Document:

Fifth Supplemental Indenture, dated as of June 29, 2010

 Exhibit 4.11 
 FIFTH SUPPLEMENTAL INDENTURE 
 FIFTH SUPPLEMENTAL INDENTURE, dated as of
June 29, 2010 (the “Supplemental Indenture”), among Massey Energy Company, a Delaware corporation, as issuer (the “Issuer”), the Guarantors (as defined in the Indenture (defined below)), En Route LLC, a Virginia limited
liability company (the “New Subsidiary”), and Wilmington Trust Company, as trustee (the “Trustee”). 
 W I
T N E S S E T H 
 WHEREAS, the Issuer, the Guarantors and the Trustee executed that certain Senior Indenture (the “Base
Indenture”), dated as of August 12, 2008, as supplemented by that First Supplemental Indenture (the “First Supplemental Indenture”), dated the same date, as further supplemented by that Second Supplemental Indenture (the
“Second Supplemental Indenture”), dated as of July 20, 2009, as further supplemented by that Third Supplemental Indenture (the “Third Supplemental Indenture”), dated as of August 28, 2009, and as further supplemented by
that Fourth Supplemental Indenture (the “Fourth Supplemental Indenture”), dated as of April 30, 2010, each by and among the Issuer, the Guarantors (defined therein) and the Trustee (the Base Indenture, the First Supplemental
Indenture, the Second Supplemental Indenture, the Third Supplemental Indenture and the Fourth Supplemental Indenture, collectively, and as amended and supplemented, the “Indenture”), providing for the issuance of the 3.25% Convertible
Senior Notes due 2015 in the principal amount of up to Six Hundred Ninety Million and 00/100 Dollars ($690,000,000). 
 WHEREAS, the New
Subsidiary was organized under the laws of the Commonwealth of Virginia. 
 WHEREAS, the New Subsidiary desires to incur Indebtedness and
to guarantee the Indebtedness of the Issuer and/or its wholly-owned subsidiaries, to the extent permitted by the Indenture. 
 WHEREAS,
pursuant to Section 1504 of the Base Indenture, the New Subsidiary desires to become a Guarantor under the Indenture. 

WHEREAS, Section 1504 of the Base Indenture provides that supplemental indentures may be executed and delivered by the Issuer, the Guarantors
and the Trustee for the purpose of amending or supplementing the Indenture so that a Subsidiary may become a party to the Indenture and issue a Note Guarantee, as attached hereto as Exhibit A. 

WHEREAS, all other acts and proceedings necessary have been done to make this Supplemental Indenture, when executed and delivered by the Issuer,
the Guarantors and the Trustee, the legal, valid and binding agreement of the Issuer and the Guarantors in accordance with its terms. 
 NOW
THEREFORE, for good and valuable consideration, the sufficiency and receipt of which are hereby acknowledged, the parties, intending to be legally bound, agree as follows: 
 Section 1. Confirmation of the Indenture; Definitions. Except as supplemented hereby, the Indenture is hereby confirmed and reaffirmed in all particulars. Anything in the Indenture or herein to the
contrary notwithstanding, all recitals, definitions and provisions contained in this Supplemental Indenture shall take precedence over the recitals, definitions and provisions of the Indenture to the extent of any conflict between the two. Unless
otherwise defined herein, terms defined in the Indenture and used herein shall have the meaning given them in the Indenture. 
 Section 2. (a)
The New Subsidiary hereby executes this Agreement as a supplemental indenture to the Indenture for the purpose of issuing a Note Guarantee, as set forth in Exhibit A, and agrees to be subject to all of the terms, conditions, waivers and covenants
applicable to a Subsidiary and Guarantor under the Indenture. Upon its execution hereof, the New Subsidiary hereby acknowledges that it shall be a Guarantor for all purposes set forth in the Indenture, effective as of the date hereof. 

 (b) None of the shareholders, trustees or officers of the New Subsidiary shall be personally liable for the
New Subsidiary’s obligations as a Guarantor arising under the Indenture. 
 Section 3. Conditions to Effectiveness of Supplemental
Indenture and to Operation of Amendments Made Hereby. This Supplemental Indenture shall become effective immediately upon its execution by the Trustee, the Issuer and the Guarantors. 
 Section 4. Counterparts. This Supplemental Indenture may be executed in any number of counterparts, each of which so executed shall be deemed to be an original, but all such counterparts shall
together constitute but one and the same instrument. 
 Section 5. Severability. In case any provision in this Supplemental Indenture
shall be invalid, illegal or unenforceable, the validity, legality and enforceability of the remaining provisions shall not in any way be effected or impaired thereby. 
 Section 6. Governing Law. This Supplemental Indenture shall be governed by and construed in accordance with the laws of the State of New York. 

