Publication: Magyar Közlöny
Issue: MK-2006-128 (Year: 2006, Number: 128)
Era: 2004-2010
Section: 217/1998. (XII. 30.) Korm. rendelet
Paragraph Index: 4829

(5) a package shall not weigh more than 120 kg. (a) The name may be replaced by a generic description covering substances of a similar nature and also compatible with the characteristics of the receptacle. (b) The units of measurement to be added each time after the numerical values. 2006/128. szám 4.1.5 Special packing provisions for goods of Class 1 4.1.5.1 The general provisions of Section 4.1.1 shall be met. 4.1.5.2 All packagings for Class 1 goods shall be so designed and constructed that: (a) They will protect the explosives, prevent them escaping and cause no increase in the risk of unintended ignition or initiation when subjected to normal conditions of carriage including foreseeable changes in temperature, humidity and pressure; (b) The complete package can be handled safely in normal conditions of carriage; and (c) The packages will withstand any loading imposed on them by foreseeable stacking to which they will be subject during carriage so that they do not add to the risk presented by the explosives, the containment function of the packagings is not harmed, and they are not distorted in a way or to an extent which will reduce their strength or cause instability of a stack. 4.1.5.3 All explosive substances and articles, as prepared for carriage, shall have been classified in accordance with the procedures detailed in 2.2.1. 4.1.5.4 Class 1 goods shall be packed in accordance with the appropriate packing instruction shown in Column (8) of Table A of Chapter 3.2, as detailed in 4.1.4. 4.1.5.5 Packagings, including IBCs and large packagings shall conform to the requirements of Chapter 6.1, 6.5 or 6.6, respectively, and shall meet the test requirements of 6.1.5, 6.5.4 or 6.6.5, respectively, for packing group II, subject to 4.1.1.13, 6.1.2.4 and 6.5.1.4.4. Packagings other than metal packagings meeting the test criteria of packing group I may be used. To avoid unnecessary confinement, metal packagings of packing group I shall not be used. 4.1.5.6 The closure device of packagings containing liquid explosives shall ensure a double protection against leakage. 4.1.5.7 The closure device of metal drums shall include a suitable gasket; if a closure device includes a screwthread, the ingress of explosive substances into the screw-thread shall be prevented. 4.1.5.8 Packagings for water soluble substances shall be water resistant. Packagings for desensitized or phlegmatized substances shall be closed to prevent changes in concentration during carriage. 4.1.5.9 (Reserved) 4.1.5.10 Nails, staples and other closure devices made of metal without protective covering shall not penetrate to the inside of the outer packaging unless the inner packaging adequately protects the explosives against contact with the metal. 4.1.5.11 Inner packagings, fittings and cushioning materials and the placing of explosive substances or articles in packages shall be accomplished in a manner which prevents the explosive substances or articles from becoming loose in the outer packaging under normal conditions of carriage. Metallic components of articles shall be prevented from making contact with metal packagings. Articles containing explosive substances not enclosed in an outer casing shall be separated from each other in order to prevent friction and impact. Padding, trays, partitioning in the inner or outer packaging, mouldings or receptacles may be used for this purpose. 4.1.5.12 Packagings shall be made of materials compatible with, and impermeable to, the explosives contained in the package, so that neither interaction between the explosives and the packaging materials, nor leakage, causes the explosive to become unsafe to carriage, or the hazard division or compatibility group to change. 4.1.5.13 The ingress of explosive substances into the recesses of seamed metal packagings shall be prevented. 4.1.5.14 Plastics packagings shall not be liable to generate or accumulate sufficient static electricity so that a discharge could cause the packaged explosive substances or articles to initiate, ignite or function. 4.1.5.15 Large and robust explosives articles, normally intended for military use, without their means of initiation or with their means of initiation containing at least two effective protective features, may be carried unpackaged. When such articles have propelling charges or are self-propelled, their ignition systems shall be protected against stimuli encountered during normal conditions of carriage. A negative result in Test Series 4 on an unpackaged article indicates that the article can be considered for carriage unpackaged. Such unpackaged articles may be fixed to cradles or contained in crates or other suitable handling, storage or launching devices in such a way that they will not become loose during normal conditions of carriage. Where such large explosive articles are as part of their operational safety and suitability tests subjected to test regimes that meet the intentions of RID and such tests have been successfully undertaken, the competent authority may approve such articles to be carried in accordance with RID. 2006/128. szám 4.1.5.16 Explosive substances shall not be packed in inner or outer packagings where the differences in internal and external pressures, due to thermal or other effects, could cause an explosion or rupture of the package. 4.1.5.17 Whenever loose explosive substances or the explosive substance of an uncased or partly cased article may come into contact with the inner surface of metal packagings (1A2, 1B2, 4A, 4B and metal receptacles), the metal packaging shall be provided with an inner liner or coating (see 4.1.1.2). 4.1.5.18 Packing instruction P101 may be used for any explosive provided the packaging has been approved by a competent authority regardless of whether the packaging complies with the packing instruction assignment in Column (8) of Table A of Chapter 3.2. 4.1.6 Special packing provisions for goods of Class 2 and goods of other classes assigned to packing instruction P200 NOTE: For goods of other classes carried in pressure receptacles and assigned to packing instructions PR1 to PR7, see 4.1.4.4. 4.1.6.1 This section provides general requirements applicable to the use of pressure receptacles and open cryogenic receptacles for the carriage of Class 2 substances and goods of other classes assigned to packing instruction P200 (e.g. UN 1051 hydrogen cyanide, stabilized). Pressure receptacles shall be constructed and closed so as to prevent any loss of contents which might be caused under normal conditions of carriage, including by vibration, or by changes in temperature, humidity or pressure (resulting from change in altitude, for example). 4.1.6.2 Parts of pressure receptacles and open cryogenic receptacles which are in direct contact with dangerous goods shall not be affected or weakened by those dangerous goods and shall not cause a dangerous effect (e.g. catalysing a reaction or reacting with the dangerous goods). Pressure receptacles for UN 1001 acetylene, dissolved, and UN 3374 acetylene, solvent free, shall be filled with a porous mass, uniformly distributed, of a type that conforms to the requirements and testing specified by the competent authority and which: (a) is compatible with the pressure receptacle and does not form harmful or dangerous compounds either with the acetylene or with the solvent in the case of UN 1001; and (b) is capable of preventing the spread of decomposition of the acetylene in the mass. In the case of UN 1001, the solvent shall be compatible with the pressure receptacles. 4.1.6.3 Pressure receptacles, including their closures and open cryogenic receptacles, shall be selected to contain a gas or a mixture of gases according to the requirements of 6.2.1.2 and the requirements of the relevant packing instructions of 4.1.4.1. This sub-section also applies to pressure receptacles which are elements of MEGCs and battery-wagons. 4.1.6.4 A change of use of a refillable pressure receptacle shall include emptying, purging and evacuation operations to the extent necessary for safe operation (see also table of standards at the end of this section). In addition, a pressure receptacle that previously contained a Class 8 corrosive substance or a substance of another class with a corrosive subsidiary risk shall not be authorized for the carriage of a Class 2 substance unless the necessary inspection and testing as specified in 6.2.1.5 have been performed. 4.1.6.5 Prior to filling, the packer shall perform an inspection of the pressure receptacle or open cryogenic receptacle and ensure that the pressure receptacle or open cryogenic receptacle is authorized for the substance to be carried and that the requirements have been met. Shut-off valves shall be closed after filling and remain closed during carriage. The consignor shall verify that the closures and equipment are not leaking. NOTE: Shut-off valves fitted to individual cylinders in bundles may be open during carriage, unless the substance carried is subject to special packing provision "k" or "q" in packing instruction P200. 4.1.6.6 Pressure receptacles and open cryogenic receptacles shall be filled according to the working pressures, filling ratios and provisions specified in the appropriate packing instruction for the specific substance being filled. Reactive gases and gas mixtures shall be filled to a pressure such that if complete decomposition of the gas occurs, the working pressure of the pressure receptacle shall not be exceeded. Bundles of cylinders shall not be filled in excess of the lowest working pressure of any given cylinder in the bundle. 4.1.6.7 Pressure receptacles, including their closures, shall conform to the design, construction, inspection and testing requirements detailed in Chapter 6.2. When outer packagings are prescribed, the pressure receptacles and open cryogenic receptacles shall be firmly secured therein. Unless otherwise specified in the detailed packing instructions, one or more inner packagings may be enclosed in one outer packaging. 4.1.6.8 Valves shall be designed and constructed in such a way that they are inherently able to withstand damage without release of the contents or shall be protected from damage which could cause inadvertent release of the contents of the pressure receptacle, by one of the following methods (see also table of standards at the end of this section): (a) Valves are placed inside the neck of the pressure receptacle and protected by a threaded plug or cap; 2006/128. szám (b) Valves are protected by caps. Caps shall possess vent-holes of sufficient cross-sectional area to evacuate the gas if leakage occurs at the valves; (c) Valves are protected by shrouds or guards; (d) Valves are placed in a protective frame; (e) Pressure receptacles are carried in frames, (e.g. cylinders in bundles); or (f) Pressure receptacles are carried in protective boxes. 4.1.6.9 Non-refillable pressure receptacles shall: (a) be carried in an outer packaging, such as a box or crate, or in shrink-wrapped or stretch-wrapped trays; (b) be of a water capacity less than or equal to 1.25 litres when filled with flammable or toxic gas; (c) not be used for toxic gases with an LC50 less than or equal to 200 ml/m3; and (d) not be repaired after being put into service. 4.1.6.10 Refillable pressure receptacles shall be periodically inspected according to the provisions of 6.2.1.6 and packing instruction P200 or P203 as applicable. Pressure receptacles shall not be filled after they become due for periodic inspection but may be carried after the expiry of the time-limit for purposes of performing inspection or disposal, including the intermediate carriage operations. 4.1.6.11 Repairs shall be consistent with the fabrication and testing requirements of the applicable design and construction standards and are only permitted as indicated in the relevant periodic inspection standards specified in Chapter 6.2. Pressure receptacles, other than the jacket of closed cryogenic receptacles, shall not be subjected to repairs of any of the following: (a) weld cracks or other weld defects; (b) cracks in walls; (c) leaks or defects in the material of the wall, head or bottom. 4.1.6.12 Pressure receptacles shall not be offered for filling: (a) when damaged to such an extent that the integrity of the pressure receptacle or its service equipment may be affected; (b) unless the pressure receptacle and its service equipment has been examined and found to be in good working order; and (c) unless the required certification, retest, and filling markings are legible. 4.1.6.13 Filled pressure receptacles shall not be offered for carriage: (a) when leaking; (b) when damaged to such an extent that the integrity of the pressure receptacle or its service equipment may be affected; (c) unless the pressure receptacle and its service equipment has been examined and found to be in good working order; and (d) unless the required certification, retest, and filling markings are legible. 4.1.6.14 For UN pressure receptacles, the ISO standards listed below shall be applied. For other pressure receptacles, the requirements of section 4.1.6 are considered to have been complied with if the following standards, as relevant, are applied: Applicable paragraphs Reference Document title ISO 11114- 1:1997 Transportable gas cylinders – Compatibility of cylinder and valve materials with gas contents – Part 1: Metallic Materials 4.1.6.2 ISO 11114- 2:2000 Transportable gas cylinders – Compatibility of cylinder and valve materials with gas contents – Part 2: Non-metallic Materials ISO 11621:1997 Gas cylinders – Procedures for change of gas service 4.1.6.4 EN 1795:1997 Gas cylinders (excluding LPG) – Procedures for change of gas service 4.1.6.8 Annex B of ISO 10297:1999 Gas cylinder – Refillable gas cylinder valves – Specification and type testing 2006/128. szám Applicable paragraphs Reference Document title Valves with inherent protection Annex A of EN 849:1996/ A2:2001 Transportable gas cylinders – Cylinder valves: Specifications and type testing – Amendment 2 EN 13152:2001 Testing and specifications of LPG cylinder valves – self closing EN 13153:2001 Testing and specifications of LPG cylinder valves – manually operated ISO 11117:1998 Gas Cylinders – Valve Protection caps and valve guards for industrial and medical gas cylinders – Design construction and tests 4.1.6.8 (b) and (c) EN 962:1996/ A2:2000 Valve protection caps and valve guards for industrial and medical gas cylinders – Design, construction and tests 4.1.7 Special packing provisions for organic peroxides of Class 5.2 and self-reactive substances of Class 4.1 4.1.7.0.1 For organic peroxides, all receptacles shall be "effectively closed". Where significant internal pressure may develop in a package by the evolution of a gas, a vent may be fitted, provided the gas emitted will not cause danger, otherwise the degree of filling shall be limited. Any venting device shall be so constructed that liquid will not escape when the package is in an upright position and it shall be able to prevent ingress of impurities. The outer packaging, if any, shall be so designed as not to interfere with the operation of the venting device. 4.1.7.1 Use of packagings 4.1.7.1.1 Packagings for organic peroxides and self-reactive substances shall meet the requirements of Chapter 6.1 or of Chapter 6.6 at the packing group II performance level. To avoid unnecessary confinement, metal packagings meeting the test criteria of packing group I shall not be used. 4.1.7.1.2 The packing methods for organic peroxides and self-reactive substances are listed in packing instruction 520 and are designated OP1 to OP8. The quantities specified for each packing method are the maximum quantities authorized per package. 4.1.7.1.3 The packing methods appropriate for the individual currently assigned organic peroxides and self-reactive substances are listed in 2.2.41.4 and 2.2.52.4. 4.1.7.1.4 For new organic peroxides, new self-reactive substances or new formulations of currently assigned organic peroxides or self-reactive substances, the following procedure shall be used to assign the appropriate packing method: (a) ORGANIC PEROXIDE, TYPE B or SELF-REACTIVE SUBSTANCE, TYPE B: Packing method OP5 shall be assigned, provided that the organic peroxide (or self-reactive substance) satisfies the criteria of 20.4.3 (b) (resp. 20.4.2 (b)) of the Manual of Tests and Criteria in a packaging authorized by the packing method. If the organic peroxide (or self-reactive substance) can only satisfy these criteria in a smaller packaging than those authorized by packing method OP5 (viz. one of the packagings listed for OP1 to OP4), then the corresponding packing method with the lower OP number is assigned; (b) ORGANIC PEROXIDE, TYPE C or SELF-REACTIVE SUBSTANCE, TYPE C: Packing method OP6 shall be assigned, provided that the organic peroxide (or self-reactive substance) satisfies the criteria of 20.4.3 (c) (resp. 20.4.2 (c)) of the Manual of Tests and Criteria in a packaging authorized by the packing method. If the organic peroxide (or self-reactive substance) can only satisfy these criteria in a smaller packaging than those authorized by packing method OP6 then the corresponding packing method with the lower OP number is assigned; (c) ORGANIC PEROXIDE, TYPE D or SELF-REACTIVE SUBSTANCE, TYPE D: Packing method OP7 shall be assigned to this type of organic peroxide or self-reactive substance; (d) ORGANIC PEROXIDE, TYPE E or SELF-REACTIVE SUBSTANCE, TYPE E: Packing method OP8 shall be assigned to this type of organic peroxide or self-reactive substance; (e) ORGANIC PEROXIDE, TYPE F or SELF-REACTIVE SUBSTANCE, TYPE F: Packing method OP8 shall be assigned to this type of organic peroxide or self-reactive substance. 2006/128. szám 4.1.7.2 Use of intermediate bulk containers 4.1.7.2.1 The currently assigned organic peroxides specifically listed in packing instruction IBC520 may be carried in IBCs in accordance with this packing instruction. 4.1.7.2.2 Other organic peroxides and self-reactive substances of type F may be carried in IBCs under conditions established by the competent authority of the country of origin when, on the basis of the appropriate tests, that competent authority is satisfied that such carriage may be safely conducted. The tests undertaken shall include those necessary: (a) To prove that the organic peroxide (or self-reactive substance) complies with the principles for classification given in 20.4.3 (f) [resp. 20.4.2 (f)] of the Manual of Tests and Criteria, exit box F of Figure 20.1 (b) of the Manual; (b) To prove the compatibility of all materials normally in contact with the substance during carriage; (c) (Reserved) (d) To design, when applicable, pressure and emergency relief devices; and (e) To determine if any special provisions are necessary for safe carriage of the substance. If the country of origin is not a COTIF Member State, the classification and transport conditions shall be recognized by the competent authority of the first COTIF Member State reached by the consignment. 4.1.7.2.3 Emergencies to be taken into account are self-accelerating decomposition and fire engulfment. To prevent explosive rupture of metal or composite IBCs with a complete metal casing, the emergency-relief devices shall be designed to vent all the decomposition products and vapours evolved during self-accelerating decomposition or during a period of not less than one hour of complete fire engulfment calculated by the equations given in 4.2.1.13.8. 4.1.8 Special packing provisions for infectious substances of Class 6.2 4.1.8.1 Consignors of infectious substances shall ensure that packages are prepared in such a manner that they arrive at their destination in good condition and present no hazard to persons or animals during carriage. 4.1.8.2 The definitions in 1.2.1 and the general requirements of 4.1.1.1 to 4.1.1.16, except 4.1.1.3, 4.1.1.9 to 4.1.1.12 and 4.1.1.15 apply to infectious substances packages. However, liquids shall be filled into packagings, including IBCs, which have an appropriate resistance to the internal pressure that may develop under normal conditions of carriage. 4.1.8.3 For UN No. 2814 and UN No. 2900, an itemized list of contents shall be enclosed between the secondary packaging and the outer packaging. When the infectious substances to be carried are unknown, but suspected of meeting the criteria for inclusion in category A and assignment to UN Nos. 2814 or 2900, the words "suspected category A infectious substance" shall be shown, in parenthesis, following the proper shipping name on the document inside the outer packaging. 4.1.8.4 Before an empty packaging is returned to the consignor, or sent elsewhere, it shall be thoroughly disinfected or sterilized and any label or marking indicating that it had contained an infectious substance shall be removed or obliterated. 4.1.8.5 The provisions of this section do not apply to UN No. 3373 Diagnostic specimens or clinical specimens (see packing instruction P650). 4.1.9 Special packing provisions for Class 7 4.1.9.1 General 4.1.9.1.1 Radioactive material, packagings and packages shall meet the requirements of Chapter 6.4. The quantity of radioactive material in a package shall not exceed the limits specified in 2.2.7.7.1. 4.1.9.1.2 The non-fixed contamination on the external surfaces of any package shall be kept as low as practicable and, under routine conditions of transport, shall not exceed the following limits: (a) 4 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters; and (b) 0.4 Bq/cm2 for all other alpha emitters. These limits are applicable when averaged over any area of 300 cm2 of any part of the surface. 2006/128. szám 4.1.9.1.3 A package shall not contain any other items except such articles and documents as are necessary for the use of the radioactive material. This requirement shall not preclude the carriage of low specific activity material or surface contaminated objects with other items. The carriage of such articles and documents in a package, or of low specific activity material or surface contaminated objects with other items may be permitted provided that there is no interaction between them and the packaging or its radioactive contents that would reduce the safety of the package. 4.1.9.1.4 Except as provided in 7.5.11, CW33, the level of non-fixed contamination on the external and internal surfaces of overpacks, containers, tanks, IBCs and wagons shall not exceed the limits specified in 4.1.9.1.2. 4.1.9.1.5 Radioactive material with a subsidiary risk shall be carried in packagings, IBCs or tanks fully complying with the requirements of the relevant chapters of Part 6 as appropriate, as well as applicable requirements of Chapters 4.1, 4.2 or 4.3 for that subsidiary risk. 4.1.9.2 Requirements and controls for carriage of LSA material and SCO 4.1.9.2.1 The quantity of LSA material or SCO in a single Type IP-1 package, Type IP-2 package, Type IP-3 package, or object or collection of objects, whichever is appropriate, shall be so restricted that the external radiation level at 3 m from the unshielded material or object or collection of objects does not exceed 10 mSv/h. 4.1.9.2.2 LSA material and SCO which is or contains fissile material shall meet the applicable requirements of 7.5.11, CV33 and 6.4.11.1. 4.1.9.2.3 LSA material and SCO in groups LSA-I and SCO-I may be carried unpackaged under the following conditions: (a) All unpackaged material other than ores containing only naturally occurring radionuclides shall be carried in such a manner that under routine conditions of carriage there will be no escape of the radioactive contents from the wagon nor will there be any loss of shielding; (b) Each wagon shall be under exclusive use, except when only carrying SCO-I on which the contamination on the accessible and the inaccessible surfaces is not greater than ten times the corresponding level according to the definition of "contamination" in 2.2.7.2; and (c) For SCO-I where it is suspected that non-fixed contamination exists on inaccessible surfaces in excess of the values specified in 2.2.7.5 (a)(i), measures shall be taken to ensure that the radioactive material is not released into the wagon. 4.1.9.2.4 LSA material and SCO, except as otherwise specified in 4.1.9.2.3, shall be packaged in accordance with the table below: Industrial package requirements for LSA material and SCO Radioactive contents Industrial package type Exclusive use Not under exclusive use LSA-I Solid(a) Liquid Type IP-1 Type IP-1 Type IP-1 Type IP-2 LSA-II Solid Liquid and gas Type IP-2 Type IP-2 Type IP-2 Type IP-3 LSA-III Type IP-2 Type IP-3 SCO-I(a) Type IP-1 Type IP-1 SCO-II Type IP-2 Type IP-2 (a) Under the conditions specified in 4.1.9.2.3, LSA-I material and SCO-I may be carried unpackaged. 2006/128. szám 4.1.10 Special provisions for mixed packing 4.1.10.1 When mixed packing is permitted in accordance with the provisions of this section, different dangerous goods or dangerous goods and other goods may be packed together in combination packagings conforming to 6.1.4.21, provided that they do not react dangerously with one another and that all other relevant provisions of this Chapter are complied with. NOTE 1: See also 4.1.1.5 and 4.1.1.6. 2: For goods of Class 7, see 4.1.9. 4.1.10.2 Except for packages containing Class 1 goods only or Class 7 goods only, if wooden or fibreboard boxes are used as outer packagings, a package containing different goods packed together shall not weigh more than 100 kg. 4.1.10.3 Unless otherwise prescribed by a special provision applicable according to 4.1.10.4, dangerous goods of the same class and the same classification code may be packed together. 