Document:

Supplemental Indenture, with respect to the 10 1/8%/10 7/8% Senior Toggle Notes

 Exhibit 4.15 
 SUPPLEMENTAL INDENTURE 
 SUPPLEMENTAL INDENTURE (this “Supplemental Indenture”) dated as of
December 20, 2007 among JUNIPER BOND HOLDINGS I LLC, a Delaware limited liability company, JUNIPER BOND HOLDINGS II LLC, a Delaware limited liability company, JUNIPER BOND HOLDINGS III LLC, a Delaware limited liability company, JUNIPER BOND
HOLDINGS IV LLC, a Delaware limited liability company (each of the foregoing a “New Guarantor” and collectively the “New Guarantors”), each New Guarantor being a subsidiary of MOMENTIVE PERFORMANCE MATERIALS INC., a Delaware
corporation (the “Company”) and WELLS FARGO BANK, NATIONAL ASSOCIATION, a national banking association, as trustee under the indenture referred to below (the “Trustee”). 
 W I T N E S S E T H : 
 WHEREAS
the Company and the existing Guarantors have heretofore executed and delivered to the Trustee an indenture (as amended, supplemented or otherwise modified, the “Indenture”) dated as of December 4, 2006, providing for the issuance of
the Company’s 10 1/8% /10 7/8
% Senior Toggle Notes due 2014 (the “Securities”), initially in the aggregate principal amount of $300,000,000; 
 WHEREAS Section 4.11 of the Indenture provides that under certain circumstances the Company is required to cause the New Guarantors to execute and
deliver to the Trustee a supplemental indenture pursuant to which the New Guarantors shall unconditionally guarantee all the Company’s Obligations under the Securities and the Indenture pursuant to a Guarantee on the terms and conditions set
forth herein; and 
 WHEREAS pursuant to Section 9.01 of the Indenture, the Trustee, the Company and the existing Guarantors are
authorized to execute and deliver this Supplemental Indenture; 
 NOW THEREFORE, in consideration of the foregoing and for other good and
valuable consideration, the receipt of which is hereby acknowledged, the New Guarantors and the Trustee mutually covenant and agree for the equal and ratable benefit of the holders of the Securities as follows: 
 1. Defined Terms. As used in this Supplemental Indenture, terms defined in the Indenture or in the preamble or recital hereto are used herein as
therein defined. The words “herein,” “hereof” and “hereby” and other words of similar import used in this Supplemental Indenture refer to this Supplemental Indenture as a whole and not to any particular section hereof.

 2. Agreement to Guarantee. The New Guarantors hereby agree, jointly and severally with all existing Guarantors (if any), to
unconditionally guarantee the Company’s Obligations under the Securities and the Indenture on the terms and subject to the conditions set forth in Articles 11 and 12 of the Indenture and to be bound by all other applicable provisions of the
Indenture and the Securities and to perform all of the obligations and agreements of a Guarantor under the Indenture. 
 3. Notices.
All notices or other communications to the New Guarantors shall be given as provided in Section 11.02 of the Indenture. 

 4. Ratification of Indenture; Supplemental Indentures Part of Indenture. Except as expressly
amended hereby, the Indenture is in all respects ratified and confirmed and all the terms, conditions and provisions thereof shall remain in full force and effect. This Supplemental Indenture shall form a part of the Indenture for all purposes, and
every holder of Securities heretofore or hereafter authenticated and delivered shall be bound hereby. 
 5. Governing Law. THIS
SUPPLEMENTAL INDENTURE SHALL BE GOVERNED BY, AND CONSTRUED IN ACCORDANCE WITH, THE LAWS OF THE STATE OF NEW YORK, WITHOUT REGARD TO PRINCIPLES OF CONFLICTS OF LAW. 
 6. Trustee Makes No Representation. The Trustee makes no representation as to the validity or sufficiency of this Supplemental Indenture. 
 7. Counterparts. The parties may sign any number of copies of this Supplemental Indenture. Each signed copy shall be an original, but all of them
together represent the same agreement. 
 8. Effect of Headings. The Section headings herein are for convenience only and shall not
effect the construction thereof. 

 IN WITNESS WHEREOF, the parties hereto have caused this Supplemental Indenture to be duly executed as of
the date first above written. 
  

			
	JUNIPER BOND HOLDINGS I LLC
	
	 By Momentive Performance Materials Inc.,
 its
Managing Member

		
	By:	 	 /s/ Douglas A. Johns

	Name:	 	Douglas A. Johns
	Title:	 	Secretary and General Counsel
	
	JUNIPER BOND HOLDINGS II LLC
	
	 By Momentive Performance Materials Inc.,
 its
Managing Member

		
	By:	 	 /s/ Douglas A. Johns

	Name:	 	Douglas A. Johns
	Title:	 	Secretary and General Counsel
	
	JUNIPER BOND HOLDINGS III LLC
	
	 By Momentive Performance Materials Inc.,
 its
Managing Member

		
	By:	 	 /s/ Douglas A. Johns

	Name:	 	Douglas A. Johns
	Title:	 	Secretary and General Counsel
	
	JUNIPER BOND HOLDINGS IV LLC
	
	 By Momentive Performance Materials Inc.,
 its
Managing Member

		
	By:	 	 /s/ Douglas A. Johns

	Name:	 	Douglas A. Johns
	Title:	 	Secretary and General Counsel
	
	 WELLS FARGO BANK, NATIONAL ASSOCIATION,
 as Trustee

		
	By:	 	 /s/ Lynn M. Steiner

	Name:	 	Lynn M. Steiner
	Title:	 	Vice PresidentSupplemental Indenture, with respect to the 9 3/4% Senior Toggle Notes

