is vaporized and diluted with air to create a test atmosphere of 3000 ml/m3 vaporized mixture in air. Ten albino rats (5 male and 5 female) are exposed to the test atmosphere for 1 hour and observed for 14 days. If five or more of the animals die within the 14-day observation period, the mixture is presumed to have an LC50 equal to or less than 3000 ml/m3; (b) A sample of the vapour in equilibrium with the liquid mixture is used to form a test atmosphere. Ten albino rats (5 male and 5 female) are exposed to the test atmosphere for 1 hour and observed for 14 days. If five or more of the animals die within the 14-day observation period, the mixture is presumed to have a volatility equal to or greater than the mixture LC50. 2.2.61.1.9.5 A mixture is assigned to packing group III only if it meets both of the following criteria, and does not meet the criteria for packing groups I or II: (a) A sample of the liquid mixture is vaporized and diluted with air to create a test atmosphere of 5000 ml/m3 vaporized mixture in air. Ten albino rats (5 male and 5 female) are exposed to the test atmosphere for 1 hour and observed for 14 days. If five or more of the animals die within the 14-day observation period, the mixture is presumed to have an LC50 equal to or less than 5000 ml/m3; (b) The vapour concentration (volatility) of the liquid mixture is measured and if the vapour concentration is equal to or greater than 1000 ml/m3, the mixture is presumed to have a volatility equal to or greater than 1/5 the mixture LC50. Methods for determining oral and dermal toxicity of mixtures 2.2.61.1.10 When classifying and assigning the appropriate packing group to mixtures in Class 6.1 in accordance with the oral and dermal toxicity criteria (see 2.2.61.1.3), it is necessary to determine the acute LD50 of the mixture. 2.2.61.1.10.1 If a mixture contains only one active substance, and the LD50 of that constituent is known, in the absence of reliable acute oral and dermal toxicity data on the actual mixture to be carried, the oral or dermal LD50 may be obtained by the following method: 2006/128. szám mass by substance active of percentage substance active of value LD n preparatio of value LD × = 2.2.61.1.10.2 If a mixture contains more than one active constituent, there are three possible approaches that may be used to determine the oral or dermal LD50 of the mixture. The preferred method is to obtain reliable acute oral and dermal toxicity data on the actual mixture to be carried. If reliable, accurate data is not available, then either of the following methods may be performed: (a) Classify the formulation according to the most hazardous constituent of the mixture as if that constituent were present in the same concentration as the total concentration of all active constituents; or (b) Apply the formula: M Z Z B B A A T T C ... T C T C = + + + where: C = the percentage concentration of constituent A, B, ..., Z in the mixture; T = the oral LD50 values of constituent A, B, ... Z; TM = the oral LD50 value of the mixture. NOTE: This formula can also be used for dermal toxicities provided that this information is available on the same species for all constituents. The use of this formula does not take into account any potentiation or protective phenomena. Classification of pesticides 2.2.61.1.11 All active pesticide substances and their preparations for which the LC50 and/or LD50 values are known and which are classified in Class 6.1 shall be classified under appropriate packing groups in accordance with the criteria given in 2.2.61.1.6 to 2.2.61.1.9. Substances and preparations which are characterized by subsidiary risks shall be classified according to the precedence of hazard Table in 2.1.3.10 with the assignment of appropriate packing groups. 2.2.61.1.11.1 If the oral or dermal LD50 value for a pesticide preparation is not known, but the LD50 value of its active substance(s) is known, the LD50 value for the preparation may be obtained by applying the procedures in 2.2.61.1.10. NOTE: LD50 toxicity data for a number of common pesticides may be obtained from the most current edition of the document "The WHO Recommended Classification of Pesticides by Hazard and Guidelines to Classification" available from the International Programme on Chemical Safety, World Health Organisation (WHO), 1211 Geneva 27, Switzerland. While that document may be used as a source of LD50 data for pesticides, its classification system shall not be used for purposes of transport classification of, or assignment of packing groups to, pesticides, which shall be in accordance with the requirements of RID. 2.2.61.1.11.2 The proper shipping name used in the carriage of the pesticide shall be selected on the basis of the active ingredient, of the physical state of the pesticide and any subsidiary risks it may exhibit (see 3.1.2). 2.2.61.1.12 If substances of Class 6.1, as a result of admixtures, come into categories of risk different from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures or solutions shall be assigned to the entries to which they belong on the basis of their actual degree of danger. NOTE: For the classification of solutions and mixtures (such as preparations and wastes), see also 2.1.3. 2.2.61.1.13 On the basis of the criteria of 2.2.61.1.6 to 2.2.61.1.11, it may also be determined whether the nature of a solution or mixture mentioned by name or containing a substance mentioned by name is such that the solution or mixture is not subject to the requirements for this Class. 2.2.61.1.14 Substances, solutions and mixtures, with the exception of substances and preparations used as pesticides, which do not meet the criteria of Directives 67/548/EEC2 or 88/379/EEC3 as amended and which are not therefore classified as highly toxic, toxic or harmful according to these directives, as amended, may be considered as substances not belonging to Class 6.1. Council Directive 67/548/EEC of 27 June 1967 on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances (Official Journal of the European Communities No. L 196 of 16.08.1967, page 1). Council Directive 88/379/EEC of 7 June 1988 on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous preparations (Official Journal of the European Communities No. L 187 of 16.07.1988, page 14). 2006/128. szám 2.2.61.2 Substances not accepted for carriage 2.2.61.2.1 Chemically unstable substances of Class 6.1 shall not be accepted for carriage unless the necessary steps have been taken to prevent their dangerous decomposition or polymerization during carriage. To this end, it shall in particular be ensured that receptacles and tanks do not contain any substance(s) likely to cause such a reaction. 2.2.61.2.2 The following substances and mixtures shall not be accepted for carriage: – Hydrogen cyanide, anhydrous or in solution, which do not meet the descriptions of UN Nos. 1051, 1613, 1614 and 3294; – Metal carbonyls, having a flash-point below 23 °C, other than UN Nos. 1259 NICKEL CARBONYL and 1994 IRON PENTACARBONYL; – 2,3,7,8-TETRACHLORODIBENZO-P-DIOXINE (TCDD) in concentrations considered highly toxic in accordance with the criteria in 2.2.61.1.7; – UN No. 2249 DICHLORODIMETHYL ETHER, SYMMETRICAL; – Preparations of phosphides without additives inhibiting the emission of toxic flammable gases. The following substances shall not be accepted for carriage by rail: – Barium azide, dry or with less than 50% water or alcohols; – UN 0135 MERCURY FULMINATE. 2006/128. szám 2.2.61.3 List of collective entries Subsidiary risk Classification code UN Name of the substance or article No. Toxic substances 1583 CHLOROPICRIN MIXTURE, N.O.S. 1602 DYE, LIQUID, TOXIC, N.O.S., or 1602 DYE INTERMEDIATE, LIQUID, TOXIC, N.O.S. 1693 TEAR GAS SUBSTANCE, LIQUID, N.O.S. 1851 MEDICINE, LIQUID, TOXIC, N.O.S. 2206 ISOCYANATES, TOXIC, N.O.S. or 2206 ISOCYANATE SOLUTION, TOXIC, N.O.S. liquid(a) T1 3140 ALKALOIDS, LIQUID, N.O.S. or 3140 ALKALOID SALTS, LIQUID, N.O.S. 3142 DISINFECTANT, LIQUID, TOXIC, N.O.S. 3144 NICOTINE COMPOUND, LIQUID, N.O.S. or 3144 NICOTINE PREPARATION, LIQUID, N.O.S. 3172 TOXINS, EXTRACTED FROM LIVING SOURCES, LIQUID, N.O.S. 3276 NITRILES, TOXIC, LIQUID, N.O.S. 3278 ORGANOPHOSPHORUS COMPOUND, TOXIC, LIQUID, N.O.S. 3381 TOXIC BY INHALATION LIQUID, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 3382 TOXIC BY INHALATION LIQUID, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 2810 TOXIC LIQUID, ORGANIC, N.O.S. organic 1544 ALKALOIDS, SOLID, N.O.S. or 1544 ALKALOID SALTS, SOLID, N.O.S. 1601 DISINFECTANT, SOLID, TOXIC, N.O.S. 1655 NICOTINE COMPOUND, SOLID, N.O.S., or 1655 NICOTINE PREPARATION, SOLID, N.O.S. solid(a),(b) T2 3143 DYE, SOLID, TOXIC, N.O.S. or 3143 DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. 3249 MEDICINE, SOLID, TOXIC, N.O.S. 3439 NITRILES, TOXIC, SOLID, N.O.S. 3448 TEAR GAS SUBSTANCE, SOLID, N.O.S. 3462 TOXINS, EXTRACTED FROM LIVING SOURCES, SOLID, N.O.S. 3464 ORGANOPHOSPHORUS COMPOUND, TOXIC, SOLID, N.O.S. 2811 TOXIC SOLID, ORGANIC, N.O.S. Without subsidiary 2026 PHENYLMERCURIC COMPOUND, N.O.S. risk 2788 ORGANOTIN COMPOUND, LIQUID, N.O.S. 3146 ORGANOTIN COMPOUND, SOLID, N.O.S. 3280 ORGANOARSENIC COMPOUND, LIQUID, N.O.S. organometallic(c),(d) T3 3281 METAL CARBONYLS, LIQUID, N.O.S. 3465 ORGANOARSENIC COMPOUND, SOLID, N.O.S. 3466 METAL CARBONYLS, SOLID, N.O.S. 3282 ORGANOMETALLIC COMPOUND, TOXIC, LIQUID, N.O.S. 3467 ORGANOMETALLIC COMPOUND, TOXIC, SOLID, N.O.S. 2006/128. szám Without subsidiary risk 1556 ARSENIC COMPOUND, LIQUID, N.O.S., inorganic including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. (cont’d) 1935 CYANIDE SOLUTION, N.O.S. T4 2024 MERCURY COMPOUND, LIQUID, N.O.S. liquid(e) 3141 ANTIMONY COMPOUND, INORGANIC, LIQUID, N.O.S. 3440 SELENIUM COMPOUND, LIQUID, N.O.S. 3381 TOXIC BY INHALATION LIQUID, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 3382 TOXIC BY INHALATION LIQUID, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 3287 TOXIC LIQUID, INORGANIC, N.O.S. inorganic 1549 ANTIMONY COMPOUND, INORGANIC, SOLID, N.O.S. 1557 ARSENIC COMPOUND, SOLID, N.O.S., including: Arsenates, n.o.s.; Arsenites, n.o.s.; and Arsenic sulphides, n.o.s. 1564 BARIUM COMPOUND, N.O.S. 1566 BERYLLIUM COMPOUND, N.O.S. 1588 CYANIDES, INORGANIC, SOLID, N.O.S. 1707 THALLIUM COMPOUND, N.O.S. 2025 MERCURY COMPOUND, SOLID, N.O.S. solid(f)(g) T5 2291 LEAD COMPOUND, SOLUBLE, N.O.S. 2570 CADMIUM COMPOUND 2630 SELENATES or 2630 SELENITES 2856 FLUOROSILICATES, N.O.S. 3283 SELENIUM COMPOUND, SOLID, N.O.S. 3284 TELLURIUM COMPOUND, N.O.S. 3285 VANADIUM COMPOUND, N.O.S. 3288 TOXIC SOLID, INORGANIC, N.O.S. 2992 CARBAMATE PESTICIDE, LIQUID, TOXIC 2994 ARSENICAL PESTICIDE, LIQUID, TOXIC 2996 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC 2998 TRIAZINE PESTICIDE, LIQUID, TOXIC 3006 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC 3010 COPPER BASED PESTICIDE, LIQUID, TOXIC 3012 MERCURY BASED PESTICIDE, LIQUID, TOXIC liquid(h) T6 3014 SUBSTITUTED NITROPHENOL PESTICIDE, LIQ- UID, TOXIC 3016 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC 3018 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC 3020 ORGANOTIN PESTICIDE, LIQUID, TOXIC 3026 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC pesticides 3348 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC 3352 PYRETHROID PESTICIDE, LIQUID, TOXIC 2902 PESTICIDE, LIQUID, TOXIC, N.O.S. 2006/128. szám Without susidiary risk (cont’d) 2757 CARBAMATE PESTICIDE, SOLID, TOXIC 2759 ARSENICAL PESTICIDE, SOLID, TOXIC 2761 ORGANOCHLORINE PESTICIDE, SOLID, TOXIC 2763 TRIAZINE PESTICIDE, SOLID, TOXIC 2771 THIOCARBAMATE PESTICIDE, SOLID, TOXIC 2775 COPPER BASED PESTICIDE, SOLID, TOXIC 2777 MERCURY BASED PESTICIDE, SOLID, TOXIC 2779 SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC solid(h) T7 2781 BIPYRIDILIUM PESTICIDE, SOLID, TOXIC 2783 ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC 2786 ORGANOTIN PESTICIDE, SOLID, TOXIC 3027 COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC 3048 ALUMINIUM PHOSPHIDE PESTICIDE 3345 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC 3349 PYRETHROID PESTICIDE, SOLID, TOXIC 2588 PESTICIDE, SOLID, TOXIC, N.O.S. samples T8 3315 CHEMICAL SAMPLE, TOXIC other toxic substances(i) T9 3243 SOLIDS CONTAINING TOXIC LIQUID, N.O.S. 3071 MERCAPTANS, LIQUID, TOXIC, FLAMMABLE, N.O.S. or 3071 MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAM- MABLE, N.O.S. liquid(j),(k) TF1 3080 ISOCYANATES, TOXIC, FLAMMABLE, N.O.S. or 3080 ISOCYANATE SOLUTION, TOXIC, FLAMMABLE, N.O.S. 3275 NITRILES, TOXIC, FLAMMABLE, N.O.S. 3279 ORGANOPHOSPHORUS COMPOUND, TOXIC, FLAMMABLE, N.O.S. 3383 TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 3384 TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 Flammable 2929 TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. TF 2006/128. szám Flammable TF (cont’d) 2991 CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAM- MABLE 2993 ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAM- MABLE 2995 ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE 2997 TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMA- BLE 3005 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE 3009 COPPER BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE 3011 MERCURY BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE pesticides (flash-point not TF2 3013 SUBSTITUTED NITROPHENOL PESTICIDE, LIQ- UID, TOXIC, FLAMMABLE less than 23 °C) 3015 BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE 3017 ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE 3019 ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAM- MABLE 3025 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE 3347 PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE 3351 PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE 2903 PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S. 1700 TEAR GAS CANDLES solid TF3 2930 TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. Solid, self-heating(c) TS 3124 TOXIC SOLID, SELF-HEATING, N.O.S. liquid TW1 3385 TOXIC BY INHALATION LIQUID, WATER- REACTIVE, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 3386 TOXIC BY INHALATION LIQUID, WATER- REACTIVE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 3123 TOXIC LIQUID, WATER-REACTIVE, N.O.S. Waterreactive(d) solid(l) TW2 3125 TOXIC SOLID, WATER-REACTIVE, N.O.S. TW liquid TO1 3387 TOXIC BY INHALATION LIQUID, OXIDIZING, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 3388 TOXIC BY INHALATION LIQUID, OXIDIZING, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 3122 TOXIC LIQUID, OXIDIZING, N.O.S. Oxidizing(m) TO solid TO2 3086 TOXIC SOLID, OXIDIZING, N.O.S. 2006/128. szám TC1 3277 CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S. liquid 3361 CHLOROSILANES, TOXIC, CORROSIVE, N.O.S. 3389 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 3390 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 2927 TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. organic solid TC2 2928 TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. Corrosive(n) TC liquid TC3 3389 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapour concentration greater than or equal to 500 LC50 3390 TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapour concentration greater than or equal to 10 LC50 3289 TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S. inorganic solid TC4 3290 TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S. Flammable, corrosive TFC 2742 CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. 