page_title: X-ray crystallography
section_title: Mineralogy and metallurgy
hierarchical_section_title: X-ray crystallography / Contributions to chemistry and material science / Mineralogy and metallurgy
caption_attribution_description: English: 10.30.2012 First X-ray View of Martian Soil http://photojournal.jpl.nasa.gov/catalog/PIA16217 This graphic shows results of the first analysis of Martian soil by the Chemistry and Mineralogy (CheMin) experiment on NASA's Curiosity rover. The image reveals the presence of crystalline feldspar, pyroxenes and olivine mixed with some amorphous (non-crystalline) material. The soil sample, taken from a wind-blown deposit within Gale Crater, where the rover landed, is similar to volcanic soils in Hawaii. Curiosity scooped the soil on Oct. 15, 2012, the 69th sol, or Martian day, of operations. It was delivered to CheMin for X-ray diffraction analysis on October 17, 2012, the 71st sol. By directing an X-ray beam at a sample and recording how X-rays are scattered by the sample at an atomic level, the instrument can definitively identify and quantify minerals on Mars for the first time. Each mineral has a unique pattern of rings, or "fingerprint," revealing its presence. The colors in the graphic represent the intensity of the X-rays, with red being the most intense. Image Credit: NASA/JPL-Caltech/Ames
context_page_description: X-ray crystallography is the experimental science determining the atomic and molecular structure of a crystal, in which the crystalline structure causes a beam of incident X-rays to diffract into many specific directions. By measuring the angles and intensities of these diffracted beams, a crystallographer can produce a three-dimensional picture of the density of electrons within the crystal. From this electron density, the mean positions of the atoms in the crystal can be determined, as well as their chemical bonds, their crystallographic disorder, and various other information.
  Since many materials can form crystals—such as salts, metals, minerals, semiconductors, as well as various inorganic, organic, and biological molecules—X-ray crystallography has been fundamental in the development of many scientific fields. In its first decades of use, this method determined the size of atoms, the lengths and types of chemical bonds, and the atomic-scale differences among various materials, especially minerals and alloys. The method also revealed the structure and function of many biological molecules, including vitamins, drugs, proteins and nucleic acids such as DNA.
context_section_description: Since the 1920s, X-ray diffraction has been the principal method for determining the arrangement of atoms in minerals and metals. The application of X-ray crystallography to mineralogy began with the structure of garnet, which was determined in 1924 by Menzer. A systematic X-ray crystallographic study of the silicates was undertaken in the 1920s. This study showed that, as the Si/O ratio is altered, the silicate crystals exhibit significant changes in their atomic arrangements. Machatschki extended these insights to minerals in which aluminium substitutes for the silicon atoms of the silicates. The first application of X-ray crystallography to metallurgy likewise occurred in the mid-1920s. Most notably, Linus Pauling's structure of the alloy Mg₂Sn led to his theory of the stability and structure of complex ionic crystals.
  On October 17, 2012, the Curiosity rover on the planet Mars at "Rocknest" performed the first X-ray diffraction analysis of Martian soil. The results from the rover's CheMin analyzer revealed the presence of several minerals, including feldspar, pyroxenes and olivine, and suggested that the Martian soil in the sample was similar to the "weathered basaltic soils" of Hawaiian volcanoes.
caption: First X-ray diffraction view of Martian soil – CheMin analysis reveals feldspar, pyroxenes, olivine and more (Curiosity rover at "Rocknest", October 17, 2012).[68]
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