page_title: Ruby
section_title: Physical properties
hierarchical_section_title: Ruby / Physical properties
caption_attribution_description: Deutsch: Kristallstruktur von Korund English: Crystal structure of corundum
context_page_description: A ruby is a pink to blood-red coloured gemstone, a variety of the mineral corundum. Other varieties of gem-quality corundum are called sapphires. Ruby is one of the traditional cardinal gems, together with amethyst, sapphire, emerald, and diamond. The word ruby comes from ruber, Latin for red. The color of a ruby is due to the element chromium.
  Some gemstones that are popularly or historically called rubies, such as the Black Prince's Ruby in the British Imperial State Crown, are actually spinels. These were once known as "Balas rubies".
  The quality of a ruby is determined by its color, cut, and clarity, which, along with carat weight, affect its value. The brightest and most valuable shade of red called blood-red or pigeon blood, commands a large premium over other rubies of similar quality. After color follows clarity: similar to diamonds, a clear stone will command a premium, but a ruby without any needle-like rutile inclusions may indicate that the stone has been treated. Ruby is the traditional birthstone for July and is usually pinker than garnet, although some rhodolite garnets have a similar pinkish hue to most rubies.
context_section_description: Rubies have a hardness of 9.0 on the Mohs scale of mineral hardness. Among the natural gems only moissanite and diamond are harder, with diamond having a Mohs hardness of 10.0 and moissanite falling somewhere in between corundum (ruby) and diamond in hardness. Sapphire, ruby, and pure corundum are α-alumina, the most stable form of Al₂O₃, in which 3 electrons leave each aluminium ion to join the regular octahedral group of six nearby O²⁻ ions; in pure corundum this leaves all of the aluminium ions with a very stable configuration of no unpaired electrons or unfilled energy levels, and the crystal is perfectly colorless.
  When a chromium atom replaces an occasional aluminium atom, it too loses 3 electrons to become a chromium³⁺ ion to maintain the charge balance of the Al₂O₃ crystal.  However, the Cr³⁺ ions are larger and have electron orbitals in different directions than aluminium. The octahedral arrangement of the O²⁻ ions is distorted, and the energy levels of the different orbitals of those Cr³⁺ ions are slightly altered because of the directions to the O²⁻ ions. Those energy differences correspond to absorption in the ultraviolet, violet, and yellow-green regions of the spectrum.
  If one percent of the aluminium ions are replaced by chromium in ruby, the yellow-green absorption results in a red color for the gem.  Additionally, absorption at any of the above wavelengths stimulates fluorescent emission of 694-nanometer-wavelength red light, which adds to its red color and perceived luster.
  After absorbing short-wavelength light, there is a short interval of time when the crystal lattice of ruby is in an excited state before fluorescence occurs. If 694-nanometer photons pass through the crystal during that time, they can stimulate more fluorescent photons to be emitted in-phase with them, thus strengthening the intensity of that red light. By arranging mirrors or other means to pass  emitted light repeatedly through the crystal, a ruby laser in this way produces a very high intensity of coherent red light.
  All natural rubies have imperfections in them, including color impurities and inclusions of rutile needles known as "silk". Gemologists use these needle inclusions found in natural rubies to distinguish them from synthetics, simulants, or substitutes. Usually, the rough stone is heated before cutting. These days, almost all rubies are treated in some form, with heat treatment being the most common practice. Untreated rubies of high quality command a large premium.
  Some rubies show a three-point or six-point asterism or "star". These rubies are cut into cabochons to display the effect properly. Asterisms are best visible with a single-light source and move across the stone as the light moves or the stone is rotated. Such effects occur when light is reflected off the "silk" (the structurally oriented rutile needle inclusions) in a certain way. This is one example where inclusions increase the value of a gemstone. Furthermore, rubies can show color changes—though this occurs very rarely—as well as chatoyancy or the "cat's eye" effect.
caption: Crystal structure of rubies
exif: {}