Document:

<PAGE>
                                 EXHIBIT 10.20

                           PERFORMANCE AWARD AGREEMENT

This Performance Award Agreement (the "Agreement"), dated effective JANUARY 15,
2004, is by and between VALERO ENERGY CORPORATION, a Delaware corporation
("Valero"), and GREGORY C. KING, a participant (the "Participant") in Valero's
2001 EXECUTIVE STOCK INCENTIVE PLAN, a plan approved by the Board of Directors
of Valero (the "Board") on March 15, 2001, and approved by Valero's stockholders
on May 10, 2001 (as may be amended, the "Plan"), pursuant to and subject to the
provisions of the Plan.

1.       GRANT OF PERFORMANCE SHARES. Valero hereby grants to Participant 12,600
         Performance Shares pursuant to Section 6(d) of the Plan. The
         Performance Shares represent rights to receive shares of Common Stock
         of Valero, subject to the terms and conditions of this Agreement and
         the Plan.

2.       PERFORMANCE PERIOD. Except as provided below with respect to a Change
         of Control (as defined in the Plan), the "Performance Period" for any
         Performance Shares eligible to vest on any given Normal Vesting Date
         (as defined below) shall be the three calendar years ending on the
         December 31 immediately preceding the Normal Vesting Date.

3.       VESTING AND DELIVERY OF SHARES. The Performance Shares granted
         hereunder shall vest over a period of three years in equal, one-third
         increments with the first increment vesting on the date of the
         regularly scheduled meeting of the Board's Compensation Committee
         ("Meeting Date") in January 2005, and the second and third increments
         vesting on the Committee's Meeting Dates in January 2006 and January
         2007, respectively (each of these three vesting dates is referred to as
         a "Normal Vesting Date"), such vesting being subject to verification of
         attainment of the Performance Objectives described in Paragraph 4 by
         the Compensation Committee. If the Committee is unable to meet in
         January of a given year, then the Normal Vesting Date for that year
         will be the date not later than March 31 of that year as selected by
         the Compensation Committee. Until shares of Common Stock are actually
         issued to Participant (or his or her estate) in settlement of the
         Performance Shares, neither Participant nor any person claiming by,
         through or under Participant shall have any rights as a stockholder of
         Valero (including, without limitation, voting rights or any right to
         receive dividends or other distributions) with respect to such shares,
         and Participant's status with respect to the issuance of such shares
         shall be that of a general creditor of Valero.

4.       PERFORMANCE OBJECTIVES.

         A.  TOTAL SHAREHOLDER RETURN. Total Shareholder Return ("TSR") will be
             compiled for a peer group of companies (the "Target Group") for the
             Performance Period immediately preceding each Normal Vesting Date.
             TSR for each such company is measured by dividing the sum of (i)
             the dividends on the common stock of such company during the
             Performance Period, assuming dividend reinvestment, and (ii) the
             difference between the price of a share of such company's common
             stock at the end and at the beginning of the period (appropriately
             adjusted for any stock dividend, stock split, spin-off, merger or
             other similar corporate events) by (iii) the price of a share of
             such company's common stock at the beginning of the period.

         B.  TARGET GROUP. The applicable Target Group shall be selected by the
             Compensation Committee of the Board of Directors of Valero, acting
             in its sole discretion, at or near the time of each Normal Vesting
             Date. The same Target Group shall be utilized to determine the
             number of Performance Shares vesting under all Performance Award
             Agreements of Valero having a similar Normal Vesting Date, but the
             decision of the Compensation Committee as to the composition of
             such Target Group shall be final.