Section 7. Trustee. The Trustee makes no representation as the validity or sufficiency of this Supplemental Indenture. 

[Signature page follows.] 

  
 2 

 IN WITNESS WHEREOF, the parties hereto have caused this Supplemental Indenture to be duly executed,
all as of the date first above written. 
  

			
	MASSEY ENERGY COMPANY
		
	By:	 	/s/ Richard R. Grinnan
	Name:	 	Richard R. Grinnan
	Title:	 	Vice President and Secretary

  

			
	ADDITIONAL GUARANTOR:
	
	EN ROUTE LLC
		
	By:	 	/s/ Richard R. Grinnan
	Name:	 	Richard R. Grinnan
	Title:	 	Corporate Secretary

  
 3 

 
			
	 ORIGINAL GUARANTORS:
  

A. T. MASSEY COAL COMPANY, INC.
 ALEX
ENERGY, INC.
 ARACOMA COAL COMPANY, INC.
 BANDMILL COAL CORPORATION
 BANDYTOWN COAL COMPANY

BARNABUS LAND COMPANY
 BELFRY COAL
CORPORATION
 BEN CREEK COAL COMPANY
 BIG BEAR MINING COMPANY
 BIG SANDY VENTURE CAPITAL CORP.

BLACK KING MINE DEVELOPMENT CO.
 BLUE
RIDGE VENTURE CAPITAL CORP.
 BOONE EAST DEVELOPMENT CO.
 BOONE ENERGY COMPANY
 BOONE WEST DEVELOPMENT CO.

CENTRAL PENN ENERGY COMPANY, INC.

CENTRAL WEST VIRGINIA ENERGY COMPANY
 CERES LAND COMPANY
 CLEAR FORK COAL COMPANY

CRYSTAL FUELS COMPANY
 DEHUE COAL COMPANY
 DELBARTON MINING COMPANY

DEMETER LAND COMPANY

DOUGLAS POCAHONTAS COAL CORPORATION
 DRIH CORPORATION
 DUCHESS COAL COMPANY

DUNCAN FORK COAL COMPANY
 EAGLE ENERGY,
INC.
 ELK RUN COAL COMPANY, INC.
 FEATS VENTURE CAPITAL CORP.
 FOGLESONG ENERGY COMPANY

GOALS COAL COMPANY
 GREEN VALLEY COAL
COMPANY
 GREYEAGLE COAL COMPANY
 HADEN FARMS, INC.
 HANNA LAND COMPANY,
LLC
(by ALEX ENERGY, INC., its Manager)
 HAZY RIDGE COAL COMPANY
 HIGHLAND MINING COMPANY
 HOPKINS CREEK COAL COMPANY

INDEPENDENCE COAL COMPANY, INC.
 JACKS
BRANCH COAL COMPANY
 JOBONER COAL COMPANY
 KANAWHA ENERGY COMPANY
 KNOX CREEK COAL CORPORATION

LAUREN LAND COMPANY
 LAXARE,
INC.
 LOGAN COUNTY MINE SERVICES, INC.
 LONG FORK COAL COMPANY
 LYNN BRANCH COAL COMPANY, INC.

MAJESTIC MINING, INC.
 MARFORK COAL
COMPANY, INC.

  
 4 

 
			
	 MARTIN COUNTY COAL CORPORATION
 MASSEY COAL SALES COMPANY, INC.
 MASSEY GAS & OIL COMPANY

MASSEY TECHNOLOGY INVESTMENTS, INC.

NEW MARKET LAND COMPANY
 NEW RIDGE
MINING COMPANY
 NEW RIVER ENERGY CORPORATION
 NICCO CORPORATION
 NICHOLAS ENERGY COMPANY

OMAR MINING COMPANY
 PEERLESS EAGLE
COAL CO.
 PERFORMANCE COAL COMPANY
 PETER CAVE MINING COMPANY
 PILGRIM MINING COMPANY, INC.

POWER MOUNTAIN COAL COMPANY
 RAVEN
RESOURCES, INC.
 RAWL SALES & PROCESSING CO.