3362 CHLOROSILANES, TOXIC, CORROSIVE, FLAM- MABLE, N.O.S. (No other collective entry available; if need be, classification under a collective entry with a classification code to be determined according to the table of precedence of hazards in 2.1.3.10) Footnotes (a) Substances and preparations containing alkaloids or nicotine used as pesticides shall be classified under UN No. 2588 PESTICIDES, SOLID, TOXIC, N.O.S., UN No. 2902 PESTICIDES, LIQUID, TOXIC, N.O.S. or UN No. 2903 PESTICIDES, LIQUID, TOXIC, FLAMMABLE, N.O.S. (b) Active substances and triturations or mixtures of substances intended for laboratories and experiments and for the manufacture of pharmaceutical products with other substances shall be classified according to their toxicity (see 2.2.61.1.7 to 2.2.61.1.11). (c) Self-heating substances, slightly toxic and spontaneously combustible organometallic compounds, are substances of Class 4.2. (d) Water-reactive substances, slightly toxic, and water-reactive organometallic compounds, are substances of Class 4.3. (e) Mercury fulminate, wetted with not less than 20% water, or mixture of alcohol and water by mass is a substance of Class 1, UN No. 0135 and shall not be accepted for carriage by rail (see 2.2.61.2.2). (f) Ferricyanides, ferrocyanides, alkaline thiocyanates and ammonium thiocyanates are not subject to the provisions of RID. (g) Lead salts and lead pigments which, when mixed in a ratio of 1:1000 with 0.07M hydrochloric acid and stirred for one hour at a temperature of 23 °C ± 2 °C, exhibit a solubility of 5% or less, are not subject to the provisions of RID. (h) Articles impregnated with this pesticide, such as fibreboard plates, paper strips, cotton-wool balls, sheets of plastics material, in hermetically closed wrappings, are not subject to the provisions of RID. (i) Mixtures of solids which are not subject to the provisions of RID and of toxic liquids may be carried under UN No. 3243 without first applying the classification criteria of Class 6.1, provided there is no free liquid visible at the time the substance is loaded or at the time the packaging, wagon or container is 2006/128. szám closed. Each packaging shall correspond to a design type that has passed a leakproofness test at the packing group II level. This entry shall not be used for solids containing a packing group I liquid. (j) Highly toxic or toxic, flammable liquids having a flash-point below 23 °C excluding substances which are highly toxic on inhalation, i.e. UN Nos. 1051, 1092, 1098, 1143, 1163, 1182, 1185, 1238, 1239, 1244, 1251, 1259, 1613, 1614, 1695, 1994, 2334, 2382, 2407, 2438, 2480, 2482, 2484, 2485, 2606, 2929, 3279 and 3294 are substances of Class 3. (k) Flammable liquids, slightly toxic, with the exception of substances and preparations used as pesticides, having a flash-point between 23 °C and 61 °C inclusive, are substances of Class 3. (l) Metal phosphides assigned to UN Nos. 1360, 1397, 1432, 1714, 2011 and 2013 are substances of Class 4.3. (m) Oxidizing substances, slightly toxic, are substances of Class 5.1. (n) Substances slightly toxic and slightly corrosive, are substances of Class 8. 2006/128. szám 2.2.62 Class 6.2: Infectious substances 2.2.62.1 Criteria 2.2.62.1.1 The heading of Class 6.2 covers infectious substances. For the purposes of RID, infectious substances are substances which are known or are reasonably expected to contain pathogens. Pathogens are defined as micro-organisms (including bacteria, viruses, rickettsia, parasites, fungi) and other agents such as prions, which can cause disease in humans or animals. NOTE 1: Genetically modified micro-organisms and organisms, biological products, diagnostic specimens and infected live animals shall be assigned to this Class if they meet the conditions for this Class. 2: Toxins from plant, animal or bacterial sources which do not contain any infectious substances or organisms or which are not contained in them are substances of Class 6.1, UN No. 3172 or 3462. 2.2.62.1.2 Substances of Class 6.2 are subdivided as follows: I1 Infectious substances affecting humans; I2 Infectious substances affecting animals only; I3 Clinical waste; I4 Diagnostic specimens. Definitions 2.2.62.1.3 For the purposes of RID: "Biological products" are those products derived from living organisms which are manufactured and distributed in accordance with the requirements of appropriate national authorities, which may have special licensing requirements, and are used either for prevention, treatment, or diagnosis of disease in humans or animals, or for development, experimental or investigational purposes related thereto. They include, but are not limited to, finished or unfinished products such as vaccines; "Cultures (laboratory stocks)" are the result of a process by which pathogens are amplified or propagated in order to generate high concentrations, thereby increasing the risk of infection when exposure to them occurs. This definition refers to cultures prepared for the intentional generation of pathogens and does not include cultures intended for diagnostic and clinical purposes; "Genetically modified micro-organisms and organisms" are micro-organisms and organisms in which genetic material has been purposely altered through genetic engineering in a way that does not occur naturally; "Medical or clinical wastes" are wastes derived from the medical treatment of animals or humans or from bio-research. Classification 2.2.62.1.4 Infectious substances shall be classified in Class 6.2 and assigned to UN Nos. 2814, 2900 or 3373, as appropriate. Infectious substances are divided into the following categories: 2.2.62.1.4.1 Category A: An infectious substance which is carried in a form that, when exposure to it occurs, is capable of causing permanent disability, life-threatening or fatal disease to humans or animals. Indicative examples of substances that meet these criteria are given in the table in this paragraph. NOTE: An exposure occurs when an infectious substance is released outside of the protective packaging, resulting in physical contact with humans or animals. (a) Infectious substances meeting these criteria which cause disease in humans or both in humans and animals shall be assigned to UN No. 2814. Infectious substances which cause disease only in animals shall be assigned to UN No. 2900; (b) Assignment to UN No. 2814 or UN No. 2900 shall be based on the known medical history and symptoms of the source human or animal, endemic local conditions, or professional judgement concerning individual circumstances of the source human or animal. NOTE 1: The proper shipping name for UN No. 2814 is "INFECTIOUS SUBSTANCE, AFFECTING HU- MANS". The proper shipping name for UN No. 2900 is "INFECTIOUS SUBSTANCE, AFFECT- ING ANIMALS only". 2: The following table is not exhaustive. Infectious substances, including new or emerging pathogens, which do not appear in the table but which meet the same criteria shall be assigned to Category A. In addition, if there is doubt as to whether or not a substance meets the criteria it shall be included in Category A. 2006/128. szám 3: In the following table, the micro-organisms written in italics are bacteria, mycoplasmas, rickettsia or fungi. Indicative examples of infectious substances included in Category A in any form unless otherwise indicated (see 2.2.62.1.4.1) UN Number and name Micro-organism Bacillus anthracis (cultures only) Brucella abortus (cultures only) Brucella melitensis (cultures only) Brucella suis (cultures only) Burkholderia mallei – Pseudomonas mallei – Glanders (cultures only) Burkholderia pseudomallei – Pseudomonas pseudomallei (cultures only) Chlamydia psittaci – avian strains (cultures only) Clostridium botulinum (cultures only) Coccidioides immitis (cultures only) Coxiella burnetii (cultures only) Crimean-Congo hemorrhagic fever virus Dengue virus (cultures only) Eastern equine encephalitis virus (cultures only) Escherichia coli, verotoxigenic (cultures only) Ebola virus Flexal virus Francisella tularensis (cultures only) Guanarito virus Hantaan virus Hantaviruses causing hantavirus pulmonary syndrome Hendra virus Hepatitis B virus (cultures only) Herpes B virus (cultures only) Human immunodeficiency virus (cultures only) Highly pathogenic avian influenza virus (cultures only) Japanese Encephalitis virus (cultures only) Junin virus Kyasanur Forest disease virus Lassa virus Machupo virus Marburg virus Monkeypox virus Mycobacterium tuberculosis (cultures only) Nipah virus Omsk hemorrhagic fever virus Poliovirus (cultures only) Rabies virus Rickettsia prowazekii (cultures only) Rickettsia rickettsii (cultures only) Rift Valley fever virus Russian spring-summer encephalitis virus (cultures only) Sabia virus Shigella dysenteriae type 1 (cultures only) Tick-borne encephalitis virus (cultures only) Variola virus Venezuelan equine encephalitis virus West Nile virus (cultures only) Yellow fever virus (cultures only) UN No. 2814 INFECTIOUS SUB- STANCES AFFECT- ING HUMANS Yersinia pestis (cultures only) 2006/128. szám UN Number and name Micro-organism African horse sickness virus African swine fever virus Avian paramyxovirus Type 1 – Newcastle disease virus Bluetongue virus Classical swine fever virus Foot and mouth disease virus Lumpy skin disease virus Mycoplasma mycoides – Contagious bovine pleuropneumonia Peste des petits ruminants virus Rinderpest virus Sheep-pox virus Goatpox virus Swine vesicular disease virus UN No. 2900 INFECTIOUS SUB- STANCES AFFECT- ING ANIMALS only Vesicular stomatitis virus 2.2.62.1.4.2 Category B: An infectious substance which does not meet the criteria for inclusion in Category A. Infectious substances in Category B shall be assigned to UN No. 3373 except that cultures, as defined in 2.2.62.1.3, shall be assigned to UN No. 2814 or UN No. 2900 as appropriate. NOTE: The proper shipping name of UN No. 3373 is "DIAGNOSTIC SPECIMENS" or "CLINICAL SPECI- MENS". 2.2.62.1.5 Substances which do not contain infectious substances or substances which are unlikely to cause disease in humans or animals are not subject to the provisions of RID unless they meet the criteria for inclusion in another class. 2.2.62.1.6 Blood or blood components which have been collected for the purposes of transfusion or for the preparation of blood products to be used for transfusion or transplantation and any tissues or organs intended for use in transplantation are not subject to the provisions of RID. 2.2.62.1.7 Substances for which there is a low probability that infectious substances are present, or where the concentration is at a level naturally encountered, are not subject to the provisions of RID. Examples are: foodstuffs, water samples, living persons and substances which have been treated so that the pathogens have been neutralized or deactivated. 2.2.62.1.8 A live animal which has been intentionally infected and is known or suspected to contain an infectious substance shall only be carried under terms and conditions approved by the competent authority4. 2.2.62.1.9 Biological products For the purposes of RID, biological products are divided into the following groups: (a) those which are manufactured and packaged in accordance with the requirements of appropriate national authorities and carried for the purposes of final packaging or distribution, and use for personal health care by medical professionals or individuals. Substances in this group are not subject to the provisions of RID; (b) those which do not fall under paragraph (a) and are known or reasonably believed to contain infectious substances and which meet the criteria for inclusion in Category A or Category B. Substances in this group shall be assigned to UN Nos. 2814, 2900 or 3373, as appropriate. NOTE: Some licensed biological products may present a biohazard only in certain parts of the world. In that case, competent authorities may require these biological products to be in compliance with local requirements for infectious substances or may impose other restrictions. 2.2.62.1.10 Genetically modified micro-organisms and organisms Genetically modified micro-organisms not meeting the definition of infectious substance shall be classified according to section 2.2.9. Such regulations are contained in, e.g. Directive 91/628/EEC (Official Journal of the European Communities No. L 340 of 11 December 1991, p. 17) and in the Recommendations of the Council of Europe (Ministerial Committee) on the carriage of certain animal species. 2006/128. szám 2.2.62.1.11 Medical or clinical wastes 2.2.62.1.11.1 Medical or clinical wastes containing Category A infectious substances or containing Category B infectious substances in cultures shall be assigned to UN No. 2814 or UN No. 2900 as appropriate. Medical or clinical wastes containing infectious substances in Category B, other than cultures, shall be assigned to UN No. 3291. 