4.1.10.4 When indicated for a given entry in Column (9b) of Table A of Chapter 3.2, the following special provisions shall apply to the mixed packing of the goods assigned to that entry with other goods in the same package. MP 1 May only be packed together with goods of the same type within the same compatibility group. MP 2 Shall not be packed together with other goods. MP 3 Mixed packing of UN No. 1873 with UN No. 1802 is permitted. MP 4 Shall not be packed together with goods of other classes or with goods which are not subject to the requirements of RID. However, if this organic peroxide is a hardener or compound system for Class 3 substances, mixed packing is permitted with these substances of Class 3. MP 5 UN No. 2814 and UN No. 2900 may be packed together in a combination packaging in conformity with P620. They shall not be packed together with other goods; this does not apply to UN No. 3373 Diagnostic specimens or clinical specimens packed in accordance with P650 or to substances added as coolants, e.g. ice, dry ice or refrigerated liquid nitrogen. MP 6 Shall not be packed together with other goods. This does not apply to substances added as coolants, e.g. ice, dry ice or refrigerated liquid nitrogen. MP 7 May – in quantities not exceeding 5 litres per inner packaging – be packed together in a combination packaging conforming to 6.1.4.21: – with goods of the same class covered by other classification codes when mixed packing is also permitted for these; or – with goods which are not subject to the requirements of RID, provided they do not react dangerously with one another. MP 8 May – in quantities not exceeding 3 litres per inner packaging – be packed together in a combination packaging conforming to 6.1.4.21: – with goods of the same class covered by other classification codes when mixed packing is also permitted for these; or – with goods which are not subject to the requirements of RID, provided they do not react dangerously with one another. MP 9 May be packed together in an outer packaging for combination packagings in accordance with 6.1.4.21: – with other goods of Class 2; – with goods of other classes, when the mixed packing is also permitted for these; or – with goods which are not subject to the requirements of RID, provided they do not react dangerously with one another. MP 10 May – in quantities not exceeding 5 kg per inner packaging – be packed together in a combination packaging conforming to 6.1.4.21: – with goods of the same class covered by other classification codes or with goods of other classes, when mixed packing is also permitted for these; or – with goods which are not subject to the requirements of RID, provided they do not react dangerously with one another. 2006/128. szám MP 11 May – in quantities not exceeding 5 kg per inner packaging – be packed together in a combination packaging conforming to 6.1.4.21: – with goods of the same class covered by other classification codes or with goods of other classes (except substances of packing group I or II of Class 5.1) when mixed packing is also permitted for these; or – with goods which are not subject to the requirements of RID, provided they do not react dangerously with one another. MP 12 May – in quantities not exceeding 5 kg per inner packaging – be packed together in a combination packaging conforming to 6.1.4.21: – with goods of the same class covered by other classification codes or with goods of other classes (except substances of packing group I or II of Class 5.1) when mixed packing is also permitted for these; or – with goods which are not subject to the requirements of RID, provided they do not react dangerously with one another. Packagings shall not weigh more than 45 kg. If fibreboard boxes are used as outer packagings however, a package shall not weigh more than 27 kg. MP 13 May – in quantities not exceeding 3 kg per inner packaging and per package – be packed together in a combination packaging conforming to 6.1.4.21: – with goods of the same class covered by other classification codes or with goods of other classes, when mixed packing is also permitted for these; or – with goods which are not subject to the requirements of RID, provided they do not react dangerously with one another. MP 14 May – in quantities not exceeding 6 kg per inner packaging – be packed together in a combination packaging conforming to 6.1.4.21: – with goods of the same class covered by other classification codes or with goods of other classes, when mixed packing is also permitted for these; or – with goods which are not subject to the requirements of RID, provided they do not react dangerously with one another. MP 15 May – in quantities not exceeding 3 litres per inner packaging – be packed together in a combination packaging conforming to 6.1.4.21: – with goods of the same class covered by other classification codes or with goods of other classes, when mixed packing is also permitted for these; or – with goods which are not subject to the requirements of RID, provided they do not react dangerously with one another. MP 16 May – in quantities not exceeding 3 litres per inner packaging and per package – be packed together in a combination packaging conforming to 6.1.4.21: – with goods of the same class covered by other classification codes or with goods of other classes, when mixed packing is also permitted for these; or – with goods which are not subject to the requirements of RID, provided they do not react dangerously with one another. MP 17 May – in quantities not exceeding 0.5 litre per inner packaging and 1 litre per package – be packed together in a combination packaging conforming to 6.1.4.21: – with goods of other classes, except Class 7, when mixed packing is also permitted for these; or – with goods which are not subject to the requirements of RID, provided they do not react dangerously with one another. MP 18 May – in quantities not exceeding 0.5 kg per inner packaging and 1 kg per package – be packed together in a combination packaging conforming to 6.1.4.21: – with goods or articles of other classes, except Class 7, when mixed packing is also permitted for these; or – with goods which are not subject to the requirements of RID, provided they do not react dangerously with one another. 2006/128. szám MP 19 May – in quantities not exceeding 5 litres per inner packaging – be packed together in a combination packaging conforming to 6.1.4.21: – with goods of the same class covered by other classification codes or with goods of other classes, when mixed packing is also permitted for these; or – with goods which are not subject to the requirements of RID, provided they do not react dangerously with one another. MP 20 May be packed together with substances covered by the same UN number. Shall not be packed together with goods and articles of Class 1 having different UN numbers. Shall not be packed together with goods of other classes or with goods which are not subject to the requirements of RID. MP 21 May be packed together with articles covered by the same UN number. Shall not be packed together with goods of Class 1 having different UN numbers, except for (a) their own means of initiation, provided that (i) the means of initiation will not function under normal conditions of carriage; or (ii) such means have at least two effective protective features which prevent explosion of an article in the event of accidental functioning of the means of initiation; or (iii) when such means do not have two effective protective features (i.e. means of initiation assigned to compatibility group B), in the opinion of the competent authority of the country of origin3 the accidental functioning of the means of initiation does not cause the explosion of an article under normal conditions of carriage; (b) articles of compatibility groups C, D and E. Shall not be packed together with goods of other classes or with goods which are not subject to the requirements of RID. When goods are packed together in accordance with this special provision, account shall be taken of a possible amendment of the classification of packages in accordance with 2.2.1.1. For the description of the goods in the consignment note, see 5.4.1.2.1 (b). MP 22 May be packed together with articles covered by the same UN number. Shall not be packed together with goods of Class 1 having different UN numbers, except for (a) their own means of initiation, provided that the means of initiation will not function under normal conditions of carriage; (b) articles of compatibility groups C, D and E. Shall not be packed together with goods of other classes or with goods which are not subject to the requirements of RID. When goods are packed together in accordance with this special provision, account shall be taken of a possible amendment of the classification of packages in accordance with 2.2.1.1. For the description of the goods in the consignment note, see 5.4.1.2.1 (b). MP 23 May be packed together with articles covered by the same UN number. Shall not be packed together with goods and articles of Class 1 having different UN numbers; however, exception is made for their own means of initiation, provided that the means of initiation will not function under normal conditions of carriage. Shall not be packed together with goods of other classes or with goods which are not subject to the requirements of RID. When goods are packed together in accordance with this special provision, account shall be taken of a possible amendment of the classification of packages in accordance with 2.2.1.1. For the description of the goods in the consignment note, see 5.4.1.2.1 (b). 3 If the country of origin is not a COTIF Member State, the approval shall require validation by the competent authority of the first COTIF Member State reached by the consignment. 2006/128. szám MP 24 May be packed together with goods with the UN numbers shown in the table below, under the following conditions: – if a letter A is indicated in the table, the goods with those UN numbers may be included in the same package without any special limitation of mass; – if a letter B is indicated in the table, the goods with those UN numbers may be included in the same package up to a total mass of 50 kg of explosive substances. When goods are packed together in accordance with this special provision, account shall be taken of a possible amendment of the classification of packages in accordance with 2.2.1.1. For the description of the goods in the consignment note, see 5.4.1.2.1 (b). UN No. A 0014 A B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B A A A A A A A A A A A A A A A A A A A A B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B B 2006/128. szám Chapter 4.2 Use of portable tanks and UN multiple-element gas containers (MEGCs) NOTE 1: For tank-wagons, demountable tanks, tank-containers and tank-swap bodies, with shells made of metallic materials, and battery-wagons and multiple element gas containers (MEGCs), see Chapter 4.3; for fibre-reinforced plastics tank-containers, see Chapter 4.4; for vacuum-operated waste tanks, see Chapter 4.5. 2: Portable tanks and UN MEGCs marked in accordance with the requirements of Chapter 6.7, but which were approved in a State that is not a COTIF Member State, may nevertheless be used for carriage under RID. 4.2.1 General provisions for the use of portable tanks for the carriage of substances of Classes 1 and 3 to 9 4.2.1.1 This section provides general provisions applicable to the use of portable tanks for the carriage of substances of Classes 1, 3, 4.1, 4.2, 4.3, 5.1, 5.2, 6.1, 6.2, 7, 8 and 9. In addition to these general provisions, portable tanks shall conform to the design, construction, inspection and testing requirements detailed in 6.7.2. Substances shall be carried in portable tanks conforming to the applicable portable tank instruction identified in Column (10) of the Table A of Chapter 3.2 and described in 4.2.5.2.6 (T1 to T23) and the portable tank special provisions assigned to each substance in Column (11) of Table A of Chapter 3.2 and described in 4.2.5.3. 4.2.1.2 During carriage, portable tanks shall be adequately protected against damage to the shell and service equipment resulting from lateral and longitudinal impact and overturning. If the shell and service equipment are so constructed as to withstand impact or overturning it need not be protected in this way. Examples of such protection are given in 6.7.2.17.5. 4.2.1.3 Certain substances are chemically unstable. They are accepted for carriage only when the necessary steps have been taken to prevent their dangerous decomposition, transformation or polymerization during carriage. To this end, care shall in particular be taken to ensure that shells do not contain any substances liable to promote these reactions. 4.2.1.4 The temperature of the outer surface of the shell excluding openings and their closures or of the thermal insulation shall not exceed 70 °C during carriage. When necessary, the shell shall be thermally insulated. 4.2.1.5 Empty portable tanks not cleaned and not gas-free shall comply with the same provisions as portable tanks filled with the previous substance. 4.2.1.6 Substances shall not be carried in the same or in adjoining compartments of shells when they may react dangerously with each other (see definition for "dangerous reaction" in 1.2.1). 4.2.1.7 The design approval certificate, the test report and the certificate showing the results of the initial inspection and test for each portable tank issued by the competent authority or its authorized body shall be retained by the authority or body and the owner. Owners shall be able to provide this documentation upon the request of any competent authority. 4.2.1.8 Unless the name of the substance(s) being carried appears on the metal plate described in 6.7.2.20.2 a copy of the certificate specified in 6.7.2.18.1 shall be made available upon the request of a competent authority or its authorized body and readily provided by the consignor, consignee or agent, as appropriate. 4.2.1.9 Degree of filling 4.2.1.9.1 Prior to filling, the filler shall ensure that the appropriate portable tank is used and that the portable tank is not filled with substances which in contact with the materials of the shell, gaskets, service equipment and any protective linings, are likely to react dangerously with them to form dangerous products or appreciably weaken these materials. The consignor may need to consult the manufacturer of the substance in conjunction with the competent authority for guidance on the compatibility of the substance with the portable tank materials. 4.2.1.9.1.1 Portable tanks shall not be filled above the extent provided in 4.2.1.9.2 to 4.2.1.9.6. The applicability of 4.2.1.9.2, 4.2.1.9.3 or 4.2.1.9.5.1 to individual substances is specified in the applicable portable tank instruction or special provisions in 4.2.5.2.6 or 4.2.5.3 and Column (10) or (11) of Table A of Chapter 3.2. 4.2.1.9.2 The maximum degree of filling (in %) for general use is determined by the formula: Degree of filling ) t - t( + = f r D 2006/128. szám 4.2.1.9.3 The maximum degree of filling (in %) for liquids of Class 6.1 and Class 8, in packing groups I and II, and liquids with an absolute vapour pressure of more than 175 kPa (1.75 bar) at 65 °C, is determined by the formula: Degree of filling ) t - t( + = f r D 4.2.1.9.4 In these formulae, D is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during carriage (tr) (both in °C). For liquids carried under ambient conditions D could be calculated by the formula: d d d  D in which d15 and d50 are the densities of the liquid at 15 °C and 50 °C, respectively. 4.2.1.9.4.1 The maximum mean bulk temperature (tr) shall be taken as 50 °C except that, for journeys under temperate or extreme climatic conditions, the competent authorities concerned may agree to a lower or require a higher temperature, as appropriate. 4.2.1.9.5 The provisions of 4.2.1.9.2 to 4.2.1.9.4.1 do not apply to portable tanks which contain substances maintained at a temperature above 50 °C during carriage (e.g. by means of a heating device). For portable tanks equipped with a heating device, a temperature regulator shall be used to ensure the maximum degree of filling is not more than 95% full at any time during carriage. 4.2.1.9.5.1 The maximum degree of filling (in %) for solids carried above their melting points and for elevated temperature liquids shall be determined by the following formula: Degree of filling d d = f r in which df and dr are the densities of the liquid at the mean temperature of the liquid during filling and the maximum mean bulk temperature during carriage respectively. 4.2.1.9.6 Portable tanks shall not be offered for carriage: (a) With a degree of filling, for liquids having a viscosity less than 2 680 mm2/s at 20 °C or maximum temperature of the substance during carriage in the case of the heated substance, of more than 20% but less than 80% unless the shells of portable tanks are divided, by partitions or surge plates, into sections of not more than 7 500 litres capacity; (b) With residue of substances previously carried adhering to the outside of the shell or service equipment; (c) When leaking or damaged to such an extent that the integrity of the portable tank or its lifting or securing arrangements may be affected; and (d) Unless the service equipment has been examined and found to be in good working order. 4.2.1.9.7 Forklift pockets of portable tanks shall be closed off when the tank is filled. This provision does not apply to portable tanks which according to 6.7.3.13.4 need not be provided with a means of closing off the forklift pockets. 4.2.1.10 Additional provisions applicable to the carriage of Class 3 substances in portable tanks 4.2.1.10.1 All portable tanks intended for the carriage of flammable liquids shall be closed and be fitted with relief devices in accordance with 6.7.2.8 to 6.7.2.15. 4.2.1.10.1.1 For portable tanks intended for use only on land, open venting systems may be used if allowed according to Chapter 4.3. 4.2.1.11 Additional provisions applicable to the carriage of Classes 4.1, 4.2 or 4.3 substances (other than Class 4.1 self-reactive substances) in portable tanks (Reserved) NOTE: For Class 4.1 self-reactive substances, see 4.2.1.13.1. 4.2.1.12 Additional provisions applicable to the carriage of Class 5.1 substances in portable tanks (Reserved) 2006/128. szám 4.2.1.13 Additional provisions applicable to the carriage of Class 5.2 substances and Class 4.1 self-reactive substances in portable tanks 4.2.1.13.1 Each substance shall have been tested and a report submitted to the competent authority of the country of origin for approval. Notification thereof shall be sent to the competent authority of the country of destination. The notification shall contain relevant transport information and the report with test results. The tests undertaken shall include those necessary: (a) To prove the compatibility of all materials normally in contact with the substance during carriage; (b) To provide data for the design of the pressure and emergency relief devices taking into account the design characteristics of the portable tank. Any additional provision necessary for safe carriage of the substance shall be clearly described in the report. 4.2.1.13.2 The following provisions apply to portable tanks intended for the carriage of Type F organic peroxides or Type F self-reactive substances with a Self-Accelerating Decomposition Temperature (SADT) of 55 °C or more. In case of conflict these provisions prevail over those specified in Section 6.7.2. Emergencies to be taken into account are self-accelerating decomposition of the substance and fire-engulfment as described in 4.2.1.13.8. 4.2.1.13.3 The additional provisions for carriage of organic peroxides or self-reactive substances with a SADT less than 55 °C in portable tanks shall be specified by the competent authority of the country of origin. Notification thereof shall be sent to the competent authority of the country of destination. 4.2.1.13.4 The portable tank shall be designed for a test pressure of at least 0.4 MPa (4 bar). 4.2.1.13.5 Portable tanks shall be fitted with temperature sensing devices. 4.2.1.13.6 Portable tanks shall be fitted with pressure-relief devices and emergency-relief devices. Vacuum-relief devices may also be used. Pressure-relief devices shall operate at pressures determined according to both the properties of the substance and the construction characteristics of the portable tank. Fusible elements are not allowed in the shell. 4.2.1.13.7 The pressure-relief devices shall consist of spring-loaded valves fitted to prevent significant build-up within the portable tank of the decomposition products and vapours released at a temperature of 50 °C. The capacity and start-to-discharge pressure of the relief valves shall be based on the results of the tests specified in 4.2.1.13.1. The start-to-discharge pressure shall, however, in no case be such that liquid would escape from the valve(s) if the portable tank were overturned. 4.2.1.13.8 The emergency-relief devices may be of the spring-loaded or frangible types, or a combination of the two, designed to vent all the decomposition products and vapours evolved during a period of not less than one hour of complete fire-engulfment as calculated by the following formula: q = 70961·F·A0,82 where: q = heat absorption [W] A = wetted area [m2 ] F = insulation factor F = 1 for non-insulated shells, or T U F  for isulated shells where: K = heat conductivity of insulation layer[W#m-1#K-1] L = thickness of insulation layer [m] U = K/L = heat transfer coefficient of the insulation [W#m-2 #K-1] T = temperature of the substance at relieving conditions [K] The start-to-discharge pressure of the emergency-relief device(s) shall be higher than that specified in 4.2.1.13.7 and based on the results of the tests referred to in 4.2.1.13.1. The emergency-relief devices shall be dimensioned in such a way that the maximum pressure in the portable tank never exceeds the test pressure of the tank. NOTE: An example of a method to determine the size of emergency-relief devices is given in Appendix 5 of the "Manual of Tests and Criteria". 2006/128. szám 4.2.1.13.9 For insulated portable tanks the capacity and setting of emergency-relief device(s) shall be determined assuming a loss of insulation from 1% of the surface area. 4.2.1.13.10 Vacuum-relief devices and spring-loaded valves shall be provided with flame arresters. Due attention shall be paid to the reduction of the relief capacity caused by the flame arrester. 4.2.1.13.11 Service equipment such as valves and external piping shall be so arranged that no substance remains in them after filling the portable tank. 4.2.1.13.12 Portable tanks may be either insulated or protected by a sun-shield. If the SADT of the substance in the portable tank is 55 °C or less, or the portable tank is constructed of aluminium, the portable tank shall be completely insulated. The outer surface shall be finished in white or bright metal. 4.2.1.13.13 The degree of filling shall not exceed 90% at 15 qC. 4.2.1.13.14 The marking as required in 6.7.2.20.2 shall include the UN number and the technical name with the approved concentration of the substance concerned. 4.2.1.13.15 Organic peroxides and self-reactive substances specifically listed in portable tank instruction T23 in 4.2.5.2.6 may be carried in portable tanks. 4.2.1.14 Additional provisions applicable to the carriage of Class 6.1 substances in portable tanks (Reserved) 4.2.1.15 Additional provisions applicable to the carriage of Class 7 substances in portable tanks 4.2.1.15.1 Portable tanks used for the carriage of radioactive material shall not be used for the carriage of other goods. 4.2.1.15.2 The degree of filling for portable tanks shall not exceed 90% or, alternatively, any other value approved by the competent authority. 4.2.1.16 Additional provisions applicable to the carriage of Class 8 substances in portable tanks 4.2.1.16.1 Pressure-relief devices of portable tanks used for the carriage of Class 8 substances shall be inspected at intervals not exceeding one year. 4.2.1.17 Additional provisions applicable to the carriage of Class 9 substances in portable tanks (Reserved) 4.2.1.18 Additional provisions applicable to the carriage of solid substances carried above their melting point 4.2.1.18.1 Solid substances carried or offered for carriage above their melting point which are not assigned a portable tank instruction in column (10) of the Table A of Chapter 3.2 or when the assigned portable tank instruction does not apply to carriage at temperatures above their melting point may be carried in portable tanks provided that the solid substances are classified in classes 4.1, 4.2, 4.3, 5.1, 6.1, 8 or 9 and have no subsidiary risk other than that of Class 6.1 or Class 8 and are in packing group II or III. 4.2.1.18.2 Unless otherwise indicated in Table A of Chapter 3.2, portable tanks used for the carriage of these solid substances above their melting point shall conform to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II. A portable tank which affords an equivalent or greater level of safety may be selected according to 4.2.5.2.5. The maximum degree of filling (in %) shall be determined according to 4.2.1.9.5 (TP3). 4.2.2 General provisions for the use of portable tanks for the carriage of non-refrigerated liquefied gases 4.2.2.1 This section provides general provisions applicable to the use of portable tanks for the carriage of nonrefrigerated liquefied gases. 4.2.2.2 Portable tanks shall conform to the design, construction, inspection and testing requirements detailed in 6.7.3. Non-refrigerated liquefied gases shall be carried in portable tanks conforming to portable tank instruction T50 as described in 4.2.5.2.6 and any portable tank special provisions assigned to specific nonrefrigerated liquefied gases in Column (11) of Table A of Chapter 3.2 and described in 4.2.5.3. 4.2.2.3 During carriage, portable tanks shall be adequately protected against damage to the shell and service equipment resulting from lateral and longitudinal impact and overturning. If the shell and service equipment are so constructed as to withstand impact or overturning it need not be protected in this way. Examples of such protection are given in 6.7.3.13.5. 2006/128. szám 4.2.2.4 Certain non-refrigerated liquefied gases are chemically unstable. They are accepted for carriage only when the necessary steps have been taken to prevent their dangerous decomposition, transformation or polymerization during carriage. To this end, care shall in particular be taken to ensure that portable tanks do not contain any non-refrigerated liquefied gases liable to promote these reactions. 4.2.2.5 Unless the name of the gas(es) being carried appears on the metal plate described in 6.7.3.16.2, a copy of the certificate specified in 6.7.3.14.1 shall be made available upon a competent authority request and readily provided by the consignor, consignee or agent, as appropriate. 4.2.2.6 Empty portable tanks not cleaned and not gas-free shall comply with the same provisions as portable tanks filled with the previous non-refrigerated liquefied gas. 4.2.2.7 Filling 4.2.2.7.1 Prior to filling the portable tank shall be inspected to ensure that it is authorized for the non-refrigerated liquefied gas to be carried and that the portable tank is not loaded with non-refrigerated liquefied gases which in contact with the materials of the shell, gaskets, service equipment and any protective linings, are likely to react dangerously with them to form dangerous products or appreciably weaken these materials. During filling, the temperature of the non-refrigerated liquefied gas shall fall within the limits of the design temperature range. 