ROAD FORK DEVELOPMENT
COMPANY, INC.
 ROBINSON-PHILLIPS COAL COMPANY
 RUM CREEK COAL SALES, INC.

RUSSELL FORK COAL COMPANY
 SC COAL
CORPORATION
 SCARLET DEVELOPMENT COMPANY

SHANNON-POCAHONTAS COAL CORPORATION
 SHANNON-POCAHONTAS MINING COMPANY     (by: SHANNON-POCAHONTAS COAL             CORPORATION, its
partner
    by: OMAR MINING COMPANY, its partner)
 SHENANDOAH
CAPITAL
MANAGEMENT CORP.
 SIDNEY COAL COMPANY, INC.
 SPARTAN MINING COMPANY
 ST. ALBAN’S
CAPITAL
MANAGEMENT CORP.
 STIRRAT COAL COMPANY
 STONE MINING COMPANY
 SUPPORT MINING COMPANY

SYCAMORE FUELS, INC.
 T.C.H. COAL
CO.
 TALON LOADOUT COMPANY

TENNESSEE CONSOLIDATED COAL COMPANY
 TENNESSEE ENERGY CORP.
 THUNDER MINING COMPANY

TOWN CREEK COAL COMPANY
 TRACE CREEK
COAL COMPANY
 TUCSON LIMITED LIABILITY COMPANY,
(by: ALEX ENERGY, INC., its
Manager)
 VANTAGE MINING COMPANY
 WEST KENTUCKY ENERGY COMPANY
 WHITE BUCK COAL COMPANY

WILLIAMS MOUNTAIN COAL COMPANY
 WYOMAC
COAL COMPANY, INC.
 JST MINING COMPANY
 JST LAND COMPANY
 CUMBERLAND RESOURCES CORPORATION

  
 5 

 
			
	 POWELL RIVER RESOURCES
 JST RESOURCES LLC
 ALLIANCE COAL CORPORATION

BIG LAUREL MINING CORPORATION
 BLUFF
SPUR COAL CORPORATION
 BULL MOUNTAIN MINING CORPORATION
 CUMBERLAND EQUIPMENT CORPORATION

DORCHESTER ENTERPRISES, INCORPORATED
 GUEST MOUNTAIN MINING CORPORATION
 MEADOW BRANCH MINING CORPORATION

MOUNTAIN MANAGEMENT, INCORPORATED

NORTH FORK COAL CORPORATION
 OSAKA
MINING CORPORATION
 PIGEON CREEK PROCESSING CORPORATION
 WINIFREDE COAL CORPORATION
 CLOVERLICK MANAGEMENT LLC

DORCHESTER ASSOCIATES LLC
 HARLAN
RECLAMATION SERVICES LLC
 MAGGARD BRANCH COAL LLC
 MEADOW BRANCH COAL LLC
 NINE MILE SPUR LLC

RESOURCE DEVELOPMENT LLC
 RESOURCE LAND
COMPANY LLC
 RODA RESOURCES LLC
 EXETER COAL CORPORATION
 MILL BRANCH COAL CORPORATION

BLACK MOUNTAIN RESOURCES, LLC
 CAVE
SPUR COAL LLC
 CLOVERLICK COAL COMPANY LLC
 HIGH SPLINT COAL LLC
 PANTHER MINING LLC

STILLHOUSE MINING LLC

		
	By:	 	/s/ Richard R. Grinnan
	Name:	 	Richard R. Grinnan
	Title:	 	Secretary
	
	MASSEY COAL SERVICES, INC.
		
	By:	 	/s/ Richard R. Grinnan
	Name:	 	Richard R. Grinnan
	Title:	 	Assistant Secretary
	
	WILMINGTON TRUST COMPANY, as Trustee
		
	By:	 	/s/ Christopher J. Slaybaugh
	Name:	 	Christopher J. Slaybaugh
	Title:	 	Vice President