2.2.62.1.11.2 Medical or clinical wastes which are reasonably believed to have a low probability of containing infectious substances shall be assigned to UN No. 3291. NOTE: The proper shipping name for UN No. 3291 is "CLINICAL WASTE, UNSPECIFIED, N.O.S." or "(BIO) MEDICAL WASTE, N.O.S". or "REGULATED MEDICAL WASTE, N.O.S.". 2.2.62.1.11.3 Decontaminated medical or clinical wastes which previously contained infectious substances are not subject to the provisions of RID unless they meet the criteria for inclusion in another class. 2.2.62.1.11.4 Medical or clinical wastes assigned to UN No. 3291 are assigned to packing group II. 2.2.62.2 Substances not accepted for carriage Live vertebrate or invertebrate animals shall not be used to carry an infectious agent unless the agent cannot be carried by other means or unless this carriage has been approved by the competent authority (see 2.2.62.1.8). 2.2.62.3 List of collective entries Classification code UN Name of the substance or article No. Infectious substances Effects on humans I1 2814 INFECTIOUS SUBSTANCE, AFFECTING HUMANS Effects on animals only I2 2900 INFECTIOUS SUBSTANCE, AFFECTING ANIMALS only Clinical waste I3 3291 CLINICAL WASTE, UNSPECIFIED, N.O.S. or 3291 (BIO)MEDICAL WASTE, N.O.S. or 3291 REGULATED MEDICAL WASTE, N.O.S. Diagnostic specimens I4 3373 DIAGNOSTIC SPECIMENS or CLINICAL SPECIMENS 2006/128. szám 2.2.7 Class 7: Radioactive material 2.2.7.1 Definition of Class 7 2.2.7.1.1 Radioactive material means any material containing radionuclides where both the activity concentration and the total activity in the consignment exceed the values specified in 2.2.7.7.2.1 to 2.2.7.7.2.6. 2.2.7.1.2 The following radioactive materials are not included in Class 7 for the purposes of RID: (a) Radioactive material that is an integral part of the means of transport; (b) Radioactive material moved within an establishment which is subject to appropriate safety regulations in force in the establishment and where the movement does not involve public roads or railways; (c) Radioactive material implanted or incorporated into a person or live animal for diagnosis or treatment; (d) Radioactive material in consumer products which have received regulatory approval, following their sale to the end user; (e) Natural material and ores containing naturally occurring radionuclides which are either in their natural state, or have only been processed for purposes other than for extraction of the radionuclides, and which are not intended to be processed for use of these radionuclides provided the activity concentration of the material does not exceed 10 times the values specified in 2.2.7.7.2; (f) Non-radioactive solid objects with radioactive substances present on any surfaces in quantities not in excess of the limit set out in the definition for "contamination" in 2.2.7.2. 2.2.7.2 Definitions A1 and A2 A1 means the activity value of special form radioactive material which is listed in Table 2.2.7.7.2.1 or derived in 2.2.7.7.2 and is used to determine the activity limits for the requirements of RID. A2 means the activity value of radioactive material, other than special form radioactive material, which is listed in Table 2.2.7.7.2.1 or derived in 2.2.7.7.2 and is used to determine the activity limits for the requirements of RID. Approval Multilateral approval means approval by the relevant competent authority both of the country of origin of the design or shipment and of each country through or into which the consignment is to be carried. Unilateral approval means an approval of a design which is required to be given by the competent authority of the country of origin of the design only. If the country of origin is not a COTIF Member State, the approval shall require validation by the competent authority of the first COTIF Member State reached by the consignment (see 6.4.22.6). Confinement system means the assembly of fissile material and packaging components specified by the designer and agreed to by the competent authority as intended to preserve criticality safety. Containment system means the assembly of components of the packaging specified by the designer as intended to retain the radioactive material during carriage. Contamination means the presence of a radioactive substance on a surface in quantities in excess of 0.4 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 0.04 Bq/cm2 for all other alpha emitters. Non-fixed contamination means contamination that can be removed from a surface during routine conditions of carriage. Fixed contamination means contamination other than non-fixed contamination. Criticality safety index (CSI) assigned to a package, overpack or container containing fissile material means a number which is used to provide control over the accumulation of packages, overpacks or containers containing fissile material. Design means the description of special form radioactive material, low dispersible radioactive material, package or packaging which enables such an item to be fully identified. The description may include specifications, engineering drawings, reports demonstrating compliance with regulatory requirements, and other relevant documentation. Exclusive use means the sole use, by a single consignor, of a wagon or of a large container, in respect of which all initial, intermediate and final loading and unloading is carried out in accordance with the directions of the consignor or consignee. Fissile material means uranium-233, uranium-235, plutonium-239, plutonium-241, or any combination of these radionuclides. Excepted from this definition is: (a) Natural uranium or depleted uranium which is unirradiated, and (b) Natural uranium or depleted uranium which has been irradiated in thermal reactors only. Large container means a container which is not a small container according to the definitions of this Subsection. Low dispersible radioactive material means either a solid radioactive material or a solid radioactive material in a sealed capsule, that has limited dispersibility and is not in powder form. 2006/128. szám NOTE: Low dispersible radioactive material may be carried by air in Type B(U) or B(M) packages in quantities as authorised for the package design as specified in the certificate of approval. This definition is included here since such packages carrying low dispersible radioactive material may also be carried by rail. Low specific activity (LSA) material, see 2.2.7.3. Low toxicity alpha emitters are: natural uranium; depleted uranium; natural thorium; uranium-235 or uranium-238; thorium-232; thorium-228 and thorium-230 when contained in ores or physical and chemical concentrates; or alpha emitters with a half-life of less than 10 days. Maximum normal operating pressure means the maximum pressure above atmospheric pressure at mean sea-level that would develop in the containment system in a period of one year under the conditions of temperature and solar radiation corresponding to environmental conditions in the absence of venting, external cooling by an ancillary system, or operational controls during carriage. Package in the case of radioactive material means the packaging with its radioactive contents as presented for carriage. The types of packages covered by RID, which are subject to the activity limits and material restrictions of 2.2.7.7 and meet the corresponding requirements, are: (a) Excepted package; (b) Industrial package Type 1 (Type IP-1 package); (c) Industrial package Type 2 (Type IP-2 package); (d) Industrial package Type 3 (Type IP-3 package); (e) Type A package; (f) Type B(U) package; (g) Type B(M) package; (h) Type C package. Packages containing fissile material or uranium hexafluoride are subject to additional requirements (see 2.2.7.7.1.7 and 2.2.7.7.1.8). NOTE: For "packages" for other dangerous goods see definitions under 1.2.1. Packaging in the case of radioactive material means the assembly of components necessary to enclose the radioactive contents completely. It may, in particular, consist of one or more receptacles, absorbent materials, spacing structures, radiation shielding and service equipment for filling, emptying, venting and pressure relief; devices for cooling, absorbing mechanical shocks, handling and tie-down, thermal insulation; and service devices integral to the package. The packaging may be a box, drum or similar receptacle, or may also be a container, tank or intermediate bulk container (IBC). NOTE: For "packagings" for other dangerous goods see definitions under 1.2.1 Radiation level means the corresponding dose rate expressed in millisieverts per hour. Radioactive contents mean the radioactive material together with any contaminated or activated solids, liquids, and gases within the packaging. Shipment means the specific movement of a consignment from origin to destination. Small container means a container which has either any overall outer dimension less than 1.5 m, or an internal volume of not more than 3 m3. Special form radioactive material, see 2.2.7.4.1. Specific activity of a radionuclide means the activity per unit mass of that nuclide. The specific activity of a material shall mean the activity per unit mass or volume of the material in which the radionuclides are essentially uniformly distributed. Surface contaminated object (SCO), see 2.2.7.5. Transport index (TI) assigned to a package, overpack or container, or to unpackaged LSA-I or SCO-I, means a number which is used to provide control over radiation exposure. Unirradiated thorium means thorium containing not more than 10-7 g of uranium-233 per gram of thorium-232. Unirradiated uranium means uranium containing not more than 2 × 103 Bq of plutonium per gram of uranium-235, not more than 9 × 106 Bq of fission products per gram of uranium-235 and not more than 5 × 10-3 g of uranium-236 per gram of uranium-235. Uranium – natural, depleted, enriched means the following: Natural uranium means chemically separated uranium containing the naturally occurring distribution of uranium isotopes (approximately 99.28% uranium-238, and 0.72% uranium-235 by mass). Depleted uranium means uranium containing a lesser mass percentage of uranium-235 than in natural uranium. Enriched uranium means uranium containing a greater mass percentage of uranium-235 than 0.72%. In all cases, a very small mass percentage of uranium-234 is present. 2006/128. szám 2.2.7.3 Low specific activity (LSA) material, determination of groups 2.2.7.3.1 Radioactive material which by its nature has a limited specific activity, or radioactive material for which limits of estimated average specific activity apply, is termed low specific activity or LSA material. External shielding materials surrounding the LSA material shall not be considered in determining the estimated average specific activity. 2.2.7.3.2 LSA material shall be in one of three groups: (a) LSA-I (i) uranium and thorium ores and concentrates of such ores, and other ores containing naturally occurring radionuclides which are intended to be processed for the use of these radionuclides; (ii) solid unirradiated natural uranium or depleted uranium or natural thorium or their solid or liquid compounds or mixtures; (iii) radioactive material for which the A2 value is unlimited, excluding fissile material in quantities not excepted under 6.4.11.2; or (iv) other radioactive material in which the activity is distributed throughout and the estimated average specific activity does not exceed 30 times the values for activity concentration specified in 2.2.7.7.2.1 to 2.2.7.7.2.6, excluding fissile material in quantities not excepted under 6.4.11.2. (b) LSA-II (i) water with tritium concentration up to 0.8 TBq/l; or (ii) other material in which the activity is distributed throughout and the estimated average specific activity does not exceed 10-4 A2/g for solids and gases, and 10-5 A2/g for liquids; (c) LSA-III – Solids (e.g. consolidated wastes, activated materials), excluding powders, in which: (i) the radioactive material is distributed throughout a solid or a collection of solid objects, or is essentially uniformly distributed in a solid compact binding agent (such as concrete, bitumen, ceramic, etc.); (ii) the radioactive material is relatively insoluble, or it is intrinsically contained in a relatively insoluble matrix, so that, even under loss of packaging, the loss of radioactive material per package by leaching when placed in water for seven days would not exceed 0.1 A2; and (iii) the estimated average specific activity of the solid, excluding any shielding material, does not exceed 2 × 10-3 A2/g. 2.2.7.3.3 LSA-III material shall be a solid of such a nature that if the entire contents of a package were subjected to the test specified in 2.2.7.3.4 the activity in the water would not exceed 0.1 A2. 2.2.7.3.4 LSA-III material shall be tested as follows: A solid material sample representing the entire contents of the package shall be immersed for 7 days in water at ambient temperature. The volume of water to be used in the test shall be sufficient to ensure that at the end of the 7 day test period the free volume of the unabsorbed and unreacted water remaining shall be at least 10% of the volume of the solid test sample itself. The water shall have an initial pH of 6-8 and a maximum conductivity of 1 mS/m at 20 °C. The total activity of the free volume of water shall be measured following the 7 day immersion of the test sample. 2.2.7.3.5 Demonstration of compliance with the performance standards in 2.2.7.3.4 shall be in accordance with 6.4.12.1 and 6.4.12.2. 2.2.7.4 Requirements for special form radioactive material 2.2.7.4.1 Special form radioactive material means either: (a) An indispersible solid radioactive material; or (b) A sealed capsule containing radioactive material that shall be so manufactured that it can be opened only by destroying the capsule. Special form radioactive material shall have at least one dimension not less than 5 mm. 2.2.7.4.2 Special form radioactive material shall be of such a nature or shall be so designed that if it is subjected to the tests specified in 2.2.7.4.4 to 2.2.7.4.8, it shall meet the following requirements: (a) It would not break or shatter under the impact, percussion and bending tests 2.2.7.4.5 (a), (b), (c), 2.2.7.4.6 (a) as applicable; (b) It would not melt or disperse in the applicable heat test 2.2.7.4.5 (d) or 2.2.7.4.6 (b) as applicable; and (c) The activity in the water from the leaching tests specified in 2.2.7.4.7 and 2.2.7.4.8 would not exceed 2 kBq; or alternatively for sealed sources, the leakage rate for the volumetric leakage assessment test specified in ISO 9978:1992 "Radiation Protection – Sealed Radioactive Sources – Leakage Test Methods", would not exceed the applicable acceptance threshold acceptable to the competent authority. 