4.2.2.7.2 The maximum mass of non-refrigerated liquefied gas per litre of shell capacity (kg/l) shall not exceed the density of the non-refrigerated liquefied gas at 50 °C multiplied by 0.95. Furthermore, the shell shall not be liquid-full at 60 °C. 4.2.2.7.3 Portable tanks shall not be filled above their maximum permissible gross mass and the maximum permissible load mass specified for each gas to be carried. 4.2.2.8 Portable tanks shall not be offered for carriage: (a) In an ullage condition liable to produce an unacceptable hydraulic force due to surge within the shell; (b) When leaking; (c) When damaged to such an extent that the integrity of the tank or its lifting or securing arrangements may be affected; and (d) Unless the service equipment has been examined and found to be in good working order. 4.2.2.9 Forklift pockets of portable tanks shall be closed off when the tank is filled. This provision does not apply to portable tanks which according to 6.7.4.12.4 need not be provided with a means of closing off the forklift pockets. 4.2.3 General provisions for the use of portable tanks for the carriage of refrigerated liquefied gases 4.2.3.1 This section provides general provisions applicable to the use of portable tanks for the carriage of refrigerated liquefied gases. 4.2.3.2 Portable tanks shall conform to the design, construction, inspection and testing requirements detailed in 6.7.4. Refrigerated liquefied gases shall be carried in portable tanks conforming to portable tank instruction T75 as described in 4.2.5.2.6 and the portable tank special provisions assigned to each substance in Column (11) of Table A of Chapter 3.2 and described in 4.2.5.3. 4.2.3.3 During carriage, portable tanks shall be adequately protected against damage to the shell and service equipment resulting from lateral and longitudinal impact and overturning. If the shell and service equipment are so constructed as to withstand impact or overturning it need not be protected in this way. Examples of such protection are provided in 6.7.4.12.5. 4.2.3.4 Unless the name of the gas(es) being carried appears on the metal plate described in 6.7.4.15.2, a copy of the certificate specified in 6.7.4.13.1 shall be made available upon a competent authority request and readily provided by the consignor, consignee or agent, as appropriate. 4.2.3.5 Empty portable tanks not cleaned and not gas-free shall comply with the same provisions as portable tanks filled with the previous substance. 4.2.3.6 Filling 4.2.3.6.1 Prior to filling the portable tank shall be inspected to ensure that it is authorized for the refrigerated liquefied gas to be carried and that the portable tank is not loaded with refrigerated liquefied gases which in contact with the materials of the shell, gaskets, service equipment and any protective linings, are likely to react dangerously with them to form dangerous products or appreciably weaken these materials. During filling, the temperature of the refrigerated liquefied gas shall be within the limits of the design temperature range. 2006/128. szám 4.2.3.6.2 In estimating the initial degree of filling the necessary holding time for the intended journey including any delays which might be encountered shall be taken into consideration. The initial degree of filling of the shell, except as provided for in 4.2.3.6.3 and 4.2.3.6.4, shall be such that if the contents, except helium, were to be raised to a temperature at which the vapour pressure is equal to the maximum allowable working pressure (MAWP) the volume occupied by liquid would not exceed 98%. 4.2.3.6.3 Shells intended for the carriage of helium can be filled up to but not above the inlet of the pressure-relief device. 4.2.3.6.4 A higher initial degree of filling may be allowed, subject to approval by the competent authority, when the intended duration of carriage is considerably shorter than the holding time. 4.2.3.7 Actual holding time 4.2.3.7.1 The actual holding time shall be calculated for each journey in accordance with a procedure recognized by the competent authority, on the basis of the following: (a) The reference holding time for the refrigerated liquefied gas to be carried (see 6.7.4.2.8.1) (as indicated on the plate referred to in 6.7.4.15.1); (b) The actual filling density; (c) The actual filling pressure; (d) The lowest set pressure of the pressure limiting device(s). 4.2.3.7.2 The actual holding time shall be marked either on the portable tank itself or on a metal plate firmly secured to the portable tank, in accordance with 6.7.4.15.2. 4.2.3.8 Portable tanks shall not be offered for carriage: (a) In an ullage condition liable to produce an unacceptable hydraulic force due to surge within the shell; (b) When leaking; (c) When damaged to such an extent that the integrity of the portable tank or its lifting or securing arrangements may be affected; (d) Unless the service equipment has been examined and found to be in good working order; (e) Unless the actual holding time for the refrigerated liquefied gas being carried has been determined in accordance with 4.2.3.7 and the portable tank is marked in accordance with 6.7.4.15.2; and (f) Unless the duration of carriage, after taking into consideration any delays which might be encountered, does not exceed the actual holding time. 4.2.3.9 Forklift pockets of portable tanks shall be closed off when the tank is filled. This provision does not apply to portable tanks which according to 6.7.4.12.4, need not be provided with a means of closing off the forklift pockets. 4.2.4 General provisions for the use of UN multiple-element gas containers (MEGCs) 4.2.4.1 This section provides general requirements applicable to the use of multiple-element gas containers (MEGCs) for the carriage of non-refrigerated gases referred to in 6.7.5. 4.2.4.2 MEGCs shall conform to the design, construction, inspection and testing requirements detailed in 6.7.5. The elements of MEGCs shall be periodically inspected according to the provisions set out in packing instruction P200 of 4.1.4.1 and in 6.2.1.5. 4.2.4.3 During carriage, MEGCs shall be protected against damage to the elements and service equipment resulting from lateral and longitudinal impact and overturning. If the elements and service equipment are so constructed as to withstand impact or overturning, they need not be protected in this way. Examples of such protection are given in 6.7.5.10.4. 4.2.4.4 The periodic testing and inspection requirements for MEGCs are specified in 6.7.5.12. MEGCs or their elements shall not be charged or filled after they become due for periodic inspection but may be carried after the expiry of the time limit. 4.2.4.5 Filling 4.2.4.5.1 Prior to filling, the MEGC shall be inspected to ensure that it is authorized for the gas to be carried and that the applicable provisions of RID have been met. 4.2.4.5.2 Elements of MEGCs shall be filled according to the working pressures, filling ratios and filling provisions specified in packing instruction P200 of 4.1.4.1 for the specific gas being filled into each element. In no case shall an MEGC or group of elements be filled as a unit in excess of the lowest working pressure of any given element. 2006/128. szám 4.2.4.5.3 MEGCs shall not be filled above their maximum permissible gross mass. 4.2.4.5.4 Isolation valves shall be closed after filling and remain closed during carriage. Toxic gases (gases of groups T, TF, TC, TO, TFC and TOC) shall only be carried in MEGCs where each element is equipped with an isolation valve. 4.2.4.5.5 The opening(s) for filling shall be closed by caps or plugs. The leakproofness of the closures and equipment shall be verified by the filler after filling. 4.2.4.5.6 MEGCs shall not be offered for filling: (a) when damaged to such an extent that the integrity of the pressure receptacles or its structural or service equipment may be affected; (b) unless the pressure receptacles and its structural and service equipment has been examined and found to be in good working order; and (c) unless the required certification, retest, and filling markings are legible. 4.2.4.6 Charged MEGCs shall not be offered for carriage; (a) when leaking; (b) when damaged to such an extent that the integrity of the pressure receptacles or its structural or service equipment may be affected; (c) unless the pressure receptacles and its structural and service equipment have been examined and found to be in good working order; and (d) unless the required certification, retest, and filling markings are legible. 4.2.4.7 Empty MEGCs that have not been cleaned and purged shall comply with the same requirements as MEGCs filled with the previous substance. 4.2.5 Portable tank instructions and special provisions 4.2.5.1 General 4.2.5.1.1 This section includes the portable tank instructions and special provisions applicable to dangerous goods authorized to be carried in portable tanks. Each portable tank instruction is identified by an alpha-numeric code (e.g. T1). Column (10) of Table A of Chapter 3.2 indicates the portable tank instruction that shall be used for each substance permitted for carriage in a portable tank. When no portable tank instruction appears in Column (10) for a specific dangerous goods entry then carriage of the substance in portable tanks is not permitted unless a competent authority approval is granted as detailed in 6.7.1.3. Portable tank special provisions are assigned to specific dangerous goods in Column (11) of Table A of Chapter 3.2. Each portable tank special provision is identified by an alpha-numeric code (e.g. TP1). A listing of the portable tank special provisions is provided in 4.2.5.3. 4.2.5.2 Portable tank instructions 4.2.5.2.1 Portable tank instructions apply to dangerous goods of Classes 1 to 9. Portable tank instructions provide specific information relevant to portable tanks provisions applicable to specific substances. These provisions shall be met in addition to the general provisions in this Chapter and the general requirements in Chapter 6.7. 4.2.5.2.2 For substances of Classes 1 and 3 to 9, the portable tank instructions indicate the applicable minimum test pressure, the minimum shell thickness (in reference steel), bottom opening requirements and pressure relief requirements. In portable tank instruction T23, self-reactive substances of Class 4.1 and Class 5.2 organic peroxides permitted to be carried in portable tanks are listed. 4.2.5.2.3 Non-refrigerated liquefied gases are assigned to portable tank instruction T50. T50 provides the maximum allowable working pressures, the requirements for the openings below liquid level, pressure-relief requirements and maximum filling density requirements for non-refrigerated liquefied gases permitted for carriage in portable tanks. 4.2.5.2.4 Refrigerated liquefied gases are assigned to portable tank instruction T75. 4.2.5.2.5 Determination of the appropriate portable tank instructions When a specific portable tank instruction is specified in Column (10) of Table A of Chapter 3.2 for a specific dangerous goods entry additional portable tanks which possess higher minimum test pressures, greater shell thicknesses, more stringent bottom opening and pressure-relief device arrangements may be used. The following guidelines apply to determining the appropriate portable tanks which may be used for carriage of particular substances: 2006/128. szám Portable tank instruction specified Portable tank instructions also permitted T 1 T 2, T 3, T 4, T 5, T 6, T 7, T 8, T 9, T 10, T 11, T 12, T 13, T 14, T 15, T 16, T 17, T 18, T 19, T 20, T 21, T 22 T 2 T 4, T 5, T 7, T 8, T 9, T 10, T 11, T 12, T 13, T 14, T 15, T 16, T 17, T 18, T 19, T 20, T 21, T 22 T 3 T 4, T 5, T 6, T 7, T 8, T 9, T 10, T 11, T 12, T 13, T 14, T 15, T 16, T 17, T 18, T 19, T 20, T 21, T 22 T 4 T 5, T 7, T 8, T 9, T 10, T 11, T 12, T 13, T 14, T 15, T 16, T 17, T 18, T 19, T 20, T 21, T 22 T 5 T 10, T 14, T 19, T 20, T 22 T 6 T 7, T 8, T 9, T 10, T 11, T 12, T 13, T 14, T 15, T 16, T 17, T 18, T 19, T 20, T 21, T 22 T 7 T 8, T 9, T 10, T 11, T 12, T 13, T 14, T 15, T 16, T 17, T 18, T 19, T 20, T 21, T 22 T 8 T 9, T 10, T 13, T 14, T 19, T 20, T 21, T 22 T 9 T 10, T 13, T 14, T 19, T 20, T 21, T 22 T 10 T 14, T 19, T 20, T 22 T 11 T 12, T 13, T 14, T 15, T 16, T 17, T 18, T 19, T 20, T 21, T 22 T 12 T 14, T 16, T 18, T 19, T 20, T 22 T 13 T 14, T 19, T 20, T 21, T 22 T 14 T 19, T 20, T 22 T 15 T 16, T 17, T 18, T 19, T 20, T 21, T 22 T 16 T 18, T 19, T 20, T 22 T 17 T 18, T 19, T 20, T 21, T 22 T 18 T 19, T 20, T 22 T 19 T 20, T 22 T 20 T 22 T 21 T 22 T 22 None T 23 None 2006/128. szám 4.2.5.2.6 Portable tank instructions Portable tank instructions specify the requirements applicable to a portable tank when used for the carriage of specific substances. Portable tank instructions T1 to T22 specify the applicable minimum test pressure, the minimum shell thickness (in mm reference steel), and the pressure-relief and bottom-opening requirements. T 1 – T 22 Portable tank instructions T 1 – T 22 These portable tank instructions apply to liquid and solid substances of Classes 3 to 9. The general provisions of Section 4.2.1 and the requirements of Section 6.7.2 shall be met. Portable tank instruction Minimum test pressure (bar) Minimum shell thickness (in mmreference steel) (see 6.7.2.4) Pressure-relief requirements (see 6.7.2.8)(a) Bottom opening requirements (see 6.7.2.6) T 1 1,5 See 6.7.2.4.2 Normal See 6.7.2.6.2 T 2 1,5 See 6.7.2.4.2 Normal See 6.7.2.6.3 T 3 2,65 See 6.7.2.4.2 Normal See 6.7.2.6.2 T 4 2,65 See 6.7.2.4.2 Normal See 6.7.2.6.3 T 5 2,65 See 6.7.2.4.2 See 6.7.2.8.3 Not allowed T 6 See 6.7.2.4.2 Normal See 6.7.2.6.2 T 7 See 6.7.2.4.2 Normal See 6.7.2.6.3 T 8 See 6.7.2.4.2 Normal Not allowed T 9 6 mm Normal Not allowed T 10 6 mm See 6.7.2.8.3 Not allowed T 11 See 6.7.2.4.2 Normal See 6.7.2.6.3 T 12 See 6.7.2.4.2 See 6.7.2.8.3 See 6.7.2.6.3 T 13 6 mm Normal Not allowed T 14 6 mm See 6.7.2.8.3 Not allowed T 15 See 6.7.2.4.2 Normal See 6.7.2.6.3 T 16 See 6.7.2.4.2 See 6.7.2.8.3 See 6.7.2.6.3 T 17 6 mm Normal See 6.7.2.6.3 T 18 6 mm See 6.7.2.8.3 See 6.7.2.6.3 T 19 6 mm See 6.7.2.8.3 Not allowed T 20 8 mm See 6.7.2.8.3 Not allowed T 21 10 mm Normal Not allowed T 22 10 mm See 6.7.2.8.3 Not allowed (a) When the word "Normal" is indicated, all the requirements of 6.7.2.8 apply except for 6.7.2.8.3. 2006/128. szám T 23 Portable tank instructions T 23 This portable tank instruction applies to self-reactive substances of Class 4.1 and organic peroxides of Class 5.2. The general provisions of Section 4.2.1 and the requirements of Section 6.7.2 shall be met. The additional provisions specific to self-reactive substances of Class 4.1 and organic peroxides of Class 5.2 in 4.2.1.13 shall also be met. UN No. Substance Minimum test pressure (bar) Minimum shell thickness (mmreference steel) Bottom opening requirements Pressurerelief requirements Degree of filling 3109 ORGANIC PEROXIDE, TYPE F, LIQUID See 6.7.2.4.2 See 6.7.2.6.3 See 4.2.1.13.13 tert-Butyl hydroperoxide(a), not more than 72% with water Cumyl hydroperoxide, not more than 90% in diluent type A See 6.7.2.8.2, 4.2.1.13.6, 4.2.1.13.7, 4.2.1.13.8 Di-tert-butyl peroxide, not more than 32% in diluent type A Isopropyl cumyl hydroperoxide, not more than 72% in diluent type A p-Menthyl hydroperoxide, not more than 72% in diluent type A Pinanyl hydroperoxide, not more than 56% in diluent type A 3110 ORGANIC PEROXIDE TYPE F, SOLID Dicumyl peroxide(b) See 6.7.2.4.2 See 6.7.2.6.3 See 6.7.2.8.2, 4.2.1.13.6, 4.2.1.13.7, 4.2.1.13.8 See 4.2.1.13.13 3229 SELF-REACTIVE LIQUID TYPE F See 6.7.2.4.2 See 6.7.2.6.3 See 6.7.2.8.2, 4.2.1.13.6, 4.2.1.13.7, 4.2.1.13.8 See 4.2.1.13.13 3230 SELF-REACTIVE SOLID TYPE F See 6.7.2.4.2 See 6.7.2.6.3 See 6.7.2.8.2, 4.2.1.13.6, 4.2.1.13.7, 4.2.1.13.8 See 4.2.1.13.13 (a) Provided that steps have been taken to achieve the safety equivalence of 65% tert-Butyl hydroperoxide and 35% water. (b) Maximum quantity per portable tank: 2000 kg. 2006/128. szám T 50 Portable tank instructions T 50 This portable tank instruction applies to non-refrigerated liquefied gases. The general provisions of Section 4.2.2 and the requirements of Section 6.7.3 shall be met. UN No. Non-refrigerated liquefied gases Max. allowable working pressure (bar) Small; Bare; Sunshield; Insulated(a) Openings below liquid level Pressurerelief requirements (see 6.7.3.7)(b) Maximum filling density (kg/l) 1005 AMMONIA, ANHYDROUS 29,0 25,7 22,0 19,7 Allowed See 6.7.3.7.3 0,53 1009 BROMOTRIFLUOROMETHANE (REFRIGERANT GAS R 13B1) 38,0 34,0 30,0 27,5 Allowed Normal 1,13 1010 BUTADIENES, STABILIZED 7,5 7,0 7,0 7,0 Allowed Normal 0,55 1010 BUTADIENES AND HYDROCAR- BON MIXTURE, STABILIZED See MAWP definition in 6.7.3.1 Allowed Normal see 4.2.2.7 1011 BUTAN 7,0 7,0 7,0 7,0 Allowed Normal 0,51 1012 BUTYLENE 8,0 7,0 7,0 7,0 Allowed Normal 0,53 1017 CHLORINE 19,0 17,0 15,0 13,5 Not Allowed See 6.7.3.7.3 1,25 1018 CHLORODIFLUOROMETHANE (REFRIGERANT GAS R 22) 26,0 24,0 21,0 19,0 Allowed Normal 1,03 1020 CHLOROPENTAFLUOROETHANE (REFRIGERANT GAS R 115) 23,0 20,0 18,0 16,0 Allowed Normal 1,06 1021 1-CHLORO-1,2,2,2-TETRA- FLUOROETHANE (REFRIGERANT GAS R 124) 10,3 9,8 7,9 7,0 Allowed Normal 1,20 1027 CYCLOPROPANE 18,0 16,0 14,5 13,0 Allowed Normal 0,53 1028 DICHLORODIFLUOROMETHANE (REFRIGERANT GAS R 12) 16,0 15,0 13,0 11,5 Allowed Normal 1,15 1029 DICHLOROFLUOROMETHANE (REFRIGERANT GAS R 21) 7,0 7,0 7,0 7,0 Allowed Normal 1,23 2006/128. szám 1030 1,1-DIFLUOROETHANE (REFRIGERANT GAS R 152A) 16,0 14,0 12,4 11,0 Allowed Normal 0,79 1032 DIMETHYLAMINE, ANHYDROUS 7,0 7,0 7,0 7,0 Allowed Normal 0,59 1033 DIMETHYL ETHER 15,5 13,8 12,0 10,6 Allowed Normal 0,58 1036 ETHYLAMINE 7,0 7,0 7,0 7,0 Allowed Normal 0,61 1037 ETHYL CHLORIDE 7,0 7,0 7,0 7,0 Allowed Normal 0,8 1040 ETHYLENE OXIDE WITH NITRO- GEN up to a total pressure of 1MPa (10 bar) at 50 °C 10,0 Not Allowed See 6.7.3.7.3 0,78 1041 ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 9% but not more than 87% ethylene oxide See MAWP definition in 6.7.3.1 Allowed Normal See 4.2.2.7 1055 ISOBUTYLENE 8,1 7,0 7,0 7,0 Allowed Normal 0,52 1060 METHYLLACETYLENE AND PROPADIENE MIXTURE, STABILIZED 28,0 24,5 22,0 20,0 Allowed Normal 0,43 1061 METHYLAMINE, ANHYDROUS 10,8 9,6 7,8 7,0 Allowed Normal 0,58 1062 METHYL BROMIDE with not more than 2% chloropicrin 7,0 7,0 7,0 7,0 Not Allowed See 6.7.3.7.3 1,51 1063 METHYL CHLORIDE (REFRIGERANT GAS R 40) 14,5 12,7 11,3 10,0 Allowed Normal 0,81 1064 METHYL MERCAPTAN 7,0 7,0 7,0 7,0 Not Allowed See 6.7.3.7.3 0,78 1067 DINITROGEN TETROXIDE 7,0 7,0 7,0 7,0 Not Allowed See 6.7.3.7.3 1,30 1075 PETROLEUM GASES, LIQUEFIED See MAWP definition in 6.7.3.1 Allowed Normal See 4.2.2.7 1077 PROPYLENE 28,0 24,5 22,0 20,0 Allowed Normal 0,43 2006/128. szám 1078 REFRIGERANT GAS, N.O.S. See MAWP definition in 6.7.3.1 Allowed Normal See 4.2.2.7 1079 SULPHUR DIOXIDE 11,6 10,3 8,5 7,6 Not Allowed See 6.7.3.7.3 1,23 1082 TRIFLUOROCHLOROETHYLENE, STABILIZED (REFRIGERANT GAS R 1113) 17,0 15,0 13,1 11,6 Not Allowed See 6.7.3.7.3 1,13 1083 TRIMETHYLAMINE, ANHYDROUS 7,0 7,0 7,0 7,0 Allowed Normal 0,56 1085 VINYL BROMIDE, STABILIZED 7,0 7,0 7,0 7,0 Allowed Normal 1,37 1086 VINYL CHLORIDE, STABILIZED 10,6 9,3 8,0 7,0 Allowed Normal 0,81 1087 VINYL METHYL ETHER, STABILIZED 7,0 7,0 7,0 7,0 Allowed Normal 0,67 1581 CHLOROPICRIN AND METHYL BROMIDE MIXTURE with more than 2% chloropicrin 7,0 7,0 7,0 7,0 Not Allowed See 6.7.3.7.3 1,51 1582 CHLOROPICRIN AND METHYL CHLORIDE MIXTURE 19,2 16,9 15,1 13,1 Not Allowed See 6.7.3.7.3 0,81 1858 HEXAFLUOROPROPYLENE (REFRIGERANT GAS R 1216) 19,2 16,9 15,1 13,1 Allowed Normal 1,11 1912 METHYL CHLORIDE AND METHYLENE CHLORIDE MIXTURE 15,2 13,0 11,6 10,1 Allowed Normal 0,81 1958 1,2-DICHLORO-1,1,2,2- TETRAFLUOROETHANE (REFRIGERANT GAS R 114) 7,0 7,0 7,0 7,0 Allowed Normal 1,30 1965 HYDROCARBON GAS, MIXTURE LIQUEFIED, N.O.S. See MAWP definition in 6.7.3.1 Allowed Normal See 4.2.2.7 1969 ISOBUTANE 8,5 7,5 7,0 7,0 Allowed Normal 0,49 1973 CHLORODIFLUOROMETHANE AND CHLOROPENTAFLUORO- ETHANE MIXTURE with fixed boiling point, with approximately 49% chlorodifluoromethane (REFRIGERANT GAS R 502) 28,3 25,3 22,8 20,3 Allowed Normal 1,05 2006/128. szám 1974 CHLORODIFLUORO- BROMOMETHANE (REFRIGERANT GAS R 12B1) 7,4 7,0 7,0 7,0 Allowed Normal 1,61 1976 OCTAFLUOROCYCLOBUTANE (REFRIGERANT GAS RC 318) 8,8 7,8 7,0 7,0 Allowed Normal 1,34 1978 PROPANE 22,5 20,4 18,0 16,5 Allowed Normal 0,42 1983 1-CHLORO-2,2,2- TRIFLUOROETHANE (REFRIGERANT GAS R 133A) 7,0 7,0 7,0 7,0 Allowed Normal 1,18 2035 1,1,1-TRIFLUOROETHANE (REFRIGERANT GAS R 143A) 31,0 27,5 24,2 21,8 Allowed Normal 0,76 2424 OCTAFLUOROPROPANE (REFRIGERANT GAS R 218) 23,1 20,8 18,6 16,6 Allowed Normal 1,07 2517 1-CHLORO-1,1- DIFLUOROETHANE (REFRIGERANT GAS R 142B) 8,9 7,8 7,0 7,0 Allowed Normal 0,99 2602 DICHLORODIFLUOROMETHANE AND 1,1-DIFLUOROETHANE AZEOTROPIC MIXTURE with approximately 74% dichlorodifluoromethane (REFRIGERANT GAS R 500) 20,0 18,0 16,0 14,5 Allowed Normal 1,01 3057 TRIFLUOROACETYL CHLORIDE 14,6 12,9 11,3 9,9 Not Allowed 6.7.3.7.3 1,17 3070 ETHYLENE OXIDE AND DICHLORODIFLUOROMETHANE MIXTURE with not more than 12.5% ethylene oxide 14,0 12,0 11,0 9,0 Allowed 6.7.3.7.3 1,09 3153 PERFLUORO (METHYL VINYL ETHER) 14,3 13,4 11,2 10,2 Allowed Normal 1,14 3159 1,1,1,2-TETRAFLUOROETHANE (REFRIGERANT GAS R 134A) 17,7 15,7 13,8 12,1 Allowed Normal 1,04 3161 LIQUEFIED GAS, FLAMMABLE, N.O.S. See MAWP definition in 6.7.3.1 Allowed Normal See 4.2.2.7 3163 LIQUEFIED GAS, N.O.S. See MAWP definition in 6.7.3.1 Allowed Normal See 4.2.2.7 3220 PENTAFLUOROETHANE (REFRIGERANT GAS R 125) 34,4 30,8 27,5 24,5 Allowed Normal 0,95 2006/128. szám 3252 DIFLUOROMETHANE (REFRIGERANT GAS R 32) 43,0 39,0 34,4 30,5 Allowed Normal 0,78 3296 HEPTAFLUOROPROPANE (REFRIGERANT GAS R 227) 16,0 14,0 12,5 11,0 Allowed Normal 1,20 3297 ETHYLENE OXIDE AND CHLOROTETRAFLUOROETHANE MIXTURE, with not more than 8.8% ethylene oxide 8,1 7,0 7,0 7,0 Allowed Normal 1,16 3298 ETHYLENE OXIDE AND PENTA- FLUOROETHANE MIXTURE, with not more than 7.9% ethylene oxide 25,9 23,4 20,9 18,6 Allowed Normal 1,02 3299 ETHYLENE OXIDE AND TETRA- FLUOROETHANE MIXTURE, with not more than 5.6% ethylene oxide 16,7 14,7 12,9 11,2 Allowed Normal 1,03 3318 AMMONIA SOLUTION, relative density less than 0.880 at 15 °C in water, with more than 50% ammonia See MAWP definition in 6.7.3.1 Allowed See 6.7.3.7.3 See 4.2.2.7 3337 REFRIGERANT GAS R 404A 31,6 28,3 25,3 22,5 Allowed Normal 0,84 3338 REFRIGERANT GAS R 407A 31,3 28,1 25,1 22,4 Allowed Normal 0,95 3339 REFRIGERANT GAS R 407B 33,0 29,6 26,5 23,6 Allowed Normal 0,95 3340 REFRIGERANT GAS R 407C 29,9 26,8 23,9 21,3 Allowed Normal 0,95 (a) "Small" means tanks having a shell with a diameter of 1.5 m or less; "Bare" means tanks having a shell with a diameter of more than 1.5 m without insulation or sun shield (see 6.7.3.2.12); "Sunshield" means tanks having a shell with a diameter of more than 1.5 m with sun shield (see 6.7.3.2.12); "Insulated" means tanks having a shell with a diameter of more than 1.5 m with insulation (see 6.7.3.2.12); (see definition of "Design reference temperature" in 6.7.3.1). (b) The word "Normal" in the pressure relief requirements column indicates that a frangible disc as specified in 6.7.3.7.3 is not required. T 75 Portable tank instruction T 75 This portable tank instruction applies to refrigerated liquefied gases. The general provisions of Section 4.2.3 and the requirements of Section 6.7.4 shall be met. 2006/128. szám 4.2.5.3 Portable tank special provisions Portable tank special provisions are assigned to certain substances to indicate provisions which are in addition to or in lieu of those provided by the portable tank instructions or the requirements in Chapter 6.7. Portable tank special provisions are identified by an alpha numeric code beginning with the letters "TP" (tank provision) and are assigned to specific substances in Column (11) of Table A of Chapter 3.2. The following is a list of the portable tank special provisions: TP 1 The degree of filling prescribed in 4.2.1.9.2 shall not be exceeded. ¸¸ ¹ · ¨¨ © §  D  f r t t filling of Degree TP 2 The degree of filling prescribed in 4.2.1.9.3 shall not be exceeded. ¸¸ ¹ · ¨¨ © §  D  f r t t filling of Degree TP 3 The maximum degree of filling (in %) for solids carried above their melting point and for elevated temperature liquids shall be determined in accordance with 4.2.1.9.5. TP 4 The degree of filling shall not exceed 90% or, alternatively, any other value approved by the competent authority (see 4.2.1.15.2). TP 5 The degree of filling prescribed in 4.2.3.6 shall be met. TP 6 To prevent the tank bursting in any event, including fire engulfment, it shall be provided with pressure-relief devices which are adequate in relation to the capacity of the tank and to the nature of the substance carried. The device shall also be compatible with the substance. TP 7 Air shall be eliminated from the vapour space by nitrogen or other means. TP 8 The test pressure may be reduced to 1.5 bar when the flash point of the substances carried is greater than 0 °C. TP 9 A substance under this description shall only be carried in a portable tank under an approval granted by the competent authority. TP 10 A lead lining, not less than 5 mm thick, which shall be tested annually, or another suitable lining material approved by the competent authority is required. TP 11 (Reserved) TP 12 This substance is highly corrosive to steel. TP 13 (Reserved) TP 14 (Reserved) TP 15 (Reserved) TP 16 The tank shall be fitted with a special device to prevent under-pressure and excess pressure during normal carriage conditions. This device shall be approved by the competent authority. Pressure-relief requirements are as indicated in 6.7.2.8.3 to prevent crystallization of the product in the pressure-relief valve. TP 17 Only inorganic non-combustible materials shall be used for thermal insulation of the tank. TP 18 Temperature shall be maintained between 18 °C and 40 °C. Portable tanks containing solidified methacrylic acid shall not be reheated during carriage. TP 19 The calculated shell thickness shall be increased by 3 mm. Shell thickness shall be verified ultrasonically at intervals midway between periodic hydraulic tests. TP 20 This substance shall only be carried in insulated tanks under a nitrogen blanket. TP 21 The shell thickness shall be not less than 8 mm. Tanks shall be hydraulically tested and internally inspected at intervals not exceeding 2.5 years. TP 22 Lubricant for joints or other devices shall be oxygen compatible. 