  
 6 

 EXHIBIT A 

NOTE GUARANTEE 
 The
undersigned (the “Guarantor”) hereby jointly and severally unconditionally guarantee, on a senior unsecured basis, to the extent set forth in the Indenture (the “Base Indenture”), dated as of August 12, 2008, as supplemented
by that First Supplemental Indenture (the “First Supplemental Indenture”), dated the same date, as further supplemented by that Second Supplemental Indenture (the “Second Supplemental Indenture”), dated as of July 20, 2009,
as further supplemented by that Third Supplemental Indenture (the “Third Supplemental Indenture”), dated as of August 28, 2009, as further supplemented by that Fourth Supplemental Indenture (the “Fourth Supplemental
Indenture”), dated as of April 30, 2010, and as further supplemented by that Fifth Supplemental Indenture (the “Fifth Supplemental Indenture”), dated June ___, 2010, each by and among the Issuer, the Guarantors (defined therein)
and the Trustee (the Base Indenture, the First Supplemental Indenture, the Second Supplemental Indenture, the Third Supplemental Indenture, the Fourth Supplemental Indenture and the Fifth Supplemental Indenture, collectively, and as amended and
supplemented, the “Indenture”), and subject to the provisions of the Indenture, (a) the due and punctual payment of the principal of, and premium, if any, interest and additional interest, if any, with respect to the Securities, when
and as the same shall become due and payable, whether at maturity, by acceleration or otherwise, the due and punctual payment of interest on overdue principal of, and premium and, to the extent permitted by law, interest or additional interest, if
any, and the due and punctual performance of all other obligations of the Company or any Guarantor to the Holders or the Trustee under this Indenture and the Securities (including amounts due the Trustee under Section 607 of the Indenture), all
in accordance with the terms set forth in Article Fifteen of the Base Indenture, and (b) in case of any extension of time of payment or renewal of any Securities or any of such other obligations, that the same shall be promptly paid in full
when due or performed in accordance with the terms of the extension or renewal, whether at Stated Maturity, by acceleration or otherwise. 
 The
obligations of the Guarantor to the Holders and to the Trustee pursuant to this Note Guarantee and the Indenture are expressly set forth in Article Fifteen of the Base Indenture and reference is hereby made to the Indenture for the precise terms and
limitations of this Note Guarantee. 
 Capitalized terms not otherwise defined herein shall have the meanings set forth in the Indenture.

 [Signature Page Follows] 

  
 7 

 IN WITNESS WHEREOF, the Guarantor has caused this Note Guarantee to be signed by a duly authorized officer.

  

			
	EN ROUTE LLC
		
	By:	 	 
	Name:	 	Richard R. Grinnan
	Title:	 	Secretary

 Dated: June ___, 2010 

  
 8Sixth Supplemental Indenture, dated as of June 1, 2011

 Exhibit 4.12 
 SIXTH SUPPLEMENTAL INDENTURE 
 SIXTH SUPPLEMENTAL INDENTURE, dated
as of June 1, 2011 (the “Supplemental Indenture”), among Massey Energy Company, a Delaware corporation, as issuer (the “Issuer”), the Guarantors (as defined in the Indenture (defined below)), Alpha Natural Resources, Inc., a
Delaware corporation (the “Parent”), and Wilmington Trust Company, as trustee (the “Trustee”). 

WITNESSETH 
 WHEREAS, the Issuer, the Guarantors and the Trustee executed that certain Senior Indenture (the “Base Indenture”), dated as of August 12, 2008, as supplemented by that First
Supplemental Indenture (the “First Supplemental Indenture”), dated the same date, as further supplemented by that Second Supplemental Indenture (the “Second Supplemental Indenture”), dated as of July 20, 2009, as further
supplemented by that Third Supplemental Indenture (the “Third Supplemental Indenture”), dated as of August 28, 2009, as further supplemented by that Fourth Supplemental Indenture (the “Fourth Supplemental Indenture”), dated
as of April 30, 2010, and as further supplemented by that Fifth Supplemental Indenture (the “Fifth Supplemental Indenture”) dated as of June 29, 2010 each by and among the Issuer, the Guarantors (defined therein) and the Trustee
(the Base Indenture, the First Supplemental Indenture, the Second Supplemental Indenture, the Third Supplemental Indenture, the Fourth Supplemental Indenture, and the Fifth Supplemental Indenture, collectively, and as amended and supplemented, the
“Indenture”), providing for the issuance of the 3.25% Convertible Senior Notes due 2015 in the principal amount of up to Six Hundred Ninety Million and 00/100 Dollars ($690,000,000) (the “Notes”); 