2006/128. szám 2.2.7.4.3 Demonstration of compliance with the performance standards in 2.2.7.4.2 shall be in accordance with 6.4.12.1 and 6.4.12.2. 2.2.7.4.4 Specimens that comprise or simulate special form radioactive material shall be subjected to the impact test, the percussion test, the bending test, and the heat test specified in 2.2.7.4.5 or alternative tests as authorized in 2.2.7.4.6. A different specimen may be used for each of the tests. Following each test, a leaching assessment or volumetric leakage test shall be performed on the specimen by a method no less sensitive than the methods given in 2.2.7.4.7 for indispersible solid material or 2.2.7.4.8 for encapsulated material. 2.2.7.4.5 The relevant test methods are: (a) Impact test: The specimen shall drop onto the target from a height of 9 m. The target shall be as defined in 6.4.14; (b) Percussion test: The specimen shall be placed on a sheet of lead which is supported by a smooth solid surface and struck by the flat face of a mild steel bar so as to cause an impact equivalent to that resulting from a free drop of 1.4 kg through 1 m. The lower part of the bar shall be 25 mm in diameter with the edges rounded off to a radius of (3.0 ± 0.3) mm. The lead, of hardness number 3.5 to 4.5 on the Vickers scale and not more than 25 mm thick, shall cover an area greater than that covered by the specimen. A fresh surface of lead shall be used for each impact. The bar shall strike the specimen so as to cause maximum damage; (c) Bending test: The test shall apply only to long, slender sources with both a minimum length of 10 cm and a length to minimum width ratio of not less than 10. The specimen shall be rigidly clamped in a horizontal position so that one half of its length protrudes from the face of the clamp. The orientation of the specimen shall be such that the specimen will suffer maximum damage when its free end is struck by the flat face of a steel bar. The bar shall strike the specimen so as to cause an impact equivalent to that resulting from a free vertical drop of 1.4 kg through 1 m. The lower part of the bar shall be 25 mm in diameter with the edges rounded off to a radius of (3.0 ± 0.3) mm; (d) Heat test: The specimen shall be heated in air to a temperature of 800 °C and held at that temperature for a period of 10 minutes and shall then be allowed to cool. 2.2.7.4.6 Specimens that comprise or simulate radioactive material enclosed in a sealed capsule may be excepted from: (a) The tests prescribed in 2.2.7.4.5 (a) and 2.2.7.4.5 (b) provided the mass of the special form radioactive material is less than 200 g and they are alternatively subjected to the Class 4 impact test prescribed in ISO 2919:1980 "Radiation protection – Sealed radioactive sources – General requirements and classification"; and (b) The test prescribed in 2.2.7.4.5 (d) provided they are alternatively subjected to the Class 6 temperature test specified in ISO 2919:1980 "Radiation protection – Sealed radioactive sources – General requirements and classification". 2.2.7.4.7 For specimens which comprise or simulate indispersible solid material, a leaching assessment shall be performed as follows: (a) The specimen shall be immersed for 7 days in water at ambient temperature. The volume of water to be used in the test shall be sufficient to ensure that at the end of the 7 day test period the free volume of the unabsorbed and unreacted water remaining shall be at least 10% of the volume of the solid test sample itself. The water shall have an initial pH of 6 – 8 and a maximum conductivity of 1 mS/m at 20 °C; (b) The water with specimen shall then be heated to a temperature of (50 ± 5) °C and maintained at this temperature for 4 hours; (c) The activity of the water shall then be determined; (d) The specimen shall then be kept for at least 7 days in still air at not less than 30 °C and relative humidity not less than 90%; (e) The specimen shall then be immersed in water of the same specification as in (a) above and the water with the specimen heated to (50 ± 5) °C and maintained at this temperature for 4 hours; (f) The activity of the water shall then be determined. 2.2.7.4.8 For specimens which comprise or simulate radioactive material enclosed in a sealed capsule, either a leaching assessment or a volumetric leakage assessment shall be performed as follows: (a) The leaching assessment shall consist of the following steps: (i) the specimen shall be immersed in water at ambient temperature. The water shall have an initial pH of 6 – 8 with a maximum conductivity of 1 mS/m at 20 °C; (ii) the water and specimen shall be heated to a temperature of (50 ± 5) °C and maintained at this temperature for 4 hours; (iii) the activity of the water shall then be determined; (iv) the specimen shall then be kept for at least 7 days in still air at not less than 30 °C and relative humidity of not less than 90%; (v) the process in (i), (ii) and (iii) shall be repeated; 2006/128. szám (b) The alternative volumetric leakage assessment shall comprise any of the tests prescribed in ISO 9978:1992 "Radiation Protection – Sealed radioactive sources – Leakage test methods", which are acceptable to the competent authority. 2.2.7.5 Surface contaminated object (SCO), determination of groups Surface contaminated object (SCO) means a solid object which is not itself radioactive but which has radioactive material distributed on its surfaces. SCO is classified in one of two groups: (a) SCO-I: A solid object on which: (i) the non-fixed contamination on the accessible surface averaged over 300 cm2 (or the area of the surface if less than 300 cm2) does not exceed 4 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 0.4 Bq/cm2 for all other alpha emitters; and (ii) the fixed contamination on the accessible surface averaged over 300 cm2 (or the area of the surface if less than 300 cm2) does not exceed 4 × 104 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 4 × 103 Bq/cm2 for all other alpha emitters; and (iii) the non-fixed contamination plus the fixed contamination on the inaccessible surface averaged over 300 cm2 (or the area of the surface if less than 300 cm2) does not exceed 4 × 104 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 4 × 103 Bq/cm2 for all other alpha emitters; (b) SCO-II: A solid object on which either the fixed or non-fixed contamination on the surface exceeds the applicable limits specified for SCO-I in (a) above and on which: (i) the non-fixed contamination on the accessible surface averaged over 300 cm2 (or the area of the surface if less than 300 cm2) does not exceed 400 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 40 Bq/cm2 for all other alpha emitters; and (ii) the fixed contamination on the accessible surface, averaged over 300 cm2 (or the area of the surface if less than 300 cm2) does not exceed 8 × 105 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 8 × 104 Bq/cm2 for all other alpha emitters; and (iii) the non-fixed contamination plus the fixed contamination on the inaccessible surface averaged over 300 cm2 (or the area of the surface if less than 300 cm2) does not exceed 8 × 105 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters, or 8 × 104 Bq/cm2 for all other alpha emitters. 2.2.7.6 Determination of transport index (TI) and criticality safety index (CSI) 2.2.7.6.1 Determination of transport index 2.2.7.6.1.1 The transport index (TI) for a package, overpack or container, or for unpackaged LSA-I or SCO-I, shall be the number derived in accordance with the following procedure: (a) Determine the maximum radiation level in units of millisieverts per hour (mSv/h) at a distance of 1 m from the external surfaces of the package, overpack, container, or unpackaged LSA-I and SCO-I. The value determined shall be multiplied by 100 and the resulting number is the transport index. For uranium and thorium ores and their concentrates, the maximum radiation level at any point 1 m from the external surface of the load may be taken as: 0.4 mSv/h for ores and physical concentrates of uranium and thorium; 0.3 mSv/h for chemical concentrates of thorium; 0.02 mSv/h for chemical concentrates of uranium, other than uranium hexafluoride; (b) For tanks, containers and unpackaged LSA-I and SCO-I, the value determined in step (a) above shall be multiplied by the appropriate factor from Table 2.2.7.6.1.1; (c) The value obtained in steps (a) and (b) above shall be rounded up to the first decimal place (e.g. 1.13 becomes 1.2), except that a value of 0.05 or less may be considered as zero. Table 2.2.7.6.1.1 - Multiplication factor for tanks, containers and unpackaged LSA-I and SCO-I Size of load(a) Multiplication factor size of load ≤ 1 m2 1 m2 < size of load ≤ 5 m2 5 m2 < size of load ≤ 20 m2 20 m2 < size of load (a) Largest cross-sectional area of the load being measured. 2.2.7.6.1.2 The transport index for each overpack, container or wagon shall be determined as either the sum of the TIs of all the packages contained, or by direct measurement of radiation level, except in the case of non-rigid overpacks for which the transport index shall be determined only as the sum of the TIs of all the packages. 2006/128. szám 2.2.7.6.2 Determination of criticality safety index (CSI) 2.2.7.6.2.1 The criticality safety index (CSI) for packages containing fissile material shall be obtained by dividing the number 50 by the smaller of the two values of N derived in 6.4.11.11 and 6.4.11.12 (i.e. CSI = 50/N). The value of the criticality safety index may be zero, provided that an unlimited number of packages is subcritical (i.e. N is effectively equal to infinity in both cases). 2.2.7.6.2.2 The criticality safety index for each overpack or container shall be determined as the sum of the CSIs of all the packages contained. The same procedure shall be followed for determining the total sum of the CSIs in a consignment or aboard a wagon. 2.2.7.7 Activity limits and material restrictions 2.2.7.7.1 Contents limits for packages 2.2.7.7.1.1 General The quantity of radioactive material in a package shall not exceed the relevant limits for the package type as specified below. 2.2.7.7.1.2 Excepted packages 2.2.7.7.1.2.1 For radioactive material other than articles manufactured of natural uranium, depleted uranium or natural thorium, an excepted package shall not contain activities greater than the following: (a) Where the radioactive material is enclosed in or is included as a component part of an instrument or other manufactured article, such as a clock or electronic apparatus, the limits specified in columns 2 and 3 of Table 2.2.7.7.1.2.1 for each individual item and each package, respectively; and (b) Where the radioactive material is not so enclosed in or is not included as a component of an instrument or other manufactured article, the package limits specified in column 4 of Table 2.2.7.7.1.2.1. Table 2.2.7.7.1.2.1 - Activity limits for excepted packages Physical state of contents Instruments or article Materials Item limits(a) Package limits(a) Package limits(a) Solids Gases 10-2 A1 10-2 A2 10-3 A2 2 x 10-2 A2 10-3 A1 10-3 A2 A1 A2 10-1 A2 2 x 10-1 A2 10-2 A1 10-2 A2 10-3 A1 10-3 A2 10-4 A2 2 x 10-2 A2 10-3 A1 10-3 A2 (a) For mixtures of radionuclides, see 2.2.7.7.2.4 to 2.2.7.7.2.6. 2.2.7.7.1.2.2 For articles manufactured of natural uranium, depleted uranium or natural thorium, an excepted package may contain any quantity of such material provided that the outer surface of the uranium or thorium is enclosed in an inactive sheath made of metal or some other substantial material. 2.2.7.7.1.3 Industrial packages The radioactive contents in a single package of LSA material or in a single package of SCO shall be so restricted that the radiation level specified in 4.1.9.2.1 shall not be exceeded, and the activity in a single package shall also be so restricted that the activity limits for a wagon specified in 7.5.11, CW33 (2) shall not be exceeded. 2.2.7.7.1.4 Type A packages 2.2.7.7.1.4.1 Type A packages shall not contain activities greater than the following: (a) For special form radioactive material – A1; or (b) For all other radioactive material – A2. 2006/128. szám 2.2.7.7.1.4.2 For mixtures of radionuclides whose identities and respective activities are known, the following condition shall apply to the radioactive contents of a Type A package: ¦ i 1 (i) A (i) B + ¦ j 2(j) A (j) C ≤ 1 where B (i) is the activity of radionuclide i as special form radioactive material and A1(i) is the A1 value for radionuclide i; and C (j) is the activity of radionuclide j as other than special form radioactive material and A2(j) is the A2 value for radionuclide j. 2.2.7.7.1.5 Type B(U) and Type B(M) packages 2.2.7.7.1.5.1 Type B(U) and Type B(M) packages shall not contain: (a) Activities greater than those authorized for the package design; (b) Radionuclides different from those authorized for the package design; or (c) Contents in a form, or a physical or chemical state different from those authorized for the package design; as specified in their certificates of approval. 2.2.7.7.1.6 Type C packages NOTE: Type C packages may be transported by air carrying radioactive material in quantities exceeding either 3 000 A1 or 100 000 A2, whichever is the lower for special form radioactive material, or 3 000 A2 for all other radioactive material. Whilst Type C packages are not required for carriage of radioactive material by rail in such quantities (Type B(U) or Type B(M) packages suffice), the following requirements are presented since such packages may also be carried by rail. Type C packages shall not contain: (a) Activities greater than those authorized for the package design; (b) Radionuclides different from those authorized for the package design; or (c) Contents in a form, or physical or chemical state different from those authorized for the package design; as specified in their certificates of approval. 