2006/128. szám TP 23 Carriage permitted under special conditions prescribed by the competent authorities. TP 24 The portable tank may be fitted with a device located under maximum filling conditions in the vapour space of the shell to prevent the build up of excess pressure due to the slow decomposition of the substance carried. This device shall also prevent an unacceptable amount of leakage of liquid in the case of overturning or entry of foreign matter into the tank. This device shall be approved by the competent authority or its authorized body. TP 25 (Reserved) TP 26 When carried under heated conditions, the heating device shall be fitted outside the shell. For UN 3176 this requirement only applies when the substance reacts dangerously with water. TP 27 A portable tank having a minimum test pressure of 4 bar may be used if it is shown that a test pressure of 4 bar or less is acceptable according to the test pressure definition in 6.7.2.1. TP 28 A portable tank having a minimum test pressure of 2.65 bar may be used if it is shown that a test pressure of 2.65 bar or less is acceptable according to the test pressure definition in 6.7.2.1. TP 29 A portable tank having a minimum test pressure of 1.5 bar may be used if it is shown that a test pressure of 1.5 bar or less is acceptable according to the test pressure definition in 6.7.2.1. TP 30 This substance shall be carried in insulated tanks. TP 31 This substance may only be carried in tanks in the solid state. TP 32 For UN Nos. 0331, 0332 and 3375, portable tanks may be used subject to the following conditions: (a) To avoid unnecessary confinement, each portable tank constructed of metal shall be fitted with a pressure-relief device that may be of the reclosing spring-loaded type, a frangible disc or a fusible element. The set to discharge or burst pressure, as applicable, shall not be greater than 2.65 bar for portable tanks with minimum test pressures greater than 4 bar. (b) The suitability for carriage in tanks shall be demonstrated. One method to evaluate this suitability is test 8 (d) in Test Series 8 (see Manual of Tests and Criteria, Part 1, Subsection 18.7). (c) Substances shall not be allowed to remain in the portable tank for any period that could result in caking. Appropriate measures shall be taken to avoid accumulation and packing of substances in the tank (e.g. cleaning, etc.). TP 33 The portable tank instruction assigned for this substance applies to granular and powdered solids and to solids which are filled and discharged at temperatures above their melting point which are cooled and carried as a solid mass. For solids which are carried above their melting point, see 4.2.1.18. TP 34 Portable tanks need not be subjected to the impact test in 6.7.4.14.1 if the portable tank is marked "NOT FOR RAIL TRANSPORT" on the plate specified in 6.7.4.15.1 and also in letters of at least 10 cm high on both sides of the outer jacket. 2006/128. szám Chapter 4.3 Use of tank-wagons, demountable tanks, tank-containers and tank swap bodies with shells made of metallic materials, and battery-wagons and multiple-element gas containers (MEGCs) NOTE: For portable tanks and UN multiple-element gas containers (MEGCs) see Chapter 4.2; for fibrereinforced plastics tank-containers, see Chapter 4.4; for vacuum-operated waste tanks, see Chapter 4.5. 4.3.1 Scope 4.3.1.1 Provisions which take up the whole width of the page apply both to tank-wagons, demountable tanks and battery-wagons, and to tank-containers, tank swap bodies and MEGCs. Provisions contained in a single column apply only to: – tank-wagons, demountable tanks and battery-wagons (left-hand column); – tank-containers, tank swap bodies and MEGCs (right-hand column). 4.3.1.2 These provisions apply to tank-wagons, demountable tanks and batterywagons tank-containers, tank swap bodies and MEGCs used for the carriage of gaseous, liquid, powdery or granular substances. 4.3.1.3 Section 4.3.2 lists the provisions applicable to tank-wagons, demountable tanks, tank-containers and tank swap bodies, intended for the carriage of substances of all classes, and to battery-wagons and MEGCs intended for the carriage of gases of Class 2. Sections 4.3.3 and 4.3.4 contain special provisions adding to or amending the provisions of Section 4.3.2. 4.3.1.4 For requirements concerning the construction, equipment, type approval, tests and marking, see Chapter 6.8. 4.3.1.5 For transitional measures concerning the application of this Chapter, see: 1.6.3. 1.6.4. 4.3.2 Provisions applicable to all classes 4.3.2.1 Use 4.3.2.1.1 A substance subject to RID may be carried in tank-wagons, demountable tanks, battery-wagons, tankcontainers, tank swap bodies and MEGCs only when provision is made for a tank code according to 4.3.3.1.1 and 4.3.4.1.1 in Column (12) of Table A in Chapter 3.2. 4.3.2.1.2 The required type of tank, battery-wagon and MEGC is given in code form in Column (12) of Table A in Chapter 3.2. The identification codes appearing there are made up of letters or numbers in a given order. The explanations for reading the four parts of the code are given in 4.3.3.1.1 (when the substance to be carried belongs to Class 2) and in 4.3.4.1.1 (when the substance to be carried belongs to Classes 3 to 9)1. 4.3.2.1.3 The required type according to 4.3.2.1.2 corresponds to the least stringent construction requirements which are acceptable for the dangerous substance in question unless otherwise prescribed in this Chapter or in Chapter 6.8. It is possible to use tanks corresponding to codes prescribing a higher minimum calculation pressure, or more stringent requirements for filling or discharge openings or for safety valves/devices (see 4.3.3.1.1 for Class 2 and 4.3.4.1.1 for Classes 3 to 9). 4.3.2.1.4 For certain substances, tanks, battery-wagons or MEGCs are subject to additional provisions which are included as special provisions in Column (13) of Table A in Chapter 3.2. 4.3.2.1.5 Tanks, battery-wagons and MEGCs shall not be loaded with any dangerous substances other than those for the carriage of which they have been approved according to 6.8.2.3.1 and which, in contact with the materials of the shell, gaskets, equipment and protective linings, are not liable to react dangerously with them (see "dangerous reaction" in 1.2.1), to form dangerous products or appreciably to weaken these materials2. An exception is made for tanks intended for the carriage of substances of classes 5.2 or 7 (see 4.3.4.1.3). It may be necessary to consult the manufacturer of the substance and the competent authority for guidance on the compatibility of the substance with the materials of the tank, battery-vehicle or MEGC. 2006/128. szám 4.3.2.1.6 Foodstuffs shall not be carried in tanks used for dangerous substances unless the necessary steps have been taken to prevent any harm to public health. 4.3.2.2 Degree of filling 4.3.2.2.1 The following degrees of filling shall not be exceeded in tanks intended for the carriage of liquids at ambient temperatures: (a) for flammable substances without additional risks (e.g. toxicity or corrosivity), in tanks with a venting system or with safety valves (even where preceded by a bursting disc): Degree of filling = ) t - (50 F α + % of capacity (b) for toxic or corrosive substances (whether flammable or not) in tanks with a venting system or with safety valves (even where preceded by a bursting disc): Degree of filling = ) t - (50 F α + % of capacity (c) for flammable substances and for slightly toxic or corrosive substances (whether flammable or not) in hermetically closed tanks without a safety device: Degree of filling = ) t - (50 F α + % of capacity (d) for highly toxic, toxic, highly corrosive or corrosive substances (whether flammable or not) in hermetically closed tanks without a safety device: Degree of filling = ) t - (50 F α + % of capacity 4.3.2.2.2 In these formulae, α is the mean coefficient of cubical expansion of the liquid between 15 °C and 50 °C, i.e. for a maximum variation in temperature of 35 °C. α is calculated by the formula: α = d d 35 x d − where d15 and d50 are the relative densities of the liquid at 15 °C and 50 °C respectively and tF is the mean temperature of the liquid during filling. 4.3.2.2.3 The provisions of 4.3.2.2.1 (a) to (d) above shall not apply to tanks whose contents are, by means of a heating device, maintained at a temperature above 50 °C during carriage. In this case the degree of filling at the outset shall be such, and the temperature so regulated, that the tank is not full to more than 95% of its capacity and that the filling temperature is not exceeded, at any time during carriage. 4.3.2.2.4 (Reserved) Where shells intended for the carriage of liquids3 are not divided by partitions or surge plates into sections of not more than 7 500 litres capacity, they shall be filled to not less than 80% or not more than 20% of their capacity. Under this provision, substances whose kinematic viscosity at 20 °C is below 2 680 mm2/s shall be deemed to be liquids. 2006/128. szám 4.3.2.3 Operation 4.3.2.3.1 The thickness of the walls of the shell shall not, throughout its use, fall below the minimum figure prescribed in: 6.8.2.1.17 and 6.8.2.1.18 6.8.2.1.17 to 6.8.2.1.20 4.3.2.3.2 (Reserved) During carriage tank-containers/MEGCs shall be loaded on the wagon in such a way as to be adequately protected by the fittings of the wagon or of the tank-container/MEGC itself against lateral and longitudinal impact and against overturning4. If the tank-containers/MEGCs, including the service equipment, are so constructed as to withstand impact or overturning they need not be protected in this way. 4.3.2.3.3 During filling and discharge of tanks, battery-wagons and MEGCs, appropriate measures shall be taken to prevent the release of dangerous quantities of gases and vapours. Tanks, battery-wagons and MEGCs shall be closed so that the contents cannot spill out uncontrolled. The openings of bottomdischarge tanks shall be closed by means of screw-threaded plugs, blank flanges or other equally effective devices. The leakproofness of the closures of the tanks, and of the battery-wagons and MEGCs shall be checked by the filler after the tank is filled. This applies in particular to the upper part of the dip tube. 4.3.2.3.4 Where several closure systems are fitted in series, that nearest to the substance being carried shall be closed first. 4.3.2.3.5 No dangerous residue of the filling substance shall adhere to the outside of the tank during carriage. 4.3.2.3.6 Substances which may react dangerously with each other shall not be carried in adjoining compartments of tanks. Substances which may react dangerously with each other may be carried in adjoining compartments of tanks, when these compartments are separated by a partition with a wall thickness equal to or greater than that of the tank itself. They may also be carried separated by an empty space or an empty compartment between loaded compartments. 4.3.2.4 Empty tanks, battery-wagons and MEGCs, uncleaned NOTE: For empty tanks, battery-wagons and MEGCs, uncleaned, special provisions TU1, TU2, TU4, TU16 and TU35 of 4.3.5 may apply. 4.3.2.4.1 No dangerous residue of the filling substance shall adhere to the outside of the tank during carriage. 4.3.2.4.2 To be accepted for carriage, empty tanks, battery-wagons and MEGCs, uncleaned, shall be closed in the same manner and be leakproof to the same degree as if they were full. 4.3.2.4.3 Where empty tanks, battery-wagons and MEGCs, uncleaned, are not closed in the same manner and are not leakproof to the same degree as if they were full and where the provisions of RID cannot be complied with, they shall be carried, with due regard to adequate safety, to the nearest suitable place where cleaning or repair can be carried out. Carriage is adequately safe if suitable measures have been taken to ensure equivalent safety commensurate with the provisions of RID and to prevent the uncontrolled release of the dangerous goods. 4.3.2.4.4 Empty tank-wagons, demountable tanks, battery-wagons, tank-containers, tank swap bodies and MEGCs, uncleaned, may also be carried after the expiry of the periods established in 6.8.2.4.2 and 6.8.2.4.3 for undergoing the inspection. Examples of protection of shells: – protection against lateral impact may, for example, consist of longitudinal bars protecting the shell on both sides at the level of the median line; – protection against overturning may, for example, consist of reinforcing rings or bars fixed transversally in relation to the frame; – protection against rear impact, may, for example, consist of a bumper or frame. 2006/128. szám 4.3.3 Special provisions applicable to Class 2 4.3.3.1 Coding and hierarchy of tanks 4.3.3.1.1 Coding of tanks, battery-wagons and MEGCs The four parts of the codes (tank codes) given in Column (12) of Table A in Chapter 3.2 have the following meanings: Part Description Tank Code Types of tank, batterywagons or MEGC C = tank, battery-wagon or MEGC for compressed gases; P = tank, battery-wagon or MEGC for liquefied gases or dissolved gases; R = tank for refrigerated liquefied gases. Calculation pressure x = value of the minimum relevant test pressure according to the table in 4.3.3.2.5; or 22 = minimum calculation pressure in bar. Openings (see 6.8.2.2 and 6.8.3.2) B = tank with bottom filling or discharge openings with 3 closures; or battery-wagon or MEGC with openings below the surface of the liquid or for compressed gases; C = tank with top filling or discharge openings with 3 closures with only cleaning openings below the surface of the liquid; D = tank with top filling or discharge openings with 3 closures; or battery-wagon or MEGC with no openings below the surface of the liquid. Safety valves/devices N = tank, battery-wagon or MEGC with safety valve according to 6.8.3.2.9 or 6.8.3.2.10 which is not hermetically closed; H = hermetically closed tank, battery-wagon or MEGC (see 1.2.1); NOTE: 1 The special provision TU17 indicated in Column (13) of Table A in Chapter 3.2 for certain gases means that the gas may only be carried in a battery-wagon or MEGC, the elements of which are composed of receptacles. 2 The pressures indicated on the tank itself or on the panel shall be not less than the value of "X" or the minimum calculation pressure. 4.3.3.1.2 Hierarchy of tanks Tank code Other tank code(s) permitted for the substances under this code C*BN C#BN, C#CN, C#DN, C#BH, C#CH, C#DH C*BH C#BH, C#CH, C#DH C*CN C#CN, C#DN, C#CH, C#DH C*CH C#CH, C#DH C*DN C#DN, C#DH C*DH C#DH P*BN P#BN, P#CN, P#DN, P#BH, P#CH, P#DH P*BH P#BH, P#CH, P#DH P*CN P#CN, P#DN, P#CH, P#DH P*CH P#CH, P#DH P*DN P#DN, P#DH P*DH P#DH R*BN R#BN, R#CN, R#DN 2006/128. szám R*CN R#CN, R#DN R*DN R#DN The figure represented by "#" shall be equal to or greater than the figure represented by "*". NOTE: This hierarchy does not take any special provisions into account (see 4.3.5 and 6.8.4) for each entry. 4.3.3.2 Filling conditions and test pressures 4.3.3.2.1 The test pressure for tanks intended for the carriage of compressed gases shall be at least 1.5 times the working pressure as defined in 1.2.1 for pressure receptacles. 4.3.3.2.2 The test pressure for tanks intended for the carriage of: – high pressure liquefied gases; and – dissolved gases shall be such that, when the shell is filled to the maximum filling ratio, the pressure reached in the shell by the substance at 55 °C for tanks with thermal insulation or 65 °C for tanks without thermal insulation does not exceed the test pressure. 4.3.3.2.3 The test pressure for tanks intended for the carriage of low pressure liquefied gases will be: (a) If the tank is equipped with thermal insulation, at least equal to the vapour pressure, reduced by 0.1 MPa (1 bar) of the liquid at 60 °C, but not less than 1 MPa (10 bar); (b) If the tank is not equipped with thermal insulation, at least equal to the vapour pressure, reduced by 0.1 MPa (1 bar), of the liquid at 65 °C, but not less than 1 MPa (10 bar). The maximum permissible mass of contents per litre of capacity is calculated as follows: Maximum permissible mass of contents per litre of capacity = 0.95 × density of the liquid phase at 50 °C (in kg/l) Moreover the vapour phase shall not disappear below 60 °C. If the shells are not more than 1.5 m in diameter, the values of the test pressure and maximum filling ratio conforming to packing instruction P200 in 4.1.4.1 shall be applicable. 4.3.3.2.4 The test pressure for tanks intended for the carriage of refrigerated liquefied gases shall be not less than 1.3 times the maximum allowable working pressure and indicated on the tank but not less than 300 kPa (3 bar) (gauge pressure); for tanks with vacuum insulation the test pressure shall be not less than 1.3 times the maximum allowable working pressure increased by 100 kPa (1 bar). 4.3.3.2.5 Table of gases and gas mixtures which may be carried in tank-wagons, battery-wagons, demountable tanks, tank-containers or MEGCs indicating the minimum test pressure for tanks and as far as applicable the filling ratio In the case of gases and gas mixtures classified under n.o.s. entries, the values of the test pressure and the filling ratio shall be prescribed by the expert approved by the competent authority. When tanks for compressed or high pressure liquefied gases have been subjected to a test pressure lower than shown in the table, and the tanks are fitted with thermal insulation, a lower maximum load may be prescribed by the expert approved by the competent authority, provided that the pressure reached in the tank by the substance at 55 °C does not exceed the test pressure stamped on the tank. 2006/128. szám Minimum test pressure for tanks With thermal insulation Without thermal insulation Maximum permissible mass of contents per litre of capacity UN No. Name Classification code MPa bar MPa bar kg ACETYLENE, DISSOLVED 4 F only in battery-wagons and MEGCs composed of receptacles AIR, COMPRESSED 1 A see 4.3.3.2.1 AIR, REFRIGERATED LIQUID 3 O see 4.3.3.2.4 AMMONIA, ANHYDROUS 2 TC 2.6 2.9 0.53 ARGON, COMPRESSED 1 A see 4.3.3.2.1 BORON TRIFLUORIDE 2 TC 22.5 22.5 0.715 0.86 BROMOTRIFLUORO- METHANE (REFRIGER- ANT GAS R13B1) 2 A 4.2 1.50 1.13 1.44 1.60 BUTADIENES, STABILIZED (1,2-butadiene) or BUTADIENES, STABILIZED (1,3-butadiene) or BUTADIENES AND HYDROCARBON MIXTURE, STABILIZED 2 F 0.55 0.59 0.50 BUTANE 2 F 0.51 1-BUTYLENE or TRANS-2-BUTYLENE or CIS-2-BUTYLENE or BUTYLENES MIXTURE 2 F 0.53 0.54 0.55 0.50 CARBON DIOXIDE 2 A 22.5 0.73 0.78 0.66 0.75 CARBON DIOXIDE AND OXYGEN MIXTURES COMPRESSED 1 O see 4.3.3.2.1 CARBON DIOXIDE AND NITROUS OXIDE MIXTURE 2 A see 4.3.3.2.2 or 4.3.3.2.3 CARBON MONOXIDE, COMPRESSED 1 TF see 4.3.3.2.1 CHLORINE 2 TC 1.7 1.9 1.25 CHLORODIFLUORO- METHANE (REFRIGER- ANT GAS R22) 2 A 2.4 2.6 1.03 CHLOROPENTAFLUORO- ETHANE (REFRIGERANT GAS R115) 2 A 2.3 1.08 1-CHLORO-1,2,2,2- TETRAFLUOROETHANE (REFRIGERANT GAS R124) 2 A 1.1 1.2 2006/128. szám Minimum test pressure for tanks With thermal insulation Without thermal insulation Maximum permissible mass of contents per litre of capacity UN No. Name Classification code MPa bar MPa bar kg CHLOROTRIFLUORO- METHANE (REFRIGER- ANT GAS R13) 2 A 22.5 0.96 1.12 0.83 0.90 1.04 1.10 COAL GAS, COMPRESSED 1 TF see 4.3.3.2.1 CYANOGEN 2 TF 0.70 CYCLOPROPANE 2 F 1.6 1.8 0.53 DICHLORODIFLUORO- METHANE (REFRIGER- ANT GAS R12) 2 A 1.5 1.6 1.15 DICHLOROFLUORO- METHANE (REFRIGER- ANT GAS R21) 2 A 1.23 1,1-DIFLUOROETHANE (REFRIGERANT GAS R152A) 2 F 1.4 1.6 0.79 DIMETHYLAMINE, ANHYDROUS 2 F 0.59 DIMETHYL ETHER 2 F 1.4 1.6 0.58 ETHANE 2 F 9.5 0.32 0.25 0.29 0.39 ETHYLAMINE 2 F 0.61 ETHYL CHLORIDE 2 F 0.8 ETHYLENE, REFRIGERATED LIQUID 3 F see 4.3.3.2.4 ETHYL METHYL ETHER 2 F 0.64 ETHYLENE OXIDE WITH NITROGEN up to a total pressure of 1 MPa (10 bar) at 50 °C 2 TF 1.5 1.5 0.78 ETHYLENE OXIDE AND CARBON DIOXIDE MIX- TURE, with more than 9% but not more than 87% ethylene oxide 2 F 2.4 2.6 0.73 HELIUM, COMPRESSED 1 A see 4.3.3.2.1 HYDROGEN BROMIDE, ANHYDROUS 2 TC 5.5 1.54 HYDROGEN, COMPRESSED 1 F see 4.3.3.2.1 HYDROGEN CHLORIDE, ANHYDROUS 2 TC 0.69 0.30 0.56 0.67 0.74 HYDROGEN SULPHIDE 2 TF 4.5 0.67 2006/128. szám Minimum test pressure for tanks With thermal insulation Without thermal insulation Maximum permissible mass of contents per litre of capacity UN No. Name Classification code MPa bar MPa bar kg ISOBUTYLENE 2 F 0.52 KRYPTON, COMPRESSED 1 A see 4.3.3.2.1 LIQUEFIED GASES, non flammable, charged with nitrogen, carbon dioxide or air 2 A 1.5 x filling pressure see 4.3.3.2.2 or 4.3.3.2.3 see 4.3.3.2.2 or 4.3.3.2.3 METHYLACETYLENE AND PROPADIENE MIX- TURE, STABILIZED: Mixture P1 Mixture P2 Propadiene with 1% to 4% methylacetylene 2 F 2.5 2.2 2.2 2.8 2.3 2.2 0.49 0.47 0.50 METHYLAMINE, ANHY- DROUS 2 F 1.1 0.58 METHYL BROMIDE with not more than 2% chloropicrin 2 T 1.51 METHYL CHLORIDE (RE- FRIGERANT GAS R40) 2 F 1.3 1.5 0.81 METHYL MERCAPTAN 2 TF 0.78 NEON, COMPRESSED 1 A see 4.3.3.2.1 NITROGEN, COMPRESSED 1 A see 4.3.3.2.1 DINITROGEN TETROXIDE (NITROGEN DIOXIDE) 2 TOC only in battery-wagons and MEGCs composed of receptacles NITROUS OXIDE 2 O 22.5 22.52 0.78 0.68 0.74 0.75 OIL GAS, COMPRESSED 1 TF see 4.3.3.2.1 OXYGEN, COMPRESSED 1 O see 4.3.3.2.1 OXYGEN, REFRIGER- ATED LIQUID 3 O see 4.3.3.2.4 PHOSGENE 2 TC only in battery-wagons and MEGCs composed of receptacles PROPYLENE 2 F 2.5 2.7 0.43 2006/128. szám Minimum test pressure for tanks With thermal insulation Without thermal insulation Maximum permissible mass of contents per litre of capacity UN No. Name Classification code MPa bar MPa bar kg 1.5 2.4 1.1 1.6 2.7 1.23 1.15 1.03 REFRIGERANT GASES, N.O.S. such as: Mixture F1 Mixture F2 Mixture F3 Other mixtures 2 A see 4.3.3.2.2 or 4.3.3.2.3 SULPHUR DIOXIDE 2 TC 1.2 1.23 SULPHUR HEXAFLUORIDE 2 A 1.34 1.04 1.33 1.37 TRIFLUOROCHLORO- ETHYLENE, STABILIZED 2 TF 1.5 1.7 1.13 TRIMETHYLAMINE, ANHYDROUS 2 F 0.56 VINYL BROMIDE, STABILIZED 2 F 1.37 VINYL CHLORIDE, STABILIZED 2 F 1.1 0.81 VINYL METHYL ETHER, STABILIZED 2 F 0.67 CHLOROPICRIN AND METHYL BROMIDE MIXTURE with more than 2% chloropicrin 2 T 1.51 CHLOROPICRIN AND METHYL CHLORIDE MIXTURE 2 T 1.3 1.5 0.81 HEXAETHYL TETRA- PHOSPHATE AND COM- PRESSED GAS MIXTURE 1 T see 4.3.3.2.1 CHLORINE TRIFLUORIDE 2 TOC 1.40 HEXAFLUOROPROPYL- ENE (REFRIGERANT GAS R 1216) 2A 1.7 1.9 1.11 SILICON TETRAFLUORIDE 2 TC 0.74 1.10 VINYL FLUORIDE, STABILIZED 2 F 22.5 0.58 0.65 0.64 METHYL CHLORIDE AND METHYLENE CHLORIDE MIXTURE 2 F 1.3 1.5 0.81 NEON, REFRIGERATED LIQUID 3 A see 4.3.3.2.4 ARGON, REFRIGERATED LIQUID 3 A see 4.3.3.2.4 ETHYLENE OXIDE AND CARBON DIOXIDE MIX- TURE, with not more than 9% ethylene oxide 2 A 0.66 0.75 2006/128. szám Minimum test pressure for tanks With thermal insulation Without thermal insulation Maximum permissible mass of contents per litre of capacity UN No. Name Classification code MPa bar MPa bar kg COMPRESSED GAS, TOXIC, FLAMMABLE, N.O.S.(a) 1 TF see 4.3.3.2.1 or 4.3.3.2.2 COMPRESSED GAS, FLAMMABLE N.O.S. 1 F see 4.3.3.2.1 or 4.3.3.2.2 COMPRESSED GAS, TOXIC, N.O.S.(a) 1 T see 4.3.3.2.1 or 4.3.3.2.2 COMPRESSED GAS, N.O.S. 1 A see 4.3.3.2.1 or 4.3.3.2.2 DEUTERIUM, COMPRESSED 1 F see 4.3.3.2.1 1,2-DICHLORO-1,1,2,2- TETRAFLUOROETHANE (REFRIGERANT GAS R114) 2 A 1.3 1,1-DIFLUOROETHYLENE (REFRIGERANT GAS R1132A) 2 F 22.5 0.66 0.78 0.77 ETHANE, REFRIGERATED LIQUID 3 F see 4.3.3.2.4 ETHYLENE 2 F 22.5 22.5 0.25 0.36 0.34 0.37 HELIUM, REFRIGERATED LIQUID 3 A see 4.3.3.2.4 HYDROCARBON GAS MIXTURE, COMPRESSED, N.O.S. 1 F see 4.3.3.2.1 or 4.3.3.2.2 1.2 1.2 1.2 1.6 2.5 1.4 1.4 1.4 1.8 2.3 2.3 2.3 2.7 0.50 0.49 0.48 0.47 0.46 0.45 0.44 0.43 0.42 HYDROCARBON GAS MIXTURE, LIQUEFIED, N.O.S. such as: Mixture A Mixture A01 Mixture A02 Mixture A0 Mixture A1 Mixture B1 Mixture B2 Mixture B Mixture C Other mixtures 2 F see 4.3.3.2.2 or 4.3.3.2.3 HYDROGEN, REFRIGERATED LIQUID 3 F see 4.3.3.2.4 INSECTICIDE GAS, TOXIC, N.O.S.(a) 2 T see 4.3.3.2.2 or 4.3.3.2.3 INSECTICIDE GAS, N.O.S. 2 A see 4.3.3.2.2 or 4.3.3.2.3 ISOBUTANE 2 F 0.49 KRYPTON, REFRIGERATED LIQUID 3 A see 4.3.3.2.4 2006/128. szám Minimum test pressure for tanks With thermal insulation Without thermal insulation Maximum permissible mass of contents per litre of capacity UN No. Name Classification code MPa bar MPa bar kg METHANE, COMPRESSED or NATURAL GAS, COMPRESSED with high methane content 1 F see 4.3.3.2.1 METHANE, REFRIGER- ATED LIQUID or NATURAL GAS, REFRIG- ERATED LIQUID with high methane content 3 F see 4.3.3.2.4 CHLORODIFLUORO- METHANE AND CHLOROPENTA- FLUOROETHANE MIX- TURE with fixed boiling point, with approximately 49% chlorodifluoromethane (REFRIGERANT GAS R502) 2 A 2.5 2.8 1.05 CHLORODIFLUORO- BROMOMETHANE (RE- FRIGERANT GAS R12B1) 2 A 1.61 OCTAFLUORO- CYCLOBUTANE (RE- FRIGERANT GAS RC318) 2 A 1.34 NITROGEN, REFRIGER- ATED LIQUID 3 A see 4.3.3.2.4 PROPANE 2 F 2.1 2.3 0.42 RARE GASES MIXTURE, COMPRESSED 1 A see 4.3.3.2.1 RARE GASES AND OXYGEN MIXTURE, COMPRESSED 1 A see 4.3.3.2.1 RARE GASES AND NITROGEN MIXTURE, COMPRESSED 1 A see 4.3.3.2.1 TETRAFLUORO- METHANE (REFRIGER- ANT GAS R14) 1 A 0.62 0.94 1-CHLORO-2,2,2- TRIFLUOROETHANE (REFRIGERANT GAS R133A) 2 A 1.18 TRIFLUOROMETHANE (REFRIGERANT GAS R23) 2 A 0.92 0.99 0.87 0.95 HYDROGEN AND METHANE MIXTURE, COMPRESSED 1 F see 4.3.3.2.1 1,1,1- TRIFLUOROETHANE (REFRIGERANT GAS R143A) 2 F 2.8 3.2 0.79 2006/128. szám Minimum test pressure for tanks With thermal insulation Without thermal insulation Maximum permissible mass of contents per litre of capacity UN No. Name Classification code MPa bar MPa bar kg XENON 2 A 1.30 1.24 2,2-DIMETHYLPROPANE 2 F 0.53 AMMONIA SOLUTION, relative density less than 0.880 at 15 °C in water, with more than 35% and not more than 40% ammonia with more than 40% and not more than 50% ammonia 4 A 1.2 1.2 0.80 0.77 CARBON DIOXIDE, REFRIGERATED LIQUID 3 A see 4.3.3.2.4 DICHLOROSILANE 2 TFC 0.90 SULFURYL FLUORIDE 2 T 1.1 HEXAFLUOROETHANE (REFRIGERANT GAS R116) 2 A 1.28 1.34 1.10 HYDROGEN IODIDE, ANHYDROUS 2 TC 1.9 2.1 2.25 PROPADIENE, STABILIZED 2 F 1.8 2.0 0.50 NITROUS OXIDE, REFRIGERATED LIQUID 3 O see 4.3.3.2.4 SILANE(b) 2 F 22.5 22.5 0.32 0.36 CARBONYL SULPHIDE 2 TF 2.7 3.0 0.84 CARBONYL FLUORIDE 2 TC 0.47 0.70 BROMOTRIFLUORO- ETHYLENE 2 F 1.19 HEXAFLUOROACETONE 2 TC 1.6 1.8 1.08 OCTAFLUOROBUT-2-ENE (REFRIGERANT GAS R1318) 2 A 1.34 OCTAFLUOROPROPANE (REFRIGERANT GAS R218) 2 A 2.1 2.3 1.07 NITROGEN TRIFLUORIDE 2 O 0.50 0.75 ETHYLACETYLENE, STABILIZED 2 F 0.57 ETHYL FLUORIDE (RE- FRIGERANT GAS R161) 2 F 2.1 2.5 0.57 METHYL FLUORIDE (RE- FRIGERANT GAS R41) 2 F 0.36 2006/128. szám Minimum test pressure for tanks With thermal insulation Without thermal insulation Maximum permissible mass of contents per litre of capacity UN No. Name Classification code MPa bar MPa bar kg 1-CHLORO-1,1- DIFLUOROETHANE (REFRIGERANT GAS R142B) 2 F 0.99 XENON, REFRIGERATED LIQUID 3 A see 4.3.3.2.4 CHLOROTRIFLUORO- METHANE AND TRIFLUOROMETHANE, AZEOTROPIC MIXTURE with approximately 60% chlorotrifluoromethane (REFRIGERANT GAS R503) 2 A 3.1 4.2 3.1 4.2 0.11 0.21 0.76 0.20 0.66 CARBON MONOXIDE AND HYDROGEN MIXTURE, COMPRESSED 1 TF see 4.3.3.2.1 CYCLOBUTANE 2 F 0.63 DICHLORODIFLUORO- METHANE AND DI- FLUORO-1,1 ETHANE, AZEOTROPIC MIXTURE with approximately 74% dichlorodifluoromethane (REFRIGERANT GAS R500) 2 A 1.8 1.01 BROMINE CHLORIDE 2 TOC 1.50 TRIFLUOROACETYL CHLORIDE 2 TC 1.3 1.5 1.17 ETHYLENE OXIDE AND DICHLORODIFLUORO- METHANE MIXTURE with not more than 12.5% ethylene oxide 2 A 1.5 1.6 1.09 PERCHLORYL FLUORIDE 2 TO 2.7 3.0 1.21 TRIFLUOROMETHANE, REFIGERATED LIQUID 3 A see 4.3.3.2.4 ETHYLENE, ACETYLENE PROPYLENE IN MIX- TURE, REFRIGERATED LIQUID, containing at least 71.5% ethylene with not more than 22.5% acetylene and not more than 6% propylene 3 F see 4.3.3.2.4 PERFLUORO(METHYL VINYL ETHER) 2 F 1.4 1.5 1.14 PERFLUORO(ETHYL VINYL ETHER) 2 F 0.98 COMPRESSED GAS, OXIDIZING, N.O.S. 1 O see 4.3.3.2.1 or 4.3.3.2.2 LIQUEFIED GAS, OXIDIZING, N.O.S. 2 O see 4.3.3.2.2 or 4.3.3.2.3 2006/128. szám Minimum test pressure for tanks With thermal insulation Without thermal insulation Maximum permissible mass of contents per litre of capacity UN No. Name Classification code MPa bar MPa bar kg GAS, REFRIGERATED LIQUID, N.O.S. 3 A see 4.3.3.2.4 1,1,1,2- TETRAFLUOROETHANE (REFRIGERANT GAS R134A) 2 A 1.6 1.8 1.04 LIQUEFIED GAS, TOXIC, FLAMMABLE, N.O.S.