page_title: Perovskite solar cell
section_title: Deposition methods
hierarchical_section_title: Perovskite solar cell / Processing / Deposition methods
caption_attribution_description: English: (a) One-step solution deposition; (b) Two-step solution deposition
context_page_description: A perovskite solar cell is a type of solar cell which includes a perovskite structured compound, most commonly a hybrid organic-inorganic lead or tin halide-based material, as the light-harvesting active layer. Perovskite materials, such as methylammonium lead halides and all-inorganic cesium lead halide, are cheap to produce and simple to manufacture.
  Solar cell efficiencies of devices using these materials have increased from 3.8% in 2009 to 25.2% in 2020 in single-junction architectures, and, in silicon-based tandem cells, to 29.1%, exceeding the maximum efficiency achieved in single-junction silicon solar cells. Perovskite solar cells are therefore currently the fastest-advancing solar technology. With the potential of achieving even higher efficiencies and very low production costs, perovskite solar cells have become commercially attractive.
context_section_description: The solution-based processing method can be classified into one-step solution deposition and two-step solution deposition. In one-step deposition, a perovskite precursor solution that is prepared by mixing lead halide and organic halide together, is directly deposited through various coating methods, such as spin coating, spraying, blade coating, and slot-die coating, to form perovskite film. One-step deposition is simple, fast, and inexpensive but it’s also more challenging to control the perovskite film uniformity and quality. In the two-step deposition, the lead halide film is first deposited then reacts with organic halide to form perovskite film. The reaction takes time to complete but it can be facilitated by adding Lewis-bases or partial organic halide into lead halide precursors. In two-step deposition method, the volume expansion during the conversion of lead halide to perovskite can fill any pinholes to realize a better film quality. The vapor phase deposition processes can be categorized into physical vapor deposition (PVD) and chemical vapor deposition (CVD). PVD refers to the evaporation of a perovskite or its precursor to form a thin perovskite film on the substrate, which is free of solvent. While CVD involves the reaction of organic halide vapor with the lead halide thin film to convert it into the perovskite film. A solution-based CVD, aerosol-assisted CVD (AACVD) was also introduced to fabricate halide perovskite films, such as CH₃NH₃PbI₃, CH₃NH₃PbBr₃, and Cs₂SnI₆.
caption: One-step solution deposition vs two-step solution deposition
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