2.2.7.7.1.7 Packages containing fissile material Packages containing fissile material shall not contain: (a) A mass of fissile material different from that authorized for the package design; (b) Any radionuclide or fissile material different from those authorized for the package design; or (c) Contents in a form or physical or chemical state, or in a spatial arrangement, different from those authorized for the package design; as specified in their certificates of approval where appropriate. 2.2.7.7.1.8 Packages containing uranium hexafluoride The mass of uranium hexafluoride in a package shall not exceed a value that would lead to an ullage smaller than 5% at the maximum temperature of the package as specified for the plant systems where the package shall be used. The uranium hexafluoride shall be in solid form and the internal pressure of the package shall be below atmospheric pressure when presented for carriage. 2.2.7.7.2 Activity levels 2.2.7.7.2.1 The following basic values for individual radionuclides are given in Table 2.2.7.7.2.1: (a) A1 and A2 in TBq; (b) Activity concentration for exempt material in Bq/g; and (c) Activity limits for exempt consignments in Bq. 2006/128. szám Table 2.2.7.7.2.1 Radionuclide (atomic number) A1 (TBq) A2 (TBq) Activity concentration for exempt material (Bq/(g) Activity limit for an exempt consignment (Bq) Actinium (89) Ac-225(a) 8 × 10-1 6 × 10-3 1 × 101 1 × 104 Ac-227(a) 9 × 10-1 9 × 10-5 1 × 10-1 1 × 103 Ac-228 6 × 10-1 5 × 10-1 1 × 101 1 × 106 Silver (47) Ag-105 2 × 100 2 × 100 1 × 102 1 × 106 Ag-108m(a) 7 × 10-1 7 × 10-1 1 × 101 (b) 1 × 106 (b) Ag-110m(a) 4 × 10-1 4 × 10-1 1 × 101 1 × 106 Ag-111 2 × 100 6 × 10-1 1 × 103 1 × 106 Aluminium (13) Al-26 1 × 10-1 1 × 10-1 1 × 101 1 × 105 Americium (95) Am-241 1 × 101 1 × 10-3 1 × 100 1 × 104 Am-242m(a) 1 × 101 1 × 10-3 1 × 100 (b) 1 × 104 (b) Am-243(a) 5 × 100 1 × 10-3 1 × 100 (b) 1 × 103 (b) Argon (18) Ar-37 4 × 101 4 × 101 1 × 106 1 × 108 Ar-39 4 × 101 2 × 101 1 × 107 1 × 104 Ar-41 3 × 10-1 3 × 10-1 1 × 102 1 × 109 Arsenic (33) As-72 3 × 10-1 3 × 10-1 1 × 101 1 × 105 As-73 4 × 101 4 × 101 1 × 103 1 × 107 As-74 1 × 100 9 × 10-1 1 × 101 1 × 106 As-76 3 × 10-1 3 × 10-1 1 × 102 1 × 105 As-77 2 × 101 7 × 10-1 1 × 103 1 × 106 Astatine (85) At-211(a) 2 × 101 5 × 10-1 1 × 103 1 × 107 Gold (79) Au-193 7 × 100 2 × 100 1 × 102 1 × 107 Au-194 1 × 100 1 × 100 1 × 101 1 × 106 Au-195 1 × 101 6 × 100 1 × 102 1 × 107 Au-198 1 × 100 6 × 10-1 1 × 102 1 × 106 Au-199 1 × 101 6 × 10-1 1 × 102 1 × 106 Barium (56) Ba-131(a) 2 × 100 2 × 100 1 × 102 1 × 106 Ba-133 3 × 100 3 × 100 1 × 102 1 × 106 Ba-133m 2 × 101 6 × 10-1 1 × 102 1 × 106 Ba-140(a) 5 × 10-1 3 × 10-1 1 × 101 (b) 1 × 105 (b) Beryllium (4) Be-7 2 × 101 2 × 101 1 × 103 1 × 107 Be-10 4 × 101 6 × 10-1 1 × 104 1 × 106 Bismuth (83) Bi-205 7 × 10-1 7 × 10-1 1 × 101 1 × 106 Bi-206 3 × 10-1 3 × 10-1 1 × 101 1 × 105 Bi-207 7 × 10-1 7 × 10-1 1 × 101 1 × 106 Bi-210 1 × 100 6 × 10-1 1 × 103 1 × 106 Bi-210m(a) 6 × 10-1 2 × 10-2 1 × 101 1 × 105 Bi-212(a) 7 × 10-1 6 × 10-1 1 × 101 (b) 1 × 105 (b) Berkelium (97) Bk-247 8 × 100 8 × 10-4 1 × 100 1 × 104 Bk-249(a) 4 × 101 3 × 10-1 1 × 103 1 × 106 Bromine (35) Br-76 4 × 10-1 4 × 10-1 1 × 101 1 × 105 Br-77 3 × 100 3 × 100 1 × 102 1 × 106 Br-82 4 × 10-1 4 × 10-1 1 × 101 1 × 106 Carbon (6) C-11 1 × 100 6 × 10-1 1 × 101 1 × 106 C-14 4 × 101 3 × 100 1 × 104 1 × 107 Calcium (20) Ca-41 Unlimited Unlimited 1 × 105 1 × 107 Ca-45 4 × 101 1 × 100 1 × 104 1 × 107 Ca-47(a) 3 × 100 3 × 10-1 1 × 101 1 × 106 Cadmium (48) 2006/128. szám Radionuclide (atomic number) A1 (TBq) A2 (TBq) Activity concentration for exempt material (Bq/(g) Activity limit for an exempt consignment (Bq) Cd-109 3 × 101 2 × 100 1 × 104 1 × 106 Cd-113m 4 × 101 5 × 10-1 1 × 103 1 × 106 Cd-115(a) 3 × 100 4 × 10-1 1 × 102 1 × 106 Cd-115m 5 × 10-1 5 × 10-1 1 × 103 1 × 106 Cerium (58) Ce-139 7 × 100 2 × 100 1 × 102 1 × 106 Ce-141 2 × 101 6 × 10-1 1 × 102 1 × 107 Ce-143 9 × 10-1 6 × 10-1 1 × 102 1 × 106 Ce-144(a) 2 × 10-1 2 × 10-1 1 × 102 (b) 1 × 105 (b) Californium (98) Cf-248 4 × 101 6 × 10-3 1 × 101 1 × 104 Cf-249 3 × 100 8 × 10-4 1 × 100 1 × 103 Cf-250 2 × 101 2 × 10-3 1 × 101 1 × 104 Cf-251 7 × 100 7 × 10-4 1 × 100 1 × 103 Cf-252 1 × 10-1 3 × 10-3 1 × 101 1 × 104 Cf-253(a) 4 × 101 4 × 10-2 1 × 102 1 × 105 Cf-254 1 × 10-3 1 × 10-3 1 × 100 1 × 103 Chlorine (17) Cl-36 1 × 101 6 × 10-1 1 × 104 1 × 106 Cl-38 2 × 10-1 2 × 10-1 1 × 101 1 × 105 Curium (96) Cm-240 4 × 101 2 × 10-2 1 × 102 1 × 105 Cm-241 2 × 100 1 × 100 1 × 102 1 × 106 Cm-242 4 × 101 1 × 10-2 1 × 102 1 × 105 Cm-243 9 × 100 1 × 10-3 1 × 100 1 × 104 Cm-244 2 × 101 2 × 10-3 1 × 101 1 × 104 Cm-245 9 × 100 9 × 10-4 1 × 100 1 × 103 Cm-246 9 × 100 9 × 10-4 1 × 100 1 × 103 Cm-247(a) 3 × 100 1 × 10-3 1 × 100 1 × 104 Cm-248 2 × 10-2 3 × 10-4 1 × 100 1 × 103 Cobalt (27) Co-55 5 × 10-1 5 × 10-1 1 × 101 1 × 106 Co-56 3 × 10-1 3 × 10-1 1 × 101 1 × 105 Co-57 1 × 101 1 × 101 1 × 102 1 × 106 Co-58 1 × 100 1 × 100 1 × 101 1 × 106 Co-58m 4 × 101 4 × 101 1 × 104 1 × 107 Co-60 4 × 10-1 4 × 10-1 1 × 101 1 × 105 Chromium (24) Cr-51 3 × 101 3 × 101 1 × 103 1 × 107 Caesium (55) Cs-129 4 × 100 4 × 100 1 × 102 1 × 105 Cs-131 3 × 101 3 × 101 1 × 103 1 × 106 Cs-132 1 × 100 1 × 100 1 × 101 1 × 105 Cs-134 7 × 10-1 7 × 10-1 1 × 101 1 × 104 Cs-134m 4 × 101 6 × 10-1 1 × 103 1 × 105 Cs-135 4 × 101 1 × 100 1 × 104 1 × 107 Cs-136 5 × 10-1 5 × 10-1 1 × 101 1 × 105 Cs-137(a) 2 × 100 6 × 10-1 1 × 101 (b) 1 × 104 (b) Copper (29) Cu-64 6 × 100 1 × 100 1 × 102 1 × 106 Cu-67 1 × 101 7 × 10-1 1 × 102 1 × 106 Dysprosium (66) Dy-159 2 × 101 2 × 101 1 × 103 1 × 107 Dy-165 9 × 10-1 6 × 10-1 1 × 103 1 × 106 Dy-166(a) 9 × 10-1 3 × 10-1 1 × 103 1 × 106 Erbium (68) Er-169 4 × 101 1 × 100 1 × 104 1 × 107 Er-171 8 × 10-1 5 × 10-1 1 × 102 1 × 106 Europium (63) Eu-147 2 × 100 2 × 100 1 × 102 1 × 106 Eu-148 5 × 10-1 5 × 10-1 1 × 101 1 × 106 Eu-149 2 × 101 2 × 101 1 × 102 1 × 107 Eu-150 (short lived) 2 × 100 7 × 10-1 1 × 103 1 × 106 Eu-150 (long lived) 7 × 10-1 7 × 10-1 1 × 101 1 × 106 Eu-152 1 × 100 1 × 100 1 × 101 1 × 106 Eu-152m 8 × 10-1 8 × 10-1 1 × 102 1 × 106 2006/128. szám Radionuclide (atomic number) A1 (TBq) A2 (TBq) Activity concentration for exempt material (Bq/(g) Activity limit for an exempt consignment (Bq) Eu-154 9 × 10-1 6 × 10-1 1 × 101 1 × 106 Eu-155 2 × 101 3 × 100 1 × 102 1 × 107 Eu-156 7 × 10-1 7 × 10-1 1 × 101 1 × 106 Fluorine (9) F-18 1 × 100 6 × 10-1 1 × 101 1 × 106 Iron (26) Fe-52(a) 3 × 10-1 3 × 10-1 1 × 101 1 × 106 Fe-55 4 × 101 4 × 101 1 × 104 1 × 106 Fe-59 9 × 10-1 9 × 10-1 1 × 101 1 × 106 Fe-60(a) 4 × 101 2 × 10-1 1 × 102 1 × 105 Gallium (31) Ga-67 7 × 100 3 × 100 1 × 102 1 × 106 Ga-68 5 × 10-1 5 × 10-1 1 × 101 1 × 105 Ga-72 4 × 10-1 4 × 10-1 1 × 101 1 × 105 Gadolinium (64) Gd-146(a) 5 × 10-1 5 × 10-1 1 × 101 1 × 106 Gd-148 2 × 101 2 × 10-3 1 × 101 1 × 104 Gd-153 1 × 101 9 × 100 1 × 102 1 × 107 Gd-159 3 × 100 6 × 10-1 1 × 103 1 × 106 Germanium (32) Ge-68(a) 5 × 10-1 5 × 10-1 1 × 101 1 × 105 Ge-71 4 × 101 4 × 101 1 × 104 1 × 108 Ge-77 3 × 10-1 3 × 10-1 1 × 101 1 × 105 Hafnium (72) Hf-172(a) 6 × 10-1 6 × 10-1 1 × 101 1 × 106 Hf-175 3 × 100 3 × 100 1 × 102 1 × 106 Hf-181 2 × 100 5 × 10-1 1 × 101 1 × 106 Hf-182 Unlimited Unlimited 1 × 102 1 × 106 Mercury (80) Hg-194(a) 1 × 100 1 × 100 1 × 101 1 × 106 Hg-195m(a) 3 × 100 7 × 10-1 1 × 102 1 × 106 Hg-197 2 × 101 1 × 101 1 × 102 1 × 107 Hg-197m 1 × 101 4 × 10-1 1 × 102 1 × 106 Hg-203 5 × 100 1 × 100 1 × 102 1 × 105 Holmium (67) Ho-166 4 × 10-1 4 × 10-1 1 × 103 1 × 105 Ho-166m 6 × 10-1 5 × 10-1 1 × 101 1 × 106 Iodine (53) I-123 6 × 100 3 × 100 1 × 102 1 × 107 I-124 1 × 100 1 × 100 1 × 101 1 × 106 I-125 2 × 101 3 × 100 1 × 103 1 × 106 I-126 2 × 100 1 × 100 1 × 102 1 × 106 I-129 Unlimited Unlimited 1 ×102 1 × 105 I-131 3 × 100 7 × 10-1 1 × 102 1 × 106 I-132 4 × 10-1 4 × 10-1 1 × 101 1 × 105 I-133 7 × 10-1 6 × 10-1 1 × 101 1 × 106 I-134 3 × 10-1 3 × 10-1 1 × 101 1 × 105 I-135(a) 6 × 10-1 6 × 10-1 1 × 101 1 × 106 Indium (49) In-111 3 × 100 3 × 100 1 × 102 1 × 106 In-113m 4 × 100 2 × 100 1 × 102 1 × 106 In-114m(a) 1 × 101 5 × 10-1 1 × 102 1 × 106 In-115m 7 × 100 1 × 100 1 × 102 1 × 106 Iridium (77) Ir-189(a) 1 × 101 1 × 101 1 × 102 1 × 107 Ir-190 7 × 10-1 7 × 10-1 1 × 101 1 × 106 Ir-192 1 × 100 (c) 6 × 10-1 1 × 101 1 × 104 Ir-194 3 × 10-1 3 × 10-1 1 × 102 1 × 105 Potassium (19) K-40 9 × 10-1 9 × 10-1 1 × 102 1 × 106 K-42 2 × 10-1 2 × 10-1 1 × 102 1 × 106 K-43 7 × 10-1 6 × 10-1 1 × 101 1 × 106 Krypton (36) Kr-79 4 x 100 1 x 100 1 x 103 1 x 105 Kr-81 4 × 101 4 × 101 1 × 104 1 × 107 Kr-85 1 × 101 1 × 101 1 × 105 1 × 104 2006/128. szám Radionuclide (atomic number) A1 (TBq) A2 (TBq) Activity concentration for exempt material (Bq/(g) Activity limit for an exempt consignment (Bq) Kr-85m 8 × 100 3 × 100 1 × 103 1 × 1010 Kr-87 2 × 10-1 2 × 10-1 1 × 102 1 × 109 Lanthanum (57) La-137 3 × 101 6 × 100 1 × 103 1 × 107 La-140 4 × 10-1 4 × 10-1 1 × 101 1 × 105 Lutetium (71) Lu-172 6 × 10-1 6 × 10-1 1 × 101 1 × 106 Lu-173 8 × 100 8 × 100 1 × 102 1 × 107 Lu-174 9 × 100 9 × 100 1 × 102 1 × 107 Lu-174m 2 × 101 1 × 101 1 × 102 1 × 107 Lu-177 3 × 101 7 × 10-1 1 × 103 1 × 107 Magnesium (12) Mg-28(a) 3 × 10-1 3 × 10-1 1 × 101 1 × 105 Manganese (25) Mn-52 3 × 10-1 3 × 10-1 1 × 101 1 × 105 Mn-53 Unlimited Unlimited 1 × 104 1 × 109 Mn-54 1 × 100 1 × 100 1 × 101 1 × 106 Mn-56 3 × 10-1 3 × 10-1 1 × 101 1 × 105 Molybdenum (42) Mo-93 4 × 101 2 × 101 1 × 103 1 × 108 Mo-99(a) 1 × 100 6 × 10-1 1 × 102 1 × 106 Nitrogen (7) N-13 9 × 10-1 6 × 10-1 1 × 102 1 × 109 Sodium (11) Na-22 5 × 10-1 5 × 10-1 1 × 101 1 × 106 Na-24 2 × 10-1 2 × 10-1 1 × 101 1 × 105 Niobium (41) Nb-93m 4 × 101 3 × 101 1 × 104 1 × 107 Nb-94 7 × 10-1 7 × 10-1 1 × 101 1 × 106 Nb-95 1 × 100 1 × 100 1 × 101 1 × 106 Nb-97 9 × 10-1 6 × 10-1 1 × 101 1 × 106 Neodymium (60) Nd-147 6 × 100 6 × 10-1 1 × 102 1 × 106 Nd-149 6 × 10-1 5 × 10-1 1 × 102 1 × 106 Nickel (28) Ni-59 Unlimited Unlimited 1 × 104 1 × 108 Ni-63 4 × 101 3 × 101 1 × 105 1 × 108 Ni-65 4 × 10-1 4 × 10-1 1 × 101 1 × 106 Neptunium (93) Np-235 4 × 101 4 × 101 1 × 103 1 × 107 Np-236 (short lived) 2 × 101 2 × 100 1 × 103 1 × 107 Np-236 (long lived) 9 × 100 2 × 10-2 1 × 102 1 × 105 Np-237 2 × 101 2 × 10-3 1 × 100 (b) 1 × 103 (b) Np-239 7 × 100 4 × 10-1 1 × 102 1 × 107 Osmium (76) Os-185 1 × 100 1 × 100 1 × 101 1 × 106 Os-191 1 × 101 2 × 100 1 × 102 1 × 107 Os-191m 4 × 101 3 × 101 1 × 103 1 × 107 Os-193 2 × 100 6 × 10-1 1 × 102 1 × 106 Os-194(a) 3 × 10-1 3 × 10-1 1 × 102 1 × 105 Phosphorus (15) P-32 5 × 10-1 5 × 10-1 1 × 103 1 × 105 P-33 4 × 101 1 × 100 1 × 105 1 × 108 Protactinium (91) Pa-230(a) 2 × 100 7 × 10-2 1 × 101 1 × 106 Pa-231 4 × 100 4 × 10-4 1 × 100 1 × 103 Pa-233 5 × 100 7 × 10-1 1 × 102 1 × 107 Lead (82) Pb-201 1 × 100 1 × 100 1 × 101 1 × 106 Pb-202 4 × 101 2 × 101 1 × 103 1 × 106 Pb-203 4 × 100 3 × 100 1 × 102 1 × 106 Pb-205 Unlimited Unlimited 1 × 104 1 × 107 Pb-210(a) 1 × 100 5 × 10-2 1 × 101 (b) 1 × 104 (b) Pb-212(a) 7 × 10-1 2 × 10-1 1 × 101 (b) 1 × 105 (b) Palladium (46) Pd-103(a) 4 × 101 4 × 101 1 × 103 1 × 108 2006/128. szám Radionuclide (atomic number) A1 (TBq) A2 (TBq) Activity concentration for exempt material (Bq/(g) Activity limit for an exempt consignment (Bq) Pd-107 Unlimited Unlimited 1 × 105 1 × 108 Pd-109 2 × 100 5 × 10-1 1 × 103 1 × 106 Promethium (61) Pm-143 3 × 100 3 × 100 1 × 102 1 × 106 Pm-144 7 × 10-1 7 × 10-1 1 × 101 1 × 106 Pm-145 3 × 101 1 × 101 1 × 103 1 × 107 Pm-147 4 × 101 2 × 100 1 × 104 1 × 107 Pm-148m(a) 8 × 10-1 7 × 10-1 1 × 101 1 × 106 Pm-149 2 × 100 6 × 10-1 1 × 103 1 × 106 Pm-151 2 × 100 6 × 10-1 1 × 102 1 × 106 Polonium (84) Po-210 4 × 101 2 × 10-2 1 × 101 1 × 104 Praseodymium (59) Pr-142 4 × 10-1 4 × 10-1 1 × 102 1 × 105 Pr-143 3 × 100 6 × 10-1 1 × 104 1 × 106 Platinum (78) Pt-188(a) 1 × 100 8 × 10-1 1 × 101 1 × 106 Pt-191 4 × 100 3 × 100 1 × 102 1 × 106 Pt-193 4 × 101 4 × 101 1 × 104 1 × 107 Pt-193m 4 × 101 5 × 10-1 1 × 103 1 × 107 Pt-195m 1 × 101 5 × 10-1 1 × 102 1 × 106 Pt-197 2 × 101 6 × 10-1 1 × 103 1 × 106 Pt-197m 1 × 101 6 × 10-1 1 × 102 1 × 106 Plutonium (94) Pu-236 3 × 101 3 × 10-3 1 × 101 1 × 104 Pu-237 2 × 101 2 × 101 1 × 103 1 × 107 Pu-238 1 × 101 1 × 10-3 1 × 100 1 × 104 Pu-239 1 × 101 1 × 10-3 1 × 100 1 × 104 Pu-240 1 × 101 1 × 10-3 1 × 100 1 × 103 Pu-241(a) 4 × 101 6 × 10-2 1 × 102 1 × 105 Pu-242 1 × 101 1 × 10-3 1 × 100 1 × 104 Pu-244(a) 4 × 10-1 1 × 10-3 1 × 100 1 × 104 Radium (88) Ra-223(a) 4 × 10-1 7 × 10-3 1 × 102 (b) 1 × 105 (b) Ra-224(a) 4 × 10-1 2 × 10-2 1 × 101 (b) 1 × 105 (b) Ra-225(a) 2 × 10-1 4 × 10-3 1 × 102 1 × 105 Ra-226(a) 2 × 10-1 3 × 10-3 1 × 101 (b) 1 × 104 (b) Ra-228(a) 6 × 10-1 2 × 10-2 1 × 101 (b) 1 × 105 (b) Rubidium (37) Rb-81 2 × 100 8 × 10-1 1 × 101 1 × 106 Rb-83(a) 2 × 100 2 × 100 1 × 102 1 × 106 Rb-84 1 × 100 1 × 100 1 × 101 1 × 106 Rb-86 5 × 10-1 5 × 10-1 1 × 102 1 × 105 Rb-87 Unlimited Unlimited 1 × 104 1 × 107 Rb (nat) Unlimited Unlimited 1 × 104 1 × 107 Rhenium (75) Re-184 1 × 100 1 × 100 1 × 101 1 × 106 Re-184m 3 × 100 1 × 100 1 × 102 1 × 106 Re-186 2 × 100 6 × 10-1 1 × 103 1 × 106 Re-187 Unlimited Unlimited 1 × 106 1 × 109 Re-188 4 × 10-1 4 × 10-1 1 × 102 1 × 105 Re-189(a) 3 × 100 6 × 10-1 1 × 102 1 × 106 Re (nat) Unlimited Unlimited 1 × 106 1 × 109 Rhodium (45) Rh-99 2 × 100 2 × 100 1 × 101 1 × 106 Rh-101 4 × 100 3 × 100 1 × 102 1 × 107 Rh-102 5 × 10-1 5 × 10-1 1 × 101 1 × 106 Rh-102m 2 × 100 2 × 100 1 × 102 1 × 106 Rh-103m 4 × 101 4 × 101 1 × 104 1 × 108 Rh-105 1 × 101 8 × 10-1 1 × 102 1 × 107 Radon (86) Rn-222(a) 3 × 10-1 4 × 10-3 1 × 101 (b) 1 × 108 (b) Ruthenium (44) Ru-97 5 × 100 5 × 100 1 × 102 1 × 107 Ru-103(a) 2 × 100 2 × 100 1 × 102 1 × 106 Ru-105 1 × 100 6 × 10-1 1 × 101 1 × 106 2006/128. szám Radionuclide (atomic number) A1 (TBq) A2 (TBq) Activity concentration for exempt material (Bq/(g) Activity limit for an exempt consignment (Bq) Ru-106(a) 2 × 10-1 2 × 10-1 1 × 102 (b) 1 × 105 (b) Sulphur (16) S-35 4 × 101 3 × 100 1 × 105 1 × 108 Antimony (51) Sb-122 4 × 10-1 4 × 10-1 1 × 102 1 × 104 Sb-124 6 × 10-1 6 × 10-1 1 × 101 1 × 106 Sb-125 2 × 100 