(a) 2 TF see 4.3.3.2.2 or 4.3.3.2.3 LIQUEFIED GAS, FLAMMABLE, N.O.S. 2 F see 4.3.3.2.2 or 4.3.3.2.3 LIQUEFIED GAS, TOXIC, N.O.S.(a) 2 T see 4.3.3.2.2 or 4.3.3.2.3 LIQUEFIED GAS, N.O.S. 2 A see 4.3.3.2.2 or 4.3.3.2.3 PENTAFLUOROETHANE (REFRIGERANT GAS R125) 2 A 4.1 4.9 0.95 DIFLUOROMETHANE (REFRIGERANT GAS R32) 2 F 3.9 4.3 0.78 HEPTAFLUOROPRO- PANE (REFRIGERANT GAS R227) 2 A 1.4 1.6 1.20 ETHYLENE OXIDE AND CHLOROTETRA- FLUOROETHANE MIXTURE, with not more than 8.8% ethylene oxide 2 A 1.16 ETHYLENE OXIDE AND PENTAFLUOROETHANE MIXTURE, with not more than 7.9% ethylene oxide 2 A 2.4 2.6 1.02 ETHYLENE OXIDE AND TETRAFLUOROETHANE MIXTURE, with not more than 5.6% ethylene oxide 2 A 1.5 1.7 1.03 ETHYLENE OXIDE AND CARBON DIOXIDE MIX- TURE, with more than 87% ethylene oxide 2 TF 2.8 2.8 0.73 COMPRESSED GAS, TOXIC, OXIDIZING, N.O.S.(a) 1 TO see 4.3.3.2.1 or 4.3.3.2.2 COMPRESSED GAS, TOXIC, CORROSIVE, N.O.S.(a) 1 TC see 4.3.3.2.1 or 4.3.3.2.2 COMPRESSED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S.(a) 1 TFC see 4.3.3.2.1 or 4.3.3.2.2 COMPRESSED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S.(a) 1 TOC see 4.3.3.2.1 or 4.3.3.2.2 2006/128. szám Minimum test pressure for tanks With thermal insulation Without thermal insulation Maximum permissible mass of contents per litre of capacity UN No. Name Classification code MPa bar MPa bar kg LIQUEFIED GAS, TOXIC, OXIDIZING, N.O.S.(a) 2 TO see 4.3.3.2.2 or 4.3.3.2.3 LIQUEFIED GAS, TOXIC, CORROSIVE, N.O.S.(a) 2 TC see 4.3.3.2.2 or 4.3.3.2.3 LIQUEFIED GAS, TOXIC, FLAMMABLE, CORRO- SIVE, N.O.S.(a) 2 TFC see 4.3.3.2.2 or 4.3.3.2.3 LIQUEFIED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S.(a) 2 TOC see 4.3.3.2.2 or 4.3.3.2.3 GAS, REFRIGERATED LIQUID, OXIDIZING, N.O.S. 3 O see 4.3.3.2.4 GAS, REFRIGERATED LIQUID, FLAMMABLE, N.O.S. 3 F see 4.3.3.2.4 AMMONIA SOLUTION, relative density less than 0.880 at 15 °C in water, with more than 50% ammonia 4 TC see 4.3.3.2.2 REFRIGERANT GAS R404A 2 A 2.9 3.2 0.84 REFRIGERANT GAS R407A 2 A 2.8 3.2 0.95 REFRIGERANT GAS R407B 2 A 3.0 3.3 0.95 REFRIGERANT GAS R407C 2 A 2.7 3.0 0.95 INSECTICIDE GAS, FLAMMABLE, N.O.S. 2 F see 4.3.3.2.2 or 4.3.3.2.3 INSECTICIDE GAS, TOXIC, FLAMMABLE, N.O.S.(a) 2 TF see 4.3.3.2.2 or 4.3.3.2.3 (a) Allowed if LC50 equal to or greater than 200 ppm. (b) Considered as pyrophoric. 4.3.3.3 Operation 4.3.3.3.1 When tanks, battery-wagons or MEGCs are approved for different gases, the change of use shall include emptying, purging and evacuation operations to the extent necessary for safe operation. 4.3.3.3.2 When tanks, battery-wagons or MEGCs are handed over for carriage, only the particulars specified in 6.8.3.5.6 applicable to the gas loaded or just discharged shall be visible; all particulars concerning other gases shall be covered up (see leaflet UIC 573 OR). 4.3.3.3.3 All the elements of a battery-wagons or MEGC shall contain only one and the same gas. 2006/128. szám 4.3.3.4 Provisions for the filling of liquid gas tankwagons (Reserved) 4.3.3.4.1 Control measures before filling (a) For each gas to be carried, the details on the tank plate (see 6.8.2.5.1 and 6.8.3.5.1 to 6.8.3.5.5) shall be checked to agree with those on the wagon panel (see 6.8.2.5.2, 6.8.3.5.6 and 6.8.3.5.7). Tank-wagons for multiple use shall especially be checked to ensure that the correct folding panels are visible on both sides of the wagon. The load limits on the wagon panel shall not exceed the maximum permissible filling mass on the tank plate. (b) The last load shall be determined, either from particulars in the consignment note or by analysis. If necessary, the tank shall be cleaned. (c) The mass of the residue shall be determined (e.g. by weighing) and taken into account in determining the filling quantity. (d) The leakproofness of the shell and its items of equipment, and their ability to function, shall be checked. (Reserved) 4.3.3.4.2 Filling procedure For filling, the provisions of the operating instructions of the tank-wagon shall be complied with. (Reserved) 4.3.3.4.3 Control measures after filling (a) After filling, whether the wagon is overfilled or overloaded shall be checked by calibrated checking devices (e.g. by weighing on a calibrated weighbridge). Overfilled or overloaded tank-wagons shall be immediately discharged in a safe manner until the permitted filling quantity is reached. (b) The partial pressure of inert gases in the gas phase shall not exceed 0.2 MPa (2 bar), or the gauge pressure in the gas phase shall not exceed by more than 0.1 MPa (1 bar) the vapour pressure (absolute) of the liquid gas at the temperature of the liquid phase. (c) After filling, bottom-discharge wagons shall be checked to ensure that the internal shut-off devices are closed so as to be leak-proof. (d) Before blank flanges or other equally effective devices are fitted, the vents shall be checked for leakproofness; any leaks shall be stopped by suitable means. (e) Blank flanges or other equally effective devices shall be fitted on the outlet of the vents. These closures shall be equipped with suitable seals. They shall be closed when using all elements provided for in their design types. (f) Lastly, a final visual check of the wagon, its equipment and marking shall be made to ensure that no filling substance is escaping. (Reserved) 2006/128. szám 4.3.4 Special provisions applicable to Classes 3 to 9 4.3.4.1 Coding, rationalized approach and hierarchy of tanks 4.3.4.1.1 Coding of tanks The four parts of the codes (tank codes) given in Column (12) of Table A in Chapter 3.2 have the following meanings: Part Description Tank code Types of tank L = tank for substances in the liquid state (liquids or solids handed over for carriage in the molten state); S = tank for substances in the solid state (powdery or granular). Calculation pressure G = Mindestberechnungsdruck gemäß allgemeinen Vorschriften des Absatzes 6.8.2.1.14 1,5; 2,65; 4; 10; 15 or 21 = minimum calculation pressure in bar (see 6.8.2.1.14). Openings (see 6.8.2.2.2) A = tank with bottom-filling and discharge openings with 2 closures; B = tank with bottom-filling and discharge openings with 3 closures; C = tank with top-filling and discharge openings with only cleaning openings below the surface of the liquid; D = tank with top-filling and discharge openings with no openings below the surface of the liquid. Safety valves/devices V = tank with a venting system, according to 6.8.2.2.6, but no flame trap; or non-explosion-pressure proof tank; F = tank with a venting system, according to 6.8.2.2.6, fitted with a flame trap; or explosion-pressure proof tank; N = tank without a venting system according to 6.8.2.2.6 and not hermetically closed; H = hermetically closed tank (see 1.2.1). 4.3.4.1.2 Rationalized approach for assignment of tank codes to groups of substances and hierarchy of tanks NOTE: Certain substances and groups of substances are not included in the rationalized approach, see 4.3.4.1.3 Rationalized approach Group of permitted substances Tank code Class Classification code Packing group Liquids LGAV F2 III M9 III LGBV 4.1 F2 II, III 5.1 O1 III M6 III M11 III and groups of permitted substances for tank code LGAV LGBF F1 II vapour pressure at 50 °C  1.1 bar F1 III D II vapour pressure at 50 °C  1.1 bar 2006/128. szám Rationalized approach Group of permitted substances Tank code Class Classification code Packing group D III LGBF (cont'd) and groups of permitted substances for tank codes LGAV and LGBV L1.5BN F1 I, II 1.1 bar < vapour pressure at 50 °C  1.75 bar F1 III Flashpoint < 23 °C, viscous, 1.1 bar < vapour pressure at 50 °C  1.75 bar D I, II 1.1 bar < vapour pressure at 50 °C  1.75 bar and groups of permitted substances for tank codes LGAV, LGBV and LGBF L4BN F1 I, III vapour pressure at 50 °C > 1.75 bar FC III D I vapour pressure at 50 °C > 1.75 bar 5.1 O1 I, II 5.1 OT1 I C1 II, III C3 II, III C4 II, III C5 II, III C7 II, III C8 II, III C9 II, III C10 II, III CF1 II CF2 II CS1 II CW1 II CW2 II CO1 II CO2 II CT1 II, III CT2 II, III CFT II M11 III and groups of permitted substances for tank codes LGAV, LGBV, LGBF and L1.5BN L4BH FT1 II, III FT2 II FC II FTC II 6.1 T1 II, III 6.1 T2 II, III 6.1 T3 II, III 6.1 T4 II, III 2006/128. szám Rationalized approach Group of permitted substances Tank code Class Classification code Packing group 6.1 T5 II, III L4BH (cont'd) 6.1 T6 II, III 6.1 T7 II, III 6.1 TF1 II 6.1 TF2 II, III 6.1 TF3 II 6.1 TS II 6.1 TW1 II 6.1 TW2 II 6.1 TO1 II 6.1 TO2 II 6.1 TC1 II 6.1 TC2 II 6.1 TC3 II 6.1 TC4 II 6.1 TFC II 6.2 I4 M2 II and groups of permitted substances for tank codes LGAV, LGBV, LGBF, L1.5BN and L4BN L4DH 4.2 S1 II,III 4.2 S3 II, III 4.2 ST1 II, III 4.2 ST3 II, III 4.2 SC1 II, III 4.2 SC3 II, III 4.3 W1 II, III 4.3 WF1 II, III 4.3 WT1 II, III 4.3 WC1 II, III CT1 II,III and groups of permitted substances for tank codes LGAV, LGBV, LGBF, L1.5BN, L4BN and L4BH L10BH C1 I C3 I C4 I C5 I C7 I C8 I C9 I C10 I CF1 I CF2 I CS1 I CW1 I CW2 I CO1 I 2006/128. szám Rationalized approach Group of permitted substances Tank code Class Classification code Packing group CO2 I L10BH (cont'd) CT1 I CT2 I COT I and groups of permitted substances for tank codes LGAV, LGBV, LGBF, L1.5BN, L4BN, and L4BH L10CH FT1 I FT2 I FC I FTC I 6.1 T1 I 6.1 T2 I 6.1 T3 I 6.1 T4 I 6.1 T5 I 6.1 T6 I 6.1 T7 I 6.1 TF1 I 6.1 TF2 I 6.1 TF3 I 6.1 TS I 6.1 TW1 I 6.1 TO1 I 6.1 TC1 I 6.1 TC2 I 6.1 TC3 I 6.1 TC4 I 6.1 TFC I and groups of permitted substances for tank codes LGAV, LGBV, LGBF, L1.5BN, L4BN, L4BH, and L10BH L10DH 4.3 W1 I 4.3 WF1 I 4.3 WT1 I 4.3 WC1 I 4.3 WFC I 5.1 OTC I CT1 I and groups of permitted substances for tank codes LGAV, LGBV, LGBF, L1.5BN, L4BN, L4BH, L4DH, L10BH and L10CH L15CH FT1 I 6.1 TF1 I and groups of permitted substances for tank codes LGAV, LGBV, LGBF, L1.5BN, L4BN, L4BH, L10BH and L10CH L21DH 4.2 S1 I 4.2 S3 I 4.2 SW I 4.2 ST3 I 2006/128. szám Rationalized approach Group of permitted substances Tank code Class Classification code Packing group L21DH (cont'd) and groups of permitted substances for tank codes LGAV, LGBV, LGBF, L1.5BN, L4BN, L4BH, L4DH, L10BH, L10CH, L10DH and L15CH Solids SGAV 4.1 F1 III 4.1 F3 III 4.2 S2 II, III 4.2 S4 III 5.1 O2 II, III C2 II, III C4 III C6 III C8 III C10 II, III CT2 III M7 III M11 II, III SGAN 4.1 F1 II 4.1 F3 II 4.1 FT1 II, III 4.1 FT2 II, III 4.1 FC1 II, III 4.1 FC2 II, III 4.2 S2 II 4.2 S4 II, III 4.2 ST2 II, III 4.2 ST4 II, III 4.2 SC2 II, III 4.2 SC4 II, III 4.3 W2 II, III 4.3 WF2 II 4.3 WS II, III 4.3 WT2 II, III 4.3 WC2 II, III 5.1 O2 II, III 5.1 OT2 II, III 5.1 OC2 II, III C2 II C4 II C6 II C8 II C10 II CF2 II CS2 II CW2 II CO2 II CT2 II 2006/128. szám Rationalized approach Group of permitted substances Tank code Class Classification code Packing group M3 III SGAN (cont'd) and groups of permitted substances for tank codes SGAV SGAH 6.1 T2 II, III 6.1 T3 II, III 6.1 T5 II, III 6.1 T7 II, III 6.1 T9 II 6.1 TF3 II 6.1 TS II 6.1 TW2 II 6.1 TO2 II 6.1 TC2 II 6.1 TC4 II M1 II, III and groups of permitted substances for tanks codes SGAV and SGAN S4AH M2 II and groups of permitted substances for tanks codes SGAV, SGAN and SGAH S10AN C2 I C4 I C6 I C8 I C10 I CF2 I CS2 I CW2 I CO2 I CT2 I and groups of permitted substances for tank codes SGAV and SGAN S10AH 6.1 T2 I 6.1 T3 I 6.1 T5 I 6.1 T7 I 6.1 TS I 6.1 TW2 I 6.1 TO2 I 6.1 TC2 I 6.1 TC4 I and groups of permitted substances for tank codes SGAV, SGAN, SGAH and S10AN Hierarchy of tanks Tanks with tank codes different from those indicated in this table or in Table A of Chapter 3.2 may also be used provided that: – the first part of the code (L or S) remains unchanged and – any other element (number or letter) of parts 2 to 4 of these tank codes correspond to a level of safety at least equivalent to the corresponding element of the tank code indicated in Table A of Chapter 3.2, according to the following increasing order: Part 2: Calculation pressure 2006/128. szám G → 1.5 →2.65 →4 →10 →15 →21 bar Part 3: Openings A → B → C → D Part 4: Safety valves/devices V → F → N → H. For example, a tank with the tank code L10CN is authorized for the carriage of a substance to which the tank code L4BN has been assigned. NOTE: The hierarchy does not take account of any special provisions for each entry (see 4.3.5 and 6.8.4) 4.3.4.1.3 The following substances and groups of substances in respect of which a "(+)" is given after the tank code in Column (12) of Table A in Chapter 3.2 are subject to special provisions. In that case the alternate use of the tanks for other substances and groups of substances is permitted only where this is specified in the certificate of type approval. Higher value tanks according to the provisions at the end of the table in 4.3.4.1.2 may be used with due regard to the special provisions indicated in Column (13) of Table A in Chapter 3.2. The requirements for these tanks are given by the following tank codes supplemented by the relevant special provisions indicated in column (13) of table A in Chapter 3.2. (a) Class 4.1 UN No. 2448 SULPHUR, MOLTEN: code LGBV; (b) Class 4.2 UN No. 1381 PHOSPHORUS, WHITE or YELLOW, DRY, or UNDER WATER or IN SOLUTION and UN No. 2447 PHOSPHORUS, WHITE or YELLOW MOLTEN: code L10DH; (c) Class 4.3 UN No. 1389 ALKALI METAL AMALGAM, LIQUID, UN No. 1391 ALKALI METAL DISPERSION or ALKALINE EARTH METAL DISPERSION, UN No. 1392 ALKALINE EARTH METAL AMALGAM, LIQUID, UN No. 1415 LITHIUM, UN No. 1420 POTASSIUM METAL ALLOYS, LIQUID, UN No. 1421 ALKALI METAL ALLOY, LIQUID, N.O.S., UN No. 1422 POTASSIUM SODIUM ALLOYS, LIQUID, UN No. 1428 SODIUM and UN No. 2257 POTASSIUM: code L10BN; UN No. 1407 CAESIUM and UN No. 1423 RUBIDIUM: code L10CH; UN No. 3401 ALKALI METAL AMALGAM, SOLID, UN No. 3402 ALKALINE EARTH METAL AMAL- GAM, SOLID, 3403 POTASSIUM METAL ALLOYS, SOLID and UN No. 3404 POTASSIUM SO- DIUM ALLOYS, solid: code L10BN; (d) Class 5.1 UN No. 1873 PERCHLORIC ACID 50-72%: code L4DN; UN No. 2015 HYDROGEN PEROXIDE, AQUEOUS SOLUTION, STABILIZED with more than 70% hydrogen peroxide: code L4DV; UN No. 2015 HYDROGEN PEROXIDE, AQUEOUS SOLUTION, STABILIZED with 60-70% hydrogen peroxide: code L4BV; UN No. 2014 HYDROGEN PEROXIDE, AQUEOUS SOLUTION with 20-60% hydrogen peroxide, and UN No. 3149 HYDROGEN PEROXIDE AND PEROXYACETIC ACID MIXTURE, STABILIZED: code L4BV; UN No. 2426 AMMONIUM NITRATE, LIQUID, hot concentrated solution with more than 80% but not more than 93%: code L4BV; UN No. 3375 AMMONIUM NITRATE EMULSION, SUSPENSION or GEL, intermediate for blasting explosives, liquid: code LGAV; UN No. 3375 AMMONIUM NITRATE EMULSION, SUSPENSION or GEL, intermediate for blasting explosives, solid: code SGAV. (e) Class 5.2 UN No. 3109 ORGANIC PEROXIDE TYPE F, LIQUID: code L4BN; UN No. 3110 ORGANIC PEROXIDE, TYPE F, SOLID: code S4AN; (f) Class 6.1 UN No. 1613 HYDROGEN CYANIDE, AQUEOUS SOLUTION and UN No. 3294 HYDROGEN CYANIDE SOLUTION IN ALCOHOL: code L15DH; (g) Class 7 All substances: special tanks; Minimum requirements for liquids: code L2.65CN; for solids: code S2.65AN Notwithstanding the general requirements of this paragraph, tanks used for radioactive material may also be used for the carriage of other goods provided the requirements of 5.1.3.2 are complied with. 2006/128. szám (h) Class 8 UN No. 1052 HYDROGEN FLUORIDE, ANHYDROUS and UN No. 1790 HYDROFLUORIC ACID, SOLUTION, with more than 85% hydrofluoric acid: code L21DH; UN No. 1744 BROMINE or BROMINE SOLUTION: code L21DH; UN No. 1791 HYPOCHLORITE SOLUTION and UN No. 1908 CHLORITE SOLUTION: code L4BV. 4.3.4.1.4 Tank-containers or tank swap bodies intended for the carriage of liquid waste, which are in accordance with the requirements of Chapter 6.10 and are fitted with two closures in accordance with 6.10.3.2, shall be assigned to tank code L4AH. If the tanks in question are equipped for the carriage of liquids and solids alternatively, they shall be assigned to combined codes L4AH and S4AH. 4.3.4.2 General provisions 4.3.4.2.1 Where hot substances are loaded, the temperature of the outer surface of the tank or of the thermal insulation shall not exceed 70 °C during carriage. 4.3.4.2.2 The connecting pipes between the shells of several independent but interconnected tank-wagons (complete train, for example) shall be empty during carriage. (Reserved) When shells approved for liquefied gases of Class 2 are also approved for liquids of other classes, the orange band in accordance with 5.3.5 shall be covered or made unrecognisable by other means so that it is not visible during the carriage of these liquids. 4.3.4.2.3 During the carriage of these liquids, the particulars according to 6.8.3.5.6 (b) or (c) shall no longer be visible on the two sides of the tank-wagon or on the panels. (Reserved) 4.3.5 Special provisions When they are shown under an entry in Column (13) of Table of A in Chapter 3.2, the following special provisions apply: TU1 The tanks shall not be handed over for carriage until the substance has solidified completely and been covered by an inert gas. Uncleaned empty tanks which have contained these substances shall be filled with an inert gas. TU2 The substance shall be covered by an inert gas. Uncleaned empty tanks which have contained these substances shall be filled with an inert gas. TU3 The inside of the shell and all parts liable to come into contact with the substance shall be kept clean. No lubricant capable of combining dangerously with the substance shall be used for pumps, valves or other devices. TU4 During carriage, these substances shall be under a layer of inert gas, the gauge pressure of which shall not be less than 50 kPa (0.5 bar). Uncleaned empty tanks which have contained these substances shall when handed over for carriage be filled with an inert gas at a gauge pressure of at least 50 kPa (0.5 bar). TU5 (Reserved) TU6 Not authorized for carriage in tanks, battery-wagons and MEGCs when having a LC50 lower than 200 ppm. TU7 The materials used to ensure leakproofness of the joints or for the maintenance of the closures shall be compatible with the contents. TU8 An aluminium-alloy tank shall not be used for carriage unless the tank is reserved solely for such carriage and the acetaldehyde is free from acid. 2006/128. szám TU9 UN No.1203 PETROL (GASOLINE) with a vapour pressure at 50 °C of more than 110 kPa (1.1 bar) but not above 150 kPa (1.5 bar) may also be carried in tanks designed according to 6.8.2.1.14 (a) and having equipment conforming to 6.8.2.2.6. TU10 (Reserved) TU11 During filling, the temperature of this substance shall not exceed 60 °C. A maximum filling temperature of 80 °C is allowed provided that smoulder spots are prevented and that the following conditions are met. After filling, the tanks shall be pressurized (e.g. with compressed air) to check tightness. It shall be ensured that no depressurization takes place during carriage. Before discharge, it shall be checked if pressure in the tanks is still above atmospheric. If this is not the case, an inert gas shall be introduced into the tanks prior to discharge. TU12 In the event of a change of use, shells and equipment shall be thoroughly cleansed of all residues before and after the carriage of this substance. TU13 Tanks shall be free from impurities at the time of filling. Service equipment such as valves and external piping shall be emptied after filling or discharging. TU14 The protective caps of closures shall be locked during carriage. TU15 Tanks shall not be used for the carriage of foodstuffs, articles of consumption or animal feeds. TU16 Uncleaned empty tanks, shall, when handed over for carriage, either: – be filled with nitrogen; or – be filled with water to not less than 96% and not more than 98% of their capacity; between 1 October and 31 March, this water shall contain sufficient anti-freeze agent to make it impossible for the water to freeze during carriage; the anti-freeze agent shall be free from corrosive action and not liable to react with phosphorus. TU17 Only to be carried in battery-wagons or MEGCs the elements of which are composed of receptacles. TU18 The degree of filling shall remain below the level at which, if the contents were raised to a temperature at which the vapour pressure equalled the opening pressure of the safety valve, the volume of the liquid would reach 95% of the tank’s capacity at that temperature. The provision in 4.3.2.3.4 shall not apply. TU19 Tanks may be filled to 98% at the filling temperature and pressure. The provision in 4.3.2.3.4 shall not apply. TU20 (Reserved) TU21 The substance shall, if water is used as a protective agent, be covered with a depth of not less than 12 cm of water at the time of filling; the degree of filling at a temperature of 60 °C shall not exceed 98%. If nitrogen is used as a protective agent, the degree of filling at a temperature of 60 °C shall not exceed 96%. The remaining space shall be filled with nitrogen in such a way that, even after cooling, the pressure at no time falls below atmospheric pressure. The tank shall be closed in such a way that no leakage of gas occurs. TU22 Tanks shall be filled to not more than 90% of their capacity; a space of 5% shall remain empty when the liquid is at an average temperature of 50 °C. TU23 The degree of filling shall not exceed 0.93 kg per litre of capacity, if filling is by mass. If filling is by volume, the degree of filling shall not exceed 85%. TU24 The degree of filling shall not exceed 0.95 kg per litre of capacity, if filling is by mass. If filling is by volume, the degree of filling shall not exceed 85%. TU25 The degree of filling shall not exceed 1.14 kg per litre of capacity, if filling is by mass. If filling is by volume, the degree of filling shall not exceed 85%. TU26 The degree of filling shall not exceed 85%. TU27 Tanks shall not be filled to more than 98% of their capacity. TU28 Tanks shall be filled to not more than 95% of their capacity at a reference temperature of 15 °C. TU29 Tanks shall be filled to not more than 97% of their capacity and the maximum temperature after filling shall not exceed 140 °C. 2006/128. szám TU30 Tanks shall be filled as set out in the test report for the type approval of the tank but shall be filled to not more than 90% of their capacity. TU31 Tanks shall not be filled to more than 1 kg per litre of capacity. TU32 Tanks shall not be filled to more than 88% of their capacity. TU33 Tanks shall be filled to not less than 88% and not more than 92% of their capacity or to 2.86 kg per litre of capacity. TU34 Tanks shall not be filled to more than 0.84 kg per litre of capacity. TU35 Empty fixed tank-wagons, empty demountable tanks and empty tank-containers, uncleaned, which have contained these substances are not subject to the requirements of RID if adequate measures have been taken to nullify any hazard. TU36 The degree of filling according to 4.3.2.2, at the reference temperature of 15 °C, shall not exceed 93% of the capacity. TU37 Carriage in tanks is limited to substances containing pathogens which are unlikely to be a serious hazard, and for which, while capable of causing serious infection on exposure, effective treatment and preventive measures are available and the risk of spread of infection is limited (i.e. moderate individual risk and low community risk). TU38 Procedure following activation of energy absorption elements When energy absorption elements have undergone plastic deformation in accordance with 6.8.4, special provision TE 22, the tank-wagon or batterywagon shall, after undergoing an inspection, be removed to a repair workshop immediately. If the loaded tank-wagon or loaded battery-wagon is capable of absorbing the shocks of a collision that might occur in normal conditions of rail transport, e.g. after the energy absorption buffers fitted have been replaced with normal buffers or after the damaged energy absorption elements have been temporarily blocked off, the tank-wagon or battery wagon may, after undergoing an inspection, be moved for the purpose of emptying and finally to a repair workshop. The information that the energy absorption elements are not working shall be made available with the tank-wagon or battery-wagon. NOTE: The symbol "*" in relation to the indication of special provision TU38 in column (13) of Table A of Chapter 3.2 means that this provision will not enter into force until 1 January 2007. (Reserved) TU39 The suitability of the substance for carriage in tanks shall be demonstrated. The method to evaluate this suitability shall be approved by the competent authority. One method is test 8(d) in Test Series 8 (see Manual of Tests and Criteria, Part 1, sub-section 18.7). Substances shall not be allowed to remain in the tank for any period that could result in caking. Appropriate measures shall be taken to avoid accumulation and packing of substances in the tank (e.g. cleaning etc.). 2006/128. szám Chapter 4.4 Use of fibre-reinforced plastics (FRP) tank-containers including tank swap bodies NOTE: For portable tanks and UN multiple-element gas containers (MEGCs), see Chapter 4.2; for tankwagons, demountable tanks, tank-containers and tank swap bodies, with shells made of metallic materials, and battery-wagons and multiple elements gas containers (MEGCs) other than UN MEGCs, see Chapter 4.3; for vacuum-operated waste containers, see Chapter 4.5. 