<PAGE>

         C.  PERFORMANCE RANKING. The TSR for the Performance Period for Valero
             and each company in the Target Group shall be arranged by rank from
             best to worst according to the TSR achieved by each company. The
             total number of companies so ranked shall then be divided into four
             groups ("Quartiles"). For purposes of assigning companies to
             Quartiles (with the 1st Quartile being the best and the 4th
             Quartile being the worst), the total number of companies ranked
             (including Valero) shall be divided into four groups as nearly
             equal in number as possible. The number of companies in each group
             shall be the total number contained in the Target Group divided by
             four. If the total number of companies is not evenly divisible by
             four, so that there is a fraction contained in such quotient, the
             extra company(ies) represented by such fraction will be included in
             one or more Quartiles as follows:

<Table>
<Caption>
                           Fraction                    Extra Company(ies)
                           --------                    ------------------
<S>                                                    <C>
                              1/4                         1st Quartile

                              1/2                         1st Quartile
                                                          2nd Quartile

                              3/4                         1st Quartile
                                                          2nd Quartile
                                                          3rd Quartile
</Table>

             Any performance shares not awarded as shares of Common Stock as a
             result of a ranking in the 3rd or 4th Quartile will carry forward
             for one more Performance Period; up to 100% of the Performance
             Shares carried forward may be awarded based on Valero's TSR during
             the next Performance Period, provided, that if any Performance
             Shares are carried forward due to a ranking in the 3rd Quartile, no
             such shares shall be awarded unless Valero's TSR in the subsequent
             period is in the 2nd or 1st Quartile.

         D.  VESTING PERCENTAGES. The number of shares of Common Stock, if any,
             that Participant will be entitled to receive in settlement of the
             vested Performance Shares will be determined on each Normal Vesting
             Date and, subject to the provisions of the Plan and this Agreement,
             on such Normal Vesting Date, the following percentage of the vested
             Performance Shares will be awarded as shares of Common Stock to the
             Participant if Valero's TSR during the Performance Period falls
             within the following ranges:

<Table>
<Caption>
                                                                      Percent of vested Performance
                                                                         Shares to be awarded as
                      Valero TSR Position                                Shares of Common Stock
                      -------------------                             -----------------------------
<S>                                                                   <C>
                          4th Quartile                                              0%
                          3rd Quartile                                             50%
                          2nd Quartile                                            100%
                          1st Quartile                                            150%
</Table>

             If Valero's TSR is the highest achieved in the 1st Quartile for the
             Performance Period, Participant shall be awarded a number of shares
             of Common Stock equal to 200% of the Performance Shares that vested
             during the Performance Period.

5.       TERMINATION OF EMPLOYMENT. Except for a Change of Control (described
         below), if Participant's employment is voluntarily terminated by the
         Participant (other than through retirement, death or disability), or is
         terminated by Valero for "cause" (as defined pursuant to the Plan),
         then (a) those Performance Shares that have not vested or been
         forfeited, and for which a Normal Vesting Date occurs on or before the
         30th day following the date of such termination, may be awarded as
         shares of Common Stock on such Normal Vesting Date in accordance with
         Paragraph 4 hereof, and (b) any such Performance Shares for which a
         Normal Vesting Date does not occur within such 30-day period,

<PAGE>

         or that are not otherwise awarded as shares of Common Stock on a Normal
         Vesting Date as a result of the application of Paragraph 4, shall
         thereupon be forfeited. Except for a Change of Control, if a
         Participant's employment is terminated through retirement, death, or
         disability, or by Valero other than for cause (as determined pursuant
         to the Plan), then (x) those Performance Shares that have not
         theretofore vested or been forfeited, and for which a Normal Vesting
         Date occurs on or before the 90th day following the date of such
         termination, shall be subject to vesting on such Normal Vesting Date in
         accordance with Paragraph 4 hereof, and (y) any such Performance Shares
         for which such a Normal Vesting Date does not occur within such 90-day
         period, or which otherwise do not vest on a Normal Vesting Date as a
         result of application of Paragraph 4, shall thereupon be forfeited.