WHEREAS, pursuant to that certain Agreement and Plan of Merger, dated as of January 28, 2011, by and among Parent, Mountain
Merger Sub, Inc. (a subsidiary of Parent) and Issuer (the “Merger Agreement”), Parent has acquired all outstanding shares of Issuer effective on the date hereof upon the consummation of the merger contemplated by the Merger Agreement (such
time of effectiveness, the “Effective Time”); 
 WHEREAS, pursuant to the Merger Agreement, Parent has agreed,
immediately upon the Effective Time, to guarantee the Notes; 
 WHEREAS, Section 901 of the Base Indenture and
Section 9.01 of the First Supplemental Indenture provide that supplemental indentures may be executed and delivered by the Issuer, the Guarantors and the Trustee for the purpose of amending or supplementing the Indenture to add Note Guarantees
and to make adjustments in accordance with the Indenture to the right to convert the Notes upon certain reclassifications or changes in the Common Stock and certain consolidations, mergers and binding share exchanges, among other things; or make any
change that would provide any additional rights or benefits to the Holders of Securities of any series or that does not adversely affect the legal rights under the Indenture of any such Holder, inter alia; 

 WHEREAS, pursuant to the Merger Agreement, holders of Common Stock shall be eligible
to receive upon the Effective Time 1.025 shares of common stock of Parent and $10.00 cash per share of Common Stock; 

WHEREAS, Section 10.11 of the First Supplemental Indenture provides that a supplemental indenture shall be executed and
delivered by the Issuer, as a condition precedent to a merger such as that contemplated by the Merger Agreement (the “Merger”), to provide for adjusted conversion rights following the Effective Time, in accordance with the terms of the
Indenture; and 
 WHEREAS, all other acts and proceedings necessary have been done to make this Supplemental Indenture,
when executed and delivered by the Issuer, the Guarantors and the Trustee, the legal, valid and binding agreement of the Issuer and the Guarantors in accordance with its terms. 

NOW THEREFORE, for good and valuable consideration, the sufficiency and receipt of which are hereby acknowledged, the parties,
intending to be legally bound, agree as follows: 
 Section 1. Confirmation of the Indenture; Definitions. Except as
supplemented hereby, the Indenture is hereby confirmed and reaffirmed in all particulars. Anything in the Indenture or herein to the contrary notwithstanding, all recitals, definitions and provisions contained in this Supplemental Indenture shall
take precedence over the recitals, definitions and provisions of the Indenture to the extent of any conflict between the two. Unless otherwise defined herein, terms defined in the Indenture and used herein shall have the meaning given them in the
Indenture. 
 Section 2. Guarantee. (a) The Parent hereby executes this Supplemental Indenture as a
supplemental indenture to the Indenture for the purpose of issuing a guarantee of the Notes (the “Parent Guarantee”), as set forth in Exhibit A. 
 (b) None of the shareholders, trustees, officers or Affiliates of the Parent shall be liable for the Parent’s obligations arising under the Parent Guarantee. 

Section 3. Conversion Rights. (a) Except as the context otherwise requires, and except as otherwise provided in this
Supplemental Indenture, from and after the Effective Time, (i) each reference in the Indenture and the Notes to a share of Common Stock shall be deemed to be a reference to a unit consisting of (A) 1.025 (as adjusted from time to time as
provided in Article X, the “Share Amount”) shares (the “Share Component”) of common stock of the Parent, $0.01 par value per share, or such other Capital Stock of the Parent as such Parent common stock is subsequently
reclassified or changed into (the “Parent Stock”), and (B) $10.00 in cash (the “Cash Component”), taken together; (ii) each reference in the Indenture and the Notes to the “Company”, solely to the extent such
reference pertains to the issuance of Parent Stock constituting the Share Component for the purpose of conversion of the Notes (including references in Section 10.05 of the First Supplemental Indenture), shall be deemed to be a reference to the
Parent (and all other references to the “Company” shall continue to refer to the Issuer); and (iii) each reference in Sections 10.05 and 10.08 and the first paragraph of Section

  
 2 

 
10.06 of the First Supplemental Indenture to the “Conversion Rate” shall be deemed to be a reference to the Share Amount. 