4.4.1 General The carriage of dangerous substances in fibre-reinforced plastics (FRP) tank-containers, including tank swap bodies, is permitted only when the following conditions are met: (a) The substance is classified in Class 3, 5.1, 6.1, 6.2, 8 or 9; (b) The maximum vapour pressure (absolute pressure) at 50 °C of the substance does not exceed 110 kPa (1.1 bar); (c) The carriage of the substance in metallic tanks is authorized according to 4.3.2.1.1; (d) The calculation pressure specified for that substance in part 2 of the tank code given in Column (12) of Table A in Chapter 3.2 does not exceed 4 bar (see also 4.3.4.1.1) and, (e) The tank-container, including tank swap bodies, complies with the provisions of Chapter 6.9 applicable for the carriage of the substance. 4.4.2 Operation 4.4.2.1 The provisions of 4.3.2.1.5 to 4.3.2.2.4, 4.3.2.3.3 to 4.3.2.3.6, 4.3.2.4.1, 4.3.2.4.2, 4.3.4.1 and 4.3.4.2 shall apply. 4.4.2.2 The temperature of the substance carried shall not exceed, at the time of filling, the maximum service temperature indicated on the tank plate referred to in 6.9.6. 4.4.2.3 When applicable to carriage in metallic tanks, the special provisions (TU) of 4.3.5 shall also apply, as indicated in Column (13) of Table A in Chapter 3.2. 2006/128. szám Chapter 4.5 Use of vacuum-operated waste tanks NOTE: For portable tanks and UN multiple elements gas containers (MEGCs), see Chapter 4.2; for tankwagons, demountable tanks, tank-containers and tank swap bodies, with shells made of metallic materials, and battery-wagons and multiple elements gas containers (MEGCs) other than UN MEGCs, see Chapter 4.3; for fibre reinforced plastics tank-containers, see Chapter 4.4. 4.5.1 Use 4.5.1.1 Wastes consisting of substances in Classes 3, 4.1, 5.1, 6.1, 6.2, 8 and 9 may be carried in vacuumoperated waste tanks conforming to Chapter 6.10 if their carriage in tank-containers or tank swap bodies is permitted according to Chapter 4.3. Substances assigned to tank code L4BH in Column (12) of Table A of Chapter 3.2 or to another tank code permitted under the hierarchy in 4.3.4.1.2 may be carried in vacuum-operated waste tanks with the letter "A" or "B" in part 3 of the tank code. 4.5.2 Operation 4.5.2.1 The requirements of Chapter 4.3 except those of 4.3.2.2.4 and 4.3.2.3.3 apply to the carriage in vacuumoperated waste tanks and are supplemented by the requirements of 4.5.2.2 to 4.5.2.4 below. 4.5.2.2 For carriage of liquids classified as flammable, vacuum-operated waste tanks shall be filled through fillings which discharge into the tank at a low level. Measures shall be made to minimize the production of spray. 4.5.2.3 When discharging flammable liquids with a flash-point below 23 °C by using air pressure, the maximum working pressure shall be 100 kPa (1 bar). 4.5.2.4 The use of tanks fitted with an internal piston operating as a compartment wall is allowed only when the substances on either side of the wall (piston) do not react dangerously with each other (see 4.3.2.3.6). 4.5.2.5 It shall be ensured that the stationary position of an existing suction boom does not change during normal conditions of transport. 2006/128. szám Chapter 5.1 General provisions 5.1.1 Application and general provisions This Part sets forth the provisions for dangerous goods consignments relative to marking, labelling, and documentation, and, where appropriate, authorization of consignments and advance notifications. 5.1.2 Use of overpacks 5.1.2.1 (a) An overpack shall be marked with the word "OVERPACK" and the UN number preceded by the letters "UN" and shall be labelled as required for packages in 5.2.2, for each item of dangerous goods contained in the overpack, unless the markings and the labels representative of all dangerous goods contained in the overpack are visible. If the same marking or the same label is required for different packages, it only needs to be applied once. (b) Label conforming to model No. 11 illustrated in 5.2.2.2.2 shall be displayed on two opposite sides of the following overpacks: – overpacks containing packages which shall be labelled in accordance with 5.2.2.1.12, unless the labels remain visible, and – overpacks containing liquids in packages which need not be labelled in accordance with 5.2.2.1.12, unless the closures remain visible. 5.1.2.2 Each package of dangerous goods contained in an overpack shall comply with all applicable provisions of RID. The "OVERPACK" marking is an indication of compliance with this requirement. The intended function of each package shall not be impaired by the overpack. 5.1.2.3 The prohibitions on mixed loading also apply to these overpacks. 5.1.3 Empty uncleaned packagings (including IBCs and large packagings), tanks, wagons and containers for carriage in bulk 5.1.3.1 Empty uncleaned packagings (including IBCs and large packagings), tanks (including tank-wagons, battery-wagons, demountable tanks, portable tanks, tank-containers, MEGCs), wagons and containers for carriage in bulk having contained dangerous goods of the different classes other than Class 7, shall be marked and labelled as if they were full. NOTE: For documentation, see Chapter 5.4. 5.1.3.2 Tanks and IBCs used for the carriage of radioactive material shall not be used for the storage or carriage of other goods unless decontaminated below the level of 0.4 Bq/cm2 for beta and gamma emitters and low toxicity alpha emitters and 0.04 Bq/cm2 for all other alpha emitters. 5.1.4 Mixed packing When two or more dangerous goods are packed within the same outer packaging, the package shall be labelled and marked as required for each substance or article. If the same label is required for different goods, it only needs to be applied once. 5.1.5 General provisions for Class 7 5.1.5.1 Requirements before shipments 5.1.5.1.1 Requirements before the first shipment of a package Before the first shipment of any package, the following requirements shall be fulfilled: (a) If the design pressure of the containment system exceeds 35 kPa (gauge), it shall be ensured that the containment system of each package conforms to the approved design requirements relating to the capability of that system to maintain its integrity under that pressure; (b) For each Type B(U), Type B(M) and Type C package and for each package containing fissile material, it shall be ensured that the effectiveness of its shielding and containment and, where necessary, the heat transfer characteristics and the effectiveness of the confinement system, are within the limits applicable to or specified for the approved design; (c) For packages containing fissile material, where, in order to comply with the requirements of 6.4.11.1, neutron poisons are specifically included as components of the package, checks shall be performed to confirm the presence and distribution of those neutron poisons. 2006/128. szám 5.1.5.1.2 Requirements before each shipment of a package Before each shipment of any package, the following requirements shall be fulfilled: (a) For any package it shall be ensured that all the requirements specified in the relevant provisions of RID have been satisfied; (b) It shall be ensured that lifting attachments which do not meet the requirements of 6.4.2.2 have been removed or otherwise rendered incapable of being used for lifting the package, in accordance with 6.4.2.3; (c) For each Type B(U), Type B(M) and Type C package and for each package containing fissile material, it shall be ensured that all the requirements specified in the approval certificates have been satisfied; (d) Each Type B(U), Type B(M) and Type C package shall be held until equilibrium conditions have been approached closely enough to demonstrate compliance with the requirements for temperature and pressure unless an exemption from these requirements has received unilateral approval; (e) For each Type B(U), Type B(M) and Type C package, it shall be ensured by inspection and/or appropriate tests that all closures, valves, and other openings of the containment system through which the radioactive contents might escape are properly closed and, where appropriate, sealed in the manner for which the demonstrations of compliance with the requirements of 6.4.8.7 were made; (f) For each special form radioactive material, it shall be ensured that all the requirements specified in the approval certificate and the relevant provisions of RID have been satisfied; (g) For packages containing fissile material the measurement specified in 6.4.11.4(b) and the tests to demonstrate closure of each package as specified in 6.4.11.7 shall be performed where applicable; (h) For each low dispersible radioactive material, it shall be ensured that all the requirements specified in the approval certificate and the relevant provisions of RID have been satisfied. 5.1.5.2 Approval of shipments and notification 5.1.5.2.1 General In addition to the approval for package designs described in Chapter 6.4, multilateral shipment approval is also required in certain circumstances (5.1.5.2.2 and 5.1.5.2.3). In some circumstances it is also necessary to notify competent authorities of a shipment (5.1.5.2.4). 5.1.5.2.2 Shipment approvals Multilateral approval shall be required for: (a) the shipment of Type B(M) packages not conforming with the requirements of 6.4.7.5 or designed to allow controlled intermittent venting; (b) the shipment of Type B(M) packages containing radioactive material with an activity greater than 3000 A1 or 3000 A2, as appropriate, or 1000 TBq, whichever is the lower; (c) the shipment of packages containing fissile materials if the sum of the criticality safety indexes of the packages exceeds 50; except that a competent authority may authorize carriage into or through its country without shipment approval, by a specific provision in its design approval (see 5.1.5.3.1). 5.1.5.2.3 Shipment approval by special arrangement Provisions may be approved by a competent authority under which a consignment, which does not satisfy all of the applicable requirements of RID may be carried under special arrangement (see 1.7.4). 5.1.5.2.4 Notifications Notification to competent authorities is required as follows: (a) Before the first shipment of any package requiring competent authority approval, the consignor shall ensure that copies of each applicable competent authority certificate applying to that package design have been submitted to the competent authority of each country through or into which the consignment is to be carried. The consignor is not required to await an acknowledgement from the competent authority, nor is the competent authority required to make such acknowledgement of receipt of the certificate; (b) For each of the following types of shipments: (i) Type C packages containing radioactive material with an activity greater than 3000 A1 or 3000 A2, as appropriate, or 1000 TBq, whichever is the lower; (ii) Type B(U) packages containing radioactive material with an activity greater than 3000 A1 or 3000 A2, as appropriate, or 1000 TBq, whichever is the lower; (iii) Type B(M) packages; 2006/128. szám (iv) Shipment under special arrangement; The consignor shall notify the competent authority of each country through or into which the consignment is to be carried. This notification shall be in the hands of each competent authority prior to the commencement of the shipment, and preferably at least 7 days in advance; (c) The consignor is not required to send a separate notification if the required information has been included in the application for shipment approval; (d) The consignment notification shall include: (i) sufficient information to enable the identification of the package or packages including all applicable certificate numbers and identification marks; (ii) information on the date of shipment, the expected date of arrival and proposed routeing; (iii) the name(s) of the radioactive material(s) or nuclide(s); (iv) descriptions of the physical and chemical forms of the radioactive material, or whether it is special form radioactive material or low dispersible radioactive material; and (v) the maximum activity of the radioactive contents during carriage expressed in becquerels (Bq) with an appropriate SI prefix (see 1.2.2.1). For fissile material, the mass of fissile material in grams (g), or multiples thereof, may be used in place of activity. 5.1.5.3 Certificates issued by the competent authority 5.1.5.3.1 Certificates issued by the competent authority are required for the following: (a) Designs for: (i) special form radioactive material; (ii) low dispersible radioactive material; (iii) packages containing 0.1 kg or more of uranium hexafluoride; (iv) all packages containing fissile material unless excepted by 6.4.11.2; (v) Type B(U) packages and Type B(M) packages; (vi) Type C packages; (b) Special arrangements; (c) Certain shipments (see 5.1.5.2.2). The certificates shall confirm that the applicable requirements are met, and for design approvals shall attribute to the design an identification mark. The package design and shipment approval certificates may be combined into a single certificate. Certificates and applications for these certificates shall be in accordance with the requirements in 6.4.23. 5.1.5.3.2 The consignor shall be in possession of a copy of each applicable certificate. The consignor shall also have a copy of any instructions with regard to the proper closing of the package and any preparation for shipment before making any shipment under the terms of the certificates. 5.1.5.3.3 For package designs where a competent authority issued certificate is not required, the consignor shall, on request, make available for inspection by the competent authority, documentary evidence of the compliance of the package design with all the applicable requirements. 5.1.5.4 Summary of approval and prior notification requirements NOTE 1: Before first shipment of any package requiring competent authority approval of the design, the consignor shall ensure that a copy of the approval certificate for that design has been submitted to the competent authority of each country en route (see 5.1.5.2.4 (a)). 2: Notification required if contents exceed 3 x 103 A1, or 3 x 103 A2, or 1000 TBq; (see 5.1.5.2.4 (b)). 3: Multilateral approval of shipment required if contents exceed 3 x 103 A1, or 3 x 103 A2, or 1000 TBq, or if controlled intermittent venting is allowed (see 5.1.5.2). 4: See approval and prior notification provisions for the applicable package for carrying this material. 2006/128. szám Competent authority approval required Subject UN Number Country of origin Countries en route(a) Consignor required to notify the competent authorities of the country of origin and of the countries en route(a) before each shipment Reference Calculation of unlisted A1 and A2 values - Yes Yes No - Excepted packages – package design – shipment 2908, 2909, 2910, No No No No No No - LSA material(b) and SCO(b) / Industrial packages types 1, 2 or 3, non fissile and fissile excepted – package design – shipment 2912, 2913, 3321, No No No No No No - Type A packages(b), non fissile and fissile excepted – package design – shipment 2915, No No No No No No - Type B(U) packages(b) non fissile and fissile excepted – package design – shipment Yes No No No See Note 1 See Note 2 5.1.5.2.4 (b), 5.1.5.3.1 (a), 6.4.22.2 Type B(M) packages(b), non fissile and fissile excepted – package design – shipment Yes See Note 3 Yes See Note 3 No Yes 5.1.5.2.4 (b), 5.1.5.3.1 (a), 5.1.5.2.2, 6.4.22.3 Type C packages(b), non fissile and fissile excepted – package design – shipment Yes No No No See Note 1 See Note 2 5.1.5.2.4 (b), 5.1.5.3.1 (a), 6.4.22.2 Packages for fissile material – package design – shipment: sum of criticality safety indexes not more than 50 sum of criticality safety indexes greater than 50 2977, 3324, 3325, 3326, 3327, 3328, 3329, 3330, 3331, Yes(c) No(d) Yes Yes(c) No(d) Yes No See Note 2 See Note 2 5.1.5.3.1 (a), 5.1.5.2.2, 6.4.22.4 Special form radioactive material – design – shipment - See Note 4 Yes See Note 4 No See Note 4 No See Note 4 1.6.6.3, 5.1.5.3.1 (a), 6.4.22.5 Low dispersable radioactive material – design – shipment - See Note 4 Yes See Note 4 No See Note 4 No See Note 4 5.1.5.3.1 (a), 6.4.22.3 Packages containing 0.1 kg or more of uranium hexafluoride – design – shipment - See Note 4 Yes See Note 4 No See Note 4 No See Note 4 5.1.5.3.1 (a), 6.4.22.1 Special Arrangement – shipment 2919, Yes Yes Yes 1.7.4.2, 5.1.5.3.1 (b), 5.1.5.2.4 (b) 2006/128. szám Competent authority approval required Subject UN Number Country of origin Countries en route(a) Consignor required to notify the competent authorities of the country of origin and of the countries en route(a) before each shipment Reference Approved packages designs subjected to transitional measures See 1.6.6 See 1.6.6 See Note 1 1.6.6.1, 1.6.6.2, 5.1.5.2.4 (b), 5.1.5.3.1 (a), 5.1.5.2.2 (a) Countries from, through or into which the consignment is carried. (b) If the radioactive contents are fissile material which is not excepted from the provisions for packages containing fissile material, then the provisions for fissile material packages apply (see 6.4.11). (c) Designs of packages for fissile material may also require approval in respect of one of the other items in the table. (d) Shipments may, however, require approval in respect of one of the other items in the table. 2006/128. szám Chapter 5.2 Marking and labelling 5.2.1 Marking of packages NOTE: For markings related to the construction, testing and approval of packagings, large packagings, gas receptacles and IBCs, see Part 6. 5.2.1.1 Unless provided otherwise in RID, the UN number corresponding to the dangerous goods contained, preceded by the letters "UN" shall be clearly and durably marked on each package. In the case of unpackaged articles the marking shall be displayed on the article, on its cradle or on its handling, storage or launching device. 5.2.1.2 All package markings required by this Chapter: (a) shall be readily visible and legible; (b) shall be able to withstand open weather exposure without a substantial reduction in effectiveness. 5.2.1.3 Salvage packagings shall additionally be marked with the word "SALVAGE". 5.2.1.4 Intermediate bulk containers of more than 450 litres capacity shall be marked on two opposite sides. 5.2.1.5 Additional provisions for goods of Class 1 For goods of Class 1, packages shall, in addition, bear the proper shipping name as determined in accordance with 3.1.2. The marking, which shall be clearly legible and indelible, shall be in an official language of the country of origin and also, if that language is not French, German, Italian or English, in French, German, Italian or English unless any international tariffs or agreements concluded between the railways provide otherwise. For military consignments within the meaning of 1.5.2 carried as a full wagon load or as a closed load, packages may be marked with the descriptions prescribed by the competent military authority instead of the proper shipping name. 5.2.1.6 Additional provisions for goods of Class 2 Refillable receptacles shall bear the following particulars in clearly legible and durable characters: (a) the UN number and the proper shipping name of the gas or mixture of gases, as determined in accordance with 3.1.2. In the case of gases classified under an N.O.S. entry, only the technical name1 of the gas has to be indicated in addition to the UN number. In the case of mixtures, not more than the two constituents which most predominantly contribute to the hazards have to be indicated; (b) for compressed gases filled by mass and for liquefied gases, either the maximum filling mass and the tare of the receptacle with fittings and accessories as fitted at the time of filling, or the gross mass; (c) the date (year) of the next periodic inspection. These marks can either be engraved or indicated on a durable information disk or label attached on the receptacle or indicated by an adherent and clearly visible marking such as by printing or by any equivalent process. NOTE 1: See also 6.2.1.7. 2: For non refillable receptacles, see 6.2.1.8. Instead of the technical name the use of one of the following names is permitted: – For UN No. 1078 refrigerant gas, N.O.S.: mixture F1, mixture F2, mixture F3; – For UN No. 1060 methylacetylene and propadiene mixtures, stabilized: mixture P1, mixture P2; – For UN No. 1965 hydrocarbon gas mixture, liquefied, N.O.S.: mixture A or butane, mixture A01 or butane, mixture A02 or butane, mixture A0 or butane, mixture A1, mixture B1, mixture B2, mixture B, mixture C or propane; – For UN No. 1010 Butadienes, stabilized: 1,2-Butadiene, stabilized, 1,3-Butadiene, stabilized. 2006/128. szám 5.2.1.7 Special marking provisions for goods of Class 7 5.2.1.7.1 Each package shall be legibly and durably marked on the outside of the packaging with an identification of either the consignor or consignee, or both. 5.2.1.7.2 For each package, other than excepted packages, the UN number preceded by the letters "UN" and the proper shipping name shall be legibly and durably marked on the outside of the packaging. In the case of excepted packages only the UN number, preceded by the letters "UN", is required. 5.2.1.7.3 Each package of gross mass exceeding 50 kg shall have its permissible gross mass legibly and durably marked on the outside of the packaging. 5.2.1.7.4 Each package which conforms to: (a) a Type IP-1 package, a Type IP-2 package or a Type IP-3 package design shall be legibly and durably marked on the outside of the packaging with "TYPE IP-1", "TYPE IP-2" or "TYPE IP-3" as appropriate; (b) a Type A package design shall be legibly and durably marked on the outside of the packaging with "TYPE A"; (c) a Type IP-2 package, a Type IP-3 package or a Type A package design shall be legibly and durably marked on the outside of the packaging with the international vehicle registration code (VRI Code)2 of the country of origin of design and the name of the manufacturers, or other identification of the packaging specified by the competent authority. 5.2.1.7.5 Each package which conforms to a design approved by the competent authority shall be legibly and durably marked on the outside of the packaging with: (a) the identification mark allocated to that design by the competent authority; (b) a serial number to uniquely identify each packaging which conforms to that design; (c) in the case of a Type B(U) or Type B(M) package design, with "TYPE B(U)" or "TYPE B(M)"; and (d) in the case of a Type C package design, with "TYPE C". 5.2.1.7.6 Each package which conforms to a Type B(U), Type B(M) or Type C package design shall have the outside of the outermost receptacle which is resistant to the effects of fire and water plainly marked by embossing, stamping or other means resistant to the effects of fire and water with the trefoil symbol shown in the figure below. Basic trefoil symbol with proportions based on a central circle of radius X. The minimum allowable size of X shall be 4 mm. 5.2.1.7.7 Where LSA-I or SCO-I material is contained in receptacles or wrapping materials and is carried under exclusive use as permitted by 4.1.9.2.3, the outer surface of these receptacles or wrapping materials may bear the marking "RADIOACTIVE LSA-I" or "RADIOACTIVE SCO-I", as appropriate. Distinguishing sign for motor vehicles in international traffic prescribed in the Vienna Convention on Road Traffic (1968). 2006/128. szám 5.2.2 Labelling of packages NOTE: For labelling purposes, small containers shall be considered as packages. 5.2.2.1 Labelling provisions 5.2.2.1.1 For each article or substance listed in Table A of Chapter 3.2, the labels shown in Column (5) shall be affixed unless otherwise provided for by a special provision in Column (6). 5.2.2.1.2 Indelebile danger markings corresponding exactly to the prescribed models may be used instead of labels. 5.2.2.1.3 - 5.2.2.1.5 (Reserved) 5.2.2.1.6 Except as provided in 5.2.2.2.1.2, each label shall: (a) be affixed to the same surface of the package, if the dimensions of the package allow; for packages of Class1 and 7, near the mark indicating the proper shipping name; (b) be so placed on the package that it is not covered or obscured by any part or attachment to the packaging or any other label or marking; and (c) be displayed next to each other when more than one label is required. Where a package is of such an irregular shape or small size that a label cannot be satisfactorily affixed, the label may be attached to the package by a securely affixed tag or other suitable means. 5.2.2.1.7 Intermediate bulk containers of more than 450 litres capacity shall be labelled on two opposite sides. 5.2.2.1.8 Special requirements for the labelling of packages containing explosive substances or articles when carried as a military consignment For the carriage of military consignments within the meaning of 1.5.2, as a full wagon load or wagon load it shall not be necessary for packages to bear the danger labels prescribed in column (5) of Table A of Chapter 3.2, provided that the mixed loading requirements prescribed in 7.5.2 are observed on the basis of the information in the consignment note, in accordance with 5.4.1.2.1 (f). 5.2.2.1.9 Special provisions for the labelling of self-reactive substances and organic peroxides (a) The label conforming to model No. 4.1 also implies that the product may be flammable and hence no label conforming to model No. 3 is required. In addition, a label conforming to model No. 1 shall be applied for self-reactive substances Type B, unless the competent authority has permitted this label to be dispensed with for a specific packaging because test data have proven that the self-reactive substance in such a packaging does not exhibit explosive behaviour. (b) The label conforming to model No. 5.2 also implies that the product may be flammable and hence no label conforming to model No. 3 is required. In addition, the following labels shall be applied: (i) A label conforming to model No. 1 for organic peroxides type B, unless the competent authority has permitted this label to be dispensed with for a specific packaging because test data have proven that the organic peroxide in such a packaging does not exhibit explosive behaviour; (ii) A label conforming to model No. 8 is required when Packing Group I or II criteria of Class 8 are met. For self-reactive substances and organic peroxides mentioned by name, the labels to be affixed are indicated in the list found in 2.2.41.4 and 2.2.52.4 respectively. 5.2.2.1.10 Special provisions for the labelling of infectious substances packages In addition to the label conforming to model No. 6.2, infectious substances packages shall bear any other label required by the nature of the contents. 