6.       CHANGE OF CONTROL. If a Change of Control occurs with respect to
         Valero, then each Performance Period with respect to any Performance
         Shares that have not vested or been forfeited shall be terminated
         effective as of the date of such Change of Control (a "Change of
         Control Vesting Date"); the TSR for Valero and for each company in the
         Target Group shall be determined for each such shortened Performance
         Period and the percentage of Performance Shares to be received by the
         Participant for each such Performance Period shall be determined in
         accordance with Paragraph 4. For purposes of determining the number of
         Performance Shares to be received as of any Change of Control Vesting
         Date, the Target Group as most recently determined by the Compensation
         Committee prior to the date of the Change of Control shall be used.

7.       PLAN INCORPORATED BY REFERENCE. The Plan is incorporated into this
         Agreement by this reference and is made a part hereof for all purposes.
         Capitalized terms not otherwise defined in this Agreement shall have
         the meaning specified in the Plan.

8.       LIMITATION OF RIGHTS OF PARTICIPANT. With respect to any Performance
         Shares, the Participant shall not have any rights that are not
         expressly conferred by the Plan and this Agreement or any other
         Performance Award Agreement between Valero and the Participant.

9.       NO ASSIGNMENT. This Agreement and the Participant's interest in the
         Performance Shares granted by this Agreement are of a personal nature,
         and, except as expressly permitted under the Plan, Participant's rights
         with respect thereto may not be sold, mortgaged, pledged, assigned,
         transferred, conveyed or disposed of in any manner by Participant,
         except by an executor or beneficiary pursuant to a will or pursuant to
         the laws of descent and distribution. Any such attempted sale,
         mortgage, pledge, assignment, transfer, conveyance or disposition shall
         be void, and Valero shall not be bound thereby.

10.      SUCCESSORS. This Agreement shall be binding upon any successors of
         Valero and upon the beneficiaries, legatees, heirs, administrators,
         executors, legal representatives, successors and permitted assigns of
         Participant.

                                  VALERO ENERGY CORPORATION

                                  By:
                                     -------------------------------------------
                                     KEITH D. BOOKE, Executive Vice President

                                  ----------------------------------------------
                                  GREGORY C. KING, Participant<PAGE>
                                  EXHIBIT 10.21

                SCHEDULE OF PERFORMANCE AWARD AGREEMENTS - TYPE B

The following have executed Performance Award Agreements substantially in the
form of the agreement attached as Exhibit 10.20 (the "Exhibit") to the Valero
Energy Corporation Form 10-K for the year ended December 31, 2003.

Keith D. Booke
Michael S. Ciskowski
Gregory C. King
William R. Klesse

The following information sets forth the material details in which the
Performance Award Agreements described in this Schedule differ from the Exhibit.

Keith D. Booke

Performance Award Agreement dated January 14, 2004 (for 8,100 Performance
Shares)

Performance Award Agreement dated January 22, 2003 (for 11,000 Performance
Shares)

Performance Award Agreement dated January 17, 2002 (for 11,000 Performance
Shares)

Michael S. Ciskowski

Performance Award Agreement dated January 14, 2004 (for 8,100 Performance
Shares)

Performance Award Agreement dated January 22, 2003 (for 7,000 Performance
Shares)

Performance Award Agreement dated January 17, 2002 (for 5,000 Performance
Shares)

Gregory C. King

Performance Award Agreement dated January 23, 2003 (for 15,000 Performance
Shares)

Performance Award Agreement dated January 17, 2002 (for 11,000 Performance
Shares)

William R. Klesse

Performance Award Agreement dated January 14, 2004 (for 10,800 Performance
Shares)

Performance Award Agreement dated January 22, 2003 (for 14,000 Performance
Shares)

Performance Award Agreement dated January 17, 2002 (for 14,000 Performance
Shares)

Source: [{"source": "alea-institute/alea-institute/kl3m-data-edgar-agreements/train-00062-of-00352.parquet"}, [{"source": "alea-institute/alea-institute/kl3m-data-edgar-agreements/train-00062-of-00352.parquet"}]]