1 × 100 1 × 102 1 × 106 Sb-126 4 × 10-1 4 × 10-1 1 × 101 1 × 105 Scandium (21) Sc-44 5 × 10-1 5 × 10-1 1 × 101 1 × 105 Sc-46 5 × 10-1 5 × 10-1 1 × 101 1 × 106 Sc-47 1 × 101 7 × 10-1 1 × 102 1 × 106 Sc-48 3 × 10-1 3 × 10-1 1 × 101 1 × 105 Selenium (34) Se-75 3 × 100 3 × 100 1 × 102 1 × 106 Se-79 4 × 101 2 × 100 1 × 104 1 × 107 Silicion (14) Si-31 6 × 10-1 6 × 10-1 1 × 103 1 × 106 Si-32 4 × 101 5 × 10-1 1 × 103 1 × 106 Samarium (62) Sm-145 1 × 101 1 × 101 1 × 102 1 × 107 Sm-147 Unlimited Unlimited 1 × 101 1 × 104 Sm-151 4 × 101 1 × 101 1 × 104 1 × 108 Sm-153 9 × 100 6 × 10-1 1 × 102 1 × 106 Tin (50) Sn-113(a) 4 × 100 2 × 100 1 × 103 1 × 107 Sn-117m 7 × 100 4 × 10-1 1 × 102 1 × 106 Sn-119m 4 × 101 3 × 101 1 × 103 1 × 107 Sn-121m(a) 4 × 101 9 × 10-1 1 × 103 1 × 107 Sn-123 8 × 10-1 6 × 10-1 1 × 103 1 × 106 Sn-125 4 × 10-1 4 × 10-1 1 × 102 1 × 105 Sn-126(a) 6 × 10-1 4 × 10-1 1 × 101 1 × 105 Strontium (38) Sr-82(a) 2 × 10-1 2 × 10-1 1 × 101 1 × 105 Sr-85 2 × 100 2 × 100 1 × 102 1 × 106 Sr-85m 5 × 100 5 × 100 1 × 102 1 × 107 Sr-87m 3 × 100 3 × 100 1 × 102 1 × 106 Sr-89 6 × 10-1 6 × 10-1 1 × 103 1 × 106 Sr-90(a) 3 × 10-1 3 × 10-1 1 × 102 (b) 1 × 104 (b) Sr-91(a) 3 × 10-1 3 × 10-1 1 × 101 1 × 105 Sr-92(a) 1 × 100 3 × 10-1 1 × 101 1 × 106 Tritium (1) T (H-3) 4 × 101 4 × 101 1 × 106 1 × 109 Tantalum (73) Ta-178 (long live(d) 1 × 100 8 × 10-1 1 × 101 1 × 106 Ta-179 3 × 101 3 × 101 1 × 103 1 × 107 Ta-182 9 × 10-1 5 × 10-1 1 × 101 1 × 104 Terbium (65) Tb-157 4 × 101 4 × 101 1 × 104 1 × 107 Tb-158 1 × 100 1 × 100 1 × 101 1 × 106 Tb-160 1 × 100 6 × 10-1 1 × 101 1 × 106 Technetium (43) Tc-95m(a) 2 × 100 2 × 100 1 × 101 1 × 106 Tc-96 4 × 10-1 4 × 10-1 1 × 101 1 × 106 Tc-96m(a) 4 × 10-1 4 × 10-1 1 × 103 1 × 107 Tc-97 Unlimited Unlimited 1 × 103 1 × 108 Tc-97m 4 × 101 1 × 100 1 × 103 1 × 107 Tc-98 8 × 10-1 7 × 10-1 1 × 101 1 × 106 Tc-99 4 × 101 9 × 10-1 1 × 104 1 × 107 Tc-99m 1 × 101 4 × 100 1 × 102 1 × 107 Tellurium (52) Te-121 2 × 100 2 × 100 1 × 101 1 × 106 Te-121m 5 × 100 3 × 100 1 × 102 1 × 105 Te-123m 8 × 100 1 × 100 1 × 102 1 × 107 Te-125m 2 × 101 9 × 10-1 1 × 103 1 × 107 Te-127 2 × 101 7 × 10-1 1 × 103 1 × 106 2006/128. szám Radionuclide (atomic number) A1 (TBq) A2 (TBq) Activity concentration for exempt material (Bq/(g) Activity limit for an exempt consignment (Bq) Te-127m(a) 2 × 101 5 × 10-1 1 × 103 1 × 107 Te-129 7 × 10-1 6 × 10-1 1 × 102 1 × 106 Te-129m(a) 8 × 10-1 4 × 10-1 1 × 103 1 × 106 Te-131m(a) 7 × 10-1 5 × 10-1 1 × 101 1 × 106 Te-132(a) 5 × 10-1 4 × 10-1 1 × 102 1 × 107 Thorium (90) Th-227 1 × 101 5 × 10-3 1 × 101 1 × 104 Th-228(a) 5 × 10-1 1 × 10-3 1 × 100 (b) 1 × 104 (b) Th-229 5 × 100 5 × 10-4 1 × 100 (b) 1 × 103 (b) Th-230 1 × 101 1 × 10-3 1 × 100 1 × 104 Th-231 4 × 101 2 × 10-2 1 × 103 1 × 107 Th-232 Unlimited Unlimited 1 × 101 1 × 104 Th-234(a) 3 × 10-1 3 × 10-1 1 × 103 (b) 1 × 105 (b) Th (nat) Unlimited Unlimited 1 × 100 (b) 1 × 103 (b) Titanium (22) Ti-44(a) 5 × 10-1 4 × 10-1 1 × 101 1 × 105 Thallium (81) Tl-200 9 × 10-1 9 × 10-1 1 × 101 1 × 106 Tl-201 1 × 101 4 × 100 1 × 102 1 × 106 Tl-202 2 × 100 2 × 100 1 × 102 1 × 106 Tl-204 1 × 101 7 × 10-1 1 × 104 1 × 104 Thulium (69) Tm-167 7 × 100 8 × 10-1 1 × 102 1 × 106 Tm-170 3 × 100 6 × 10-1 1 × 103 1 × 106 Tm-171 4 × 101 4 × 101 1 × 104 1 × 108 Uranium (92) U-230 (fast lung absorption)(a)(d) 4 × 101 1 × 10-1 1 × 101 (b) 1 × 105 (b) U-230 (medium lung absorption)(a)(e) 4 × 101 4 × 10-3 1 × 101 1 × 104 U-230 (slow lung absorption)(a)(f) 3 × 101 3 × 10-3 1 × 101 1 × 104 U-232 (fast lung absorption)(d) 4 × 101 1 × 10-2 1 × 100 (b) 1 × 103 (b) U-232 (medium lung absorption)(e) 4 × 101 7 × 10-3 1 × 101 1 × 104 U-232 (slow lung absorption)(f) 1 × 101 1 × 10-3 1 × 101 1 × 104 U-233 (fast lung absorption)(d) 4 × 101 9 × 10-2 1 × 101 1 × 104 U-233 (medium lung absorption)(e) 4 × 101 2 × 10-2 1 × 102 1 × 105 U-233 (slow lung absorption)(f) 4 × 101 6 × 10-3 1 × 101 1 × 105 U-234 (fast lung absorption)(d) 4 × 101 9 × 10-2 1 × 101 1 × 104 U-234 (medium lung absorption)(e) 4 × 101 2 × 10-2 1 × 102 1 × 105 U-234 (slow lung absorption)(f) 4 × 101 6 × 10-3 1 × 101 1 × 105 U-235 (all lung absorption types)(a)(d)(e)(f) Unlimited Unlimited 1 × 101 (b) 1 × 104 (b) U-236 (fast lung absorption)(d) Unlimited Unlimited 1 × 101 1 × 104 U-236 (medium lung absorption)(e) 4 × 101 2 × 10-2 1 × 102 1 × 105 U-236 (slow lung absorption)(f) 4 × 101 6 × 10-3 1 × 101 1 × 104 U-238 (all lung absorption types)(d)(e)(f) Unlimited Unlimited 1 × 101 (b) 1 × 104 (b) U (nat) Unlimited Unlimited 1 × 100 (b) 1 × 103 (b) U (enriched to 20% or less)(g) Unlimited Unlimited 1 × 100 1 × 103 U (dep) Unlimited Unlimited 1 × 100 1 × 103 Vanadium (23) V-48 4 × 10-1 4 × 10-1 1 × 101 1 × 105 V-49 4 × 101 4 × 101 1 × 104 1 × 107 Tungsten (74) W-178(a) 9 × 100 5 × 100 1 × 101 1 × 106 W-181 3 × 101 3 × 101 1 × 103 1 × 107 W-185 4 × 101 8 × 10-1 1 × 104 1 × 107 W-187 2 × 100 6 × 10-1 1 × 102 1 × 106 W-188(a) 4 × 10-1 3 × 10-1 1 × 102 1 × 105 Xenon (54) Xe-122(a) 4 × 10-1 4 × 10-1 1 × 102 1 × 109 Xe-123 2 × 100 7 × 10-1 1 × 102 1 × 109 2006/128. szám Radionuclide (atomic number) A1 (TBq) A2 (TBq) Activity concentration for exempt material (Bq/(g) Activity limit for an exempt consignment (Bq) Xe-127 4 × 100 2 × 100 1 × 103 1 × 105 Xe-131m 4 × 101 4 × 101 1 × 104 1 × 104 Xe-133 2 × 101 1 × 101 1 × 103 1 × 104 Xe-135 3 × 100 2 × 100 1 × 103 1 × 1010 Yttrium (39) Y-87(a) 1 × 100 1 × 100 1 × 101 1 × 106 Y-88 4 × 10-1 4 × 10-1 1 × 101 1 × 106 Y-90 3 × 10-1 3 × 10-1 1 × 103 1 × 105 Y-91 6 × 10-1 6 × 10-1 1 × 103 1 × 106 Y-91m 2 × 100 2 × 100 1 × 102 1 × 106 Y-92 2 × 10-1 2 × 10-1 1 × 102 1 × 105 Y-93 3 × 10-1 3 × 10-1 1 × 102 1 × 105 Ytterbium (70) Yb-169 4 × 100 1 × 100 1 × 102 1 × 107 Yb-175 3 × 101 9 × 10-1 1 × 103 1 × 107 Zinc (30) Zn-65 2 × 100 2 × 100 1 × 101 1 × 106 Zn-69 3 × 100 6 × 10-1 1 × 104 1 × 106 Zn-69m(a) 3 × 100 6 × 10-1 1 × 102 1 × 106 Zirconium (40) Zr-88 3 × 100 3 × 100 1 × 102 1 × 106 Zr-93 Unlimited Unlimited 1 × 103 (b) 1 × 107 (b) Zr-95(a) 2 × 100 8 × 10-1 1 × 101 1 × 106 Zr-97(a) 4 × 10-1 4 × 10-1 1 × 101 (b) 1 × 105 (b) (a) A1 and/or A2 values include contributions from daughter nuclides with half-lives less than 10 days. (b) Parent nuclides and their progeny included in secular equilibrium are listed in the following: Sr-90 Y-90 Zr-93 Nb-93m Zr-97 Nb-97 Ru-106 Rh-106 Cs-137 Ba-137m Ce-134 La-134 Ce-144 Pr-144 Ba-140 La-140 Bi-212 Tl-208 (0.36), Po-212 (0.64) Pb-210 Bi-210, Po-210 Pb-212 Bi-212, Tl-208 (0.36), Po-212 (0.64) Rn-220 Po-216 Rn-222 Po-218, Pb-214, Bi-214, Po-214 Ra-223 Rn-219, Po-215, Pb-211, Bi-211, Tl-207 Ra-224 Rn-220, Po-216, Pb-212, Bi-212, Tl-208 (0.36), Po-212 (0.64) Ra-226 Rn-222, Po-218, Pb-214, Bi-214, Po-214, Pb-210, Bi-210, Po-210 Ra-228 Ac-228 Th-226 Ra-222, Rn-218, Po-214 Th-228 Ra-224, Rn-220, Po-216, Pb212, Bi-212, Tl208 (0.36), Po-212 (0.64) Th-229 Ra-225, Ac-225, Fr-221, At-217, Bi-213, Po-213, Pb-209 Th-nat Ra-228, Ac-228, Th-228, Ra-224, Rn-220, Po-216, Pb-212, Bi-212, Tl-208 (0.36), Po-212 (0.64) Th-234 Pa-234m U-230 Th-226, Ra-222, Rn-218, Po-214 U-232 Th-228, Ra-224, Rn-220, Po-216, Pb-212, Bi-212, Tl-208 (0.36), Po-212 (0.64) U-235 Th-231 U-238 Th-234, Pa-234m U-nat Th-234, Pa-234m, U-234, Th-230, Ra-226, Rn-222, Po-218, Pb-214, Bi-214, Po-214, Pb-210, Bi-210, Po-210 U-240 Np-240m 2006/128. szám Np-237 Pa-233 Am-242m Am-242 Am-243 Np-239 (c) The quantity may be determined from a measurement of the rate of decay or a measurement of the radiation level at a prescribed distance from the source. (d) These values apply only to compounds of uranium that take the chemical form of UF6, UO2F2 and UO2(NO3)2 in both normal and accident conditions of carriage. (e) These values apply only to compounds of uranium that take the chemical form of UO3, UF4, UCl4 and hexavalent compounds in both normal and accident conditions of carriage. (f) These values apply to all compounds of uranium other than those specified in (d) and (e) above. (g) These values apply to unirradiated uranium only. 2.2.7.7.2.2 For individual radionuclides which are not listed in Table 2.2.7.7.2.1 the determination of the basic radionuclide values referred to in 2.2.7.7.2.1 shall require competent authority approval or, for international carriage, multilateral approval. Where the chemical form of each radionuclide is known, it is permissible to use the A2 value related to its solubility class as recommended by the International Commission on Radiological Protection, if the chemical forms under both normal and accident conditions of carriage are taken into consideration. Alternatively, the radionuclide values in Table 2.2.7.7.2.2 may be used without obtaining competent authority approval. Table 2.2.7.7.2.2 – Basic radionuclide values for unknown radionuclides or mixtures Radioactive contents A1 A2 Activity concentration for exempt material Activity limit for an exempt consignment (TBq) (TBq) (Bq/g) (Bq) Only beta or gamma emitting nuclides are known to be present 0,1 0,02 1 x 101 1 x 104 Only alpha emitting nuclides are known to be present 0,2 9 x 10-5 1 x 10-1 1 x 103 No relevant data are available 0,001 9 x 10-5 1 x 10-1 1 x 103 2.2.7.7.2.3 In the calculations of A1 and A2 for a radionuclide not in Table 2.2.7.7.2.1, a single radioactive decay chain in which the radionuclides are present in their naturally occurring proportions, and in which no daughter nuclide has a half-life either longer than 10 days or longer than that of the parent nuclide, shall be considered as a single radionuclide; and the activity to be taken into account and the A1 or A2 value to be applied shall be those corresponding to the parent nuclide of that chain. In the case of radioactive decay chains in which any daughter nuclide has a half-life either longer than 10 days or greater than that of the parent nuclide, the parent and such daughter nuclides shall be considered as mixtures of different nuclides. 2.2.7.7.2.4 For mixtures of radionuclides, the determination of the basic radionuclide values referred to in 2.2.7.7.2.1 may be determined as follows: Xm = ¦ i X(i) f(i) where, f(i) is the fraction of activity or activity concentration of radionuclide i in the mixture; X(i) is the appropriate value of A1 or A2, or the activity concentration for exempt material or the activity limit for an exempt consignment as appropriate for the radionuclide i; and Xm is the derived value of A1 or A2, or the activity concentration for exempt material or the activity limit for an exempt consignment in the case of a mixture. 2.2.7.7.2.5 When the identity of each radionuclide is known but the individual activities of some of the radionuclides are not known, the radionuclides may be grouped and the lowest radionuclide value, as appropriate, for the radionuclides in each group may be used in applying the formulas in 2.2.7.7.2.4 and 2.2.7.7.1.4.2. Groups may be based on the total alpha activity and the total beta/gamma activity when these are known, using the lowest radionuclide values for the alpha emitters or beta/gamma emitters, respectively. 2006/128. szám 2.2.7.7.2.6 For individual radionuclides or for mixtures of radionuclides for which relevant data are not available, the values shown in Table 2.2.7.7.2.2 shall be used. 2.2.7.8 Limits on transport index (TI), criticality safety index (CSI), radiation levels for packages and overpacks 2.2.7.8.1 Except for consignments under exclusive use, the transport index of any package or overpack shall not exceed 10, nor shall the criticality safety index of any package or overpack exceed 50. 2.2.7.8.2 Except for packages or overpacks carried under exclusive use by road under the conditions specified in 7.5.11, CW33 (3.5) (a), the maximum radiation level at any point on any external surface of a package or overpack shall not exceed 2 mSv/h. 2.2.7.8.3 The maximum radiation level at any point on any external surface of a package or overpack under exclusive use shall not exceed 10 mSv/h. 2.2.7.8.4 Packages and overpacks shall be assigned to either category I-WHITE, II-YELLOW or III-YELLOW in accordance with the conditions specified in Table 2.2.7.8.4 and with the following requirements: (a) For a package or overpack, both the transport index and the surface radiation level conditions shall be taken into account in determining which is the appropriate category. Where the transport index satisfies the condition for one category but the surface radiation level satisfies the condition for a different category, the package or overpack shall be assigned to the higher category. For this purpose, category I-WHITE shall be regarded as the lowest category; (b) The transport index shall be determined following the procedures specified in 2.2.7.6.1.1 and 2.2.7.6.1.2; (c) If the surface radiation level is greater than 2 mSv/h, the package or overpack shall be carried under exclusive use and under the provisions of 7.5.11, CW33 (3.5) (a); (d) A package carried under a special arrangement shall be assigned to category III-YELLOW; (e) An overpack which contains packages carried under special arrangement shall be assigned to category III-YELLOW. Table 2.2.7.8.4 – Categories of packages and overpacks Conditions Category Transport index (TI) Maximum radiation level at any point on external surface 0(a) Not more than 0.005 mSv/h I-WHITE More than 0 but not more than 1(a) More than 0.005 mSv/h but not more than 0.5 mSv/h II-YELLOW More than 1 but not more than 10 More than 0.5 mSv/h but not more than 2 mSv/h III-YELLOW More than 10 More than 2 mSv/h but not more than 10 mSv/h III-YELLOW(b) (a) If the measured TI is not greater than 0.05, the value quoted may be zero in accordance with 2.2.7.6.1.1 (c). (b) Shall also be carried under exclusive use. 2.2.7.9 Requirements and controls for carriage of excepted packages 2.2.7.9.1 Excepted packages which may contain radioactive material in limited quantities, instruments, manufactured articles as specified in 2.2.7.7.1.2 and empty packagings as specified in 2.2.7.9.6 may be carried under the following conditions: (a) The applicable requirements specified in 2.2.7.9.2, 3.3.1 (special provision 290, if relevant), 4.1.9.1.2, 5.2.1.2, 5.2.1.7.1, 5.2.1.7.2, 5.2.1.7.3, 5.4.1.1.1 (a), 7.5.11 CW33 (5.2) and, as applicable 2.2.7.9.3 to 2.2.7.9.6; (b) The requirements for excepted packages specified in 6.4.4; (c) If the excepted package contains fissile material, one of the fissile exceptions provided by 6.4.11.2 shall apply and the requirement of 6.4.7.2 shall be met. 2.2.7.9.2 The radiation level at any point on the external surface of an excepted package shall not exceed 5 µSv/h. 2006/128. szám 2.2.7.9.3 Radioactive material which is enclosed in or is included as a component part of an instrument or other manufactured article, with activity not exceeding the item and package limits specified in columns 2 and 3 respectively of Table 2.2.7.7.1.2.1, may be carried in an excepted package provided that: (a) The radiation level at 10 cm from any point on the external surface of any unpackaged instrument or article is not greater than 0.1 mSv/h; and (b) Each instrument or manufactured article bears the marking "RADIOACTIVE" except: (i) radioluminescent time-pieces or devices; (ii) consumer products that either have received regulatory approval according to 2.2.7.1.2 (d) or do not individually exceed the activity limit for an exempt consignment in column (5) of Table 2.2.7.7.2.1, provided such products are carried in a package that bears the marking "RADIOAC- TIVE" on an internal surface in such a manner that warning of the presence of radioactive material is visible on opening the package; and (c) The active material is completely enclosed by non-active components (a device performing the sole function of containing radioactive material shall not be considered to be an instrument or manufactured article). 