5.2.2.1.11 Special provisions for the labelling of radioactive material 5.2.2.1.11.1 Except as provided for large containers and tanks in accordance with 5.3.1.1.3, each package, overpack and container containing radioactive material shall bear at least two labels which conform to the models Nos.7A, 7B, and 7C as appropriate according to the category (see 2.2.7.8.4) of that package, overpack or container. Labels shall be affixed to two opposite sides on the outside of the package or on the outside of all four sides of the container. Each overpack containing radioactive material shall bear at least two labels on opposite sides of the outside of the overpack. In addition, each package, overpack and container containing fissile material, other than fissile material excepted under 6.4.11.2 shall bear labels which conform to model No.7E; such labels, where applicable shall be affixed adjacent to the labels for radioactive material. Labels shall not cover the markings specified in 5.2.1. Any labels which do not relate to the contents shall be removed or covered. 2006/128. szám 5.2.2.1.11.2 Each label conforming to models Nos.7A, 7B, and 7C shall be completed with the following information. (a) Contents: (i) except for LSA-I material, the name(s) of the radionuclide(s) as taken from Table 2.2.7.7.2.1, using the symbols prescribed therein. For mixtures of radionuclides, the most restrictive nuclides shall be listed to the extent the space on the line permits. The group of LSA or SCO shall be shown following the name(s) of the radionuclide(s). The terms "LSA-II", "LSA-III", "SCO-I" and "SCO-II" shall be used for this purpose; (ii) for LSA-I material, only the term "LSA-I" is necessary; the name of the radionuclide is not necessary; (b) Activity: The maximum activity of the radioactive contents during carriage expressed in becquerels (Bq) with the appropriate SI prefix (see 1.2.2.1). For fissile material, the mass of fissile material in grams (g), or multiples thereof, may be used in place of activity; (c) For overpacks and containers the "contents" and "activity" entries on the label shall bear the information required in (a) and (b) above, respectively, totalled together for the entire contents of the overpack or container except that on labels for overpacks or containers containing mixed loads of packages containing different radionuclides, such entries may read "See Consignment Note"; (d) Transport index: see 2.2.7.6.1.1 and 2.2.7.6.1.2 (no transport index entry is required for category I-WHITE). 5.2.2.1.11.3 Each label conforming to the model No. 7E shall be completed with the criticality safety index (CSI) as stated in the certificate of approval for special arrangement or the certificate of approval for the package design issued by the competent authority. 5.2.2.1.11.4 For overpacks and containers, the criticality safety index (CSI) on the label shall bear the information required in 5.2.2.1.11.3 totalled together for the fissile contents of the overpack or container. 5.2.2.1.12 Additional labelling With the exception of Classes 1 and 7, label conforming to model No. 11 illustrated in 5.2.2.2.2 shall be displayed on two opposite sides of a package on the following packages: – packages containing liquids in receptacles, the closures of which are not visible from the outside; – packages containing vented receptacles or vented receptacles without outer packaging; and – packages containing refrigerated liquefied gases. 5.2.2.2 Provisions for labels 5.2.2.2.1 Labels shall satisfy the provisions below and conform, in terms of colour, symbols and general format, to the models shown in 5.2.2.2.2. 5.2.2.2.1.1 Labels, except label conforming to model No. 11, shall be in the form of a square set at an angle of 45° (diamond-shaped) with minimum dimensions of 100 mm by 100 mm. They have a line of the same colour as the symbol, 5 mm inside the edge and running parallel with it. Label conforming to model No. 11 shall be rectangular, of standard format A5 (148 x 210 mm). For receptacles intended for the carriage of refrigerated liquefied gases the standard format of A7 (74 x 105 mm) may also be used. If the size of the package so requires, the dimensions of the labels may be reduced, provided that they remain clearly visible. 5.2.2.2.1.2 Cylinders for Class 2 may, on account of their shape, orientation and securing mechanisms for carriage, bear labels representative of those specified in this section, which have been reduced in size, according to the dimensions outlined in ISO 7225:1994, "Gas cylinders – Precautionary labels", for display on the non-cylindrical part (shoulder) of such cylinders. Notwithstanding the provisions of 5.2.2.1.6, labels may overlap to the extent provided for by ISO 7225. However, in all cases, the primary risk label and the figures appearing on any label shall remain fully visible and the symbols recognizable. 5.2.2.2.1.3 Labels, except label conforming to model No.11, are divided into halves. With the exception of Divisions 1.4, 1.5 and 1.6, the upper half of the label is reserved for the pictorial symbol and the lower half for texts and the class number and the compatibility group letter as appropriate. NOTE: For the labels of Classes 1, 2, 3, 5.1, 5.2, 7, 8 and 9, the respective class number shall be shown in the bottom corner. For the labels of Classes 4.1, 4.2 and 4.3 and of Classes 6.1 and 6.2 only figures 4 and 6 respectively shall be shown in the bottom corner (see 5.2.2.2.2). 5.2.2.2.1.4 Except for Divisions 1.4, 1.5 and 1.6, labels for Class 1 show in the lower half the division number and compatibility group letter for the substance or article. Labels for Divisions 1.4, 1.5 and 1.6 show in the upper half the division number and in the lower half the compatibility group letter. 2006/128. szám 5.2.2.2.1.5 On labels other than those for material of Class 7, the optional insertion of any text (other than the class number) in the space below the symbol shall be confined to particulars indicating the nature of the risk and precautions to be taken in handling. 5.2.2.2.1.6 The symbols, text and numbers shall be clearly legible and indelible and shall be shown in black on all labels except for: (a) the Class 8 label, where the text (if any) and class number shall appear in white; (b) labels with entirely green, red or blue backgrounds where they may be shown in white; and (c) labels conforming to model No. 2.1 displayed on cylinders and gas cartridges for gases UN Nos. 1011, 1075, 1965 and 1978, where they may be shown in the background colour of the receptacle if adequate contrast is provided. 5.2.2.2.1.7 All labels shall be able to withstand open weather exposure without a substantial reduction in effectiveness. 2006/128. szám 2006/128. szám 2006/128. szám 2006/128. szám 2006/128. szám Chapter 5.3 Placarding and marking NOTE: For placarding and marking of containers, MEGCs, tank-containers and portable tanks for carriage in a transport chain including a maritime journey, see also 1.1.4.2.1. 5.3.1 Placarding 5.3.1.1 General provisions 5.3.1.1.1 As and when required in this section, placards shall be affixed to the exterior surface of large containers, MEGCs, tank-containers, portable tanks and wagons. Placards shall correspond to the labels required in Column (5) and, where appropriate, Column (6) of Table A of Chapter 3.2 for the dangerous goods contained in the large container, MEGC, tank-container, portable tank or wagon and shall conform to the specifications given in 5.3.1.7. NOTE: For shunting model labels Nos. 13 and 15, see 5.3.4. 5.3.1.1.2 For Class 1, compatibility groups shall not be indicated on placards if the wagon or large container is carrying substances or articles belonging to two or more compatibility groups. Wagons or large containers carrying substances or articles of different divisions shall bear only placards conforming to the model of the most dangerous division in the order: 1.1 (most dangerous), 1.5, 1.2, 1.3, 1.6, 1.4 (least dangerous). When 1.5 D substances are carried with substances or articles of Division 1.2, the wagon or large container shall be placarded as Division 1.1. Wagons and large containers in which packages are loaded to be carried as military consignments, within the meaning of 1.5.2, and which in conformity with 5.2.2.1.8 do not bear danger labels, shall, in the case of wagons, bear on both sides and, in the case of large containers, bear on all four sides, the placards in accordance with column (5) of Table A of Chapter 3.2. 5.3.1.1.3 For Class 7, the primary risk placard shall conform to model No. 7D as specified in 5.3.1.7.2. This placard is not required for wagons or large containers carrying excepted packages. Where both Class 7 labels and placards would be required to be affixed to wagons, large containers, MEGCs, tank-containers or portable tanks, an enlarged label corresponding to the label required may be displayed instead of placard No.7D to serve both purposes. 5.3.1.1.4 Large containers, MEGCs, tank-containers, portable tanks or wagons containing goods of more than one class need not bear a subsidiary risk placard if the hazard represented by that placard is already indicated by a primary or subsidiary risk placard. 5.3.1.1.5 Placards which do not relate to the dangerous goods being carried, or residues thereof, shall be removed or covered. 5.3.1.2 Placarding of large containers, MEGCs, tank-containers and portable tanks The placards shall be affixed to both sides and at each end of the large container, MEGC, tank-container or portable tank. When the tank-container or portable tank has multiple compartments and carries two or more dangerous goods, the appropriate placards shall be displayed along each side at the position of the relevant compartments and one placard of each model shown on each side at both ends. 5.3.1.3 Placarding of wagons carrying large containers, MEGCs, tank-containers or portable tanks and of wagons used for piggyback transport 5.3.1.3.1 If the placards affixed to the large containers, MEGCs, tank-containers or portable tanks are not visible from outside the carrying wagons, the same placards shall also be affixed to both sides of the wagon. Otherwise, no placard need be affixed on the carrying wagon. 5.3.1.3.2 Carrying wagons used in piggyback transport shall bear the placards on both sides. The placarding of carrying wagons used in piggyback transport is not necessary (a) where use is made of the “rolling road” system (loading of lorries with or without trailer and of semitrailers with tractor on wagons used for this system of transport), unless the railways concerned on a particular route decide to the contrary, and (b) for other carriage of road tank vehicles and road vehicles carrying dangerous goods in bulk. 2006/128. szám 5.3.1.4 Placarding of wagons for carriage in bulk, tank-wagons, battery-wagons and wagons with demountable tanks Placards shall be affixed to both sides. When the tank-wagon or the demountable tank carried on the wagon has multiple compartments and carries two or more dangerous goods, the appropriate placards shall be displayed along each side at the position of the relevant compartments. However, in such case, if all compartments have to bear the same placards, these placards need be displayed only once along each side. Where more than one placard is required for the same compartment, these placards shall be displayed adjacent to each other. 5.3.1.5 Placarding of wagons carrying packages only Placards shall be affixed to both sides. 5.3.1.6 Placarding of empty tank-wagons, battery-wagons, MEGCs, tank-containers, portable tanks and empty wagons and large containers for carriage in bulk Empty tank-wagons, wagons with demountable tanks, battery-wagons, MEGCs, tank-containers and portable tanks uncleaned and not degassed or decontaminated, and empty wagons and large containers for carriage in bulk, uncleaned or not decontaminated, shall continue to display the placards required for the previous load. 5.3.1.7 Specifications for placards 5.3.1.7.1 Except as provided in 5.3.1.7.2 for the Class 7 placard, a placard shall: (a) Be not less than 250 mm by 250 mm, with a line of the same colour as the symbol running 12.5mm inside the edge and parallel with it; (b) Correspond to the label required for the dangerous goods in question with respect to colour and symbol (see 5.2.2.2); and (c) Display the numbers (and for goods of Class 1, the compatibility group letter) prescribed for the dangerous goods in question in 5.2.2.2 for the corresponding label, in digits not less than 25 mm high. The requirements of 5.2.2.1.2 shall also apply. 5.3.1.7.2 The Class 7 placard shall be not less than 250 mm by 250 mm with a black line running 5 mm inside the edge and parallel with it and is otherwise as shown below (Model No. 7D). The number "7" shall not be less than 25 mm high. The background colour of the upper half of the placard shall be yellow and of the lower half white, the colour of the trefoil and the printing shall be black. The use of the word "RADIOACTIVE" in the bottom half is optional to allow the use of this placard to display the appropriate UN number for the consignment. 2006/128. szám Placard for radioactive material of Class 7 (No.7D) Symbol (trefoil): black; Background: upper half yellow with white border, lower half white; The lower half shall show the word "RADIOACTIVE" or alternatively, when required, the appropriate UN Number (see 5.3.2.1.2) and the figure "7" in the bottom corner. 5.3.1.7.3 For tank-containers with a capacity of not more than 3 m3, placards may be replaced by labels conforming to 5.2.2.2. 5.3.1.7.4 The dimensions of the placards to be affixed to wagons may be reduced to 150 mm x 150 mm. In this case, the other dimensions prescribed for the trefoil, lines, figures and letters do not apply. 5.3.2 Orange-coloured plate marking 5.3.2.1 General orange-coloured plate marking provisions 5.3.2.1.1 A rectangular, orange-coloured marking conforming to 5.3.2.2.1 shall be affixed on each side of a – tank-wagon, – battery-wagon, – wagon with demountable tanks, – tank-container, – MEGC, – portable tank, – wagon for carriage in bulk, – small or large container for carriage in bulk, – wagons and containers carrying packaged radioactive material with a single UN number under exclusive use and no other dangerous goods 10 mm MINIMUM 5 mm RADIOACTIVE MINIMUM DIMENSION 250 mm MINIMUM DIMENSION 250 mm 2006/128. szám used for the carriage of goods for which a hazard identification number is given in column (20) of Table A of Chapter 3.2. This marking may also be affixed on both sides of wagon loads made up of packages containing one and the same substance. 5.3.2.1.2 These orange-coloured plates shall bear the hazard identification number and the UN number, in accordance with 5.3.2.2.2, prescribed respectively in columns (20) and (1) of Table A of Chapter 3.2 for the substance carried. 5.3.2.1.3 When a number of different substances are carried in a tank-wagon, battery-wagon, wagon with demountable tank, tank-container, MEGC or portable tank in separate tanks or separate compartments of the same tank, the consignor shall affix the orange-coloured marking as required in 5.3.2.1.1, bearing the appropriate numbers, on each side of the tanks or tank compartments, parallel to the longitudinal axis of the wagon, tank-container or portable tank and so as to be clearly visible. 5.3.2.1.4 The requirements of 5.3.2.1.1 to 5.3.2.1.3 shall be valid also for empty tank-wagons, battery-wagons, wagons with demountable tanks, tank-containers, MEGCs or portable tanks which have not been cleaned, degassed or decontaminated and for empty wagons, large containers and small containers for bulk goods which have not been cleaned or degassed. Once the dangerous substances have been unloaded and the tanks cleaned, degassed or decontaminated, the orange markings shall no longer be visible. 5.3.2.2 Specifications for the orange-coloured plates 5.3.2.2.1 The orange-coloured plates shall be of 40 cm base and of 30 cm high; they shall have a black border of 15 mm wide. The marking shall be affixed by means of a plate, a self-adhesive sheet, paint or any other equivalent process, on condition that the material used for this purpose is weather-resistant and guarantees durable marking. NOTE: The orange colour of the marking in conditions of normal use should have chromaticity co-ordinates lying within the area on the chromaticity diagram formed by joining the following co-ordinates Chromaticity co-ordinates of points at the corners of the area on the chromaticity diagram x y 0,52 0,38 0,52 0,40 0,578 0,422 0,618 0,38 Luminance factor of non- reflectorized colour: ȕ ≥ 0.22, of reflectorized colour: ȕ > 0.12. Reference centre E, standard illuminant C, normal incidence 45°, viewed at 0°. 5.3.2.2.2 The hazard identification number and the UN number shall consist of black digits 100 mm high and of 15 mm stroke thickness. The hazard-identification number shall be inscribed in the upper part of the plate and the UN number in the lower part; they shall be separated by a horizontal black line, 15 mm in stroke width, extending from side to side of the plate at mid-height (see 5.3.2.2.3). 5.3.2.2.3 Example of orange-coloured plate with hazard identification number and UN number Background orange. Border, horizontal line and figures black, 15 mm thickness. Hazard Identification number (2 or 3 figures preceded where appropriate by the letter "X", see 5.3.2.3) UN number (4 figures) 10 cm 10 cm 40 cm 30 cm 10 cm 2006/128. szám 5.3.2.2.4 The permitted tolerances for dimensions specified in this sub-section are ± 10%. 5.3.2.3 Meaning of hazard identification numbers 5.3.2.3.1 The hazard identification number consists of two or three figures. In general, the figures indicate the following hazards: Emission of gas due to pressure or to chemical reaction Flammability of liquids (vapours) and gases or self-heating liquid Flammability of solids or self-heating solid Oxidizing (fire-intensifying) effect Toxicity or risk of infection Radioactivity Corrosivity Risk of spontaneous violent reaction NOTE: The risk of spontaneous violent reaction within the meaning of figure 9 include the possibility following from the nature of a substance of a risk of explosion, disintegration and polymerization reaction following the release of considerable heat or flammable and/or toxic gases. Doubling of a figure indicates an intensification of that particular hazard. Where the hazard associated with a substance can be adequately indicated by a single figure, this is followed by zero. The following combinations of figures, however, have a special meaning: 22, 323, 333, 362, 382, 423, 44, 446, 462, 482, 539, 606, 623, 642, 823, 842, 90 and 99, see 5.3.2.3.2 below. If a hazard identification number is prefixed by the letter "X", this indicates that the substance will react dangerously with water. For such substances, water may only be used by approval of experts. For substances and articles of Class 1, the classification code in accordance with column (3b) of Table A of Chapter 3.2 shall be used as the hazard identification number. The classification code consists of: – the division number in accordance with 2.2.1.1.5 and – the compatibility group letter in accordance with 2.2.1.1.6. 5.3.2.3.2 The hazard identification numbers listed in Column (20) of table A of Chapter3.2 have the following meanings: Asphyxiant gas or gas with no subsidiary risk Refrigerated liquefied gas, asphyxiant Refrigerated liquefied gas, flammable Refrigerated liquefied gas, oxidizing (fire-intensifying) Flammable gas Gas, flammable corrosive Flammable gas, which can spontaneously lead to violent reaction Oxidizing (fire-intensifying) gas Toxic gas Toxic gas, flammable Toxic gas, oxidizing (fire-intensifying) Toxic gas, corrosive Gas, corrosive Gas, corrosive, oxidizing – Flammable liquid (flash-point between 23 °C and 61 °C, inclusive) or – Flammable liquid or solid in the molten state with a flash-point above 61 °C, heated to a temperature equal to or above its flash-point, or – Self-heating liquid Flammable liquid which reacts with water, emitting flammable gases X323 Flammable liquid which reacts dangerously with water, emitting flammable gases3 Highly flammable liquid (flash-point below 23 °C) Pyrophoric liquid X333 Pyrophoric liquid which reacts dangerously with water3 Highly flammable liquid, toxic Highly flammable liquid, corrosive Water not to be used except by approval of experts. 2006/128. szám X338 Highly flammable liquid, corrosive, which reacts dangerously with water3 Highly flammable liquid which can spontaneously lead to violent reaction Flammable liquid (flash-point between 23 °C and 61 °C, inclusive), slightly toxic, or self-heating liquid, toxic Flammable liquid, toxic, which reacts with water, emitting flammable gases X362 Flammable liquid toxic, which reacts dangerously with water, emitting flammable gases3 Flammable liquid, toxic, corrosive Flammable liquid (flash-point between 23 °C and 61 °C, inclusive), slightly corrosive or self-heating liquid, corrosive Flammable liquid, corrosive, which reacts with water, emitting flammable gases X382 Flammable liquid, corrosive, which reacts dangerously with water, emitting flammable gases3 Flammable liquid, which can spontaneously lead to violent reaction Flammable solid, or self-reactive substance, or self-heating substance Solid which reacts with water, emitting flammable gases X423 Flammable solid which reacts dangerously with water, emitting flammable gases3 Spontaneously flammable (pyrophoric) solid Flammable solid, in the molten state at an elevated temperature Flammable solid, toxic, in the molten state, at an elevated temperature Flammable or self-heating solid, toxic Toxic solid which reacts with water, emitting flammable gases X462 Solid which reacts dangerously with water, emitting toxic gases3 Flammable or self-heating solid, corrosive Corrosive solid which reacts with water, emitting flammable gases X482 Solid which reacts dangerously with water, emitting corrosive gases3 Oxidizing (fire-intensifying) substance Flammable organic peroxide Strongly oxidizing (fire-intensifying) substance Strongly oxidizing (fire-intensifying) substance, toxic Strongly oxidizing (fire-intensifying) substance, corrosive Strongly oxidizing (fire-intensifying) substance, which can spontaneously lead to violent reaction Oxidizing substance (fire-intensifying), toxic Oxidizing substance (fire-intensifying), toxic, corrosive Oxidizing substance (fire-intensifying), corrosive Oxidizing substance (fire-intensifying) which can spontaneously lead to violent reaction Toxic or slightly toxic substance Infectious substance Toxic liquid, which reacts with water, emitting flammable gases Toxic substance, flammable (flash-point between 23 °C and 61 °C, inclusive) Toxic substance, flammable (flash-point between 23 °C and 61 °C, inclusive), corrosive Toxic substance, flammable (flash-point not above 61 °C) which can spontaneously lead to violent reaction Toxic solid, flammable or self-heating Toxic solid, which reacts with water, emitting flammable gases Toxic substance, oxidizing (fire-intensifying) Highly toxic substance Highly toxic substance, flammable (flash-point not above 61 °C) Highly toxic solid, flammable or self-heating Highly toxic substance, oxidizing (fire-intensifying) Highly toxic substance, corrosive Highly toxic substance which can spontaneously lead to violent reaction Toxic substance, corrosive Toxic or slightly toxic substance, which can spontaneously lead to violent reaction Radioactive material Radioactive material, corrosive Corrosive or slightly corrosive substance X80 Corrosive or slightly corrosive substance, which reacts dangerously with water3 Corrosive liquid which reacts with water, emitting flammable gases Corrosive or slightly corrosive substance, flammable (flash-point between 23 °C and 61 °C, inclusive) X83 Corrosive or slightly corrosive substance, flammable (flash-point between 23 °C and 61 °C, inclusive), which reacts dangerously with water3 Corrosive or slightly corrosive substance, flammable (flash-point between 23 °C and 61 °C inclusive) which can spontaneously lead to violent reaction X839 Corrosive or slightly corrosive substance, flammable (flash-point between 23 °C and 61 °C inclusive), which can spontaneously lead to violent reaction and which reacts dangerously with water3 2006/128. szám Corrosive solid, flammable or self-heating Corrosive solid which reacts with water, emitting flammable gases Corrosive or slightly corrosive substance, oxidizing (fire-intensifying) Corrosive or slightly corrosive substance, oxidizing (fire-intensifying) and toxic Corrosive or slightly corrosive substance, toxic Highly corrosive substance X88 Highly corrosive substance, which reacts dangerously with water3 Highly corrosive substance, flammable (flash-point between 23 °C and 61 °C inclusive) Highly corrosive solid, flammable or self-heating Highly corrosive substance, oxidizing (fire-intensifying) Highly corrosive substance, toxic X886 Highly corrosive substance, toxic, which reacts dangerously with water3 Corrosive or slightly corrosive substance, which can spontaneously lead to violent reaction Environmentally hazardous substance; miscellaneous dangerous substances Miscellaneous dangerous substance carried at an elevated temperature. 5.3.3 Mark for elevated temperature substances Tank-wagons, tank-containers, portable tanks, special wagons or large containers or especially equipped wagons or large containers for which a mark for elevated temperature substances is required according to special provision 580 in Column (6) of Table A of Chapter 3.2 shall bear on both sides for wagons, and on both sides and at each end for large containers, tank-containers and portable tanks, a triangular shaped mark with sides of at least 250 mm, to be shown in red, as reproduced below. 2006/128. szám 5.3.4 Shunting labels conforming to Models 13 and 15 5.3.4.1 General provisions The general provisions of 5.3.1.1.1 and 5.3.1.1.5 and of 5.3.1.3 to 5.3.1.6 shall also apply to the shunting labels conforming to models Nos. 13 and 15. Instead of the shunting labels, indelible marking corresponding exactly to the prescribed models may be affixed. This may simply consist of the red triangle with a black exclamation mark (at least 100 mm base by 70 mm height). 