page_title: Oil refinery
section_title: Corrosion
hierarchical_section_title: Oil refinery / Corrosion
caption_attribution_description: Bidboland gas refinery Aghajary Iran
context_page_description: An oil refinery or petroleum refinery is an industrial process plant where crude oil is transformed and refined into more useful products such as petroleum naphtha, gasoline, diesel fuel, asphalt base, heating oil, kerosene, liquefied petroleum gas, jet fuel and fuel oils. Petrochemicals feed stock like ethylene and propylene can also be produced directly by cracking crude oil without the need of using refined products of crude oil such as naphtha.
  Oil refineries are typically large, sprawling industrial complexes with extensive piping running throughout, carrying streams of fluids between large chemical processing units, such as distillation columns. In many ways, oil refineries use much of the technology, and can be thought of, as types of chemical plants.
  The crude oil feedstock has typically been processed by an oil production plant. There is usually an oil depot at or near an oil refinery for the storage of incoming crude oil feedstock as well as bulk liquid products.
  Petroleum refineries are very large industrial complexes that involve many different processing units and auxiliary facilities such as utility units and storage tanks.
context_section_description: Corrosion of metallic components is a major factor of inefficiency in the refining process. Because it leads to equipment failure, it is a primary driver for the refinery maintenance schedule. Corrosion-related direct costs in the U.S. petroleum industry as of 1996 were estimated at US$3.7 billion.
  Corrosion occurs in various forms in the refining process, such as pitting corrosion from water droplets, embrittlement from hydrogen, and stress corrosion cracking from sulfide attack. From a materials standpoint, carbon steel is used for upwards of 80 per cent of refinery components, which is beneficial due to its low cost. Carbon steel is resistant to the most common forms of corrosion, particularly from hydrocarbon impurities at temperatures below 205 °C, but other corrosive chemicals and environments prevent its use everywhere. Common replacement materials are low alloy steels containing chromium and molybdenum, with stainless steels containing more chromium dealing with more corrosive environments. More expensive materials commonly used are nickel, titanium, and copper alloys. These are primarily saved for the most problematic areas where extremely high temperatures and/or very corrosive chemicals are present.
  Corrosion is fought by a complex system of monitoring, preventative repairs and careful use of materials. Monitoring methods include both offline checks taken during maintenance and online monitoring. Offline checks measure corrosion after it has occurred, telling the engineer when equipment must be replaced based on the historical information they have collected. This is referred to as preventative management.
  Online systems are a more modern development, and are revolutionizing the way corrosion is approached. There are several types of online corrosion monitoring technologies such as linear polarization resistance, electrochemical noise and electrical resistance. Online monitoring has generally had slow reporting rates in the past (minutes or hours) and been limited by process conditions and sources of error but newer technologies can report rates up to twice per minute with much higher accuracy (referred to as real-time monitoring). This allows process engineers to treat corrosion as another process variable that can be optimized in the system. Immediate responses to process changes allow the control of corrosion mechanisms, so they can be minimized while also maximizing production output. In an ideal situation having online corrosion information that is accurate and real-time will allow conditions that cause high corrosion rates to be identified and reduced.  This is known as predictive management.
  Materials methods include selecting the proper material for the application. In areas of minimal corrosion, cheap materials are preferable, but when bad corrosion can occur, more expensive but longer lasting materials should be used. Other materials methods come in the form of protective barriers between corrosive substances and the equipment metals. These can be either a lining of refractory material such as standard Portland cement or other special acid-resistant cements that are shot onto the inner surface of the vessel. Also available are thin overlays of more expensive metals that protect cheaper metal against corrosion without requiring much material.
caption: Oil refinery in Iran.
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