2.2.7.9.4 Radioactive material in forms other than as specified in 2.2.7.9.3, with an activity not exceeding the limit specified in column 4 of Table 2.2.7.7.1.2.1, may be carried in an excepted package provided that: (a) The package retains its radioactive contents under routine conditions of carriage; and (b) The package bears the marking "RADIOACTIVE" on an internal surface in such a manner that a warning of the presence of radioactive material is visible on opening the package. 2.2.7.9.5 A manufactured article in which the sole radioactive material is unirradiated natural uranium, unirradiated depleted uranium or unirradiated natural thorium may be carried as an excepted package provided that the outer surface of the uranium or thorium is enclosed in an inactive sheath made of metal or some other substantial material. 2.2.7.9.6 An empty packaging which had previously contained radioactive material may be carried as an excepted package provided that: (a) It is in a well maintained condition and securely closed; (b) The outer surface of any uranium or thorium in its structure is covered with an inactive sheath made of metal or some other substantial material; (c) The level of internal non-fixed contamination does not exceed one hundred times the levels specified in 4.1.9.1.2; and (d) Any labels which may have been displayed on it in conformity with 5.2.2.1.11.1 are no longer visible. 2.2.7.9.7 The following provisions do not apply to excepted packages and the controls for carriage of excepted packages: 2.2.7.4.1, 2.2.7.4.2, 4.1.9.1.3, 4.1.9.1.4, 5.1.3.2, 5.1.5.1.1, 5.1.5.1.2, 5.2.2.1.11.1, 5.4.1.1.1 except (a), 5.4.1.2.5.1, 5.4.1.2.5.2, 5.4.3, 6.4.6.1, 7.5.11 CW 33 except (5.2). 2.2.7.10 (Reserved) 2006/128. szám 2.2.8 Class 8: Corrosive substances 2.2.8.1 Criteria 2.2.8.1.1 The heading of Class 8 covers substances and articles containing substances of this Class which by chemical action attack epithelial tissue – of skin or mucous membranes – with which they are in contact, or which in the event of leakage are capable of damaging or destroying other goods, or means of transport. The heading of this Class also covers other substances which form a corrosive liquid only in the presence of water, or which produce corrosive vapour or mist in the presence of natural moisture of the air. 2.2.8.1.2 Substances and articles of Class 8 are subdivided as follows: C1 - C10 Corrosive substances without subsidiary risk: C1 - C4 Acid substances: C1 Inorganic, liquid; C2 Inorganic, solid; C3 Organic, liquid; C4 Organic, solid; C5 - C8 Basic substances: C5 Inorganic, liquid; C6 Inorganic, solid; C7 Organic, liquid; C8 Organic, solid; C9 - C10 Other corrosive substances: C9 Liquid; C10 Solid; C11 Articles; CF Corrosive substances, flammable: CF1 Liquid; CF2 Solid; CS Corrosive substances, self-heating: CS1 Liquid; CS2 Solid; CW Corrosive substances which, in contact with water, emit flammable gases: CW1 Liquid; CW2 Solid; CO Corrosive substances, oxidizing: CO1 Liquid; CO2 Solid; CT Corrosive substances, toxic: CT1 Liquid; CT2 Solid; CFT Corrosive substances, flammable, liquid, toxic; COT Corrosive substances, oxidizing, toxic. Classification and assignment of packing groups 2.2.8.1.3 Substances of Class 8 shall be classified in three packing groups according to the degree of danger they present for carriage, as follows: Packing group I: highly corrosive substances Packing group II: corrosive substances Packing group III: slightly corrosive substances. 2.2.8.1.4 Substances and articles classified in Class 8 are listed in Table A of Chapter 3.2. Allocation of substances to packing groups I, II and III has been made on the basis of experience taking into account such additional factors as inhalation risk (see 2.2.8.1.5) and reactivity with water (including the formation of dangerous decomposition products). 2.2.8.1.5 A substance or preparation meeting the criteria of Class 8 having an inhalation toxicity of dusts and mists (LC50) in the range of packing group I, but toxicity through oral ingestion or dermal contact only in the range of packing group III or less, shall be allocated to Class 8. 2006/128. szám 2.2.8.1.6 Substances, including mixtures, not mentioned by name in Table A of Chapter 3.2 can be assigned to the relevant entry of 2.2.8.3, and to the relevant packing group on the basis of the length of time of contact necessary to produce full thickness destruction of human skin in accordance with the criteria of (a) to (c) below. Substances which are judged not to cause full thickness destruction of human skin shall still be considered for their potential to cause corrosion to certain metal surfaces. In assigning the packing group, account shall be taken of human experience in instances of accidental exposure. In the absence of human experience, the grouping shall be based on data obtained from experiments in accordance with OECD Guideline 4045. (a) Packing group I is assigned to substances that cause full thickness destruction of intact skin tissue within an observation period up to 60 minutes starting after the exposure time of 3 minutes or less. (b) Packing group II is assigned to substances that cause full thickness destruction of intact skin tissue within an observation period up to 14 days starting after the exposure time of more than 3 minutes but not more than 60 minutes. (c) Packing group III is assigned to substances that: – cause full thickness destruction of intact skin tissue within an observation period up to 14 days starting after the exposure time of more than 60 minutes but not more than 4 hours; or – are judged not to cause full thickness destruction of intact skin tissue, but which exhibit a corrosion rate on steel or aluminium surfaces exceeding 6.25 mm a year at a test temperature of 55 °C. For the purposes of testing steel, type S235JR+CR (1.0037 resp. St 37-2), S275J2G3+CR (1.0144 resp. St 44-3), ISO 3574, Unified Numbering System (UNS) G10200 or SAE 1020, and for testing aluminium, non-clad, types 7075-T6 or AZ5GU-T6 shall be used. An acceptable test is prescribed in the Manual of Tests and Criteria, Part III, Section 37. 2.2.8.1.7 If substances of Class 8, as a result of admixtures, come into categories of risk different from those to which the substances mentioned by name in Table A of Chapter 3.2 belong, these mixtures or solutions shall be assigned to the entries to which they belong, on the basis of their actual degree of danger. NOTE: For the classification of solutions and mixtures (such as preparations and wastes), see also 2.1.3. 2.2.8.1.8 On the basis of the criteria set out in paragraph 2.2.8.1.6, it may also be determined whether the nature of a solution or mixture mentioned by name or containing a substance mentioned by name is such that the solution or mixture is not subject to the provisions for this Class. 2.2.8.1.9 Substances, solutions and mixtures, which – do not meet the criteria of Directives 67/548/EEC6 or 88/379/EEC7 as amended and therefore are not classified as corrosive according to these directives, as amended; and – do not exhibit a corrosive effect on steel or aluminium, may be considered as substances not belonging to Class 8. NOTE: UN No. 1910 calcium oxide and UN No. 2812 sodium aluminate, listed in the UN Model Regulations, are not subject to the provisions of RID. 2.2.8.2 Substances not accepted for carriage 2.2.8.2.1 The chemically unstable substances of Class 8 shall not be accepted for carriage unless the necessary steps have been taken to prevent their dangerous decomposition or polymerization during carriage. To this end it shall in particular be ensured that receptacles and tanks do not contain any substance liable to promote these reactions. 2.2.8.2.2 The following substances shall not be accepted for carriage: – UN No. 1798 NITROHYDROCHLORIC ACID; – Chemically unstable mixtures of spent sulphuric acid; – Chemically unstable mixtures of nitrating acid or mixtures of residual sulphuric and nitric acids, not denitrated; – Perchloric acid aqueous solution with more than 72% pure acid, by mass, or mixtures of perchloric acid with any liquid other than water. OECD guidelines for Testing of Chemicals, No. 404 " Acute Dermal Irritation/Corrosion" (1992). Council Directive 67/548/EEC of 27 June 1967 on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances (Official Journal of the European Communities No. L 196 of 16.08.1967, page 1). Council Directive 88/379/EEC of 7 June 1988 on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous preparations (Official Journal of the European Communities No. L.187 of 16.07.1988, page 14). 2006/128. szám The following substance shall not be accepted for carriage by rail: – Sulphur trioxide, at least 99.95% pure, without inhibitor (non-stabilized). 2.2.8.3 List of collective entries Classification code UN Name of the substance or article No. Corrosive substances without subsidiary risk 2584 ALKYLSULPHONIC ACIDS, LIQUID with more than 5% free sulphuric acid or 2584 ARYLSULPHONIC ACIDS, LIQUID with more than 5% free sulphuric acid liquid 2693 BISULPHITES, AQUEOUS SOLUTION, N.O.S. C1 2837 BISULPHATES, AQUEOUS SOLUTION 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. inorganic 1740 HYDROGENDIFLUORIDES, N.O.S. Acid solid C2 2583 ALKYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid or 2583 ARYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid 3260 CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. 2586 ALKYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid or 2586 ARYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid liquid 2987 CHLOROSILANES, CORROSIVE, N.O.S. C3 3145 ALKYLPHENOLS, LIQUID, N.O.S. (including C2-C12 homologues) 3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. organic 2430 ALKYLPHENOLS, SOLID, N.O.S. (including C2-C12 homologues) solid C4 2585 ALKYLSULPHONIC ACIDS, SOLID with not more than 5% free sulphuric acid or 2585 ARYLSULPHONIC ACIDS, SOLID with not more than 5% free sulphuric acid 3261 CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. 1719 CAUSTIC ALKALI LIQUID, N.O.S. liquid 2797 BATTERY FLUID, ALKALI C5 3266 CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. inorganic solid C6 3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. Basic 2735 AMINES, LIQUID, CORROSIVE, N.O.S. or liquid 2735 POLYAMINES, LIQUID, CORROSIVE, N.O.S. C7 3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. organic solid 3259 AMINES, SOLID, CORROSIVE, N.O.S., or 3259 POLYAMINES, SOLID, CORROSIVE, N.O.S. C8 3263 CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. 2006/128. szám Corrosive substances without subsidiary risk (cont’d) 1903 DISINFECTANT, LIQUID, CORROSIVE, N.O.S. 2801 DYE, LIQUID, CORROSIVE, N.O.S. or 2801 DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. liquid C9 3066 PAINT (including paint, enamel, stain, shellac, varnish, polish, liquid filler and lacquer base) or 3066 PAINT RELATED MATERIAL (including paint thinning or reducing compound) Other 1760 CORROSIVE LIQUID, N.O.S. corrosive Substances solid(a) C10 3147 DYE, SOLID, CORROSIVE, N.O.S. or 3147 DYE INTERMEDIATE, SOLID, CORROSIVE, N.O.S. 3244 SOLIDS CONTAINING CORROSIVE LIQUID, N.O.S. 1759 CORROSIVE SOLID, N.O.S. 2794 BATTERIES, WET, FILLED WITH ACID, electric storage Articles C11 2795 BATTERIES, WET, FILLED WITH ALKALI, electric storage 2800 BATTERIES, WET, NON-SPILLABLE, electric storage 3028 BATTERIES, DRY, CONTAINING POTASSIUM HY- DROXIDE SOLID, electric storage Subsidiary risk Classification code UN Name of the substance or article No. Corrosive substances with subsidiary risk 2734 AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or 2734 POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. liquid(b) CF1 2986 CHLOROSILANES, CORROSIVE, FLAMMABLE, N.O.S. Flammable 2920 CORROSIVE LIQUID, FLAMMABLE, N.O.S. CF solid CF2 2921 CORROSIVE SOLID, FLAMMABLE, N.O.S. liquid CS1 3301 CORROSIVE LIQUID, SELF-HEATING, N.O.S. Self-heating CS solid CS2 3095 CORROSIVE SOLID, SELF-HEATING, N.O.S. liquid(b) CW1 3094 CORROSIVE LIQUID, WATER-REACTIVE, N.O.S. Water-reactive CW solid CW2 3096 CORROSIVE SOLID, WATER-REACTIVE, N.O.S. Oxidizing liquid CO1 3093 CORROSIVE LIQUID, OXIDIZING, N.O.S. CO solid CO2 3084 CORROSIVE SOLID, OXIDIZING, N.O.S. liquid(c) CT1 2922 CORROSIVE LIQUID, TOXIC, N.O.S. Toxic(d) CT solid(e) CT2 2923 CORROSIVE SOLID, TOXIC, N.O.S. Flammable, liquid, toxic(d) CFT (No collective entry with this classification code available; if need be, classification under a collective entry with a classification code to be determined according to table of precedence of hazard in 2.1.3.10.) Oxidizing, toxic(d),(e) COT (No collective entry with this classification code available; if need be, classification under a collective entry with a classification code to be determined according to table of precedence of hazard in 2.1.3.10.) 