page_title: Transparency and translucency
section_title: Transparent ceramics
hierarchical_section_title: Transparency and translucency / Introduction / Transparent ceramics
caption_attribution_description: English: Mushroom gills&#160;revealed through backlighting. Mushroom (unknown species) pictured from below, backlit by morning sun.
context_page_description: In the field of optics, transparency is the physical property of allowing light to pass through the material without appreciable scattering of light. On a macroscopic scale, the photons can be said to follow Snell's Law. Translucency allows light to pass through, but does not necessarily follow Snell's law; the photons can be scattered at either of the two interfaces, or internally, where there is a change in index of refraction. In other words, a translucent material is made up of components with different indices of refraction. A transparent material is made up of components with a uniform index of refraction. Transparent materials appear clear, with the overall appearance of one color, or any combination leading up to a brilliant spectrum of every color. The opposite property of translucency is opacity.
  When light encounters a material, it can interact with it in several different ways. These interactions depend on the wavelength of the light and the nature of the material. Photons interact with an object by some combination of reflection, absorption and transmission.
context_section_description: Optical transparency in polycrystalline materials is limited by the amount of light which is scattered by their microstructural features. Light scattering depends on the wavelength of the light. Limits to spatial scales of visibility (using white light) therefore arise, depending on the frequency of the light wave and the physical dimension of the scattering center. For example, since visible light has a wavelength scale on the order of a micrometer, scattering centers will have dimensions on a similar spatial scale. Primary scattering centers in polycrystalline materials include microstructural defects such as pores and grain boundaries. In addition to pores, most of the interfaces in a typical metal or ceramic object are in the form of grain boundaries which separate tiny regions of crystalline order. When the size of the scattering center (or grain boundary) is reduced below the size of the wavelength of the light being scattered, the scattering no longer occurs to any significant extent.
  In the formation of polycrystalline materials (metals and ceramics) the size of the crystalline grains is determined largely by the size of the crystalline particles present in the raw material during formation (or pressing) of the object. Moreover, the size of the grain boundaries scales directly with particle size. Thus a reduction of the original particle size well below the wavelength of visible light (about 1/15 of the light wavelength or roughly 600/15 = 40 nanometers) eliminates much of light scattering, resulting in a translucent or even transparent material.
  Computer modeling of light transmission through translucent ceramic alumina has shown that microscopic pores trapped near grain boundaries act as primary scattering centers. The volume fraction of porosity had to be reduced below 1% for high-quality optical transmission (99.99 percent of theoretical density). This goal has been readily accomplished and amply demonstrated in laboratories and research facilities worldwide using the emerging chemical processing methods encompassed by the methods of sol-gel chemistry and nanotechnology.
  Transparent ceramics have created interest in their applications for high energy lasers, transparent armor windows, nose cones for heat seeking missiles, radiation detectors for non-destructive testing, high energy physics, space exploration, security and medical imaging applications. Large laser elements made from transparent ceramics can be produced at a relatively low cost. These components are free of internal stress or intrinsic birefringence, and allow relatively large doping levels or optimized custom-designed doping profiles. This makes ceramic laser elements particularly important for high-energy lasers.
  The development of transparent panel products will have other potential advanced applications including high strength, impact-resistant materials that can be used for domestic windows and skylights. Perhaps more important is that walls and other applications will have improved overall strength, especially for high-shear conditions found in high seismic and wind exposures. If the expected improvements in mechanical properties bear out, the traditional limits seen on glazing areas in today's building codes could quickly become outdated if the window area actually contributes to the shear resistance of the wall.
  Currently available infrared transparent materials typically exhibit a trade-off between optical performance, mechanical strength and price. For example, sapphire (crystalline alumina) is very strong, but it is expensive and lacks full transparency throughout the 3–5 micrometer mid-infrared range. Yttria is fully transparent from 3–5 micrometers, but lacks sufficient strength, hardness, and thermal shock resistance for high-performance aerospace applications. Not surprisingly, a combination of these two materials in the form of the yttrium aluminium garnet (YAG) is one of the top performers in the field.
caption: Translucency of a material being used to highlight the structure of a photographic subject
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