 Exhibit 4.16 
 SUPPLEMENTAL INDENTURE 
 SUPPLEMENTAL INDENTURE (this “Supplemental Indenture”) dated as of
December 20, 2007 among JUNIPER BOND HOLDINGS I LLC, a Delaware limited liability company, JUNIPER BOND HOLDINGS II LLC, a Delaware limited liability company, JUNIPER BOND HOLDINGS III LLC, a Delaware limited liability company, JUNIPER BOND
HOLDINGS IV LLC, a Delaware limited liability company (each of the foregoing a “New Guarantor” and collectively the “New Guarantors”), each New Guarantor being a subsidiary of MOMENTIVE PERFORMANCE MATERIALS INC., a Delaware
corporation (the “Company”) and WELLS FARGO BANK, NATIONAL ASSOCIATION, a national banking association, as trustee under the indenture referred to below (the “Trustee”). 
 W I T N E S S E T H : 
 WHEREAS
the Company and the existing Guarantors have heretofore executed and delivered to the Trustee an indenture (as amended, supplemented or otherwise modified, the “Indenture”) dated as of December 4, 2006, providing for the issuance of
the Company’s 93/4% Senior Notes due 2014 (the
“Securities”), initially in the aggregate principal amount of $765,000,000; 
 WHEREAS Section 4.11 of the
Indenture provides that under certain circumstances the Company is required to cause the New Guarantors to execute and deliver to the Trustee a supplemental indenture pursuant to which the New Guarantors shall unconditionally guarantee all the
Company’s Obligations under the Securities and the Indenture pursuant to a Guarantee on the terms and conditions set forth herein; and 
 WHEREAS pursuant to Section 9.01 of the Indenture, the Trustee, the Company and the existing Guarantors are authorized to execute and deliver this Supplemental Indenture; 
 NOW THEREFORE, in consideration of the foregoing and for other good and valuable consideration, the receipt of which is hereby acknowledged, the New
Guarantors and the Trustee mutually covenant and agree for the equal and ratable benefit of the holders of the Securities as follows: 
 1.
Defined Terms. As used in this Supplemental Indenture, terms defined in the Indenture or in the preamble or recital hereto are used herein as therein defined. The words “herein,” “hereof” and “hereby” and other
words of similar import used in this Supplemental Indenture refer to this Supplemental Indenture as a whole and not to any particular section hereof. 
 2. Agreement to Guarantee. The New Guarantors hereby agree, jointly and severally with all existing Guarantors (if any), to unconditionally guarantee the Company’s Obligations under the Securities and the
Indenture on the terms and subject to the conditions set forth in Articles 11 and 12 of the Indenture and to be bound by all other applicable provisions of the Indenture and the Securities and to perform all of the obligations and agreements of a
Guarantor under the Indenture. 
 3. Notices. All notices or other communications to the New Guarantors shall be given as provided in
Section 11.02 of the Indenture. 

 4. Ratification of Indenture; Supplemental Indentures Part of Indenture. Except as expressly
amended hereby, the Indenture is in all respects ratified and confirmed and all the terms, conditions and provisions thereof shall remain in full force and effect. This Supplemental Indenture shall form a part of the Indenture for all purposes, and
every holder of Securities heretofore or hereafter authenticated and delivered shall be bound hereby. 
 5. Governing Law. THIS
SUPPLEMENTAL INDENTURE SHALL BE GOVERNED BY, AND CONSTRUED IN ACCORDANCE WITH, THE LAWS OF THE STATE OF NEW YORK, WITHOUT REGARD TO PRINCIPLES OF CONFLICTS OF LAW. 
 6. Trustee Makes No Representation. The Trustee makes no representation as to the validity or sufficiency of this Supplemental Indenture. 
 7. Counterparts. The parties may sign any number of copies of this Supplemental Indenture. Each signed copy shall be an original, but all of them
together represent the same agreement. 
 8. Effect of Headings. The Section headings herein are for convenience only and shall not
effect the construction thereof. 

 IN WITNESS WHEREOF, the parties hereto have caused this Supplemental Indenture to be duly executed as of
the date first above written. 
  

			
	JUNIPER BOND HOLDINGS I LLC
	
	 By Momentive Performance Materials Inc.,
 its
Managing Member

		
	By:	 	 /s/ Douglas A. Johns

	Name:	 	Douglas A. Johns
	Title:	 	Secretary and General Counsel
	
	JUNIPER BOND HOLDINGS II LLC
	
	 By Momentive Performance Materials Inc.,
 its
Managing Member

		
	By:	 	 /s/ Douglas A. Johns

	Name:	 	Douglas A. Johns
	Title:	 	Secretary and General Counsel
	
	JUNIPER BOND HOLDINGS III LLC
	
	 By Momentive Performance Materials Inc.,
 its
Managing Member

		
	By:	 	 /s/ Douglas A. Johns

	Name:	 	Douglas A. Johns
	Title:	 	Secretary and General Counsel
	
	JUNIPER BOND HOLDINGS IV LLC
	
	 By Momentive Performance Materials Inc.,
 its
Managing Member

		
	By:	 	 /s/ Douglas A. Johns

	Name:	 	Douglas A. Johns
	Title:	 	Secretary and General Counsel
	
	WELLS FARGO BANK, NATIONAL ASSOCIATION, as Trustee
		
	By:	 	 /s/ Lynn M. Steiner

	Name:	 	Lynn M. Steiner
	Title:	 	Vice President

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