(b) Notwithstanding clause 3(a) of this Supplemental Indenture, from and after the Effective Time, (i) each reference to the Common
Stock in (A) the definition of “Market Disruption Event” in Section 1.02 of the First Supplemental Indenture, (B) the definition of “Trading Day” in Section 1.02 of the First Supplemental Indenture,
(C) the definition of “Termination of Trading” in Section 3.02(K)(ii) of the First Supplemental Indenture, (D) Sections 10.02(A)(iii), 10.02(C)-(G), 10.03-10.05, 10.07, 10.08 and 10.13 of the First Supplemental Indenture and
(E) the form of Conversion Notice appended to the Notes shall be deemed to be a reference to the Parent Stock; and (ii) in determining, from time to time, the Closing Sale Price or Volume Weighted Average Price of the Common Stock (other
than for purposes of Section 10.05 of the First Supplemental Indenture), (A) the Share Component thereof shall be valued as set forth in the definition of “Closing Sale Price” or “Volume-Weighted Average Price” as the
case may be (for which purpose, the term “Common Stock” shall be deemed to be a reference to the Parent Stock), (B) the Cash Component thereof shall be valued at the stated amount thereof and (C) the two values shall be summed.

 (c) For the avoidance of doubt, in consequence of the foregoing Section 3(a), from and after the Effective Time, the
Holder of each Note then outstanding shall have the right to convert such Note (pursuant to, and subject to the conditions under, Article X of the First Supplemental Indenture and subject to adjustment by any Make-Whole Applicable Increase
applicable to a given conversion) into [    ] shares of common stock of the Parent and $[    ] in cash per $1,000 principal amount of Notes (resulting from application of the Conversion Rate of
[    ] to the Common Stock as the meaning of such term is modified above), subject to further adjustments as described in this Indenture; provided, however, that at and after the Effective Time, the portion
of each Daily Settlement Amount payable in cash under the Indenture upon the conversion of a Note shall continue to be payable in cash. 
 Section 4. Conditions to Effectiveness of Supplemental Indenture and to Operation of Amendments Made Hereby. This Supplemental Indenture shall become effective immediately upon the Effective
Time. 
 Section 5. Counterparts. This Supplemental Indenture may be executed in any number of counterparts, each of
which so executed shall together constitute but one and the same instrument. 
 Section 6. Severability. In case any
provision in this Indenture shall be invalid, illegal or unenforceable, the validity, legality and enforceability of the remaining provisions shall not in any way be affected or impaired thereby. 

Section 7. Governing Law. This Supplemental Indenture shall be governed by and construed in accordance with the laws of the
State of New York. 
 Section 8. Trustee. The Trustee makes no representation as the validity or sufficiency of this
Supplemental Indenture. 
 [Signature page follows.] 

  
 3 

 IN WITNESS WHEREOF, the parties hereto have caused this Supplemental Indenture to be
duly executed, all as of the date first above written. 
  

			
	MASSEY ENERGY COMPANY
		
	By:	 	 /s/ Richard R. Grinnan

	Name:	 	Richard R. Grinnan
	Title:	 	Vice President and Secretary
	
	ADDITIONAL GUARANTOR:
	
	ALPHA NATURAL RESOURCES, INC.
		
	By:	 	 /s/ Frank J. Wood

	Name:	 	Frank J. Wood
	Title:	 	Executive Vice President, Chief Financial Officer, Treasurer and Assistant Secretary

  
 3.25%
Convertible Notes Supplemental Indenture 

 
	
	ORIGINAL GUARANTORS:
	
	A. T. MASSEY COAL COMPANY, INC.
	ALEX ENERGY, INC.
	ARACOMA COAL COMPANY, INC.
	BANDMILL COAL CORPORATION
	BANDYTOWN COAL COMPANY
	BARNABUS LAND COMPANY
	BELFRY COAL CORPORATION
	BEN CREEK COAL COMPANY
	BIG BEAR MINING COMPANY
	BLACK KING MINE DEVELOPMENT CO.
	BOONE EAST DEVELOPMENT CO.
	BOONE ENERGY COMPANY
	BOONE WEST DEVELOPMENT CO.
	CENTRAL PENN ENERGY COMPANY, INC.
	CENTRAL WEST VIRGINIA ENERGY COMPANY
	CERES LAND COMPANY
	CLEAR FORK COAL COMPANY
	CRYSTAL FUELS COMPANY
	DEHUE COAL COMPANY
	DELBARTON MINING COMPANY
	DEMETER LAND COMPANY
	DOUGLAS POCAHONTAS COAL CORPORATION
	DRIH CORPORATION
	DUCHESS COAL COMPANY
	EAGLE ENERGY, INC.
	ELK RUN COAL COMPANY, INC.
	FOGLESONG ENERGY COMPANY
	GOALS COAL COMPANY
	GREEN VALLEY COAL COMPANY
	GREYEAGLE COAL COMPANY
	HADEN FARMS, INC.
	HANNA LAND COMPANY, LLC
	(by ALEX ENERGY, INC., its Manager)
	HAZY RIDGE COAL COMPANY
	HIGHLAND MINING COMPANY
	HOPKINS CREEK COAL COMPANY
	INDEPENDENCE COAL COMPANY, INC.
	JACKS BRANCH COAL COMPANY
	JOBONER COAL COMPANY
	KANAWHA ENERGY COMPANY
	KNOX CREEK COAL CORPORATION
	LAUREN LAND COMPANY LAXARE, INC.
	LOGAN COUNTY MINE SERVICES, INC.
	LONG FORK COAL COMPANY

