page_title: Electrophilic addition
hierarchical_section_title: Electrophilic addition
caption_attribution_description: A representation of an Electrophilic addition reaction.
context_page_description: In organic chemistry, an electrophilic addition reaction is an addition reaction where, in a chemical compound, a π bond is broken and two new σ bonds are formed. The substrate of an electrophilic addition reaction must have a double bond or triple bond.
  The driving force for this reaction is the formation of an electrophile X⁺ that forms a covalent bond with an electron-rich unsaturated C=C bond. The positive charge on X is transferred to the carbon-carbon bond, forming a carbocation during the formation of the C-X bond.
  In step 2 of an electrophilic addition, the positively charged intermediate combines with that is electron-rich and usually an anion to form the second covalent bond.
  Step 2 is the same nucleophilic attack process found in an SN1 reaction. The exact nature of the electrophile and the nature of the positively charged intermediate are not always clear and depend on reactants and reaction conditions.
  In all asymmetric addition reactions to carbon, regioselectivity is important and often determined by Markovnikov's rule. Organoborane compounds give anti-Markovnikov additions.
context_section_description: In organic chemistry, an electrophilic addition reaction is an addition reaction where, in a chemical compound, a π bond is broken and two new σ bonds are formed. The substrate of an electrophilic addition reaction must have a double bond or triple bond.
  The driving force for this reaction is the formation of an electrophile X⁺ that forms a covalent bond with an electron-rich unsaturated C=C bond. The positive charge on X is transferred to the carbon-carbon bond, forming a carbocation during the formation of the C-X bond.
  In step 2 of an electrophilic addition, the positively charged intermediate combines with (Y) that is electron-rich and usually an anion to form the second covalent bond.
  Step 2 is the same nucleophilic attack process found in an SN1 reaction. The exact nature of the electrophile and the nature of the positively charged intermediate are not always clear and depend on reactants and reaction conditions.
  In all asymmetric addition reactions to carbon, regioselectivity is important and often determined by Markovnikov's rule. Organoborane compounds give anti-Markovnikov additions. Electrophilic attack to an aromatic system results in electrophilic aromatic substitution rather than an addition reaction.
  In Electrophilic addition the electrophile with the positive charge effects the formation of the total structure, which thus bears a positive charge as well, to make up for the new addition, which then results in the intermediate, bearing that positive charge.  This intermediate is the key to understanding the electrophilic addition, which is due to the positive nature of the particles involved.  If this is done, then the reactions can be understood by these additions as positively charged reactions. The positive charge bears result as the intermediate form otherwise known as the total structure of such an intermediate.  The end product thus contains the complete structure, with  the addition of Y, a nucleophile.
caption: The overall reaction for electrophilic addition to ethylene.
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