2006/128. szám Footnotes (a) Mixtures of solids which are not subject to the provisions of RID and of corrosive liquids may be carried under UN No. 3244 without being subject to the classification criteria of Class 8, provided there is no free liquid visible at the time the substance is loaded or at the time the packaging, wagon or container is closed. Each packaging shall correspond to a design type which has passed the leakproofness test for Packing group II level. (b) Chlorosilanes which, in contact with water or moist air, emit flammable gases, are substances of Class 4.3. (c) Chloroformates having predominantly toxic properties are substances of Class 6.1. (d) Corrosive substances which are highly toxic by inhalation, as defined in 2.2.61.1.4 to 2.2.61.1.9 are substances of Class 6.1. (e) UN No. 1690 SODIUM FLUORIDE, SOLID, UN No. 1812 POTASSIUM FLUORIDE, SOLID, UN No. 2505 AMMONIUM FLUORIDE, UN No. 2674 SODIUM FLUOROSILICATE, UN No. 2856 FLUORO- SILICATES, N.O.S., UN No. 3415 SODIUM FLUORIDE SOLUTION and UN No. 3422 POTASSIUM FLUORIDE SOLUTION are substances of Class 6.1. 2006/128. szám 2.2.9 Class 9: Miscellaneous dangerous substances and articles 2.2.9.1 Criteria 2.2.9.1.1 The heading of Class 9 covers substances and articles which, during carriage, present a danger not covered by the heading of other classes. 2.2.9.1.2 The substances and articles of Class 9 are subdivided as follows: M1 Substances which, on inhalation as fine dust, may endanger health; M2 Substances and apparatus which, in the event of fire, may form dioxins; M3 Substances evolving flammable vapour; M4 Lithium batteries; M5 Life-saving appliances; M6-M8 Environmentally hazardous substances: M6 Pollutant to the aquatic environment, liquid; M7 Pollutant to the aquatic environment, solid; M8 Genetically modified micro-organisms and organisms; M9-M10 Elevated temperature substances: M9 Liquid; M10 Solid; M11 Other substances presenting a danger during carriage, but not meeting the definitions of another class. Definitions and classification 2.2.9.1.3 Substances and articles classified in Class 9 are listed in Table A of Chapter 3.2. The assignment of substances and articles not mentioned by name in Table A of Chapter 3.2 to the relevant entry of that Table or of 2.2.9.3 shall be done in accordance with 2.2.9.1.4 to 2.2.9.1.14 below. Substances which, on inhalation as fine dust, may endanger health 2.2.9.1.4 Substances which, on inhalation as fine dust, may endanger health include asbestos and mixtures containing asbestos. Substances and apparatus which, in the event of fire, may form dioxins 2.2.9.1.5 Substances and apparatus which, in the event of fire, may form dioxins include polychlorinated biphenyls (PCBs) and terphenyls (PCTs) and polyhalogenated biphenyls and terphenyls and mixtures containing these substances, as well as apparatus such as transformers, condensers and apparatus containing those substances or mixtures. NOTE: Mixtures with a PCB or PCT content of not more than 50 mg/kg are not subject to the provisions of RID. Substances evolving flammable vapour 2.2.9.1.6 Substances evolving flammable vapour include polymers containing flammable liquids with a flash-point not exceeding 55 °C. Lithium batteries 2.2.9.1.7 Lithium cells and batteries may be assigned to Class 9 if they meet the requirements of special provision 230 of Chapter 3.3. They are not subject to the provisions of RID if they meet the requirements of special provision 188 of Chapter 3.3. They shall be classified in accordance with the procedures of Section 38.3 of the Manual of Tests and Criteria. Life-saving appliances 2.2.9.1.8 Life-saving appliances include life-saving appliances and motor vehicle components which meet the descriptions of special provisions 235 or 296 of Chapter 3.3. Environmentally hazardous substances 2.2.9.1.9 Environmentally hazardous substances include liquid or solid substances pollutant to the aquatic environment and solutions and mixtures of such substances (such as preparations and wastes), which cannot be classified in the other classes or under any other entry of Class 9 listed in Table A of Chapter 3.2. It also includes genetically modified micro-organisms and organisms. 2006/128. szám Pollutants to the aquatic environment 2.2.9.1.10 Assignment of a substance to the entries UN No. 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S and UN No. 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. as pollutant to the aquatic environment shall be as indicated in 2.3.5. Notwithstanding the provisions of 2.3.5, substances which cannot be assigned to other classes of RID or to other entries of Class 9, and which are not identified in Council Directive 67/548/EEC of 27 June 1967 on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances8, as amended, as substances to which letter N "Environmentally hazardous" (R50; R50/53; R51/53) has been allocated, are not subject to RID. Notwithstanding the provisions of 2.1.3.8, solutions and mixtures (such as preparations and wastes) of substances to which letter N "Environmentally hazardous" (R50; R50/53; R51/53) has been allocated in Directive 67/548/EEC, as amended, need only be assigned to UN Nos. 3077 or 3082 if, according to Directive 1999/45/EC of the European Parliament and of the Council of 31 May 1999 concerning the approximation of the laws, regulations and administrative provisions of the Member States relating to the classification, packaging and labelling of dangerous preparations9, as amended, they are also allocated letter N "Environmentally hazardous" (R50; R50/53; R51/53) and they cannot be assigned to one of classes 1 to 8 or to any other entry of Class 9. Genetically modified micro-organisms or organisms 2.2.9.1.11 Genetically modified micro-organisms (GMMOs) and genetically modified organisms (GMOs) are microorganisms and organisms in which genetic material has been purposely altered through genetic engineering in a way that does not occur naturally. They are assigned to Class 9 (UN No. 3245) if they do not meet the definition of infectious substances, but are capable of altering animals, plants or microbiological substances in a way not normally the result of natural reproduction. NOTE 1: GMMOs which are infectious are substances of Class 6.2 (UN Nos. 2814 and 2900). 2: GMMOs or GMOs are not subject to the provisions of RID when authorized for use by the competent authorities of the countries of origin, transit and destination10. 3: Live animals shall not be used to carry genetically modified micro-organisms classified in Class 9 unless the substance can be carried no other way. 2.2.9.1.12 Genetically modified organisms, which are known or suspected to be dangerous to the environment shall be carried in accordance with conditions specified by the competent authority of the country of origin. Elevated temperature substances 2.2.9.1.13 Elevated temperature substances include substances which are carried or handed over for carriage in the liquid state at or above 100 °C and, in the case of those with a flash-point, below their flash-point. They also include solids which are carried or handed over for carriage at or above 240 °C. NOTE: Elevated temperature substances may be assigned to Class 9 only if they do not meet the criteria of any other class. Other substances presenting a danger during carriage but not meeting the definitions of another class. 2.2.9.1.14 The following other miscellaneous substances not meeting the definitions of another class are assigned to Class 9: Solid ammonia compounds having a flash-point below 61 °C Low hazard dithionites Highly volatile liquids Substances emitting noxious fumes Substances containing allergens Chemical kits and first aid kits Official Journal of the European Communities No.196, of 16 August 1967, pp.1-5. Official Journal of the European Communities No. L 200, of 30 July 1999, pp.1-68. 10 See in particular Part C of Directive 2001/18/EC of the European Parliament and of the Council on the deliberate release into the environment of genetically modified organisms and repealing Council Directive 90/220/EEC (Official Journal of the European Communities, No. L 106, of 17 April 2001, pp. 8-14), which sets out the authorization procedures for the European Community. 2006/128. szám NOTE: UN No. 1845 CARBON DIOXIDE, SOLID (DRY ICE), UN No. 2071 AMMONIUM NITRATE FERTILIZERS, UN No. 2216 FISH MEAL (FISH SCRAP), STABILIZED, UN No. 2807 MAGNETIZED MATERIAL, UN No. 3166 ENGINE, INTERNAL COMBUSTION or VEHICLE, FLAMMABLE GAS POWERED or VEHICLE, FLAMMABLE LIQUID POWERED, UN No. 3171 BATTERY-POWERED VEHICLE or 3171 BATTERY-POWERED EQUIPMENT (WET BATTERY), UN No. 3334 AVIATION REGULATED LIQUID, N.O.S., UN No. 3335 AVIATION REGULATED SOLID, N.O.S., UN No. 3363 DANGEROUS GOODS IN MACHINERY or UN No. 3363 DANGEROUS GOODS IN APPARATUS, listed in the UN Model Regulations, are not subject to the provisions of RID. Assignment of the packing groups 2.2.9.1.15 The substances and articles of Class 9 listed as such in Table A of Chapter 3.2 shall be assigned to one of the following packing groups according to their degree of danger: Packing group II: substances presenting medium danger Packing group III: substances presenting low danger 2.2.9.2 Substances and articles not accepted for carriage The following substances and articles shall not be accepted for carriage: – Lithium batteries which do not meet the relevant conditions of special provisions 188, 230 or 636 of Chapter 3.3. – Uncleaned empty containment vessels for apparatus such as transformers and condensers containing substances assigned to UN Nos. 2315, 3151 or 3152. 2.2.9.3 List of entries Classification code UN Name of the substance or article No. Miscellaneous dangerous substances and articles Substances which, on inhalation as fine dust, may M1 2212 BLUE ASBESTOS (crocidolite) or 2212 BROWN ASBESTOS (amosite, mysorite) endanger health 2590 WHITE ASBESTOS (chrysotile, actinolite, anthophyllite, tremolite) 2315 POLYCHLORINATED BIPHENYLS, LIQUID 3432 POLYCHLORINATED BIPHENYLS, SOLID Substances and apparatus which, in the event of fire, M2 3151 POLYHALOGENATED BIPHENYLS, LIQUID or 3151 POLYHALOGENATED TERPHENYLS, LIQUID may form dioxins 3152 POLYHALOGENATED BIPHENYLS, SOLID or 3152 POLYHALOGENATED TERPHENYLS, SOLID 2211 POLYMERIC BEADS, EXPANDABLE, evolving flammable vapour Substances evolving flammable vapour M3 3314 PLASTICS MOULDING COMPOUND in dough, sheet or extruded rope form evolving flammable vapour 3090 LITHIUM BATTERIES Lithium batteries M4 3091 LITHIUM BATTERIES CONTAINED IN EQUIPMENT or 3091 LITHIUM BATTERIES PACKED WITH EQUIPMENT 2990 LIFE-SAVING APPLIANCES, SELF-INFLATING such as aircraft evacuation chutes, aircraft survival kits and maritime life-saving appliances Live-saving appliances M5 3072 LIFE-SAVING APPLIANCES NOT SELF-INFLATING containing dangerous goods as equipment 3268 AIR BAG INFLATORS or 3268 AIR BAG MODULES or 3268 SEAT-BELT PRETENSIONERS 2006/128. szám liquid M6 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. pollutant to the aquatic environment solid M7 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. Environmentally hazardous substances genetically modified micro-organisms and organisms 3245 GENETICALLY MODIFIED MICRO-ORGANISMS liquid M9 3257 ELEVATED TEMPERATURE LIQUID, N.O.S., at or above 100 °C and below its flash-point (including molten metal, molten salts, etc.) Elevated temperature substances solid M10 3258 ELEVATED TEMPERATURE SOLID, N.O.S., at or above 240 °C Other substances or articles presenting a danger during carriage, but not meeting the definitions of another class M11 No collective entry available. Only substances listed in Table A of Chapter 3.2 are subject to the provisions for Class 9 under this classification code, as follows: 1841 ACETALDEHYDE AMMONIA 1931 ZINC DITHIONITE (ZINC HYDROSULPHITE) 1941 DIBROMODIFLUOROMETHANE 1990 BENZALDEHYDE 2969 CASTOR BEANS or 2969 CASTOR MEAL or 2969 CASTOR POMACE or 2969 CASTOR FLAKE 3316 CHEMICAL KIT or 3316 FIRST AID KIT 3359 FUMIGATED UNIT 2006/128. szám Chapter 2.3 Test methods 2.3.0 General Unless otherwise provided for in Chapter 2.2 or in this Chapter, the test methods to be used for the classification of dangerous goods are those described in the Manual of Tests and Criteria. 2.3.1 Exudation test for blasting explosives of Type A 2.3.1.1 Blasting explosives of type A (UN No. 0081) shall, if they contain more than 40% liquid nitric ester, in addition to the testing specified in the Manual of Tests and Criteria, satisfy the following exudation test. 2.3.1.2 The apparatus for testing blasting explosive for exudation (figs. 1 to 3) consists of a hollow bronze cylinder. This cylinder, which is closed at one end by a plate of the same metal, has an internal diameter of 15.7 mm and a depth of 40 mm. It is pierced by 20 holes 0.5 mm in diameter (four sets of five holes) on the circumference. A bronze piston, cylindrically fashioned over a length of 48 mm and having a total length of 52 mm, slides into the vertically placed cylinder. The piston, whose diameter is 15.6 mm, is loaded with a mass of 2 220 g so that a pressure of 120 kPa (1.20 bar) is exerted on the base of the cylinder. 2.3.1.3 A small plug of blasting explosive weighing 5 to 8 g, 30 mm long and 15 mm in diameter, is wrapped in very fine gauze and placed in the cylinder; the piston and its loading mass are then placed on it so that the blasting explosive is subjected to a pressure of 120 kPa (1.20 bar). The time taken for the appearance of the first signs of oily droplets (nitroglycerine) at the outer orifices of the cylinder holes is noted. 2.3.1.4 The blasting explosive is considered satisfactory if the time elapsing before the appearance of the liquid exudations is more than five minutes, the test having been carried out at a temperature of 15 °C to 25 °C. 2006/128. szám Test of blasting explosive for exudation Fig. 1 to 3:

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