  
 3.25%
Convertible Notes Supplemental Indenture 

 
	
	LYNN BRANCH COAL COMPANY, INC.
	MAJESTIC MINING, INC.
	MARFORK COAL COMPANY, INC.
	MARTIN COUNTY COAL CORPORATION
	MASSEY COAL SALES COMPANY, INC.
	MASSEY GAS & OIL COMPANY
	NEW MARKET LAND COMPANY
	NEW RIDGE MINING COMPANY
	NEW RIVER ENERGY CORPORATION
	NICCO CORPORATION
	NICHOLAS ENERGY COMPANY
	OMAR MINING COMPANY
	PEERLESS EAGLE COAL CO.
	PERFORMANCE COAL COMPANY
	PETER CAVE MINING COMPANY
	PILGRIM MINING COMPANY, INC.
	POWER MOUNTAIN COAL COMPANY
	RAVEN RESOURCES, INC.
	RAWL SALES & PROCESSING CO.
	ROSTRAVER ENERGY COMPANY
	ROAD FORK DEVELOPMENT COMPANY, INC.
	ROBINSON-PHILLIPS COAL COMPANY
	RUM CREEK COAL SALES, INC.
	RUSSELL FORK COAL COMPANY
	SC COAL CORPORATION
	SCARLET DEVELOPMENT COMPANY
	SHANNON-POCAHONTAS COAL CORPORATION
	SHENANDOAH CAPITAL MANAGEMENT CORP.
	SIDNEY COAL COMPANY, INC.
	SPARTAN MINING COMPANY
	STIRRAT COAL COMPANY
	STONE MINING COMPANY
	SUPPORT MINING COMPANY
	SYCAMORE FUELS, INC.
	T.C.H. COAL CO.
	TALON LOADOUT COMPANY
	TENNESSEE CONSOLIDATED COAL COMPANY
	TENNESSEE ENERGY CORP.
	THUNDER MINING COMPANY
	TOWN CREEK COAL COMPANY
	TRACE CREEK COAL COMPANY
	TUCSON LIMITED LIABILITY COMPANY,
	(by: ALEX ENERGY, INC., its Manager)
	VANTAGE MINING COMPANY
	WEST KENTUCKY ENERGY COMPANY
	WHITE BUCK COAL COMPANY

  
 3.25%
Convertible Notes Supplemental Indenture 

 
			
	WILLIAMS MOUNTAIN COAL COMPANY
	WYOMAC COAL COMPANY, INC.
	JST MINING COMPANY
	JST LAND COMPANY
	CUMBERLAND RESOURCES CORPORATION
	POWELL RIVER RESOURCES
	JST RESOURCES LLC
	ALLIANCE COAL CORPORATION
	BIG LAUREL MINING CORPORATION
	BLUFF SPUR COAL CORPORATION
	BULL MOUNTAIN MINING CORPORATION
	CUMBERLAND EQUIPMENT CORPORATION
	DORCHESTER ENTERPRISES, INCORPORATED
	GUEST MOUNTAIN MINING CORPORATION
	MEADOW BRANCH MINING CORPORATION
	MOUNTAIN MANAGEMENT, INCORPORATED
	NORTH FORK COAL CORPORATION
	OSAKA MINING CORPORATION
	PIGEON CREEK PROCESSING CORPORATION
	WINIFREDE COAL CORPORATION
	CLOVERLICK MANAGEMENT LLC
	DORCHESTER ASSOCIATES LLC
	HARLAN RECLAMATION SERVICES LLC
	MEADOW BRANCH COAL LLC
	NINE MILE SPUR LLC
	RESOURCE DEVELOPMENT LLC
	RESOURCE LAND COMPANY LLC
	RODA RESOURCES LLC
	EXETER COAL CORPORATION
	MILL BRANCH COAL CORPORATION
	BLACK MOUNTAIN RESOURCES, LLC
	CAVE SPUR COAL LLC
	CLOVERLICK COAL COMPANY LLC
	HIGH SPLINT COAL LLC
	PANTHER MINING LLC
	STILLHOUSE MINING LLC
	EN ROUTE LLC
	MASSEY EUROPEAN SALES, INC.
	MAGGARD BRANCH COAL LLC
		