5.3.4.2 Description of shunting labels conforming to Models 13 and 15 The shunting labels conforming to Models 13 and 15 shall have the shape of a rectangle not smaller than A7 format (74 mm x 105 mm). No. 13 Shunt with care No. 15 Loose shunting or hump shunting forbidden. Shall be accompanied by a motive power unit. Shall not bump, or be bumped by, other wagons. red triangle with an exclamation mark in black on white background three triangles, red, with black exclamation mark 5.3.5 Orange band Tank wagons intended for the carriage of liquefied, refrigerated liquefied or dissolved gases shall be marked with an unbroken, orange4, non-reflectorized band, about 30cm wide, encircling the shell at midheight. See 5.3.2.2.1 NOTE. 2006/128. szám Chapter 5.4 Documentation 5.4.0 Any carriage of goods governed by RID shall be accompanied by the documentation prescribed in this Chapter, as appropriate, unless exempted under 1.1.3.1 to 1.1.3.5. NOTE: The use of electronic data processing (EDP) or electronic data interchange (EDI) techniques as an aid to or instead of paper documentation is permitted, provided that the procedures used for the capture, storage and processing of electronics data meet the legal requirements as regards the evidential value and availability of data during transport in a manner at least equivalent to that of paper documentation. 5.4.1 Dangerous goods consignment note and related information NOTE: Consignment note shall mean the consignment note in accordance with the Contract of Carriage or another transport document meeting the provisions of this section. 5.4.1.1 General information required in the consignment note 5.4.1.1.1 Next to the cross to be entered in the appropriate box, the consignment note(s) shall contain the following information for each dangerous substance, material or article handed over for carriage, (a) the UN number preceded by the letters "UN"; (b) the proper shipping name supplemented, when applicable (see 3.1.2.8.1) with the technical name (see 3.1.2.8.1.1), as determined in accordance with 3.1.2; (c) – for substances and articles of Class 1: the classification code given in Column (3 b) of Table A in Chapter 3.2. When, in Column (5) of Table A of Chapter 3.2, label model numbers other than 1, 1.4, 1.5, 1.6, 13 or 15 are given, these label model numbers, in brackets, shall follow the classification code; – for radioactive material of Class 7: the Class number "7"; – for substances and articles of other classes: the label model numbers, apart from 13, given in Column (5) of Table A in Chapter 3.2. When more than one label model numbers are given, the numbers following the first one shall be given in brackets. For substances and articles for which no label model is given in Column (5) of Table A in Chapter 3.2, their class according to Column (3a) shall be given instead; (d) where assigned, the packing group for the substance which may be preceded by the letters "PG" (e.g. "PG II"), or the initials corresponding to the words "Packing Group" in the languages used according to 5.4.1.4.1; NOTE: For radioactive material of Class 7 with subsidiary risks, see special provision 172 (b) in Chapter 3.3. (e) the number and a description of the packages (see also CIM Article 7 § 1 (h) and (i)); (f) with the exception of empty means of containment, uncleaned, the total quantity of each type of dangerous goods bearing a different UN number, proper shipping name or packing group (as a volume or as a gross mass, or as a net mass as appropriate); (g) the name and address of the consignor (see also CIM Article 7 § 1 (b)); (h) the name and address of the consignee(s) (see also CIM Article 7 § 1 (g)); (i) a declaration as required by the terms of any special agreement; (j) when a marking in accordance with 5.3.2.1 is prescribed, the hazard identification number shall also be inscribed before the UN number. The hazard identification number shall also be shown where full wagon loads made up of packages containing one and the same substance are marked in accordance with 5.3.2.1. The location and order in which the elements of information required appear in the consignment note is left optional, except that (a), (b), (c) and (d) shall be shown either in sequence (a), (b), (c), (d) or in sequence (b), (c), (a,) (d) with no information interspersed, except as provided in RID. Examples of such permitted dangerous goods descriptions are: "UN 1098 ALLYL ALCOHOL, 6.1 (3), I" or "ALLYL ALCOHOL, 6.1 (3), UN 1098, I" When a marking in accordance with 5.3.2.1 is required, (a), (b), (c), (d), and (j) shall be shown in the sequence (j), (a), (b), (c), (d) or in the order (b), (c), (j), (a), (d) with no information interspersed, except as provided in RID. 2006/128. szám Examples of such permitted dangerous goods descriptions taking account of the marking in accordance with 5.3.2.1 are: “663, UN 1098 ALLYL ALCOHOL, 6.1(3), I” or “ALLYL ALCOHOL, 6.1(3), 663, UN 1098, I”. 5.4.1.1.2 The information required on a consignment note shall be legible. Although upper case is used in Chapter 3.1 and in Table A in Chapter 3.2 to indicate the elements which shall be part of the proper shipping name, and although upper and lower case are used in this Chapter to indicate the information required in the consignment note, the use of upper or of lower case for entering the information in the consignment note is left optional. 5.4.1.1.3 Special provisions for wastes If waste containing dangerous goods (other than radioactive wastes) is being carried, the UN number and the proper shipping name shall be preceded by the word "WASTE", unless this term is part of the proper shipping name, e.g. – "WASTE, UN 1230 METHANOL, 3 (6.1), II" or – "WASTE, METHANOL, 3 (6.1), UN 1230, II" or – "WASTE, UN 1993 FLAMMABLE LIQUID, N.O.S. (toluene and ethyl alcohol), 3, II" or – "WASTE, FLAMMABLE LIQUID, N.O.S. (toluene and ethyl alcohol), 3, UN 1993, II". 5.4.1.1.4 Special provisions for dangerous goods packed in limited quantities No information is required in the consignment note, if any, for carriage of dangerous goods packed in limited quantities according to Chapter 3.4. 5.4.1.1.5 Special provisions for salvage packagings When dangerous goods are carried in a salvage packaging, the words "SALVAGE PACKAGE" shall be added after the description of the goods in the consignment note. 5.4.1.1.6 Special provisions for empty uncleaned means of containment 5.4.1.1.6.1 For empty packagings, uncleaned, which contain the residue of dangerous goods of classes other than Class 7 including empty uncleaned receptacles for gases with a capacity of not more than 1000 litres, the description in the consignment note shall be "EMPTY PACKAGING", "EMPTY RECEPTACLE", "EMPTY IBC", "EMPTY LARGE PACKAGING", as appropriate, followed by the information of the goods last loaded, as described in 5.4.1.1.1 (c). See example as follows: "EMPTY PACKAGING, 6.1 (3)". 5.4.1.1.6.2 For empty means of containment other than packagings, uncleaned, which contain the residue of dangerous goods of classes other than Class 7 and for empty uncleaned receptacles for gases with a capacity of more than 1000 litres, the description in the consignment note shall be "EMPTY TANK-WAGON", "EMPTY TANK-VEHICLE", "EMPTY DEMOUNTABLE TANK", "EMPTY BAT- TERY-WAGON", "EMPTY BATTERY-VEHICLE", "EMPTY PORTABLE TANK", "EMPTY TANK- CONTAINER", "EMPTY MEGC", "EMPTY WAGON", "EMPTY VEHICLE", "EMPTY CONTAINER", "EMPTY RECEPTACLE", followed by the words "LAST LOAD" together with the information of the goods last loaded, as prescribed in 5.4.1.1.1 (a) to (d) and (j) in one of the sequences as prescribed. See examples as follows: "EMPTY TANK-WAGON, LAST LOAD: 663 UN 1098 ALLYLALCOHOL, 6.1 (3), I" or "EMPTY TANK-WAGON, LAST LOAD: ALLYLALCOHOL, 6.1 (3), 663, UN 1098, I". 5.4.1.1.6.3 If empty uncleaned tank-wagons, empty uncleaned battery-wagons, empty uncleaned demountable tanks, empty uncleaned portable tanks, empty uncleaned tank-containers, empty uncleaned MEGCs, empty uncleaned wagons and empty uncleaned containers as well as empty tank-vehicle(s), uncleaned, empty demountable tank(s), uncleaned, and/or empty battery-vehicle(s), uncleaned, carried in piggyback transport in accordance with 1.1.4.4, for the carriage of goods in bulk are carried to the nearest suitable place for cleaning or repair, the consignment note shall also contain the following: "CARRIAGE IN ACCORDANCE WITH 4.3.2.4.3" or "CARRIAGE IN ACCORDANCE WITH 7.5.8.1". 2006/128. szám 5.4.1.1.7 Special provisions for carriage in a transport chain including maritime or air carriage5 For carriage in accordance with 1.1.4.2.1, a statement shall be included in the consignment note, as follows: "CARRIAGE IN ACCORDANCE WITH 1.1.4.2.1". 5.4.1.1.8 (Reserved) 5.4.1.1.9 Special provisions for piggyback transport For the carriage of tanks or dangerous goods in bulk which, in accordance with ADR 5.3.2.1.4 to 5.3.2.1.6, must bear plates, the hazard identification number shall also be entered in the consignment note before the name of the goods. The instruction in writing prescribed in ADR 5.4.3 shall be attached to the consignment note. 5.4.1.1.10 (Reserved) 5.4.1.1.11 Special provisions for the carriage of IBCs after the date of expiry of the last periodic test inspection For carriage in accordance with 4.1.2.2, a statement to this effect shall be included in the consignment note, as follows: "CARRIAGE IN ACCORDANCE WITH 4.1.2.2". 5.4.1.1.12 Special provisions for carriage in accordance with transitional requirements For carriage in accordance with 1.6.1.1, a statement shall be included in the consignment note, as follows: "CARRIAGE IN ACCORDANCE WITH RID IN FORCE BEFORE 1 JANUARY 2005". 5.4.1.1.13 (Reserved) 5.4.1.1.14 Special provisions for the carriage of substances carried under elevated temperature If the proper shipping name of a substance which is carried or offered for carriage in a liquid state at a temperature equal to or exceeding 100 °C, or in a solid state at a temperature equal to or exceeding 240 °C, does not convey the elevated temperature condition (for example, by using the term "MOLTEN" or "ELE- VATED TEMPERATURE" as part of the proper shipping name), the word "HOT" shall immediately precede the proper shipping name. 5.4.1.1.15 (Reserved) 5.4.1.1.16 Information required in accordance with special provision 640 in Chapter 3.3 Where it is required by special provision 640 of Chapter 3.3, the consignment note shall bear the inscription "SPECIAL PROVISION 640X" where "X" is the capital letter appearing after the pertinent reference to special provision 640 in column (6) of Table A of Chapter 3.2. 5.4.1.1.17 Special provisions for the carriage of solids in bulk containers conforming to 6.11.4 When solid substances are carried in bulk containers conforming to 6.11.4, the following statement shall be shown in the consignment note (see Note at the beginning of 6.11.4): "BULK CONTAINER BK(X) APPROVED BY THE COMPETENT AUTHORITY OF …". For carriage in a transport chain including maritime or air carriage, a copy of the documentation (e.g. form for the multimodal transport of dangerous goods in accordance with 5.4.4) prescribed for maritime or air carriage may be attached to the consignment note. These documents shall be the same size as the consignment note. If the form for the multimodal transport of dangerous goods in accordance with 5.4.4 is attached to the consignment note, the information concerning the dangerous goods already contained on this form need not be shown in the consignment note, but a reference to this supplementary sheet shall be entered in the appropriate box on the consignment note. 2006/128. szám 5.4.1.2 Additional or special information required for certain classes 5.4.1.2.1 Special provisions for Class 1 (a) For wagon loads or full wagon loads, the consignment note shall indicate the number of packages, the mass of each package in kg and the total net mass in kg of explosive substance. In addition to the information in accordance with 5.4.1.1.1 (f), the consignment note shall indicate the net mass in kg of explosive substance; (b) For mixed packing of two different goods, the description of the goods in the consignment note shall include the UN numbers and names printed in capitals in Columns (1) and (2) of Table A of Chapter 3.2 of both substances or articles. If more than two different goods are contained in the same package in conformity with the mixed packing provisions given in 4.1.10 special provisions MP1, MP2 and MP20 to MP24, the consignment note shall indicate under the description of the goods the UN numbers of all the substances and articles contained in the package, in the form, "GOODS OF UN NOS ..."; (c) For the carriage of substances and articles assigned to an n.o.s. entry or the entry "0190 SAMPLES, EXPLOSIVE" or packed conforming to packing instruction P101 of 4.1.4.1, a copy of the competent authority approval with the conditions of carriage shall be attached to the consignment note. It shall be in an official language of the forwarding country and also, if that language is not French, German, Italian or English, in French, German, Italian or English, unless international tariffs or agreements between the railways provide otherwise; (d) If packages containing substances and articles of compatibility groups B and D are loaded together in the same wagon in accordance with the requirements of 7.5.2.2, the approval certificate of the protective compartment or containment system in accordance with 7.5.2.2, footnote (a) under the table, shall be attached to the consignment note; (e) When explosive substances or articles are carried in packagings conforming to packing instruction P101, the consignment note shall bear the inscription "PACKAGING APPROVED BY THE COMPE- TENT AUTHORITY OF (indication of the state (distinguishing sign of the states for motor vehicles in international traffic), on whose behalf the competent authority is acting)" (see 4.1.4.1, packing instruction P101); (f) In the case of military consignments within the meaning of 1.5.2, the descriptions prescribed by the competent military authority may be used in place of the descriptions in accordance with Table A of Chapter 3.2. For the carriage of military consignments to which the derogations in accordance with 5.2.1.5, 5.2.2.1.8 and 5.3.1.1.2 and in 7.2.4, special provision W2, the following shall be entered in the consignment note: "MILITARY CONSIGNMENT". (g) When fireworks of UN Nos. 0333, 0334, 0335, 0336 and 0337 are carried, the consignment note shall bear the inscription: "CLASSIFICATION RECOGNIZED BY THE COMPETENT AUTHORITY OF ... (State referred to in special provision 645 of 3.3.1)". NOTE: The commercial or technical name of the goods may be entered additionally to the proper shipping name in the consignment note. 5.4.1.2.2 Additional provisions for Class 2 (a) For the carriage of mixtures (see 2.2.2.1.1) in tank-wagons, battery-wagons, wagons with demountable tanks, portable tanks, tank-containers or MEGCs, the composition of the mixture as a percentage of the volume or as a percentage of the mass shall be given. Constituents below 1% need not be indicated (see also 3.1.2.8.1.2); (b) For the carriage of cylinders, tubes, pressure drums, cryogenic receptacles and bundles of cylinders under the conditions of 4.1.6.10, the following entry shall be included in the consignment note: "CARRIAGE IN ACCORDANCE WITH 4.1.6.10". (c) Where tank-wagons have been refilled without having been previously cleaned out, the consignment note shall show, as total weight of goods carried, the sum of the weight of the new load and of the residual load, which will be the same as the gross weight of the tank-wagon, less its registered unladen weight. In addition, the words "MASS WHEN FILLED ... KG" may also be added. (d) In the case of tank-wagons and tank-containers containing refrigerated liquefied gases, the consignor shall enter in the consignment note: “The tank is guaranteed as insulated in order that the valves cannot open before ... (date accepted by the railway)”. 2006/128. szám 5.4.1.2.3 Additional provisions for self-reactive substances of Class 4.1 and organic peroxides of Class 5.2 5.4.1.2.3.1 (Reserved) 5.4.1.2.3.2 When for certain self-reactive substances of Class 4.1 and certain organic peroxides of Class 5.2 the competent authority has permitted the label conforming to model No.1 to be dispensed with for a specific packaging (see 5.2.2.1.9), a statement to this effect shall be included in the consignment note, as follows: "THE LABEL CONFORMING TO MODEL NO.1 IS NOT REQUIRED". 5.4.1.2.3.3 When organic peroxides and self-reactive substances are carried under conditions where approval is required (for organic peroxides see 2.2.52.1.8, 4.1.7.2.2 and special provision TA2 of 6.8.4; for self-reactive substances see 2.2.41.1.13 and 4.1.7.2.2, a statement to his effect shall be included in the consignment note, e.g. "CARRIAGE IN ACCORDANCE WITH 2.2.52.1.8". A copy of the approval of the competent authority with the conditions of carriage shall be attached to the consignment note. 5.4.1.2.3.4 When a sample of an organic peroxide (see 2.2.52.1.9) or a self-reactive substance (see 2.2.41.1.15) is carried, a statement to this effect shall be included in the consignment note, e.g. "CARRIAGE IN ACCORDANCE WITH 2.2.52.1.9". 5.4.1.2.3.5 When self-reactive substances type G (see Manual of Tests and Criteria, Part II, paragraph 20.4.2 (g)) are carried, the following statement may be given in the consignment note: "NOT A SELF-REACTIVE SUBSTANCE OF CLASS 4.1". When organic peroxides type G (see Manual of Tests and Criteria, Part II, paragraph 20.4.3 (g)) are carried, the following statement may be given in the consignment note: "NOT A SUBSTANCE OF CLASS 5.2". 5.4.1.2.4 Additional provisions for Class 6.2 In addition to the information concerning the consignee (see 5.4.1.1.1 (h)), the name and telephone number of a responsible person shall be indicated. 5.4.1.2.5 Additional provisions for Class 7 5.4.1.2.5.1 The following information shall be inserted in the consignment note for each consignment of Class 7 material, as applicable, in the order given and immediately after the information required under 5.4.1.1.1 (a) to (c): (a) The name or symbol of each radionuclide or, for mixtures of radionuclides, an appropriate general description or a list of the most restrictive nuclides; (b) A description of the physical and chemical form of the material, or a notation that the material is special form radioactive material or low dispersible radioactive material. A generic chemical description is acceptable for chemical form. For radioactive material with a subsidiary risk, see last sentence of special provision 172 of Chapter 3.3; (c) The maximum activity of the radioactive contents during carriage expressed in becquerels (Bq) with an appropriate SI prefix (see 1.2.2.1). For fissile material, the mass of fissile material in grams (g), or appropriate multiples thereof, may be used in place of activity; (d) The category of the package, i.e. I-WHITE, II-YELLOW, III-YELLOW; (e) The transport index (categories II-YELLOW and III-YELLOW only); (f) For consignments including fissile material other than consignments excepted under 6.4.11.2, the criticality safety index; (g) The identification mark for each competent authority approval certificate (special form radioactive material, low dispersible radioactive material, special arrangement, package design, or shipment) applicable to the consignment; (h) For consignments of more than one package, the information required in 5.4.1.1.1 and in (a) to (g) above shall be given for each package. For packages in an overpack, container or wagon, a detailed statement of the contents of each package within the overpack, container or wagon and, where appropriate, of each overpack, container or wagon shall be included. If packages are to be removed from the overpack, container or wagon at a point of intermediate unloading, appropriate consignment notes shall be made available; (i) Where a consignment is required to be shipped under exclusive use, the statement "EXCLUSIVE USE SHIPMENT"; and 2006/128. szám (j) For LSA-II and LSA-III substances, SCO-I and SCO-II, the total activity of the consignment as a multiple of A2. 5.4.1.2.5.2 The consignor shall provide in the consignment note a statement regarding actions, if any, that are required to be taken by the carrier. The statement shall be in the languages deemed necessary by the carrier or the authorities concerned, and shall include at least the following information: (a) Supplementary requirements for loading, stowage, carriage, handling and unloading of the package, overpack or container including any special stowage provisions for the safe dissipation of heat (see special provision CW33 (3.2) of 7.5.11), or a statement that no such requirements are necessary; (b) Restrictions on the mode of carriage or wagon and any necessary routeing instructions; (c) Emergency arrangements appropriate to the consignment. 5.4.1.2.5.3 The applicable competent authority certificates need not necessarily accompany the consignment. The consignor shall make them available to the carrier(s) before loading and unloading. 5.4.1.3 (Reserved) 5.4.1.4 Format and language to be used 5.4.1.4.1 The consignment note shall be filled out in one or more languages, one of which shall be French, German or English. 5.4.1.4.2 A separate consignment note shall be made out for consignments which, because of the prohibitions in 7.5.2, may not be loaded together in the same wagon or container. In addition to the consignment note, for multimodal carriage, the use of documents corresponding to the example shown in 5.4.4 is considered advisable6. 5.4.1.5 Non-dangerous goods When goods mentioned by name in Table A of Chapter 3.2, are not subject to RID because they are considered as non-dangerous according to Part 2, the consignor may enter in the consignment note a statement to that effect, e.g.: "NOT GOODS OF CLASS ...". NOTE: This provision may be used in particular when the consignor considers that, due to the chemical nature of the goods (e.g. solutions and mixtures) carried or to the fact that such goods are deemed dangerous for other regulatory purposes the consignment might be subject to control during the journey. 5.4.2 Container packing certificate If the carriage of dangerous goods in a large container precedes a voyage by sea, a container packing certificate conforming to section 5.4.2 of the IMDG Code7 shall be provided with the consignment note8. If used, the relevant recommendations of the UN/ECE Working Party on Facilitation of International Trade Procedures may be consulted, in particular Recommendation No.1 (United Nations Lay-out Key for Trade Documents) (ECE/TRADE/137, edition 96.1), Recommendation No.11 (Documentary Aspects of the International Transport of Dangerous Goods) ECE/TRADE/204,edition 96.1) and Recommendation No.22 (Lay-out Key for standard Consignment Instructions) (ECE/TRADE/168, edition 96.1). Refer to the Trade Data Elements Directory, Volume III, Trade Facilitation Recommendations (ECE/TRADE/200) (United Nations publication Sales No.E.96.II.E.13). Guidelines for use in practice and in training for loading goods in transport units have also been drawn up by the International Maritime Organization (IMO), the International Labour Organization (ILO) and the United Nations Economic Commission for Europe (UN/ECE) and have been published by IMO ("IMO/ILO/UN-ECE Guidelines for Packing of Cargo Transport Units (CTUs)"). Section 5.4.2 of the IMDG Code requires the following: "5.4.2 Container/vehicle packing certificate 5.4.2.1 When dangerous goods are packed or loaded into any container or vehicle, those responsible for packing the container or vehicle shall provide a “container/vehicle packing certificate” specifying the container/vehicle identification number(s) and certifying that the operation has been carried out in accordance with the following conditions: .1 The container/vehicle was clean, dry and apparently fit to receive the goods; 2006/128. szám The functions of the consignment note required under 5.4.1 and of the container packing certificate as provided above may be incorporated into a single document; if not, these documents shall be attached one to the other. If these functions are incorporated into a single document, the inclusion in the consignment note of a statement that the loading of the container has been carried out in accordance with the applicable modal regulations together with the identification of the person responsible for the container packing certificate shall be sufficient. NOTE: The container packing certificate is not required for portable tanks, tank-containers and MEGCs. 5.4.3 (Reserved) 5.4.4 Example of a multimodal dangerous goods form Example of a form which may be used as a combined dangerous goods declaration and container packing certificate for multimodal carriage of dangerous goods. .2 Packages, which need to be segregated in accordance with applicable segregation requirements, have not been packed together onto or in the container/vehicle [unless approved by the competent authority concerned in accordance with 7.2.2.3 (of the IMDG Code)]; .3 All packages have been externally inspected for damage, and only sound packages have been loaded; .4 Drums have been stowed in an upright position, unless otherwise authorized by the competent authority, and all goods have been properly loaded, and, where necessary, adequately braced with securing material to suit the mode(s) of transport for the intended journey; .5 Goods loaded in bulk have been evenly distributed within the container/vehicle; .6 For consignments including goods of class 1, other than division 1.4, the container/vehicle is structurally serviceable in conformity with 7.4.6 (of the IMDG Code); .7 The container/vehicle and packages are properly marked, labelled, and placarded, as appropriate; .8 When solid carbon dioxide (CO2-dry ice) is used for cooling purposes, the container/vehicle is externally marked or labelled in a conspicuous place, such as, at the door end, with the words: "DANGEROUS CO2 GAS (DRY ICE) INSIDE. VENTILATE THO- ROUGHLY BEFORE ENTERING”; and .9 A dangerous goods transport document, as indicated in 5.4.1 (of the IMDG Code) has been received for each dangerous goods consignment loaded in the container/vehicle. NOTE: The container/vehicle packing certificate is not required for tanks. 5.4.2.2 The information required in the dangerous goods transport document and the container/vehicle packing certificate may be incorporated into a single document; if not, these documents shall be attached one to the other. If the information is incorporated into a single document, the document shall include a signed declaration such as “It is declared that the packing of the goods into the container/vehicle has been carried out in accordance with the applicable provisions". This declaration shall be dated and the person signing this declaration shall be identified on the document. " 2006/128. szám MULTIMODAL DANGEROUS GOODS FORM (right edge black hatchings)

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