	By:	 	 /s/ Richard R. Grinnan

	Name:	 	Richard R. Grinnan
	Title:	 	Secretary

  
 3.25%
Convertible Notes Supplemental Indenture 

 
			
	MASSEY COAL SERVICES, INC.
		
	By:	 	 /s/ Richard R. Grinnan

	Name:	 	Richard R. Grinnan
	Title:	 	Vice President and Secretary

  
 3.25%
Convertible Notes Supplemental Indenture 

 
			
	 WILMINGTON TRUST COMPANY
 as Trustee

		
	By:	 	 /s/ Geoffrey J. Lewis

	Name:	 	Geoffrey J. Lewis
	Title:	 	Assistant Vice President

  
 3.25%
Convertible Notes Supplemental Indenture 

 EXHIBIT A 
 PARENT GUARANTEE 
 The undersigned (the “Parent”) hereby jointly and
severally, with the Guarantors, unconditionally guarantees, on a senior unsecured basis, to the extent set forth in the Senior Indenture (the “Base Indenture”), dated as of August 12, 2008, as supplemented by the First Supplemental
Indenture (the “First Supplemental Indenture”), dated the same date, as further supplemented by that Second Supplemental Indenture (the “Second Supplemental Indenture”) dated as of July 20, 2009, as further supplemented by
that Third Supplemental Indenture (the “Third Supplemental Indenture”), dated as of August 28, 2009, as further supplemented by that Fourth Supplemental Indenture (the “Fourth Supplemental Indenture”), dated as of
April 30, 2010, as further supplemented by that Fifth Supplemental Indenture (the “Fifth Supplemental Indenture”), dated June 29, 2010, each by and among the Issuer, the Guarantors (defined therein) and the Trustee and the Sixth
Supplemental Indenture (the “Sixth Supplemental Indenture”), dated June 1, 2011, by and among the Issuer, the Guarantors (defined therein), the Parent (defined therein) and the Trustee (the Base Indenture, the First Supplemental
Indenture, the Second Supplemental Indenture, the Third Supplemental Indenture, the Fourth Supplemental Indenture, the Fifth Supplemental Indenture and as further supplemented by the Sixth Supplemental Indenture, collectively, and as amended and
supplemented, the “Indenture”), and subject to the provisions of the Indenture, (a) the due and punctual payment of the principal of, and premium, if any, interest and additional interest, if any, with respect to the Securities, when
and as the same shall become due and payable, whether at maturity, by acceleration or otherwise, the due and punctual payment of interest on overdue principal of, and premium and, to the extent permitted by law, interest or additional interest, if
any, and the due and punctual performance of all other obligations of the Company or any Guarantor to the holders or the Trustee under this Indenture and the Securities (including amounts due the Trustee under Section 607 of the Indenture), and
(b) in case of any extension of time of payments or renewal of any Securities or any of such other obligations, that the same shall be promptly paid in full when due or performed in accordance with the terms of the extension or renewal, whether
at Stated Maturity, by acceleration or otherwise. 
 The provisions of Sections 1501, 1502, 1505 and 1507 of the Indenture are
incorporated herein except that, to the extent appropriate, all references therein to “Guarantor” shall be deemed to refer to Parent and all references therein to “Note Guarantee” shall be deemed to refer to this Parent
Guarantee. 
 Capitalized terms not otherwise defined herein shall have the meanings set forth in the Indenture. 

[Signature Page Follows] 

 IN WITNESS WHEREOF, the Guarantor has caused this Parent Guarantee to be signed by a duly
authorized officer: 
  

			
	ALPHA NATURAL RESOURCES, INC.
		
	By:	 	 /s/ Frank J. Wood

	Name:	 	Frank J. Wood
	Title:	 	Executive Vice President, Chief Financial Officer, Treasurer and Assistant Secretary

 Dated: June 1, 2011

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